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JP7518982B2 - Packaged coffee drink containing γ-aminobutyric acid - Google Patents

Packaged coffee drink containing γ-aminobutyric acid Download PDF

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JP7518982B2
JP7518982B2 JP2024000789A JP2024000789A JP7518982B2 JP 7518982 B2 JP7518982 B2 JP 7518982B2 JP 2024000789 A JP2024000789 A JP 2024000789A JP 2024000789 A JP2024000789 A JP 2024000789A JP 7518982 B2 JP7518982 B2 JP 7518982B2
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gaba
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沙織 結城
鷹明 谷
範之 神崎
透 片山
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Suntory Holdings Ltd
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Description

本発明は、ボディ感が増強された容器詰コーヒー飲料に関する。 The present invention relates to a packaged coffee beverage with enhanced body.

コーヒー飲料は嗜好性が高く、広く世界中で愛飲されている。コーヒー飲料が消費者に提供される形態は多岐に亘り、例えば家庭や飲食店等で直接提供される形態(所謂レギュラーコーヒー)の他、小売店や自動販売機でRTD(READY TO DRINK)タイプの容器詰コーヒー飲料の形態でも提供されている。 Coffee drinks are highly popular and enjoyed widely around the world. Coffee drinks are provided to consumers in a wide variety of forms, including direct provision at home or restaurants (so-called regular coffee), as well as RTD (ready to drink) packaged coffee drinks at retail stores or vending machines.

容器詰コーヒー飲料は、いつでも手軽にコーヒーを楽しむことができるという利便性により、全清涼飲料市場の中において最大の市場規模を有しているが、抽出後にすぐ飲用に供されるレギュラーコーヒーと比較した場合には、呈味や香味が弱くコク味を感じにくいという問題がある。これは、容器詰コーヒー飲料は、製造時に過酷な加熱殺菌が行われるために化学変化が起こりコーヒー飲料の香味が変化すること、長期保存中のpH変化を抑制するために配合されるpH調整剤由来の味がコーヒー飲料本来の香味を損なうこと等の理由が挙げられる。 Packaged coffee drinks have the largest market size in the entire soft drink market due to their convenience of being able to enjoy coffee easily at any time, but compared to regular coffee that is consumed immediately after extraction, they have a problem in that they have a weaker taste and aroma, and it is difficult to feel the full-bodied flavor. This is because packaged coffee drinks are produced through harsh heat sterilization, which causes chemical changes that change the aroma of the coffee drink, and because the taste derived from the pH adjuster that is added to suppress pH changes during long-term storage detracts from the original aroma of the coffee drink.

そこで、容器詰コーヒー飲料のコク味を付与する方法が種々提案されている。不溶性のコーヒー粉末(微粉砕コーヒー粉末)を配合する方法(特許文献1)、サイクロデキストリンを添加する方法(特許文献2)、馬鈴薯由来でDEが2以上5未満であるデキストリンを添加する方法(特許文献3)、イソクエルシトリン及びその糖付加物をカフェインに対して一定の量比で配合する方法(特許文献4)などがある。 Therefore, various methods have been proposed for imparting full-bodied flavor to packaged coffee beverages. These include blending insoluble coffee powder (finely ground coffee powder) (Patent Document 1), adding cyclodextrin (Patent Document 2), adding potato-derived dextrin with a DE of 2 or more and less than 5 (Patent Document 3), and blending isoquercitrin and its sugar adducts in a fixed ratio to caffeine (Patent Document 4).

特開2015-164401号公報JP 2015-164401 A 特開昭54-145268号公報Japanese Unexamined Patent Publication No. 54-145268 特開2012-115247号公報JP 2012-115247 A 特開2015-119701号公報JP 2015-119701 A

コーヒー飲料のボディ感を増強するには、コーヒー固形分を増やせばよいと考えられる。しかしながら、容器詰コーヒー飲料において単にコーヒー固形分を増やしても、コーヒーの苦味、酸味等の風味のバランスが損なわれ、効果的にボディ感を増強することはできない。 It is thought that the body of a coffee beverage can be enhanced by increasing the coffee solids content. However, simply increasing the coffee solids content in a packaged coffee beverage impairs the balance of coffee flavors such as bitterness and acidity, and the body cannot be enhanced effectively.

本発明は、過酷な加熱殺菌が施され、かつpH調整剤が配合されるような容器詰コーヒー飲料において、ボディ感が十分に付与された容器詰コーヒー飲料を提供することを目的とする。 The present invention aims to provide a packaged coffee beverage that has been subjected to severe heat sterilization and contains a pH adjuster, and that has a sufficient body.

本発明者らは、上記目的を達成すべく鋭意検討した結果、特定量のγ-アミノ酪酸を含有させることにより、容器詰コーヒー飲料のボディ感を増強でき、その目的を達成し得ることを見出し、本発明を完成するに至った。 As a result of intensive research into achieving the above-mentioned objective, the inventors discovered that the body of a packaged coffee beverage can be enhanced by adding a specific amount of γ-aminobutyric acid, thereby achieving the objective, and thus completed the present invention.

本発明は、これに限定されるものではないが、以下の態様を包含する。
[1]焙煎コーヒー豆抽出物を含む容器詰コーヒー飲料であって、
飲料100g中にコーヒー生豆換算で5.0g以上のコーヒー豆抽出物を含み、
11~70mg/100gのγ-アミノ酪酸を含有する、容器詰コーヒー飲料。
[2]γ-アミノ酪酸含有量が15~60mg/100gである、[1]に記載の容器詰コーヒー飲料。
[3]pH調整剤を含む、[1]又は[2]に記載の容器詰コーヒー飲料。
The present invention includes, but is not limited to, the following aspects.
[1] A packaged coffee beverage containing a roasted coffee bean extract,
The beverage contains 5.0 g or more of coffee bean extract in terms of green coffee beans per 100 g of the beverage,
A packaged coffee beverage containing 11 to 70 mg/100 g of γ-aminobutyric acid.
[2] The packaged coffee beverage according to [1], having a γ-aminobutyric acid content of 15 to 60 mg/100 g.
[3] A packaged coffee beverage according to [1] or [2], which contains a pH adjuster.

本発明により、加熱殺菌が施され、かつpH調整剤が配合されるような容器詰コーヒー飲料であるにも関わらず、十分なボディ感が付与された嗜好性の高いコーヒー飲料を提供することが可能となる。 The present invention makes it possible to provide a highly palatable coffee beverage with sufficient body, even though it is a packaged coffee beverage that has been heat sterilized and contains a pH adjuster.

(コーヒー飲料)
家庭や飲食店等で抽出後にすぐ飲用に供されるレギュラーコーヒーでは、コーヒーを口に含んだ時の印象や重量感、すなわち苦味、酸味等の呈味、さらにはその他の呈味成分との共存により構成される総体としてのボディ(「コク」や「厚み」)を、「フルボディ(full-bodied)」や「ライトボディ」といった用語で表現する。具体的には、一口飲んだ時
に「口の中にしっかりとした味わいが広がる」「グッと来る」「後味が濃い」「ストロングテイスト」「重い」と感じるコーヒーをフルボディと呼び、「さらっとしている」「後味がすっきり」「ライトテイスト」「軽い」と感じるコーヒーをライトボディと呼ぶ。
(Coffee drinks)
For regular coffee that is brewed and consumed immediately at home or in a restaurant, the overall body (richness or thickness) of the coffee, which is the overall impression or weight when the coffee is held in the mouth, i.e., the tastes of bitterness, sourness, etc., as well as the coexistence of other taste components, is expressed with terms such as "full-bodied" or "light-bodied." Specifically, coffee that feels "a solid flavor spreads in the mouth,""comesback,""has a strong aftertaste,""strongtaste," or "heavy" when taken in a sip is called full-bodied, while coffee that feels "smooth,""has a clean aftertaste,""lighttaste," or "light" is called light-bodied.

