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JPS5944831A - Deposition of thin film - Google Patents

Deposition of thin film

Info

Publication number
JPS5944831A
JPS5944831A JP15470382A JP15470382A JPS5944831A JP S5944831 A JPS5944831 A JP S5944831A JP 15470382 A JP15470382 A JP 15470382A JP 15470382 A JP15470382 A JP 15470382A JP S5944831 A JPS5944831 A JP S5944831A
Authority
JP
Japan
Prior art keywords
film
deposition
deposited
resistor pattern
etching
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP15470382A
Other languages
Japanese (ja)
Inventor
Tsunetoshi Arikado
経敏 有門
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Tokyo Shibaura Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp, Tokyo Shibaura Electric Co Ltd filed Critical Toshiba Corp
Priority to JP15470382A priority Critical patent/JPS5944831A/en
Publication of JPS5944831A publication Critical patent/JPS5944831A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Drying Of Semiconductors (AREA)
  • Physical Deposition Of Substances That Are Components Of Semiconductor Devices (AREA)

Abstract

PURPOSE:To deposit an insulating film on an uneven surface of a substrate with a good step coverage by performing etching and deposition at the same time and making deposition speed faster than etching speed. CONSTITUTION:An Al-1%Si alloy film 14 of 1mum thickness is deposited on a P type Si substrate 12 by a magnetron sputtering equipment and a resistor pattern 15 of 1mum width for Al wiring is also formed. Then Al film 14 is etched using the resistor pattern 15 as a masking and the resistor pattern 15 is removed. Then a silicon oxide film 16 is deposited by ion plating method in the atmosphere of O2/CF4 which contains CF4 whose floating ratio against O2 is 1/10. Then the second Al film 17 is deposited by magnetron sputtering method.

Description

【発明の詳細な説明】 〔発明の属する技術分野〕 この発明は、薄膜堆積方法に関し′ヒCに凹凸ある7+
’−扱、34而七でのγ;、’J、 liへ堆れ1方法
の改良に係わる。
[Detailed description of the invention] [Technical field to which the invention pertains] This invention relates to a method for depositing a thin film.
'- Treatment, 34 and 7, γ;, 'J, li 1 Concerning the improvement of the method.

[i11’、31′技術とその問題点〕近年it%(L
 S Iロジックデバイスには、Ae多層配線技術が必
要とされCいる。多層配線技術には、層1110pH、
I!’i’= lli卓が必す5゛2ニされる。層間絶
縁脱杭1−51帽圧が充分大であること、リーク?イ淀
が小であることおよび可動イオンを含まないこと等、絶
、縁1時と17で本来備えるべき性ηに加えて、堆積中
に1層目のAeにヒロックを生じない様、低温で堆稈+
 r”3’ 61°であること1、・よびステップカバ
レッジが口りjであることなどの干」三値が要求される
[i11', 31' technology and its problems] In recent years it% (L
SI logic devices require Ae multilayer wiring technology. Multilayer wiring technology includes layer 1110pH,
I! 'i'=lli table must be 5゛2. Interlayer insulation pile removal 1-51 Check that the cap pressure is sufficiently large, leakage? In addition to the properties η that should be present in the Ae layers 1 and 17, such as having a small Ae stagnation and not containing mobile ions, it is necessary to Culm +
The following three values are required: r"3' is 61 degrees, and the step coverage is 61 degrees.

従来、層間絶縁膜(・」1、スパッタリング法やグラス
Y CV D (Che+n1cal Vapor r
)epnsition )汐によりバ2成されてきたが
、質的に良好な絶縁膜を形成するだめには、300°0
以上の基板温用を必9jiとすZ)1−、ステップカバ
レッジ1は必ずしも1.lJJでi、、1ないという問
題点があった。
Conventionally, interlayer insulating films (・'1, sputtering method and glass YCVD (Che+n1cal vapor r
)epnstation) Although the insulation film has been formed by Ushio, in order to form a qualitatively good insulating film, it is necessary to
The above substrate temperature must be 9jiZ) 1-, step coverage 1 is not necessarily 1. There was a problem that there was no i,,1 in lJJ.

〔発明の目的〕[Purpose of the invention]

本発明は、上記り”1#点に鮨みてなされたものてちり
、凹凸ある基板表面上に良好なステップカバ1゜ツジで
絶縁膜の堆積を行なうとどを目的とl、 fいる。
The present invention is based on the above-mentioned point 1# and aims to deposit an insulating film on an uneven substrate surface with a good step cover.

