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JPH11189885A - Method for pickling hot rolled steel strip - Google Patents

Method for pickling hot rolled steel strip

Info

Publication number
JPH11189885A
JPH11189885A JP35836797A JP35836797A JPH11189885A JP H11189885 A JPH11189885 A JP H11189885A JP 35836797 A JP35836797 A JP 35836797A JP 35836797 A JP35836797 A JP 35836797A JP H11189885 A JPH11189885 A JP H11189885A
Authority
JP
Japan
Prior art keywords
steel strip
pickling
speed
scale thickness
pickling tank
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP35836797A
Other languages
Japanese (ja)
Inventor
Masato Koide
正人 小出
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Priority to JP35836797A priority Critical patent/JPH11189885A/en
Publication of JPH11189885A publication Critical patent/JPH11189885A/en
Pending legal-status Critical Current

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  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

PROBLEM TO BE SOLVED: To suitably set the sheet passing rate in a pickling tank in a pickling method for a hot rolled steel strip and to execute sufficient pickling to be required in accordance with the thickness of scales. SOLUTION: A scale thickness measuring device 3 is set on a prescribed position on the stream side upper than a pickling tank 6, and the thickness of scales formed on the surface and back faces of a steel strip S is detected. A control device 11 detects the maximum value in the prescribed length range of the steel strip from the detected value, and the sheet passing rate in the pickling tank 6 is set per the range from the maximum value of the detected scale thickness.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、熱間圧延鋼帯を巻
き戻しながら連続的に酸洗槽を通過させることにより、
当該熱間圧延鋼帯の表面に生成しているスケールを除去
する熱間圧延鋼帯の酸洗方法に関する。
The present invention relates to a hot-rolled steel strip which is continuously rewound and passed through a pickling tank.
The present invention relates to a method for pickling a hot-rolled steel strip for removing scale generated on the surface of the hot-rolled steel strip.

【0002】[0002]

【従来の技術】一般に、熱間圧延鋼帯の連続酸洗は、ペ
イオフリールで鋼帯を巻き戻しながら塩酸や硫酸等の入
った酸洗槽、すすぎ槽、乾燥装置等を通過させて巻き取
る設備によって行われている。熱間圧延鋼帯の酸洗工程
は、鋼帯表面に生じているスケール(酸化物)を塩酸や
硫酸等と反応させて除去する工程であり、表面のスケー
ルが厚ければ酸洗性は悪くなる。また、酸洗液の温度や
酸の濃度が同じ場合には、通板速度を遅くして浸漬時間
を長くすれば酸洗効果が高くなる。
2. Description of the Related Art Generally, continuous pickling of a hot-rolled steel strip is carried out by passing the strip through a pickling tank containing hydrochloric acid, sulfuric acid, etc., a rinsing tank, a drying device, etc. while rewinding the steel strip with a pay-off reel. It is done by facilities. The pickling step of the hot-rolled steel strip is a step of removing scale (oxide) generated on the surface of the steel strip by reacting with hydrochloric acid, sulfuric acid, or the like. If the scale of the surface is thick, the pickling property is poor. Become. Further, when the temperature of the pickling solution and the concentration of the acid are the same, the pickling effect is enhanced by reducing the plate passing speed and lengthening the dipping time.

【0003】ここで、鋼帯の長さ方向においてスケール
厚は大きく変動するが、従来は、スケール除去不足によ
る品質不良を防止するために、想定されるスケール厚の
最大値に合わせて、酸洗液の温度および酸濃度は高め
に、酸洗通板速度は遅めに設定している。
Here, the scale thickness greatly fluctuates in the longitudinal direction of the steel strip. However, conventionally, in order to prevent quality deterioration due to insufficient scale removal, pickling is performed in accordance with the assumed maximum value of the scale thickness. The temperature and the acid concentration of the liquid are set to be high, and the pickling plate speed is set to be low.