本発明の飲料は、十分なボディ感が付与されたコーヒー飲料である。本発明の飲料が目標とするボディ感は、レギュラーコーヒーのフルボディのような印象や重量感である。本発明の十分なボディ感が付与されたコーヒー飲料とは、加熱殺菌前のコーヒー飲料やpH調整剤を配合しないコーヒー飲料と同程度の十分なボディ感が感じられる飲料である。本発明のコーヒー飲料は、飲料を飲み込んだ後もその余韻(後味)を楽しむことができる。 The beverage of the present invention is a coffee beverage imparted with a sufficient body. The body that the beverage of the present invention aims for is an impression and weightiness similar to that of a full-bodied regular coffee. A coffee beverage of the present invention imparted with a sufficient body is a beverage that has a sufficient body similar to that of a coffee beverage before heat sterilization or a coffee beverage that does not contain a pH adjuster. The coffee beverage of the present invention leaves an aftertaste that can be enjoyed even after swallowing the beverage.

本発明におけるコーヒー飲料は、焙煎コーヒー豆抽出物を主とするものであり、公正取引委員会が告示した「コーヒー飲料等の表示に関する公正競争規約」で規定される「コーヒー」、すなわち飲料100g中にコーヒー生豆換算で5.0g以上のコーヒー豆抽出物を含むものをいう。同規約において「コーヒー飲料」と規定される内容量100g中の生豆換算量2.5g以上5g未満のものや、「コーヒー入り清涼飲料」と規定される内容量100g中の生豆換算量1g以上2.5g未満のものは本発明のコーヒー飲料ではない。なお、同規約の第2条には以下の通りに記載されている:
「第2条 この規約で「コーヒー飲料等」とは、コーヒー豆を原料とした飲料及びこれに糖類、乳製品、乳化された食用油脂その他の可食物を加え容器に密封した飲料であって、次のいずれかに該当するものをいう。ただし、粉末飲料、飲用乳の表示に関する公正競争規約の適用を受けるもの、豆乳類の表示に関する公正競争規約の適用を受けるもの及び酒税法(昭和28年法律第6号)に規定する酒類を除く。
(1)この規約で「コーヒー」とは、内容量100グラム中にコーヒー生豆換算で5グラム以上のコーヒー豆から抽出又は溶出したコーヒー分を含むものをいう。
(2)この規約で「コーヒー飲料」とは、内容量100グラム中にコーヒー生豆換算で2.5グラム以上5グラム未満のコーヒー豆から抽出又は溶出したコーヒー分を含むものをいう。
(3)この規約で「コーヒー入り清涼飲料」とは、内容量100グラム中にコーヒー生豆換算で1グラム以上2.5グラム未満のコーヒー豆から抽出又は溶出したコーヒー分を含むものをいう。」
また、「コーヒー飲料等の表示に関する公正競争規約施行規則」の第1条には、コーヒー生豆換算の定義として、以下の通り記載されている:
「第1条 規約第2条第1項に規定するコーヒー生豆換算は、次に掲げる基準により算出する。
(1)焙煎豆を使用するときは1.3倍
(2)インスタントコーヒーを使用するときは3.0倍
(3)コーヒー抽出液を使用するときはその製造者による証明」。
The coffee beverage of the present invention is primarily made of roasted coffee bean extract, and is defined as "coffee" as defined in the "Fair Competition Code for Labeling of Coffee Beverages, etc." issued by the Japan Fair Trade Commission, i.e., a beverage containing 5.0 g or more of coffee bean extract in terms of green coffee beans per 100 g of beverage. In the same code, "coffee beverages" defined as beverages containing 2.5 g or more but less than 5 g of green coffee bean extract per 100 g of content, and "coffee-containing soft drinks" defined as beverages containing 1 g or more but less than 2.5 g of green coffee bean extract per 100 g of content, are not coffee beverages of the present invention. Article 2 of the same code states as follows:
Article 2: In these regulations, "coffee beverages, etc." refers to beverages made from coffee beans and beverages to which sugar, dairy products, emulsified edible oils and fats or other edible substances have been added and sealed in containers, and which fall under any of the following. However, this does not include powdered beverages, beverages subject to the Fair Competition Code on the Labeling of Drinking Milk, beverages subject to the Fair Competition Code on the Labeling of Soy Milk, and alcoholic beverages as stipulated in the Liquor Tax Act (Act No. 6 of 1953).
(1) In these regulations, "coffee" means a beverage that contains 5 grams or more of extracted or dissolved coffee from coffee beans, calculated as green coffee beans, per 100 grams.
(2) In these regulations, a “coffee beverage” means a beverage that contains coffee extracted or dissolved from coffee beans in an amount equivalent to 2.5 grams or more and less than 5 grams of raw coffee beans per 100 grams.
(3) In this regulation, "coffee-containing soft drinks" refers to drinks that contain coffee extracted or dissolved from coffee beans in an amount of 1 gram or more and less than 2.5 grams of raw coffee beans per 100 grams.
In addition, Article 1 of the "Fair Competition Code Enforcement Regulations for the Labeling of Coffee Drinks, etc." defines the coffee bean equivalent as follows:
"Article 1: The green coffee bean equivalent stipulated in Article 2, Paragraph 1 of the Regulations shall be calculated according to the following standards.
(1) 1.3 times when roasted beans are used; (2) 3.0 times when instant coffee is used; (3) Certification by the manufacturer when coffee extract is used.

本発明は、pH調整剤が配合され、加熱殺菌されるコーヒー飲料において不足しがちなボディ感を、飲料100gあたりのコーヒー豆抽出物の量が生豆換算で5.0g以上という高いコーヒー豆使用量と、後述のγ-アミノ酪酸の添加とにより補い、コーヒー飲料に十分なボディ感を付与したものである。 The present invention compensates for the lack of body that tends to be present in coffee beverages that contain a pH adjuster and are heat-sterilized by using a high amount of coffee beans (5.0 g or more of coffee bean extract per 100 g of beverage, calculated as green beans) and adding γ-aminobutyric acid, which will be described later, to impart sufficient body to the coffee beverage.

本発明のコーヒー飲料は、焙煎コーヒー豆抽出物を含む飲料で、そのまま摂取可能な液体形態の飲料であれば、ブラックコーヒー飲料であっても、ミルク入りコーヒー飲料であってもよい。ここで、本明細書でいうブラックコーヒー飲料とは、実質的に乳分を含まないコーヒー飲料をいい、ミルク入りコーヒー飲料とは、ミルク風味やミルク感を付与するための成分(乳分)が添加されたコーヒー飲料をいう。乳分とは、主に乳、牛乳及び乳製品のことをいい、例えば、生乳、牛乳、特別牛乳、部分脱脂乳、加工乳、クリーム、濃縮乳、無糖れん乳、全粉乳、クリームパウダー、バターミルクパウダー、調整粉乳、脱脂乳、濃縮ホエイ、脱脂濃縮乳、加糖脱脂れん乳、脱脂粉乳、ホエイパウダーなどが挙げられる。 The coffee beverage of the present invention is a beverage containing an extract of roasted coffee beans, and may be either a black coffee beverage or a coffee beverage containing milk, so long as it is in a liquid form that can be consumed as is. In this specification, a black coffee beverage refers to a coffee beverage that does not substantially contain milk, and a coffee beverage containing milk refers to a coffee beverage to which a component (milk component) for imparting a milk flavor or milky feel has been added. Milk components mainly refer to milk, milk, and dairy products, and examples of such milk components include raw milk, cow's milk, special milk, partially skimmed milk, processed milk, cream, concentrated milk, unsweetened condensed milk, whole milk powder, cream powder, buttermilk powder, adjusted milk powder, skim milk, concentrated whey, skim concentrated milk, sweetened condensed skim milk, skim milk powder, whey powder, etc.

