JPH01210028A - Emulsified composition - Google Patents
Emulsified compositionInfo
- Publication number
- JPH01210028A JPH01210028A JP63033545A JP3354588A JPH01210028A JP H01210028 A JPH01210028 A JP H01210028A JP 63033545 A JP63033545 A JP 63033545A JP 3354588 A JP3354588 A JP 3354588A JP H01210028 A JPH01210028 A JP H01210028A
- Authority
- JP
- Japan
- Prior art keywords
- integer
- formula
- molecular weight
- high molecular
- emulsified composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 31
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 16
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 7
- 239000001257 hydrogen Substances 0.000 claims abstract description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 4
- 125000000217 alkyl group Chemical group 0.000 claims abstract 4
- 150000005846 sugar alcohols Polymers 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims 5
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 239000003921 oil Substances 0.000 abstract description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 9
- 238000002156 mixing Methods 0.000 abstract description 8
- 239000002537 cosmetic Substances 0.000 abstract description 5
- 229940099259 vaseline Drugs 0.000 abstract description 2
- -1 polyoxyethylene Polymers 0.000 description 13
- 235000019198 oils Nutrition 0.000 description 10
- 239000004205 dimethyl polysiloxane Substances 0.000 description 8
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 8
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 8
- 238000009835 boiling Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 5
- 239000003814 drug Substances 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 230000001804 emulsifying effect Effects 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 229920002545 silicone oil Polymers 0.000 description 4
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 235000015110 jellies Nutrition 0.000 description 3
- 239000008274 jelly Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- HOVAGTYPODGVJG-UVSYOFPXSA-N (3s,5r)-2-(hydroxymethyl)-6-methoxyoxane-3,4,5-triol Chemical compound COC1OC(CO)[C@@H](O)C(O)[C@H]1O HOVAGTYPODGVJG-UVSYOFPXSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- HOVAGTYPODGVJG-UHFFFAOYSA-N methyl beta-galactoside Natural products COC1OC(CO)C(O)C(O)C1O HOVAGTYPODGVJG-UHFFFAOYSA-N 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 1
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- 208000002874 Acne Vulgaris Diseases 0.000 description 1
- 241000195940 Bryophyta Species 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- IUMSDRXLFWAGNT-UHFFFAOYSA-N Dodecamethylcyclohexasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 IUMSDRXLFWAGNT-UHFFFAOYSA-N 0.000 description 1
- 239000004386 Erythritol Substances 0.000 description 1
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229920002683 Glycosaminoglycan Polymers 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- MUPFEKGTMRGPLJ-RMMQSMQOSA-N Raffinose Natural products O(C[C@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@@H](O[C@@]2(CO)[C@H](O)[C@@H](O)[C@@H](CO)O2)O1)[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 MUPFEKGTMRGPLJ-RMMQSMQOSA-N 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- 229920002385 Sodium hyaluronate Polymers 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- MUPFEKGTMRGPLJ-UHFFFAOYSA-N UNPD196149 Natural products OC1C(O)C(CO)OC1(CO)OC1C(O)C(O)C(O)C(COC2C(C(O)C(O)C(CO)O2)O)O1 MUPFEKGTMRGPLJ-UHFFFAOYSA-N 0.000 description 1
- YFCGDEUVHLPRCZ-UHFFFAOYSA-N [dimethyl(trimethylsilyloxy)silyl]oxy-dimethyl-trimethylsilyloxysilane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C YFCGDEUVHLPRCZ-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 206010000496 acne Diseases 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 229940082483 carnauba wax Drugs 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000003937 drug carrier Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- NFVSFLUJRHRSJG-UHFFFAOYSA-N hexadecamethylheptasiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C NFVSFLUJRHRSJG-UHFFFAOYSA-N 0.000 description 1
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000011929 mousse Nutrition 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000004447 silicone coating Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229940010747 sodium hyaluronate Drugs 0.000 description 1
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 238000001356 surgical procedure Methods 0.000 description 1
- GSANOGQCVHBHIF-UHFFFAOYSA-N tetradecamethylcycloheptasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 GSANOGQCVHBHIF-UHFFFAOYSA-N 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Colloid Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、高分子量シリコーンをポリオキシアルキレン
変性オルガノポリシロキサンを用いて効率よく安定に乳
化し、且つ得られた乳化組成物の撥水性、肌への密着感
、毛髪へのなめらかき賦与等の使用性が良好で、化粧料
又は医薬品基剤として有用な乳化組成物に関する。Detailed Description of the Invention [Industrial Field of Application] The present invention is directed to efficiently and stably emulsifying a high molecular weight silicone using a polyoxyalkylene-modified organopolysiloxane, and improving the water repellency of the resulting emulsified composition. The present invention relates to an emulsified composition that has good usability such as adhesion to the skin and smoothness to the hair, and is useful as a base for cosmetics or pharmaceuticals.