【0004】[0004]

【発明が解決しようとする課題】しかしながら、前記従
来の方法によれば、スケール厚の比較的小さい部分が酸
洗槽を通過している際には、過剰な仕様で酸洗されてい
ることになり、酸洗液や熱エネルギー(一般には蒸気エ
ネルギー)が無駄になっている。また、酸洗時間が必要
以上に長くなっているため、時間も無駄になっている。
However, according to the conventional method, when a portion having a relatively small scale thickness is passed through the pickling tank, it is pickled with excessive specifications. In other words, the pickling liquid and heat energy (generally, steam energy) are wasted. Further, since the pickling time is longer than necessary, the time is wasted.

【0005】本発明はこのような従来技術の問題点に着
目してなされたものであり、酸洗槽内での通板速度を適
切に設定して、スケール厚に応じた必要十分な酸洗が行
われるようにすることを課題とする。
The present invention has been made in view of such problems of the prior art, and it is necessary to appropriately set a passing speed in a pickling tank to pick up a necessary and sufficient pickling according to the scale thickness. Is to be performed.

【0006】[0006]

【課題を解決するための手段】上記課題を解決するため
に、本発明は、熱間圧延鋼帯を巻き戻しながら連続的に
酸洗槽を通過させることにより、当該熱間圧延鋼帯の表
面に生成しているスケールを除去する熱間圧延鋼帯の酸
洗方法において、酸洗槽より上流側の所定位置でスケー
ルの厚さを検出し、このスケール厚検出値の鋼帯の所定
長さ範囲での最大値を検出し、この検出されたスケール
厚最大値から前記範囲毎に鋼帯の酸洗槽内での通板速度
を設定することを特徴とする熱間圧延鋼帯の酸洗方法を
提供するものである。
SUMMARY OF THE INVENTION In order to solve the above-mentioned problems, the present invention relates to a hot-rolled steel strip which is continuously rewound and passed through a pickling tank while being unwound. In the pickling method of a hot-rolled steel strip for removing scale generated in the pickling tank, a scale thickness is detected at a predetermined position upstream of the pickling tank, and a predetermined length of the steel strip of the scale thickness detection value is detected. Pickling of a hot-rolled steel strip characterized by detecting a maximum value in a range, and setting a passing speed of the steel strip in a pickling tank for each range from the detected scale thickness maximum value. It provides a method.

【0007】前記所定位置(スケール厚の検出位置)
は、少なくとも上述の所定長さ(スケール厚最大値を検
出する範囲の鋼帯の長さ)分だけ、酸洗槽より上流側の
位置とする。
[0007] The predetermined position (scale thickness detection position)
Is set at a position on the upstream side of the pickling tank by at least the above-mentioned predetermined length (the length of the steel strip in the range where the maximum scale thickness is detected).

【0008】[0008]

【発明の実施の形態】以下、本発明の実施形態について
説明する。図1は、本発明の方法の一実施形態が適用可
能な設備列を示す概略構成図である。この設備列は、入
側から順に、鋼帯Sを巻き戻すペイオフリール1A,1
Bと、先行する鋼帯の尾端と後続の鋼帯の先端とを溶接
するウエルダー2と、鋼帯Sのスケール厚を測定するス
ケール厚測定装置3と、入側ルーパー4と、入側の速度
可変ロール5と、前処理装置61,62と、酸洗槽6
と、後処理装置63と、出側の速度可変ロール7と、出
側ルーパー8と、走間シャー9と、巻取りリール10
A,10Bと、制御装置11とで構成される。
Embodiments of the present invention will be described below. FIG. 1 is a schematic configuration diagram showing a facility row to which an embodiment of the method of the present invention can be applied. This equipment row includes payoff reels 1A and 1 for rewinding the steel strip S in order from the entry side.
B, a welder 2 for welding the tail end of the preceding steel strip and the tip of the following steel strip, a scale thickness measuring device 3 for measuring the scale thickness of the steel strip S, an entry-side looper 4, and an entry-side looper 4. Variable speed roll 5, pretreatment devices 61 and 62, pickling tank 6
, A post-processing device 63, an exit-side variable speed roll 7, an exit-side looper 8, a run-in shear 9, and a take-up reel 10.
A, 10B and the control device 11.