本発明のコーヒー飲料に用いるコーヒー豆の種類は、特に限定されない。栽培樹種としては、例えば、アラビカ種、ロブスタ種、リベリカ種等が挙げられ、コーヒー品種としては、モカ、ブラジル、コロンビア、グアテマラ、ブルーマウンテン、コナ、マンデリン、キリマンジャロ等が挙げられる。コーヒー豆は1種でもよいし、複数種をブレンドして用いてもよい。本発明ではコーヒー豆を焙煎して焙煎コーヒー豆とし、焙煎コーヒー豆を抽出して焙煎コーヒー豆抽出物として飲料に用いる。なお、本明細書でいうコーヒー豆抽出物には、コーヒー豆の抽出液、及び抽出液を乾燥処理して粉末化した粉末状のものが含まれる。コーヒー豆抽出物は、常法により製造することができる。焙煎コーヒー豆の焙煎方法については特に制限はなく、焙煎温度、焙煎環境についても何ら制限はなく、通常の方法を採用できる。さらに、その焙煎コーヒー豆からの抽出方法についても何ら制限はなく、例えば焙煎コーヒー豆を粗挽き、中挽き、細挽き等に粉砕した粉砕物から水や温水(0~100℃)を用いて10秒~30分間抽出する方法が挙げられる。抽出方法は、ドリップ式、サイフォン式、ボイリング式、ジェット式、連続式などがある。 The type of coffee beans used in the coffee beverage of the present invention is not particularly limited. Examples of cultivated tree species include Arabica, Robusta, and Liberica, and examples of coffee varieties include Mocha, Brazil, Colombia, Guatemala, Blue Mountain, Kona, Mandheling, and Kilimanjaro. One type of coffee beans may be used, or multiple types may be blended. In the present invention, coffee beans are roasted to obtain roasted coffee beans, and the roasted coffee beans are extracted and used as a roasted coffee bean extract for the beverage. The coffee bean extract referred to in this specification includes coffee bean extract and powdered extract obtained by drying and powdering the extract. The coffee bean extract can be produced by a conventional method. There is no particular restriction on the roasting method of the roasted coffee beans, and there is no restriction on the roasting temperature or roasting environment, and conventional methods can be used. Furthermore, there are no limitations on the method of extraction from the roasted coffee beans, and examples include a method in which roasted coffee beans are ground into coarse, medium, fine, etc., and then extracted for 10 seconds to 30 minutes using water or hot water (0 to 100°C). Extraction methods include drip, siphon, boiling, jet, and continuous methods.

本発明のコーヒー飲料は、飲料100g中にコーヒー生豆換算で5.0g以上のコーヒー豆抽出物を含むが、コーヒー飲料中のコーヒー固形分としては、コーヒー固形物換算で0.9~1.8重量%が好ましく、0.9~1.6重量%がより好ましく、1.0~1.5重量%がさらに好ましい。ここで、コーヒー固形分とは、コーヒー原料を一般的な乾燥法(凍結乾燥、蒸発乾固など)を用いて乾燥させて水分を除いた後の、乾固物の重量のことをいう。すなわち、コーヒー飲料におけるコーヒー固形分は、コーヒー飲料に含まれ得る可溶性固形分のうち、乳分、甘味成分、pH調整剤、香料等のコーヒー豆に由来しない成分を除いた固形分をいう。コーヒー抽出液中のコーヒー固形分の含有量は、コーヒー抽出液のBrix(%)に相当し、当該Brixは、糖度計(糖用屈折計)を用いて測定することができる。 The coffee beverage of the present invention contains 5.0 g or more of coffee bean extract in terms of raw coffee beans per 100 g of beverage, and the coffee solid content in the coffee beverage is preferably 0.9 to 1.8 wt %, more preferably 0.9 to 1.6 wt %, and even more preferably 1.0 to 1.5 wt % in terms of coffee solids. Here, the coffee solid content refers to the weight of the dried matter after the coffee raw material is dried using a general drying method (freeze drying, evaporation to dryness, etc.) to remove moisture. In other words, the coffee solid content in the coffee beverage refers to the solid content of the soluble solids that may be contained in the coffee beverage, excluding components that are not derived from coffee beans, such as milk, sweet components, pH adjusters, and flavorings. The content of the coffee solid content in the coffee extract corresponds to the Brix (%) of the coffee extract, and the Brix can be measured using a saccharometer (refractometer for sugar).

(γ-アミノ酪酸)
本発明は、γ-アミノ酪酸(γ-aminobutyric acid, 以下「GABA」と略記する)を添加することにより容器詰コーヒー飲料のボディ感を増強する。
(γ-aminobutyric acid)
The present invention enhances the body of a packaged coffee beverage by adding γ-aminobutyric acid (hereinafter abbreviated as "GABA").

GABAは、野菜類、果物類、穀類、発酵食品等に幅広く含まれるアミノ酸の一種である。本発明に用いられるGABAとしては、特に限定されるものではなく、例えば野菜類、果物類、穀類などから抽出されたGABA、醗酵により生産されたGABA、有機合成により得られたGABA等を用いることができる。飲料自体の香味への影響を最小限にして本発明の効果を享受するために、本発明の飲料に用いるGABAとしては、GABAを80質量%以上、好ましくは85質量%以上、より好ましくは90質量%以上含有するGABAの精製品を使用することが好ましい。精製品の形態としては、固体、水溶液、スラリー状など種々のものを用いることができる。市販されているGABAの精製品としては、GABA100%ピュアパウダー(NOW FOODS社)、オリザギャバ(登録商標)エキスHC-90(オリザ油化社)などがある。 GABA is a type of amino acid that is widely contained in vegetables, fruits, grains, fermented foods, etc. The GABA used in the present invention is not particularly limited, and may be, for example, GABA extracted from vegetables, fruits, grains, etc., GABA produced by fermentation, GABA obtained by organic synthesis, etc. In order to enjoy the effects of the present invention while minimizing the influence on the flavor of the beverage itself, it is preferable to use a refined product of GABA containing 80% by mass or more, preferably 85% by mass or more, and more preferably 90% by mass or more of GABA as the GABA used in the beverage of the present invention. The refined product may be in various forms such as a solid, an aqueous solution, or a slurry. Commercially available refined products of GABA include GABA 100% pure powder (NOW FOODS Co., Ltd.), Oryza GABA (registered trademark) Extract HC-90 (Oryza Oil & Fat Chemical Co., Ltd.), etc.

