Nothing Special   »   [go: up one dir, main page]

JPH01189145A - Manufacture of semiconductor substrate - Google Patents

Manufacture of semiconductor substrate

Info

Publication number
JPH01189145A
JPH01189145A JP1433688A JP1433688A JPH01189145A JP H01189145 A JPH01189145 A JP H01189145A JP 1433688 A JP1433688 A JP 1433688A JP 1433688 A JP1433688 A JP 1433688A JP H01189145 A JPH01189145 A JP H01189145A
Authority
JP
Japan
Prior art keywords
semiconductor substrate
semiconductor
film
insulating film
substrates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1433688A
Other languages
Japanese (ja)
Inventor
Hisao Hayashi
久雄 林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sony Corp
Original Assignee
Sony Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sony Corp filed Critical Sony Corp
Priority to JP1433688A priority Critical patent/JPH01189145A/en
Publication of JPH01189145A publication Critical patent/JPH01189145A/en
Pending legal-status Critical Current

Links

Landscapes

  • Local Oxidation Of Silicon (AREA)

Abstract

PURPOSE:To stick two substrates rigidly at low temperature, by incorporating nonmetallic impurities in the insulating film of the surface of at least one semiconductor substrates of the two semiconductor substrates. CONSTITUTION:A BPSG film 3, doped with B and P, is provided on the surface of a semiconductor substrate 1. A non-doped SiO2 film 4 is provided with thermal oxidation on the surface of a semiconductor 2. The films 3 and 4 are overlapped and irradiated with laser beams. Then, the BPSG undergoes reflow at relatively low temperature. B or P is diffused in the SiO2 and acts as enclosure at the interface bonding at the boundary part of both films. Thus, a unitary SiO2 film 5 is obtained. As a result, the semiconductor substrates 1 and 2 can be stuck rigidly at the low heating temperature.

Description

【発明の詳細な説明】 以下の順序に従って本発明を説明する。[Detailed description of the invention] The present invention will be described in the following order.

A、産業上の利用分野 B0発明の概要 C0従来技術[第2図] D0発明が解決しようとする問題点 E0問題点を解決するための手段 F8作用 G、実施例[第1図] H0発明の効果 (A、産業上の利用分野) 本発明は半導体基板の製造方法、特に表面に絶縁膜を形
成した2枚の半導体基板を貼り合わせて1つの半導体基
板を得る半導体基板の製造方法に関する。
A. Industrial field of application B0 Overview of the invention C0 Prior art [Fig. 2] D0 Problem to be solved by the invention E0 Means for solving the problem F8 Effect G. Examples [Fig. 1] H0 Invention Effects (A. Field of Industrial Application) The present invention relates to a method for manufacturing a semiconductor substrate, and particularly to a method for manufacturing a semiconductor substrate in which one semiconductor substrate is obtained by bonding two semiconductor substrates each having an insulating film formed on the surface thereof.

(B、発明の概要) 本発明は、上記の半導体基板の製造方法において、 低い温度で強固に半導体基板を貼り合わせることができ
るようにするため、 少くとも一方の半導体基板の表面の絶縁膜に非金属不純
物を含有させておくものである。
(B. Summary of the Invention) In the method for manufacturing a semiconductor substrate described above, the present invention provides the following method: in order to be able to firmly bond the semiconductor substrates together at a low temperature, an insulating film on the surface of at least one semiconductor substrate is coated with the insulating film. It contains non-metallic impurities.

(C,従来技術)[第2図] SOI基板表面の半導体層にMISトラジスタ等の素子
を形成するSol技術は電気的特性の優れた回路を形成
することができる等の種々の利点を有しており、最近S
ol技術の開発、研究が盛んに行われている。ところで
、SOI基板は、シリコン半導体基板の形成に絶縁膜を
部分的に形成し、半導体基板の表面に窓(露出部)を種
として半導体層をエピタキシャル成長させるという方法
で製造することができる。しかし、このような製造方法
では良好で均質なrp−結晶半導体層を形成することが
難しく、実用性が低いという問題があった。
(C, Prior Art) [Figure 2] Sol technology, which forms elements such as MIS transistors in the semiconductor layer on the surface of an SOI substrate, has various advantages such as being able to form circuits with excellent electrical characteristics. Recently, S
The development and research of ol technology is actively being carried out. Incidentally, an SOI substrate can be manufactured by a method in which an insulating film is partially formed in the formation of a silicon semiconductor substrate, and a semiconductor layer is epitaxially grown on the surface of the semiconductor substrate using a window (exposed portion) as a seed. However, such a manufacturing method has a problem in that it is difficult to form a good and homogeneous RP-crystalline semiconductor layer, and the practicality of the method is low.

