JPS55124734A - Preparation of methacrylic acid - Google Patents
Preparation of methacrylic acidInfo
- Publication number
- JPS55124734A JPS55124734A JP3232379A JP3232379A JPS55124734A JP S55124734 A JPS55124734 A JP S55124734A JP 3232379 A JP3232379 A JP 3232379A JP 3232379 A JP3232379 A JP 3232379A JP S55124734 A JPS55124734 A JP S55124734A
- Authority
- JP
- Japan
- Prior art keywords
- isobutylene
- methacrylic acid
- tertiary butanol
- oxidation
- methacrolein
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 title abstract 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 4
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 230000003647 oxidation Effects 0.000 abstract 3
- 238000007254 oxidation reaction Methods 0.000 abstract 3
- STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 229910052776 Thorium Inorganic materials 0.000 abstract 1
- 229910052785 arsenic Inorganic materials 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 239000012495 reaction gas Substances 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 abstract 1
- 239000012808 vapor phase Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8877—Vanadium, tantalum, niobium or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
- B01J27/198—Vanadium
- B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3232379A JPS55124734A (en) | 1979-03-22 | 1979-03-22 | Preparation of methacrylic acid |
| GB8007725A GB2046252B (en) | 1979-03-22 | 1980-03-06 | Process for producing methacrylic acid |
| NL8001507A NL8001507A (nl) | 1979-03-22 | 1980-03-13 | Bereidingswijze van methacrylzuur. |
| DE19803010434 DE3010434A1 (de) | 1979-03-22 | 1980-03-19 | Verfahren zur herstellung von methacrylsaeure |
| BE0/199849A BE882303A (fr) | 1979-03-22 | 1980-03-19 | Procede de production de l'acide methacrylique |
| FR8006172A FR2451907B1 (fr) | 1979-03-22 | 1980-03-19 | Procede pour produire de l'acide methacrylique par oxydation en phase vapeur de la methacroleine |
| ES490544A ES490544A0 (es) | 1979-03-22 | 1980-03-21 | Procedimiento para la fabricacion de acido metacrilico |
| IT20829/80A IT1195265B (it) | 1979-03-22 | 1980-03-21 | Processo per produrre acido metacrilico |
| SU802896304A SU1246889A3 (ru) | 1979-03-22 | 1980-03-21 | Способ получени метакриловой кислоты |
| CS801954A CS215020B2 (en) | 1979-03-22 | 1980-03-21 | Method of making the metacryl acid |
| US06/484,620 US4652673A (en) | 1979-03-22 | 1983-05-18 | Process for producing methacrylic acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3232379A JPS55124734A (en) | 1979-03-22 | 1979-03-22 | Preparation of methacrylic acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS55124734A true JPS55124734A (en) | 1980-09-26 |
Family
ID=12355725
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3232379A Pending JPS55124734A (en) | 1979-03-22 | 1979-03-22 | Preparation of methacrylic acid |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4652673A (ja) |
| JP (1) | JPS55124734A (ja) |
| BE (1) | BE882303A (ja) |
| CS (1) | CS215020B2 (ja) |
| DE (1) | DE3010434A1 (ja) |
| ES (1) | ES490544A0 (ja) |
| FR (1) | FR2451907B1 (ja) |
| GB (1) | GB2046252B (ja) |
| IT (1) | IT1195265B (ja) |
| NL (1) | NL8001507A (ja) |
| SU (1) | SU1246889A3 (ja) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5732734A (en) * | 1980-08-05 | 1982-02-22 | Standard Oil Co | Metachlorine oxidation catalyst and its use |
| JPS58166938A (ja) * | 1982-03-10 | 1983-10-03 | バスフ アクチエンゲゼルシヤフト | メタクリル酸又はアクリル酸の製造用触媒 |
| JPS594445A (ja) * | 1982-06-07 | 1984-01-11 | ロ−ム・アンド・ハ−ス・カンパニ− | 不飽和カルボン酸製造用触媒 |
| JP2010528078A (ja) * | 2007-05-25 | 2010-08-19 | エボニック レーム ゲゼルシャフト ミット ベシュレンクテル ハフツング | 酸化によるメタクリル酸の製造における原料組成物の使用 |
| US20130261335A1 (en) * | 2012-03-27 | 2013-10-03 | Sumitomo Chemical Company, Limited | Process for producing alkyl methacrylate |