本発明においては、飲料中のGABAの濃度が11mg/100g以上、好ましくは15mg/100g以上、さらに好ましくは20mg/100g以上、特に好ましくは25mg/100g以上となるように添加する。GABAの含有量が11mg/100gに満たない場合は、本発明の効果が十分に得られないことがある。また、GABAの含有量は70mg/100g以下が好ましく、65mg/100g以下がより好ましく、60mg/100g以下がさらに好ましい。GABAの含有量は、アミノ酸分析装置を用いて測定することができる。 In the present invention, GABA is added so that the concentration of GABA in the beverage is 11 mg/100 g or more, preferably 15 mg/100 g or more, more preferably 20 mg/100 g or more, and particularly preferably 25 mg/100 g or more. If the GABA content is less than 11 mg/100 g, the effects of the present invention may not be fully obtained. In addition, the GABA content is preferably 70 mg/100 g or less, more preferably 65 mg/100 g or less, and even more preferably 60 mg/100 g or less. The GABA content can be measured using an amino acid analyzer.

(容器詰コーヒー飲料)
本発明のコーヒー飲料は、小売店や自動販売機で提供されるRTD(READY TO
DRINK)タイプの容器詰コーヒー飲料である。本発明のコーヒー飲料に使用される容器は、一般のRTD対応の飲料用の容器と同様に、ポリエチレンテレフタレートを主成分とする成形容器(いわゆるPETボトル)、金属缶、金属箔やプラスチックフィルムと複合された紙容器、瓶などであり、本発明のコーヒー飲料はこれらに詰めた通常の形態で提供することができる。容器内のコーヒー飲料の容量は、特に限定されないが、例えば150mL~1000mLであり、好ましくは190mL~800mLである。
(Packaged coffee drink)
The coffee beverage of the present invention is a ready-to-drink (RTD) beverage provided at retail stores or vending machines.
The container used for the coffee beverage of the present invention is, like general RTD beverage containers, a molded container mainly made of polyethylene terephthalate (so-called PET bottle), a metal can, a paper container combined with metal foil or plastic film, a bottle, etc., and the coffee beverage of the present invention can be provided in a normal form packed in these. The volume of the coffee beverage in the container is not particularly limited, but is, for example, 150 mL to 1000 mL, and preferably 190 mL to 800 mL.

(pH調整剤)
常温で長期保存可能な容器詰コーヒー飲料には、通常、殺菌時におけるpH低下を緩和する目的でpH調整剤が配合される。このpH調整剤に由来する塩味、ぬめり、キレ味の悪さがコーヒー飲料本来の香味を損ない、コーヒー飲料のボディ感を低下させる一因となり得る。本発明のコーヒー飲料は、飲料100g中にコーヒー生豆換算で5.0g以上のコーヒー豆抽出物を含むという高いコーヒー豆使用量と、一定範囲の量のγ-アミノ酪酸の添加とにより、十分なボディ感が付与される。したがって、本来ボディ感が不足しがちなpH調整剤が配合されたコーヒー飲料は、本発明によりボディ感の不足を補うことができ、本発明の効果を顕著に享受できる観点から、好ましい態様である。pH調整剤としては、殺菌時におけるpH低下を緩和しうる成分で、水に溶解した時にアルカリ性を示す物質、具体的には、炭酸水素ナトリウム(重曹)、水酸化ナトリウム、炭酸カリウム、水酸化カリウム、リン酸三ナトリウム、リン酸三カリウムなどが用いられる。本発明のコーヒー飲料はのpHは、5.0~7.0であることが好ましく、5.3~6.8であることがより好ましく、5.3~6.5であることがさらに好ましい。
(pH adjuster)
A pH adjuster is usually blended in a packaged coffee beverage that can be stored for a long time at room temperature in order to mitigate the pH drop that occurs during sterilization. The salty taste, sliminess, and poor sharpness that result from this pH adjuster can impair the original aroma and flavor of the coffee beverage, and can be a factor in reducing the fullness of the coffee beverage. The coffee beverage of the present invention is imparted with a sufficient fullness by using a high amount of coffee beans, i.e., 5.0 g or more of coffee bean extract in terms of green coffee beans per 100 g of beverage, and adding a certain amount of γ-aminobutyric acid. Therefore, a coffee beverage that is blended with a pH adjuster that tends to lack fullness is a preferred embodiment from the viewpoint of being able to make up for the lack of fullness by the present invention and to significantly enjoy the effects of the present invention. The pH adjuster is a component that can mitigate the pH drop that occurs during sterilization, and is a substance that exhibits alkalinity when dissolved in water, specifically, sodium hydrogen carbonate (baking soda), sodium hydroxide, potassium carbonate, potassium hydroxide, trisodium phosphate, tripotassium phosphate, etc. The pH of the coffee beverage of the present invention is preferably 5.0 to 7.0, more preferably 5.3 to 6.8, and even more preferably 5.3 to 6.5.

(加熱殺菌済飲料)
容器詰コーヒー飲料は、製造時に過酷な加熱殺菌が行われるため、加水分解を主とする化学変化が起こり、コーヒー飲料の香味が変化してボディ感が低減することが知られている。本発明のコーヒー飲料は、このような加熱処理をしたコーヒー飲料のボディ感の不足を補強し得ることから、加熱処理、すなわち加熱殺菌済のコーヒー飲料は本発明の飲料の好適な態様である。加熱処理の条件は、例えば、食品衛生法に定められた条件と同等の効果が得られる方法を選択することができ、具体的には、60~150℃、好ましくは90
~150℃、より好ましくは110~150℃で、1秒間~60分間、好ましくは1秒間~30分間とすることができる。より詳細には、容器として耐熱性容器(金属缶、ガラス等)を使用する場合には、レトルト殺菌(110~140℃、1~数十分間)を行えばよい。また、容器として非耐熱性容器(PETボトル、紙容器等)を用いる場合は、例えば、調合液を予めプレート式熱交換器等で高温短時間殺菌後(UHT殺菌:110~150℃、1~数十秒間)し、一定の温度まで冷却した後、その非耐熱性容器に充填することができる。本発明の所期の効果を顕著に発現することから、加熱処理が、100℃を超える過酷な加熱条件の加熱殺菌済のコーヒー飲料は本発明の飲料の特に好適な態様である。
(Heat-sterilized beverages)
It is known that packaged coffee beverages undergo severe heat sterilization during production, which causes chemical reactions, primarily hydrolysis, that change the flavor and aroma of the coffee beverage and reduce its body. The coffee beverage of the present invention can make up for the lack of body in such heat-treated coffee beverages, and thus a heat-treated, i.e. heat-sterilized, coffee beverage is a preferred embodiment of the beverage of the present invention. Heat treatment conditions can be selected from methods that provide the same effects as those stipulated in the Food Sanitation Act, and specifically, a temperature of 60 to 150°C, preferably 90
The sterilization time can be set to 150°C, more preferably 110-150°C, for 1 second to 60 minutes, preferably 1 second to 30 minutes. More specifically, when a heat-resistant container (metal can, glass, etc.) is used as the container, retort sterilization (110-140°C, 1 to several tens of minutes) can be performed. When a non-heat-resistant container (PET bottle, paper container, etc.) is used as the container, for example, the prepared liquid can be sterilized at high temperature for a short time in a plate-type heat exchanger or the like (UHT sterilization: 110-150°C, 1 to several tens of seconds), cooled to a certain temperature, and then filled into the non-heat-resistant container. A heat-sterilized coffee beverage, in which the heat treatment is performed under harsh heating conditions exceeding 100°C, is a particularly preferred embodiment of the beverage of the present invention, since it significantly exhibits the desired effects of the present invention.

