Nothing Special   »   [go: up one dir, main page]

JPH11279044A - Cosmetic - Google Patents

Cosmetic

Info

Publication number
JPH11279044A
JPH11279044A JP10100162A JP10016298A JPH11279044A JP H11279044 A JPH11279044 A JP H11279044A JP 10100162 A JP10100162 A JP 10100162A JP 10016298 A JP10016298 A JP 10016298A JP H11279044 A JPH11279044 A JP H11279044A
Authority
JP
Japan
Prior art keywords
cosmetic
present
oily substance
ingredient
phenoxyethanol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP10100162A
Other languages
Japanese (ja)
Other versions
JP4073539B2 (en
Inventor
Tadashi Matsui
正 松井
Katsuhiko Yoshida
勝彦 吉田
Yuichi Tsuchiya
雄一 土屋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kanebo Ltd
Original Assignee
Kanebo Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kanebo Ltd filed Critical Kanebo Ltd
Priority to JP10016298A priority Critical patent/JP4073539B2/en
Publication of JPH11279044A publication Critical patent/JPH11279044A/en
Application granted granted Critical
Publication of JP4073539B2 publication Critical patent/JP4073539B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Landscapes

  • Cosmetics (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain a cosmetic good in the degree of transparency or cloudiness and capable of manifesting excellent feeling of use and preservation stability by dissolving a nonionic surfactant and an oily substance in phenoxyethanol and/or phenethyl alcohol and then mixing the resultant solution with water. SOLUTION: This cosmetic is obtained by dissolving (B) a nonionic surfactant [e.g. a polyethylene glycol ester of a fatty acid having >=8 value of hydrophile- lipophile balance(HLB) in the polyglyethylene glycol esters of the fatty acids, etc.], and (C) an oily substance (preferably tocopherol or its derivative) in (A) phenoxyethanol and/or phenethyl alcohol then mixing the resultant solution with (D) water. The amounts of the formulated ingredients based on the total cosmetic composition are preferably 0.01-2.0 wt.% ingredient A, 0.02-4.0 wt.% ingredient B and 0.01-1.0 wt.% ingredient C. Thereby, the resultant cosmetic is good in compatibility without causing stickiness in use.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、透明から白濁まで
の外観が良好で、かつ保存安定性と使用感に優れた化粧
料に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cosmetic having a good appearance from transparent to cloudy, and having excellent storage stability and feeling of use.

【0002】[0002]

【従来の技術】従来、外観が透明な化粧料としては、エ
チルアルコールまたは多価アルコールに親水性界面活性
剤と香料等の油性物質を溶解した後に水と混合して得ら
れる化粧水、整髪剤、シェイビングローション等が、外
観が白濁した化粧料としては、水相成分に油相成分およ
び界面活性剤を加えて乳化分散させて得られるものや、
エチルアルコールに界面活性剤と油性物質を溶解しこの
油相成分を水相成分に分散させて得られるものなどが知
られている。
2. Description of the Related Art Conventionally, cosmetics having a transparent appearance include a lotion and a hair styling agent obtained by dissolving a hydrophilic surfactant and an oily substance such as a fragrance in ethyl alcohol or polyhydric alcohol and then mixing the resultant with water. , Shaving lotions, etc., as cosmetics whose appearance becomes cloudy, those obtained by emulsifying and dispersing an oil phase component and a surfactant in an aqueous phase component,
There are known those obtained by dissolving a surfactant and an oily substance in ethyl alcohol and dispersing the oil phase component in an aqueous phase component.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、外観が
透明または白濁した従来の化粧料は、各々製造方法や界
面活性剤の選択が難しく、一つの技術で透明から白濁ま
での外観を得ることは困難で、保存安定性にも劣るとい
う欠点を有していた。また、外観が透明な化粧料ではエ
チルアルコールによる皮膚刺激や多価アルコールによる
使用時のべたつき等の問題点が、外観が白濁した化粧料
では水溶性増粘剤を添加し保存安定性を向上させる必要
があり使用感の点でべたつく、なじみが悪い等の問題点
があった。
However, in the case of conventional cosmetics having a transparent or cloudy appearance, it is difficult to select a manufacturing method and a surfactant, and it is difficult to obtain a transparent to cloudy appearance by one technique. And had a disadvantage that storage stability was poor. In addition, cosmetics having a transparent appearance have problems such as skin irritation due to ethyl alcohol and stickiness when used with polyhydric alcohol, and cosmetics having an opaque appearance improve the storage stability by adding a water-soluble thickener. There was a problem that it was necessary and was sticky in terms of usability and that it was not familiar.

