JPH07197087A - Detergent aid made from rice - Google Patents

Abstract

PURPOSE:To obtain a detergent aid which reduces environmental pollution as a result of a reduction in the total amount of discharged detegents and has also an effect as a natural humectant moistening the skin. CONSTITUTION:This detergent aid entirely or partially consists of a member selected from among (1) a product obtained by grinding rice or germinated rice, (2) an extract of rice or germinated rice, (3) a product obtained by the enzymatic decomposition by malted rice of or the action of malted rice on a mixture of rice or germinated rice with water, (4) a product obtained by the enzymatic decomposition by malted rice of or the action of malted rice on rice or germinated rice before, during or after its extraction, and (5) a product obtained by the alcoholic fermentation or the organic acid fermentation of an extract of rice or germinated rice or a product obtained by the enzymatic decomposition by malted rice of or the action of malted rice on rice or germinated rice.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION The present invention uses rice or sprouted rice to dramatically increase detergency and bubble power even when the concentration of surfactants etc. is low, and the total amount of surfactant discharged. The present invention relates to a cleaning aid which is excellent in environmental protection from the viewpoint and has a remarkable moisturizing effect and a smooth effect on the skin.

[0002]

2. Description of the Related Art Conventionally, various cleaning agents have appeared on the market for the purpose of removing dirt depending on the field of use and the type of dirt. Soap-based, petroleum, coconut oil, and surfactants derived from palm oil are the surfactants. But these are
In all cases, rough skin is the biggest problem, and since it is not in nature, it causes environmental problems. On the other hand, rice is not only staple food, but also sake, shochu, mirin, vinegar,
It has been developed for use as koji and has been indispensable for daily life. However, almost no new applications have been developed. This may be due to the fact that rice was viewed as just a staple food, or at best viewed only as a source of starch. Also,
Nukabukuro is known as an application other than food, but it is said that it is good for the skin even if it is a bran bag, and it was only used conventionally as it is, and if there is no concept of an active ingredient, it is said that an active ingredient is used. I had no idea.

[0003]

In recent years, rough skin and environmental pollution have become very serious problems for cleaning agents in general, but no effective solution has been found. Regarding environmental problems, water pollution of rivers and the sea has become a major problem. Although natural products are said to be good for the environment, charcoal, rice bran, etc., which are known as natural detergents, are not currently used because they have no detergency against oily substances.

On the other hand, synthetic detergents have a detergency, but have become a serious problem from the viewpoint of rough hands and environmental pollution. Therefore, soap movements are being carried out in various places, but even with this soap, synthetic detergent (standard usage is generally 1.5 ml /
If the same amount is used as compared to the standard amount, it is good for the environment.
Unless it is used in a large amount of 7.5 ml / liter, it has no detergency, so recently it is said that there is an environmental problem in terms of the total amount discharged, in addition to the feeling of use. In addition, even in synthetic detergents, in order to prevent rough hands, the surfactant concentration is generally 27-29%.
However, the cleaning power is inevitably reduced by the general standard usage amount, and the standard usage amount is 2.
This is the same from the environmental point of view, as it increases to 5 ml / liter. That is, there is a long-felt need for a cleaning aid that provides a sufficient cleaning power even with a low surfactant concentration and a small amount used. In addition, in order to prevent rough hands, there are some products that use a low concentration of surfactant, or natural fruit juice, aloe, glycerin, dipropylene glycol, etc. are added as moisturizers. Solution has not been reached.

The same can be said with respect to face washing foams, body soaps and other baths, and toiletry products. Up to now, we have been providing moisturizing properties mainly with oils, amino acids, polysaccharides, etc. However, recently in this field, safety has become a problem, and there are some that contain natural moisturizers such as natural oils, hyaluronic acid, placenta extract, etc. The cleaning power is poor. The present inventor has already developed a detergent from rice (Japanese Patent Application Laid-Open No. 4-146981). However, it has been desired to develop a cleaning aid which has the same or higher effects as those of the preceding invention at a lower cost and more easily.

