JPS57200407A - Polymerization of alpha-olefin - Google Patents
Polymerization of alpha-olefinInfo
- Publication number
- JPS57200407A JPS57200407A JP8569181A JP8569181A JPS57200407A JP S57200407 A JPS57200407 A JP S57200407A JP 8569181 A JP8569181 A JP 8569181A JP 8569181 A JP8569181 A JP 8569181A JP S57200407 A JPS57200407 A JP S57200407A
- Authority
- JP
- Japan
- Prior art keywords
- olefin
- compound
- aralkyl
- polymerizing
- cycloalkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
PURPOSE: To produce a highly stereoregular polyolefin in high activity, by polymerizing an α-olefin with a catalyst comprising a specified activated titanium catalytic component and a specified organoaluminum compound.
CONSTITUTION: A polyolefin having high polymerization activity, high stereoregularity and a high bulk density is produced by polymerizing an α-olefin with the aid of a catalyst comprising (A) a product obtained by reacting a titanium tetrahalide with an alkoxide of formulaIor II, wherein R1 and R2 are each a 1W20C alkyl, cycloalkyl, aryl or aralkyl, and reacting the resulting solid substance with a halogen-containing titanium compound of formula III, wherein R3 is a 1W20C alkyl, cycloalkyl, aryl or aralkyl, X is a halogen and n is in the range of 0≤n<4, in the presence of an electron-donating compound (e.g., ethyl benzoate) and (B) an organoaluminum compound (e.g., trimethylaluminum).
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8569181A JPS57200407A (en) | 1981-06-05 | 1981-06-05 | Polymerization of alpha-olefin |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8569181A JPS57200407A (en) | 1981-06-05 | 1981-06-05 | Polymerization of alpha-olefin |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS57200407A true JPS57200407A (en) | 1982-12-08 |
JPS64963B2 JPS64963B2 (en) | 1989-01-10 |
Family
ID=13865860
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP8569181A Granted JPS57200407A (en) | 1981-06-05 | 1981-06-05 | Polymerization of alpha-olefin |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57200407A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4870040A (en) * | 1987-11-24 | 1989-09-26 | Shell Oil Company | Olefin polymerization catalysts from soluble magnesium alkoxides made from alkyl or aryl magnesium mixed with a branched or aromatic aldehyde |
US4870039A (en) * | 1987-11-24 | 1989-09-26 | Shell Oil Company | Olefin polymerization catalysts from soluble magnesium alkoxides made from mixed magnesium alkyls and aryls |
JP2008518075A (en) * | 2004-10-29 | 2008-05-29 | サムソン トータル ペトロケミカルズ カンパニー リミテッド | Propylene polymerization catalyst and propylene polymerization method using the same |
-
1981
- 1981-06-05 JP JP8569181A patent/JPS57200407A/en active Granted
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4870040A (en) * | 1987-11-24 | 1989-09-26 | Shell Oil Company | Olefin polymerization catalysts from soluble magnesium alkoxides made from alkyl or aryl magnesium mixed with a branched or aromatic aldehyde |
US4870039A (en) * | 1987-11-24 | 1989-09-26 | Shell Oil Company | Olefin polymerization catalysts from soluble magnesium alkoxides made from mixed magnesium alkyls and aryls |
JP2008518075A (en) * | 2004-10-29 | 2008-05-29 | サムソン トータル ペトロケミカルズ カンパニー リミテッド | Propylene polymerization catalyst and propylene polymerization method using the same |
Also Published As
Publication number | Publication date |
---|---|
JPS64963B2 (en) | 1989-01-10 |
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