JPH03293002A - Mineral liquid and its extraction method - Google Patents

Abstract

PURPOSE:To improve the long-period stability of its effect by extracting the mineral liq. from the rock consisting of mantle substances, the rock consisting of the substances constituting the land, etc., with an aq. acidic or alkaline soln. CONSTITUTION:One or more kinds among the rock consisting of mantle substances such as peridotite, serpentine and garnet, the rock consisting of the substances constituting the land such as granite, rhyolite and andesite and the rock consisting of mineral substances such as obsidian, pitchstone and amphibole are gathered. A 20-40% aq. soln. of the rock in sulfuric acid, hydrochloric acid and nitric acid or a 20-40% aq. soln. of the rock in sodium hydroxide and potassium hydroxide is boiled at 80-110 deg.C to obtain a mineral liq. The mineral liq. has the mineral crystallites consisting of a mineral crystal structure.

Description

[Detailed Description of the Invention] [Industrial Application Field] This invention relates to a mineral liquid extracted from a rock made of mantle material, a rock made of continental material, a rock made of minerals, etc., and a method for extracting the same. More specifically, the present invention relates to a mineral liquid having remarkable bioactive functions, a function of separating substances dissolved in wood from water, a function of dissolving hardly soluble substances in water, etc., and a method for extracting the same.

[Prior Art] Conventionally, mineral-containing rocks have been used as a soil conditioner by putting them into the soil, or as a means of improving water, or they have been made into a fine powder and orally administered to treat concretions. It was used as such.

For example, lime is used as an improvement agent for acidic soil by plowing into cultivated land, and fertilizer made by reacting magnesium extracted from peridotite or serpentinite with phosphate rock at high temperatures is used as a soil improvement method. Ta.

In addition, the medicinal stone was powdered and mixed into feed and administered to livestock, or it was sprinkled on the cultivated soil for edible vegetables.

Furthermore, Maihan stone was used to purify the aquaculture water by putting it into carp and other aquaculture ponds.

The use of rocks is generally based on long-established empirical rules, and it is often used vaguely without fully understanding what components of the rocks are responsible for the actions and effects brought about by the rocks used. It has been commonly used by pulverizing rock and plowing it directly into cultivated land, by putting it directly into treated water, or by giving it orally to livestock.

In addition, the bioactive functions of plants and animals and the purifying function of treated water, which are possessed by the rocks used in these methods, are not effectively brought out in a short period of time, and the empirically recognized effects usually slow down over time. It is common for this to occur.

The conventional method of using rocks is to prepare rocks with different properties of minerals contained in each rock, and use each rock individually as a soil conditioner, etc., to improve the effects of each rock. After comparing the effects, it became clear that the unique effects of each rock are influenced by the minerals contained in these rocks.

Therefore, we artificially extract these types of minerals from rocks, prepare mineral extracts that have the unique actions and effects of each rock, and then customize this mineral extract to the characteristics of each rock. Attempts are being made to use them together.

The precipitated flocculant for water treatment according to the invention of Japanese Patent Application No. 57-98747 is a flocculant obtained by extracting minerals from rocks. It was composed of saprolites (sabrolites) produced by the weathering of granite, soils in which these saprolites were further weathered, or a mixture of these saprolites and this weathered soil.

In addition, minerals can be extracted from these sacrificial rocks and the weathered soil of these sacrificial rocks using a 25% aqueous sulfuric acid solution.
The weight ratio of this aqueous solution and the extraction raw material is 4:4 or 4:3.
This was accomplished by mixing the mixture so that

Furthermore, extraction was carried out by stirring the above-mentioned mixture in a 25% aqueous sulfuric acid solution at 100° C. for several hours.

The extract obtained in this manner contains silicon, aluminum, magnesium, iron, potassium, sodium, etc. contained in the extraction target in the form of sulfur, acid salts, or oxides in the sulfuric acid aqueous solution. It had the property of preventing cloudy solids from agglomerating and redispersing due to charge neutralization. or,
It has the property of decomposing organic substances and coagulating them into metal and nonmetal double salts and complex salts.

In addition, the active silicic acid contained therein had the property of particularly promoting aggregation.

[Problems to be Solved by the Invention] However, the precipitated flocculant for water treatment according to the invention of Japanese Patent Application No. 57-98747 has been found to have a flocculating effect on suspended solids, etc., and has a relatively low flocculating effect. is formed slowly, and when treating suspended solids, a long time and a large number of aggregation agents are required, and it is not necessarily satisfactory as a water treatment agent in terms of immediate effect, flocculation efficiency, etc. There wasn't.

In addition, when growing root vegetables using the extract extracted using the above sulfuric acid aqueous solution and spreading it on the planting soil, the growth rate was higher than when growing root vegetables in the planting soil where the extract was not applied. Although a slight increase in yield was observed, no outstanding features were observed in planting.

Furthermore, the extract extracted using the above sulfuric acid aqueous solution is mixed with the tree on which cut flowers are arranged, and the freshness of the cut flower is maintained. When comparing the degree of freshness, it was found that there were significant differences in terms of the number of days the cut flowers were kept alive and the degree of freshness maintenance, but overall no significant freshness preservation effect was achieved. Ta.

Furthermore, a comparison was made between cases in which livestock were reared by mixing the above extract into their feed, and cases in which animals were reared without administering this extract, and it was found that there was a difference between the two. I wanted most of the differences above to be recognized. In addition, a comparison was made of the aquaculture efficiency between the case where the above-mentioned extract was administered into the fish culture tank and the case where the aquaculture was carried out after the administration of this extract. The difference in efficiency was hardly improved.

The disadvantage of these conventional extraction liquids in terms of their effects and effects is that the object to be extracted is sacrificial rock produced by weathering of granite, or soil grown by further weathering of these sacrificial rocks. One reason for this is that the crystal structure of the minerals contained in the extracted liquid is incomplete, such as montmorillonite and vermiculite.
Other cations are added to stabilize the structure in a relatively rough manner, and its properties can be changed with a small amount of energy.
It has disadvantages such as being easily influenced by the outside world.

It is believed that one of the main causes of the inconvenience caused by the effects and effects of flFi extracts on the extraction target is extraction under the above-mentioned extraction conditions. Using a pickle, extract the target material by weight and
After stirring and mixing with a sulfuric acid aqueous solution in a ratio of 3:4 or 4:4,
In the method of extracting the extract by leaving it for several hours, or in the extraction method of obtaining the extract by stirring the mixture for several hours under conditions of heating the mixture to 100°C, the obtained extract is If the characteristics of the target rock etc. are not fully brought out, or the minerals in the extracted liquid are not stabilized and recrystallize over time, the characteristics of the target rock etc. are not fully brought out. Disadvantages include the small crystal structure of minerals, which easily change their properties with a small amount of energy, and not having enough activation energy, and similarly, the condensation force due to the charge neutralization effect of suspended solids is not sufficient. It had

The mineral liquid and its extraction method according to the present invention eliminate the disadvantages of the mineral liquid produced by the conventional method, and preserve the remarkable characteristics inherent to rocks etc. The purpose of the present invention is to provide a mineral liquid having the following properties and a method for extracting the mineral liquid having the following properties.

[Means for Solving the Problems] The present invention achieves the following objects, and the invention of claim 1 provides: (1) Rocks made of mantle materials such as peridotite, serpentine, and garnet. , (2) Rocks made of continental materials such as granite, rhyolite, quartz diorite, andesite, basalt, and gabbro; (3) Obsidian 4 made of mineral materials such as pitchstone, amphibole, and pyroxene. One or more types of rocks selected from the rock groups (1) to (3) are prepared, and from this rock, an acidic aqueous solution such as a sulfuric acid aqueous solution, a hydrochloric acid aqueous solution, a nitric acid aqueous solution, etc.
Alternatively, a mineral liquid is extracted using an alkaline aqueous solution such as sodium hydroxide, potassium hydroxide, calcium hydroxide, etc., and this extracted mineral liquid has mineral microcrystals consisting of the crystal structure of the mineral of the rock to be extracted. be.