[0006]

[Means for Solving the Problems] From the viewpoint of animal and plant harmony, the present inventors have conducted research on various plant components centering on rice, which is a staple food. In the process, it has become clear that rice has a number of potential and benefits that were previously unpredictable. Therefore, we picked up rice, which is used as a staple food and proved to have the highest safety, as the theme,
I have conducted comprehensive utilization research on rice. As one of the themes, we have conducted intensive research on cleaning aids from rice.In the process, rice and sprouted rice were used with a smaller amount than the standard amount of surfactant used. The inventors have found that the composition contains a component that is extremely excellent in detergency and bubble power, and has a remarkable moisturizing and slippery effect on the skin, and completed the present invention.

In the present invention, the components having the above-mentioned effects contained in rice and germinated rice have not yet been clarified, but rice and germinated rice treated as described below are used as detergents. It was found that when it was contained in the composition, it exhibited a cleaning aid effect. Crushed rice or germinated rice as it is or containing it. Rice or germinated rice extract as it is or containing it. Enzyme-decomposed or hydrolyzed rice hydrolyzed as it is, or containing it. When extracting rice or sprouted rice, the one that has been subjected to enzymatic decomposition or koji before or at the same time as or after the extraction is used as it is or containing it. An extract of rice or germinated rice or a product of enzymatic decomposition or koji which has been subjected to alcohol fermentation or organic acid fermentation as it is or containing it.

The rice used in the present invention is Japonica,
Regardless of indica rice, it refers to non-glutinous rice, brown rice such as sticky rice, and white rice, regardless of variety and type. Further, 92% or more of red rice bran or 92% or less of white rice bran, which appears during whitening, may be used, which is inexpensive and economical. Also,
Germinated rice is used. In addition, since the active ingredient is stable to heat and light, the above raw materials are dipping, steaming, roasting (all sand roasting, net roasting, hot air roasting, etc.),
The raw material treatment such as steam roasting, surface modification such as freeze-drying, photo-modification such as UV irradiation, pressure roasting such as Patrice, and frying may be performed, and the effect was not changed.

Although the rice and germinated rice are effective as they are, they are preferably crushed for practical use. In order to pulverize the rice and the sprouted rice into powder, a pulverizer or a rice mill may be used and a general method may be used. When sprouting rice, germinated rice is soaked in water or sprayed with water to germinate. The temperature for germination is 5 to 70 ° C. However, the temperature and time do not matter as long as they germinate. Also, if there is a risk of water spoiling during germination, replace the water so that it does not decay, or
It is preferable to carry out some preservatives. Here, germination means
It refers to everything from just before germination to germinated ones. The germinated rice is washed well before use. At this time, it may be dried before use.

When extracting rice or germinated rice, or subjecting it to enzymatic decomposition or koji, the raw material rice is pulverized into granules or powders, thereby increasing the surface area and improving efficiency. You don't have to grind, but in this case,
It takes a long time to decompose and extract the rice tissue. When extracting rice or germinated rice with water, a high extraction temperature is effective, but sufficient extraction can be performed even at a low temperature.
However, in the case of a low temperature of 40 ° C. or lower, it is desirable to make PH acidic or alkaline, or add a preservative or alcohol to treat the rice so that it does not spoil.
The extraction time may be long or short as long as the active ingredient can be extracted, and may be determined depending on the extraction temperature. The extraction may be carried out under pressure, at normal pressure, or under reduced pressure.

In the case of water extraction, the gelatinization phenomenon is the most problematic. If it becomes pasty, not only the extraction efficiency will deteriorate, but it will be extremely difficult in actual work. In order to prevent this, the reaction may be carried out by adding amylase or acidification may be carried out with hydrochloric acid or the like to cut the starch. By using this method, it can be sufficiently solved and there is no problem in practice.
Since the active ingredient in the extract is stable to acid and alkali, acid decomposition extraction or alkali decomposition extraction is also effective. In this case, neutralization and desalting are performed if necessary.

Also when extracting with an organic solvent, it is desirable to pulverize or pulverize rice as much as possible before extracting. The organic solvent may be a general organic solvent such as alcohol, acetone, n-hexane and methanol, but those harmful to the human body are preferably safe because it is necessary to completely remove the solvent after extraction. In addition, rice or germinated rice may be enzymatically decomposed or koji may be allowed to act. Enzymatic degradation here means starch degrading enzyme, proteolytic enzyme, lipolytic enzyme,
It refers to the action of one or more enzymes that act on rice, such as fiber degrading enzymes, lignin degrading enzymes, and pectin degrading enzymes. The koji mold may be any kind of koji mold, rice variety or kind.