そこで、最近有望視されてきたのが2枚の半導体ウェハ
を貼り合わせるSOI基板の製造方法である。勿論、チ
ップどうしを貼り合わせる半導体基板の製造方法は特公
昭41−8173号公報、特公昭39−17869号公
報によって紹介されているように古くから知られている
が、2枚の半導体基板を製造する技術は比較的最近開発
された技術である。第2図(A)乃至(C)はかかるS
ol基板の製造方法の従来例を工程順に示すものである
。この製造方法は同図(A)に示すように表面に絶縁H
9,bを形成した2枚の半導体基板a、cを用意し、同
図(B)に示すようにその2枚の゛h導体基板a、cど
うしを絶縁膜す、bにて熱圧着して貼り合わせ、その後
、同図(C)に示すように一方の半導体基板例えばaを
裏面から研磨し、その半導体基板が薄い半導体層a′と
して残存するようにするものである。a″は研磨により
除去された部分である。
Therefore, a method of manufacturing an SOI substrate in which two semiconductor wafers are bonded together has recently been viewed as promising. Of course, the manufacturing method of semiconductor substrates by bonding chips together has been known for a long time as introduced in Japanese Patent Publication No. 41-8173 and Japanese Patent Publication No. 39-17869. This is a relatively recently developed technology. Figures 2 (A) to (C) show such S
A conventional example of a method for manufacturing an OL substrate is shown in order of steps. This manufacturing method is as shown in the same figure (A).
Two semiconductor substrates a and c on which 9 and b are formed are prepared, and as shown in the same figure (B), the two conductor substrates a and c are bonded together by thermocompression with insulating films 9 and b. Then, as shown in FIG. 2C, one semiconductor substrate, for example, a, is polished from the back side so that the semiconductor substrate remains as a thin semiconductor layer a'. a'' is a portion removed by polishing.

このような方法によれば、5in2からなる絶縁膜b、
bの表面に存在するOH基によって5in2が水素結合
し、絶縁膜す、bどうしが密着し、2枚のウェハ状半導
体基板a、cを1枚のウェハ状Sol基板にすることが
できる。
According to such a method, the insulating film b consisting of 5in2,
5in2 is hydrogen bonded by the OH group present on the surface of b, the insulating films S and B are brought into close contact with each other, and the two wafer-shaped semiconductor substrates a and c can be made into one wafer-shaped Sol substrate.

(D、発明が解決しようとする問題点)ところで、絶縁
膜す、bは5in2からなり融点が高いので、貼り合わ
せのための加熱温度を相当に高くしなければ強固に半導
体基板a、cどうしを固着することができない。
(D. Problem to be solved by the invention) By the way, the insulating films A and B are made of 5in2 and have a high melting point, so unless the heating temperature for bonding is considerably high, the semiconductor substrates A and C cannot be firmly connected to each other. cannot be fixed.

そこで、本発明は比較的低い温度で加熱処理しても2枚
の半導体基板を強固に貼り合わせることかできるように
することを目的とする。
Therefore, an object of the present invention is to enable two semiconductor substrates to be firmly bonded together even when heat-treated at a relatively low temperature.

(E、問題点を解決するための手段) 本発明半導体基板の製造方法は上記問題点を解決するた
め、 貼り合される2枚の半導体基板の少なくとも一方の半導
体基板の絶縁膜に非金属不純物を含有させておくことを
特徴とする。
(E. Means for Solving the Problems) In order to solve the above-mentioned problems, the method for manufacturing a semiconductor substrate of the present invention includes the step of adding non-metallic impurities to the insulating film of at least one of the two semiconductor substrates to be bonded together. It is characterized by containing.

(F、作用) 本発明半導体基板の製造方法によれば、一方の半導体基
板の絶縁膜に非金属不純物が含有されているので、その
絶縁膜の融点が低くなる。従って、低い温度で加熱して
も半導体基板どうしを固着することができる。しかも、
非金属不純物は加熱処理の際に拡散して2つの絶縁膜の
境界部での界面結合の介在物として働くので、2つの絶
縁膜を強固に固着することができる。
(F. Effect) According to the method for manufacturing a semiconductor substrate of the present invention, since the insulating film of one semiconductor substrate contains a nonmetallic impurity, the melting point of the insulating film is lowered. Therefore, the semiconductor substrates can be fixed to each other even when heated at a low temperature. Moreover,
The nonmetallic impurities diffuse during the heat treatment and act as inclusions for interfacial bonding at the boundary between the two insulating films, so that the two insulating films can be firmly bonded.