Next, in the invention of claim 2, a rock made of a substance constituting the upper part of the continent such as granite, rhyolite, quartz diorite, andesite, and one or more rocks selected from these. At the same time, from this rock, a sulfuric acid aqueous solution,
Extraction is performed using an acidic aqueous solution such as a hydrochloric acid aqueous solution or a nitric acid aqueous solution, or an alkaline aqueous solution such as sodium hydroxide, potassium hydroxide, calcium hydroxide, etc., and this extracted mineral liquid is
The mineral microcrystal has a crystal structure of the mineral of the rock to be extracted, and has a bioactive function.

Furthermore, in the invention of claim 3, one or more rocks selected from rocks consisting of substances forming the upper part of the continent, such as granite, rhyolite, quartz diorite, andesite, and (1) peridotite. Rocks made of mantle materials such as rock, serpentine, and garnet; (2) Rocks made of materials that make up the bottom of continents such as basalt and gabbro; (3) Rocks made of materials such as obsidian, pitchstone, amphibole, and pyroxene. A rock made of mineral substances, and one or more rocks selected from these, is prepared, and from this rock, acidic aqueous solutions such as sulfuric acid aqueous solution, hydrochloric acid aqueous solution, nitric acid aqueous solution, or sodium hydroxide, water A mineral liquid is extracted using an alkaline aqueous solution of potassium oxide, calcium hydroxide, etc., and the extracted mineral liquid is a mineral microcrystal having a crystal structure of the mineral of the rock to be extracted, and has a bioactive function. This is assumed to have fine crystals.

In the invention of claim 4, the rock to be extracted is one or more rocks selected from the rocks consisting of substances forming the upper part of the continent, such as granite and rhyolite, and mica. The extracted mineral 7 night contains mineral microcrystals with bioactive functions.

In the invention of claim 5, the extracted mineral liquid whose target rock is a rock mixture consisting of peridotite, serpentine, granite, andesite, and basalt has mineral microcrystals having bioactive functions.

In the invention of claim 6, the extracted mineral liquid whose target rock is a rock mixture consisting of granite or andesite, peridotite, quartz syrenite, and basalt has mineral microcrystals having bioactive functions. It is.

In the invention of claim 7, the extracted mineral liquid whose target rock is a rock mixture consisting of granite or rhyolite, obsidian, pitchstone, and amphibole has microcrystals of minerals having bioactive functions. be.

In the invention of claim 8, (1) a mixed rock of rhyolite, zeolite, obsidian, and pyroxene; (2) a mixed rock of rhyolite, zeolite, and quartz diorite; (3) rhyolite, green zeolite, and pitch. It is assumed that the extracted mineral liquid whose extraction target rock is any one of the mixed rocks of stone and has mineral microcrystals having a biochemical function.

In the invention of claim 9, the target rock is a rock made of mantle materials such as peridotite, serpentine, and garnet, and one or more rocks selected from these rocks are extracted, and from this rock, Mineral liquid is extracted using an acidic aqueous solution such as a sulfuric acid aqueous solution, a hydrochloric acid aqueous solution, or a nitric acid aqueous solution, or an alkaline aqueous solution such as sodium hydroxide, potassium hydroxide, calcium hydroxide, etc., and this mineral liquid is used to extract minerals from the rock to be extracted. A mineral microcrystal having a crystal structure having a function of separating a substance X completely dissolved in water from water.

In the invention according to claim 10, one or more types of rocks selected from among rocks consisting of substances constituting the continental bottom such as basalt and gabbro are the rocks to be extracted, and a sulfuric acid aqueous solution and a hydrochloric acid aqueous solution are extracted from this rock. , acidic aqueous solutions such as nitric acid aqueous solutions,
Alternatively, a mineral liquid is extracted using an alkaline aqueous solution such as sodium hydroxide, potassium hydroxide, calcium hydroxide, etc., and the extracted mineral liquid is a mineral microcrystal having the crystal structure of the mineral of the rock to be extracted, (a) It has mineral microcrystals that have the function of dissolving the molten substance in water.

In the invention of claim 11, (1) rocks made of mantle materials such as peridotite, serpentine, and garnet; (2) granite, rhyolite, quartz diorite, andesite, and basalt;
Prepare one or more types of rocks selected from the following: (3) rocks that are materials that make up continents such as gabbro; (3) rocks that are made of minerals such as obsidian, pitchstone, amphibole, and pyroxene; death,
This rock is mixed with an acidic aqueous solution such as a sulfuric acid aqueous solution, a hydrochloric acid aqueous solution, or a nitric acid aqueous solution with a concentration of 1120 to 40%.

(2) Using an alkaline aqueous solution of sodium hydroxide, potassium hydroxide, calcium hydroxide, etc. with a concentration of 20 to 40%, the mineral liquid is extracted by boiling within a temperature range of 80°C to 110°C.

In the invention of claim 12, from rocks made of mantle materials such as peridotite, serpentine, and garnet, and from materials constituting continents such as granite, rhyolite, quartz diorite, andesite, basalt, and gabbro. 20% to 40% of rocks composed of minerals S'K such as obsidian, pitchstone, amphibole, pyroxene, etc.
When boiling using an acidic aqueous solution such as a concentrated sulfuric acid aqueous solution, a hydrochloric acid aqueous solution, or a nitric acid aqueous solution, or an alkaline aqueous solution such as a 20% to 40% concentrated aqueous solution of sodium hydroxide, potassium hydroxide, calcium hydroxide, etc., these acidic aqueous solutions or Mineral liquid is extracted by diluting the alkaline aqueous solution with pure water having an electrical resistance of >MΩ.

In the invention of claim 13, from rocks made of mantle materials such as peridotite, serpentine, and garnet, and from materials constituting continents such as granite, rhyolite, quartz diorite, andesite, basalt, and gabbro. When boiling a rock made of minerals such as obsidian, pitchstone, amphibole, pyroxene, etc. in an acidic aqueous solution with a concentration of 20% to 40% or an alkaline aqueous solution with a concentration of 20% to 40%, the boiling treatment time The mineral liquid is extracted within 30 minutes.

In the invention of claim 14, (1) rocks made of mantle materials such as peridotite, serpentine, and garnet; (2) granite, rhyolite, quartz diorite, andesite, and basalt;
Prepare one or more types of rocks selected from: (3) rocks made of materials that make up continents such as gabbro; (3) rocks made of minerals such as obsidian, pitchstone, amphibole, and pyroxene; death,
This rock is the rock to be extracted, and (2) an acidic aqueous solution such as sulfuric acid aqueous solution, hydrochloric acid aqueous solution, nitric acid aqueous solution with a concentration of 20% to 40% diluted with pure water having an electrical resistance of 111 MΩ or more (2) an electrical resistance of 1 MΩ or more Mix it with an alkaline aqueous solution such as sodium hydroxide, potassium hydroxide, calcium hydroxide, etc. with a concentration of 20% to 40% diluted with pure water with a After the reaction has occurred, pure water at 100° C. is further added to cause the reaction to occur again, thereby extracting the mineral liquid.

In the invention of claim 15, (1) rocks made of mantle materials such as peridotite, serpentine, and garnet; (2) granite, rhyolite, quartz diorite, andesite, and basalt;
Extract one or more types of rocks from the following: (3) rocks made of materials that make up continents such as gabbro; (3) rocks made of minerals such as obsidian, pitchstone, amphibole, and pyroxene; (1) An acidic aqueous solution of 20% to 40% sulfuric acid aqueous solution, hydrochloric acid aqueous solution, nitric acid aqueous solution M'ip diluted with pure water having an electrical resistance of 1 MΩ or more 20% to 40% concentration of sodium hydroxide diluted with pure water with resistance,
After mixing with either an alkaline aqueous solution such as potassium hydroxide or calcium hydroxide and causing a reaction under conditions of maintaining the temperature at 80°C to 110°C for up to 30 minutes, further add an amount equal to the above alkaline or acidic aqueous solution. Pure water at 100° C. and having an electrical resistance of 1 MΩ or more is added to the mixture to promote re-reaction and extract the mineral liquid.

