JPH01168737A - Coloration of synthetic resin article containing reclaimed rubber - Google Patents
Coloration of synthetic resin article containing reclaimed rubberInfo
- Publication number
- JPH01168737A JPH01168737A JP32890387A JP32890387A JPH01168737A JP H01168737 A JPH01168737 A JP H01168737A JP 32890387 A JP32890387 A JP 32890387A JP 32890387 A JP32890387 A JP 32890387A JP H01168737 A JPH01168737 A JP H01168737A
- Authority
- JP
- Japan
- Prior art keywords
- synthetic resin
- pigment
- reclaimed rubber
- mixture
- kneading
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920003002 synthetic resin Polymers 0.000 title claims abstract description 26
- 239000000057 synthetic resin Substances 0.000 title claims abstract description 26
- 239000000049 pigment Substances 0.000 claims abstract description 13
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 11
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 11
- 238000004898 kneading Methods 0.000 claims abstract description 10
- 238000010438 heat treatment Methods 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 14
- 238000004040 coloring Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 abstract description 8
- 239000000843 powder Substances 0.000 abstract description 5
- 239000002270 dispersing agent Substances 0.000 abstract description 4
- 239000010920 waste tyre Substances 0.000 abstract description 4
- 238000001746 injection moulding Methods 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract 5
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000011236 particulate material Substances 0.000 abstract 1
- -1 polypropylene Polymers 0.000 description 9
- 239000004743 Polypropylene Substances 0.000 description 8
- 229920001155 polypropylene Polymers 0.000 description 8
- 239000008187 granular material Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/201—Pre-melted polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2319/00—Characterised by the use of rubbers not provided for in groups C08J2307/00 - C08J2317/00
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明は、廃棄タイヤ等から再生された再生ゴムを混合
材料として利用した再生ゴムを含有する合成樹脂製品の
着色方法に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a method for coloring a synthetic resin product containing recycled rubber using recycled rubber recycled from waste tires and the like as a mixed material.
(従来の技術)
ポリプロピレン、ポリエチレン等の熱可塑性合成樹脂製
品は、−膜内に釘打ちが困難であるため、例えば、広い
ベランダの床面上に多数敷設したスノコ同士を連結させ
るためには、別体の連結板とボルト・ナツトを用いなけ
ればならず、従って、連結作業に多くの時間と労力とを
必要とするという欠点があった。(Prior Art) Thermoplastic synthetic resin products such as polypropylene and polyethylene are difficult to nail into the membrane. This method has the disadvantage that a separate connecting plate and bolts and nuts must be used, and therefore, a lot of time and labor are required for the connecting work.
そこで、上述の欠点を解消する方法としては、合成樹脂
にゴムを添加することによって製品素材に弾力性を持た
せるようにすることが考えられる。Therefore, one possible way to overcome the above-mentioned drawbacks is to add rubber to the synthetic resin to impart elasticity to the product material.
即ち、熱可塑性合成樹脂原料に5%〜40%位の割合で
ゴムを添加した状態で加熱混練することによって、所要
の弾力性を備えた合成樹脂製品が得られ、従って、例え
ばスノコの両連結部に予めテーパー穴を形成し、該テー
パー穴より少し大径の打ち込み脚部を備えたカスガイ状
の連結金具を打ち込んでいくだけでスノコ同士を釘打ち
と同様の感覚で容易かつ迅速に連結できるようになる。That is, by heating and kneading a thermoplastic synthetic resin raw material with rubber added at a ratio of about 5% to 40%, a synthetic resin product with the required elasticity can be obtained. By forming a tapered hole in advance in the section and driving in a slat-like connecting fitting with a leg slightly larger in diameter than the tapered hole, you can easily and quickly connect the drainboards together with the same feeling as driving nails. It becomes like this.
(発明が解決しようとする問題点)
しかしながら、ゴムは合成樹脂に比べると単価か高いの
で、ゴムの添加によって製品コストが高くなるという問
題点がある。(Problems to be Solved by the Invention) However, since rubber is more expensive than synthetic resins, there is a problem in that the addition of rubber increases the product cost.
もっとも、ゴム原料として廃棄タイヤ等から再生される
再生ゴムを利用すれば、単価が安いので製品コストか高
くなることはないか、再生ゴムの原料となる廃棄タイヤ
には、ゴム素材に耐摩耗性、耐光性、耐熱性等を付与す
るために添加されたカーボンブラックか20%〜40%
位の割合で含有されている関係上、合成樹脂との加熱混
練の際にこのカーボンブラックが溶出して製品全体が黒
くなり、このため再生ゴムを利用できる製品の種類や用
途がごく限られた範囲に制限されてしまうという問題点
があった。However, if recycled rubber recycled from waste tires etc. is used as a rubber raw material, the unit price is low, so the product cost will not increase. , 20% to 40% carbon black added to impart light resistance, heat resistance, etc.