［従来の技術］
従来、化粧料等で高い撥水性や優れた使用性等が求めら
れる場合の油相構成としては、シリコーンオイルや流動
パラフィンの様な液状油分や、ワセリンの様な常温でペ
ースト状の油分が用いられてきたが、これらは水洗−に
よって容易に洗い流されてしまったり、或はべたつく等
の欠点を有していた。一方、本発明に用いる様な高分子
量シリコーンは、その形成する被膜から曇れた撥水性や
使用性や光沢が期待されるが、これまで安定な乳化組成
物を得ることが困難だった。[Conventional technology] Conventionally, when high water repellency and excellent usability are required for cosmetics, etc., the oil phase composition has been composed of liquid oils such as silicone oil and liquid paraffin, and pastes at room temperature such as vaseline. However, these oils have disadvantages such as being easily washed away by washing with water or being sticky. On the other hand, high molecular weight silicones such as those used in the present invention are expected to have cloudy water repellency, ease of use, and gloss from the films they form, but until now it has been difficult to obtain stable emulsified compositions.
［発明が解決しようとする課題］
本発明者らは、高分子シリコーン被膜の性質である撥水
性やなめらかな感触を与え且つ乳化組成物として良好な
安定性を示す乳化系を得るべく鋭意検討した結果、乳化
剤としてポリオキシアルキレン変性オルガノポリシロキ
サンを用いると前述の様な欠点が解消されるこを見出し
本発明を完成した。[Problems to be Solved by the Invention] The present inventors have conducted extensive studies in order to obtain an emulsifying system that provides water repellency and a smooth feel, which are the properties of a polymeric silicone coating, and also exhibits good stability as an emulsified composition. As a result, they discovered that the above-mentioned drawbacks can be overcome by using polyoxyalkylene-modified organopolysiloxane as an emulsifier, and have completed the present invention.
［課題を解決するための手段］
即ち、本発明は、下記一般式［Ｉ］で表わされる高分子
量シリコーンの一種又は二種以上と、下記一般式［Ａ］
〜［Ｄ］で表わされるポリオキシアルキレン変性オルガ
ノポリシロキサンの一種又は二種以上と、水及び／又は
多価アルコールとを含有することを特徴とする乳化組成
物を提供するものである。[Means for Solving the Problems] That is, the present invention provides one or more high molecular weight silicones represented by the following general formula [I], and one or more high molecular weight silicones represented by the following general formula [A]
The present invention provides an emulsified composition containing one or more polyoxyalkylene-modified organopolysiloxanes represented by [D] and water and/or a polyhydric alcohol.
（Ｒ＋はメチル基又は一部がフェニル基を表わし、Ｒ２
はメチル基又は水酸基を表わす。又、ｎは３．０００〜
２０．０００の整数を表わす。）（以下余白）
以下、本発明について詳述する。(R+ represents a methyl group or a part of phenyl group, R2
represents a methyl group or a hydroxyl group. Also, n is 3.000~
Represents an integer of 20.000. ) (blank below) The present invention will be described in detail below.
本発明に用いられる高分子量シリコーンは、上記一般式
［Ｉ］で表わきれるもので、式中のｎの値が３．０００
〜２０，０００であり、常温で軟質ゴム状の性状を呈す
るものである。具体例で示すと、ジメチルポリシロキサ
ン、メチルフェニルポリシロキサン、末端水酸基含有ジ
メチルポリシロキサン、末端水酸基含有メチルフェニル
ポリシロキサン等が挙げられる。従来、重合度が３〜６
５０の範囲のジメチルポリシロキサンは、化粧料や医薬
品等に使用されているが、本発明のごとき高分子量シリ
コーンを乳化し配合した例は全く見られない。The high molecular weight silicone used in the present invention is represented by the above general formula [I], and the value of n in the formula is 3.000.
~20,000, and exhibits soft rubber-like properties at room temperature. Specific examples include dimethylpolysiloxane, methylphenylpolysiloxane, dimethylpolysiloxane containing a terminal hydroxyl group, and methylphenylpolysiloxane containing a terminal hydroxyl group. Conventionally, the degree of polymerization is 3 to 6.
Dimethylpolysiloxane in the range of 50 is used in cosmetics, pharmaceuticals, etc., but there has never been any example of emulsifying and blending high molecular weight silicone as in the present invention.
