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JP7357467B2 - Flour composition for confectionery, mix for confectionery, and method for producing confectionery - Google Patents

Flour composition for confectionery, mix for confectionery, and method for producing confectionery Download PDF

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JP7357467B2
JP7357467B2 JP2019101263A JP2019101263A JP7357467B2 JP 7357467 B2 JP7357467 B2 JP 7357467B2 JP 2019101263 A JP2019101263 A JP 2019101263A JP 2019101263 A JP2019101263 A JP 2019101263A JP 7357467 B2 JP7357467 B2 JP 7357467B2
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真希子 白取
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Showa Sangyo Co Ltd
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Description

本発明は、菓子類の製造に用いられる菓子類用小麦粉組成物、菓子類用ミックス、および菓子類の製造方法に関する。 The present invention relates to a confectionery flour composition, a confectionery mix, and a confectionery manufacturing method used in the production of confectionery.

近年、消費者の嗜好の多様化により、菓子類において、食感、香ばしさ、コクなどを感じることができる菓子類が好まれ、様々な方法が提案されている。例えば、特定品種の小麦由来の小麦粉を用いることにより、さっくりとした食感で、口溶けが良い焼き菓子を得られる焼き菓子類用小麦粉が知られている(特許文献1)。また、特定のココナッツオイルを含有する油脂を用いることで菓子類にコクを付与できること(特許文献2)や、菓子類に加えた糖類を高温で反応させることで菓子類に香ばしさを付与できること(特許文献3)が知られている。 In recent years, with the diversification of consumer tastes, confectionery products that offer texture, aroma, richness, etc. are preferred, and various methods have been proposed. For example, flour for baked confectionery is known that uses flour derived from a specific variety of wheat to produce baked confectionery that has a light texture and melts well in the mouth (Patent Document 1). In addition, it is possible to impart richness to confectionery by using fats and oils containing specific coconut oil (Patent Document 2), and it is possible to impart flavor to confectionery by reacting sugars added to confectionery at high temperatures (Patent Document 2). Patent Document 3) is known.

特開2013-070626号公報JP2013-070626A 国際公開2016/136688号公報International Publication No. 2016/136688 特開2012-175931号公報Japanese Patent Application Publication No. 2012-175931

近年、消費者の嗜好を満たすため、菓子類においては、砂糖や油脂などを多く加えることで香ばしさやコクを付与することが行われているが、このような添加物を増やさなくても、小麦本来の香ばしさやコクを菓子類に付与することができる菓子類用小麦粉組成物が求められていた。 In recent years, in order to satisfy consumer tastes, confectionery products have been given flavor and richness by adding large amounts of sugar, fats and oils, etc. However, even without increasing these additives, wheat There has been a need for a flour composition for confectionery that can impart the original aroma and richness to confectionery.

本発明は、小麦粉を原料とする菓子類を製造する場合に、香ばしさおよびコクを付与することができる菓子類用小麦粉組成物、菓子類用ミックス、および菓子類の製造方法を提供することを目的とする。 The present invention aims to provide a flour composition for confectionery, a mix for confectionery, and a method for producing confectionery that can impart aroma and richness to confectionery made from wheat flour. purpose.

本発明は、以下の(1)~()の菓子類用小麦粉組成物、()の菓子類用ミックス、および()の菓子類の製造方法に関する。
(1)ランス産Oregrain種の小麦由来の小麦粉を20質量%以上含有する、菓子類を製造するための菓子類用小麦粉組成物であって、ウエスタン・ホワイト小麦由来の小麦粉よりも、製造した菓子類における、遊離アミノ酸の総含有率、または、ピラジン類およびフラン類の含有率が高く、前記菓子類に、前記遊離アミノ酸、または、ピラジン類およびフラン類に由来するコクを前記菓子類に付与するための、菓子類用小麦粉組成物。
(2)前記菓子類に香ばしさを付与するための、上記(1)に記載の菓子類用小麦粉組成物。
)前記フランス産小麦由来の小麦粉を40質量%以上含有する、上記(1)または(2)のいずれかに記載の菓子類用小麦粉組成物。
)前記菓子類が、焼き菓子類、揚げ菓子類、または蒸し菓子類である、上記(1)ないし()のいずれかに記載の菓子類用小麦粉組成物。
)上記(1)ないし()のいずれかに記載の菓子類用小麦粉組成物を含む、前記菓子類に前記コクを付与するための菓子類用ミックス。
)上記(1)ないし()のいずれかに記載の菓子類用小麦粉組成物、または上記()に記載の菓子類用ミックスを使用した、菓子類の製造方法。
The present invention relates to the following flour compositions for confectionery (1) to ( 4 ), mix for confectionery ( 5 ), and method for producing confectionery ( 6 ).
(1) A flour composition for confectionery for manufacturing confectionery containing 20% by mass or more of flour derived from French Oregrain wheat, which is manufactured from wheat flour derived from Western white wheat. The total content of free amino acids or the content of pyrazines and furans in the confectionery is high, and the confectionery has a richness derived from the free amino acids or pyrazines and furans . A flour composition for confectionery.
(2) The flour composition for confectionery according to (1) above, for imparting aroma to the confectionery.
( 3 ) The flour composition for confectionery according to any one of (1) or (2) above, which contains 40% by mass or more of the flour derived from French wheat.
( 4 ) The flour composition for confectionery according to any one of (1) to ( 3 ) above, wherein the confectionery is a baked confectionery, a fried confectionery, or a steamed confectionery.
( 5 ) A mix for confectionery for imparting the richness to the confectionery, comprising the flour composition for confectionery according to any one of (1) to ( 4 ) above.
( 6 ) A method for producing confectionery using the flour composition for confectionery according to any one of (1) to ( 4 ) above or the mix for confectionery according to ( 5 ) above.

本発明によれば、小麦粉を原料とする菓子類を製造する場合に、香ばしさおよびコクを付与することができる菓子類用小麦粉組成物、菓子類用ミックス、および菓子類の製造方法を提供することができる。 According to the present invention, there are provided a flour composition for confectionery, a mix for confectionery, and a method for producing confectionery that can impart aroma and richness to confectionery made from wheat flour. be able to.

以下、本発明に係る菓子類用小麦粉組成物、菓子類用ミックス、およびそれを使用した菓子類の製造方法について説明する。 Hereinafter, a flour composition for confectionery, a mix for confectionery, and a method for manufacturing confectionery using the same according to the present invention will be described.