【0004】[0004]

【課題を解決するための手段】本発明者等は、上記問題
点のない化粧料を得るべく鋭意研究を重ねた結果、フェ
ノキシエタノールおよび/またはフェネチルアルコール
に非イオン性界面活性剤および油性物質を溶解した後、
水と混合することで、透明または白濁度が良好でかつ保
存安定性と使用感に優れた化粧料が得られることを見出
だし、本発明を完成させた。
Means for Solving the Problems The inventors of the present invention have conducted intensive studies to obtain cosmetics free from the above-mentioned problems, and as a result, have dissolved a nonionic surfactant and an oily substance in phenoxyethanol and / or phenethyl alcohol. After doing
It has been found that by mixing with water, a cosmetic having good transparency or turbidity and excellent storage stability and feeling of use can be obtained, and completed the present invention.

【0005】すなわち、本発明は、フェノキシエタノー
ルおよび/またはフェネチルアルコールに非イオン性界
面活性剤および油性物質を溶解した後、水と混合して得
られることを特徴とする化粧料である。
[0005] That is, the present invention is a cosmetic obtained by dissolving a nonionic surfactant and an oily substance in phenoxyethanol and / or phenethyl alcohol, and then mixing the resultant with water.

【0006】[0006]

【発明の実施の形態】以下、本発明の実施の形態を述べ
る。本発明で使用されるフェノキシエタノールは、エチ
レングリコールモノフェニルエーテルとも呼ばれ、無色
透明な粘性液体である。本発明で使用されるフェネチル
アルコールは、β−フェニルエチルアルコールとも呼ば
れ、無色透明な粘性液体である。本発明のフェノキシエ
タノールおよび/またはフェネチルアルコールは、本発
明の化粧料の全組成に対し通常で0.01〜2.0重量
%(以下、単に%で示す)の範囲で配合される。これら
の配合量が0.01%未満では溶解が困難となる場合が
あり、2.0%を超える配合量では使用感が好まれなく
なる場合がある。
Embodiments of the present invention will be described below. Phenoxyethanol used in the present invention is also called ethylene glycol monophenyl ether and is a colorless and transparent viscous liquid. The phenethyl alcohol used in the present invention is also called β-phenylethyl alcohol and is a colorless and transparent viscous liquid. The phenoxyethanol and / or phenethyl alcohol of the present invention is usually added in the range of 0.01 to 2.0% by weight (hereinafter simply indicated as%) based on the total composition of the cosmetic of the present invention. If the amount is less than 0.01%, dissolution may be difficult, and if the amount is more than 2.0%, the feeling of use may not be favorable.

【0007】本発明で使用される非イオン性界面活性剤
は、例えば、ポリエチレングリコール脂肪酸エステル、
ポリオキシエチレンソルビット脂肪酸エステル、ポリオ
キシエチレンソルビタン脂肪酸エステル、ポリオキシエ
チレン硬化ヒマシ油、ポリオキシエチレン硬化ヒマシ油
脂肪酸エステル、ポリオキシエチレンアルキルエーテ
ル、ポリオキシエチレンポリオキシプロピレンアルキル
エーテル、ポリオキシエチレンソルビットミツロウ、ポ
リオキシエチレングリセリン脂肪酸エステル、ポリオキ
シエチレントリメチロールプロパン脂肪酸エステル、ポ
リグリセリン脂肪酸エステル、グリセリン脂肪酸エステ
ル、ソルビタン脂肪酸エステル、プロピレングリコール
脂肪酸エステル等のうちそのHLB値が8以上となるも
のであり、本発明の化粧料の全組成に対し通常で0.0
2〜4.0%の範囲で配合される。HLB値が8未満ま
たは配合量が0.02%未満では安定な透明または白濁
の外観が得難く、4.0%を超える配合量では使用感が
好まれない場合がある。なお、本発明で使用される親水
性界面活性剤の配合量は、本発明で使用される油性物質
に対し0.1〜10倍量の範囲が好ましい。0.1倍未
満では安定な透明または白濁の外観が得難く、10倍を
超える場合には使用感が好まれない場合がある。なお、
非イオン性界面活性剤はフェノキシエタノールおよび/
またはフェネチルアルコールに溶解させることが、本発
明の化粧料において必要である。
The nonionic surfactant used in the present invention is, for example, polyethylene glycol fatty acid ester,
Polyoxyethylene sorbit fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene polyoxypropylene alkyl ether, polyoxyethylene sorbit beeswax , Polyoxyethylene glycerin fatty acid ester, polyoxyethylene trimethylolpropane fatty acid ester, polyglycerin fatty acid ester, glycerin fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, etc., whose HLB value is 8 or more. 0.0 to the total composition of the cosmetic of the invention
It is blended in the range of 2 to 4.0%. If the HLB value is less than 8 or the blending amount is less than 0.02%, a stable transparent or cloudy appearance is difficult to obtain, and if the blending amount exceeds 4.0%, the feeling of use may not be preferred. The amount of the hydrophilic surfactant used in the present invention is preferably in the range of 0.1 to 10 times the amount of the oily substance used in the present invention. If it is less than 0.1 times, it is difficult to obtain a stable transparent or cloudy appearance, and if it exceeds 10 times, the feeling of use may not be preferred. In addition,
The nonionic surfactant is phenoxyethanol and / or
Alternatively, it is necessary for the cosmetic of the present invention to dissolve it in phenethyl alcohol.