(その他成分)
その他、本発明の飲料には、本発明の所期の目的を逸脱しない範囲であれば、上記成分に加え、飲料に一般的に配合される成分、例えば、甘味成分、酸化防止剤(エリソルビン酸ナトリウムなど)、香料、ビタミン、乳化剤、増粘安定剤等を適宜添加することができる。
(Other ingredients)
In addition to the above-mentioned components, the beverage of the present invention may contain appropriate components that are generally blended into beverages, such as sweeteners, antioxidants (such as sodium erythorbate), flavorings, vitamins, emulsifiers, thickening stabilizers, etc., so long as the blend does not deviate from the intended object of the present invention.

ここで、甘味成分とは甘味を呈する成分のことをいう。具体的には、黒砂糖、白下糖、カソナード(赤砂糖)、和三盆、ソルガム糖、メープルシュガーなどの含蜜糖、ザラメ糖(白双糖、中双糖、グラニュー糖など)、車糖(上白糖、三温糖など)、加工糖(角砂糖、氷砂糖、粉砂糖、顆粒糖など)、液糖などの精製糖、単糖類(ぶどう糖、果糖、木糖、ソルボース、ガラクトース、異性化糖など)、二糖類(蔗糖 、麦芽糖、乳糖、異性化乳
糖、パラチノースなど)、オリゴ糖類(フラクトオリゴ糖、マルトオリゴ糖、イソマルトオリゴ糖、ガラクトオリゴ糖、カップリングシュガーなど)、糖アルコール類(エリスリトール、ソルビトール、キシリトール、マンニトール、マルチトール、イソマルチトール、ラクチトール、マルトトリイトール、イソマルトトリイトール、パニトール、オリゴ糖アルコール、粉末還元麦芽糖水飴)などのような糖質甘味料の他、天然非糖質甘味料(ステビア抽出物、カンゾウ抽出物等)や合成非糖質甘味料(アスパルテーム、アセスルファムK等)のような高甘味度甘味料などの甘味料が挙げられる。中でも、アセスルファムカリウム及びステビア抽出物から選択される1種以上の甘味料を使用したコーヒー飲料は、本発明の効果の顕著さから、好適な態様である。
Here, the sweetening component refers to a component that exhibits sweetness. Specifically, molasses sugars such as brown sugar, shiroshitato, cassonade (brown sugar), wasanbon, sorghum sugar, maple sugar, etc., granulated sugar (white double sugar, medium double sugar, granulated sugar, etc.), processed sugar (sugar cubes, crystal sugar, powdered sugar, granulated sugar, etc.), refined sugars such as liquid sugar, monosaccharides (glucose, fructose, wood sugar, sorbose, galactose, isomerized sugar, etc.), disaccharides (sucrose, etc.), , maltose, lactose, isomerized lactose, palatinose, etc.), oligosaccharides (fructooligosaccharides, maltooligosaccharides, isomaltooligosaccharides, galactooligosaccharides, coupling sugar, etc.), sugar alcohols (erythritol, sorbitol, xylitol, mannitol, maltitol, isomaltitol, lactitol, maltotriitol, isomaltotriitol, panitol, oligosaccharide alcohols, powdered reduced maltose syrup), etc., as well as high-intensity sweeteners such as natural non-sugar sweeteners (stevia extract, licorice extract, etc.) and synthetic non-sugar sweeteners (aspartame, acesulfame K, etc.). Among these, a coffee beverage using one or more sweeteners selected from acesulfame potassium and stevia extract is a preferred embodiment due to the remarkable effects of the present invention.

(製造方法)
本発明のコーヒー飲料は、原料としてGABAを配合する以外は、通常のコーヒー飲料と同じようにして製造することができる。すなわち、焙煎コーヒー豆抽出物とGABAとを混合して調合液を調製する工程、pH調整剤を配合して調合液のpHを5.0~7.0に調整する工程、調合液を容器に充填する工程、加熱殺菌する工程を含む工程により製造される。
(Production method)
The coffee beverage of the present invention can be produced in the same manner as a normal coffee beverage, except that GABA is added as a raw material, that is, by a process including a step of mixing a roasted coffee bean extract and GABA to prepare a preparation, a step of adding a pH adjuster to adjust the pH of the preparation to 5.0 to 7.0, a step of filling the preparation into a container, and a step of heat sterilization.

本発明のコーヒー飲料は、コーヒー豆の使用量が高い飲料である。本発明の飲料がブラックコーヒー飲料である場合、製造時や保存中のコーヒー成分の凝集、沈殿を抑制する目的で、調合液を清澄濾過工程に供してもよい。濾過機は、特に制限されるものではないが、例えば、フィルターカートリッジや、膜を用いた方法が挙げられる。フィルターカートリッジを用いた濾過工程では、コーヒーのボディ感を創出するのに重要な成分であるコーヒー油分が吸着除去されることがあり、容器詰コーヒー飲料のボディ感が一層低減することが知られている。本発明のコーヒー飲料は、このような清澄濾過工程を経たコーヒー飲料のボディ感の不足を補強し得ることから、清澄濾過工程を含む工程を経て製造されるブラックコーヒー飲料は、本発明の好適な態様の一つである。フィルターカートリッジとしては、ポリプロピレン等の不織布等を素材として用いて作製し、固形分を物理的な捕捉のみで取り除くことができるフィルター(例えば、住友スリーエム社製のPPK-010、PPK-005等)や、素材の吸着作用によって取り除くことができるフィルター(例えば、住友スリーエム社製のゼータプラス(登録商標)30C、ゼータプラス(登録商標)
50C等、フィルテック社製のNA45KS、NA60KS、NA90KS、NA150KS、NA300KS等)を用いることができる。
The coffee beverage of the present invention is a beverage that uses a large amount of coffee beans. When the beverage of the present invention is a black coffee beverage, the prepared liquid may be subjected to a clarifying filtration step in order to suppress aggregation and precipitation of coffee components during production or storage. The filter is not particularly limited, and examples thereof include a method using a filter cartridge or a membrane. It is known that a filtration step using a filter cartridge may adsorb and remove coffee oil, which is an important component for creating the full-bodied feel of coffee, and further reduce the full-bodied feel of the packaged coffee beverage. The coffee beverage of the present invention can compensate for the lack of full-bodied feel of a coffee beverage that has been subjected to such a clarifying filtration step, and therefore a black coffee beverage produced through a process including a clarifying filtration step is one of the preferred embodiments of the present invention. Filter cartridges are made of nonwoven fabric such as polypropylene and can remove solids only by physical capture (e.g., PPK-010, PPK-005, etc., manufactured by Sumitomo 3M) or can remove solids by the adsorption action of the material (e.g., ZetaPlus (registered trademark) 30C, ZetaPlus (registered trademark), manufactured by Sumitomo 3M).
50C, and NA45KS, NA60KS, NA90KS, NA150KS, NA300KS, etc. manufactured by Filtech.

