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JP7265335B2 - Method for producing chocolate-like food - Google Patents

Method for producing chocolate-like food Download PDF

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JP7265335B2
JP7265335B2 JP2018195546A JP2018195546A JP7265335B2 JP 7265335 B2 JP7265335 B2 JP 7265335B2 JP 2018195546 A JP2018195546 A JP 2018195546A JP 2018195546 A JP2018195546 A JP 2018195546A JP 7265335 B2 JP7265335 B2 JP 7265335B2
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立志 田中
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Kaneka Corp
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Description

本発明は、チョコレート様食品の製造方法に関する。 The present invention relates to a method for producing chocolate-like food.

油脂中に非油溶性固形分であるココアパウダー、砂糖、粉乳類等を分散させたチョコレート様食品は、非油溶性固形分が油脂中に溶解せずに分散しているために素材の風味を感じやすく、また、油脂特有の口溶け感を得ることもでき、菓子の中でも代表的なものとして親しまれている。 Chocolate-like foods, in which non-oil-soluble solids such as cocoa powder, sugar, and milk powder are dispersed in fats and oils, do not have the flavor of the ingredients because the non-oil-soluble solids are dispersed in fats and oils without dissolving them. It is easy to feel, and you can also get the unique melting feeling of fats and oils, and it is popular as a typical confectionery.

当該チョコレート様食品を製造するにあたっては、従来、全ての原材料、又は、コンチングの際に事後添加する一部の油脂以外の全ての原材料を配合した後、(1)ロールミルを用いた湿式粉砕によるリファイニング工程、(2)コンチングと言われる混練工程、(3)テンパリングと言われる調温工程、及び(4)成型冷却固化工程、が実施されている。 In producing the chocolate-like food, conventionally, after blending all raw materials or all raw materials other than some fats and oils added after conching, (1) Refining by wet grinding using a roll mill An inning process, (2) a kneading process called conching, (3) a temperature control process called tempering, and (4) a molding, cooling and solidification process are carried out.

このようなチョコレート様食品の一般的な製造方法では、リファイニングやコンチング時に使用する製造装置は洗浄性が悪く、チョコレート様食品の品種を切り換える際に必要な、製造装置の洗浄に時間がかかるため、色調や風味の異なる様々な品種を同じ製造装置で順次製造していくことが難しい。また、従来の混練工程では、チョコレート様食品の水分量を1%以下に低減し、工業的に利用可能な加工性(例えばコーティング性)や、良好な風味及び食感を製品に付与するには、半日から1日以上という長い時間をかけてコンチングを行う必要があり、生産性が低い。 In such a general method for producing chocolate-like food, the production equipment used for refining and conching has poor cleanability, and it takes time to clean the production equipment required when changing the type of chocolate-like food. , it is difficult to sequentially manufacture various varieties with different colors and flavors using the same manufacturing equipment. In addition, in the conventional kneading process, in order to reduce the water content of the chocolate-like food to 1% or less and impart industrially usable processability (for example, coating property) and good flavor and texture to the product. , it is necessary to perform conching over a long period of time, from half a day to more than one day, resulting in low productivity.

特許文献1では、チョコレートの製造における歩留りを良くするために、(A工程)コンチング装置で原料組成物Aをコンチングすることにより中間生産物を得て、該中間生産物をコンチング装置から取り出す、(B工程)A工程後のコンチング装置に残留した中間生産物を、取置き油脂で洗浄することで洗浄物Aを得る、(C工程)中間生産物と洗浄物Aを混合することでチョコレートを得る製造方法が開示されている。この方法によると、製造時の歩留りは向上するものの、煩雑な洗浄作業が必要であり、また、依然として長時間のコンチングが必要であった。 In Patent Document 1, in order to improve the yield in the production of chocolate, (A step) an intermediate product is obtained by conching the raw material composition A with a conching device, and the intermediate product is taken out from the conching device. B step) The intermediate product remaining in the conching apparatus after the A step is washed with the reserved oil to obtain the washed product A. (C step) The intermediate product and the washed product A are mixed to obtain chocolate. A method of manufacture is disclosed. According to this method, although the yield at the time of production is improved, a complicated cleaning operation is required and a long period of conching is still required.

特開2016-2014号公報Japanese Unexamined Patent Application Publication No. 2016-2014

本発明の目的は、リファイニング又はコンチング後の製造装置の洗浄性が良好で、かつ、短時間でコンチングを実施できるにも関わらず、工業的に利用可能な加工性(例えばコーティング性)を有し、風味及び食感の良好なチョコレート様食品を製造できる、チョコレート様食品の製造方法を提供することである。 An object of the present invention is to have industrially available processability (for example, coating property) despite the fact that the manufacturing equipment after refining or conching can be washed well and conching can be performed in a short time. The object of the present invention is to provide a method for producing a chocolate-like food, which can produce a chocolate-like food having good flavor and texture.