(G、実施例)[第1図] 以下、本発明半導体基板の製造方法を図示実施例に従っ
て詳細に説明する。
(G, Example) [FIG. 1] Hereinafter, the method for manufacturing a semiconductor substrate of the present invention will be described in detail according to the illustrated example.

第1図(A)乃至(C)は本発明半導体基板の製造方法
の一つの実施例を工程順に示す断面図である。
FIGS. 1A to 1C are cross-sectional views showing one embodiment of the method for manufacturing a semiconductor substrate of the present invention in the order of steps.

先ず、第1図(A)に示すように表面に絶縁膜が形成さ
れた2枚のウェハ状の半導体基板1.2を′用意する。
First, as shown in FIG. 1A, two wafer-shaped semiconductor substrates 1.2 having insulating films formed on their surfaces are prepared.

一方の半導体基板1の表面には例えばホウ素B及びリン
Pがドープされたシリコン酸化膜であるBPSG膜3が
形成されており、他方の゛ト導体基板2の表面には熱酸
化によりノンドープシリコン酸化膜4が形成されている
A BPSG film 3, which is a silicon oxide film doped with, for example, boron B and phosphorus P, is formed on the surface of one semiconductor substrate 1, and a non-doped silicon oxide film 3 is formed on the surface of the other conductor substrate 2 by thermal oxidation. A film 4 is formed.

次に、同図(B)に示すように半導体基板2の表面に半
導体基板1を表面を下向きにして貼り合わせ、そして、
半導体基板IMしにCO2レーザからのレーザビームを
シリコン酸化膜3.4に照射する。すると、比較的低い
温度でBPSGIIQ3の表面にリフローが生しシリコ
ン酸化1摸4と接着し易くなる。そして、BPSG膜3
中のホウ素BあるいはリンPがシリコン酸化膜4中に拡
散し、BPSG膜3とシリコン酸化膜4の境界部での界
面結合の介在物として働き、同図(C)に示すようにB
PSG膜3とシリコン酸化rIFA4とが一体のシリコ
ン酸化膜5となる。その結果、低い加熱温度で強固に半
導体基板1と2を貼り合わせることができる。
Next, as shown in the same figure (B), the semiconductor substrate 1 is bonded to the surface of the semiconductor substrate 2 with the surface facing downward, and
The silicon oxide film 3.4 is irradiated with a laser beam from a CO2 laser while the semiconductor substrate IM is being processed. Then, reflow occurs on the surface of BPSGIIQ3 at a relatively low temperature, making it easier to adhere to silicon oxide 1 and 4. And BPSG film 3
The boron B or phosphorus P inside diffuses into the silicon oxide film 4 and acts as an inclusion for interfacial bonding at the boundary between the BPSG film 3 and the silicon oxide film 4, and as shown in FIG.
The PSG film 3 and silicon oxide rIFA 4 form an integrated silicon oxide film 5. As a result, the semiconductor substrates 1 and 2 can be firmly bonded together at a low heating temperature.

その後は図示しないが、−・方の半導体基板例えば半導
体基板1をその裏面側から研磨し半導体基板lがシリコ
ン酸化膜5上に薄く残存するようする。すると、SOI
構造の半導体基板が出来上ることになる。そして、シリ
コン酸化膜5上に薄く残存した半導体基板に薄膜トラン
ジスタ等の素子が形成されることになる。
Thereafter, although not shown, the semiconductor substrate 1, for example the semiconductor substrate 1, is polished from its back side so that the semiconductor substrate 1 remains thin on the silicon oxide film 5. Then, SOI
A semiconductor substrate with this structure is completed. Elements such as thin film transistors are then formed on the semiconductor substrate remaining thinly on the silicon oxide film 5.

尚、上記実施例においではC02レーザ光の照射により
加熱処理をしていた。これは、C02レーザ光の波長が
約10μmであり、シリコンの結晶中は透過するが5i
n2には吸収され半導体基板1を徒らに温度上昇させる
ことな(BPSGJI5! 3、シリコン酸化膜4を効
果的に加熱することができるからである。これは貼り合
わせ後半導体基板が加熱されて結晶欠陥が生じるのを防
止することにもなる。尚、レーザ光をパルスにして与え
れば半導体基板lの温度上昇を非常に有効に防止しなが
ら貼り合わせのためのBPSG膜3、シリコン酸化膜4
の加熱を行うことができる。しかし、普通の加熱処理に
より貼り合わせを行うようにしても良いことはいうまで
もない。
In the above embodiment, the heat treatment was performed by irradiation with C02 laser light. This is because the wavelength of the C02 laser beam is approximately 10 μm, and although it passes through the silicon crystal, 5i
This is because the silicon oxide film 4 can be effectively heated without being absorbed by n2 and causing the temperature of the semiconductor substrate 1 to rise needlessly (BPSGJI5! 3).This is because the semiconductor substrate is heated after bonding. This also prevents crystal defects from occurring.Incidentally, if the laser beam is applied in the form of pulses, the temperature rise of the semiconductor substrate 1 can be very effectively prevented, while the BPSG film 3 and silicon oxide film 4 used for bonding can be prevented.
can be heated. However, it goes without saying that the bonding may be performed by ordinary heat treatment.