本発明に用いられる高分子量シリコーンの配合量は、組
成物中の０．０１〜５０重量％、好ましくは０゜１〜５
重量％である。The amount of high molecular weight silicone used in the present invention is 0.01 to 50% by weight, preferably 0.1 to 5% by weight of the composition.
Weight%.
本発明に用いられるポリオキシアルキレン変性オルガノ
ポリシロキサンは、上記一般式［Ａ］〜［Ｄ］で表わさ
れ、平均分子量は１０００以上を有するものが好ましく
、更に好ましくは３０００以上である。また、ポリオキ
シアルキレン変性オルガノポリシロキサン分子中にポリ
オキシアルキレン基を２〜８５重量％含有するものが好
ましく、効果発現の面から更に好ましくは、４０〜８０
重量％である。The polyoxyalkylene-modified organopolysiloxane used in the present invention is represented by the above general formulas [A] to [D], and preferably has an average molecular weight of 1,000 or more, more preferably 3,000 or more. In addition, polyoxyalkylene-modified organopolysiloxane molecules preferably contain 2 to 85% by weight of polyoxyalkylene groups, and more preferably 40 to 85% by weight from the viewpoint of effect expression.
Weight%.
本発明に用いられるポリオキシアルキレン変性オルガノ
ポリシロキサンの配合量は、組成物中の０．１〜１０重
量％であり、好ましくは乳化安定性を考慮して０．５〜
５重量％である。The amount of polyoxyalkylene-modified organopolysiloxane used in the present invention is 0.1 to 10% by weight in the composition, preferably 0.5 to 10% by weight in consideration of emulsion stability.
It is 5% by weight.
本発明に用いられる多価アルコールは、プロピレングリ
コール、１，３−ブタンジオール、ジプロピレングリコ
ール、グリセリン、ジグリセリン、トリグリセリン等の
ポリグリセリン、トリメチロールエタン、トリメチロー
ルプロパン、エリスリトール、ペンタエリスリトール、
ソルビタン、グルコース、ソルビトール、マルチトール
、シュクロース、ラフィノース、トレハロース、ポリオ
キシエチレンメチルグルコシド、ポリオキシプロピレン
メチルグルコシド等が挙げられ、また適量の水を含んで
もよい。乳化組成物の調製に際してはこれらのうち一種
又は二種以上が組み合わきれて用いられる。Polyhydric alcohols used in the present invention include propylene glycol, 1,3-butanediol, dipropylene glycol, glycerin, diglycerin, polyglycerin such as triglycerin, trimethylolethane, trimethylolpropane, erythritol, pentaerythritol,
Examples include sorbitan, glucose, sorbitol, maltitol, sucrose, raffinose, trehalose, polyoxyethylene methyl glucoside, polyoxypropylene methyl glucoside, and may contain an appropriate amount of water. When preparing an emulsified composition, one or a combination of two or more of these may be used.
分子内に２個以上の水酸基を有する多価アルコールの配
合量は、ポリオキシアルキレン変性オルガノポリシロキ
サンに対し重量比で１〜１ 、０００倍の範囲である。The amount of the polyhydric alcohol having two or more hydroxyl groups in the molecule is in the range of 1 to 1,000 times the weight of the polyoxyalkylene-modified organopolysiloxane.
多価アルコールの配合量がポリオキシアルキレン変性オ
ルガノポリシロキサンに対し１未満であるとポリオキシ
アルキレン変性オルガノポリシロキサンの溶解性が悪く
なり、１，０００を越えると乳化安定性が悪くなる。If the amount of polyhydric alcohol is less than 1 to the polyoxyalkylene-modified organopolysiloxane, the solubility of the polyoxyalkylene-modified organopolysiloxane will be poor, and if it exceeds 1,000, the emulsion stability will be poor.
本発明の高分子量シリコーンを乳化する場合、低沸点鎮
状シリコーン油や、低沸点環状シリコーン油や、低沸点
イソパラフィン系炭化水素等の揮発性油分に溶解して用
いることが好ましい。When emulsifying the high molecular weight silicone of the present invention, it is preferable to use it by dissolving it in a volatile oil such as a low-boiling quenched silicone oil, a low-boiling cyclic silicone oil, or a low-boiling isoparaffinic hydrocarbon.
低沸点鎖状シリコーンは次の一般式で表され、具体例を
挙げれば、ヘキサメチルジシロキサン、オクタメチルト
リシロキサン、デカメチルテトラシロキサン、ヘキサデ
カメチルヘプタシロキサンなどである。The low-boiling chain silicone is represented by the following general formula, and specific examples include hexamethyldisiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, and hexadecamethylheptasiloxane.