本発明者らは上記課題を解決するために鋭意研究を重ねた結果、油脂と非油溶性固形分を含むチョコレート様食品を製造するにあたって、油脂と非油溶性固形分の含有量をそれぞれ特定範囲に設定し、かつ両成分の合計含有量も特定量以上とすることに加えて、チョコレート様食品中の非油溶性固形分の平均粒径を特定範囲とし、油脂の溶融物と非油溶性固形分とを、特定の温度下で、特定の回転数で攪拌混合しながら、水分量が特定量以下になるまで減圧処理することにより、上記課題を解決できることを見出し、本発明を完成するに至った。 The present inventors have conducted intensive research to solve the above problems, and found that when producing a chocolate-like food containing fats and oil-insoluble solids, the content of fats and oil-insoluble solids is set to a specific range. In addition to setting the total content of both components to a specific amount or more, the average particle size of the non-oil-soluble solids in the chocolate-like food is set to a specific range, and the melted fat and oil-insoluble solids We have found that the above problems can be solved by performing decompression treatment until the water content is less than a specific amount while stirring and mixing at a specific temperature and at a specific rotation speed, and have completed the present invention. rice field.

即ち、本発明は、チョコレート様食品全体中、油脂を27~50重量%と、非油溶性固形分49.5~72.5重量%とを含み、油脂と非油溶性固形分とを合計で90重量%以上含むチョコレート様食品の製造方法であって、油脂を溶融させて溶融物とし、前記油脂の溶融物と前記非油溶性固形分を、40~80℃の温度下、500~30000rpmの回転数で攪拌混合しながら、水分量が2重量%以下になるまで減圧処理する工程を含み、チョコレート様食品中の非油溶性固形分の平均粒径が5~40μmであることを特徴とする、チョコレート様食品の製造方法に関する。前記油脂の溶融物と前記非油溶性固形分を混合し、40~80℃の温度下、500~30000rpmの回転数で攪拌混合して、撹拌混合物の粘度が10Pa・s以下になってから、前記減圧処理を開始することが好ましい。 That is, the present invention contains 27 to 50% by weight of fat and 49.5 to 72.5% by weight of non-oil-soluble solids in the whole chocolate-like food, and the total of fats and oils and non-oil-soluble solids is A method for producing a chocolate-like food containing 90% by weight or more, wherein fat is melted to form a melt, and the melt of the fat and the non-oil-soluble solid content is heated at a temperature of 40 to 80 ° C. at 500 to 30000 rpm. The chocolate-like food includes a step of depressurizing until the water content is 2% by weight or less while stirring and mixing at a rotational speed, and the average particle size of the oil-insoluble solids in the chocolate-like food is 5 to 40 μm. , to a method for producing a chocolate-like food product. The melted oil and fat and the oil-insoluble solids are mixed, stirred and mixed at a temperature of 40 to 80° C. and a rotation speed of 500 to 30000 rpm, and after the viscosity of the stirred mixture becomes 10 Pa s or less, It is preferable to start the decompression process.

本発明に従えば、リファイニング又はコンチング後の製造装置の洗浄性が良好で、かつ、短時間でコンチングを実施できるにも関わらず、工業的に利用可能な加工性(例えばコーティング性)を有し、風味及び食感の良好なチョコレート様食品を製造できる、チョコレート様食品の製造方法を提供することができる。 According to the present invention, the manufacturing equipment after refining or conching has good cleanability, and despite the fact that conching can be performed in a short time, it has industrially available workability (for example, coatability). Thus, it is possible to provide a method for producing a chocolate-like food that can produce a chocolate-like food with good flavor and texture.

以下、本発明につき、さらに詳細に説明する。本発明におけるチョコレート様食品とは、油脂と非油溶性固形分を主に含み、前記油脂中に前記非油溶性固形分が溶解せずに分散している食品をいう。ただし、チョコレート様食品とは、チョコレートと同様の物理的形態を有する食品を意味し、カカオ風味を有する食品に限定するものではなく、カカオ風味以外の風味を有する食品も含まれる。 The present invention will be described in more detail below. The chocolate-like food in the present invention is a food that mainly contains oil and non-oil-soluble solids, and in which the non-oil-soluble solids are dispersed in the oil without being dissolved. However, chocolate-like food means food having the same physical form as chocolate, and is not limited to food having cacao flavor, but includes food having flavor other than cacao flavor.

チョコレート様食品を製造するために配合する油脂成分としては、食用の油脂であれば特に限定されず、例えば、パーム系油脂、シア脂、サル脂、カカオバター、パーム核油、やし油、菜種油、大豆油、コーン油、米油、綿実油等の植物油、牛脂、豚脂等の動物脂、魚油、乳脂肪等や、それらの分別油、エステル交換油、極度硬化油等が挙げられ、これらの群から選ばれる少なくとも1種以上を配合することが望ましい。本発明では、当該油脂成分として、ラウリン系の代用脂(例えば、パーム核油、ヤシ油や、それらの分別油、エステル交換油、極度硬化油等)を好適に用いることができる。 The oil and fat component to be blended to produce the chocolate-like food is not particularly limited as long as it is an edible oil and fat. , vegetable oils such as soybean oil, corn oil, rice oil, cottonseed oil, animal fats such as beef tallow and lard, fish oil, milk fat, fractionated oils thereof, transesterified oils, and extremely hardened oils. It is desirable to blend at least one or more selected from the group. In the present invention, laurin-based substitute fats (eg, palm kernel oil, coconut oil, their fractionated oils, transesterified oils, extremely hardened oils, etc.) can be suitably used as the fat component.