本発明のコーヒー飲料がミルク入りコーヒー飲料である場合、通常、加熱殺菌する工程の前に、均質化処理工程を含む。この均質化処理により、加熱殺菌時及び保存時の乳分の分離が抑制できるが、乳分の脂肪球の粒子径が1μm以下程度にまで微細化されるために、ボディ感がより不足しやすくなる。本発明のコーヒー飲料は、このような均質化処理を経たコーヒー飲料のボディ感の不足を補強し得ることから、均質化処理を経て製造されるミルク入りコーヒー飲料は、本発明の好適な態様の一つである。均質化処理は、高圧ホモジナイザーなどの均質機を用いて行うことができる。均質化する際の圧力は、特に制限されないが、通常10~50MPa、好ましくは10~40MPa、さらに好ましくは10~30MPa程度である。均質化処理を行う際の温度としては、30~70℃、好ましくは40~70℃の温度を挙げることができる。 When the coffee beverage of the present invention is a coffee beverage containing milk, a homogenization process is usually included before the heat sterilization process. This homogenization process can suppress separation of the milk content during heat sterilization and storage, but since the particle size of the milk fat globules is reduced to about 1 μm or less, the body is more likely to be lacking. The coffee beverage of the present invention can compensate for the lack of body of the coffee beverage that has been subjected to such a homogenization process, so that a milk-containing coffee beverage produced through a homogenization process is one of the preferred embodiments of the present invention. The homogenization process can be performed using a homogenizing machine such as a high-pressure homogenizer. The pressure during homogenization is not particularly limited, but is usually about 10 to 50 MPa, preferably 10 to 40 MPa, and more preferably about 10 to 30 MPa. The temperature during the homogenization process can be 30 to 70°C, preferably 40 to 70°C.

以下、実験例を示して本発明の詳細を具体的に説明するが、本発明はこれに限定されるものではない。また、本明細書において、特に記載しない限り、数値範囲はその端点を含むものとして記載される。 The details of the present invention will be specifically explained below with reference to experimental examples, but the present invention is not limited thereto. Furthermore, in this specification, unless otherwise specified, numerical ranges are stated to include their endpoints.

実験例1 無糖コーヒー飲料の調製(1)
焙煎度L値18のアラビカ種コーヒー豆を中挽きに粉砕した後、コーヒー豆の重量の約14倍の重量の95℃の熱水でドリップ抽出を行った。抽出終了後は抽出液を速やかに25℃以下程度まで冷却し、遠心分離(クラリファイアー)により抽出後のコーヒー豆の固液分離を行って焙煎コーヒー豆抽出液を調製した(対照品1:Brix 1.3、pH5
.8)。また、このコーヒー豆抽出液をポリプロピレン不織布のフィルターカートリッジを用いて清澄濾過したコーヒー豆抽出液を調製した(対照品2:Brix 1.3、pH
5.8)。さらに、対照品2にpHが6.6になるように炭酸水素ナトリウムを添加したコーヒー飲料を調製し(対照品3:Brix 1.3、pH6.6)、このコーヒー飲料
185gを190mL用缶に充填し、レトルト殺菌(130℃、5分)を行い、容器詰コーヒー飲料を製造した(対照品4:Brix 1.3、pH6.2)。
Experimental Example 1 Preparation of sugar-free coffee drink (1)
Arabica coffee beans with a roasting level L value of 18 were ground to a medium grind and then drip-extracted with 95°C hot water in an amount approximately 14 times the weight of the coffee beans. After extraction, the extract was quickly cooled to 25°C or less, and the extracted coffee beans were subjected to solid-liquid separation using a centrifuge (clarifier) to prepare a roasted coffee bean extract (Control 1: Brix 1.3, pH 5.0).
.8). In addition, this coffee bean extract was filtered through a polypropylene nonwoven filter cartridge to prepare a coffee bean extract (Control Product 2: Brix 1.3, pH 7.0).
5.8). Furthermore, a coffee beverage was prepared by adding sodium bicarbonate to Control Product 2 so that the pH was 6.6 (Control Product 3: Brix 1.3, pH 6.6), and 185 g of this coffee beverage was filled into a 190 mL can and subjected to retort sterilization (130°C, 5 minutes) to produce a packaged coffee beverage (Control Product 4: Brix 1.3, pH 6.2).

得られた対照品1~4について、専門パネル5名による官能評価を行った。パネルは、提示されたペアのうちどちらの飲料がボディ感をより強く感じるか、2点識別試験により評価した。結果を表1に示す。ボディ感は、対照品1>対照品2>対照品3>対照品4の順に低下した。これより、容器詰コーヒー飲料の製造におけるポリプロピレン不織布等を用いた清澄濾過工程、pH調整剤の添加工程、加熱殺菌工程の各工程によりボディ感が低減することが示唆された。 A sensory evaluation of the obtained control products 1 to 4 was conducted by a panel of five experts. The panel used a two-point discrimination test to evaluate which of the pairs of beverages presented had a stronger full body. The results are shown in Table 1. The full body decreased in the following order: Control product 1 > Control product 2 > Control product 3 > Control product 4. This suggests that the full body is reduced by each of the following steps in the production of packaged coffee beverages: the clarification filtration process using polypropylene nonwoven fabric, the process of adding a pH adjuster, and the heat sterilization process.

Figure 0007518982000001
Figure 0007518982000001

実験例2 無糖コーヒー飲料の調製(2)
GABAを配合すること以外は、実験例1と同様にして容器詰コーヒー飲料を製造した
。具体的には、焙煎度L値18のアラビカ種コーヒー豆を中挽きに粉砕した後、コーヒー豆の重量の約14倍の重量の95℃の熱水でドリップ抽出を行った。抽出終了後は抽出液を速やかに25℃以下程度まで冷却し、遠心分離(クラリファイアー)により抽出後のコーヒー豆の固液分離を行い、さらにポリプロピレン不織布のフィルターカートリッジを用いて清澄濾過し、焙煎コーヒー豆の抽出物(Brix 1.3、pH5.8)を得た。こ
の焙煎コーヒー豆の抽出物に、γ-アミノ酪酸(GABA)の含有量が5~80mg/100gの濃度となるようにGABA(純度99%以上)を添加し、pHが6.6になるように炭酸水素ナトリウム(pH調整剤)を添加してよく攪拌し、飲料100g中にコーヒー生豆換算で6.3gのコーヒー豆抽出物を含むブラックコーヒー飲料を得た。この飲料185gを190mL用缶に充填し、レトルト殺菌(130℃、5分)を行い、容器詰コーヒー飲料を製造した。
Experimental Example 2 Preparation of sugar-free coffee drink (2)
A packaged coffee beverage was produced in the same manner as in Experimental Example 1, except that GABA was added. Specifically, Arabica coffee beans with a roasting degree L value of 18 were ground to medium grinding, and then drip-extracted with hot water at 95°C in an amount approximately 14 times the weight of the coffee beans. After the extraction was completed, the extract was quickly cooled to about 25°C or less, and the extracted coffee beans were subjected to solid-liquid separation by centrifugation (clarifier), and further clarified and filtered using a filter cartridge made of polypropylene nonwoven fabric to obtain an extract of roasted coffee beans (Brix 1.3, pH 5.8). GABA (purity 99% or more) was added to this extract of roasted coffee beans so that the content of γ-aminobutyric acid (GABA) was 5 to 80 mg/100 g, and sodium bicarbonate (pH adjuster) was added to the extract so that the pH was 6.6, and the mixture was thoroughly stirred to obtain a black coffee beverage containing 6.3 g of coffee bean extract in terms of raw coffee beans per 100 g of beverage. 185 g of this beverage was filled into a 190 mL can and subjected to retort sterilization (130° C., 5 minutes) to produce a packaged coffee beverage.