（式中、ｎはＯ〜５の整数を表す。）
環状シリコーンは次の一般式で表され、具体例を挙げれ
ば、オクタメヂルシクロテトラシロキサン、デカメチル
シクロペンタシロキサン、ドデカメチルシクロヘキサシ
ロキサン、テトラデカメチルシクロヘプタシロキサンな
どである。(In the formula, n represents an integer of O to 5.) The cyclic silicone is represented by the following general formula, and specific examples include octamedylcyclotetrasiloxane, decamethylcyclopentasiloxane, and dodecamethylcyclohexasiloxane. , tetradecamethylcycloheptasiloxane, etc.
（式中、ｎは３〜７の整数を表す。）
低沸点イソパラ゛フィン累炭化水素としては、常圧にお
ける沸点が６０〜２６０℃の範囲にあるイソパラフイン
系炭化水素を挙げることができ、例えばエクソン社製の
アイソパー（登録商標）Ａ１同Ｃ１同Ｄ１同Ｅ１同Ｇ１
同Ｈ１同に１同Ｌ１同Ｍ１シェル社製のシェルゾール（
登録商標）７１、フィリップ社製のツルトロール（登録
商標）１００あるいは同１３０１同２２０などを挙げる
ことができる。(In the formula, n represents an integer of 3 to 7.) Examples of low-boiling isoparaffinic hydrocarbons include isoparaffinic hydrocarbons having a boiling point in the range of 60 to 260°C at normal pressure, For example, Exxon's Isopar (registered trademark) A1 C1 D1 E1 G1
Same H1 Same as Same L1 Same as M1 Shell Sol made by Shell (
Examples include Tsurutrol (registered trademark) 71, Tsurutrol (registered trademark) 100, 1301 and 220 manufactured by Philips.
上記低沸点油は任意の一種又は二種以上を用いることか
で苦、合計の配合量は高分子量シリコーンに対して１〜
５０倍（重量）が好ましい。It is difficult to use one or more of the above low boiling point oils, and the total blending amount is 1 to 1 to 100% of the high molecular weight silicone.
50 times (by weight) is preferable.
本発明の乳化組成物の油相を構成する油としては、高分
子量シリコーンとともにその他のつぎのような油を併用
することができる。As the oil constituting the oil phase of the emulsified composition of the present invention, the following other oils can be used in combination with the high molecular weight silicone.
すなわち、オリーブ油、ヤシ油、サフラワー油、ヒマシ
油、綿実油などの油脂類、ラノリン、ホホバ油、カルナ
バロウなどのロウ類、流動パラフィン、スクワラン、ワ
セリン、揮発性イソパラフィンなどの炭化水素油、脂肪
酸類、アルコール類、オクタン酸セチル、ミリスチン酸
イソプロピルなどのエステル油、ジメチルポリシロキサ
ン、メチルフェニルポリシロキサンなどのシリコーン油
、シリコーン樹脂等の油である。In other words, oils and fats such as olive oil, coconut oil, safflower oil, castor oil, and cottonseed oil, waxes such as lanolin, jojoba oil, and carnauba wax, hydrocarbon oils such as liquid paraffin, squalane, petrolatum, and volatile isoparaffin, fatty acids, These include alcohols, ester oils such as cetyl octoate and isopropyl myristate, silicone oils such as dimethylpolysiloxane and methylphenylpolysiloxane, and oils such as silicone resins.