【0008】本発明で使用される油性物質は、化粧料、
医薬品等に通常使用されるものでよく、例えばオリーブ
油、コメヌカ油、スクワラン等の動植物油脂、流動パラ
フィン、ワセリン等の鉱物油、シリコーン油、高級アル
コ−ル高級脂肪酸エステル類、高級アルコ−ル類、高級
脂肪酸類、コレステロ−ル脂肪酸エステル類、炭酸ジア
ルキル類、香料、脂溶性ビタミン類などが挙げられ、こ
れらは1種又は2種以上を組み合わせて使用され、特に
好ましいものとしては、トコフェロールまたはその誘導
体を含む場合である。これらトコフェロールまたはその
誘導体としては、α−トコフェロール、β−トコフェロ
ール、γ−トコフェロール、δ−トコフェロール等のト
コフェロールと、これらの酢酸エステル、コハク酸エス
テル、ニコチン酸エステル、高級脂肪酸エステル等の誘
導体が挙げられる。本発明で使用される油性物質の配合
量は、本発明の化粧料の全組成に対し通常0.01〜
1.0%の範囲で配合される。0.01%未満では安定
な透明または白濁の外観が得難く、1.0%を超える多
い配合量では使用感が好まれない場合がある。
The oily substance used in the present invention includes cosmetics,
What is usually used for pharmaceuticals and the like may be used, for example, olive oil, rice bran oil, animal and vegetable oils such as squalane, liquid paraffin, mineral oils such as petrolatum, silicone oil, higher alcohol higher fatty acid esters, higher alcohols, Higher fatty acids, cholesterol fatty acid esters, dialkyl carbonates, fragrances, fat-soluble vitamins, and the like are used, and these are used alone or in combination of two or more. Particularly preferred are tocopherol and derivatives thereof. Is included. Examples of these tocopherols or derivatives thereof include tocopherols such as α-tocopherol, β-tocopherol, γ-tocopherol, and δ-tocopherol, and derivatives thereof such as acetates, succinates, nicotinates, and higher fatty acid esters. . The compounding amount of the oily substance used in the present invention is usually from 0.01 to the total composition of the cosmetic of the present invention.
It is blended in a range of 1.0%. If it is less than 0.01%, it is difficult to obtain a stable transparent or cloudy appearance, and if it is more than 1.0%, the feeling of use may not be preferred.

【0009】水分量は本発明の使用目的、適切な物性に
応じて適宜選択し得る。
The amount of water can be appropriately selected according to the purpose of use of the present invention and appropriate physical properties.

【0010】本発明では、さらに化粧料、医薬品等に通
常使用される薬効剤、保湿成分、抗炎症剤、殺菌剤、防
腐剤、紫外線吸収剤、酸化防止剤、有機及び無機粉体、
色素などを必要に応じて配合することができる。
[0010] In the present invention, furthermore, a medicinal agent, a moisturizing component, an anti-inflammatory agent, a bactericide, a preservative, an ultraviolet absorber, an antioxidant, an organic and inorganic powder, which are commonly used in cosmetics, pharmaceuticals, etc.
Dyes and the like can be added as needed.

【0011】[0011]

【実施例】次に実施例を挙げて本発明を説明するが、そ
れに先立ち評価方法を示す。尚、本発明はこれら実施例
に限定されるものではない。
EXAMPLES The present invention will be described below with reference to examples, but prior to that, an evaluation method will be described. Note that the present invention is not limited to these examples.

【0012】評価方法 (保存安定性)20℃および40℃の恒温槽に試作品を
いれ、1か月後に観察を行った。
Evaluation method (Storage stability) The prototype was placed in a thermostat at 20 ° C. and 40 ° C., and observed one month later.