[Function] (1) From rocks made of mantle materials such as peridotite, serpentinite, and garnet, and materials constituting continents such as granite, rhyolite, quartz diorite, andesite, basalt, and gabbro. Rocks composed of minerals such as obsidian, pitchstone, amphibole, pyroxene, etc. have relatively tight structures, so acidic water such as sulfur(2) acid aqueous solution, hydrochloric acid aqueous solution, nitric acid aqueous solution, etc. M? &
, or by extraction using an alkaline aqueous solution of sodium hydroxide, potassium hydroxide, calcium hydroxide, etc., so that the extracted mineral liquid contains fine mineral crystals consisting of the crystal structure of the mineral of the rock to be extracted. , the mineral microcrystals of this extracted mineral liquid can be used to activate catalysts, enzymes, sterilizers, etc. specific to each rock or mineral to be extracted, or to separate substances that are completely dissolved in wood from water, or to remove poorly soluble substances. The function is to melt water into water.

(2) Rocks made of materials that make up the upper part of continents, such as granite, rhyolite, quartz diorite, andesite, have a relatively similar structure. The rock to be extracted is treated with sulfuric acid water ('8 solution, hydrochloric acid aqueous solution,
Extraction is performed using an acidic aqueous solution such as a nitric acid aqueous solution, or an alkaline aqueous solution such as sodium hydroxide, potassium hydroxide, calcium hydroxide, etc., and this extracted mineral liquid is a mineral microcrystal consisting of the crystal structure of the mineral of the target rock. By containing , the mineral microcrystals of this extracted mineral liquid function to activate living organisms.

(3) One or more types of rocks selected from among the rocks that constitute the upper part of continents such as granite, rhyolite, quartz diorite, andesite, and peridotite, serpentine, garnet, etc. A type or type selected from rocks made of mantle materials, rocks made of materials constituting the continental bottom such as basalt and gabbro, and rocks made of minerals such as obsidian, pitchstone, amphibole, and pyroxene. Two or more types of rocks are the target rocks for extraction, and the target rocks are extracted using an acidic aqueous solution such as a sulfuric acid aqueous solution, a hydrochloric acid aqueous solution, or a nitric acid aqueous solution, or an alkaline aqueous solution such as sodium hydroxide, potassium hydroxide, calcium hydroxide, etc. By extracting and making this extracted mineral liquid contain mineral microcrystals made of the crystal structure of the minerals of the target rock, the mineral microcrystals of this extracted mineral liquid function to activate living organisms. .

(4) A rock mixture consisting of mica and one or more types of rocks selected from rocks consisting of materials that constitute the upper part of the continent, such as granite and rhyolite, is used as the target rock for extraction, and this is extracted with an acidic aqueous solution or By extracting with an alkaline aqueous solution and making it contain mineral microcrystals consisting of the crystal structure of the minerals of the rocks to be extracted, the mineral microcrystals of this extracted mineral liquid function to activate living organisms.

(5) A rock mixture consisting of peridotite, serpentine, granite, andesite, and basalt is used as the target rock for extraction, and this is extracted with an acidic aqueous solution or an alkaline aqueous solution to extract the crystal structure of the minerals of these target rocks. By containing mineral microcrystals, the mineral microcrystals in this extracted mineral liquid function to activate living organisms.

A rock mixture consisting of granite or andesite, peridotite, quartz diorite, and basalt is the target rock for extraction, and this is extracted with an acidic or alkaline aqueous solution to extract minerals that have the crystal structure of the minerals of these target rocks. By containing microcrystals, the microcrystals of this extracted mineral liquid function to activate living organisms.

(7) The target rock for extraction is a rock mixture consisting of granite or rhyolite, obsidian, pitchstone, and amphibole, and the ore consists of the crystal structure of the minerals of these target rocks. (6) Contains fine crystals. By doing this, the mineral microcrystals contained in this extracted mineral liquid function to activate living organisms.

Extract any one of the mixed rocks of rhyolite, zeolite, obsidian, and pyroxene, or the mixed rocks of rhyolite, zeolite, and quartz diorite, or the mixed rocks of rhyolite, green zeolite, and pitchstone. By making the target rocks contain mineral microcrystals having the crystal structure of the minerals of these extraction target rocks, the mineral microcrystals of this extracted mineral liquid function to activate living organisms.

(9) One or more types of rocks selected from rocks made of mantle materials such as peridotite, serpentine, and garnet are to be extracted, and these are extracted using an aqueous solution of sulfuric acid, aqueous hydrochloric acid (8), nitric acid. Extraction using an acidic aqueous solution such as an aqueous solution, or an alkaline aqueous solution such as sodium hydroxide, potassium hydroxide, calcium hydroxide, etc., so that it contains mineral microcrystals consisting of the crystal structure of the minerals of the rocks to be extracted. Therefore, the mineral microcrystals of this extracted mineral liquid function to separate substances completely dissolved in the water from the water.

(10) One or more types of rocks selected from rocks consisting of substances that make up the continental bottom such as basalt and gabbro are the target rocks for extraction, and the target rocks are mixed with an aqueous solution of sulfuric acid, an aqueous solution of hydrochloric acid, The extracted mineral solution is extracted using an acidic aqueous solution such as a nitric acid aqueous solution or an alkaline aqueous solution such as sodium hydroxide, potassium hydroxide, calcium hydroxide, etc. By containing such minerals, the mineral microcrystals of this extracted mineral liquid function to dissolve substances that are hardly soluble in water.

(11) Rocks made of mantle materials such as peridotite, serpentine, and garnet, and rocks made of continental materials such as granite, rhyolite, quartz diorite, andesite, basalt, and gabbro; and rocks consisting of minerals such as obsidian, pitchstone, amphibole, pyroxene, etc., are the target rocks for extraction.
% concentration sulfuric acid aqueous solution, hydrochloric acid aqueous solution, nitric acid aqueous fJ solution, or 20 to 40% concentration sodium hydroxide,
By using an alkaline aqueous solution of potassium hydroxide, calcium hydroxide, etc. and at an extraction temperature of 80°C to 110°C, the extracted mineral liquid contains fine mineral crystals consisting of the crystal structure of the minerals such as the target rock. is brought about.

(12) During this extraction, use an acidic aqueous solution such as sulfuric acid aqueous solution, hydrochloric acid aqueous solution, or nitric acid aqueous solution diluted with pure water having an electrical resistance of 1 MΩ or more, or sodium hydroxide diluted with pure water having an electrical resistance of 1 MΩ or more. By using alkaline aqueous solutions such as potassium hydroxide, calcium hydroxide, etc., the mineral microcrystals contained in the extracted mineral liquid will not react with impurities contained in the dilution water during this extraction process, and will be more It is considered to be a stable mineral microcrystal.

(13) Furthermore, during the above-mentioned extraction, recrystallization of the extracted mineral microcrystals with each other during extraction can be avoided by limiting the extractor boiling treatment time to 30 minutes or less.

(14) Next, after the above extraction process, 100°C pure water is added to this extracted mineral liquid to promote re-reaction, so that the mineral microcrystals contained in the extracted mineral liquid after extraction are Recrystallization is eliminated.

(15) In addition, in the post-treatment of the re-reaction for this extraction treatment liquid, the pure water used should have an electrical resistance of 1 MΩ or more, and the acidic aqueous solution used for extraction,
Alternatively, by making the amount equal to that of the alkaline aqueous solution, recrystallization of mineral fine crystals contained in the extracted mineral liquid in the extracted liquid is eliminated.

[Example] The present invention will be explained in detail below.

First, the rocks used in the second measurement are (1) rocks made of mantle materials such as peridotite, serpentinite, and garnet, and (2) rocks from the upper part of the continent such as granite, rhyolite, andesite, and quartz diorite. (3) Rocks made of materials that make up the bottom of continents, such as basalt and gabbro; (4) Minerals that make up continents, such as obsidian, pitchstone, amphibole, and pyroxene. The target rock is a rock consisting of the following properties, and one or more types of rocks selected from these target rocks are used.

These target rocks are rock groups that have not been significantly weathered, and we excluded corroded rocks such as morillonite and vermiculite, as well as soils in which these corroded rocks have been further weathered.

In particular, in the Examples, peridotite, which is available at low cost, and serpentinite, which is a weathered version of peridotite, and garnet were used as the rocks consisting of upper mantle materials.

In addition, basalt and gabbro, which are rocks made of continental floor materials, were mostly found in national parks or quasi-national parks, so we used foreign ones.