〔発明の概要〕[Summary of the invention]

本発明は薄1漠の堆uiと准稍しfr、 II!Jの:
T−ソブングを同時に進行さぜることを/lす徴とジろ
The present invention is similar to the one described above, II! J's:
T-Sobung should be progressed at the same time.

〔発明の効果〕〔Effect of the invention〕

本発明によればステップカバレッジの良t「な薄II(
厚l(1精がoJ能である。
According to the present invention, step coverage is good.
Thick l (1 essence is oJ ability.

〔発明の実施例〕[Embodiments of the invention]

本発明において4−J1薄膜形成の一手段と1〜でイメ
ンプレーデイング法を採用した。第1図は、本発明で1
4・用し/r、イオンブレーティング装置〜の概略を示
す。ペルジャー1内に、ウエーノ・ステージ2゜rf放
電用コイル醒極3.ノ・−ス4.宜子銃5を備える。排
気糸は、油回転ポンプ11とクライオポンプ6から成る
。バリアプルリークパルプ7を介[7でペルジャー1内
に酸素ガスを導入し、10’’rn rr台の圧力下で
、ハース4内のシリコン8を電子ヒームによりXIに梵
さぜ、スイッチング回y?i 9を介しでrf tKi
)Gi 1 (+から供給されたrf電力により、蒸発
し7j3iと0.を数箱せしめる。81は02分子およ
び放電によって発生した酸素ラジカルヤイメンによって
酸化ゴれ、ウエーノ・ステージ2下面に固定されたウェ
ーノル11上に堆f0する。rf放電することなく、酸
素分子だけで蒸発したシリコンの酸化は可卵である。こ
の方法を、反応性蒸]楕汐と叶ぶことにする。
In the present invention, the Imen plating method was adopted as one means for forming the 4-J1 thin film. FIG.
4. An outline of the ion blating device is shown. Inside the Pelger 1, a Ueno stage 2° RF discharge coil is placed.3. No-s 4. Equipped with Yiko gun 5. The exhaust line consists of an oil rotary pump 11 and a cryopump 6. Oxygen gas is introduced into the perger 1 through the barrier pull leak pulp 7 [7], and under a pressure on the order of 10''rnrr, the silicon 8 in the hearth 4 is heated to ? rf tKi via i9
)Gi 1 (Due to the rf power supplied from +, it is evaporated and several boxes of 7j3i and 0. The oxidation of silicon evaporated by oxygen molecules only without RF discharge is possible.This method will be realized as a reactive evaporation method.

第2図は、1μmの高さの矩形パターンおよび:3μ所
程度の71ダの上に約1μm71斤の5i02股を准1
1°・1.だ21ハ合の形状を模式的に示しだ図であ2
)。′++J子ビー広ビーム蒸発源1.2KW、 O,
圧力3 X 10−’ Torrと1−、た。
Figure 2 shows a rectangular pattern with a height of 1 μm and a 5i02 crotch of about 1 μm and 71 loaves on a 71 da of about 3 μm.
1°・1. Figure 2 schematically shows the shape of the joint.
). '++J Bee wide beam evaporation source 1.2KW, O,
The pressure was 3 x 10 Torr and 1 Torr.

(a)(ハ反応性蒸着法の場合であり、ステップエツジ
において、オーバーハング形状を呈するっこれrat 
1スパツタリング法や蒸着法において一般的にすc−)
れる現象であり、ステップによるシャドインク効堅カ原
因テアル。一方(+3) ld、rf ′(I力5 (
1(l Wのイオンシレーティング法−で116 fl
’i t、だを1台であ2)か、良好な形状を呈する。
(a) (C) This is the case of the reactive vapor deposition method, and this rat exhibits an overhang shape at the step edge.
1 Generally in sputtering method and vapor deposition method c-)
This is a phenomenon caused by the shadow ink effect caused by steps. On the other hand (+3) ld, rf ′(I force 5 (
1 (l W ion silating method - 116 fl
'It is possible to obtain a good shape with just one machine.

これ1は放電し一〇ノ′ラスマを発。This 1 discharges and emits 10 no's of lasma.