【0013】(使用感)女子20人(パネラー)が1週
間連続使用した後、使用感(べたつきのなさ、なじみ)
の良否を下記の基準に従って評価した。
(Feeling of use) The feeling of use (non-stickiness, familiarity) after 20 women (panelers) have used for a week continuously
Was evaluated according to the following criteria.

【0014】実施例1〜3、比較例1〜2(透明保湿ロ
ーション) 表1に示す透明保湿ローションは次の製造法により調製
した。(製造法)表中の(A)各成分を均一に混合溶解
する。表中の(B)各成分を均一に混合溶解する。
(A)に(B)を撹拌しながら加えて各透明保湿ローシ
ョンを得る。これを試料として上記の評価方法に従って
評価した。その結果を表1に示す。
Examples 1 to 3 and Comparative Examples 1 and 2 (Transparent Moisturizing Lotion) The transparent moisturizing lotions shown in Table 1 were prepared by the following production methods. (Production method) Each component (A) in the table is uniformly mixed and dissolved. The components (B) in the table are uniformly mixed and dissolved.
(A) is added to (A) with stirring to obtain each transparent moisturizing lotion. This was used as a sample and evaluated according to the above evaluation method. Table 1 shows the results.

【0015】[0015]

【表1】 [Table 1]

【0016】表1より本発明品は、外観が透明で、べた
つかず、なじみが良好で、さらに保存安全性にも優れて
いる。
From Table 1, it can be seen that the product of the present invention has a transparent appearance, is not sticky, has good conformability, and is excellent in storage stability.

【0017】実施例4〜5、比較例3〜4(白濁老化防
止ローション) 表2で示す組成にて表1と同様に白濁老化防止ローショ
ンを調製した。
Examples 4 to 5 and Comparative Examples 3 to 4 (anti-opaque anti-aging lotion) Lotion-preventing anti-opaque lotions having the compositions shown in Table 2 were prepared in the same manner as in Table 1.

【0018】[0018]

【表2】 [Table 2]

【0019】表2より本発明品は、保存安定性、使用時
のべたつきのなさ・なじみの良さにも優れている。
From Table 2, it can be seen that the product of the present invention is excellent in storage stability, non-stickiness and conformability during use.

【0020】実施例6(白濁アフターシェービングロー
ション) 表3で示す組成にて白濁アフターシェービングローショ
ンを調製した。
Example 6 (Cloudy after-shaving lotion) A cloudy after-shaving lotion having the composition shown in Table 3 was prepared.

【0021】[0021]

【表3】 [Table 3]

【0022】表3より本発明品は、保存安定性、使用時
のべたつきのなさ・なじみの良さにも優れている。
From Table 3, it can be seen that the product of the present invention is excellent in storage stability, non-stickiness during use, and good conformability.

【0023】[0023]

【発明の効果】以上記載の通り、本発明は外観が良好
で、使用時にべたつかず、なじみが良好で、かつすぐれ
た使用感を有し、保存安定性にすぐれる化粧料を提供す
ることは明らかである。
As described above, according to the present invention, it is possible to provide a cosmetic which has a good appearance, is not sticky at the time of use, has good conformability, has an excellent feeling in use, and has excellent storage stability. it is obvious.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 フェノキシエタノールおよび/またはフ
ェネチルアルコールに非イオン性界面活性剤および油性
物質を溶解した後、水と混合して得られることを特徴と
する化粧料。
1. A cosmetic obtained by dissolving a nonionic surfactant and an oily substance in phenoxyethanol and / or phenethyl alcohol and mixing with water.
【請求項2】 油性物質がトコフェロールまたはその誘
導体の一種または二種以上である請求項1記載の化粧
料。
2. The cosmetic according to claim 1, wherein the oily substance is one or more of tocopherol or a derivative thereof.
JP10016298A 1998-03-26 1998-03-26 Cosmetics Expired - Fee Related JP4073539B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10016298A JP4073539B2 (en) 1998-03-26 1998-03-26 Cosmetics

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10016298A JP4073539B2 (en) 1998-03-26 1998-03-26 Cosmetics

Publications (2)

Publication Number Publication Date
JPH11279044A true JPH11279044A (en) 1999-10-12
JP4073539B2 JP4073539B2 (en) 2008-04-09

Family

ID=14266629

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10016298A Expired - Fee Related JP4073539B2 (en) 1998-03-26 1998-03-26 Cosmetics

Country Status (1)