本発明に係る菓子類用小麦粉組成物は、当該菓子類用小麦粉組成物を使用して菓子類を製造した場合に、菓子類に香ばしさおよびコクを付与することができることを特徴とし、フランス産小麦のうちの特定品種由来の小麦粉を20質量%以上含有することを特徴とする。このようなフランス産小麦の特定品種としては、Agle種、Allezy種、Aprilio種、Arezzo種、Bienfait種、Boregar種、Calabro種、Calumet種、Cellule種、Descartes種、Foxyl種、Fructidor種、Goncourt種、Hybello種、Hydrock種、Hypodrom種、Hywin種、Iilico種、Ionesco種、Laurier種、Lg Absalon種、Lg Armstrong種、Maori種、Matheo種、Nemo種、Oregrain種、Pibrac種、Rgt Kilimanjaro種、Rgt Tekno種、Rgt Venezio種、Rubisko種、Scenario種、Sepia種、Sy Mattis種、Sy Moisson種、およびTerroir種が挙げられる。本発明に係る菓子類用小麦粉組成物は、これら特定品種から選ばれる1種以上の品種の小麦粉を20質量%以上含有しており、たとえば上記特定品種のうち1種の小麦粉だけを20質量%以上含有していてもよいし、上記特定品種のうち2種以上の品種の小麦粉を合計で20質量%以上含有していてもよい。 The flour composition for confectionery according to the present invention is characterized in that when confectionery is manufactured using the flour composition for confectionery, it can impart aroma and richness to confectionery. It is characterized by containing 20% by mass or more of wheat flour derived from a specific variety of wheat. Specific varieties of French wheat include Aigle , Allezy, Aprilio, Arezzo, Bienfait, Boregar, Calabro, Calumet, Cellule, Descartes, Foxyl, and Fructi. dor species, Goncourt species, Hybello species, Hydrock species, Hypodrom species, Hywin species, Iilico species, Ionesco species, Laurier species, Lg Absalon species, Lg Armstrong species, Maori species, Matheo species, Nemo species, Ore species grain species, Pibrac species, Rgt Kilimanjaro species , Rgt Tekno species, Rgt Venezio species, Rubisko species, Scenario species, Sepia species, Sy Mattis species, Sy Moisson species, and Terroir species. The flour composition for confectionery according to the present invention contains 20% by mass or more of wheat flour of one or more types selected from these specific varieties, for example, 20% by mass of only one type of wheat flour among the above specific varieties. The wheat flour may contain 20% by mass or more of two or more types of wheat flour among the above-mentioned specific types.

また、本発明に係る菓子類用小麦粉組成物は、上記特定品種から選ばれる1種以上の小麦由来の小麦粉を20質量%以上含有していればよいが、好ましくは40%以上、より好ましくは50%以上、さらに好ましくは60%以上、上記特定品種から選ばれる1種以上の小麦由来の小麦粉を含有することがよい。また、本発明に係る菓子類用小麦粉組成物は、上記特定品種から選ばれる1種以上の小麦由来の小麦粉だけを含有していてもよいし(すなわち、上記特定品種から選ばれる1種以上の小麦由来の小麦粉を100質量%含有していてもよいし)、上記特定品種から選ばれる1種以上の小麦由来の小麦粉に加えて、菓子類の種類に応じて適宜、上記特定品種以外の小麦由来の小麦粉(薄力粉、中力粉、強力粉、デュラム小麦粉など)を含有していてもよい。上記特定品種以外の小麦としては、特に限定されないが、たとえば日本産小麦である、きたほなみ、春よ恋、ゆめちから、キタノカオリ、はるゆたか、はるきらり、さとのそら、農林61号、あやひかり、つるぴかり、イワイノダイチなど、アメリカ産の小麦であるDNS(ダーク・ノーザン・スプリング)、WW(ウエスタン・ホワイト)など、カナダ産の小麦である1CW(NO1カナダ・ウエスタン・レッド・スプリング)など、あるいは、オーストラリア産の小麦であるASW(オーストラリア・スタンダード・ホワイト)などが挙げられる。 Further, the flour composition for confectionery according to the present invention may contain at least 20% by mass of flour derived from one or more types of wheat selected from the above specific varieties, preferably at least 40%, more preferably at least 40% by mass. It is preferable to contain 50% or more, more preferably 60% or more, of wheat flour derived from one or more types of wheat selected from the above specific varieties. Further, the flour composition for confectionery according to the present invention may contain only flour derived from one or more types of wheat selected from the above specific varieties (i.e., one or more types of wheat derived from the above specific varieties). In addition to one or more types of wheat-derived flour selected from the above-mentioned specific varieties, wheat other than the above-mentioned specific varieties may be used as appropriate depending on the type of confectionery. It may contain wheat flour (weak flour, medium flour, strong flour, durum flour, etc.) derived from the wheat flour. Examples of wheat other than the specific varieties listed above include, but are not limited to, Japanese wheat such as Kitahonami, Haruyo Koi, Yumechikara, Kitano Kaori, Haruyutaka, Harukirari, Satonosora, Norin 61, and Aya. Hikari, Tsurpikari, Iwainodaichi, etc., American wheat such as DNS (Dark Northern Spring) and WW (Western White), Canadian wheat 1CW (NO1 Canadian Western Red Spring), etc. Another example is ASW (Australian Standard White), which is Australian wheat.

本発明に係る菓子類用小麦粉組成物は、菓子類の製造に用いることができるが、製造される菓子類は特に限定されず、焼き菓子類の製造に使用することもできるし、揚げ菓子類の製造に使用することもできるし、また、蒸し菓子類の製造に使用することもできる。具体的には、スポンジケーキ、バターケーキ、ビスケット、クッキー、クラッカー、シュー菓子、パイ類、ドーナツ、かりんとう、蒸しパンなどが挙げられる。特に、香ばしさを感じやすいことから、焼き菓子に使用することがより好ましい。また、本発明に係る菓子類用小麦粉組成物は、胚乳部分からなる小麦粉、外皮を含む全粒粉のいずれを使用してもよく、菓子類の種類に応じて適宜選択することができる。 The flour composition for confectionery according to the present invention can be used for manufacturing confectionery, but the confectionery to be manufactured is not particularly limited, and it can also be used for manufacturing baked confectionery, fried confectionery, etc. It can also be used in the production of steamed confectioneries. Specific examples include sponge cake, butter cake, biscuits, cookies, crackers, choux pastries, pies, donuts, karinto, and steamed bread. In particular, it is more preferable to use it for baked goods because the aroma is easily felt. In addition, the flour composition for confectionery according to the present invention may use either wheat flour consisting of an endosperm portion or whole wheat flour containing a husk, and can be appropriately selected depending on the type of confectionery.