Furthermore, granite, rhyolite, andesite, quartz diorite, as well as obsidian, pitchstone, amphibole, pyroxene, and zeolite, a special metamorphic rock, were used as rocks consisting of continental floor materials.

In addition to these rocks, there are many other rocks that can be used, but due to acquisition costs and other reasons,
The above-mentioned rock groups were mainly used as target rocks in this example.

The target rock used in this process is either a body of rock having its own characteristics, or a composite of two or more rocks in a blending ratio tailored to the characteristics of each, depending on the purpose of the extracted mineral liquid. In both cases, it is best to use rocks that are in a fresh state and maintain the solid crystalline structure unique to the rock's minerals.

The particle size of the crushed rock is 100 μm or more by crushing the rock.
Try to align them within 0.5 μm. The finer the crushed powder of the rock used, the more minerals can be extracted during the following extraction process. However, in this example, the crushed rock powder was used in such a way that the particle size was adjusted to the above-mentioned particle size.

Next, as the acidic aqueous solution used for extraction, typical sulfuric acid water m fl , hydrochloric acid aqueous solution, and nitric acid aqueous solution were used.

Further, as the alkaline aqueous solution, typical sodium hydroxide, potassium hydroxide, and calcium hydroxide were used.

The aqueous solution used here was diluted with pure water having an electrical resistance of 1 MΩ or more, and both the acidic aqueous solution and the alkaline wood fJ solution had a diluted concentration of 20 to 40%.
It is preferable that

If the extraction liquid used in the saw is an acidic or alkaline aqueous solution with a concentration of 20% or less, it is difficult to effectively extract minerals from the target rock, and the extraction liquid tends to be difficult due to the unique effects of the target rock. It shows
It is preferable to use an acidic aqueous solution or an alkaline aqueous solution with a concentration of 20% or more. In addition, when minerals are extracted from the rock using acidic water (IJ?M) or alkaline aqueous solution of 40% or more, it is difficult to maintain the properties of the minerals in the extracted liquid stably, and moreover, sulfate ions and chloride ions It tends to increase significantly, so it is preferable to use an acidic aqueous solution or an alkaline aqueous solution with a concentration of 40% or less.

In addition, the pure water used in this process preferably has an electrical resistance of 1 MΩ or more, and by using such pure water, the impurities contained in the dilution water are removed from the minerals contained in the extracted mineral liquid. Since reaction with fine crystals is avoided, a mineral extract containing stable mineral fine crystals can be obtained.

Next, the crushed rock is mixed with the acidic aqueous solution or alkaline aqueous solution prepared above, and the reaction temperature is maintained at 80°C to 110°C by external heating and reaction heat for up to 30 minutes. , allowing the reaction to continue in the reactor. The valence of the mineral extract is controlled within this temperature range. Although it is possible to extract the minerals of the target rock even if the reaction temperature is 80°C or lower, it is difficult for the mineral microcrystals contained in the extracted mineral liquid to have the unique crystal structure of the minerals of the target rock. The trend is shown, and the reaction temperature is 110
℃ or higher and the reaction time is 30 minutes or more, the mineral microcrystals contained in the extracted mineral liquid tend to react with each other again and recrystallize.

Next, prepare pure water at 100 °C with an electrical resistance of 1 MΩ or more, match this pure water to the reaction temperature, add it to the reaction tank after treatment in equal amounts, and continue the reaction for 30 minutes. and extract the mineral liquid.

By this re-reaction treatment using pure water, the valence of the mineral fine crystals in the extracted mineral liquid is controlled and maintained stably, making it difficult for recrystallization to occur.For example, this re-reaction treatment Regarding this, the iron contained in the extracted mineral liquid is said to be in a stable divalent state.

Furthermore, by adding pure water at room temperature having an electrical resistance of 1 MΩ or more to the extracted mineral liquid, continuing stirring for 60 minutes or more, and then maintaining it in a stationary state for 12 hours or more,
An extracted mineral liquid with mineral microcrystals in a more stable state was obtained.

By stabilizing the mineral microcrystals contained in this extracted mineral liquid, the mineral microcrystals contained in the extracted mineral liquid maintain their structure in the same state and recrystallize. Never.

In an embodiment corresponding to the invention of claim 2, the extraction target rock is one or two selected from rocks consisting of materials constituting the upper part of the continent, such as granite, rhyolite, quartz diorite, andesite, etc. By using a rock of more than a species, the mineral liquid extracted by the method of the above embodiment contains mineral microcrystals having bioactive functions.

Next, as an embodiment corresponding to the invention of claim 3, the above-mentioned rock to be extracted is one type or two or more rocks selected from rocks consisting of materials constituting the upper part of the continent, such as granite, rhyolite, andesite. Rocks, rocks made of mantle materials such as peridotite, serpentine, and garnet; rocks made of materials that make up the continental floor such as basalt and gabbro; minerals such as obsidian, pitchstone, amphibole, and pyroxene. By using one or more types of rocks selected from the following, the mineral liquid extracted by the method of the embodiment described above contains microcrystals of minerals having bioactive functions.

Furthermore, as an embodiment corresponding to the invention of claim 4, the extraction target rock is one or more kinds of rocks selected from rocks made of substances forming the upper part of the continent, such as granite and rhyolite. By forming a rock mixture consisting of and : mother, the mineral liquid extracted by the method of the above example,
It is said to contain mineral microcrystals that have bioactive functions.

Next, as an embodiment corresponding to the invention of claim 5, the extraction target rock is a mixture of rocks consisting of peridotite, serpentine, granite, andesite, and basalt, and the extraction is performed by the method of the embodiment. The mineral liquid to be prepared contains mineral microcrystals having bioactive functions.

Next, as an embodiment corresponding to the invention of claim 6, the extraction target rock is a rock mixture consisting of granite or andesite, peridotite, quartz diorite, and basalt. The mineral liquid extracted by this method contains microcrystals of minerals having bioactive functions.

Furthermore, as an embodiment corresponding to the invention of claim 7, the extraction target rock is a rock mixture consisting of granite or rhyolite, obsidian, pitchstone, and amphibole. The mineral liquid extracted by this method contains microcrystals of minerals having bioactive functions.

Further, as an embodiment corresponding to the invention of claim 8, the extraction target rock is a mixed rock of rhyolite, zeolite, obsidian, and pyroxene, or a mixed rock of rhyolite, zeolite, and quartz diorite, or a mixed rock of rhyolite, zeolite, and quartz diorite. Any one mixed rock selected from the mixed rocks of granite, green zeolite, and pitchstone,
By extracting a mineral liquid from this mixed rock using the method described in the above embodiment, the extracted mineral liquid contains microcrystals of minerals having bioactive functions.

Furthermore, as an embodiment corresponding to the invention of claim 9, the rock to be extracted is one or more rocks selected from rocks made of mantle materials such as peridotite, serpentine, and garnet. , by extracting a mineral liquid from this rock by the method of the above embodiment, the extracted mineral liquid contains fine mineral crystals that have the function of separating substances completely dissolved in water from water. It is said that

Next, as an embodiment corresponding to the invention of claim 10, the above-mentioned extraction target rock is one or more kinds selected from rocks consisting of substances constituting the bottom of continents such as basalt and gabbro. By extracting a mineral liquid from this rock using the method described in the above embodiment, the extracted mineral liquid contains fine mineral crystals that have the function of dissolving poorly soluble substances in water.

Example 1 Peridotite, which is an unoxidized rock of the upper mantle, serpentinite, which is a weathered version of peridotite, and garnet are prepared separately. After pulverizing each powder to a certain extent, each crushed rock powder is mixed with an equal amount of a sulfuric acid aqueous solution and a hydrochloric acid aqueous solution, or a double amount of a sulfuric acid aqueous solution and a hydrochloric acid aqueous solution, and boiled for 30 minutes while maintaining a temperature of 80°C to 110°C. Furthermore, an equal amount of pure water at 100° C. with an electrical resistance of 1 MΩ or more was added to cause a re-reaction to extract the mineral liquid, and at the same time, pure water at room temperature with an electrical resistance of 1 MΩ or more was added. After continuing stirring for 1 minute,
The mineral solution was obtained by maintaining the stationary state for 5 hours.

In the extraction of this mineral liquid, a 15-40% concentration sulfuric acid aqueous solution and a hydrochloric acid aqueous solution diluted with pure water having an electrical resistance of 1 MΩ or more were used.

The properties of the mineral liquid obtained by this process were as follows.

2-1-1 50 parts by weight of peridotite / 100 parts by weight of sulfuric acid wood solution - 2-1 parts by weight of serpentine 50 parts by weight / 100 parts by weight of sulfuric acid aqueous solution 1-2-2 Serpentine] 00 parts by weight / sulfuric acid aqueous solution 100 1-]-2 peridotite 100 stacked part/sulfuric acid water fa liquid 10
0 parts by weight - 1 50 parts by weight of pyroxene / 100 parts by weight of sulfuric acid solution 100 parts by weight 1-3-2 parts by weight of pyroxene ioo / 1.00 parts by weight of sulfuric acid solution - 2-1 parts by weight of serpentine 50 parts by weight / 100 parts by weight of hydrochloric acid aqueous solution 2-1-1 50 parts by weight of peridotite / aqueous hydrochloric acid solution + 00 parts by weight 2-2-2 100 parts by weight of serpentine / 100 parts by weight of aqueous hydrochloric acid -1-2 100 parts by weight of peridotite / aqueous hydrochloric acid solution 2-3- 1 50 parts by weight of garnet / 100 parts by weight of aqueous hydrochloric acid solution 2-3-2 100 parts by weight of garnet / 100 parts by weight of aqueous hydrochloric acid solution As far as the electrical conductivity of each of the above extracted mineral solutions is concerned, the target rock to be extracted is better than serpentinite. Peridotite is better than peridotite, and garnet is better than peridotite, and the more beads of acidic aqueous solution used for extraction, the better the conductivity. The rate is showing a tendency to improve.

As is clear from this example, extraction using an aqueous sulfuric acid solution or an aqueous hydrochloric acid solution with a concentration lower than 20% resulted in a small amount of mineral extraction and was unsuitable for practical use. Furthermore, when the minerals were extracted by increasing the concentration of the sulfuric acid aqueous solution and hydrochloric acid aqueous solution used for extraction above 40%, sulfate ions and chloride ions were extremely increased in the extracted mineral solution, making it unsuitable for practical use. .

Next, the above-mentioned extracted mineral liquid was blended with tap water, and its coagulation and precipitation effect was confirmed.

When peridotite was coagulated and precipitated using a mineral solution extracted with sulfuric acid water (8 liquids), the organic matter in tap water started to dissolve in 25 seconds after mixing and stirring in tap water. In the case of aggregation using minerals extracted in an aqueous solution, the aggregation of the minerals in the tap water was started after 30 seconds of fMI release after mixing and stirring in the tap water.In both cases,
After adjusting Pl+ to 11-12 with lime etc., add Pl+ to the acidic side.
It was observed that separation of species started at P) 110 to 11, in which the H value was shifted by 1 to 2.

The mineral liquid obtained by extracting serpentinite using the above method as the target rock exhibits the same behavior as the above-mentioned peridotite, and in particular exhibits the characteristics that the separation rate of organic matter is extremely fast at 5 to 7 seconds. Separation of organic substances started when the pH was in the range of 10 to 11.

The mineral liquid obtained by extracting garnet as the target rock by the above method exhibits the same behavior as peridotite.
Separation of organic matter started at the H7 position.

In the above examples, clear tap water is used, and the mineral liquid in each of the above examples has the function of separating organic substances completely dissolved in this transparent drinking tap water from the water. It was recognized that the company had From these wastes, it is inferred that the mineral liquids obtained in each of the above examples have the function of destroying the structured water surrounding dissolved organic matter.

In addition, for mineral liquids obtained from any of the target rocks, the flocculation and precipitation effects of mineral liquids using an aqueous sulfuric acid solution for extraction tended to be superior to those using an aqueous hydrochloric acid solution. Ta.

Next, as a typical example of application of the mineral extract obtained above, it was applied to papermaking wastewater, which is a typical example of industrial wastewater.

Use paper manufacturing wastewater that has a strange odor and dilute it twice with tap water. 1. ooocc was taken as beer and adjusted with lime so that the pH value was 12.

When 10 ccti of serpentinite extract was added to this and stirring was continued for 10 seconds, the organic matter in the sample wastewater was rapidly separated, coagulated and precipitated, and the strange odor disappeared.

pH until the end of the reaction due to the addition of this serpentinite extract
After confirming the above reaction, the value was approximately 1O, leaning toward strong alkalinity, and then 15 cc of garnet extract was added and the reaction was caused at a pH value of approximately 7, resulting in the above reaction. It was observed that similar aggregation and precipitation occurred.

In this way, in coagulation and precipitation using garnet extract, P
Since it reacts when the H value is around 7 and produces excellent coagulation and precipitation effects, the coagulation and precipitation treated water could be discharged into rivers etc. by simply filtering it with an appropriate filter material.

By adjusting the purchase of this filter material, etc., it was possible to bring the BOD, COD, and other values of the wastewater within environmental standards.

Furthermore, when it was used to purify lakes, rivers, and groundwater, tap water and treated water were obtained, and trihalomethane and trichloroethane in groundwater were separated.

Comparative Example 1 A mineral liquid was extracted under the same conditions as in Example 1 except that the extraction temperature with the sulfuric acid aqueous solution and the hydrochloric acid aqueous solution was 75°C.

It was revealed that the extracted mineral liquid obtained in this way contained an extremely small amount of minerals, and moreover, it took more than 10 minutes for the agglomeration and precipitation effects peculiar to the target rock to be extracted.

Comparative Example 2 A mineral liquid was extracted under the same conditions as in Example 1 except that the extraction temperature with an aqueous sulfuric acid solution and an aqueous hydrochloric acid solution was 115° C. under pressurized conditions.

Although the extracted mineral liquid obtained by this process contains a large amount of minerals, the extracted minerals are not stabilized and recrystallize over time, and it takes more than 5 minutes to react to the unique agglomeration and precipitation effects of the target rock. It took.

Comparative Example 3 Boiling treatment with sulfuric acid aqueous solution and hydrochloric acid aqueous solution at 110 ° C.
Myoral extraction was carried out for 7 nights under the same conditions as in Example 1 except that i4 was continued for 0 minutes.

The extracted mineral liquid obtained in this case showed the same behavior as in Example 2 in the above ratio (2), and did not exhibit the agglomeration and precipitation effects peculiar to the rock to be extracted.

Comparative Example 4 The dilution water for the sulfuric acid aqueous solution and the hydrochloric acid aqueous solution used in the extraction process was normal tap water, and the 100°C water added after the boiling process for re-reaction and the stabilizing water at room temperature that was added after the boiling process were normal tap water. Mineral liquid was extracted under the same conditions as in Example 1 except that tap water was used.

It has been revealed that the extracted mineral liquid obtained by this method does not cause the agglomeration and precipitation effects that are characteristic of the rocks to be extracted, as the organic matter contained in tap water and the extracted minerals react with each other. Ta.

Comparative Example 5 100°C after boiling treatment with sulfuric acid aqueous solution and hydrochloric acid aqueous solution
The conditions for extraction without adding pure water were the same as in Example 1 above.
Mineral liquid was extracted under the same conditions.

The extracted mineral liquid obtained by sawing turns brown after extraction, and the iron content contained in the extracted mineral liquid is found to be oxidized.It is in an unstable state where it is likely to cause a re-reaction. It was unsuitable for practical use because it did not produce crystals and did not cause the agglomeration and precipitation effects characteristic of the rocks to be extracted.

Comparative Example 6 After boiling treatment with sulfuric acid aqueous solution and hydrochloric acid aqueous solution, equal amount of 1
The mineral liquid was extracted under the same conditions as in Example 1 except that pure water at 00°C was added to cause a re-reaction to extract the mineral liquid, and the mixture was left in that state.

The mineral liquid obtained by this S was unsuitable for practical use because the minerals reacted with each other over time and recrystallized, and did not exhibit the agglomeration and precipitation effects characteristic of the rocks to be extracted. .