チョコレート様食品に含まれる油脂が示す上昇融点は10~45℃が好ましく、12~42℃がより好ましい。上昇融点が10℃未満ではチョコレート様食品の耐熱保形性が劣って、多くの用途で利用が困難になる場合がある。上昇融点が45℃を超えると、配合した風味素材由来の風味を感じにくくなったり、口溶けが悪化したりする場合がある。ここで、油脂の上昇融点は、基準油脂分析試験法に従って測定することができる。なお、ここでいう油脂の上昇融点とは、配合した油脂成分と、非油溶性固形分に本来含まれている油脂分を合わせて、チョコレート様食品に含まれる油脂全体が示す上昇融点である。 The elevated melting point exhibited by fats and oils contained in chocolate-like foods is preferably 10 to 45°C, more preferably 12 to 42°C. If the rising melting point is less than 10°C, the heat-resistant shape-retaining property of the chocolate-like food is inferior, and it may become difficult to use in many applications. If the rising melting point exceeds 45°C, the flavor derived from the blended flavoring material may become difficult to perceive, or the meltability in the mouth may deteriorate. Here, the rising melting point of fats and oils can be measured in accordance with the standard method for analysis of fats and oils. The rising melting point of fats and oils here is the rising melting point exhibited by the total fats and oils contained in the chocolate-like food, including the blended fats and oils and the fats and oils originally contained in the non-oil-soluble solids.

チョコレート様食品に含まれる油脂の含有量は、チョコレート様食品中27~50重量%が好ましく、30~45重量%がより好ましく、30~40重量%が更に好ましい。含有量が27重量%未満では、チョコレート様食品を製造する過程で粘度が高くなりすぎてチョコレート様食品を製造できなかったり、相対的に非油溶性固形分が多くなりすぎ、食した時にざらつきが感じられたり、口溶け感が悪化する場合がある。含有量が50重量%を超えると、チョコレート様食品を溶解させた時の粘度が低くなりすぎ、チョコレート様食品をコーティングする際に厚みが無くなったり、チョコレート様食品の耐熱保形性が低下する場合がある。なお、ここでいう油脂の含有量は、配合した油脂成分と、非油溶性固形分に本来含まれている油脂分を合わせて、チョコレート様食品に含まれる油脂全体が、チョコレート様食品中で占める含有量である。 The content of fats and oils contained in the chocolate-like food is preferably 27 to 50% by weight, more preferably 30 to 45% by weight, and even more preferably 30 to 40% by weight. If the content is less than 27% by weight, the viscosity becomes too high in the process of producing the chocolate-like food, making it impossible to produce the chocolate-like food, or the non-oil-soluble solid content becomes relatively too high, resulting in a rough texture when eaten. It may be felt or the melt-in-the-mouth feeling may worsen. If the content exceeds 50% by weight, the viscosity of the melted chocolate-like food becomes too low, and the thickness of the coating of the chocolate-like food is lost, and the heat-resistant shape retention of the chocolate-like food is lowered. There is In addition, the content of fats and oils here refers to the total amount of fats and oils contained in the chocolate-like food, including the blended fat and oil components and the fat and oil originally contained in the non-oil-soluble solids. content.

チョコレート様食品を製造するために配合する非油溶性固形分は、食用として用いられる常温で固形状または粉末状の物質のことであって、実質的に油脂に溶解しない配合物のことを指し、食品、食品添加物を問わない。その種類は特に限定されないが、例えば、カカオマス、ココアパウダーなどのカカオ由来成分、大豆粉、小麦粉、米粉などの穀粉類、ショ糖、果糖、麦芽糖、ブドウ糖、乳糖、トレハロースなどの単糖類や二糖類、デキストリン、各種スターチ、セルロース、増粘多糖類、食物繊維などの多糖類、全粉乳、脱脂粉乳、バターミルクパウダー、ホエーパウダー、ホエー蛋白濃縮物(WPC)、乳蛋白濃縮物(MPC)、乳清ミネラルなどの粉乳類、酵母エキス、昆布エキス、魚醤エキスなどの風味エキス類、クエン酸、酒石酸、コハク酸、リンゴ酸などの有機酸類、食塩、塩化カリウムなどの塩類、乳酸菌粉末などの乾燥菌類、アミノ酸類、ペプチド類、タンパク質、核酸などの調味素材、抹茶粉末、フルーツパウダー、コーヒーなどの風味素材などが挙げられ、これらの群から選ばれる少なくとも1種を配合することが望ましい。 The non-oil-soluble solid content to be blended to produce chocolate-like food refers to a substance that is solid or powdery at room temperature and is used for food, and refers to a compound that does not substantially dissolve in fats and oils. Any food or food additive. Although the type is not particularly limited, for example, cacao mass, cocoa-derived components such as cocoa powder, grain flour such as soy flour, wheat flour, rice flour, sucrose, fructose, maltose, glucose, lactose, trehalose Monosaccharides and disaccharides such as , dextrin, various starches, cellulose, thickening polysaccharides, polysaccharides such as dietary fiber, whole milk powder, skimmed milk powder, buttermilk powder, whey powder, whey protein concentrate (WPC), milk protein concentrate (MPC), milk Powdered milk such as sei minerals, flavor extracts such as yeast extract, kelp extract, and fish sauce extract, organic acids such as citric acid, tartaric acid, succinic acid, and malic acid, salts such as salt and potassium chloride, and dried lactic acid bacteria powder Seasoning materials such as fungi, amino acids, peptides, proteins and nucleic acids, and flavoring materials such as green tea powder, fruit powder, and coffee can be mentioned, and at least one selected from these groups is desirably blended.