得られた容器詰コーヒー飲料について、専門パネル5名による官能評価を行った。評価は、実験例1の対照品1(未殺菌でpH調整剤が添加されていない、所謂レギュラーコーヒー)のボディ感を評点3、対照品4(pH調整剤を添加した清澄濾過済みの焙煎コーヒー豆の抽出物を用い、かつGABAを配合していない加熱殺菌済の容器詰コーヒー飲料)のボディ感を評点1として、パネル間で基準合わせを行った後に実施した。各容器詰コーヒー飲料について、対照品4(GABA無添加品)と差がないボディ感であり、評点1に近い飲料を「N(=no difference)」、対照品4よりもボディ感が大きく付与され評点3のフルボディに近づいた飲料を「B(=big difference)」、対照品4よりも若干のボデ
ィ感が付与された飲料を「A(=a difference)」として、それぞれパネルの人数をカウ
ントした。
The resulting packaged coffee beverages were subjected to a sensory evaluation by a panel of five experts. The evaluation was performed after the panels were standardized by assigning a score of 3 to the body of Control Product 1 (a so-called regular coffee that is unsterilized and does not contain a pH adjuster) in Experimental Example 1, and a score of 1 to the body of Control Product 4 (a packaged coffee beverage that uses a filtered roasted coffee bean extract to which a pH adjuster has been added and is heat-sterilized and does not contain GABA). For each packaged coffee beverage, a beverage that had a body that was no different from Control Product 4 (a product without added GABA) and was close to score 1 was assigned an "N (=no difference)," a beverage that had a larger body than Control Product 4 and was close to the full-bodied score of 3 was assigned an "B (=big difference)," and a beverage that had a slightly more body than Control Product 4 was assigned an "A (=a difference)," and the number of panelists was counted for each score.

結果を表2に示す。GABA含有量が11~80mg/100gとなるようにGABAを添加することにより、容器詰コーヒー飲料にボディ感が付与されることが示された。特に、飲料中のGABA含有量が25mg/100g以上となるGABAを添加した場合には、パネルの半数以上が「B(=big difference)」を選択し、明らかにボディ感が強く
なったと評価した。GABA0~80mg/100gの容器詰コーヒー飲料のうち、最もボディ感が強いと感じるサンプルをブラインドテストしたところ、GABA含有量:50mg/100gが1人、GABA含有量:80mg/100gが4人であった。一方で、50mg/100g以上の添加では、ボディ感の強さに大きな差がないこと、GABA含有量が80mg/100gでは、GABA由来の酸味を感じるパネルが存在したことから、GABAの上限は70mg/100g程度が好ましいことが示された。
The results are shown in Table 2. It was shown that adding GABA to give a GABA content of 11 to 80 mg/100 g gave a full-bodied feel to the packaged coffee beverage. In particular, when GABA was added so that the GABA content in the beverage was 25 mg/100 g or more, more than half of the panel members selected "B (=big difference)," indicating that the beverage had a clearly stronger full-bodied feel. In a blind test of packaged coffee beverages with GABA content of 0 to 80 mg/100 g, one panel member felt that the beverage had the most full-bodied feel, and four panel members felt that the beverage had a GABA content of 50 mg/100 g and 80 mg/100 g, respectively. On the other hand, when 50 mg/100 g or more was added, there was no significant difference in the intensity of the body sensation, and at a GABA content of 80 mg/100 g, some panels sensed a sour taste derived from GABA, indicating that an upper limit of GABA is preferably around 70 mg/100 g.

Figure 0007518982000002
Figure 0007518982000002

実験例3 ミルク入りコーヒー飲料の調製(1)
焙煎度L値20のアラビカ種コーヒー豆を細挽きに粉砕した後、攪拌を行いながら、コーヒー豆の重量の約10倍の重量の90℃の熱水で、15分間抽出を行った。抽出終了後、市販の紙製の濾過フィルターで抽出液を濾過し、濾液を速やかに25℃以下程度まで冷却した。得られた焙煎コーヒー豆抽出液のBrixは2.3であり、抽出率は25%であった。このコーヒー豆抽出液と、適量の水と、表3に示す処方の甘味成分(ショ糖、アセスルファムカリウム)及びpH調整剤とを加えて完全に溶解させた後、乳化剤、牛乳、香料を加えて調合液とした(「調合液(未殺菌)」)。この調合液をホモゲナイズ処理(1次圧150kg/cm、2次圧50kg/cm)して均質化した(「調合液のホモゲナイズ処理液(未殺菌)」)。このホモゲナイズ処理液を、90℃に昇温後、190mL缶に充填し、レトルト殺菌(124℃、20分)を行い、飲料100g中にコーヒー生豆換算で5.1gのコーヒー豆抽出物を含む容器詰ミルク入りコーヒー飲料(加熱殺菌済み、pH6.3)を製造した。
Experimental Example 3 Preparation of coffee drink with milk (1)
Arabica coffee beans with a roasting degree L value of 20 were finely ground, and then extracted with hot water at 90° C., about 10 times the weight of the coffee beans, for 15 minutes while stirring. After the extraction, the extract was filtered with a commercially available paper filter, and the filtrate was quickly cooled to about 25° C. or less. The Brix of the obtained roasted coffee bean extract was 2.3, and the extraction rate was 25%. This coffee bean extract was added to an appropriate amount of water, and the sweetening components (sucrose, acesulfame potassium) and pH adjuster in the formulation shown in Table 3 were completely dissolved, and then an emulsifier, milk, and flavoring were added to prepare a preparation ("preparation (unsterilized)"). This preparation was homogenized (primary pressure 150 kg/cm 2 , secondary pressure 50 kg/cm 2 ) ("homogenized preparation (unsterilized)"). This homogenized liquid was heated to 90°C, filled into 190 mL cans, and subjected to retort sterilization (124°C, 20 minutes) to produce a packaged milk-added coffee beverage (heat-sterilized, pH 6.3) containing 5.1 g of coffee bean extract, calculated as green coffee beans, per 100 g of beverage.

Figure 0007518982000003
Figure 0007518982000003

上記の調合液(未殺菌)、調合液のホモゲナイズ処理液(未殺菌)、及び容器詰ミルク入りコーヒー飲料(加熱殺菌済)について、専門パネル5名による官能評価を行った。パ
ネルは、提示されたペアのうちどちらの飲料がボディ感をより強く感じるか、2点識別試験により評価した。結果を表4に示す。ボディ感は、調合液>ホモゲナイズ処理液>容器詰ミルク入りコーヒー飲料(加熱殺菌済)の順に低下した。これより、容器詰ミルク入りコーヒー飲料の製造における均質化処理工程、加熱殺菌工程の各工程によりボディ感が低減することが示唆された。
A sensory evaluation was conducted by a panel of five experts on the above-mentioned prepared liquid (unsterilized), the homogenized prepared liquid (unsterilized), and the packaged coffee beverage with milk (sterilized by heat). The panel used a two-point discrimination test to evaluate which of the pairs of beverages presented had a stronger sense of body. The results are shown in Table 4. The sense of body decreased in the following order: prepared liquid > homogenized liquid > packaged coffee beverage with milk (sterilized by heat). This suggests that the sense of body is reduced by the homogenization process and the heat sterilization process in the production of packaged coffee beverage with milk.

