JPS56104864A - Pyrrolidine derivative - Google Patents
Pyrrolidine derivativeInfo
- Publication number
- JPS56104864A JPS56104864A JP748180A JP748180A JPS56104864A JP S56104864 A JPS56104864 A JP S56104864A JP 748180 A JP748180 A JP 748180A JP 748180 A JP748180 A JP 748180A JP S56104864 A JPS56104864 A JP S56104864A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- compound
- alkylthio
- methylene substituted
- groups
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Pyrrole Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
NEW MATERIAL:Pyrrolidine derivatives of formula I (R1 is H, lower alkyl, formyl; R2 is hydroxymethylene, methylene substituted with lower alkoxy groups, methylene substituted with lower alkylthio groups, methylene substituted with aralkyl or lower alkylthio-lower-alkylthio groups, methyl disubstituted with lower alkoxy or alkylthio, sulfur-containing saturated heterocyclic group; X is O, S).
EXAMPLE: 3-(α-Methoxy-α-methylthio)methyl-2-thioxyopyrrolidine, which is named raphantin.
USE: Hypotensor and anesthetic and their synthetic intermediate.
PREPARATION: For example, a compound of formula II is brought into contact with lithium di-isopropylamide to increase the reactivity. Then, the compound of formula II is made to react with a formic ester to form a compound of formula I in which R2 is CHOH.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP748180A JPS56104864A (en) | 1980-01-24 | 1980-01-24 | Pyrrolidine derivative |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP748180A JPS56104864A (en) | 1980-01-24 | 1980-01-24 | Pyrrolidine derivative |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS56104864A true JPS56104864A (en) | 1981-08-20 |
JPS6310948B2 JPS6310948B2 (en) | 1988-03-10 |
Family
ID=11666950
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP748180A Granted JPS56104864A (en) | 1980-01-24 | 1980-01-24 | Pyrrolidine derivative |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS56104864A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1992012129A1 (en) * | 1991-01-10 | 1992-07-23 | Santen Pharmaceutical Co., Ltd. | Cyclic compound |
-
1980
- 1980-01-24 JP JP748180A patent/JPS56104864A/en active Granted
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1992012129A1 (en) * | 1991-01-10 | 1992-07-23 | Santen Pharmaceutical Co., Ltd. | Cyclic compound |
US5461158A (en) * | 1991-01-10 | 1995-10-24 | Santen Pharmaceutical Co., Ltd. | Substituted butaneolides and butane lactams, and pharmaceutical use thereof |
Also Published As
Publication number | Publication date |
---|---|
JPS6310948B2 (en) | 1988-03-10 |
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