Further, in carrying out the above-mentioned extraction, the above-mentioned enzymatic decomposition and koji may be applied before the extraction, at the same time as the extraction, or after the extraction. In the present invention, when the organic acid fermentation such as alcohol fermentation, lactic acid fermentation, or acetic acid fermentation is carried out simultaneously with or after the above treatment, the following points are also effective. When alcohol fermentation is carried out, not only is there no stickiness at the time of application, but it is also easy to concentrate and the active ingredient is easily concentrated. If necessary, aeration fermentation with yeast, alcohol precipitation, synthetic adsorbents and the like may be used for sugar removal. Further, when the red bran portion of 92% or more was examined, it was found that it was effective but weak.

The product of the present invention obtained as described above is used as it is without separating the residue, or after being pressed and filtered. The treated product of rice thus obtained or sprouted rice may be added to and mixed with various detergents. That is, since a simple method of addition and mixing is sufficient, it can be used in a wide range of applications such as makeup soap, wash soap, shampoo, body soap, face wash, kitchen detergent, household detergent, hand washer and the like. When mixing, in the case of a liquid such as a kitchen detergent, the product of the present invention is directly mixed with the base surfactant and stirred well. The amount added is 1 for the final product, depending on the intended use and purpose.
~ 30%. In the case of a creamy face-washing foam, 1 to 30% is added during saponification or mixing. Also, when it is better to make powder like a detergent for washing, it is spray-dried to make powder, granulate, and well mixed. In any case, if it is desired to obtain a better effect, the addition amount may be increased.

Next, description will be made based on concrete experimental data. First, based on what was adjusted the concentration of the surfactant to 29% and 20% as a base, this was mixed with the product of the present invention, and the concentration of the surfactant was adjusted to 20%. Method, the dish washing test method, and the loss-miles test as the bubble force test, and the results are shown in Table 1. As the test method, the Leanut test method and the loss miles method were performed in accordance with JIS standards. In addition, as a method of the dish washing test method, commercially available lard and sponge (110 m
m x 75 mm x 30 mm), dish (φ25 cm), sample (1 g of each detergent + 1 g of tap water) 2 g are prepared. First, attach 2.5 g of commercial lard to the surface of the dish and spread it with your fingers at 25 ° C. Saved before and after. Apply 1g of sample to a dry sponge, lightly brush it to make bubbles, wash the outside and inside of the dish once each time with this sponge, repeat this 5 times with 1 dish, and wash as many times as possible until the bubbles disappear Was tested 5 times and the average value was examined.

[0016]

[Table 1] Note 1 Base is sodium polyoxyethylene lauryl ether sulfate: coconut oil fatty acid amide propyl betaine:
It is a mixture of lauryl dimethylamine oxide: coconut oil fatty acid diethanolamide = 21: 7: 2: 3. Note 2: Surfactant concentration is the concentration when the final product is used.

As can be seen by comparing the numerical values of only the surfactant base, the surfactant concentration is from 29% to 20%.
However, even if the surfactant concentration is reduced to 20% by adding and mixing the product of the present invention, the detergent concentration is better than the 29% surfactant-based base alone. There is power and bubble power comes out. As described above, the product of the present invention was found to be remarkably effective as a detergent base even in the JIS standard test method. In addition, according to the expert who performed these, the product of the present invention has not only a clear difference in detergency as compared with the surfactant-based product alone, but also has no effect on the skin after washing as a conventional detergent. There was a moist feeling that was not there. Further, it was found that the fact that such a remarkable difference was further proved in the dish washing test close to actual household stains was extremely effective in practical use.

