JPS55137105A - Suspension stabilizer - Google Patents
Suspension stabilizerInfo
- Publication number
- JPS55137105A JPS55137105A JP4461279A JP4461279A JPS55137105A JP S55137105 A JPS55137105 A JP S55137105A JP 4461279 A JP4461279 A JP 4461279A JP 4461279 A JP4461279 A JP 4461279A JP S55137105 A JPS55137105 A JP S55137105A
- Authority
- JP
- Japan
- Prior art keywords
- suspension stabilizer
- anionic hydrophilic
- particles
- side chain
- suspension
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Polymerisation Methods In General (AREA)
Abstract
PURPOSE: To provide suspension stabilizer for suspension polymn, which produces a vinyl polymer having an appropriate apparent specific gravity, good plasticizer absorption and sharp particle size distribution, consisting of a partially saponified PVA having anionic hydrophilic gp. on its side chain.
CONSTITUTION: A copolymer of an unsaturated aliph. carboxylic acid or an ester thereof and vinyl acetate is saponified to obtain a suspension stabilizer consisting of partially saponified PVA contg. anionic hydrophilic gp. of 0.02W5mol% on its side chain and having a degree of saponification of 60W80mol%. The anionic hydrophilic gp. of the suspension stabilizer imoparts an anionic property to polymer particles. The distribution of the particles is promoted by electrical repulsion. When primary particles are agglomerated and adhere to one another to grow, appropriate voids are formed and a porous vinyl polymer is obtained.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4461279A JPS55137105A (en) | 1979-04-12 | 1979-04-12 | Suspension stabilizer |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4461279A JPS55137105A (en) | 1979-04-12 | 1979-04-12 | Suspension stabilizer |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS55137105A true JPS55137105A (en) | 1980-10-25 |
Family
ID=12696257
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP4461279A Pending JPS55137105A (en) | 1979-04-12 | 1979-04-12 | Suspension stabilizer |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS55137105A (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56159202A (en) * | 1980-05-14 | 1981-12-08 | Denki Kagaku Kogyo Kk | Suspension polymerization of vinyl chloride |
JPS56159201A (en) * | 1980-05-14 | 1981-12-08 | Denki Kagaku Kogyo Kk | Suspension stabilizer |
JPS57119902A (en) * | 1981-01-16 | 1982-07-26 | Kuraray Co Ltd | Dispersion stabilizer for suspension polymerization of vinyl compound |
US6613853B1 (en) | 1999-10-28 | 2003-09-02 | The Nippon Synthetic Chemical Industry Co., Ltd. | Production method of vinyl resin |
US7193012B2 (en) | 2003-01-30 | 2007-03-20 | The Nippon Synthetic Chemical Industry Co., Ltd. | Dispersing agent comprising vinyl alcohol polymer having conjugated double bonds in its molecule |
JP2008050413A (en) * | 2006-08-22 | 2008-03-06 | Denki Kagaku Kogyo Kk | Latex and polymerizing method therefor |
WO2015019613A1 (en) * | 2013-08-07 | 2015-02-12 | 株式会社クラレ | Dispersion stabilizer for suspension polymerization, and manufacturing method for vinyl resin |
WO2015019614A1 (en) * | 2013-08-07 | 2015-02-12 | 株式会社クラレ | Dispersion stabilizer for suspension polymerization, and manufacturing method for vinyl resin |
US10106635B2 (en) | 2014-03-28 | 2018-10-23 | Synthomer (Uk) Limited | Secondary suspending agent for suspension polymerisation reaction |
US10647793B2 (en) | 2014-03-28 | 2020-05-12 | Synthomer (Uk) Limited | Use of a sulphur or phosphorous-containing polymer as a processing aid in a polyvinyl chloride polymer composition |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5424989A (en) * | 1977-07-26 | 1979-02-24 | Nippon Synthetic Chem Ind Co Ltd:The | Suspension polymerization of vinyl compound |
JPS5433580A (en) * | 1977-08-19 | 1979-03-12 | Denki Kagaku Kogyo Kk | Polymerization of vynyl chloride |
-
1979
- 1979-04-12 JP JP4461279A patent/JPS55137105A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5424989A (en) * | 1977-07-26 | 1979-02-24 | Nippon Synthetic Chem Ind Co Ltd:The | Suspension polymerization of vinyl compound |
JPS5433580A (en) * | 1977-08-19 | 1979-03-12 | Denki Kagaku Kogyo Kk | Polymerization of vynyl chloride |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56159202A (en) * | 1980-05-14 | 1981-12-08 | Denki Kagaku Kogyo Kk | Suspension polymerization of vinyl chloride |
JPS56159201A (en) * | 1980-05-14 | 1981-12-08 | Denki Kagaku Kogyo Kk | Suspension stabilizer |
JPS57119902A (en) * | 1981-01-16 | 1982-07-26 | Kuraray Co Ltd | Dispersion stabilizer for suspension polymerization of vinyl compound |
JPH0224842B2 (en) * | 1981-01-16 | 1990-05-30 | Kuraray Co | |
US6613853B1 (en) | 1999-10-28 | 2003-09-02 | The Nippon Synthetic Chemical Industry Co., Ltd. | Production method of vinyl resin |
US7193012B2 (en) | 2003-01-30 | 2007-03-20 | The Nippon Synthetic Chemical Industry Co., Ltd. | Dispersing agent comprising vinyl alcohol polymer having conjugated double bonds in its molecule |
JP2008050413A (en) * | 2006-08-22 | 2008-03-06 | Denki Kagaku Kogyo Kk | Latex and polymerizing method therefor |
WO2015019613A1 (en) * | 2013-08-07 | 2015-02-12 | 株式会社クラレ | Dispersion stabilizer for suspension polymerization, and manufacturing method for vinyl resin |
WO2015019614A1 (en) * | 2013-08-07 | 2015-02-12 | 株式会社クラレ | Dispersion stabilizer for suspension polymerization, and manufacturing method for vinyl resin |
CN105431460A (en) * | 2013-08-07 | 2016-03-23 | 株式会社可乐丽 | Dispersion stabilizer for suspension polymerization, and manufacturing method for vinyl resin |
US9562115B2 (en) | 2013-08-07 | 2017-02-07 | Kuraray Co., Ltd. | Dispersion stabilizer for suspension polymerization and method for producing vinyl resin |
JPWO2015019614A1 (en) * | 2013-08-07 | 2017-03-02 | 株式会社クラレ | Dispersion stabilizer for suspension polymerization and method for producing vinyl resin |
US9650455B2 (en) | 2013-08-07 | 2017-05-16 | Kuraray Co., Ltd. | Dispersion stabilizer for suspension polymerization and method for producing vinyl resin |
US10106635B2 (en) | 2014-03-28 | 2018-10-23 | Synthomer (Uk) Limited | Secondary suspending agent for suspension polymerisation reaction |
US10647793B2 (en) | 2014-03-28 | 2020-05-12 | Synthomer (Uk) Limited | Use of a sulphur or phosphorous-containing polymer as a processing aid in a polyvinyl chloride polymer composition |
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