本発明の乳化組成物の調製方法は、特に限定されないが
、あらかじめポリオキシアルキレン変−性オルガノボリ
シロキサンと多価アルコールとの混合物を調製し、つい
で高分子量シリコーン（又は高分子量シリコーンと他の
油分）と混合して得る方法が最も好ましい。ここに得ら
れた乳化組成物は、透明乃至半透明、若しくは乳白色の
粘稠液体又はゲルであり、ハンドクリーム、美容ゼリー
、マツサージゼリー、薬用ゼリー等に使用することがで
きる。またこのようにして得られた乳化組成物と、水又
は水相成分とを混合すれば、乳液、クリーム、ファンデ
ーション、シャンプー、リンス、アクネクリーム等に使
用できる水中油型乳化組成 ・物が得られ、産業上非常
に有用である。なお、ここで水相成分とは、水に保湿剤
、薬剤、防腐剤、高分子、顔料、分散剤、金属イオン封
鎖剤、低級アルコール、生薬抽出物、ムコ多糖、アミノ
酸、色素等の成分を溶解、分散したものである。The method for preparing the emulsified composition of the present invention is not particularly limited, but a mixture of a polyoxyalkylene-modified organoborisiloxane and a polyhydric alcohol is prepared in advance, and then a mixture of a high molecular weight silicone (or a high molecular weight silicone and other oil) is prepared. ) is most preferred. The emulsified composition obtained here is a transparent to translucent or milky white viscous liquid or gel, and can be used in hand creams, beauty jelly, pine surgery jelly, medicated jelly, and the like. Furthermore, by mixing the emulsion composition thus obtained with water or an aqueous phase component, an oil-in-water emulsion composition that can be used for emulsions, creams, foundations, shampoos, conditioners, acne creams, etc. can be obtained. , which is very useful in industry. Note that the aqueous phase components here refer to components such as humectants, drugs, preservatives, polymers, pigments, dispersants, sequestering agents, lower alcohols, crude drug extracts, mucopolysaccharides, amino acids, and pigments in water. It is dissolved and dispersed.
本発明に係わる乳化組成物には、使用目的によっては薬
剤、紫外線吸収剤、防腐剤、酸化防止剤、アルコール、
色素、香料等を添加してもよい。Depending on the purpose of use, the emulsified composition according to the present invention may include drugs, ultraviolet absorbers, preservatives, antioxidants, alcohol,
Colorants, fragrances, etc. may also be added.
［発明の効果］
本発明の乳化組成物は、安定性、撥水性、肌への密着感
、毛髪へのなめらかき賦与等の使用性に優れ、化粧料又
は医薬品基剤として有用なものである。[Effects of the Invention] The emulsion composition of the present invention has excellent usability such as stability, water repellency, adhesion to the skin, and imparts smoothness to hair, and is useful as a cosmetic or pharmaceutical base. .
［実施例］
以下、本発明を実施例及び比較例によって更に詳細に説
明する。本発明はこれにより限定されるものではない。[Examples] Hereinafter, the present invention will be explained in more detail with reference to Examples and Comparative Examples. The present invention is not limited thereby.
配合量は重量％である。The blending amount is in weight%.
実施例１ 乳化組成物
（１）デカメチルシクロペンタシロキサン ５０（２）
ジメチルポリシロキサン
（一般式［Ｉ］でＲ１および
Ｒ２はメチル基、ｎ＝５０００）１４
（３）ジプロピレングリコール １３（４）
１．３−ブチレングリコール １３（５）イ
オン交換水 ５（６）ポリオキシ
アルキレン変性
オルガノポリシロキサン
（一般式［Ａ］、Ｒはメチル基。Example 1 Emulsified composition (1) decamethylcyclopentasiloxane 50 (2)
Dimethylpolysiloxane (in general formula [I], R1 and R2 are methyl groups, n = 5000) 14 (3) Dipropylene glycol 13 (4)
1.3-Butylene glycol 13(5) Ion-exchanged water 5(6) Polyoxyalkylene-modified organopolysiloxane (general formula [A], R is a methyl group.
Ｒｏは水素、 ｐ＝３゜ ポリオキシエチレン基含有率７０％。Ro is hydrogen, p=3° Polyoxyethylene group content 70%.
粘度１００Ｃ３／２５℃） ５製
法
（１）に（２）を溶解し、（３）〜（６）の混合物に加
えて乳化する。Viscosity: 100C3/25°C) 5 Manufacturing method: Dissolve (2) in (1), add to the mixture of (3) to (6), and emulsify.
比較例１
実施例１においてポリオキシアルキレン変性オルガノポ
リシロキサンの代りにポリエチレン（６０）硬化ヒマシ
油エステルを全量用いたものを比較例１とする。Comparative Example 1 Comparative Example 1 was prepared by using the entire amount of polyethylene (60) hardened castor oil ester in place of the polyoxyalkylene-modified organopolysiloxane in Example 1.
実施例１及び比較例１で得た乳化組成物の専門パネルに
よる使用性評価を表−１に示す。Table 1 shows usability evaluations of the emulsified compositions obtained in Example 1 and Comparative Example 1 by a specialized panel.