また、本発明に係る菓子類用ミックスとして、上述した菓子類用小麦粉組成物と、他の食品材料とを混合したミックスを調製し提供することもできる。 Moreover, as a mix for confectionery according to the present invention, a mix obtained by mixing the above-mentioned flour composition for confectionery with other food materials can also be prepared and provided.

たとえば、本発明に係る菓子類用ミックスとして、本発明に係る菓子類用小麦粉組成物と、以下の食品材料とを混合したミックスが開示される。本発明に係る菓子類用ミックスに含まれる小麦粉組成物以外の食品材料としては、小麦粉以外の穀粉類(米粉、大麦粉、ライ麦粉、とうもろこし粉、あわ粉、ひえ粉、はと麦粉、そば粉)、澱粉類(とうもろこし、もち種とうもろこし、馬鈴薯、葛、タピオカ、サゴ等を原材料とした未加工の澱粉、また、それら澱粉を原材料として、物理的及び/または化学的処理等(酵素処理、湿熱処理、α化、ヒドロキシプロピル化、アセチル化、架橋等)を施した澱粉または加工澱粉)、油脂類(ショートニング、ラード、マーガリン、バター、液状油、粉末油脂等)、食塩、糖類(トレハロース、ぶどう糖、砂糖、マルトース、イソマルトース、デキストリン等の、液状または粉粒状の糖類)、糖アルコール類(ソルビトール、マルチトール、パラチニット、還元水飴等の、液状または粉粒状の糖アルコール類)、ベーキングパウダー、乳化剤(レシチン、ショ糖脂肪酸エステル、グリセリン脂肪酸エステル等)、酵素類、調味料(アミノ酸、核酸等)、および香料のうち1以上の成分を一例として挙げることができるが、これに限定されず、他の食品材料も菓子類用ミックスに含めることができる。 For example, as a mix for confectionery according to the present invention, a mix is disclosed in which the flour composition for confectionery according to the present invention is mixed with the following food materials. Food materials other than the wheat flour composition contained in the confectionery mix according to the present invention include grain flours other than wheat flour (rice flour, barley flour, rye flour, corn flour, millet flour, millet flour, pigeon flour, buckwheat flour). ), starches (unprocessed starches made from corn, glutinous corn, potatoes, kudzu, tapioca, sago, etc.), and starches that are processed using physical and/or chemical treatments (enzyme treatment, moisturizing, etc.) as raw materials. Starch or modified starch that has undergone heat treatment, gelatinization, hydroxypropylation, acetylation, crosslinking, etc.), fats and oils (shortening, lard, margarine, butter, liquid oil, powdered fat, etc.), salt, sugars (trehalose, glucose, etc.) , sugar, maltose, isomaltose, dextrin, etc.), sugar alcohols (liquid or powder sugar alcohols, such as sorbitol, maltitol, palatinit, reduced starch syrup, etc.), baking powder, emulsifiers (lecithin, sucrose fatty acid ester, glycerin fatty acid ester, etc.), enzymes, seasonings (amino acids, nucleic acids, etc.), and fragrances. Food ingredients can also be included in the confectionery mix.

本発明に係る菓子類用小麦粉組成物の実施例について説明する。本実施例では、焼き菓子類であるシュー皮、揚げ菓子類であるケーキドーナツ、および蒸し菓子類である蒸しパンを、本発明に係る菓子類用小麦粉組成物を使用して作製し、これら菓子類について、「香ばしさ」、「コク」および「小麦の風味」の3つの項目について、5段階で官能評価を行った。 Examples of the flour composition for confectionery according to the present invention will be described. In this example, a choux pastry that is a baked confectionery, a cake donut that is a fried confectionery, and a steamed bread that is a steamed confectionery were prepared using the flour composition for confectionery according to the present invention, and these confectionery A sensory evaluation was conducted on a five-point scale for three items: "fragrance," "richness," and "wheat flavor."

なお、官能評価は、専門の訓練を受けた10名のパネルにて以下の評価基準で行い、評価結果は、評価点の平均値で示した。「香ばしさ」の評価は、後述するコントロールを基準として、コントロールよりも香ばしさが強い場合は5点、コントロールよりも香ばしさがやや強い場合は4点、コントロールと香ばしさが同程度の場合は3点、コントロールよりも香ばしさがやや弱い場合は2点、コントロールよりも香ばしさが弱い場合は1点として評価を行った。また、「コク」の評価は、コントロールを基準として、コントロールよりもコクが強い場合は5点、コントロールよりもコクがやや強い場合は4点、コントロールとコクが同程度の場合は3点、コントロールよりもコクがやや弱い場合は2点、コントロールよりもコクが弱い場合は1点として評価を行った。さらに、「小麦の風味」の評価は、コントロールを基準として、コントロールよりも小麦の風味が強い場合は5点、コントロールよりも小麦の風味がやや強い場合は4点、コントロールと小麦の風味が同程度の場合は3点、コントロールよりも小麦の風味がやや弱い場合は2点、コントロールよりも小麦の風味が弱い場合は1点として評価を行った。 The sensory evaluation was performed by a panel of 10 people who received specialized training using the following evaluation criteria, and the evaluation results were expressed as the average value of the evaluation scores. The evaluation of "fragrance" is based on the control described below. If the aroma is stronger than the control, it will be 5 points, if the aroma is slightly stronger than the control, it will be 4 points, and if the aroma is the same as the control, it will be 4 points. 3 points, 2 points if the fragrance was slightly weaker than the control, and 1 point if the fragrance was weaker than the control. In addition, the evaluation of "richness" is based on the control, 5 points if the richness is stronger than the control, 4 points if the richness is slightly stronger than the control, 3 points if the richness is about the same as the control, and 3 points if the richness is the same as the control. A score of 2 points was given if the flavor was slightly weaker than that of the control, and a score of 1 point was given if the flavor was weaker than the control. Furthermore, the evaluation of "wheat flavor" is based on the control, and points are 5 points if the wheat flavor is stronger than the control, 4 points if the wheat flavor is slightly stronger than the control, and 4 points if the wheat flavor is the same as the control. The score was 3 points if the wheat flavor was weaker than the control, 2 points if the wheat flavor was slightly weaker than the control, and 1 point if the wheat flavor was weaker than the control.

