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JPS56161407A - Polymerization of ethylene - Google Patents

Polymerization of ethylene

Info

Publication number
JPS56161407A
JPS56161407A JP6564080A JP6564080A JPS56161407A JP S56161407 A JPS56161407 A JP S56161407A JP 6564080 A JP6564080 A JP 6564080A JP 6564080 A JP6564080 A JP 6564080A JP S56161407 A JPS56161407 A JP S56161407A
Authority
JP
Japan
Prior art keywords
organic
compound
catalyst
mixture containing
mole ratio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP6564080A
Other languages
Japanese (ja)
Other versions
JPS6360766B2 (en
Inventor
Hiromi Miyanishi
Takeo Shimada
Shigekazu Hayashi
Mitsuyuki Matsuura
Ryuhei Matsui
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Petrochemical Co Ltd
Original Assignee
Mitsubishi Petrochemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Petrochemical Co Ltd filed Critical Mitsubishi Petrochemical Co Ltd
Priority to JP6564080A priority Critical patent/JPS56161407A/en
Priority to DE19803027885 priority patent/DE3027885A1/en
Priority to GB8024252A priority patent/GB2057468B/en
Publication of JPS56161407A publication Critical patent/JPS56161407A/en
Publication of JPS6360766B2 publication Critical patent/JPS6360766B2/ja
Granted legal-status Critical Current

Links

Landscapes

  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

PURPOSE: To obtain a low-melt flow index polymer in high yields, by (co)polymerizing ethylene at high pressure and temperature by use of a highly active Ziegler catalyst obtained from an organic Al compound, a titanium compound, etc.
CONSTITUTION: A catalyst is prepared by combining (A) a mixture containing at a specific mole ratio organic Al compounds represented by formulas I and II, wherein R1, R2 and R3 are each a C1WC10 hydrocarbon, X1 is a halogen or H, 0≤m≤2 and 1≤n≤2, or a mixture containing at a specified mole ratio an organic Al compound of formula I and an alkylsiloxalane derivative represented by formula III, wherein R4WR8 are each a C1WC10 saturated hydrocarbon or H, with (B) a solid product obtained by contacting a titanium compound with an activated magnesium dihalide. Then, the polymer of the purpose is obtained by (co)polymerizing ethylene at a high pressure of at least 200kg/cm2 and a high temperature of at least 125°C by use of the catalyst.
COPYRIGHT: (C)1981,JPO&Japio
JP6564080A 1979-07-24 1980-05-17 Polymerization of ethylene Granted JPS56161407A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP6564080A JPS56161407A (en) 1980-05-17 1980-05-17 Polymerization of ethylene
DE19803027885 DE3027885A1 (en) 1979-07-24 1980-07-23 POLYMERIZATION OF ETHYLENE
GB8024252A GB2057468B (en) 1979-07-24 1980-07-24 Process for polymerizing ethylene

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6564080A JPS56161407A (en) 1980-05-17 1980-05-17 Polymerization of ethylene

Publications (2)

Publication Number Publication Date
JPS56161407A true JPS56161407A (en) 1981-12-11
JPS6360766B2 JPS6360766B2 (en) 1988-11-25

Family

ID=13292814

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6564080A Granted JPS56161407A (en) 1979-07-24 1980-05-17 Polymerization of ethylene

Country Status (1)

Country Link
JP (1) JPS56161407A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59133210A (en) * 1982-12-24 1984-07-31 ソシエテ・シミツク・デ・シヤルボナ−ジユ Catalysts for polymerizing ethylene and polymerization
JPS6025993A (en) * 1983-07-05 1985-02-08 デユポン・カナダ・インコ−ポレ−テツド Manufacture of triethyldimethylsiloxalane
JPS6032805A (en) * 1983-08-02 1985-02-20 Ube Ind Ltd Polymerization of ethylene
JPS6369805A (en) * 1986-09-11 1988-03-29 Mitsubishi Chem Ind Ltd Production of olefin polymer

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB828828A (en) * 1955-10-10 1960-02-24 Dow Chemical Co Polymerization of alpha-olefines
JPS5050487A (en) * 1973-08-21 1975-05-06
JPS52103485A (en) * 1976-02-25 1977-08-30 Charbonnages Ste Chimique Polymerization of ethylene
JPS5426889A (en) * 1977-08-01 1979-02-28 Charbonnages Ste Chimique Method of controlling ethylene polymerization by separative injection of catalyst component
JPS5445696A (en) * 1977-09-17 1979-04-11 Mitsubishi Petrochem Co Ltd Catalyst composition for olefin polymerization
JPS55131007A (en) * 1979-03-23 1980-10-11 Charbonnages Ste Chimique Ethyleneepropylene copolymer and its manufacture

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB828828A (en) * 1955-10-10 1960-02-24 Dow Chemical Co Polymerization of alpha-olefines
JPS5050487A (en) * 1973-08-21 1975-05-06
JPS52103485A (en) * 1976-02-25 1977-08-30 Charbonnages Ste Chimique Polymerization of ethylene
JPS5426889A (en) * 1977-08-01 1979-02-28 Charbonnages Ste Chimique Method of controlling ethylene polymerization by separative injection of catalyst component
JPS5445696A (en) * 1977-09-17 1979-04-11 Mitsubishi Petrochem Co Ltd Catalyst composition for olefin polymerization
JPS55131007A (en) * 1979-03-23 1980-10-11 Charbonnages Ste Chimique Ethyleneepropylene copolymer and its manufacture

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59133210A (en) * 1982-12-24 1984-07-31 ソシエテ・シミツク・デ・シヤルボナ−ジユ Catalysts for polymerizing ethylene and polymerization
JPH0531566B2 (en) * 1982-12-24 1993-05-12 Charbonnages Ste Chimique
JPS6025993A (en) * 1983-07-05 1985-02-08 デユポン・カナダ・インコ−ポレ−テツド Manufacture of triethyldimethylsiloxalane
JPS6032805A (en) * 1983-08-02 1985-02-20 Ube Ind Ltd Polymerization of ethylene
JPH0432842B2 (en) * 1983-08-02 1992-06-01 Ube Industries
JPS6369805A (en) * 1986-09-11 1988-03-29 Mitsubishi Chem Ind Ltd Production of olefin polymer

Also Published As

Publication number Publication date
JPS6360766B2 (en) 1988-11-25

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