表−１
０：べたつかない、なじみ良好、
つやあり、皮膜透明
△：べたつき、なじみ及びつやが普通、皮膜やや白濁
×：べたつく、なじみ悪い、つやなし、皮膜白濁
表−１から明らかなように実施例１は、比較例１に比べ
て、べたつき、なじみ、つや、皮膜の透明度が優れてい
た。また安定性も非常に良好であった。Table-1 0: Not sticky, good blending, glossy, transparent film △: Sticky, normal blending and gloss, slightly cloudy film ×: Sticky, poor blending, no gloss, cloudy film Implemented as shown in Table-1 Example 1 was superior to Comparative Example 1 in stickiness, conformability, gloss, and film transparency. Moreover, the stability was also very good.
実施例２ ハンドクリーム
（１）ジメチルポリシロキサン５ｃｓ ３７．
５（２）メチルフェニルポリシロキサン
（一般式［Ｉ］で、
Ｒ１はメチル基：フェニル基＝１＝１、Ｒ２はメチル基
、ｎ ＝１０，０００） １５．０（３）グリ
セリン １５．０（４） １
、３−ブチレンゲリコール ２５．０（５）
イオン交換水 ４．４５（６）ヒ
アルロン酸ナトリウム ０．０５（７）ポ
リオキシアルキレン変性
オルガノポリシロキサン
（−Ｍ式［Ａ］、Ｒの５％がフェニル基で残りはメチル
基Ｒｌはメチル基、 ｐ＝３゜ポリオキシエチレン基含
有率７５％。Example 2 Hand Cream (1) Dimethylpolysiloxane 5cs 37.
5 (2) Methylphenyl polysiloxane (general formula [I], R1 is a methyl group: phenyl group = 1 = 1, R2 is a methyl group, n = 10,000) 15.0 (3) Glycerin 15.0 ( 4) 1
, 3-butylene gellicol 25.0 (5)
Ion-exchanged water 4.45 (6) Sodium hyaluronate 0.05 (7) Polyoxyalkylene-modified organopolysiloxane (-M formula [A], 5% of R is a phenyl group and the rest is a methyl group Rl is a methyl group, p=3° polyoxyethylene group content 75%.
ポリオキシプロピレン基含有率５％。Polyoxypropylene group content 5%.
粘度３２０ＣＳ／２５℃）３．０
製法
（１）に（２）を溶解し、（３）〜（７）の混合物に加
えて乳化する。Viscosity: 320CS/25°C) 3.0 Dissolve (2) in manufacturing method (1), add to the mixture of (3) to (7), and emulsify.
実施例３ ヘアブロー
（１）オクタメチルシクロ
テトラシロキサン １５．０
（２）ジメチルポリシロキサン
（一般式［Ｉ］で、Ｒ１はメチル基、
Ｒ２は水酸基、ｎ ＝７．０ＯＯ） ３．０
（３）１．３−ブチレングリコール ３．
０（４）ポリオキシアルキレン変性
オルガノポリシロキサン
（一般式［Ｃ］、Ｒはメチル基。Example 3 Hair blow (1) Octamethylcyclotetrasiloxane 15.0 (2) Dimethylpolysiloxane (in general formula [I], R1 is a methyl group, R2 is a hydroxyl group, n = 7.0OO) 3.0
(3) 1.3-butylene glycol 3.
0(4) Polyoxyalkylene-modified organopolysiloxane (general formula [C], R is a methyl group.
Ｒｏは水素、 ｐ ＝３゜ ポリオキシエチレン基含有率４０％。Ro is hydrogen, p = 3゜ Polyoxyethylene group content 40%.
粘度２００Ｃ３／２５℃）２．０
（５）エタノール １５．０（
６）イオン交換水 ６２．０（７
）香料 適量製法
（１）に（２）を溶解し、（３）（４）の混合物に加え
て乳化して、（５）〜（７）と混合する。Viscosity 200C3/25℃) 2.0 (5) Ethanol 15.0 (
6) Ion exchange water 62.0 (7
) Fragrance Dissolve appropriate amount of (2) in (1), add to mixture of (3) and (4), emulsify, and mix with (5) to (7).
実施例４ ヘアムースの
（１）デカメチルシクロ
ペンタシロキサン ２０．０
（２）ジメチルポリシロキサン
（一般式［Ｉ］で、Ｒ１はメチル基、
Ｒ２は水酸基、ｎ ＝６，０００） ５．０
（３）ジプロピレングリコール ５．０（
４）ポリオキシアルキレン変性
オルガノポリシロキサン
（一般式［Ｂ］、Ｒはメチル基。Example 4 Hair mousse (1) Decamethylcyclopentasiloxane 20.0 (2) Dimethylpolysiloxane (in general formula [I], R1 is a methyl group, R2 is a hydroxyl group, n = 6,000) 5.0
(3) Dipropylene glycol 5.0 (
4) Polyoxyalkylene-modified organopolysiloxane (general formula [B], R is a methyl group.