(試験1:シュー皮)
まず、本発明に係る菓子類用小麦粉組成物を用いて作製したシュー皮の評価について説明する。本実施例では、アメリカ産のウエスタン・ホワイト小麦由来の小麦粉と、フランス産小麦のOregrain種由来の小麦粉と、フランス産小麦のFructidor種由来の小麦粉とを、下記表1に示す割合にて配合し、シュー皮用の小麦粉組成物をそれぞれ調製した。
(Test 1: Choux skin)
First, evaluation of choux pastry made using the flour composition for confectionery according to the present invention will be explained. In this example, wheat flour derived from American Western White wheat, wheat flour derived from the Oregrain variety of French wheat, and flour derived from the Fructidor variety of French wheat were blended in the proportions shown in Table 1 below. and flour compositions for choux pastry were prepared.

具体的には、コントロールでは、ウエスタン・ホワイト小麦由来の小麦粉だけからなる小麦粉組成物を使用しており、実施例1では、フランス産小麦であるOregrain種由来の小麦粉を100質量%含有する小麦粉組成物を使用しており、実施例2では、フランス産小麦であるFructidor種由来の小麦粉を100質量%含有する小麦粉組成物を使用した。また、実施例3~6に係る小麦粉組成物では、上記表1に示すように、ウエスタン・ホワイト小麦由来の小麦粉とフランス産小麦であるOregrain種由来の小麦粉とを混合しており、その混合比率は実施例ごとに異なるが、Oregrain種由来の小麦粉の比率は全て20質量%以上となっている。一方、比較例1に係る小麦粉組成物は、ウエスタン・ホワイト小麦由来の小麦粉とフランス産小麦であるOregrain種由来の小麦粉とを混合したものであるが、Oregrain種由来の小麦粉の含有量は20質量%未満となっている。 Specifically, in the control, a flour composition consisting only of wheat flour derived from Western white wheat was used, and in Example 1, a flour composition containing 100% by mass of flour derived from the Oregrain variety, which is French wheat, was used. In Example 2, a flour composition containing 100% by mass of wheat flour derived from the Fructidor variety, which is a French wheat, was used. In addition, in the flour compositions according to Examples 3 to 6, as shown in Table 1 above, flour derived from Western white wheat and flour derived from Oregrain, a French wheat, are mixed, and the mixing ratio Although it differs from example to example, the proportion of wheat flour derived from the Oregrain variety is all 20% by mass or more. On the other hand, the flour composition according to Comparative Example 1 is a mixture of wheat flour derived from Western white wheat and flour derived from the Oregrain variety, which is French wheat, but the content of the flour derived from the Oregrain variety is 20% by mass. It is less than %.

そして、調製した小麦粉組成物を用いて、シュー皮を製造した。具体的には、下記表2に示す配合量に基づいて、マーガリン、食塩、水をボールに入れて沸騰させ、そこに、それぞれ調製した小麦粉組成物とグラニュー糖とを加え混合した。そして、全卵とベーキングパウダーとを混合したものを数回に分けて加えて混合し、生地を調製した。生地を天板に絞り、上火195℃/下火210℃で16分焼成し、さらに上火205℃/下火210℃で3分30秒焼成して、各シュー皮を得た。
Then, a choux pastry was manufactured using the prepared flour composition. Specifically, based on the amounts shown in Table 2 below, margarine, salt, and water were placed in a bowl and brought to a boil, and the flour compositions and granulated sugar prepared respectively were added thereto and mixed. Then, a mixture of whole eggs and baking powder was added in several portions and mixed to prepare dough. The dough was squeezed onto a baking sheet and baked for 16 minutes at 195° C. for upper heat and 210° C. for lower heat, and then for 3 minutes and 30 seconds at 205° C. for upper heat and 210° C. for lower heat to obtain each choux pastry.

そして、下記表3に示すように、コントロールにおける「香ばしさ」、「コク」および「小麦の風味」の各項目を基準点(3点)として、比較例1および実施例1~6について官能評価を行った。
As shown in Table 3 below, sensory evaluation was performed for Comparative Example 1 and Examples 1 to 6 using each item of "fragrance", "richness", and "wheat flavor" in the control as reference points (3 points). I did it.

その結果、上記表3に示すように、比較例1では、「香ばしさ」、「コク」および「小麦の風味」の全ての項目について、コントロールとほぼ同程度の評価が得られた。一方、フランス産小麦であるOregrain種由来の小麦粉を20質量%以上含有する小麦粉組成物を使用した実施例1,3~6、およびフランス産小麦のFructidor種由来の小麦粉を100質量%含有する小麦粉組成物を使用した実施例2については、コントロールおよび比較例1と比べて、「香ばしさ」、「コク」、および「小麦の風味」の各項目の評価が相対的に高くなった。特に、Oregrain種由来の小麦粉を20質量%以上含有する小麦粉組成物を使用した実施例1,3~6のうち、Oregrain種由来の小麦粉を40質量%以上含有する小麦粉組成物を使用した実施例1,3~5では、「香ばしさ」および「コク」がやや強いとの評価が得られた。また、Oregrain種由来の小麦粉を20質量%以上含有した実施例1,3~6の評価結果から、Oregrain種由来の小麦粉の含有量が多くなるほど、「香ばしさ」、「コク」、および「小麦の風味」の全ての項目について評価が高くなることがわかった。さらに、Fructidor種由来の小麦粉を100質量%含有する小麦粉組成物を使用した実施例2においても、「香ばしさ」、「コク」、および「小麦の風味」の全ての項目について、Oregrain種由来の小麦粉を100質量%含有する小麦粉組成物を使用した実施例1と同程度の評価となっており、このことから、Fructidor種由来の小麦粉を20質量%以上含有することで、Oregrain種由来の小麦粉を20質量%含有する小麦粉組成物と同様に、「香ばしさ」、「コク」および「小麦の風味」を焼き菓子類に付与することができると考えられる。 As a result, as shown in Table 3 above, in Comparative Example 1, almost the same evaluation as the control was obtained for all items of "aroma," "richness," and "wheat flavor." On the other hand, Examples 1 and 3 to 6 using flour compositions containing 20% by mass or more of wheat flour derived from the French wheat variety Oregrain, and flour containing 100% by mass of wheat flour derived from the Fructidor variety of French wheat. Regarding Example 2 using the composition, compared to the control and Comparative Example 1, the evaluation of each item of "fragrance", "richness", and "wheat flavor" was relatively high. In particular, among Examples 1 and 3 to 6 using flour compositions containing 20% by mass or more of wheat flour derived from the Oregrain variety, examples using flour compositions containing 40% by mass or more of wheat flour derived from the Oregrain variety. For items 1, 3 to 5, the evaluation was that the "fragrance" and "richness" were somewhat strong. In addition, from the evaluation results of Examples 1, 3 to 6, which contained 20% by mass or more of wheat flour derived from the Oregrain variety, it was found that the higher the content of the flour derived from the Oregrain variety, the lower the "fragrance", "richness", and "wheat flour". It was found that the evaluation of all items of ``flavor'' was high. Furthermore, in Example 2 using a flour composition containing 100% by mass of wheat flour derived from the Fructidor variety, all items of "fragrance", "richness", and "wheat flavor" were The evaluation was comparable to that of Example 1, which used a wheat flour composition containing 100% by mass of wheat flour, and from this, by containing 20% by mass or more of wheat flour derived from Fructidor species, wheat flour derived from Oregrain species It is thought that it is possible to impart "fragrance", "richness" and "wheat flavor" to baked confectionery products in the same way as a wheat flour composition containing 20% by mass of.