Furthermore, it has been pointed out that in order to prevent hand roughening, which is a major problem in kitchen detergents, kitchen detergents containing the product of the present invention are more moist than hand-friendly. Therefore, in order to exemplify this moisturizing effect, a kitchen detergent containing the product of the present invention was used by each of 10 panelists for 1 month, and the horny layer water content and transepidermal water loss before and after 1 month use. (Hereinafter abbreviated as TWL)
Was measured and the results are shown in Table 2. The stratum corneum water content was measured with a high frequency conductivity measuring device, and the transepidermal water loss was measured with an evaporation meter. Measurement condition is temperature 2
The environment is set to 0 ° C and humidity 40%, and the panelist measures 3
From 0 minutes before, it was allowed to rest in the above environment, and then measured.

[0019]

[Table 2]

As can be seen from Table 2, the panelist using the kitchen detergent containing all the products of the present invention has an increased amount of water in the stratum corneum after one month and also an increased TWL. In contrast, the panel-only panelists had decreased stratum corneum water content and increased TWL. This tendency appeared as the surfactant concentration increased. Surfactants are generally said to disrupt the barrier mechanism of the skin. Therefore TWL
, And the water content of the stratum corneum decreases. That is, the fact that both the stratum corneum water content and the TWL are increased by blending with the product of the present invention means that the barrier mechanism is not destroyed and the water supply from the dermis is also strong. It was unthinkable with other cleaning agents, and until now it was either detergency or even a little hand-friendly, but a natural one was found to be compatible. It can be said that this is a breakthrough discovery. When soap was also tested for detergency and moisturizing feel, the results were similar to those of synthetic detergents. Not only that, but with soap, the feeling of sliminess was a major problem in use, but the feeling of sliminess could be almost eliminated.

Further, when the product of the present invention was blended with a detergent for washing, it was found that the stain was removed well even with a small amount of use, and that the product was soft and moist even with a hand after washing. Furthermore, when the facial cleansing foam containing the product of the present invention was used by 10 panelists among the bath and toiletry products whose usage has recently increased dramatically, compared to the facial cleansing foam base alone, it became clear and moist for all. There was something. In other words, the product of the present invention has a clear moisturizing property even when it is generally used as a cosmetic product such as a face-washing foam, and from this fact, the excellent moisturizing property of the product of the present invention is demonstrated. It was done. Furthermore, all respondents said that when they were washed with the facial cleansing foam of the present invention, they were not only moist, but also smooth.

Then, the slippery effect of the facial cleansing foam containing the product of the present invention was illustrated. That is, the facial cleansing foam containing the product of the present invention, and the artificial leather washed with the facial cleansing foam not containing the product of the present invention, by a dynamic friction meter,
The coefficient of friction was measured. The measuring method is 0.7
The artificial leather was immersed in 100 g of distilled water dissolved in 100 ml of distilled water, left for 5 minutes, thoroughly washed with water, dried at 25 ° C. for 25 minutes, and the friction coefficient was measured with a dynamic friction meter. The ratio of the average friction coefficient was set as a comparison% when water was 100%, and the results are shown in Table 3.

[0023]

[Table 3]

As is clear from Table 3, it was found that by mixing the product of the present invention with a facial cleansing foam, an excellent facial cleansing foam having an effect of making the skin smooth after the facial cleansing can be obtained. From the above results, by simply adding and mixing the product of the present invention to the detergent base according to the present invention, it is possible to easily obtain excellent cleaning power and foaming power even when the surfactant concentration is low, and
It has been proved that a very good cleansing agent which gives moistness and smoothness to the skin can be obtained.
Further, according to the present invention, even if the concentration of the surfactant is low, a detergent having excellent detergency and bubble power can be obtained. Therefore, it becomes possible to reduce the total amount of the surfactant discharged, and to prevent environmental pollution. Will also make a very important contribution. Further, the product of the present invention obtained as described above, as it is or after being dried, is used in accordance with ordinary methods in accordance with ordinary methods such as kitchen detergents, detergents, toiletries such as soap, cleansing, face-washing foam, cosmetic soap, and body. Dosage form like shampoo, cosmetics for shampoo. That is, a cleaning aid that can be used in various fields can be obtained.