Comparative Example: The concentration of the sulfuric acid aqueous solution and hydrochloric acid aqueous solution used for extraction was 50%.
The mineral liquid was extracted under the same conditions as in Example 1 except that the temperature of the boiling treatment was 115°C.

Although the mineral liquid obtained by this process contains a large amount of extracted mineral components, it recrystallizes over time, and the extracted mineral liquid contains a large amount of free sulfuric acid and free hydrochloric acid, which is characteristic of the rock to be extracted. It was unsuitable for practical use because it did not cause any agglomeration or precipitation effects.

Example 2 Minerals were extracted under the same conditions as in Example 1 except that the rocks to be extracted were basalt and gabbro, a 35% aqueous sulfuric acid solution was used, and the reaction was conducted at 80 to 110°C for 30 minutes. I got the liquid.

Before using the extract obtained in this step, add 1,000 ml of tap water.
The serpentinite extract is mixed with the cc and stirred to separate and coagulate the organic matter contained in the tap water, and in the separated and coagulated state of the organic matter, the basalt extraction (r!1lOcc) is carried out.
When the water was added and stirred, the organic matter that had been separated and aggregated within υ for approximately 3 seconds was completely dissolved in the tap water, resulting in clear water.

When 10 cc of the above-mentioned gabbro extract was added and stirred under the same conditions, it exhibited exactly the same behavior as the above-mentioned basalt extract.

Furthermore, 1000cc of papermaking wastewater diluted twice with tap water
The above sample was adjusted to pH 12, 10 cc of serpentinite extract was added to it, and 15 cc of pyroxene extract was added at the start of aggregation to further promote aggregation. 10 cc of the basalt extract was added to the treated water. The organic matter that had been in an aggregated state began to dissolve into water, and the aggregates were no longer found.

Instead of this basalt extract, use 10cc of gabbro extract.
It was observed that the same behavior as when the basalt extract was added was observed.

Furthermore, when the above-mentioned extract was used to prepare a lotion by dissolving shark liver oil (squalene) in water, it was possible to obtain a lotion that was familiar to the skin.

Example 3 Example 2 except that the extraction target rocks were rocks constituting the upper part of the continent, such as granite, rhyolite, quartz diorite, andesite, etc.
A mineral extract was obtained under the same conditions.

The extract obtained here was similar to the extracts obtained in Example 1 and Example 2, and no satisfactory results were obtained for water treatment.

However, the extract obtained in this example was
Dilute to 0.25 ppm and spray on potted tricolor violets.
When compared with an unsprayed tricolor violet, 3 to 4 days after spraying, the green color of the pollen became darker and the color of the flowers became clearer.When this spraying was continued, the flowering period was longer than that of an unsprayed tricolor violet. It's been a long time. In addition, in the spraying experiment of this extract, all of the granite extract, rhyolite extract, and andesite extract showed the same effect.

Next, 05~ in a small aquarium! Goldfish were reared by adding pp+a of the extracted mineral solution. The aquarium used in this project was small compared to the number of fish being raised, and was made to have a mild oxygen deficiency without aeration, so that the weaker fish would die within 1 to 2 days. Goldfish were reared in an aquarium to which the extracted mineral solution was administered and an aquarium to which it was not administered.

In this breeding experiment, in the aquarium to which the extracted mineral solution was not administered, the amount of food consumed was low, and the number of fi4W fish died within two days, and the fish bodies were noticeably dirty. On the other hand, the goldfish in the aquarium to which the extracted mineral solution was administered ate a large amount of food, had shiny fish bodies, and none of the goldfish died. It is recognized that the growth effect associated with the administration of this extracted mineral liquid worsens in the order of the above-mentioned granite extract, rhyolite extract, and andesite extract in the tank in which it is administered. It has become clear that the use of this method yields favorable results.

Furthermore, the above-mentioned extraction 7r! i was used to maintain the freshness of cut flowers.

In this example experiment, we used 0.25pp of cut flowers of wilted chrysanthemums.
The sample was soaked in water diluted with the above extract solution of No. m and left to stand. The chrysanthemums soaked in the water diluted with this extract lost their wilting state within 2 to 3 hours, and the leaves and stems became active.After 24 hours, it was observed that the flower pieces gradually fell off.

Therefore, the above-mentioned granite, rhyolite, and andesite were used as the rocks to be extracted, and the mineral solution was was prepared for extraction, and this alkaline extracted mineral solution was used in combination with the above-mentioned acidic extracted mineral solution.

In this example, these extracted mineral liquids were all
．． Prepared at a concentration of 25pp Otori, one in which withered chrysanthemums were arranged individually in the extracted mineral solution prepared for each, and one in which the withered chrysanthemums were arranged in an acidic extracted mineral solution after soaking in an alkaline extracted mineral solution for 10 minutes. A comparison was made between chrysanthemums prepared by immersing them in an acidic mineral extraction solution for 10 minutes, and then arranging them withered in an alkaline mineral extraction solution.

In this experiment, flower pieces of chrysanthemums individually placed in acidic and alkaline mineral extracts began to fall from the next day, and the effect of extending flower life was weak.

In addition, cut flowers that have been soaked in an alkaline extracted mineral solution and then in an acidic extracted mineral solution maintain their freshness for more than a week without a single flower piece falling off after being put into flower. Cut flowers that were soaked in an acidic mineral extract solution and then in an alkaline extracted mineral solution did not have any pore pieces falling for 6 days, and the cut flowers stopped falling at the 78th day.

In order to maintain the freshness of cut flowers, it is preferable to alternately soak them in both an acidic extracted mineral solution and an alkaline extracted mineral solution.

From the above examples, it has become clear that the extracted mineral liquid has a significant relationship with the growth of animals and plants, and has a remarkable effect on the activation of animals and plants.

In general, Japanese agriculture has undergone a drastic change in cultivation methods from crop rotation to continuous cropping, resulting in a significant deterioration of the soil environment.
The country is in an environment where soil diseases are likely to occur, and this has led to the spread of agricultural methods using pesticides.

One reason for this tendency is that with continuous cropping, certain minerals contained in the soil rapidly become deficient, and the balance of minerals contained in the soil is lost. In particular, it has been brought about by the proliferation of only microorganisms that can adapt to such mineral imbalance conditions.

There is a growing demand from various quarters to improve the soil environment by administering the extracted mineral liquid to the soil and restoring the mineral balance to the previous state.

From this point of view, we conducted experiments on growing vegetables using typical mineral extracts from various rocks, with the premise of soil improvement.

The following extracted mineral solution was used in this growth experiment.

(1) One or two types of rocks such as granite and rhyolite, and 20
A mineral liquid extracted from the target rock under the same conditions as in Example 1 except that the target rock was extracted with a sulfuric acid aqueous solution or a hydrochloric acid aqueous solution.
・Liquid A.

(2) A mixed rock of peridotite and serpentinite in equal weight ratios, a mixed rock of granite and andesite in equal weight ratios, and basalt are mixed in a volume ratio of each month. Mineral liquid B liquid, which was extracted under the same conditions as in Example 1 except that the rock to be extracted was extracted with an aqueous sulfuric acid solution or an aqueous hydrochloric acid solution.

(3) Conditions other than extracting a mixed rock containing either granite or andesite and peridotite, quartz diorite, or basalt in a volume ratio of each month with an aqueous sulfuric acid solution or an aqueous hydrochloric acid solution. Mineral liquid extracted under the same conditions as in Example 1 above...Liquid C.

(4) A mixed rock containing an equal volume ratio of either granite or rhyolite and any one of obsidian, pitchstone, or amphibole is mixed with an aqueous sulfuric acid solution. Or a mineral liquid extracted under the same conditions as in Example 1 except for extraction with an aqueous hydrochloric acid solution...Liquid B.

Example 4 When cultivating eggplant in a greenhouse, first, eggplant seedlings were soaked in 10% of solution C.
In addition to soaking in the 00 times diluted solution, 100 times of solution A is added to the cultivation soil.
Sprinkle 0x diluted 1R solution until the soil is moistened to about 5 cm and plant, then spray 1000x solution of solution C on the leaves every two weeks, and use regular river water. We attempted to cultivate eggplants in greenhouses by separating the area from the area where only shrubs were planted.