Ｒｏはブチル基、ｐ＝＝３゜ ポリオキシエチレン基含有率５０％。Ro is a butyl group, p==3゜ Polyoxyethylene group content 50%.
ポリオキシプロピレン基含有率１０％。Polyoxypropylene group content 10%.
粘度１００ＣＳ／２５℃） ・ ３
．０（５）エタノール １０．
０（６）イオン交換水 ５１．０
（７）香料 適量（８）
ブタン ４．０（９）ジメ
チルエーテル ２．０製法
（１）に（２）を溶解し、（３）（４）の混合物に加え
て乳化して、（５）〜（７）とを混合してなる溶液をエ
アゾール容器に入れて弁を取りつけた後に（８）（９）
を充填する。Viscosity 100CS/25℃) ・3
．． 0(5) Ethanol 10.
0(6) Ion exchange water 51.0
(7) Flavoring (appropriate amount) (8)
Butane 4.0 (9) Dimethyl ether 2.0 Manufacturing method Dissolve (2) in (1), add to the mixture of (3) and (4), emulsify, and mix with (5) to (7). After putting the solution into the aerosol container and attaching the valve (8) (9)
Fill it.
実施例２〜４は、安定性、撥水性、使用性に優れていた
。Examples 2 to 4 were excellent in stability, water repellency, and usability.
特許出願人 株式会社 資生堂Patent applicant: Shiseido Co., Ltd.
Claims (1)
ーンの一種又は二種以上と、下記一般式［Ａ］〜［Ｄ］
で表わされるポリオキシアルキレン変性オルガノポリシ
ロキサンの一種又は二種以上と、水及び／又は多価アル
コールとを含有することを特徴とする乳化組成物。 ▲数式、化学式、表等があります▼［ I ］ （Ｒ＿１はメチル基又は一部がフェニル基を表わし、Ｒ
＿２はメチル基又は水酸基を表わす。又、ｎは３，００
０〜２０，０００の整数を表わす。）▲数式、化学式、
表等があります▼［Ａ］ ▲数式、化学式、表等があります▼［Ｂ］ ▲数式、化学式、表等があります▼［Ｃ］ ▲数式、化学式、表等があります▼［Ｄ］ （式中、Ｒは炭素数１乃至３のアルキル基、又はフエニ
ル基、Ｒ′は水素、又は炭素数１乃至１２のアルキル基
、ｐは１乃至５の整数、ｍは０乃至１００の整数、ｎお
よびｘは１乃至５０の整数、ｔおよびｙは０乃至５０の
整数である。）(1) One or more high molecular weight silicones represented by the following general formula [I] and the following general formulas [A] to [D]
An emulsified composition comprising one or more polyoxyalkylene-modified organopolysiloxanes represented by the following formula, and water and/or a polyhydric alcohol. ▲There are mathematical formulas, chemical formulas, tables, etc.▼ [I] (R_1 represents a methyl group or a part of it is a phenyl group, and R
_2 represents a methyl group or a hydroxyl group. Also, n is 3,00
Represents an integer from 0 to 20,000. )▲Mathematical formula, chemical formula,
There are tables, etc. ▼ [A] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [B] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [C] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [D] (In the formula , R is an alkyl group having 1 to 3 carbon atoms or a phenyl group, R' is hydrogen or an alkyl group having 1 to 12 carbon atoms, p is an integer of 1 to 5, m is an integer of 0 to 100, n and x is an integer from 1 to 50, and t and y are integers from 0 to 50.)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63033545A JP2743067B2 (en) | 1988-02-16 | 1988-02-16 | Emulsion composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63033545A JP2743067B2 (en) | 1988-02-16 | 1988-02-16 | Emulsion composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01210028A true JPH01210028A (en) | 1989-08-23 |
| JP2743067B2 JP2743067B2 (en) | 1998-04-22 |
Family
ID=12389540
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63033545A Expired - Fee Related JP2743067B2 (en) | 1988-02-16 | 1988-02-16 | Emulsion composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2743067B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0446111A (en) * | 1990-06-11 | 1992-02-17 | Kao Corp | Hair-treating agent |
| JP2000256128A (en) * | 1999-03-09 | 2000-09-19 | Pola Chem Ind Inc | Impregnated-type sheet-like pack |
| FR2826292A1 (en) * | 2001-06-22 | 2002-12-27 | Rhodia Chimie Sa | OIL OIL EMULSIONS COMPRISING SILICONE, DISPERSIONS OF SUCH EMULSIONS AND USE |
| JP2007169184A (en) * | 2005-12-20 | 2007-07-05 | Shiseido Co Ltd | Skin cosmetic |