Country Link
JP (1) JP4073539B2 (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002212052A (en) * 2001-01-15 2002-07-31 Hajime Ito External preparation
JP2002241279A (en) * 2001-02-16 2002-08-28 Kanebo Ltd Package-containing product and method for preventing adsorption
FR2842728A1 (en) * 2002-07-24 2004-01-30 Oreal Transparent composition useful as a cosmetic or dermatological product comprises di(1,1,1-trimethylolpropane) tetrastearate and an organic solvent with a defined refractive index
JP2005220031A (en) * 2004-02-03 2005-08-18 Pola Chem Ind Inc Cosmetic containing aromatic-group-having aliphatic alcohol
JP2007326820A (en) * 2006-06-08 2007-12-20 Shiseido Co Ltd Transparent liquid cleaning agent
JP2008195676A (en) * 2007-02-15 2008-08-28 Noevir Co Ltd Transparent cosmetic
GB2486951A (en) * 2010-12-30 2012-07-04 Lvmh Rech Cosmetic composition comprising a tocopherol phosphate and process for the preparation thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002212052A (en) * 2001-01-15 2002-07-31 Hajime Ito External preparation
JP2002241279A (en) * 2001-02-16 2002-08-28 Kanebo Ltd Package-containing product and method for preventing adsorption
FR2842728A1 (en) * 2002-07-24 2004-01-30 Oreal Transparent composition useful as a cosmetic or dermatological product comprises di(1,1,1-trimethylolpropane) tetrastearate and an organic solvent with a defined refractive index
JP2005220031A (en) * 2004-02-03 2005-08-18 Pola Chem Ind Inc Cosmetic containing aromatic-group-having aliphatic alcohol
JP2007326820A (en) * 2006-06-08 2007-12-20 Shiseido Co Ltd Transparent liquid cleaning agent
JP2008195676A (en) * 2007-02-15 2008-08-28 Noevir Co Ltd Transparent cosmetic
GB2486951A (en) * 2010-12-30 2012-07-04 Lvmh Rech Cosmetic composition comprising a tocopherol phosphate and process for the preparation thereof

Also Published As

Publication number Publication date
JP4073539B2 (en) 2008-04-09

Similar Documents

Publication Publication Date Title
EP1353629B1 (en) Translucent nanoemulsion, production method, and uses thereof in the cosmetic, dermatological and/or ophthalmological fields
CN105030610B (en) A kind of anti-apolexis composition and preparation method thereof
JP2007238625A (en) Stabilized ascorbic acid solution; use thereof; process for its preparation; and formulation comprising the same
KR101145060B1 (en) O/W cosmetic composition having improved cosmetics formulation stability
JP2010248169A (en) Water-in-oil type emulsion skin lotion
JPH10194922A (en) Solubilized cosmetic
JPH11279044A (en) Cosmetic
JP2003003013A (en) Oil-in-water emulsifier composition composed of alkylated polysaccharide and cosmetic using the same
WO2013021775A1 (en) Liquid skin-conditioning composition
JP2013047206A (en) Fine emulsion composition containing ultraviolet absorber, and cosmetic
JP4101437B2 (en) Gel cosmetic
JP2008094811A (en) O/w type emulsified composition and its preparing method
KR100245796B1 (en) A water-in-oil type cosmetic composition having low viscosity
JP3725328B2 (en) Cloudy cosmetic
JP2799568B2 (en) Antioxidant composition
JP2003012492A (en) Cosmetic
JP4685536B2 (en) Emulsified composition and cosmetic containing the same
JPH0699271B2 (en) Translucent cosmetics
JPH0816047B2 (en) Translucent liquid cosmetics
JPH11269055A (en) Cloudy cosmetic
JP3000396B2 (en) Translucent cosmetics
JPH0899827A (en) Skin external agent
JP2019131524A (en) Cosmetic and skin external preparation
JPH10120521A (en) Translucent cosmetic
JP2019131507A (en) Skin external preparations or cosmetics

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20040701

A711 Notification of change in applicant

Free format text: JAPANESE INTERMEDIATE CODE: A711

Effective date: 20040805

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A821

Effective date: 20040806

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20050224

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20050308

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20050421

A711 Notification of change in applicant

Free format text: JAPANESE INTERMEDIATE CODE: A711

Effective date: 20060328

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20070703

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20071009

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20071122

A911 Transfer of reconsideration by examiner before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20071205

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20080122

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20080123

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110201

Year of fee payment: 3

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120201

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120201

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130201

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20140201

Year of fee payment: 6

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees