JPH10183172A - Cleaning agent composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a cleaning agent composition excellent in detergency, foamability and foam sustainability, and high in germicidal and antimicrobial effects by containing a specific sulfuric ester-based surfactant, a specific germicide and an alkanolamide-based surfactant. SOLUTION: This cleaning agent composition is formulated by (A) 5-50wt.% of a sulfuric ester-based surfactant of the formula R<1> O-(CH2 CH2 O)n -SO3 M<1> [R<1> is an 8-20C straight- or branched-chain alkyl, etc.; (n) is 0-10; M<1> is an alkaline (earth) metal, etc.], (B) 0.2-5wt.% of at least one member selected from a cationic germicide of formula I (R<2> and R<3> are each a 6-14C long-chain alkyl with the number of C atoms totaling 16-26, etc.; R<4> and R<5> are each a 1-3C alkyl, etc.; Z<1> is a halogen, an amino acid, etc.), formula II (R<6> is an 8-14C hydrocarbon moiety, a group of formula III, etc.), formula IV (Z<2> is acetic acid, HCl, etc.), or formula V (R<7> is a 6-18C straight- or branched-chain alkyl; Z<3> is an amino acid, a fatty acid, etc.), and polyhexamethylenebiguanide, (C) 0.1-10wt.% of an alkanolamide-based surfactant and (D) optionally, e.g. a metal chelating agent.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a detergent composition, and more particularly, to a detergent composition which is excellent in detergency, foaming power and foam sustainability and can stably incorporate a cationic bactericide, and has a high disinfection and antibacterial effect. The present invention relates to a cleaning composition which has excellent scalp and body Kayumi prevention and deodorization effects and can prevent dandruff on the scalp.

[0002]

2. Description of the Related Art Conventionally, cleaning agents, particularly hair cleaning agents, include:
In many cases, an anionic surfactant such as polyoxyethylene alkyl ether sulfate or alkenyl ether sulfate was used as a main base for the purpose of obtaining excellent detergency and foaming power.

On the other hand, detergents, especially for hair and body, are required to have a bactericidal and antibacterial effect in addition to the washing effect. The use of a cationic disinfectant as a disinfectant is known.

[0004] However, when an anionic surfactant and a cationic germicide are used in combination, these complexes are formed, resulting in a problem that not only the detergency is reduced but also the bactericidal effect is not sufficiently exhibited. Furthermore, there are problems such as impairing the foaming properties of the anionic surfactant and the sustainability of the foam.

As a method for preventing such a decrease in the bactericidal effect, a method of coating a cationic bactericide with a high-molecular nonionic activator or a pH-sensitive polymer has been adopted.

However, in the method of coating with such a polymer, the activity of the cationic germicide decreases,
It is not a fundamental solution.

[0007]

SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to provide a high bactericidal effect and a high antibacterial effect by stably blending a cationic germicide with excellent detergency, foamability and foam continuity. By doing so, anti-dandruff property, anti-itch property,
An object of the present invention is to provide a detergent composition having a deodorizing effect.

[0008]

Means for Solving the Problems In view of such circumstances, the present inventors have conducted intensive studies and as a result, have determined that a specific sulfate ester-based surfactant, a specific cationic bactericide and an alkanolamide-based surfactant can be used in specific amounts. When used in combination, the detergent has high detergency, high foaming properties, long lasting foam, and has sufficient bactericidal and antibacterial properties. As a result, it has excellent anti-dandruff, anti-kayumi, and deodorant effects. The inventors have found that a composition can be obtained and completed the present invention.