【0009】スケール厚測定装置3は、鋼帯Sの表裏面
に付着しているスケールの合計厚を非接触で測定する装
置であり、このスケール厚検出値Tを制御装置11に出
力する。ここで、酸洗層6の長さは100mであって、
スケール厚測定装置3は、酸洗層6の入り口から約50
0m上流側である入側ルーパ4の直前に配置されてい
る。
The scale thickness measuring device 3 is a device for measuring the total thickness of the scale adhering to the front and back surfaces of the steel strip S in a non-contact manner, and outputs the detected scale thickness value T to the control device 11. Here, the length of the pickling layer 6 is 100 m,
The scale thickness measuring device 3 is approximately 50 mm from the entrance of the pickling layer 6.
It is arranged immediately before the entrance looper 4 which is 0 m upstream.

【0010】入側の速度可変ロール5を駆動する電動機
51には、電動機51の回転速度を検出するパルスジェ
ネレータ52が接続してあり、このパルスジェネレータ
52からの速度検出値V1が制御装置11に出力され
る。出側の速度可変ロール7を駆動する電動機71に
は、電動機71の回転速度を検出するパルスジェネレー
タ72が接続してあり、このパルスジェネレータ72か
らの速度検出値V2が制御装置11に出力される。
A pulse generator 52 for detecting the rotation speed of the electric motor 51 is connected to the electric motor 51 for driving the variable speed roll 5 on the input side. Is output. A pulse generator 72 for detecting the rotation speed of the electric motor 71 is connected to the electric motor 71 that drives the output-side variable speed roll 7, and a detected speed value V 2 from the pulse generator 72 is output to the control device 11. .

【0011】制御装置11は、スケール厚測定装置3か
ら入力されたスケール厚検出値Tに基づいて酸洗槽6内
での通板速度を設定し、この速度設定値が達成されるよ
うに、速度設定値と速度検出値V1,V2との偏差分に
相当する電動機の電流値A1,A2をそれぞれ電動機5
1,71に出力する。すなわち、鋼帯Sの酸洗槽6内で
の通板速度は、前処理装置61の直前に設置された速度
可変ロール5および後処理装置63の直後に設置された
速度可変ロール7を、同一の前記速度設定値を達成する
速度で回転させることにより、前記速度設定値に制御さ
れるようになっている。
The control device 11 sets the passing speed in the pickling tank 6 based on the scale thickness detection value T input from the scale thickness measuring device 3 and sets the speed so that the speed setting value is achieved. The motor current values A1 and A2 corresponding to the difference between the speed set value and the speed detection values V1 and V2 are respectively expressed by the motor 5
1, 71. That is, the passing speed of the steel strip S in the pickling tank 6 is the same as that of the variable speed roll 5 installed immediately before the pretreatment device 61 and the variable speed roll 7 installed immediately after the post-treatment device 63. By rotating at a speed that achieves the speed set value, the speed set value is controlled.

【0012】ここで、図2の曲線は、スケール厚と酸洗
不良が生じない酸洗速度の上限値との関係を示してお
り、前記速度設定値は、この曲線を用いて、予め設定さ
れた鋼帯の長さ範囲毎に設定されるようになっている。
すなわち、制御装置11は、前記スケール厚検出値Tか
ら各範囲におけるスケール厚の最大値を検出し、この最
大スケール厚で酸洗不良が生じない酸洗速度の上限値を
図2の曲線から設定し、この設定された酸洗速度に応じ
た通板速度を前記速度設定値として算出する。なお、上
述の速度設定値を設定する単位になる鋼帯の長さ範囲
は、ここでは例えば100mとする。
Here, the curve in FIG. 2 shows the relationship between the scale thickness and the upper limit value of the pickling speed at which the pickling failure does not occur, and the speed set value is set in advance using this curve. The length is set for each length range of the steel strip.
That is, the control device 11 detects the maximum value of the scale thickness in each range from the scale thickness detection value T, and sets the upper limit value of the pickling speed at which the pickling failure does not occur at the maximum scale thickness from the curve in FIG. Then, the sheet passing speed according to the set pickling speed is calculated as the speed set value. Here, the length range of the steel strip as a unit for setting the above-mentioned speed setting value is, for example, 100 m.