| JP2014181203A (ja) * | 2013-03-19 | 2014-09-29 | Sumitomo Chemical Co Ltd | メタクリル酸の製造方法 |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3260477D1 (en) * | 1981-02-05 | 1984-09-06 | Ube Industries | Process for producing methacrolein and methacrylic acid |
| DE3208571A1 (de) * | 1982-03-10 | 1983-09-22 | Basf Ag, 6700 Ludwigshafen | Oxidationskatalysator, insbesondere fuer die herstellung von methacrylsaeure durch gasphasenoxidation von methacrolein |
| JPS59115750A (ja) * | 1982-12-22 | 1984-07-04 | Nippon Shokubai Kagaku Kogyo Co Ltd | メタクリル酸合成用触媒 |
| DE3308625A1 (de) * | 1983-03-11 | 1984-09-13 | Basf Ag, 6700 Ludwigshafen | Verfahren und katalysator zur herstellung von methacrylsaeure |
| DE3508649A1 (de) * | 1985-03-12 | 1986-09-18 | Röhm GmbH, 6100 Darmstadt | Heteropolysaeure h(pfeil abwaerts)8(pfeil abwaerts)pmo(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)vo(pfeil abwaerts)3(pfeil abwaerts)(pfeil abwaerts)9(pfeil abwaerts), deren anhydrid pmo(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)vo(pfeil abwaerts)3(pfeil abwaerts)(pfeil abwaerts)5(pfeil abwaerts)und ihre verwendung |
| JPH0791212B2 (ja) * | 1988-07-11 | 1995-10-04 | 三菱レイヨン株式会社 | メタクリル酸の製造法 |
| DE3844087A1 (de) * | 1988-12-28 | 1990-07-05 | Basf Ag | Verfahren zur herstellung von methacrylsaeure durch oxidation von methacrolein |
| DE69013623T3 (de) * | 1989-08-29 | 2002-12-19 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Katalysator zur Herstellung von Methacrylsäure. |
| DE4113423A1 (de) * | 1991-04-25 | 1992-10-29 | Roehm Gmbh | Mit makroporen durchsetzter oxidationskatalysator |
| DE4240085A1 (de) * | 1992-11-28 | 1994-06-01 | Roehm Gmbh | Katalytische Oxidation von Isobutan zu Methacrylsäure und Methacrolein |
| TWI341219B (en) * | 2003-02-20 | 2011-05-01 | Nippon Kayaku Kk | Catalyst for producing methacrylic acid and preparation method thereof |
| US20070010394A1 (en) * | 2003-05-30 | 2007-01-11 | Sudo Atsushi | Process for producing catalyst for methacrylic acid production |
| US7732367B2 (en) * | 2005-07-25 | 2010-06-08 | Saudi Basic Industries Corporation | Catalyst for methacrolein oxidation and method for making and using same |
| US7851397B2 (en) * | 2005-07-25 | 2010-12-14 | Saudi Basic Industries Corporation | Catalyst for methacrolein oxidation and method for making and using same |
| US7649112B2 (en) * | 2005-07-25 | 2010-01-19 | Saudi Basic Industries Corporation | Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon |
| US7649111B2 (en) * | 2005-07-25 | 2010-01-19 | Saudi Basic Industries Corporation | Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same |
| KR100807972B1 (ko) * | 2005-08-10 | 2008-02-28 | 주식회사 엘지화학 | 아크릴산 선택성이 높은 복합 금속 산화물 촉매 |
| US7799946B2 (en) * | 2007-02-14 | 2010-09-21 | Saudi Basic Industries Corporation | Process for separating methacrolein from methacrylic acid in a gas phase product from the partial oxidation of isobutene |
| EP2085376B1 (en) | 2008-01-30 | 2012-09-05 | Evonik Röhm GmbH | Process for preparation of high purity methacrylic acid |
| US8921257B2 (en) | 2011-12-02 | 2014-12-30 | Saudi Basic Industries Corporation | Dual function partial oxidation catalyst for propane to acrylic acid conversion |
| US8722940B2 (en) | 2012-03-01 | 2014-05-13 | Saudi Basic Industries Corporation | High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins |
| WO2013163806A1 (en) | 2012-05-03 | 2013-11-07 | Evonik Industries Ag | Process for preparation of highly pure, non-yellowing methacrylic acid |
| CN105050995A (zh) | 2013-03-18 | 2015-11-11 | 赢创罗姆有限公司 | 甲基丙烯酸和甲基丙烯酸酯的制备方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2248261B1 (ja) * | 1973-10-23 | 1978-04-28 | Union Carbide Corp | |
| DE2460541C3 (de) * | 1973-12-29 | 1979-10-18 | Nippon Shokubai Kagaku Kogyo Co. Ltd., Osaka (Japan) | Phosphor, Molybdän und Vanadium sowie gegebenenfalls Kupfer, Kobalt, Zirkon, Wismut, Antimon und/oder Arsen enthaltender Oxydkatalysator und dessen Verwendung zur Herstellung von Methacrylsäure |