また、上記実施例においては、一方の絶縁膜3がBPS
Gからなり、他方の絶縁W;84がノンドープのシリコ
ン酸化膜からなっていた。しかし、一方の絶縁11!2
3をBPSGに代えてPSG、BSGあるいはAs5G
で形成するようにしても良いし、更には絶縁膜3を例え
ばBPSG等非金属不純物がドープされた絶縁膜とノン
ドープの絶縁膜の二層構造にしても良い。
Further, in the above embodiment, one of the insulating films 3 is made of BPS.
The other insulator W; 84 was made of a non-doped silicon oxide film. However, one insulation 11!2
Replace 3 with BPSG: PSG, BSG or As5G
Furthermore, the insulating film 3 may have a two-layer structure of an insulating film doped with a non-metallic impurity such as BPSG and a non-doped insulating film.

また、一方の絶縁膜3を非金属不純物ドープ絶縁膜とノ
ンドープ絶縁膜の二層構造にし、他方の絶縁膜4をBP
SGあるいはPSG等非金属不純物がトープされたシリ
コン酸化膜で形成するようにしても良い等本発明には種
々の変形例が考えられ得る。
Further, one insulating film 3 has a two-layer structure of a non-metal impurity doped insulating film and a non-doped insulating film, and the other insulating film 4 has a BP-doped insulating film.
Various modifications can be considered to the present invention, such as forming the silicon oxide film doped with nonmetallic impurities such as SG or PSG.

(H,発明の効果) 以上に述べたように、本発明半導体基板の製造方法は、
互いに貼り合される2枚の半導体基板の少くとも一方の
半導体基板の表面に形成された絶縁膜の少なくとも表面
部に非金属不純物を予めドープしておくことを特徴とす
るものである。
(H, Effect of the invention) As described above, the method for manufacturing a semiconductor substrate of the present invention is as follows:
This method is characterized in that at least the surface portion of an insulating film formed on the surface of at least one of two semiconductor substrates that are bonded together is doped with a non-metallic impurity in advance.

従って、本発明半導体基板の製造方法によれば、一方の
半導体基板の絶縁膜に非金属不純物が含有されているの
で、その絶縁膜の融点が低くなる。従って、低い温度で
加熱しても半導体基板どうしを固着することができる。
Therefore, according to the method for manufacturing a semiconductor substrate of the present invention, since the insulating film of one semiconductor substrate contains non-metallic impurities, the melting point of the insulating film is lowered. Therefore, the semiconductor substrates can be fixed to each other even when heated at a low temperature.

しかも、非金属不純物は加熱処理の際に拡散して2つの
絶縁膜の境界部での界面結合の介在物として働くので、
2つの絶縁膜を強固に固着することができる。
Moreover, nonmetallic impurities diffuse during heat treatment and act as inclusions for interfacial bonding at the boundary between two insulating films.
Two insulating films can be firmly fixed.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図(A)乃至(C)は本発明半導体基板の製造方法
の一つの実施例を工程順に示す断面図、第2図(A)乃
t(C)は従来例を工程順に示す断面図である。 符号の説明 1.2・・・半導体基板、 3・・・非金属不純物がドープされた絶縁膜、4・・・
絶縁膜。 出 願 人  ソニー株式会社
FIGS. 1(A) to (C) are cross-sectional views showing one embodiment of the method for manufacturing a semiconductor substrate of the present invention in the order of steps, and FIGS. 2(A) to (C) are cross-sectional views showing a conventional example in the order of steps. It is. Explanation of symbols 1.2... Semiconductor substrate, 3... Insulating film doped with non-metallic impurities, 4...
Insulating film. Applicant Sony Corporation

Claims (1)

