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JPS6475494A - Production of n-acyl, o,s-dimethylphosphoroamidethioate - Google Patents

Production of n-acyl, o,s-dimethylphosphoroamidethioate

Info

Publication number
JPS6475494A
JPS6475494A JP23348087A JP23348087A JPS6475494A JP S6475494 A JPS6475494 A JP S6475494A JP 23348087 A JP23348087 A JP 23348087A JP 23348087 A JP23348087 A JP 23348087A JP S6475494 A JPS6475494 A JP S6475494A
Authority
JP
Japan
Prior art keywords
formula
expressed
dimethylphosphoroamidethioate
acid anhydride
dimethyl sulfate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP23348087A
Other languages
Japanese (ja)
Inventor
Michio Tani
Masaji Nojiri
Tsutomu Imagawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Soda Co Ltd
Original Assignee
Nippon Soda Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Soda Co Ltd filed Critical Nippon Soda Co Ltd
Priority to JP23348087A priority Critical patent/JPS6475494A/en
Publication of JPS6475494A publication Critical patent/JPS6475494A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To obtain the titled compound advantageously on an industrial scale in acylation attained in high yield as well as in facilitated separation of catalyst, by reacting O,S-dimethylphosphorothioate with an acid anhydride using dimethyl sulfate as a catalyst. CONSTITUTION:O,S-dimethylphosphoroamidethioate expressed by formula I is reacted with an acid anhydride expressed by formula II (R is lower alkyl) using dimethyl sulfate expressed by the formula (CH3)2SO4, normally at 0-100 deg.C for 30min-several hr to provide the aimed compound expressed by formula III. Further more, when O,O-dimethylphosphoroamidethioate is reacted with dimethyl sulfate to afford a compound expressed by formula I, an acid anhydride expressed by formula II is added to the above-mentioned reaction liquid without liberating the compound expressed by formula I and acylation is carried out.
JP23348087A 1987-09-17 1987-09-17 Production of n-acyl, o,s-dimethylphosphoroamidethioate Pending JPS6475494A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP23348087A JPS6475494A (en) 1987-09-17 1987-09-17 Production of n-acyl, o,s-dimethylphosphoroamidethioate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP23348087A JPS6475494A (en) 1987-09-17 1987-09-17 Production of n-acyl, o,s-dimethylphosphoroamidethioate

Publications (1)

Publication Number Publication Date
JPS6475494A true JPS6475494A (en) 1989-03-22

Family

ID=16955666

Family Applications (1)

Application Number Title Priority Date Filing Date
JP23348087A Pending JPS6475494A (en) 1987-09-17 1987-09-17 Production of n-acyl, o,s-dimethylphosphoroamidethioate

Country Status (1)

Country Link
JP (1) JPS6475494A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0703238A1 (en) 1994-09-22 1996-03-27 Sumitomo Chemical Company, Limited A method for purifying O,S-dimethyl N-acetylphosphoramidothioate
CN112979698A (en) * 2021-02-24 2021-06-18 湖南沅江赤蜂农化有限公司 Synthesis method of acephate

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0703238A1 (en) 1994-09-22 1996-03-27 Sumitomo Chemical Company, Limited A method for purifying O,S-dimethyl N-acetylphosphoramidothioate
US5616769A (en) * 1994-09-22 1997-04-01 Sumitomo Chemical Company, Limited Method for purifying O,S-dimethyl N-acetylphosphoramidothioate
US5684174A (en) * 1994-09-22 1997-11-04 Sumitomo Chemical Company, Limited Method for purifying O, S-dimethyl N-acetylphosphoramidothioate
CN112979698A (en) * 2021-02-24 2021-06-18 湖南沅江赤蜂农化有限公司 Synthesis method of acephate

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