チョコレート様食品にチョコレート風味を付与するには、非油溶性固形分としてカカオマス、ココアパウダーなどのカカオ由来成分を配合することが好ましい。その場合、カカオ由来成分の含有量は、チョコレート様食品全体中3~70重量%であることが好ましい。 In order to impart chocolate flavor to chocolate-like foods, it is preferable to blend cocoa-derived components such as cocoa mass and cocoa powder as oil-insoluble solids. In that case, the content of cacao-derived components is preferably 3 to 70% by weight of the entire chocolate-like food.

チョコレート様食品に含まれる非油溶性固形分の含有量は、チョコレート様食品全体中49.5~72.5重量%が好ましく、55~70重量%がより好ましく、60~70重量%が更に好ましい。含有量が49.5重量%未満では相対的に油脂量が多くなり、チョコレート様食品を溶解させた時の粘度が低くなりすぎ、チョコレート様食品をコーティングする際に厚みが無くなったり、チョコレート様食品の耐熱保形性が低下したりする場合がある。含有量が72.5重量%を超えると、チョコレート様食品を製造する過程で粘度が高くなりすぎてチョコレート様食品を製造できなかったり、食した時に非油溶性固形分のざらつきが感じられたり、口溶けが悪化する場合がある。なお、ここでいう非油溶性固形分の含有量は、配合した非油溶性固形分がそれ本来の油脂分を含んでいる場合には、当該油脂分の重量を除外して算出した、油脂分以外の非油溶性固形分がチョコレート様食品中で占める含有量である。除外した油脂分の重量は、前述したように油脂の含有量に含める。 The content of non-oil-soluble solids contained in the chocolate-like food is preferably 49.5 to 72.5% by weight, more preferably 55 to 70% by weight, and even more preferably 60 to 70% by weight in the entire chocolate-like food. . If the content is less than 49.5% by weight, the amount of oil and fat becomes relatively large, and the viscosity of the chocolate-like food becomes too low when the chocolate-like food is dissolved. The heat-resistant shape retention of may be reduced. If the content exceeds 72.5% by weight, the viscosity becomes too high in the process of producing the chocolate-like food, making it impossible to produce the chocolate-like food. Dissolving in the mouth may worsen. It should be noted that the content of non-oil-soluble solids here is calculated by excluding the weight of the fats and oils when the blended non-oil-soluble solids contain their original fats and oils. It is the content of non-oil-soluble solids other than occupied in the chocolate-like food. The weight of the excluded fats and oils is included in the content of fats and oils as described above.

前記油脂と前記非油溶性固形分の合計含有量は、チョコレート様食品全体中90重量%以上が好ましく、95重量%以上がより好ましく、98重量%以上がさらに好ましい。合計含有量が90重量%より少ないと、チョコレート様食品の物性や風味の面で問題が起きる場合がある。 The total content of the fats and oils and the non-oil-soluble solids is preferably 90% by weight or more, more preferably 95% by weight or more, and even more preferably 98% by weight or more in the entire chocolate-like food. If the total content is less than 90% by weight, problems may arise in terms of the physical properties and flavor of the chocolate-like food.

チョコレート様食品には、前記油脂と前記非油溶性固形分以外の成分を配合してもよい。そのような成分としては特に限定されないが、例えば、グリセリン、液糖などの水溶性液体や乳化剤、香料成分等が挙げられる。 The chocolate-like food may contain ingredients other than the fats and oils and the non-oil-soluble solids. Such ingredients are not particularly limited, but include, for example, water-soluble liquids such as glycerin and liquid sugar, emulsifiers, flavoring ingredients, and the like.

チョコレート様食品中で測定される前記非油溶性固形分の平均粒径は、5~40μmが好ましく、8~35μmがより好ましく、8~30μmが更に好ましく、8~20μmが特に好ましい。特に、チョコレート様食品をコーティング用途で使用する場合の平均粒径は、8~35μmが好ましい。平均粒径が5μm未満では、非油溶性固形分の粉砕工程に過剰なエネルギーが必要となったり、チョコレート様食品を製造する過程で粘度が高くなり過ぎて取り扱いにくくなる場合がある。平均粒径が40μmを超えると、食した時に非油溶性固形分のざらつきが感じられて食感が悪化したり、チョコレート様食品を溶解させた時の粘度が低くなりすぎ、チョコレート様食品のコーティング性が劣る場合がある。ここで、チョコレート様食品中の非油溶性固形分の平均粒径は、レーザー回折/散乱式粒子分布測定装置を用いて測定することができる。 The average particle size of the oil-insoluble solid content measured in the chocolate-like food is preferably 5-40 μm, more preferably 8-35 μm, even more preferably 8-30 μm, and particularly preferably 8-20 μm. In particular, when chocolate-like food is used for coating purposes, the average particle size is preferably 8 to 35 μm. If the average particle size is less than 5 μm, excessive energy may be required in the process of pulverizing the non-oil-soluble solids, or the viscosity may become too high in the process of producing the chocolate-like food, making it difficult to handle. If the average particle size exceeds 40 μm, the texture of the non-oil-soluble solids is felt rough when eaten, and the texture is deteriorated, or the viscosity of the chocolate-like food when dissolved becomes too low, resulting in coating of the chocolate-like food. may be inferior. Here, the average particle size of the oil-insoluble solid content in the chocolate-like food can be measured using a laser diffraction/scattering particle distribution analyzer.