【0013】また、制御装置11は、上記方法で各範囲
毎に算出された速度設定値を記憶する記憶手段を有し、
鋼帯の対応する範囲が酸洗槽6内に導入される直前に、
この記憶手段から対応する速度設定値を呼び出し、この
呼び出された速度設定値を達成する制御を行うように構
成されている。
Further, the control device 11 has storage means for storing the speed set value calculated for each range by the above method,
Immediately before the corresponding area of the steel strip is introduced into the pickling tank 6,
A corresponding speed set value is called from the storage means, and control is performed to achieve the called speed set value.

【0014】したがって、この設備によれば、鋼帯Sの
酸洗槽6内での通板速度が、鋼帯Sの所定長さ範囲毎
に、実測されたスケール厚に応じて、最大スケール厚の
部分でも酸洗不良が生じない酸洗速度となるように制御
されるため、鋼帯Sの全長において、スケール厚に応じ
た必要十分な酸洗が行われるようになる。
Therefore, according to this equipment, the passing speed of the steel strip S in the pickling tank 6 is set at the maximum scale thickness according to the actually measured scale thickness for each predetermined length range of the steel strip S. Is controlled so that the pickling rate does not cause poor pickling even in the portion of the steel strip S, so that the necessary and sufficient pickling according to the scale thickness is performed over the entire length of the steel strip S.

【0015】また、本実施形態の方法によれば、鋼帯の
所定長さ範囲毎にスケール厚の最大値に基づいて通板速
度の制御を行うため、スケール厚が増加方向および減少
方向に交互に頻繁に変化した場合でも通板速度を頻繁に
変化させる必要がない。これにより、適切な制御を行い
ながら設備にかかる負担を軽くすることができる。
Further, according to the method of this embodiment, since the passing speed is controlled based on the maximum value of the scale thickness for each predetermined length range of the steel strip, the scale thickness alternates in the increasing direction and the decreasing direction. It is not necessary to frequently change the passing speed even if the speed changes frequently. This makes it possible to reduce the load on the equipment while performing appropriate control.

【0016】これに対して、酸洗槽内での通板速度をス
ケール厚の変化に対応させて変化させる制御方法では、
スケール厚が増加方向と減少方向に交互に頻繁に変化し
た場合等には、通板速度の変化が頻繁になって設備にか
かる負担が大きくなる。
On the other hand, in the control method for changing the passing speed in the pickling tank in accordance with the change in the scale thickness,
For example, when the scale thickness alternately and frequently changes in the increasing direction and the decreasing direction, the passing speed changes frequently and the load on the equipment increases.

【0017】また、本実施形態では、スケール厚測定装
置を、酸洗層の入り口から酸洗槽の長さ分より上流側の
位置に設置しているため、鋼帯のある範囲の先端位置が
酸洗層内に入る前に当該範囲用の速度設定値が確実に設
定される。そのため、制御の応答遅れが生じ難く、確実
な速度制御が行われる。
In this embodiment, the scale thickness measuring device is installed at a position upstream of the pickling tank from the entrance of the pickling layer. Before entering the pickling layer, the speed setpoint for that range is reliably set. Therefore, a delay in control response hardly occurs, and reliable speed control is performed.

【0018】なお、前記設備において、速度可変ロール
5,7により通板速度を変化させることによって生じる
鋼帯Sの弛みや伸びは、入側ルーパ4および出側ルーパ
8によって許容されるようになっている。
In the above-mentioned equipment, the slack or elongation of the steel strip S caused by changing the passing speed by the variable speed rolls 5 and 7 is allowed by the entrance looper 4 and the exit looper 8. ing.