The soil used for this planting was the soil used for cultivation in conventional greenhouses, and greenhouse cultivation was carried out in the conventional manner by administering chemical fertilizers and organic fertilizers under the same conditions.

Chart of conventional greenhouse cultivation: The average yield per greenhouse is 4 to 5 tons, and the skin is a little hard.
Eggplants are grown in greenhouses by separating the planted parts that have been soaked in salt for 2 hours and the planted parts that are only irrigated with river water. I tried.

The soil used for this planting was the soil used for cultivation in conventional greenhouses, and greenhouse cultivation was carried out in the conventional manner by administering chemical fertilizers and organic fertilizers under the same conditions.

Conventional greenhouse cultivation diagram: The average yield per greenhouse is 4 to 5 tons, the skin is quite hard,
The flavor was poor, the freshness could only be maintained for about 4 days, and the effect of salting for 2 hours was small.

Chart of greenhouse cultivation using mineral solution: The average yield per greenhouse was 10 tons, the skin was soft, the flavor was good, the freshness lasted for more than 7 days, and after 2 hours of salting, it had a salty taste to the core.

Example 5 Holen cars were cultivated in greenhouses with areas to which the extracted mineral liquid was applied and areas to which it was not applied.

Conventional greenhouse soil was used as the planting soil, and conventional chemical fertilizers and organic fertilizers were applied and watering was performed.

In areas where the extracted mineral solution was not applied, Sanhiem was used to disinfect the soil to prevent the occurrence of standing hemorrhoids and eta disease.
Seeds were sown after being soaked in water for 2 hours, and tap water was sprinkled.

To apply the extracted mineral solution, prepare the seeds by soaking them in a 1000-fold dilution of Solution A for 12 hours, sow the seeds in soil that has been sprinkled with a 1000-fold dilution of Solution A, and apply Solution C from the second leaf of the tree. 1
A 1:000 diluted solution was sprayed on the leaves every 5th day.

The spinach in the area where the extracted mineral solution was applied had poor root development, pale leaf color, varying leaf heights, and low yields. In addition, when eaten raw, it tastes bitter, making it difficult to maintain freshness.

The growth of root hairs on the spinach in the area where the extracted mineral solution was applied was extremely good, resulting in dark, dark-colored, thick-walled leaves with a uniform pattern and a marked increase in yield. In addition, when eaten raw, there was no bitterness and the shelf life was longer than 2 days compared to untreated spinach.

Furthermore, continuous cropping was carried out under the same conditions in a plot without application of the above-mentioned extracted mineral liquid and a plot in which it was applied.

In areas where extracted mineral liquid was not applied, the yield decreased with repeated application, and diseases such as standing slime disease occurred, and the summer yield became extremely low.

In the plots where the extracted mineral solution was applied, the yield increased with repeated application, there was no disease onset without the use of pesticides, and there was no reduction in acid dioxide even during cultivation in August when the temperature exceeded 40°C.

When the extracted mineral liquid was used in greenhouse cultivation of cucumbers, the yield of cucumbers increased, and fruits with good color and luster and less curl were obtained. In particular, even during summer cultivation, the yield did not decrease and no occurrence of nematodes was observed.

Example 6 Seedlings of rice seedlings were raised and paddy rice was cultivated in areas where the extracted mineral liquid was applied and areas where it was not applied.

The rice paddies used for seedling raising and rice cultivation are the same as the rice paddies used in the past, and the same management conditions as normal fertilization conditions are applied. cultivated.

In the area where the extracted mineral solution was not applied, the excavated seeds were used in a seedling box, and after the seeds were disinfected and soaked in water, the seeds were sown, and a fungicide was sprinkled on them as needed to raise the seedlings.

The seedlings in this non-applied area had uneven growth, thin appearance, and were weak overall.

The area where the extracted mineral solution is applied uses soil from the site in the seedling box.
Said A? Seeds were soaked in a 1000 times diluted solution for 3 days and sown, and after germination the same solution was periodically sprinkled to raise seedlings.

In the area to which the extracted mineral solution was applied, growth was uniform, the stem diameter was thick, rooting was good, and hairy roots were protruding from the holes at the bottom of the seedling box. Furthermore, no mold was generated even though no mold inhibitor was used and no mountain soil was used.

The seedlings obtained in the non-applied area were transplanted to paddy fields in the usual manner and managed hydroponically.

In rice fields using seedlings from this non-applied area, the number of tillers is small, the lower leaves are yellow-brown, and the yield is poor at 130 to 150 grains per panicle.

Extracted minerals obtained above? A 1000-fold diluted solution of Solution C was applied to the seedlings in the area where & was applied, and the seedlings were left to stand for several days before being planted in a watered paddy field.

In rice fields using seedlings from this application area, the number of tillers was 34 to 3.
There were as many as 5 trees, and the lower leaves were yellowing, even in livestock-like hangings, and the stems were thick and did not lodge.

In addition, the number of fruiting panicles increased significantly, and the yield was 180 to 190 grains per panicle, which was a 25% increase in yield compared to the non-applied plot.

In addition, in Hokkaido, cultivation is carried out using the same method as in the above-mentioned application area, and 100% of the above-mentioned solution is applied just before flowering.
When the 0 diluted solution was sprayed on rice fields, the yield was higher than in conventional rice fields, and rice with good flavor could be obtained.

Further experiments were carried out using the above-mentioned Solutions A to D, and it was found that Solution A eliminated the problem of continuous cropping, had excellent effects on soil sterilization, promotion of germination, promotion of rooting, promotion of fertilization, etc., and was also used as a bath additive. It was also found that it produced excellent effects.

Solution B is effective for root vegetables such as radish, burdock, carrots, potatoes, and sweet potatoes.In particular, by using Solution A to prepare the soil environment and then spraying Solution B, ideal crops could be obtained without pesticides.

Furthermore, Liquid C promotes rooting and activates photosynthesis of paddy rice, wheat, beans, leafy vegetables, and fruits, reducing yields by approximately 2.
It was found that when the amount was increased to 5% or more, an excellent effect of increasing the flavor was produced.

Next, it was found that Solution D is effective against low-temperature damage, and has an excellent effect of activating flowering hormones in floriculture, agricultural products, fruit trees, etc., and increasing the sugar content of fruits.

Example 7 The extracted mineral liquid was used as a drink to confirm its effectiveness.

The rocks to be extracted were (1) a mixed rock in which rhyolite, zeolite, and obsidian or amphibole were locally mixed in volume ratios, (2) rhyolite or pyroxene, zeolite, and quartz diorite. (3) a mixed rock in which rhyolite, green zeolite, and pitchstone are locally mixed in volume ratio; (3) a mixed rock in which rhyolite, green zeolite, and pitchstone are locally mixed in volume ratio; Sulfuric acid water? Minerals were extracted under the same conditions as in Example 1 except that they were extracted with 8 liquids.

The mineral liquid obtained by this process is diluted with water to 1100pp.
When administered continuously to cats, their fur became glossy, their appetite increased, and their characteristic cat odor disappeared.

Furthermore, when we administered mineral diluted water to humans at a concentration of 100 pp+n, which was confirmed to have the same pp-order blood composition as human blood, fecal impaction was excreted on the 3rd or 4th day, and fatigue was significantly reduced. . Furthermore, after continuing the administration for one month, a decrease in blood pressure was observed, and the patient was able to work comfortably.

The extracted mineral liquid used in this example was as described in (1') above.
The materials obtained from any of the rock groups listed in ~ (3) exhibit the behavior of f! It has been recognized that it has a soothing effect, and it has also been found to have excellent effects in relieving pain and prolonging the life of terminal cancer patients.

Although it is not clear why this effect occurs, it is possible that administering an extracted mineral liquid with the same composition as human blood into the body can activate enzymes in the body and have a favorable effect on intestinal bacteria. It seems that there is one underlying cause.

Comparative Example 8 100 parts by weight of vermiculite was mixed with 100 parts by weight of a 25% aqueous sulfuric acid solution, and the mixture was boiled at 100° C. for several hours to obtain a mineral extract.

Add this mineral extract to 200cc of surface water at 0.08
When 0.02 CC2 was added to a test solution mixed with cc of lime water and stirred, the reaction and separation of organic substances was slow, and sufficient aggregation and
No precipitate was observed.