また、本発明に係る菓子類用小麦粉組成物の特性を検証するために、本試験1で製造したコントロール、実施例1、および実施例5のシュー皮について、遊離アミノ酸および揮発性成分を分析した。 In addition, in order to verify the characteristics of the flour composition for confectionery according to the present invention, free amino acids and volatile components of the control, Example 1, and Example 5 choux pastries produced in Test 1 were analyzed. .

下記表4は、遊離アミノ酸の分析結果を示す表である。本試験1においては、高速液体クロマトグラフ法により、コントロール、実施例1、および実施例5のシュー皮に含まれる遊離アミノ酸を定量した。
Table 4 below is a table showing the analysis results of free amino acids. In this Test 1, free amino acids contained in the choux pastry of the control, Example 1, and Example 5 were quantified by high-performance liquid chromatography.

上記表4に示すように、ウエスタン・ホワイト小麦由来の小麦粉だけからなるコントロールに対して、フランス産小麦であるOregrain種由来の小麦粉を20質量%以上含有する小麦粉組成物を使用した実施例1および実施例5では、遊離アミノ酸の含有量(総量)が有意に高くなった。また、Oregrain種由来の小麦粉を40質量%含有する小麦粉組成物で製造した実施例5のシュー皮に比べて、Oregrain種由来の小麦粉を100質量%含有する小麦粉組成物で製造した実施例1のシュー皮では、遊離アミノ酸をより多く含むことが分かった。アミノ酸は、食品のコクや風味に寄与することが知られており、このことから、表3に示すように、本発明に係る菓子類用小麦粉組成物を用いたことで、菓子類のコクや風味を向上させることができたものと考えられる。 As shown in Table 4 above, Example 1 using a flour composition containing 20% by mass or more of wheat flour derived from Oregrain, a French wheat, and In Example 5, the content (total amount) of free amino acids was significantly higher. Furthermore, compared to the choux pastry of Example 5, which was produced using a flour composition containing 40% by mass of wheat flour derived from the Oregrain variety, the choux pastry of Example 1, which was produced using a flour composition containing 100% by mass of wheat flour derived from the Oregrain variety. Choux skin was found to contain more free amino acids. Amino acids are known to contribute to the richness and flavor of foods, and therefore, as shown in Table 3, by using the flour composition for confectionery according to the present invention, the richness and flavor of confectionery can be improved. It is thought that the flavor could be improved.

また、ガスクロマトグラフ-質量分析法により、コントロール、実施例1、および実施例5のシュー皮に含まれる揮発性成分を検出した。具体的には、試料(シュー皮の底の焦げた部分は取り除いた)20gをバイアル瓶に入れ、55℃で加温し、気相部分の揮発性成分を固相微量抽出法により吸着した。これをGC-MSに導入し、揮発性成分のピークエリアの比較を行った。なお、化合物の同定は、GC-MS附属のライブラリー検索、および標品により行った。下記表5は揮発性成分の分析結果を示す表であり、アルコール類、アルデヒド類、ケトン類、酸類、ピラジン類、フラン類、並びにこれら以外の香気成分とその合計量をまとめた。
In addition, volatile components contained in the choux pastry of the control, Example 1, and Example 5 were detected by gas chromatography-mass spectrometry. Specifically, 20 g of the sample (the burnt part at the bottom of the choux pastry was removed) was placed in a vial, heated at 55°C, and volatile components in the gas phase were adsorbed by solid phase microextraction. This was introduced into GC-MS and the peak areas of volatile components were compared. The compound was identified by searching a library attached to GC-MS and using a standard sample. Table 5 below is a table showing the analysis results of volatile components, and summarizes alcohols, aldehydes, ketones, acids, pyrazines, furans, and other aroma components and their total amounts.

上記表5に示すように、ウエスタン・ホワイト小麦由来の小麦粉だけからなるコントロールに対して、フランス産小麦であるOregrain種由来の小麦粉を20質量%以上含有する小麦粉組成物を使用した実施例1および実施例5のシュー皮では、香ばしさに寄与する香り成分であるピラジン類、および甘い香りのフラン類の検出量が多くなった。また、Oregrain種由来の小麦粉を40質量%含有する小麦粉組成物で製造した実施例5のシュー皮に比べて、Oregrain種由来の小麦粉を100質量%含有する小麦粉組成物で製造した実施例1のシュー皮では、ピラジン類およびフラン類の検出合計量がより多くなった。 As shown in Table 5 above, Example 1 using a flour composition containing 20% by mass or more of wheat flour derived from Oregrain, a French wheat, and In the choux pastry of Example 5, the detected amounts of pyrazines, which are aroma components contributing to aroma, and furans, which have a sweet aroma, were increased. Furthermore, compared to the choux pastry of Example 5, which was produced using a flour composition containing 40% by mass of wheat flour derived from the Oregrain variety, the choux pastry of Example 1, which was produced using a flour composition containing 100% by mass of wheat flour derived from the Oregrain variety. In choux pastry, the total amount of pyrazines and furans detected was higher.