【0019】本発明の方法を採用した場合の、酸洗槽内
での通板速度の鋼帯の長さ方向における変化の一例(実
線A)と、従来例(一点鎖線B)を図3に示す。この図
から分かるように、従来は、酸洗槽内での通板速度を一
定(想定される最大スケール厚が確実に除去されるのに
十分な通板速度)にしているが、本発明の方法では、実
際のスケール厚(所定長さ範囲での最大値)に応じた通
板速度となっている。そのため、本発明の方法によれ
ば、例えば平均速度を従来より約20%も大きくするこ
とができる。
FIG. 3 shows an example (solid line A) and a conventional example (dashed-dotted line B) of the change in the stripping speed in the length direction of the steel strip in the pickling tank when the method of the present invention is adopted. Show. As can be seen from this figure, conventionally, the passing speed in the pickling tank is constant (sufficient passing speed for surely removing the assumed maximum scale thickness). In the method, the passing speed is set according to the actual scale thickness (the maximum value in the predetermined length range). Therefore, according to the method of the present invention, for example, the average speed can be increased by about 20% as compared with the related art.

【0020】[0020]

【発明の効果】以上説明したように、本発明の方法によ
れば、酸洗槽内での通板速度が適切に設定されて、スケ
ール厚に応じた必要十分な酸洗を行うことができる。そ
の結果、十分な酸洗性を得ながら、生産性を向上させ、
酸洗コストも低減することができる。
As described above, according to the method of the present invention, a necessary and sufficient pickling according to the scale thickness can be performed by appropriately setting the passing speed in the pickling tank. . As a result, while obtaining sufficient pickling properties, improve productivity,
The pickling cost can also be reduced.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の方法の一実施形態が適用可能な設備列
を示す概略構成図である。
FIG. 1 is a schematic configuration diagram showing an equipment row to which an embodiment of the method of the present invention can be applied.

【図2】スケール厚と酸洗不良が生じない酸洗速度の上
限値との関係を示すグラフである。
FIG. 2 is a graph showing the relationship between the scale thickness and the upper limit of the pickling rate at which no pickling failure occurs.

【図3】本発明の方法を採用した場合の、酸洗槽内での
通板速度の鋼帯の長さ方向における変化の一例(実線
A)と、従来例(一点鎖線B)を示すグラフである。
FIG. 3 is a graph showing an example (solid line A) of a change in a sheet passing speed in a length direction of a steel strip in a pickling tank in a case where the method of the present invention is adopted (solid line A) and a conventional example (dashed line B) It is.

【符号の説明】[Explanation of symbols]

S 鋼帯 1A ペイオフリール 1B ペイオフリール 2 ウエルダー 3 スケール厚測定装置 4 入側ルーパー 5 速度可変ロール 6 酸洗槽 61 前処理装置 62 前処理装置 63 後処理装置 7 速度可変ロール 8 出側ルーパー 9 走間シャー 10A 巻取りリール 10B 巻取りリール 11 制御装置 51 電動機 52 パルスジェネレータ 71 電動機 72 パルスジェネレータ S Steel strip 1A Payoff reel 1B Payoff reel 2 Welder 3 Scale thickness measuring device 4 Inlet looper 5 Variable speed roll 6 Pickling tank 61 Pretreatment device 62 Pretreatment device 63 Posttreatment device 7 Variable speed roll 8 Exit looper 9 Run Intermediate shear 10A Take-up reel 10B Take-up reel 11 Controller 51 Motor 52 Pulse generator 71 Motor 72 Pulse generator

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 熱間圧延鋼帯を巻き戻しながら連続的に
酸洗槽を通過させることにより、当該熱間圧延鋼帯の表
面に生成しているスケールを除去する熱間圧延鋼帯の酸
洗方法において、 酸洗槽より上流側の所定位置でスケールの厚さを検出
し、このスケール厚検出値の鋼帯の所定長さ範囲での最
大値を検出し、この検出されたスケール厚最大値から前
記範囲毎に鋼帯の酸洗槽内での通板速度を設定すること
を特徴とする熱間圧延鋼帯の酸洗方法。
1. A hot-rolled steel strip which is continuously rolled through an pickling tank while being unwound to remove the scale formed on the surface of the hot-rolled steel strip. In the washing method, the scale thickness is detected at a predetermined position on the upstream side of the pickling tank, and the maximum value of the scale thickness detection value within a predetermined length range of the steel strip is detected. A pickling method for a hot-rolled steel strip, comprising setting a sheet passing speed in a pickling tank of the steel strip for each of the ranges from the values.
JP35836797A 1997-12-25 1997-12-25 Method for pickling hot rolled steel strip Pending JPH11189885A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP35836797A JPH11189885A (en) 1997-12-25 1997-12-25 Method for pickling hot rolled steel strip