That is, the present invention provides the following component (A):
(B) and (C); (A) General formula (1) R ¹ O— (CH ₂ CH ₂ O) _n —SO ₃ M ¹ (1) [wherein, R ¹ is a straight chain having 8 to 20 carbon atoms. Represents an alkyl or alkenyl group having a chain or a branched chain, n represents a number of 0 to 10 on average, and M ¹ represents an alkali metal atom, an alkaline earth metal atom, an ammonium group, an alkyl ammonium group or an alkanol ammonium group. 5 to 50% by weight of a sulfate ester surfactant represented by the following formula: (B) a cationic fungicide represented by the following general formulas (2), (3), (4) and (5); and polyhexamethylene. One or more selected from biguanides 0.2 to 5% by weight,

[0010]

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[R ² and R ³ each represent a long-chain alkyl group, long-chain alkenyl group or long-chain hydroxyalkyl group having 6 to 14 carbon atoms and a total of 16 to 26 carbon atoms. May be. R ⁴ and R ⁵ have 1 carbon atom
Represents an alkyl group, a hydroxyalkyl group or a polyoxyethylene group having an average number of moles of 10 or less, which may be the same or different. Z ¹ is a halogen atom, an amino acid, a fatty acid, an anionic residue of a phosphate ester, a phosphonate ester, a sulfonate ester or a sulfate ester having a linear or branched alkyl or alkenyl group having 1 to 30 carbon atoms, or polymerization Degree 3
An anionic oligomer or polymer containing a formalin condensate of a sulfonated polycyclic aromatic compound having styrene sulfonic acid or having a hydrocarbon group as a substituent is described. ]

[0012]

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Wherein R ⁶ is a hydrocarbon group having 8 to 14 carbon atoms or

[0014]

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Wherein Z ¹ is a halogen atom, an amino acid, a fatty acid, a phosphoric ester, a phosphonic ester or a sulfonic acid having a linear or branched alkyl or alkenyl group having 1 to 30 carbon atoms. An anion residue of an ester or a sulfate ester, or an anion containing a formalin condensate of a sulfonated polycyclic aromatic compound having styrenesulfonic acid having a degree of polymerization of 3 or more or having a hydrocarbon group as a substituent Shows a functional oligomer or polymer. ]

[0016]

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[Z ² represents gluconic acid, acetic acid or hydrochloric acid. ]

[0018]

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[In the formula, R ⁷ represents a linear or branched alkyl group having 6 to 18 carbon atoms, and Z ³ represents a halogen atom, an amino acid, a fatty acid, a linear or branched alkyl group having 1 to 30 carbon atoms. May have an anionic residue of a phosphoric acid ester, a phosphonic acid ester, a sulfonic acid ester or a sulfuric acid ester having a carboxylic acid group or an alkenyl group, or a styrenesulfonic acid having a degree of polymerization of 3 or more, or may have a hydrocarbon group as a substituent. An anionic oligomer or polymer containing a formalin condensate of a sulfonated cyclic aromatic compound is shown. ] (C) 0.1 to 10% by weight of an alkanolamide-based surfactant, and a detergent composition characterized by comprising component (A) a sulfate-based surfactant as a main cleaning base. Is what you do.

[0020]

BEST MODE FOR CARRYING OUT THE INVENTION In the formula (1) showing (A) a sulfate ester surfactant used in the present invention, R ¹ is a linear or branched alkyl or alkenyl group having 10 to 16 carbon atoms. And n is preferably 0 to 6 on average from the viewpoint of detergency and foaming property, more preferably 0 to 4, and particularly preferably 1 to 4. Also particularly preferred is a sodium atom, ammonium and triethanol ammonium as M ^1.

The sulfate ester surfactant of the component (A) serves as a main cleaning base of the cleaning composition of the present invention, and is used in an amount of 50% by weight or more of the total detersive surfactant. is there. In addition, from the viewpoints of detergency, foaming properties, and incorporation of other components, 5 to 50% by weight (hereinafter simply referred to as%), preferably 7 to 30%, particularly preferably 8 to 25% by weight in the whole composition. %.

The cationic bactericide of the component (B) used in the present invention includes a quaternary ammonium salt represented by the general formula (2), a benzalkonium salt represented by the general formula (3), and benzethonium. One or more selected from a salt, a chlorhexidine salt represented by the general formula (4), a pyridinium salt represented by the general formula (5), and polyhexamethylene biguanide. Polyhexamethylene biguanide is available from CTFA's International Cosmetic Ingredient Di
ctionary 5th edition, POLYAMINOPROPYL BIGUANIDE
"Cosmocil",
Known under the trademark “Mikrokill”. As Z ¹ in the general formulas (2) and (3), a halogen atom is particularly preferable.

Specific examples of preferred component (B) include benzalkonium chloride, benzethonium chloride, cetylpyridinium chloride, chlorhexidine gluconate, chlorhexidine acetate, chlorhexidine hydrochloride, and the like, with benzalkonium chloride and benzethonium chloride being particularly preferred. . Furthermore, the general formula (3a)

[0024]

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[In the formula, R ^6a represents a linear or branched alkyl or alkenyl group having 8 to 14 carbon atoms.]

The benzalkonium chloride represented by the formula is preferred.

The cationic bactericide of the component (B) can be used alone or in combination of two or more. From the viewpoint of the antibacterial effect, 0.2 to 5%, preferably 0.3 to 4% in the total composition. %,
Particularly preferably, the content is 0.5 to 2%.

The alkanolamide surfactant of the component (C) used in the present invention is represented by the general formula (6):

[0029]

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(Wherein, R ⁸ represents a linear or branched alkyl or alkenyl group having 7 to 19 carbon atoms;
Each represents an integer of 0 to 10, and at least one of p and q is 1 or more), wherein p + q is 1 to 5, particularly 1 or 2, and R ⁸ is carbon. Those which are linear or branched alkyl groups or alkenyl groups of the formulas 7 to 15 are more preferable. The alkanolamide-based surfactant as the component (C) is contained in the total composition in an amount of from 0.1 to 0.1 from the viewpoints of detergency, foaming property, foam retention and antibacterial effect.
10%, preferably 1-8%, more preferably 2-7%
Be blended.

In the cleaning composition of the present invention, (A)
The weight ratio of / (C) is preferably 1 to 50, more preferably 2 to 30, and more preferably 2 to 30, from the viewpoint of the bactericidal / antibacterial effect of the component (B).
15 is more preferred.

The detergent composition of the present invention may further contain a chelating agent to enhance the bactericidal and antibacterial effects. The metal chelating agent used in the present invention is not particularly limited as long as it has the ability to chelate metal ions, aminopolycarboxylic acid chelating agents,
Aromatic and aliphatic carboxylic acid chelating agents, amino acid chelating agents, ether polycarboxylic acid chelating agents, iminodimethylphosphonic acid (IDP), alkyl diphosphonic acid (ADPA), 1-hydroxyethane-1,1-diphosphone Examples thereof include a phosphonic acid-based chelating agent such as an acid (DEQUEST ^™ 2010), a hydroxycarboxylic acid-based chelating agent, a phosphoric acid-based chelating agent, a polymer electrolyte (including an oligomer electrolyte) -based chelating agent, and dimethylglyoxime (DG). Each of these chelating agents may be in a free acid form or in a salt form such as a sodium salt, a potassium salt, and an ammonium salt. In addition, they may be in the form of their hydrolyzable ester derivatives.

Specific examples of the aminopolycarboxylic acid chelating agent include: a) a compound represented by the chemical formula R ⁹ N (Y) ₂ , b) a compound represented by the chemical formula N (Y) ₃ , c) a chemical formula R ⁹ -N (Y) a compound represented by _{-CH 2 CH 2 -N (Y)} -R 9, represented by d) formula _{^{R 9 -N (Y) -CH 2}} CH 2 -N (Y) 2 A compound, e) a compound represented by the chemical formula (Y) ₂ NR ¹⁰ -N (Y) ₂ , and f) a compound similar to the compound of e), wherein the compound contains 4 or more Y, for example, a compound represented by the formula

[0034]

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And the like.

In the above formula, Y is -CH ₂ COOH or -CH ₂ CH ₂ COOH
R ⁹ represents a group constituting a known chelating agent such as a hydrogen atom, an alkyl group, a hydroxyl group, a hydroxyalkyl group, and R ¹⁰ represents a known chelating agent of this type such as an alkylene group or a cycloalkylene group. A group to be used.