| WO2017122581A1 (en) * | 2016-01-15 | 2017-07-20 | 信越化学工業株式会社 | Organopolysiloxane emulsion composition and resin composition |
| WO2018029966A1 (en) * | 2016-08-10 | 2018-02-15 | 信越化学工業株式会社 | Organopolysiloxane emulsion compositon and resin composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60126209A (en) * | 1983-12-09 | 1985-07-05 | Lion Corp | Cosmetic |
| JPS616A (en) * | 1984-03-15 | 1986-01-06 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Hair conditioning composition |
| JPS6190732A (en) * | 1984-10-03 | 1986-05-08 | ツエ−ハ−．ゴ−ルドシユミツト アクチエンゲゼルシヤフト | Use of polyoxyalkylene/polysiloxane copolymer as emulsifier for producing water/oil type emulsion |
-
1988
- 1988-02-16 JP JP63033545A patent/JP2743067B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60126209A (en) * | 1983-12-09 | 1985-07-05 | Lion Corp | Cosmetic |
| JPS616A (en) * | 1984-03-15 | 1986-01-06 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Hair conditioning composition |
| JPS6190732A (en) * | 1984-10-03 | 1986-05-08 | ツエ−ハ−．ゴ−ルドシユミツト アクチエンゲゼルシヤフト | Use of polyoxyalkylene/polysiloxane copolymer as emulsifier for producing water/oil type emulsion |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0446111A (en) * | 1990-06-11 | 1992-02-17 | Kao Corp | Hair-treating agent |
| JP2000256128A (en) * | 1999-03-09 | 2000-09-19 | Pola Chem Ind Inc | Impregnated-type sheet-like pack |
| FR2826292A1 (en) * | 2001-06-22 | 2002-12-27 | Rhodia Chimie Sa | OIL OIL EMULSIONS COMPRISING SILICONE, DISPERSIONS OF SUCH EMULSIONS AND USE |
| WO2003000396A1 (en) * | 2001-06-22 | 2003-01-03 | Rhodia Chimie | Oil-in-oil emulsions comprising a silicone, dispersions and use of said emulsions |
| JP2007169184A (en) * | 2005-12-20 | 2007-07-05 | Shiseido Co Ltd | Skin cosmetic |
| CN108473771A (en) * | 2016-01-15 | 2018-08-31 | 信越化学工业株式会社 | Organopolysiloxane emulsification composition and resin combination |
| JP2017125139A (en) * | 2016-01-15 | 2017-07-20 | 信越化学工業株式会社 | Organopolysiloxane emulsion composition and resin composition |
| WO2017122581A1 (en) * | 2016-01-15 | 2017-07-20 | 信越化学工業株式会社 | Organopolysiloxane emulsion composition and resin composition |
| KR20180102109A (en) * | 2016-01-15 | 2018-09-14 | 신에쓰 가가꾸 고교 가부시끼가이샤 | Organopolysiloxane emulsion composition and resin composition |
| EP3404068A4 (en) * | 2016-01-15 | 2019-08-14 | Shin-Etsu Chemical Co., Ltd. | Organopolysiloxane emulsion composition and resin composition |
| US10703908B2 (en) | 2016-01-15 | 2020-07-07 | Shin-Etsu Chemical Co., Ltd. | Organopolysiloxane emulsion composition and resin composition |
| TWI713673B (en) * | 2016-01-15 | 2020-12-21 | 日商信越化學工業股份有限公司 | Organic polysiloxane emulsion composition and resin composition |
| WO2018029966A1 (en) * | 2016-08-10 | 2018-02-15 | 信越化学工業株式会社 | Organopolysiloxane emulsion compositon and resin composition |
| JPWO2018029966A1 (en) * | 2016-08-10 | 2018-12-27 | 信越化学工業株式会社 | Organopolysiloxane emulsion composition and resin composition |
| CN109563346A (en) * | 2016-08-10 | 2019-04-02 | 信越化学工业株式会社 | Organopolysiloxane emulsification composition and resin combination |
| CN109563346B (en) * | 2016-08-10 | 2021-08-24 | 信越化学工业株式会社 | Organopolysiloxane emulsion composition and resin composition |
| US11242458B2 (en) | 2016-08-10 | 2022-02-08 | Shin-Etsu Chemical Co., Ltd. | Organopolysiloxane emulsion composition and resin composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2743067B2 (en) | 1998-04-22 |
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