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP35836797A JPH11189885A (en) 1997-12-25 1997-12-25 Method for pickling hot rolled steel strip

Publications (1)

Publication Number Publication Date
JPH11189885A true JPH11189885A (en) 1999-07-13

Family

ID=18458931

Family Applications (1)

Application Number Title Priority Date Filing Date
JP35836797A Pending JPH11189885A (en) 1997-12-25 1997-12-25 Method for pickling hot rolled steel strip

Country Status (1)

Country Link
JP (1) JPH11189885A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1162287A2 (en) * 2000-06-06 2001-12-12 SMS Demag AG Process and apparatus for pickling a rolled metal strand, particularly for steel strip
JP2014226720A (en) * 2013-05-27 2014-12-08 新日鐵住金株式会社 Coil with leader strip, and method of and system for producing the same
JP2017170489A (en) * 2016-03-24 2017-09-28 日新製鋼株式会社 Method for manufacturing ferritic stainless steel sheet
WO2019124968A1 (en) * 2017-12-19 2019-06-27 주식회사 포스코 Pickling apparatus and pickling method
WO2019202644A1 (en) * 2018-04-16 2019-10-24 Primetals Technologies Japan株式会社 Pickling facility and method for operating pickling facility
WO2021167331A1 (en) * 2020-02-18 2021-08-26 주식회사 포스코 High-carbon steel sheet having good surface quality and manufacturing method therefor
JP2023514592A (en) * 2020-02-18 2023-04-06 ポスコホールディングス インコーポレーティッド Steel sheet with excellent surface quality and its manufacturing method

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1162287A2 (en) * 2000-06-06 2001-12-12 SMS Demag AG Process and apparatus for pickling a rolled metal strand, particularly for steel strip
EP1162287A3 (en) * 2000-06-06 2004-01-07 SMS Demag AG Process and apparatus for pickling a rolled metal strand, particularly for steel strip
JP2014226720A (en) * 2013-05-27 2014-12-08 新日鐵住金株式会社 Coil with leader strip, and method of and system for producing the same
JP2017170489A (en) * 2016-03-24 2017-09-28 日新製鋼株式会社 Method for manufacturing ferritic stainless steel sheet
WO2019124968A1 (en) * 2017-12-19 2019-06-27 주식회사 포스코 Pickling apparatus and pickling method
CN111886364A (en) * 2018-04-16 2020-11-03 普锐特冶金技术日本有限公司 Pickling device and method for operating pickling device
WO2019202644A1 (en) * 2018-04-16 2019-10-24 Primetals Technologies Japan株式会社 Pickling facility and method for operating pickling facility
JPWO2019202644A1 (en) * 2018-04-16 2021-03-11 Primetals Technologies Japan株式会社 Pickling equipment and how to operate the pickling equipment
CN111886364B (en) * 2018-04-16 2022-07-26 普锐特冶金技术日本有限公司 Pickling device and method for operating pickling device
US11814736B2 (en) 2018-04-16 2023-11-14 Primetals Technologies Japan, Ltd. Pickling facility and operation method of pickling facility
WO2021167331A1 (en) * 2020-02-18 2021-08-26 주식회사 포스코 High-carbon steel sheet having good surface quality and manufacturing method therefor
CN115135796A (en) * 2020-02-18 2022-09-30 株式会社Posco High carbon steel sheet having good surface quality and method for manufacturing same
JP2023514592A (en) * 2020-02-18 2023-04-06 ポスコホールディングス インコーポレーティッド Steel sheet with excellent surface quality and its manufacturing method
CN115135796B (en) * 2020-02-18 2023-12-05 株式会社Posco High carbon steel sheet with good surface quality and method for manufacturing the same

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