A typical example of an aminopolycarboxylic acid chelating agent is ethylenediaminetetraacetic acid (EDT).
A), cyclohexanediaminetetraacetic acid (CDT
A), nitrilotriacetic acid (NTA), iminodiacetic acid (I
DA), N- (2-hydroxyethyl) iminodiacetic acid (HIMDA), diethylenetriaminepentaacetic acid (D
TPA), N- (2-hydroxyethyl) ethylenediaminetriacetic acid (EDTA-OH) and glycol etherdiaminetetraacetic acid (GEDTA), and salts thereof.

Examples of the aromatic or aliphatic carboxylic acid chelating agents used in the present invention include oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, itaconic acid, aconitic acid, pyruvic acid, salicylic acid, Examples include acetylsalicylic acid, hydroxybenzoic acid, aminobenzoic acid (including anthranilic acid), phthalic acid, trimellitic acid and gallic acid, and salts, methyl esters and ethyl esters thereof. Examples of the amino acid chelating agent used in the present invention include glycine, serine, alanine, lysine, cystine, cysteine, ethionine, tyrosine, methionine, and salts and derivatives thereof.

Further, examples of the ether polycarboxylic acid-based chelating agent used in the present invention include diglycolic acid, compounds represented by the following formula, analogous compounds thereof and salts thereof (for example, sodium salts). .

[0040]

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Examples of the hydroxycarboxylic acid chelating agents used in the present invention include malic acid, citric acid, glycolic acid, gluconic acid, heptonic acid, tartaric acid, lactic acid and salts thereof. Examples of the phosphate chelating agent used in the present invention include orthophosphoric acid, pyrophosphoric acid, triphosphoric acid and polyphosphoric acid. Examples of the polymer electrolyte (including oligomer electrolyte) chelating agent used in the present invention include acrylic acid polymer, maleic anhydride polymer, α-hydroxyacrylic acid polymer, itaconic acid polymer, Copolymers composed of two or more kinds of constituent monomers of the union and epoxy succinic acid polymers are exemplified. Furthermore, in the present invention, ascorbic acid, thioglycolic acid, phytic acid, glyoxylic acid and glyoxalic acid, and salts thereof can also be suitably used as a chelating agent.

Among the above-mentioned chelating agents, particularly preferred are ethylenediaminetetraacetic acid (EDTA), succinic acid, salicylic acid, oxalic acid, lactic acid, fumaric acid, tartaric acid, 1-hydroxyethane-1,1-diphosphonic acid and the like. Salts.

The metal chelating agent is preferably added in an amount of 0.1 to 8%, more preferably 0.2 to 5%, particularly preferably 0.2 to 3% in the whole composition.

Further, the detergent composition of the present invention may contain an anionic surfactant which is usually used in detergents as long as the effect of the present invention is not impaired. Such anionic surfactants include alkyl sulfonates,
Sulfosuccinates, α-sulfofatty acid ester salts, α-olefin sulfonates, saturated or unsaturated higher fatty acid salts, monoester phosphate surfactants, acylated amino acids, acylated isethionates, and the like.

Further, by adding 0.1 to 5% of a silicone derivative to the cleaning composition of the present invention, a good sliding feeling and a smooth feeling can be obtained. The silicone derivative is not particularly limited as long as it is generally used in detergents and cosmetics. Examples thereof include dimethylpolysiloxane, methylphenylpolysiloxane, polyether-modified silicone, epoxy-modified silicone, alkoxy-modified silicone, and amino-modified silicone. , Fatty acid-modified silicone, fluorine-modified silicone and the like.

The cleaning composition of the present invention may contain 0.1 to 5% of an anti-dandruff agent. Here, examples of the anti-dandruff agent include zinc pyrithione, pyrocton auramine, selenium disulfide and the like.