Figure 0007518982000004
Figure 0007518982000004

実験例4 ミルク入りコーヒー飲料の調製(2)
GABAを配合すること以外は、実験例3と同様にして容器詰ミルク入りコーヒー飲料を製造した。具体的には、焙煎度L値20のアラビカ種コーヒー豆を細挽きに粉砕した後、攪拌を行いながら、コーヒー豆の重量の約10倍の重量の90℃の熱水で、15分間抽出を行った。抽出終了後、市販の紙製の濾過フィルターで抽出液を濾過し、濾液を速やかに25℃以下程度まで冷却した。このコーヒー豆抽出液(Brixは2.3)に表5に示すGABAを含む各種成分を加えて調合液とした。この調合液をホモゲナイズ処理(1次圧150kg/cm、2次圧50kg/cm)して均質化し、90℃に昇温後、190mL缶に充填し、レトルト殺菌(124℃、20分)を行い、飲料100g中にコーヒー生豆換算で5.1gのコーヒー豆抽出物を含む容器詰ミルク入りコーヒー飲料(pH6.3)を製造した。
Experimental Example 4 Preparation of coffee drink with milk (2)
A packaged coffee drink with milk was produced in the same manner as in Experimental Example 3, except that GABA was added. Specifically, Arabica coffee beans with a roasting degree L value of 20 were finely ground and then extracted for 15 minutes with 90°C hot water of about 10 times the weight of the coffee beans while stirring. After extraction, the extract was filtered with a commercially available paper filter, and the filtrate was quickly cooled to about 25°C or less. Various components including GABA shown in Table 5 were added to this coffee bean extract (Brix is 2.3) to prepare a mixed liquid. This prepared liquid was homogenized (primary pressure 150 kg/ cm2 , secondary pressure 50 kg/ cm2 ), heated to 90°C, filled into 190 mL cans, and subjected to retort sterilization (124°C, 20 minutes) to produce a packaged milk-added coffee beverage (pH 6.3) containing 5.1 g of coffee bean extract, calculated as green coffee beans, per 100 g of beverage.

Figure 0007518982000005
Figure 0007518982000005

得られた容器詰ミルク入りコーヒー飲料について、専門パネル5名による官能評価を行った。評価は、実験例3の調合液(未殺菌)のボディ感を評点3、実験例3の容器詰ミルク入りコーヒー飲料(GABAを配合していない加熱殺菌済の容器詰コーヒー飲料)のボディ感を評点1として、パネル間で基準合わせを行った後に実施した。各容器詰ミルク入りコーヒー飲料について、GABA無添加の実験例3の容器詰ミルク入りコーヒー飲料(加熱殺菌済み)と差がないボディ感であり、評点1に近い飲料を「N(=no difference)
」、上記のGABA無添加品よりもボディ感が大きく付与され評点3のフルボディに近づいた飲料を「B(=big difference)」、GABA無添加品よりも若干のボディ感が付与
された飲料を「A(=a difference)」として、それぞれパネルの人数をカウントした。
A sensory evaluation was conducted by a panel of five experts on the obtained packaged coffee beverages with milk. The evaluation was conducted after the panels standardized their evaluation, with the body of the preparation of Experimental Example 3 (unpasteurized) being given a score of 3, and the body of the packaged coffee beverage with milk of Experimental Example 3 (a packaged coffee beverage that has not been blended with GABA and has been heat-sterilized) being given a score of 1. For each packaged coffee beverage with milk, beverages that had a body that was no different from the packaged coffee beverage with milk of Experimental Example 3 (heat-sterilized) without added GABA and were close to a score of 1 were rated as "N (=no difference)
The number of panelists for each category was counted, with drinks that had a greater body than the GABA-free drink and were closer to a full-bodied rating of 3 given a "B (=big difference)" and drinks that had slightly more body than the GABA-free drink given an "A (=a difference)."

結果を表6に示す。容器詰ミルク入りコーヒー飲料の場合も、GABA含有量が11~80mg/100gとなるようにGABAを添加することにより、ボディ感が付与されることが示された。特に、飲料中のGABA含有量が25mg/100g以上となるGABAを添加した場合には、パネルの半数以上が「B(=big difference)」を選択し、明ら
かにボディ感が強くなった、複雑味が付与されたと評価した。GABA0~80mg/100gの容器詰ミルク入りコーヒー飲料のうち、最もボディ感が強いと感じるサンプルをブラインドテストしたところ、GABA含有量:70mg/100gが1人、GABA含有量:80mg/100gが4人であった。一方で、70mg/100gと80mg/100gとでは、パネル全員がボディ感の強さに大差がないとも評価したことから、経済的観点も加味してGABAの上限は70mg/100g程度が好ましいことがわかった。
The results are shown in Table 6. In the case of packaged coffee beverages with milk, it was shown that adding GABA to the beverage so that the GABA content was 11 to 80 mg/100 g gave the beverage a full-bodied feel. In particular, when GABA was added so that the GABA content in the beverage was 25 mg/100 g or more, more than half of the panelists selected "B (=big difference)," and evaluated that the beverage had a clearly stronger full-bodied feel and a complex flavor. In a blind test of packaged coffee beverages with milk containing 0 to 80 mg/100 g of GABA, the sample that was felt to have the strongest full-bodied feel was chosen by one panelist for a GABA content of 70 mg/100 g and by four panels for a GABA content of 80 mg/100 g. On the other hand, all panelists rated that there was not much difference in the intensity of the body sensation between 70 mg/100 g and 80 mg/100 g, and therefore, taking into account economic considerations, it was found that the upper limit of GABA is preferably around 70 mg/100 g.

Figure 0007518982000006
Figure 0007518982000006

実験例5 ミルク入りコーヒー飲料の調製(3)
コーヒー飲料の処方を表7に変える以外は、実験例4と同様にして容器詰ミルク入りコーヒー飲料を製造した。飲料100g中のコーヒー豆抽出物の量はコーヒー生豆換算で5.5gであった。得られた飲料について、実験例3の調合液(未殺菌)と実験例3の容器詰ミルク入りコーヒー飲料(加熱殺菌済み)を基準として、実験例4と同様にボディ感を評価した。結果を表8に示す。甘味成分等の処方が変わった場合にも、GABA含有量が11mg/100g以上となるようにGABAを添加することにより、ボディ感が付与されることが確認できた。
Experimental Example 5 Preparation of coffee drink with milk (3)
A packaged coffee beverage with milk was produced in the same manner as in Experimental Example 4, except that the formulation of the coffee beverage was changed to that shown in Table 7. The amount of coffee bean extract per 100 g of beverage was 5.5 g calculated as green coffee beans. The body of the obtained beverage was evaluated in the same manner as in Experimental Example 4, using the prepared liquid of Experimental Example 3 (unsterilized) and the packaged coffee beverage with milk of Experimental Example 3 (heat-sterilized) as standards. The results are shown in Table 8. It was confirmed that a body was imparted by adding GABA so that the GABA content was 11 mg/100 g or more, even when the formulation of sweetening ingredients, etc. was changed.

Figure 0007518982000007
Figure 0007518982000007

Figure 0007518982000008
Figure 0007518982000008

Claims (3)

焙煎コーヒー豆抽出物、pH調整剤、及び乳分を含む容器詰ミルク入りコーヒー飲料であって、
飲料100g中にコーヒー生豆換算で5.0g以上のコーヒー豆抽出物を含み、
25~70mg/100gのγ-アミノ酪酸を含有する、容器詰ミルク入りコーヒー飲料。
A packaged milk-containing coffee beverage comprising a roasted coffee bean extract , a pH adjuster, and milk ,
The beverage contains 5.0 g or more of coffee bean extract in terms of green coffee beans per 100 g of the beverage,
A packaged coffee drink containing milk , containing 25 to 70 mg/100 g of γ-aminobutyric acid.
γ-アミノ酪酸含有量が25~60mg/100gである、請求項1に記載の容器詰ミルク入りコーヒー飲料。 2. The packaged coffee beverage with milk according to claim 1, wherein the γ-aminobutyric acid content is 25 to 60 mg/100 g. pHが5.0~7.0である、請求項1又は2に記載の容器詰ミルク入りコーヒー飲料。3. The packaged coffee beverage with milk according to claim 1 or 2, having a pH of 5.0 to 7.0.
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