本発明のチョコレート様食品を製造するにあたって、非油溶性固形分は、市販されているものを入手してそのまま配合してもよいし、大粒径の非油溶性固形分を粉砕して平均粒径を調整してから配合してもよい。また、2種類以上の非油溶性固形分を配合する場合には、2種類以上の非油溶性固形分を混合してから粉砕してもよいし、それぞれを個別に粉砕してから配合してもよい。また、粉砕した非油溶性固形分と、粉砕していない非油溶性固形分を併用してもよい。いずれの方法を採るにしても、非油溶性固形分全体としての平均粒径が上記範囲内にあればよい。 In producing the chocolate-like food of the present invention, the non-oil-soluble solids may be commercially available and blended as they are, or the non-oil-soluble solids having a large particle size may be pulverized into average grains. It may be blended after adjusting the diameter. In the case of blending two or more types of non-oil-soluble solids, the two or more types of non-oil-soluble solids may be mixed and then pulverized, or each of them may be pulverized separately and then blended. good too. In addition, pulverized non-oil-soluble solids and non-pulverized non-oil-soluble solids may be used in combination. Regardless of which method is adopted, the average particle size of the oil-insoluble solid content as a whole should be within the above range.

配合前に非油溶性固形分を粉砕する場合、その粉砕方法としては、扱いやすさや洗浄性の観点から、乾式粉砕が好ましい。使用可能な粉砕装置としても特に限定されず、例えば、ピンミル、ハンマーミル、ボールミル、ジェットミルなどの一般的な粉砕装置を用いることができる。発熱の少なさや扱いやすさ、洗浄性などの観点から、ハンマーミル、ピンミルなどの衝撃型の乾式粉砕装置が好ましい。また、より品質を安定化させるために、粉砕装置に分級装置を付加させてもよい。 When the oil-insoluble solid content is pulverized before blending, the pulverization method is preferably dry pulverization from the viewpoint of ease of handling and cleaning. Usable pulverizing devices are not particularly limited, and for example, general pulverizing devices such as pin mills, hammer mills, ball mills and jet mills can be used. Impact-type dry pulverizers such as hammer mills and pin mills are preferred from the viewpoints of low heat generation, ease of handling, washability, and the like. In addition, a classification device may be added to the pulverization device in order to further stabilize the quality.

非油溶性固形分を粉砕するにあたって、粉砕に供する非油溶性固形分は、その油脂分含有量が27重量%以下であることが好ましく、20重量%以下がより好ましく、10重量%以下が更に好ましい。非油溶性固形分の油脂分含有量が27重量%を超えると、粉砕が困難になる場合がある。 In pulverizing the oil-insoluble solids, the oil-insoluble solids to be pulverized preferably have a fat content of 27% by weight or less, more preferably 20% by weight or less, and further preferably 10% by weight or less. preferable. If the oil-insoluble solid content exceeds 27% by weight, pulverization may become difficult.

次に、本発明のチョコレート様食品の製造方法の手順を具体的に説明する。まず、配合する油脂を溶融させて溶融物とする。これにより油脂中での非油溶性固形分の分散性が向上し、次の撹拌混合工程を短時間で実施することが可能になる。油脂を溶融させる際の温度は、配合する油脂の融点を考慮して適宜決定すればよいが、作業時間を短縮する観点から、40~80℃が好ましい。 Next, the procedure of the method for producing the chocolate-like food of the present invention will be specifically described. First, fats and oils to be blended are melted to form a melt. As a result, the dispersibility of the non-oil-soluble solids in the oil is improved, and the subsequent stirring and mixing step can be carried out in a short time. The temperature at which the fats and oils are melted may be appropriately determined in consideration of the melting point of the fats and oils to be blended.