Further, the detergent composition of the present invention may contain 0.1 to 5% of a feel improving agent. Examples of the feel improver include cationic cellulose derivatives, cationic starch, cationic guar gum derivatives, copolymers of diallyl quaternary ammonium salts and acrylamide, quaternized polyvinylpyrrolidone derivatives, and cations such as polyglycolamine condensates. Polymer.

Further, in addition to the above-mentioned components, the detergent composition of the present invention may further contain, if necessary, components usually incorporated in cosmetics, pharmaceuticals, foods, etc., for example, non-cationic fungicides,
Anti-inflammatory agents such as glycyrrhizic acid, dihydrocholesterin and allantoin, medicinal agents and preservatives; humectants such as propylene glycol, glycerin, diethylene glycol monoethyl ether, sorbitol and panthenol; dyes;
Coloring agents such as pigments; Pearling agents, chitosan derivatives such as hydroxypropyl chitosan; various compounded fragrances; and other encyclopedias of shampoos and ingredients
E PRESS 1985)] can be appropriately blended as long as the effects of the present invention are not impaired.

The cleaning composition of the present invention can be produced according to a usual method, and can be in the form of paste, gel, liquid or the like. It is also suitable as a hair, body, and finger cleaner.

[0050]

The cleaning composition of the present invention has excellent detergency, foaming properties and foam sustainability, and can stably incorporate a cationic bactericide. -Since it exhibits an antibacterial spectrum, it can impart sufficient antidandruff properties to the scalp and antipruritic and deodorant effects to the body and scalp.

[0051]

EXAMPLES Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples. In addition, the compounding amount of each component in the following examples was shown on the basis of the effective component.

Examples 1 to 7 Comparative Examples A to C A cleaning composition having the composition shown in Table 1 was prepared by a conventional method, and its cleaning power, foaming power, foam persistence, antibacterial activity, antidandruff property and The deodorant effect was evaluated. Table 1 shows the results.

(Evaluation Criteria) <Evaluation Method and Evaluation Criteria of Detergency> Five healthy men and women were allowed to wash their hair once a day for one week with each cleaning composition. Was evaluated.

(Evaluation criteria) 5: Detergency was good 4: Detergency was somewhat good 3: Detergency was normal 2: Detergency was not so good 1: Detergency Felt bad

The results were expressed as the average value of 10 panelists as detergency according to the following criteria. ◎: Good for 4.0 or more ○: Somewhat good for 3.2 to 3.9 △: Normal for 2.5 to 3.1 ×: Poor for 2.4 or less

<Evaluation Method and Evaluation Criteria of Foaming Property> 1 g of the present cleaning composition was applied to 20 g (15 cm) of hair of a healthy Japanese woman, washed for 30 seconds, and foamed by 10 expert panelists. The evaluation was performed according to the following criteria.

(Evaluation Criteria) 5: Foaming was felt good 4: Foaming was somewhat good 3: Foaming was normal 2: Foaming was not so good 1: Foaming was not good Was

As a result, the average value of 10 panelists was expressed as a foaming power according to the following criteria. ◎: Good for 4.0 or more ○: Somewhat good for 3.2 to 3.9 △: Normal for 2.5 to 3.1 ×: Poor for 2.4 or less

<Evaluation Method and Evaluation Criteria of Foam Persistence> The present detergent composition was washed once a day by a panel of five men and women once a day for one week, and the sensory evaluation of foam persistence during cleaning was conducted. Was performed according to the following criteria.