Due to the fact that the carbon black is contained in such a large proportion, when heated and kneaded with the synthetic resin, this carbon black is eluted and the entire product turns black, which limits the types and uses of products for which recycled rubber can be used. There was a problem that the range was limited.
(問題点を解決するための手段)
本発明は、上述のような問題点を解決することを目的と
してなされたもので、この目的達成のために本発明では
、熱可塑性合成樹脂原料と再生ゴム原料とを加熱混練す
る過程において、黒色以外の色の顔料を添加混練すると
いう方法を採用した。(Means for Solving the Problems) The present invention has been made for the purpose of solving the above-mentioned problems, and in order to achieve this purpose, the present invention uses thermoplastic synthetic resin raw materials and recycled rubber. In the process of heating and kneading the raw materials, a method was adopted in which a pigment of a color other than black was added and kneaded.
(作用)
本発明の再生ゴムを含有する合成樹脂製品の着色方法で
は、上述のように、熱可塑性合成樹脂原料と再生ゴム原
料とを加熱混練する過程において、黒色以外の色の顔料
を添加混練することによって、はぼ希望の色に近い色に
着色された再生ゴム入り合成樹脂製品か得られるように
なり、従って、再生ゴムを利用できる製品の種類や用途
の制限か解消され、あらゆる分野の合成樹脂製品に安価
な再生ゴムか広く利用できるようになる。(Function) In the method for coloring synthetic resin products containing recycled rubber of the present invention, as described above, in the process of heating and kneading the thermoplastic synthetic resin raw material and the recycled rubber raw material, a pigment of a color other than black is added and kneaded. By doing this, it becomes possible to obtain synthetic resin products containing recycled rubber that are colored in a color close to the desired color.Therefore, the restrictions on the types and uses of products that can use recycled rubber are eliminated, and it is used in all fields. Cheap recycled rubber will become widely available for synthetic resin products.
(実施例)
以下、本発明の実施例を図面に基づいて詳細に説明する
。尚、この実施例ではスノコを製造する場合を例にとる
。(Example) Hereinafter, an example of the present invention will be described in detail based on the drawings. In this embodiment, a case where a drainboard is manufactured will be taken as an example.
まず、熱可塑性合成樹脂原料としてポリプロピレンの粒
原料を用い、このポリプロピレンの粒原料100部に対
し添加剤(または分散剤)を0.1部添加混合したもの
に、希望する色(例えばグリーン)の顔料を1.0部添
加して単純混合することによって、ポリプロピレンの粒
原料の表面に顔料か添着する。First, a polypropylene granule raw material is used as a thermoplastic synthetic resin raw material, and 0.1 part of an additive (or dispersant) is added to 100 parts of this polypropylene granule raw material. By adding 1.0 part of the pigment and simply mixing it, the pigment is attached to the surface of the polypropylene granular raw material.
次に、廃棄タイヤより再生した再生ゴム粉(好ましくは
冷凍粉砕品でできるたけ微粒のもの)を25%の割合で
単純混合させる。Next, recycled rubber powder recycled from discarded tires (preferably frozen and pulverized powder as fine as possible) is simply mixed at a ratio of 25%.
以上のようにして混合された原料をスクリュ式射出成型
機にかけると、該原料は加熱シリンダ内で加熱されて溶
融すると共に、スクリュの回転で混練されながら金型方
向へ送られ、スクリュヘットまで送られた時点ではポリ
プロピレンの粒原料と顔料と再生ゴム粉とが完全に溶融
混練され、全体がグリーンに着色された混合原料となっ
て金型内に射出され、グリーンに着色されたスノコAが
成型されることになる。When the raw materials mixed in the above manner are applied to a screw-type injection molding machine, the raw materials are heated and melted within the heating cylinder, and are sent toward the mold while being kneaded by the rotation of the screw, until reaching the screw head. At the time of delivery, the polypropylene granular raw material, pigment, and recycled rubber powder are completely melted and kneaded, and the whole mixed raw material is colored green and injected into the mold, and the green colored drainboard A is made. It will be molded.