次いで、油脂の溶融物と、非油溶性固形分とを、特定条件下で撹拌混合する。該撹拌混合は、40~80℃の温度下で行なうことが好ましく、40~70℃がより好ましい。撹拌混合時の温度が40℃よりも低いと、チョコレート様食品を製造する過程で粘度が高くなりすぎてチョコレート様食品を製造できなかったり、撹拌混合物中の水分量が十分に減少せず、前記油脂としてラウリン系の代用脂を配合した場合には経時的に油脂が加水分解してラウリン酸が遊離し、結果、チョコレート様食品の風味が悪化する場合がある。撹拌混合時の温度が80℃よりも高くなると、後述する減圧処理時に低沸点の香気成分が飛散しやすくなりチョコレート様食品の風味が低下する場合がある。 Next, the melted fat and oil and the non-oil-soluble solid content are stirred and mixed under specific conditions. The stirring and mixing is preferably carried out at a temperature of 40-80°C, more preferably 40-70°C. If the temperature during stirring and mixing is lower than 40°C, the viscosity becomes too high in the process of producing the chocolate-like food, making it impossible to produce the chocolate-like food, or the water content in the stirred mixture is not sufficiently reduced, resulting in the above-mentioned. When a laurin-based substitute fat is blended as the fat, the fat hydrolyzes over time to liberate lauric acid, and as a result, the flavor of the chocolate-like food may deteriorate. If the temperature at the time of stirring and mixing is higher than 80° C., the flavor of the chocolate-like food may deteriorate due to the tendency of the low-boiling aromatic components to scatter during the decompression treatment described below.

前記油脂の溶融物と前記非油溶性固形分を撹拌混合する際には、一般的な高速撹拌装置を使用することができ、特に限定されないが、例えば、ホモミキサーやそれに類する装置を使用することができる。撹拌混合にあたっては、使用する攪拌装置の回転数を、500~30000rpmに設定することが好ましく、1500~20000rpmがより好ましく、2000~10000rpmが更に好ましい。回転数が500rpm未満では、非油溶性固形分と油脂の馴致が十分でなく、食した時にざらつきが感じられて食感が悪化する場合がある。30000rpmを超えると、撹拌時の発熱が著しくなり、チョコレート様食品の風味が変化したり、非油溶性固形分が変質する場合がある。 When stirring and mixing the melted fat and oil and the non-oil-soluble solids, a general high-speed stirring device can be used without particular limitation, but for example, a homomixer or similar device can be used. can be done. In stirring and mixing, the rotation speed of the stirrer used is preferably set to 500 to 30,000 rpm, more preferably 1,500 to 20,000 rpm, and even more preferably 2,000 to 10,000 rpm. If the number of rotations is less than 500 rpm, the non-oil-soluble solids and fats and oils are not sufficiently mixed, and the food may feel rough when eaten, resulting in poor texture. If it exceeds 30,000 rpm, heat generation during stirring becomes significant, and the flavor of the chocolate-like food may change, or the non-oil-soluble solid content may deteriorate.

前述したように油脂と非油溶性固形分は40~80℃の温度下で撹拌混合するが、製造されるチョコレート様食品の風味を増強させる観点から、40~80℃の温度で撹拌する前の事前処理として、チョコレート様食品中にカカオマス及び/又はココアパウダーを含む場合は、該成分を油脂と共に、90~150℃の温度で撹拌しながら加熱処理することが好ましい。このような高温での事前処理を行なうことで、メイラード反応を進行させて、チョコレート様食品の風味を増強させることができる。該加熱温度は95~120℃がより好ましい。当該事前処理の加熱温度が90℃未満では、メイラード反応が十分に進まず、風味の増強が不十分な場合があり、150℃を超えると風味が悪化する場合がある。また、当該事前処理の加熱処理の時間は、1~60分間が好ましく、1~30分間がより好ましく、4~15分間が更に好ましい。1分間より短いとメイラード反応が十分に進まず、風味の増強が不十分な場合があり、60分間を超えると風味が悪化する場合がある。当該事前処理時の撹拌に関しても一般的な撹拌装置を使用することができ、その回転数は特に限定されない。 As described above, fats and oils and non-oil-soluble solids are stirred and mixed at a temperature of 40 to 80 ° C., but from the viewpoint of enhancing the flavor of the produced chocolate-like food, As a pretreatment, when cocoa mass and/or cocoa powder is contained in chocolate-like food, it is preferable to heat-treat the ingredients together with fats and oils at a temperature of 90 to 150° C. while stirring. By performing pretreatment at such a high temperature, the Maillard reaction can be advanced and the flavor of the chocolate-like food can be enhanced. The heating temperature is more preferably 95 to 120°C. If the heating temperature for the pretreatment is less than 90°C, the Maillard reaction may not proceed sufficiently, and the flavor may not be sufficiently enhanced. If it exceeds 150°C, the flavor may deteriorate. The heat treatment time for the pretreatment is preferably 1 to 60 minutes, more preferably 1 to 30 minutes, and even more preferably 4 to 15 minutes. If it is shorter than 1 minute, the Maillard reaction may not proceed sufficiently, and the enhancement of the flavor may be insufficient. If it exceeds 60 minutes, the flavor may deteriorate. A general stirrer can also be used for stirring during the pretreatment, and the rotation speed is not particularly limited.