(Evaluation Criteria) 5: Sustained foam was felt good 4: Sustained foam was somewhat good 3: Sustained foam was normal 2: Sustained foam was very good I felt that there was no 1: I felt that the foam persistence was not good

As a result, the average value of 10 panelists was expressed as the foam persistence according to the following criteria. ◎: Good for 4.0 or more ○: Somewhat good for 3.2 to 3.9 △: Normal for 2.5 to 3.1 ×: Poor for 2.4 or less

<Anti-dandruff evaluation method and evaluation criteria> One month of hair was applied to the monitor of five men with the cleaning composition of the present invention for one month.
Washed once a day. After the last shampoo, the shampoo was stopped for about 48 hours, and the hair was washed once again with 3 g of the detergent composition twice to collect the entire shampoo. The entire amount of the collected hair washing liquid was filtered through a 50 nylon mesh to remove unnecessary dust and hair. The total amount of the filtrate was filtered through a 255 nylon mesh (100 × 100 μm) whose weight was measured in advance. After the nylon mesh was air-dried for about 48 hours at room temperature, the dandruff weight was determined by the weight of the stratum corneum captured by the 255 nylon mesh. The average value of the dandruff weights of six persons was expressed as anti-dandruff property according to the following criteria.

：: dandruff weight ≦ 30 mg ○: 30 mg <dandruff weight ≦ 40 mg Δ: 40 mg <dandruff weight ≦ 50 mg ×: 50 mg <dandruff weight

<Evaluation Method and Evaluation Criteria of Deodorant Effect> For each cleaning composition, a usage test was conducted once a day for two weeks by panelists of five males and five females. With respect to the deodorant effect, a body odor 24 hours after the final washing was evaluated by a professional evaluator according to the following evaluation criteria.

(Evaluation criteria) 5: No smell 4: Slight smell 3: Smell 2: Slight smell 1: Very strong smell

The results were expressed as an average of 10 panelists as a deodorant effect according to the following criteria. ◎: Good for 4.0 or more ○: Somewhat good for 3.2 to 3.9 △: Normal for 2.5 to 3.1 ×: Poor for 2.4 or less

<Test method for antibacterial activity> Test bacterium Staphylococcus
aureus (St. aureus) IFO 12732
CD medium (manufactured by Nippon Pharmaceutical Co., Ltd.), test strain Malass ezia fu
For rfur (M. furfur) IFO 658, preculture is Malt-Yeast
Medium (Casitone (Difco) 0.5%, Yest-extract (Difco
0.67%, Yeast-Nitrogen-base (Difco) 0.5%,
Glucose 2%, Reodol TW-S120 (manufactured by Kao Corporation)
0.1%) at 35 ° C.

The pre-cultured bacterial solution was prepared using SCD agar medium (manufactured by Nippon Pharmaceutical Co., Ltd.) for St. aureus, and Malt agar medium (Malt-extract (manufactured by Difco)) for M. furfur.
%, Leo Doll TW-S120 (manufactured by Kao Corporation) 0.1% agar 1.5
%). After injecting 50 μl of the detergent composition, a water-washed paper disc (diameter 8 mm) is placed on an agar medium smeared with a bacterial solution, and the diameter (mm) of the inhibition circle after 24 hours at 35 ° C. is determined. did.

[0069]

[Table 1]

Example 8 A systemic detergent having the following composition was produced by a conventional method.

Polyoxyethylene coco ether sulfate sodium salt (EO = 3) 16% lauroyldiethanolamide 3% cetylpyridinium chloride 1% disodium succinate 1% 1-hydroxyethane-1,1-diphosphonic acid solution (60%) 0.3% Glycerin 3% Methylparaben 0.2% Pearling agent (ethylene glycol distearate) 2% Dibutylhydroxytoluene 0.2% Fragrance 0.1% Water Balance meter 100.0%

The obtained whole body detergent was excellent in detergency and foaming power, and had high deodorant effect and antidandruff effect.

Example 9 A hair cleansing composition having the following composition was produced by a conventional method.

Polyoxyethylene lauryl ether sulfate sodium salt (EO = 2) 18% Coconut oil fatty acid monoethanolamide 2% Benzalkonium chloride ^{* 1} 0.5% Disodium succinate 1% 1-Hydroxyethane-1,1 -Diphosphonic acid liquid (60%) 0.3% Butyl paraben 0.2% Fragrance 0.2% Water balance meter 100.0%

The obtained hair cleansing agent was excellent in detergency and foaming power, and had a high anti-dandruff effect.

Example 10 A hand cleanser having the following composition was produced by a conventional method.