[0025]

【Example】

(Example 1) 1 kg of rice without germ was soaked in water at 25 ° C for 3 days to germinate rice. After thoroughly washing the germinated rice, it is dried at 50 ° C. for 24 hours, and then,
The product was finely pulverized to obtain 990 g of the product of the present invention. (Example 2) Brown rice was crushed to obtain a crushed brown rice product 500
g was obtained. 1500 ml of water was added to this pulverized product, PH was dropped with hydrochloric acid, and the mixture was left for 10 days. Then, it was squeezed with a squeezing machine to neutralize the resulting clear liquid to obtain 1200 ml of the product of the present invention and 760 g of a residue. (Example 3) Using 500 g of the product of the present invention obtained in Example 1, the same operation as in Example 3 was carried out to obtain another product of the present invention 11
90 ml was obtained.

Example 4 Brown rice was crushed to obtain 500 g of crushed brown rice. Liquefaction enzyme 10g and water 1500ml were added to this ground product. Then, the temperature was gradually raised, and the mixture was boiled and extracted for 5 minutes and then cooled. Then, it was squeezed with a squeezing machine to obtain 1420 ml of the product of the present invention and 560 g of a residue. (Example 5) Using 500 g of the product of the present invention obtained in Example 1, the same operation as in Example 4 was carried out to obtain another product of the present invention 14
00 ml was obtained. (Example 6) Brown rice is crushed by a crusher to obtain crushed brown rice 500
g was obtained. 1500 ml of 2N-NaOH was added to this pulverized product and the mixture was left for 5 days. Then, it was squeezed with a squeezing machine to obtain 1350 ml of the clear liquid and 650 g of the residue. 1 of this clarified liquid
Neutralization with 0N-HCl gave 1480 ml of the product of the present invention.

Example 7 Using 500 g of the product of the present invention obtained in Example 1, the same operation as in Example 6 was carried out to obtain another 1490 ml of the product of the present invention. (Embodiment 8) Brown rice is crushed to obtain a crushed brown rice product 500
g was obtained. 1500 ml of 95% ethanol is added to this pulverized product.
Was added and left for 5 days. After that, squeeze with a wringer,
1300 ml of clear liquid and 650 g of residue were obtained. 2000 ml of water was added to this clarified liquid and concentrated by a rotary evaporator to obtain 1500 ml of the product of the present invention. (Example 9) Using 500 g of the present invention product obtained in Example 1, the same operation as in Example 8 was carried out to obtain another invention product 15
00 ml was obtained.

Example 10 Brown rice was crushed to obtain 500 g of crushed brown rice. 300 g of koji and 1500 ml of water were added to this pulverized product, and the mixture was left at 55 ° C. for 20 hours. Then, squeezing with a squeezing machine, 1230 ml of the present invention product and 100 residues
0 g was obtained. (Example 11) Using 500 g of the present invention product obtained in Example 1, the same operation as in Example 10 was carried out to obtain another 1210 ml of the present invention product. (Example 12) Brown rice is crushed to obtain a crushed brown rice product 50
0 g was obtained. 2 g of protease and 150 water
0 ml was added and the mixture was left at 50 ° C. for 20 hours. Then, the product was squeezed with a squeezing machine to obtain 1310 ml of the product of the present invention and 670 g of a residue.

Example 13 Using 500 g of the product of the present invention obtained in Example 1, the same operation as in Example 12 was carried out,
Another 1380 ml of the product of the present invention was obtained. (Example 14) Brown rice is crushed to obtain 50 crushed brown rice.
0 g was obtained. 2 g of lipolytic enzyme and 150 water
0 ml was added and the mixture was left at 50 ° C. for 20 hours. Then, it was squeezed with a squeezing machine to obtain 1290 ml of the product of the present invention and 680 g of a residue. (Example 15) The same operation as in Example 14 was carried out using 500 g of the product of the present invention obtained in Example 1 to obtain 1360 ml of another product of the present invention.

Example 16 Brown rice was crushed with a crusher to obtain 500 g of crushed brown rice. Fiber-degrading enzyme 2 in this crushed product
g and 1500 ml of water were added, and the mixture was left at 50 ° C. for 20 hours. Then, the product was squeezed with a squeezing machine to obtain 1330 ml of the product of the present invention and 650 g of a residue. (Example 17) The same operation as in Example 16 was carried out using 500 g of the product of the present invention obtained in Example 1 to obtain 1370 ml of another product of the present invention. (Example 18) Brown rice was crushed to obtain a crushed brown rice product 50
0 g was obtained. 2g starch degrading enzyme and 150g water
0 ml was added and the mixture was left at 55 ° C. for 20 hours. Then, it was squeezed with a squeezing machine to obtain 1380 ml of the product of the present invention and 600 g of a residue.