尚、この実施例のスノコAは、第1図及び第2図に示す
ように、所要間隔のもとに複数本配設された脚台lの上
面に、複数枚の板状体2を少しづつ隙間を開けた状態で
敷設した形態に一体成型されると共に、スノコAの長手
方向両側縁部となる各脚台1の両端部に相当する板状体
2には、カスガイ状の連結金具3の水平部30を収容可
能な溝20が脚台lの長手方向に沿ってそれぞれ構設さ
れると共に、6溝20の内方端部には、連結金具3の両
打ち込み脚部31の直径より少し小径のテーパー穴21
が、脚台1方向へ向けて垂直に開設された構成となって
いる。Incidentally, as shown in FIGS. 1 and 2, the drainboard A of this embodiment has a plurality of plate-like bodies 2 placed on the top surface of a plurality of pedestals L arranged at required intervals. The plate-shaped body 2 corresponding to both ends of each leg base 1, which is the longitudinal side edges of the drainboard A, has a hook-like connecting fitting 3. Grooves 20 capable of accommodating the horizontal portions 30 of the six grooves 20 are respectively constructed along the longitudinal direction of the leg base l, and the inner ends of the six grooves 20 are provided with a diameter larger than the diameter of both driving legs 31 of the connecting fitting 3. Slightly small diameter tapered hole 21
is vertically opened toward one direction of the footrest.
この実施例のスノコAでは、上記構成より成るため、広
いベランダの床面上に敷設した各スノコA、A同士を連
結させたときは、カスガイ状の連結金具3の両打ち込み
脚部31.31を互いに隣接するスノコA、Aの各テー
パー穴21.21内にそれぞれ打ち込むことにより、各
テーパー穴21.21を構成する素材の弾力性によって
、釘打ちと同様の感覚で連結金具3の打ち込みが容易か
つ迅速に行なわれることになる。そして、連結金具3を
打ち込んだ状態では、連結金具3の水平部30が両スノ
コA、Aの溝20.20内に収容され、スノコAの上面
に連結金具3が全く突出しない状態となる。Since the drainboard A of this embodiment has the above-mentioned configuration, when the drainboards A and A are connected to each other on the floor of a wide balcony, both the driven legs 31 and 31 of the slat-shaped connecting fitting 3 By driving the connecting fittings 3 into the respective tapered holes 21.21 of the adjacent drainboards A and A, the elasticity of the material constituting each tapered hole 21.21 allows the connecting fitting 3 to be driven in with the same feeling as driving a nail. It will be done easily and quickly. When the connecting fitting 3 is driven in, the horizontal portion 30 of the connecting fitting 3 is accommodated in the grooves 20 and 20 of both the drainboards A, and the connecting fitting 3 does not protrude from the upper surface of the drainboard A at all.
以上説明してきたように本実施例の再生ゴムを含有する
合成樹脂製品の着色方法によれば、熱可塑性合成樹脂原
料であるポリプロピレンの粒原料と廃棄タイヤより再生
した再生ゴム粉に、更にクリーンの顔料を添加した状態
で加熱混練することによって、グリーンに着色されたス
ノコAか得られるようになる。As explained above, according to the method of coloring synthetic resin products containing recycled rubber according to the present example, the raw material of polypropylene particles, which are raw materials for thermoplastic synthetic resin, and the recycled rubber powder recycled from waste tires are added to By heating and kneading with the pigment added, a green colored drainboard A can be obtained.
また実施例では、ポリプロピレンの粒原料にまず添着剤
(または分散剤)を添加混合した後に、顔料を単純温合
するようにしたことで、ポリプロピレンの粒原料への顔
料の添着力を向上させることかできるようになる。In addition, in the example, the adhesion of the pigment to the polypropylene granule material was improved by adding and mixing the impregnating agent (or dispersant) to the polypropylene granule material and then simply heating the pigment. You will be able to do this.
以上、本発明の実施例を図面により詳述してきたか、具
体的な方法及びこの方法に用いられる部材や装置類の具
体的構成はこの実施例に限定されるものではなく、本発
明の要旨を逸脱しない範囲における具体的方法の変更等
があっても本発明に含まれる。Although the embodiments of the present invention have been described in detail with reference to the drawings, the specific method and the specific configuration of the members and devices used in this method are not limited to these embodiments. Even if there are changes in the specific method without departing from the scope, they are included in the present invention.
例えば、実施例では、添加剤(または分散剤)を添加さ
せる場合を示したが、この添加は任意であり、また、そ
の他の添加剤を加えることも任意である。For example, although the examples show cases in which additives (or dispersants) are added, this addition is optional, and addition of other additives is also optional.
また、各素材の混合割合や混合順序も任意であり、製品
の種類やその用途に応じて決定することかできる。Furthermore, the mixing ratio and mixing order of each material are arbitrary, and can be determined depending on the type of product and its use.
(発明の効果)
以上説明してきたように本発明の再生ゴムな含有する合
成樹脂製品の着色方法にあ7ては、熱可塑性合成樹脂原
料と再生ゴム原料とを加熱混練する過程において、黒色
以外の色の顔料を添加混練することによって、はぼ希望
の色に近い色に着色された再生ゴム入り合成樹脂製品が
得られるようになり、従って、再生ゴムを利用できる製
品の種類や用途の制限が解消され、あらゆる分野の合成
樹脂製品に安価な再生ゴムが広く利用できるようになる
という効果が得られる。(Effects of the Invention) As explained above, in the method for coloring a synthetic resin product containing recycled rubber according to the present invention, in the process of heating and kneading the thermoplastic synthetic resin raw material and the recycled rubber raw material, coloring other than black color is possible. By adding and kneading pigments of the same color, it is now possible to obtain a synthetic resin product containing recycled rubber that is colored in a color close to the desired color, thus limiting the types of products and applications for which recycled rubber can be used. This has the effect that inexpensive recycled rubber can now be widely used in synthetic resin products in all fields.