Polyoxyethylene lauryl ether sulfate ammonium (EO = 3) 15% coconut oil fatty acid diethanolamide 3% benzalkonium chloride ^{* 1} 1% salicylic acid sodium salt 0.2% 1-hydroxyethane-1,1-diphosphonic acid Liquid (60%) 0.2% Polyvinyl alcohol 1% Butyl paraben 0.2% Propylene glycol 0.5% Pearling agent (ethylene glycol distearate) 2% Fragrance 0.1% Water balance meter 100.0%

The obtained hand-washing agent was excellent in detergency and foaming power, and had high sterilizing and antibacterial effects.

──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. ⁶ Identification code FI C11D 3/48 C11D 3/48 (72) Inventor Yasuhiro Doi 1334 Minato, Wakayama-shi, Wakayama Pref.

Claims (2)

[Claims] 1. The following components (A), (B) and (C): (A) General formula (1) R ¹ O— (CH ₂ CH ₂ O) _n —SO ₃ M ¹ (1) In the formula, R ¹ represents a linear or branched alkyl or alkenyl group having 8 to 20 carbon atoms, n represents an average of 0 to 10, M ¹ represents an alkali metal atom, an alkaline earth metal atom, or ammonium. Group, an alkylammonium group or an alkanolammonium group] 5 to 50% by weight of a sulfate-based surfactant represented by the following general formulas (2), (3), (4) and (5) 0.2 to 5% by weight of one or more selected from a cationic fungicide and polyhexamethylene biguanide represented by the following formula: [R ² and R ³ each have 6 to 14 carbon atoms and a total of 16 to
26 represents a long-chain alkyl group, a long-chain alkenyl group, or a long-chain hydroxyalkyl group, which may be the same or different. R ⁴ and R ^{5 each} represent an alkyl group having 1 to 3 carbon atoms, a hydroxyalkyl group or a polyoxyethylene group having an average number of moles of 10 or less, which may be the same or different. Z ¹ is a halogen atom, an amino acid, a fatty acid, an anionic residue of a phosphate ester, a phosphonate ester, a sulfonate ester or a sulfate ester having a linear or branched alkyl group or alkenyl group having 1 to 30 carbon atoms, or polymerization An anionic oligomer or polymer containing a formalin condensate of a sulfonated polycyclic aromatic compound which may have styrenesulfonic acid of degree 3 or more or may have a hydrocarbon group as a substituent. [Chemical formula 2] [Wherein R ⁶ is a hydrocarbon group having 8 to 14 carbon atoms or And Z ¹ represents a halogen atom, an amino acid,
Fatty acids, phosphoric acid esters having a linear or branched alkyl or alkenyl group having 1 to 30 carbon atoms, phosphonic acid esters, sulfonic acid esters or sulfuric acid ester anionic residues, or styrene sulfonic acid having a polymerization degree of 3 or more. An anionic oligomer or polymer containing a formalin condensate of a sulfonated polycyclic aromatic compound which may have or have a hydrocarbon group as a substituent is shown. [Formula 4] [Z ² represents gluconic acid, acetic acid or hydrochloric acid. [Chemical formula 5] [Wherein, R ⁷ represents a linear or branched alkyl group having 6 to 18 carbon atoms, and Z ³ represents a halogen atom, an amino acid, a fatty acid, a linear or branched alkyl group or alkenyl having 1 to 30 carbon atoms. Anionic residue of a phosphoric acid ester, a phosphonic acid ester, a sulfonic acid ester or a sulfuric acid ester, or a polycyclic aromatic compound having styrenesulfonic acid having a degree of polymerization of 3 or more or having a hydrocarbon group as a substituent An anionic oligomer or polymer containing a formalin condensate of a sulfonated group compound is shown. ] (C) 0.1 to 10% by weight of an alkanolamide-based surfactant, and the component (A) a sulfate-based surfactant as a main cleaning base. 2. The cleaning composition according to claim 1, further comprising one or more metal chelating agents.