Example 19 The same operation as in Example 18 was carried out using 500 g of the product of the present invention obtained in Example 1,
Another 1400 ml of the product of the present invention was obtained. (Example 20) Brown rice is crushed to obtain a crushed brown rice product 50
0 g was obtained. Add 2 g of pectin-degrading enzyme and 1 part of water to this ground product.
500 ml was added and left at 50 ° C. for 20 hours. After that, squeezing with a squeezing machine, 1320 ml of the present invention product and residue 660
g was obtained. (Example 21) Using 500 g of the present invention product obtained in Example 1, the same operation as in Example 20 was carried out to obtain another 1300 ml of the present invention product.

(Example 22) Brown rice was crushed to obtain 500 g of crushed brown rice. Proteolytic enzyme 2 in this crushed product
g, lipolytic enzyme 2 g, fiber degrading enzyme 2 g, starch degrading enzyme 2 g, pectin degrading enzyme 2 g and 1500 ml of water were added, and the mixture was allowed to stand at 50 ° C. for 20 hours. Then, it was squeezed with a squeezing machine to obtain 1420 ml of the product of the present invention and 560 g of a residue. (Example 23) Using 500 g of the product of the present invention obtained in Example 1, the same operation as in Example 22 was carried out to obtain another 1440 ml of the product of the present invention. (Example 24) The same operation as in Example 22 was carried out to obtain 2000 g of an enzymatic decomposition product of rice. Then, the temperature was gradually raised, and the mixture was boiled and extracted for 5 minutes and then cooled. Then, it was squeezed with a squeezing machine to obtain 1400 ml of the product of the present invention and 550 g of a residue.

Example 25 Using 500 g of the product of the present invention obtained in Example 1, the same operation as in Example 24 was carried out,
1420 ml of another product of the present invention was obtained. (Example 26) Brown rice was crushed to obtain a crushed brown rice product 50
0 g was obtained. To this crushed product, 300 g of koji and 1500 ml of 40% ethanol were added, and the mixture was left at 55 ° C. for 48 hours. After that, squeeze with a squeezing machine and clarified liquid 1300 ml and residue 850
g was obtained. Then, 1000 ml of water was added to the clarified solution and concentrated with a rotary evaporator to obtain the product of the present invention 13
00 ml was obtained. (Example 27) The same operation as in Example 26 was carried out using 500 g of the present invention product obtained in Example 1 to obtain another 1300 ml of the present invention product.

(Example 28) In the same manner as in Example 4, 2000 g of a rice extract was obtained. To this extract, 2 g of proteolytic enzyme, 2 g of lipolytic enzyme, 2 g of fiber degrading enzyme, 2 g of starch degrading enzyme, 2 g of pectin degrading enzyme were added, and the mixture was heated at 50 ° C for 2
It was left for 4 hours. After that, the product of the present invention 14
00 ml and 580 g of residue were obtained. (Example 29) The same operation as in Example 28 was carried out using 500 g of the present invention product obtained in Example 1 to obtain another 1390 ml of the present invention product. (Example 30) In the same manner as in Example 24, 2000 g of an enzyme-decomposed extract of rice was obtained. Yeast was added to this enzyme-decomposed extract, and alcoholic fermentation was carried out for 16 days. Then, it was squeezed with a squeezing machine to obtain 1880 ml of the product of the present invention and 80 g of a residue.

(Example 31) The same operation as in Example 30 was carried out using 500 g of the product of the present invention obtained in Example 1,
Another 1800 ml of the product of the present invention was obtained. (Example 32) In the same manner as in Example 24, 2000 g of an enzyme-decomposed extract of rice was obtained. The enzyme-decomposed extract was sterilized by boiling, cooled to 37 ° C., 200 ml of a starter in which lactic acid bacteria had been cultured in advance was added, and the mixture was well stirred and sealed, and
Lactic acid fermentation was performed at 7 ° C for 2 days. Then, it was squeezed with a squeezing machine to obtain 1380 ml of the product of the present invention and 590 g of a residue. (Example 33) Using 500 g of the present invention product obtained in Example 1, the same operation as in Example 32 was carried out to obtain another 1400 ml of the present invention product.