生じた結果、試料表面にもシースが形成びれ、イメンが
基板に対して乎直に入射し1.唯f/l した)1・、
Vの一部をリスバッターしたためシャドイング効果が緩
和式れたものと考えられる。
As a result, a sheath is also formed on the sample surface, and the particles are directly incident on the substrate.1. Yui f/l did) 1・,
It is thought that the shadowing effect was alleviated because part of the V was subjected to squirrel batter.

3/17’l1%を度の溝の場合に1rl1、;i’t
 ’l l:l (+1)のどとくイオンブレーティン
グ法により埋め込むことブベE11 rii’であるが
、1μフルあるいはザフ゛ミクロンの濯3の」甲め込み
は容易ではない。イオンシレーティング法においても、
オーバーハング形状となる。このオーバーハング形状と
なる溝の寸法は、Iff¥frt速度と密接な関係があ
る。第3図は、イオンシレーティング法において、Jl
ITn高さのステップにはさ゛まれた(+”#に、1μ
ml’lのS +021i/Mを堆積した場合にrf 
′rig力5 U OW、 (’)t 11−力3 X
 10−”rorr ”4子ビーム1.2KWにお0る
メーパーハング形状を呈する溝の寸法と堆積1乗FWの
関係4・示す。たとえ17.l:1.i1和1!(慮p
i2000人/分の時、寸法11nnの溝ではオーバー
ハング形状となり、うまく埋め込めないが、150X、
/分では、05μmの溝までオーバーハング形状を示さ
ず埋め込むことが司#i1′である。この現象(lよ、
第2図でも述べたとおり、リスバッターの効〃・で説明
されると考えられる。す/rわち、一定rf電力による
)J’(ti℃下で1・l1、圧力か−>’rlでろ、
ろ限り、発生するイオンlji’、 If、1、一定で
あり、リスバッタ−1東度は一定である。
3/17'l1% in case of groove of degree 1rl1, ;i't
Although it is possible to embed it using the ion blating method, it is not easy to embed it with 1μ full or 1 μm ion blasting. Also in the ion silating method,
It has an overhang shape. The dimensions of the groove forming this overhang shape are closely related to the If\frt speed. Figure 3 shows Jl in the ion silating method.
ITn height step (+”#, 1μ
rf when depositing ml'l of S+021i/M
'rig force 5 U OW, (')t 11-force 3 X
10-"Relationship 4 between the dimension of a groove exhibiting a mapper hang shape and the first power of deposition FW for a 1.2 KW quadrupling beam is shown. Parable 17. l:1. i1 sum 1! (considered)
At i2000 people/min, a groove with a dimension of 11 nn will have an overhang shape and cannot be filled well, but 150X,
/min, it is necessary to embed the groove up to 05 μm without showing an overhang shape. This phenomenon (l,
As mentioned in Figure 2, this is thought to be explained by the effect of squirrel batter. S/r, that is, due to constant rf power) J' (1·l1 at ti℃, pressure ->'rl,
As long as the ions are constant, the generated ions lji', If, 1 are constant, and the east degree of the squirrel batter 1 is constant.

このリスバッタi!i Inに対して、堆積速度が(止
めて犬である時、ごく少h1のリスバッターでりよシャ
ドイング効果を抑制しきれ外いため、刊−バーハング形
状となる。一方堆fit 1yfi IQ、が小の時、
リスバッターは充分に作用し、オーバーハング形状を抑
制する。
This squirrel grasshopper i! For i In, when the deposition rate is small, the shadowing effect cannot be suppressed by a very small squirrel batter, resulting in a bar hang shape.On the other hand, the deposition rate is small. Time,
The squirrel batter works well and suppresses the overhang shape.

上記結果からの9”、Ii推として、リスバッターとI
’ij1様な方向性エツチングを強制的に起と干ことに
より、より狭い溝を埋め込むことが用卵であると(II
Mされる。そこで、系内に02: CF4= 10 :
 1の1111杓でCF4ガス多・導入して第3図と同
様の実験を行なった結芽・を第4図に示す。方向性エツ
チングの動片は明らかである。
From the above results, Squirrel Batter and I are recommended as 9” and Ii.
The idea is to embed a narrower groove by forcing directional etching like 'ij1 (II
M is done. Therefore, in the system 02: CF4= 10:
Fig. 4 shows the germination results of an experiment similar to Fig. 3 in which a large amount of CF4 gas was introduced using the 1111 ladle of No. 1. The movement of directional etching is obvious.