第1図は実施例のスノコを示す斜視図、第2図は第1図
1−1線における拡大断面図である。
特 許 出 願 人
秋 山 和 男 (他1名)FIG. 1 is a perspective view showing a drainboard according to an embodiment, and FIG. 2 is an enlarged sectional view taken along the line 1-1 in FIG. Patent application: Kazuo Hitoakiyama (1 other person)
Claims (1)
する過程において、黒色以外の色の顔料を添加混練する
ことを特徴とする再生ゴムを含有する合成樹脂製品の着
色方法。1) A method for coloring a synthetic resin product containing recycled rubber, which comprises adding and kneading a pigment of a color other than black in the process of heating and kneading a thermoplastic synthetic resin raw material and a recycled rubber raw material.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP32890387A JPH01168737A (en) | 1987-12-24 | 1987-12-24 | Coloration of synthetic resin article containing reclaimed rubber |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP32890387A JPH01168737A (en) | 1987-12-24 | 1987-12-24 | Coloration of synthetic resin article containing reclaimed rubber |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH01168737A true JPH01168737A (en) | 1989-07-04 |
Family
ID=18215379
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP32890387A Pending JPH01168737A (en) | 1987-12-24 | 1987-12-24 | Coloration of synthetic resin article containing reclaimed rubber |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH01168737A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1500673A4 (en) * | 2002-04-19 | 2005-06-08 | Ube Industries | Method for reusing crushed synthetic resin product having cured resin incorporated therein |
JP2007245726A (en) * | 2002-04-19 | 2007-09-27 | Ube Ind Ltd | Method for reusing crushed synthetic resin product having cured resin mixed therein |
JP2007291402A (en) * | 2002-05-09 | 2007-11-08 | Ube Ind Ltd | Method for reusing pulverized synthetic resin product |
JP2009173947A (en) * | 2003-10-17 | 2009-08-06 | Ube Ind Ltd | Resin composition for vehicular interior using crushed material of vehicular bumper mixed with insoluble substance as raw material, and molding thereof |
KR100973961B1 (en) * | 2002-05-09 | 2010-08-05 | 우베 고산 가부시키가이샤 | Method for reusing crushed synthetic resin product |
WO2012133789A1 (en) * | 2011-03-31 | 2012-10-04 | 宇部興産株式会社 | Polyolefin resin composition molded body having high scratch resistance |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5620039A (en) * | 1979-07-24 | 1981-02-25 | Vredestein Icopro Bv | Thermoplastic elastomer composition and its manufacture |
-
1987
- 1987-12-24 JP JP32890387A patent/JPH01168737A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5620039A (en) * | 1979-07-24 | 1981-02-25 | Vredestein Icopro Bv | Thermoplastic elastomer composition and its manufacture |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1500673A4 (en) * | 2002-04-19 | 2005-06-08 | Ube Industries | Method for reusing crushed synthetic resin product having cured resin incorporated therein |
JP2007245726A (en) * | 2002-04-19 | 2007-09-27 | Ube Ind Ltd | Method for reusing crushed synthetic resin product having cured resin mixed therein |
JP2009235419A (en) * | 2002-04-19 | 2009-10-15 | Ube Ind Ltd | Recycling method of synthetic resin product triturate in which resin cured material is intermingled |
KR100973962B1 (en) * | 2002-04-19 | 2010-08-05 | 우베 고산 가부시키가이샤 | Method for reusing crushed synthetic resin product having cured resin incorporated therein |
JP2007291402A (en) * | 2002-05-09 | 2007-11-08 | Ube Ind Ltd | Method for reusing pulverized synthetic resin product |
KR100973961B1 (en) * | 2002-05-09 | 2010-08-05 | 우베 고산 가부시키가이샤 | Method for reusing crushed synthetic resin product |
JP2011153310A (en) * | 2002-05-09 | 2011-08-11 | Ube Industries Ltd | Method for reusing pulverized synthetic resin product |
JP2009173947A (en) * | 2003-10-17 | 2009-08-06 | Ube Ind Ltd | Resin composition for vehicular interior using crushed material of vehicular bumper mixed with insoluble substance as raw material, and molding thereof |
WO2012133789A1 (en) * | 2011-03-31 | 2012-10-04 | 宇部興産株式会社 | Polyolefin resin composition molded body having high scratch resistance |
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