Example 34 80 ml of 95% ethanol was added to 1000 ml of the product of the present invention obtained in Example 24, and acetic acid fermentation was carried out for 20 days. Then, filtration was performed to obtain 990 ml of the product of the present invention. (Example 35) Using 500 g of the present invention product obtained in Example 1, the same operation as in Example 34 was carried out to obtain another 1000 ml of the present invention product. (Example 36) Kitchen detergent Sodium polyoxyethylene lauryl ether sulfate:
Coconut oil fatty acid amide propyl betaine: lauryl dimethylamine oxide: coconut oil fatty acid diethanolamide =
16.5 parts of a surfactant mixed at 21: 7: 2: 3 were prepared, and 15 parts of the product of the present invention obtained in Example 14 and 18.5 parts of water were added thereto to make 50 parts, and well stirred. Then, 50 parts of the product of the present invention was obtained.

(Example 37) Face-washing foam To 25 parts of purified water, 6 parts of potassium hydroxide was added and heated, and 30 parts of myristic acid and 7 parts of stearic acid were added.
And 7 parts of lipophilic glyceryl monostearate were heated and melted, first, 10 parts of glycerin was added and immediately adjusted to 70 ° C., and this was gradually added while stirring well to make soap. . This was cooled to 40 to 50 ° C. with sufficient stirring, 15 parts of the product of the present invention obtained in Example 24 was added thereto, and further cooled to 35 ° C.,
95 parts of the product of the present invention was obtained. (Example 38) Detergent 6 kg of dextrin was added to 10 liters of the product of the present invention obtained in Example 30, and spray-dried to obtain 6.5 kg of a powder extract. 7 parts of this powdered extract was put into 40 parts of well-stirred sodium tallow fatty acid, 20 parts of sodium coconut oil fatty acid and 40 parts of sodium carbonate, and further stirred to obtain 100 parts of the present invention as a powder-washing detergent. .

[0038]

As is clear from the above analytical data and sensory evaluation, the use of a small amount of a detergent or a treated product of sprouted rice in a detergent base allows the detergent to be used in a small amount even if the surfactant concentration is low. It has been found that a sufficient amount of a detergent having sufficient detergency can be obtained. This greatly contributes to the problem of environmental pollution, which is a big problem at present, from the viewpoint of reducing the total amount of surfactant discharged.
Furthermore, by adding processed products of rice or sprouted rice to the cleaning agent base, it not only prevents skin roughening, which was the fate of the cleaning agent, but also a remarkable moisturizing effect and smoothing effect. It has been found that a product that gives and is stable is obtained.

As described above, the present invention germinated both the problem of environmental pollution, which has been a problem with detergents, and the contradictory main problems of protecting the skin without deteriorating the detergency. At the same time, we were able to solve the problem with a safe and inexpensive rice processing product. In addition, the idea of using the active ingredient of rice has never existed before, and it is an epoch-making invention from the viewpoint of effective use of rice and expansion of new uses.

Continuation of the front page (51) Int.Cl. ⁶ Identification number Office reference number FI technical display location C11D 7/44 11/00

Claims (5)

[Claims] 1. A cleaning aid from rice or a ground product of germinated rice as it is or containing it. 2. A cleaning aid from rice or an extract of germinated rice as it is or containing it. 3. A washing aid from rice, which is obtained by enzymatically decomposing or hydrolyzing rice or a hydrolyzed rice germ, or containing it. 4. Extraction of rice or sprouted rice is carried out before, at the same time as or after the extraction, which has been subjected to enzymatic decomposition or koji, as is, or washed from rice containing the same. Auxiliary agent. 5. Washing of rice or germinated rice extract or enzyme-decomposed or koji-acted one that has been subjected to alcohol fermentation or organic acid fermentation as it is or from rice containing the same. Auxiliary agent.