また、表5に示すように、コントロールに対して、実施例1および実施例5では、アルデヒド類およびケトン類についても検出合計量が多くなった。さらに、Oregrain種由来の小麦粉を40質量%含有する小麦粉組成物で製造した実施例5のシュー皮に比べて、Oregrain種由来の小麦粉を100質量%含有する小麦粉組成物で製造した実施例1のシュー皮では、アルデヒド類およびケトン類の検出合計量がより多くなった。 Furthermore, as shown in Table 5, the total detected amounts of aldehydes and ketones were also greater in Examples 1 and 5 than in the control. Furthermore, compared to the choux pastry of Example 5, which was manufactured using a flour composition containing 40% by mass of wheat flour derived from the Oregrain variety, the choux pastry of Example 1, which was manufactured using a flour composition containing 100% by mass of wheat flour derived from the Oregrain variety, was In choux pastry, the total amount of aldehydes and ketones detected was higher.

このように、アルコール類とその他の香気成分(酢酸ブチルなど)を除く、アルデヒド類、ケトン類、酸類、ピラジン類およびフラン類の各香気成分の検出合計量はそれぞれ、コントロールに対して、実施例1および実施例5のシュー皮で多く、さらに、Oregrain種由来の小麦粉を40質量%含有する小麦粉組成物で製造した実施例5のシュー皮に比べて、Oregrain種由来の小麦粉を100質量%含有する小麦粉組成物で製造した実施例1のシュー皮では、各香気成分の検出合計量がより多くなった。また、全ての香気成分の検出合計量は、コントロールに対して、実施例1および実施例5のシュー皮で多く、さらに、Oregrain種由来の小麦粉を40質量%含有する小麦粉組成物で製造した実施例5のシュー皮に比べて、Oregrain種由来の小麦粉を100質量%含有する小麦粉組成物で製造した実施例1のシュー皮では、全ての香気成分の検出合計量がより多くなった。このように、実施例1,5では、コントロールと比べて、香気成分を多く含んでおり、このことから、表3に示すように、本発明に係る菓子類用小麦粉組成物を用いることで、菓子類の香ばしさやコクを向上させることができたものと考えられる。特に、本発明に係る菓子類用小麦粉組成物では、香ばしさに寄与する香り成分であるピラジン類、および甘い香りのフラン類の検出量が、コントロールと比べて多くなることで、菓子類の香ばしさやコクを向上させることができたものと考えられる。 In this way, the total amount detected of each aroma component of aldehydes, ketones, acids, pyrazines, and furans, excluding alcohols and other aroma components (butyl acetate, etc.), was different from that of the control example. In comparison to the choux pastry of Example 5, which was produced using a flour composition containing 40% by mass of wheat flour derived from the Oregrain variety, the choux pastry of Example 5 contained 100% by mass of wheat flour derived from the Oregrain variety. In the choux pastry of Example 1 produced using the wheat flour composition, the total amount of each aroma component detected was higher. In addition, the total detected amount of all aroma components was higher in the choux pastry of Example 1 and Example 5 than in the control, and furthermore, the total detected amount of all aroma components was higher in the choux pastry of Example 1 and Example 5 than in the control. Compared to the choux pastry of Example 5, the total detected amount of all aroma components was higher in the choux pastry of Example 1, which was manufactured using a flour composition containing 100% by mass of wheat flour derived from the Oregrain variety. In this way, Examples 1 and 5 contain more aroma components than the control, and from this, as shown in Table 3, by using the flour composition for confectionery according to the present invention, It is thought that the aroma and richness of sweets could be improved. In particular, in the flour composition for confectionery according to the present invention, the detected amounts of pyrazines, which are aroma components that contribute to aroma, and furans, which have a sweet aroma, are increased compared to the control, which improves the aroma of confectionery. It is thought that the richness of the pods could be improved.

(試験例2:ケーキドーナツ)
次いで、本発明に係る菓子類用小麦粉組成物を用いて製造したケーキドーナツの評価について説明する。本実施例では、アメリカ産のウエスタン・ホワイト小麦由来の小麦粉と、フランス産小麦のOregrain種由来の小麦粉と、フランス産小麦のFructidor種由来の小麦粉と、フランス産小麦であるRubisko種由来の小麦粉とを、下記表6に示す割合にて配合し、ケーキドーナツ用の小麦粉組成物をそれぞれ調製した。
(Test example 2: cake donut)
Next, evaluation of cake donuts produced using the flour composition for confectionery according to the present invention will be explained. In this example, wheat flour derived from Western white wheat produced in the United States, flour derived from the Oregrain variety of French wheat, flour derived from the Fructidor variety of French wheat, and flour derived from the Rubisko variety of French wheat were used. were blended in the proportions shown in Table 6 below to prepare flour compositions for cake donuts.

具体的には、コントロールは、ウエスタン・ホワイト小麦由来の小麦粉だけからなる小麦粉を使用しており、実施例7ではフランス産小麦であるOregrain種由来の小麦粉を100質量%含有する小麦粉組成物を使用しており、実施例8ではフランス産小麦であるFructidor種由来の小麦粉を100質量%含有する小麦粉組成物を使用している。また、実施例9~11では、上記表6に示すように、フランス産小麦であるRubisko種を単体、または、ウエスタン・ホワイト小麦由来の小麦粉とフランス産小麦であるRubisko種由来の小麦粉とを、Rubisko種由来の小麦粉の比率が20質量%以上となるように混合した小麦粉組成物を使用している。 Specifically, the control uses flour made only of wheat flour derived from Western white wheat, and in Example 7, a flour composition containing 100% by mass of wheat flour derived from the Oregrain variety, which is French wheat, was used. In Example 8, a flour composition containing 100% by mass of wheat flour derived from the Fructidor variety, which is a French wheat, was used. In addition, in Examples 9 to 11, as shown in Table 6 above, Rubisko, a French wheat, was used alone, or wheat flour derived from Western white wheat and flour derived from Rubisko, a French wheat, were used. A flour composition is used in which the proportion of flour derived from Rubisko variety is 20% by mass or more.