| JPS5827255B2 (ja) * | 1974-05-31 | 1983-06-08 | 三菱レイヨン株式会社 | 不飽和脂肪酸の製造方法 |
| JPS51115414A (en) * | 1975-04-03 | 1976-10-12 | Mitsubishi Rayon Co Ltd | Process for preparation of unsaturated fatty acids |
| JPS51136615A (en) * | 1975-05-23 | 1976-11-26 | Toyo Soda Mfg Co Ltd | Process for preparation of methacrylic acid |
| JPS5946934B2 (ja) * | 1976-02-09 | 1984-11-15 | 東ソー株式会社 | メタクリル酸の製法 |
| JPS5331615A (en) * | 1976-09-06 | 1978-03-25 | Nippon Kayaku Co Ltd | Production of methacrylic acid and catalyst used thereof |
| JPS5353613A (en) * | 1976-10-26 | 1978-05-16 | Nippon Zeon Co Ltd | Preparation of methacrylic acid |
| JPS6048496B2 (ja) * | 1977-07-22 | 1985-10-28 | 東ソー株式会社 | メタクリル酸の製造方法 |
| JPS5924140B2 (ja) * | 1977-10-31 | 1984-06-07 | 日本化薬株式会社 | メタクリル酸の製造法及び触媒 |
| JPS5498717A (en) * | 1978-01-17 | 1979-08-03 | Nippon Zeon Co Ltd | Preparation of unsaturated carboxylic acid |
| JPS552619A (en) * | 1978-06-21 | 1980-01-10 | Nippon Kayaku Co Ltd | Preparation of methacrylic acid and catalyst |
| DD148728A5 (de) * | 1978-12-13 | 1981-06-10 | Nippon Kayaku Kk | Verfahren zur herstellung eines katalysators mit heteropolysaeurestruktur |
-
1979
- 1979-03-22 JP JP3232379A patent/JPS55124734A/ja active Pending
-
1980
- 1980-03-06 GB GB8007725A patent/GB2046252B/en not_active Expired
- 1980-03-13 NL NL8001507A patent/NL8001507A/nl not_active Application Discontinuation
- 1980-03-19 BE BE0/199849A patent/BE882303A/fr not_active IP Right Cessation
- 1980-03-19 FR FR8006172A patent/FR2451907B1/fr not_active Expired
- 1980-03-19 DE DE19803010434 patent/DE3010434A1/de not_active Ceased
- 1980-03-21 SU SU802896304A patent/SU1246889A3/ru active
- 1980-03-21 IT IT20829/80A patent/IT1195265B/it active
- 1980-03-21 CS CS801954A patent/CS215020B2/cs unknown
- 1980-03-21 ES ES490544A patent/ES490544A0/es active Granted
-
1983
- 1983-05-18 US US06/484,620 patent/US4652673A/en not_active Expired - Lifetime
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5732734A (en) * | 1980-08-05 | 1982-02-22 | Standard Oil Co | Metachlorine oxidation catalyst and its use |
| JPH0221859B2 (ja) * | 1980-08-05 | 1990-05-16 | Standard Oil Co | |
| JPS58166938A (ja) * | 1982-03-10 | 1983-10-03 | バスフ アクチエンゲゼルシヤフト | メタクリル酸又はアクリル酸の製造用触媒 |
| JPH0358776B2 (ja) * | 1982-03-10 | 1991-09-06 | Basf Ag | |
| JPS594445A (ja) * | 1982-06-07 | 1984-01-11 | ロ−ム・アンド・ハ−ス・カンパニ− | 不飽和カルボン酸製造用触媒 |
| JPH0428417B2 (ja) * | 1982-06-07 | 1992-05-14 | Rohm & Haas | |
| JP2010528078A (ja) * | 2007-05-25 | 2010-08-19 | エボニック レーム ゲゼルシャフト ミット ベシュレンクテル ハフツング | 酸化によるメタクリル酸の製造における原料組成物の使用 |
| US9206108B2 (en) | 2007-05-25 | 2015-12-08 | Evonik Roehm Gmbh | Use of a feed compositions in preparation of methacrylic acid by oxidation |
| US20130261335A1 (en) * | 2012-03-27 | 2013-10-03 | Sumitomo Chemical Company, Limited | Process for producing alkyl methacrylate |
| JP2013203668A (ja) * | 2012-03-27 | 2013-10-07 | Sumitomo Chemical Co Ltd | メタクリル酸の製造方法 |
| US9045406B2 (en) | 2012-03-27 | 2015-06-02 | Sumitomo Chemical Company, Limited | Process for producing alkyl methacrylate |
| JP2014181203A (ja) * | 2013-03-19 | 2014-09-29 | Sumitomo Chemical Co Ltd | メタクリル酸の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CS215020B2 (en) | 1982-06-25 |
| NL8001507A (nl) | 1980-09-24 |
| FR2451907A1 (fr) | 1980-10-17 |
| BE882303A (fr) | 1980-09-19 |
| SU1246889A3 (ru) | 1986-07-23 |
| GB2046252A (en) | 1980-11-12 |
| DE3010434A1 (de) | 1980-11-20 |
| ES8103014A1 (es) | 1981-02-16 |
| IT8020829A0 (it) | 1980-03-21 |
| FR2451907B1 (fr) | 1986-10-24 |
| ES490544A0 (es) | 1981-02-16 |
| US4652673A (en) | 1987-03-24 |
| GB2046252B (en) | 1983-05-11 |
| IT1195265B (it) | 1988-10-12 |
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