In addition, 50pp of this mineral extract was added to tap water.
When chrysanthemums were roasted overnight at a concentration of m, they withered within a short period of time, and the shelf life could not be extended.

[Effects of the Invention] The extracted mineral liquid according to the present invention has a remarkable bioactive function because it has mineral microcrystals that have a crystal structure similar to that of the minerals of the rocks to be extracted, and has a remarkable bioactive function. This makes it possible to increase yields by activating plants, promoting germination, promoting rooting, and activating hormones, etc., and to harvest excellent grains, root vegetables, fruits, etc.

Similarly, the mineral microcrystals contained in the extracted mineral liquid activate enzymes in the body, restore the balance of minerals in the body, etc., thereby improving the diseased constitution, increasing appetite, lowering blood pressure, lowering blood sugar levels, and preventing fecal impaction. Along with excretion, it enables the body to naturally normalize, such as healing gastric ulcers.

Furthermore, the mineral microcrystals contained in the extracted mineral liquid promote bioactivation of farmed animals, promote fattening, and reduce the incidence of disease, making it possible to obtain high-quality meat or fish meat.

Next, the mineral crystals contained in the extracted mineral liquid reacted with organic matter to cause significant aggregation and precipitation, making it possible to efficiently purify industrial wastewater.

Furthermore, the mineral microcrystals contained in the extracted mineral liquid have the ability to easily dissolve organic substances that do not dissolve in water, making it possible to easily dissolve oily substances in water.

In addition, in the mineral liquid extraction method according to the present invention, the extracted mineral liquid has well-organized mineral microcrystals, and has remarkable biological activity functions, purification functions, water solubilization functions of the H-dissolving device, etc. It was considered possible for this to occur.

Furthermore, the mineral liquid extracted in this way is stable and can maintain the same effect over a long period of time.

Claims (1)

[Scope of Claims] 1. Rocks made of mantle materials such as peridotite, serpentinite, and garnet; materials that constitute continents such as granite, rhyolite, quartz diorite, andesite, basalt, and gabbro; Acid aqueous solutions such as sulfuric acid aqueous solution, hydrochloric acid aqueous solution, nitric acid aqueous solution, or water Sodium oxide, potassium hydroxide,
A mineral liquid extracted using an alkaline aqueous solution of calcium hydroxide or the like, wherein the mineral extract liquid has fine mineral crystals having a crystal structure of the mineral of the rock to be extracted. 2. Acidic solutions such as sulfuric acid aqueous solution, hydrochloric acid aqueous solution, nitric acid aqueous solution, etc. from one or more types of rocks selected from rocks consisting of materials that constitute the upper part of the continent such as granite, rhyolite, quartz diorite, andesite, etc. Aqueous solution, or sodium hydroxide, potassium hydroxide,
A mineral extract extracted using an alkaline aqueous solution such as calcium hydroxide, characterized in that the extract has mineral microcrystals having a crystal structure of the mineral of the rock to be extracted, which has a bioactive function. mineral liquid. 3. One or more types of rocks selected from among the rocks that make up the upper part of the continent, such as granite, rhyolite, quartz diorite, andesite, and mantle such as peridotite, serpentine, and garnet. One or more types selected from the following: rocks made of substances such as basalt and gabbro, which constitute the continental bottom, and rocks made of mineral substances such as obsidian, pitchstone, amphibole, and pyroxene. from rocks, acidic aqueous solutions such as sulfuric acid aqueous solution, hydrochloric acid aqueous solution, nitric acid aqueous solution, or sodium hydroxide, potassium hydroxide,
A mineral extract extracted using an alkaline aqueous solution such as calcium hydroxide, characterized in that the extract has mineral microcrystals having a crystal structure of the mineral of the rock to be extracted, which has a bioactive function. mineral liquid. 4. One or more types of rocks selected from rocks consisting of materials that make up the upper part of the continent, such as granite and rhyolite;
3. The mineral liquid according to claim 2, wherein the mineral liquid is extracted from a rock mixture consisting of mica and mica. 5. The mineral liquid according to claim 3, wherein the rock to be extracted is a rock mixture consisting of peridotite, serpentine, granite, andesite, and basalt. 6. The mineral solution according to claim 3, wherein the rock to be extracted is a rock mixture consisting of granite or andesite, and peridotite, quartz diorite, and basalt. 7. Granite or rhyolite, obsidian or pitch stone,
3. The mineral liquid according to claim 2, wherein the rock to be extracted is a rock mixture consisting of amphibole. 8. A mixed rock of rhyolite, zeolite, obsidian, and pyroxene, or a mixed rock of rhyolite, zeolite, and quartz diorite, or a mixed rock of rhyolite, green zeolite, and pitchstone. The mineral liquid according to claim 3, wherein the mineral liquid is a rock to be extracted. 9. Acidic aqueous solutions such as sulfuric acid aqueous solution, hydrochloric acid aqueous solution, nitric acid aqueous solution, or sodium hydroxide, from one or more types of rocks selected from rocks consisting of mantle materials such as peridotite, serpentine, and garnet; potassium hydroxide,
A mineral extract extracted using an alkaline aqueous solution such as calcium hydroxide, which has the function of separating substances completely dissolved in water from the minerals of the target rock. A mineral liquid characterized by having mineral microcrystals having a crystalline structure. 10. Acidic aqueous solutions such as sulfuric acid aqueous solution, hydrochloric acid aqueous solution, nitric acid aqueous solution, or sodium hydroxide from one or more types of rocks selected from rocks consisting of substances that make up the continental floor such as basalt and gabbro. , potassium hydroxide,
A mineral extract extracted using an alkaline aqueous solution such as calcium hydroxide, which contains mineral fines made of the crystal structure of the mineral of the rock to be extracted, which has the function of dissolving poorly soluble substances in water. A mineral liquid characterized by having crystals. 11. Rocks made of mantle materials such as peridotite, serpentine, and garnet; rocks made of continental materials such as granite, rhyolite, quartz diorite, andesite, basalt, and gabbro; obsidian; Rocks made of minerals such as pitchstone, amphibole, and pyroxene, and one or more rocks selected from the following are mixed with an acidic aqueous solution such as a 20 to 40% concentration sulfuric acid aqueous solution, hydrochloric acid aqueous solution, nitric acid aqueous solution, or A method for extracting a mineral liquid, which comprises boiling an alkaline aqueous solution of sodium hydroxide, potassium hydroxide, calcium hydroxide, etc. at a concentration of 20 to 40% within a temperature range of 80 to 110C. 12. The method for extracting mineral liquid according to claim 11, wherein the acidic aqueous solution or alkaline aqueous solution is diluted with pure water having an electrical resistance of 1 MΩ or more. 13. The method for extracting a mineral liquid according to claim 11, wherein the boiling is performed for less than 30 minutes. 14. Rocks made of mantle materials such as peridotite, serpentine, and garnet; rocks made of continental materials such as granite, rhyolite, quartz diorite, andesite, basalt, and gabbro; obsidian; A 20-40% aqueous sulfuric acid solution prepared by diluting one or more rocks selected from minerals such as pitchstone, amphibole, and pyroxene with pure water having an electrical resistance of 1 MΩ or more. , mixed with an acidic aqueous solution such as a hydrochloric acid aqueous solution or a nitric acid aqueous solution, or an alkaline aqueous solution such as sodium hydroxide, potassium hydroxide, calcium hydroxide, etc. with a concentration of 20 to 40% diluted with pure water having an electrical resistance of 1 MΩ or more. While maintaining the temperature between ℃ and 110℃,
A method for extracting a mineral liquid, which is characterized by reacting for a maximum time of 30 minutes, and then adding pure water at 100°C and reacting again. 15. The pure water used for the re-reaction has an electrical resistance of 1 MΩ or more, and the acidic aqueous solution used for extraction such as sulfuric acid aqueous solution, hydrochloric acid aqueous solution, nitric acid aqueous solution, or sodium hydroxide, potassium hydroxide, calcium hydroxide, etc. 15. The method for extracting mineral liquid according to claim 14, wherein the amount is equal to that of the alkaline aqueous solution.