前記事前処理は、非油溶性固形分の一種である風味成分としてカカオマス及び/又はココアパウダーを使用する態様において特に有用である。このような高温での事前処理を行なうことで、メイラード反応を進行させて、チョコレート様食品が呈するチョコレート風味を増強させることができる。この際、カカオマス及び/又はココアパウダーに含まれる無脂カカオ分100重量部に対するカカオマス及び又はココアパウダーに含まれる油脂分及びそれらに加えて事前加熱処理時に別途追加する油脂分の合計含有量が50~400重量部であることが好ましい。当該油脂分の合計含有量が50重量部未満になると、混合物の粘度が上がり、混合物の取扱いが難しくなったり、加熱の際に攪拌効率が悪くなって局所的に高温になり、風味が悪化する場合がある。400重量部を超えると、無脂カカオ分の比率に対して油脂の比率が多くなりすぎて、加熱により劣化する油脂の比率が高くなり効率が悪くなる場合がある。なおここで、無脂カカオ分の含有量は、チョコレート様食品全体中3~35重量%が好ましい。但し、前記事前加熱処理時に別途追加する油脂分および加熱処理後に別途追加する油脂分は、チョコレート様食品に含まれる油脂の含有量がチョコレート様食品中27~50重量%になるよう、調整することが好ましい。 Said pretreatment is particularly useful in embodiments using cocoa mass and/or cocoa powder as a flavor ingredient, which is one type of non-oil soluble solids. By performing such a high-temperature pretreatment, the Maillard reaction can be advanced and the chocolate flavor exhibited by the chocolate-like food can be enhanced. At this time, the total content of fats and oils contained in cocoa mass and/or cocoa powder and fats and oils separately added during preheating in addition to them is 50 parts by weight per 100 parts by weight of non-fat cacao contained in cocoa mass and/or cocoa powder. It is preferably ~400 parts by weight. If the total content of the oils and fats is less than 50 parts by weight, the viscosity of the mixture increases, making it difficult to handle the mixture, or the efficiency of stirring during heating deteriorates, resulting in localized high temperatures and poor flavor. Sometimes. If the amount is more than 400 parts by weight, the ratio of fats and oils to the fat-free cacao content becomes too large, and the ratio of fats and oils that deteriorate due to heating increases, resulting in poor efficiency. Here, the content of non-fat cacao is preferably 3 to 35% by weight of the whole chocolate-like food. However, the oil and fat content separately added during the pre-heating treatment and the oil and fat content separately added after the heat treatment are adjusted so that the content of oil and fat contained in the chocolate-like food is 27 to 50% by weight in the chocolate-like food. is preferred.

本発明によると、前記油脂の溶融物と前記非油溶性固形分を40~80℃の温度下で500~30000rpmの回転数で攪拌混合しながら、前記油脂と前記非油溶性固形分との撹拌混合物中の水分量が2重量%以下になるまで減圧処理することが好ましい。より好ましい水分量は1.5重量%以下であり、さらに好ましくは1%重量以下である。減圧処理を行なうことで、撹拌混合物中の水分量を低減することができ、これにより、チョコレート様食品の融解時の粘度が低下するため、チョコレート様食品に、工業的に利用可能な加工性(例えばコーティング性)を付与することができる。減圧処理後の水分量が2重量%を超えると、チョコレート様食品を製造する過程で粘度が高くなりすぎてチョコレート様食品を製造できなかったり、製造されたチョコレート様食品の加工性が十分でなかったり、また、前記油脂としてラウリン系の代用脂を配合した場合には経時的に油脂が加水分解してラウリン酸が遊離し、結果、チョコレート様食品の風味が悪化する場合がある。 According to the present invention, the melt of the fat and the oil-insoluble solid are stirred and mixed at a temperature of 40 to 80° C. and a rotation speed of 500 to 30000 rpm, while stirring the fat and the oil-insoluble solid. It is preferable to carry out the vacuum treatment until the water content in the mixture becomes 2% by weight or less. More preferably, the water content is 1.5% by weight or less, and more preferably 1% by weight or less. By performing decompression treatment, it is possible to reduce the amount of water in the stirred mixture, which reduces the viscosity of the chocolate-like food when it is melted. For example, coating properties) can be imparted. If the water content after the decompression treatment exceeds 2% by weight, the viscosity becomes too high during the process of producing the chocolate-like food, making it impossible to produce the chocolate-like food, or the produced chocolate-like food does not have sufficient processability. In addition, when a laurin-based substitute fat is blended as the fat and oil, the fat and oil hydrolyze over time to release lauric acid, and as a result, the flavor of the chocolate-like food may deteriorate.

当該減圧処理は、撹拌混合物中の水分量が特定量以下になるまで実施すればよく、その際の減圧度や時間は特に限定されないが、一例として、50~2000Paの圧力で20~120分間減圧処理を行えばよい。 The decompression treatment may be performed until the amount of water in the stirred mixture becomes a specific amount or less, and the degree of decompression and time at that time are not particularly limited. Processing should be performed.

前記減圧処理は、40~80℃の温度下、500~30000rpmの回転数で攪拌混合を始めると同時に、又はその直後に開始してもよいが、前記減圧処理による脱水効率、及び減圧処理時の発泡抑制の観点から、常圧で前記撹拌混合を開始した後、油脂と非油溶性固形分との撹拌混合物の粘度が10Pa・s以下になってから前記減圧処理を開始することが好ましい。 The reduced pressure treatment may be started at the same time as or immediately after starting stirring and mixing at a temperature of 40 to 80 ° C. and a rotation speed of 500 to 30000 rpm, but the dehydration efficiency by the reduced pressure treatment, and during the reduced pressure treatment From the viewpoint of suppressing foaming, it is preferable to start the depressurization treatment after starting the stirring and mixing at normal pressure and after the viscosity of the stirred mixture of the fat and oil-insoluble solid content becomes 10 Pa·s or less.