以下に本発明の実施例を図面を用いて説、明する。Embodiments of the present invention will be described and explained below using the drawings.

P型31基板12を20枚を形成する。つづいでマグネ
トロンスパッタ装置により、he  1 % Sr 合
金膜14を1μm膜J7で堆積し、ポジ型7メトレジス
ト(東京応化社製QFPR−800)  を9J・+1
1シて、1μm、 +1]のAe配線川用しストパター
ン15を形成し。
20 P-type 31 substrates 12 are formed. Next, using a magnetron sputtering device, a he 1% Sr alloy film 14 was deposited with a thickness of 1 μm J7, and a positive type 7 metresist (QFPR-800 manufactured by Tokyo Ohka Co., Ltd.) was deposited at 9J·+1.
After that, an Ae wiring pattern 15 of 1 μm and +1 was formed.

だ(図5 (a) )。該レジストパターン15をマヌ
クトシ、CCl4/C11t (m ht 20m(1
’ 、 NIJeJt 1 : 1 ) r(出力35
0Wの苧件下でA(? IIM 1.4のエツチングを
行なった後、レジスト膜を除去し7た。ここで20枚の
Si基本を10枚づつ2和に分け、一方を0!雰囲気で
のイオンブレーティング法(0,圧力3 X 10 ’
Torr1!j  g+11出力1.2 KW 、 r
f 7J力500W)で、他方をO1/ CF4 r)
Y負1比1(1:lの割合でCF、を含有した雰囲気下
でのイオンフレーティング法で、それぞれ酸化シリコン
膜16をftfi (J4 Lだ。47いてマグネトロ
ンスパッタ法により2層目のAl膜17を堆t/lL、
1層]1と同様の工、T′−でパターン形式を行なった
。次にfPJ1層目と同様の条件で2P目の^e膜のエ
ツチングを行庁いhe配縮を形成した。(+))該2層
目のA6配線のオープン/ショートテストを行なったと
ころ (N Fl、を含まない争件下で層間?縁膜の堆
積を行なつt二場合(f」:、I N1目のAI!膜エ
ツジ、1−?)I(K:位置する2層目のAe配線にメ
ープン不良が多く見られた。
(Figure 5(a)). The resist pattern 15 is coated with CCl4/C11t (m ht 20m (1
' , NIJeJt 1 : 1 ) r (output 35
After performing A(? IIM 1.4 etching) under 0W conditions, the resist film was removed and the 20 Si basics were divided into 2 sums of 10 each, and one was etched in a 0! atmosphere. Ion brating method (0, pressure 3 x 10'
Torr1! j g+11 output 1.2 KW, r
f 7J force 500W) and the other O1/CF4 r)
The silicon oxide film 16 was formed by ftfi (J4 L) using an ion plating method in an atmosphere containing CF at a ratio of 1:1, and the second layer of Al was formed by magnetron sputtering. Deposit the membrane 17/lL,
[Layer 1] The same process as in 1 was carried out, and a pattern was formed at T'-. Next, the 2P^e film was etched under the same conditions as for the first fPJ layer to form a he arrangement. (+)) An open/short test was conducted on the A6 wiring in the second layer. Eye AI! Membrane edge, 1-?) I (K: Many maple defects were observed in the located Ae wiring of the second layer.

【図面の簡単な説明】[Brief explanation of drawings]

t111図は、本発明で使用したイオンレ“レーティン
グj0 f#fの概略を示す図、第2図は、スペースに
よ?ける堆積形状を示す図、第3図及び$4図は、堆積
速熱゛と埋め込み可能なスペース寸法との関係金示す図
、第5図は、Ae配線のメーグン/ショートテスト用試
料作製二■二程を示す断面図である。 1・・・ペルジャー  21ウエーハスデージ3・・コ
イル?IHU   4・・・ハース5・・・’r眞子Q
フィラメント 6・・クライオボニ・)7・・・バリア
プルリークパルプ  8・・・、919・・・マツチン
グ回路   10・・・rf電源11・・油回転ポンプ
    12・・・F’fFASi基版13・・基部1
3膜      14・・1層目Ne s15・・Al
配縮用レジストパターン 16・・・酸化シリコン膜   17・・・2層目Ae
 +++a(7317)代理人弁理士 則 近 憲 佑
(+5.か1名)第  1  図 第2図 第  3  図 in;噸ヒ、及 (1〆も〆3)゛ン 第  4  図 五播連及(iβ)
Figure t111 is a diagram showing the outline of the ion rating j0f#f used in the present invention, Figure 2 is a diagram showing the deposition shape depending on the space, Figures 3 and 4 are diagrams showing the deposition rate Figure 5 is a cross-sectional view showing the steps 2 and 2 of preparing a sample for the Ae wiring magnet/short test. 1... Pelger 21 wafer stage 3 ... Coil? IHU 4... Hearth 5...'r Mako Q
Filament 6...Cryobony) 7...Barrier pull leak pulp 8..., 919...Matching circuit 10...RF power source 11...Oil rotary pump 12...F'fFASi base plate 13... base 1
3 films 14...1st layer Ne s15...Al
Resist pattern for shrinkage 16...Silicon oxide film 17...Second layer Ae
+++a (7317) Representative Patent Attorney Kensuke Chika (+5. or 1 person) Figure 1, Figure 2, Figure 3 in; (iβ)