本実施例では、下記表7に示す配合に基づいて、グラニュー糖、食塩、脱脂粉乳、ベーキングパウダーをよく混合した。その後、水を少しずつ加え、良く混ぜ、さらに全卵を加えよく混合した。そして、それぞれ調製した小麦粉組成物、強力粉を加え混合した後、ショートニングを加えて混合し、生地を調製した。生地を180~185℃の油で1分油ちょうし、反転後さらに1分油ちょうして、各ケーキドーナツを得た。
In this example, granulated sugar, salt, skim milk powder, and baking powder were thoroughly mixed based on the formulation shown in Table 7 below. Thereafter, water was added little by little and mixed well, and then whole eggs were added and mixed well. Then, after adding and mixing the respective prepared flour compositions and strong flour, shortening was added and mixed to prepare dough. The dough was fried with oil at 180 to 185° C. for 1 minute, and after being turned over, it was fried with oil for another minute to obtain each cake donut.

そして、下記表8に示すように、コントロールにおける「香ばしさ」、「コク」および「小麦の風味」の各項目を基準点(3点)として、実施例7~11について官能評価を行った。
Then, as shown in Table 8 below, a sensory evaluation was performed for Examples 7 to 11 using each item of "fragrance", "richness", and "wheat flavor" in the control as reference points (3 points).

その結果、上記表8に示すように、Oregrain種由来の小麦粉を20質量%以上含有する小麦粉組成物を使用した実施例7、Fructidor種由来の小麦粉を20質量%以上含有する小麦粉組成物を使用した実施例8、およびRubisko種由来の小麦粉を20質量%以上含有する小麦粉組成物を使用した実施例9~11では、コントロールと比べて、「香ばしさ」、「コク」および「小麦の風味」の各項目について相対的に評価が高くなることが分かった。また、Rubisko種由来の小麦粉を20質量%以上含有した実施例9~11の評価結果から、Rubisko種由来の小麦粉の含有量が多くなるほど、「香ばしさ」、「コク」、および「小麦の風味」の全ての項目について評価が高くなることがわかった。さらに、Oregrain種由来の小麦粉を100質量%含有する小麦粉組成物を使用した実施例7、Fructidor種由来の小麦粉を100質量%含有する小麦粉組成物を使用した実施例8においても、「香ばしさ」、「コク」、および「小麦の風味」の全ての項目について、Rubisko種由来の小麦粉を100質量%含有する小麦粉組成物を使用した実施例9と同程度の評価が得られており、このことから、Oregrain種由来の小麦粉やFructidor種由来の小麦粉を20質量%以上含有することで、Rubisko種由来の小麦粉を20質量%含有する小麦粉組成物と同様に、「香ばしさ」、「コク」および「小麦の風味」を揚げ菓子類に付与することができるものと考えられる。 As a result, as shown in Table 8 above, Example 7 used a wheat flour composition containing 20% by mass or more of wheat flour derived from the Oregrain variety, and Example 7 used a flour composition containing 20% by mass or more of wheat flour derived from the Fructidor variety. In Example 8 and Examples 9 to 11 using flour compositions containing 20% by mass or more of flour derived from the Rubisko variety, "fragrance", "richness" and "wheat flavor" were improved compared to the control. It was found that the evaluation of each item was relatively high. In addition, from the evaluation results of Examples 9 to 11 containing 20% by mass or more of flour derived from the Rubisko variety, it was found that the higher the content of flour derived from the Rubisko variety, the more the "fragrance", "richness", and "wheat flavor" It was found that the evaluation was high for all items. Furthermore, in Example 7, which used a flour composition containing 100% by mass of wheat flour derived from the Oregrain variety, and in Example 8, which used a flour composition containing 100% by mass of wheat flour derived from the Fructidor variety, the "fragrance" , "Body", and "Wheat Flavor", the same level of evaluation was obtained as in Example 9 using a flour composition containing 100% by mass of wheat flour derived from the Rubisko variety. Therefore, by containing 20% by mass or more of wheat flour derived from the Oregrain variety or flour derived from the Fructidor variety, similar to a flour composition containing 20% by mass of wheat flour derived from the Rubisko variety, "fragrance", "richness", and It is considered that "wheat flavor" can be imparted to fried confectionery.

(試験例3:蒸しパン)
次いで、本発明に係る小麦粉組成物を用いて製造した蒸しパンの官能評価について説明する。本実施例では、アメリカ産のウエスタン・ホワイト小麦由来の小麦粉と、フランス産小麦のFructidor種由来の小麦粉とを、下記表9に示す割合にて配合し、蒸しパン用の小麦粉組成物をそれぞれ調製した。
(Test Example 3: Steamed bread)
Next, sensory evaluation of steamed bread produced using the flour composition according to the present invention will be explained. In this example, wheat flour derived from American Western White wheat and flour derived from French wheat Fructidor were mixed in the proportions shown in Table 9 below to prepare flour compositions for steamed bread. did.

具体的には、コントロールは、ウエスタン・ホワイト小麦由来の小麦粉だけからなる小麦粉を使用しており、実施例12ではフランス産小麦であるFructidor種由来の小麦粉を100質量%含有する小麦粉組成物を使用している。また、実施例13~14に係る小麦粉組成物は、上記表9に示すように、ウエスタン・ホワイト小麦由来の小麦粉とフランス産小麦であるFructidor種由来の小麦粉とを混合しており、その混合比率は実施例ごとに異なるが、Fructidor種由来の小麦粉の比率は全て20質量%以上となっている。 Specifically, the control uses flour made only of wheat flour derived from Western White wheat, and Example 12 uses a flour composition containing 100% by mass of flour derived from the Fructidor variety, which is a French wheat. are doing. In addition, as shown in Table 9 above, the flour compositions according to Examples 13 and 14 are a mixture of wheat flour derived from Western white wheat and flour derived from the Fructidor variety, which is a French wheat, and the mixing ratio Although it differs from example to example, the proportion of wheat flour derived from Fructidor seeds is all 20% by mass or more.

本実施例では、下記表10に示す配合に基づいて、調製した小麦粉組成物、砂糖およびベーキングパウダーをよく混合し、ショートニングと水を加え、混合した後、生地を量り、型に流したのち、15分間蒸して、各蒸しパンを得た。
In this example, the flour composition, sugar, and baking powder prepared based on the formulation shown in Table 10 below were thoroughly mixed, shortening and water were added, and after mixing, the dough was weighed and poured into a mold. Each steamed bun was steamed for 15 minutes.

そして、下記表11に示すように、コントロールにおける「香ばしさ」、「コク」および「小麦の風味」の各項目を基準点(3点)として、実施例12~14について官能評価を行った。
Then, as shown in Table 11 below, sensory evaluation was performed for Examples 12 to 14 using each item of "fragrance", "richness", and "wheat flavor" in the control as reference points (3 points).