【特許請求の範囲】[Claims] (1)表面に絶縁膜を形成した2枚の半導体基板を絶縁
膜表面どうしが密着するように重ねて加熱処理すること
により貼り合わせて1枚の半導体基板とする半導体基板
の製造方法において、 互いに貼り合される2枚の半導体基板の少くとも一方の
半導体基板の表面に形成された絶縁膜の少なくとも表面
部に非金属不純物を予めドープしておくことを特徴とす
る半導体基板の製造方法
(1) In a method of manufacturing a semiconductor substrate, in which two semiconductor substrates each having an insulating film formed on their surfaces are stacked and heat-treated so that the surfaces of the insulating films are in close contact with each other, the semiconductor substrates are bonded together to form a single semiconductor substrate. A method for manufacturing a semiconductor substrate, comprising doping in advance at least a surface portion of an insulating film formed on the surface of at least one of two semiconductor substrates to be bonded together with a non-metallic impurity.
JP1433688A 1988-01-23 1988-01-23 Manufacture of semiconductor substrate Pending JPH01189145A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1433688A JPH01189145A (en) 1988-01-23 1988-01-23 Manufacture of semiconductor substrate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1433688A JPH01189145A (en) 1988-01-23 1988-01-23 Manufacture of semiconductor substrate

Publications (1)

Publication Number Publication Date
JPH01189145A true JPH01189145A (en) 1989-07-28

Family

ID=11858225

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1433688A Pending JPH01189145A (en) 1988-01-23 1988-01-23 Manufacture of semiconductor substrate

Country Status (1)

Country Link
JP (1) JPH01189145A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5453394A (en) * 1992-01-31 1995-09-26 Canon Kabushiki Kaisha Process for preparing semiconductor substrate by bringing first and second substrates in contact
JP2019513294A (en) * 2016-03-07 2019-05-23 グローバルウェーハズ カンパニー リミテッドGlobalWafers Co.,Ltd. Semiconductor on insulator structure including low temperature flowable oxide layer and method of manufacturing the same

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5451388A (en) * 1977-09-29 1979-04-23 Cho Lsi Gijutsu Kenkyu Kumiai Method of producing semiconductor
JPS5717158A (en) * 1980-07-04 1982-01-28 Fujitsu Ltd Manufacture of semiconductor device
JPS62287648A (en) * 1986-06-06 1987-12-14 Yokogawa Electric Corp Si bonding method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5451388A (en) * 1977-09-29 1979-04-23 Cho Lsi Gijutsu Kenkyu Kumiai Method of producing semiconductor
JPS5717158A (en) * 1980-07-04 1982-01-28 Fujitsu Ltd Manufacture of semiconductor device
JPS62287648A (en) * 1986-06-06 1987-12-14 Yokogawa Electric Corp Si bonding method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5453394A (en) * 1992-01-31 1995-09-26 Canon Kabushiki Kaisha Process for preparing semiconductor substrate by bringing first and second substrates in contact
JP2019513294A (en) * 2016-03-07 2019-05-23 グローバルウェーハズ カンパニー リミテッドGlobalWafers Co.,Ltd. Semiconductor on insulator structure including low temperature flowable oxide layer and method of manufacturing the same

Similar Documents

Publication Publication Date Title
US4771016A (en) Using a rapid thermal process for manufacturing a wafer bonded soi semiconductor
JP2857802B2 (en) Method of connecting two objects together
US4404735A (en) Method for manufacturing a field isolation structure for a semiconductor device
JP2856030B2 (en) Method for manufacturing bonded wafer
JP2806277B2 (en) Semiconductor device and manufacturing method thereof
JP3395661B2 (en) Method for manufacturing SOI wafer
JPS61296709A (en) Manufacture of semiconductor
JPH05251292A (en) Manufacture of semiconductor device
JPH05217826A (en) Semiconductor base body and its manufacture
JPS6242385B2 (en)
JPH0719738B2 (en) Bonded wafer and manufacturing method thereof
KR20070055382A (en) Method of manufacturing bonded wafer
JP4273540B2 (en) Bonded semiconductor substrate and manufacturing method thereof
JP2624186B2 (en) Manufacturing method of bonded silicon substrate
JPH01189145A (en) Manufacture of semiconductor substrate
JPH05129258A (en) Production of semiconductor wafer and semiconductor integrated circuit device
JP3570530B2 (en) Manufacturing method of SOI wafer
JPS61174661A (en) Semiconductor integrated circuit device and manufacture thereof
JPH10189405A (en) Manufacture of direct-bonded silicon substrate
JP2006245567A (en) Method of manufacturing semiconductor device
JPH09116125A (en) Soi wafer and its manufacture
JP3216535B2 (en) SOI substrate and manufacturing method thereof
JP2581531B2 (en) Method for manufacturing semiconductor device
JPH11214503A (en) Manufacture of semiconductor device
JP2001144273A (en) Method for fabricating semiconductor device