Claims (1)

【特許請求の範囲】 (11エツチングと堆積を同時に進行させ、堆積:、4
< r’、−がエツチング11豊8をトまわる東部下で
行々うことをQ!?徴とする+iす+lR堆[【゛1方
法。 (2)  l’l/!νiはスパッタリンク法、蒸着法
またはイオンブレーティング法により行われ、系内に少
Mの少ブcくとも] 1fffのハロゲン元素を含有す
るガスがダ゛7人されることを特徴とする特許請求範囲
第1^ J)′(ハ’ il+! 0) 7411. l内■情
方法。
[Claims] (11 Etching and deposition proceed simultaneously, deposition:, 4
<r', - Q to go under the eastern part of etching 11 Toyo 8! ? Sign +iS +lR [[゛1 method. (2) l'l/! A patent characterized in that ν is performed by a sputter link method, vapor deposition method, or ion blating method, and a gas containing a halogen element of at least 1fff with a small amount of M is introduced into the system. Claim No. 1^ J)'(Ha'il+! 0) 7411. ■Inner way.
JP15470382A 1982-09-07 1982-09-07 Deposition of thin film Pending JPS5944831A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP15470382A JPS5944831A (en) 1982-09-07 1982-09-07 Deposition of thin film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP15470382A JPS5944831A (en) 1982-09-07 1982-09-07 Deposition of thin film

Publications (1)

Publication Number Publication Date
JPS5944831A true JPS5944831A (en) 1984-03-13

Family

ID=15590102

Family Applications (1)

Application Number Title Priority Date Filing Date
JP15470382A Pending JPS5944831A (en) 1982-09-07 1982-09-07 Deposition of thin film

Country Status (1)

Country Link
JP (1) JPS5944831A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61182219A (en) * 1985-02-08 1986-08-14 Nippon Telegr & Teleph Corp <Ntt> Thin film growing method
JPS6362238A (en) * 1986-09-02 1988-03-18 Toshiba Corp Depositing method of thin film
US5112776A (en) * 1988-11-10 1992-05-12 Applied Materials, Inc. Method for planarizing an integrated circuit structure using low melting inorganic material and flowing while depositing
US5244841A (en) * 1988-11-10 1993-09-14 Applied Materials, Inc. Method for planarizing an integrated circuit structure using low melting inorganic material and flowing while depositing
JPH07166360A (en) * 1984-10-25 1995-06-27 Applied Materials Inc Method for making film adhere from reactive gas plasma on base with small-sized and high density step shape
US6087276A (en) * 1996-10-29 2000-07-11 National Science Council Method of making a TFT having an ion plated silicon dioxide capping layer

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07166360A (en) * 1984-10-25 1995-06-27 Applied Materials Inc Method for making film adhere from reactive gas plasma on base with small-sized and high density step shape
JPS61182219A (en) * 1985-02-08 1986-08-14 Nippon Telegr & Teleph Corp <Ntt> Thin film growing method
JPS6362238A (en) * 1986-09-02 1988-03-18 Toshiba Corp Depositing method of thin film
US5112776A (en) * 1988-11-10 1992-05-12 Applied Materials, Inc. Method for planarizing an integrated circuit structure using low melting inorganic material and flowing while depositing
US5244841A (en) * 1988-11-10 1993-09-14 Applied Materials, Inc. Method for planarizing an integrated circuit structure using low melting inorganic material and flowing while depositing
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