その結果、上記表11に示すように、Fructidor種由来の小麦粉を20質量%以上含有する小麦粉組成物を使用した実施例12~14では、コントロールと比べて「香ばしさ」、「コク」および「小麦の風味」の各項目の評価が相対的に高くなること分かった。また、Fructidor種由来の小麦粉を20質量%以上含有する小麦粉組成物を使用した実施例12~14の評価結果から、Fructidor種由来の小麦粉の含有量が多くなるほど、「香ばしさ」、「コク」、および「小麦の風味」の全ての項目について評価が高くなることがわかった。 As a result, as shown in Table 11 above, Examples 12 to 14, which used flour compositions containing 20% by mass or more of wheat flour derived from Fructidor species, had "fragrance", "richness" and "richness" compared to the control. It was found that the evaluation of each item of ``wheat flavor'' was relatively high. In addition, from the evaluation results of Examples 12 to 14 using flour compositions containing 20% by mass or more of flour derived from Fructidor species, it was found that the higher the content of flour derived from Fructidor species, the better the "fragrance" and "richness". It was found that evaluations were high for all items of , and "wheat flavor".

以上のように、本発明に係る菓子類用小麦粉組成物は、フランス産小麦由来の小麦粉を20質量%以上含有する、菓子類を製造するための小麦粉であって、上記フランス産小麦が、Agle種、Allezy種、Aprilio種、Arezzo種、Bienfait種、Boregar種、Calabro種、Calumet種、Cellule種、Descartes種、Foxyl種、Fructidor種、Goncourt種、Hybello種、Hydrock種、Hypodrom種、Hywin種、Iilico種、Ionesco種、Laurier種、Lg Absalon種、Lg Armstrong種、Maori種、Matheo種、Nemo種、Oregrain種、Pibrac種、Rgt Kilimanjaro種、Rgt Tekno種、Rgt Venezio種、Rubisko種、Scenario種、Sepia種、Sy Mattis種、Sy Moisson種、およびTerroir種から選ばれる1種以上の小麦であることを特徴とする。これにより、本発明に係る菓子類用小麦粉組成物を原料として菓子類を製造した場合に、香ばしさやコクを菓子類に付与することができる。また、本発明に係る菓子類用小麦粉組成物を原料として菓子類を製造した場合に、「香ばしさ」および「コク」を菓子類に付与するだけではなく、「小麦の風味」も付与することができるという効果を奏することができる。
As described above, the flour composition for confectionery according to the present invention is a flour for producing confectionery containing 20% by mass or more of wheat flour derived from French wheat, in which the French wheat is A i gle species, Allezy species, Aprilio species, Arezzo species, Bienfait species, Boregar species, Calabro species, Calumet species, Cellule species, Descartes species, Foxyl species, Fructidor species, Goncourt species species, Hybello species, Hydrock species, Hypodrom species, Hywin Seeds, Iilico, Ionesco, Laurier, Lg Absalon, Lg Armstrong, Maori, Matheo, Nemo, Oregrain, Pibrac, Rgt Kilimanjaro, Rgt Tekno species, Rgt Venezio species, Rubisko species, Scenario The wheat is characterized by being one or more types of wheat selected from the following types: Seed, Sepia, Sy Mattis, Sy Moisson, and Terroir. Thereby, when confectionery is manufactured using the flour composition for confectionery according to the present invention as a raw material, aroma and richness can be imparted to the confectionery. Furthermore, when confectionery is produced using the flour composition for confectionery according to the present invention as a raw material, it is possible to impart not only "fragrance" and "richness" to the confectionery but also "wheat flavor". It is possible to achieve the effect of being able to do the following.

以上、本発明の好ましい実施形態例について説明したが、本発明の技術的範囲は上記実施形態例の記載に限定されるものではない。上記実施形態例には様々な変更・改良を加えることが可能であり、そのような変更または改良を加えた形態のものも本発明の技術的範囲に含まれる。 Although preferred embodiments of the present invention have been described above, the technical scope of the present invention is not limited to the description of the above embodiments. Various changes and improvements can be made to the embodiments described above, and forms with such changes and improvements are also included within the technical scope of the present invention.

Claims (6)

ランス産Oregrain種の小麦由来の小麦粉を20質量%以上含有する、菓子類を製造するための菓子類用小麦粉組成物であって、
ウエスタン・ホワイト小麦由来の小麦粉よりも、製造した菓子類における、遊離アミノ酸の総含有率、または、ピラジン類およびフラン類の含有率が高く、前記遊離アミノ酸、または、ピラジン類およびフラン類に由来するコクを前記菓子類に付与するための、菓子類用小麦粉組成物。
A flour composition for confectionery for producing confectionery, containing 20% by mass or more of flour derived from French Oregrain wheat ,
The total content of free amino acids or the content of pyrazines and furans in the manufactured confectionery is higher than that of wheat flour derived from Western white wheat, and the content is derived from the free amino acids or pyrazines and furans. A flour composition for confectionery for imparting richness to the confectionery.
前記菓子類に香ばしさを付与するための、請求項1に記載の菓子類用小麦粉組成物。 The flour composition for confectionery according to claim 1, for imparting aroma to the confectionery. 前記フランス産小麦由来の小麦粉を40質量%以上含有する、請求項1または2に記載の菓子類用小麦粉組成物。 The flour composition for confectionery according to claim 1 or 2 , which contains 40% by mass or more of flour derived from the French wheat. 前記菓子類が、焼き菓子類、揚げ菓子類、または蒸し菓子類のいずれかである、請求項1ないしのいずれか一項に記載の菓子類用小麦粉組成物。 The flour composition for confectionery according to any one of claims 1 to 3 , wherein the confectionery is one of baked confectionery, fried confectionery, or steamed confectionery. 請求項1ないしのいずれか一項に記載の菓子類用小麦粉組成物を含む、前記菓子類に前記コクを付与するための菓子類用ミックス。 A confectionery mix for imparting the richness to the confectionery, comprising the confectionery flour composition according to any one of claims 1 to 4 . 請求項1ないしのいずれか一項に記載の菓子類用小麦粉組成物、または請求項に記載の菓子類用ミックスを使用した、菓子類の製造方法。 A method for producing confectionery using the flour composition for confectionery according to any one of claims 1 to 4 or the mix for confectionery according to claim 5 .
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