前記減圧処理によって油脂と非油溶性固形分との撹拌混合物を得た後、該撹拌混合物に対し、定法に従って成型及び冷却固化工程を行なうことで、チョコレート様食品を得ることができる。 After obtaining a stirred mixture of fats and oils and non-oil-soluble solids by the vacuum treatment, a chocolate-like food can be obtained by subjecting the stirred mixture to molding and cooling and solidification steps according to a conventional method.

本発明により得られたチョコレート様食品は、そのまま食用として用いることもできるし、コーティング用途、サンド用途、フィリング用途、混ぜ込み用途などにおいて、パンや菓子など様々な食品に対し用いることができる。本発明により得られたチョコレート様食品は、コーティング性が良好であるため、コーティング用途において特に好適に用いることができる。 The chocolate-like food obtained by the present invention can be used for food as it is, or can be used for various food such as bread and confectionery for coating, sandwich, filling, mixing and the like. Since the chocolate-like food obtained by the present invention has good coating properties, it can be used particularly preferably in coating applications.

以下に実施例を示し、本発明をより具体的に説明するが、本発明はこれらの実施例に何ら限定されるものではない。なお、実施例において「部」や「%」は重量基準である。 EXAMPLES The present invention will be described in more detail with reference to examples below, but the present invention is not limited to these examples. In addition, "parts" and "%" in the examples are based on weight.

<粘度の測定>
粘度は、サンプルを45℃に温調してBM型粘度計(東機産業株式会社製)を使用して測定した。
<Measurement of viscosity>
The viscosity was measured by adjusting the temperature of the sample to 45° C. and using a BM type viscometer (manufactured by Toki Sangyo Co., Ltd.).

<水分量の測定方法>
水分量は、カールフィッシャー水分計(メトローム社製「860KF Thermoprep」、「801 Stirrer」、又は「900Touch Control」)を用いて気化法により測定した。
<Method for measuring water content>
The moisture content was measured by a vaporization method using a Karl Fischer moisture meter ("860KF Thermoprep", "801 Stirrer", or "900Touch Control" manufactured by Metrohm).

<油脂の上昇融点の測定方法>
油脂の上昇融点は、チョコレート様食品から定法により油脂を抽出し、「日本油化学会制定 基準油脂分析試験法2.2.4.2(1996)1996年版」に準拠して測定した。
<Method for measuring rising melting point of fats and oils>
The rising melting point of fats and oils was determined by extracting fats and oils from chocolate-like foods by a standard method and measuring them in accordance with "Japan Oil Chemistry Society Standard Fat Analysis Test Method 2.2.4.2 (1996) 1996 Edition".

<平均粒径の測定方法>
チョコレート様食品中の非油溶性固形分の平均粒径は、チョコレート様食品をサンプルとして、レーザー回折/散乱式粒子分布測定装置(堀場製作所社製「LA-920」)を用い、アイソパーHを分散媒として測定し、算術平均径として得られた値を平均粒径とした。
<Method for measuring average particle size>
The average particle size of the non-oil-soluble solids in the chocolate-like food was measured using a laser diffraction/scattering particle distribution analyzer ("LA-920" manufactured by Horiba, Ltd.) using the chocolate-like food as a sample, and isopar H was dispersed. The value obtained as the arithmetic mean diameter was taken as the average particle diameter.

<リファイニング(粉砕)後の洗浄性>
乾式粉砕の場合は、市販のブラシ付き掃除機を使用し、粉体の付着が目立たなくなるまで洗浄を行った。湿式粉砕の場合は、40℃に保温した菜種油をキムタオルにしみこませながら拭いて、粉体の付着が目立たなくなるまで洗浄を行った。これらの洗浄に要した時間に基づいて下記評価基準に基づいて洗浄性を評価した。
◎:洗浄時間が、比較例1に比べて70%以上短縮する
○:洗浄時間が、比較例1に比べて40%以上、70%未満短縮する
△:洗浄時間が、比較例1に比べて10%以上、40%未満短縮する
×:洗浄時間が、比較例1に比べて10%未満短縮、もしくは同等以上かかる
<Washability after refining (grinding)>
In the case of dry pulverization, cleaning was carried out using a commercially available vacuum cleaner with a brush until adhesion of powder became inconspicuous. In the case of wet pulverization, rapeseed oil kept at 40° C. was soaked in Kimtowel and wiped until the adhesion of powder became inconspicuous. Based on the time required for these washings, the washability was evaluated according to the following evaluation criteria.
◎: The cleaning time is shortened by 70% or more compared to Comparative Example 1 ○: The cleaning time is shortened by 40% or more and less than 70% compared to Comparative Example 1 △: The cleaning time is shortened compared to Comparative Example 1 Reduced by 10% or more and less than 40% ×: The cleaning time is reduced by less than 10% compared to Comparative Example 1, or it takes the same amount or more.

<コンチング(撹拌混和)後の洗浄性>
撹拌操作にAGI HOMO MIXERを使用した場合は、80℃の温水に中性洗剤を少量加えた温水を用いて、2回10000rpmで付着がなくなるまでホモミキサーで攪拌して洗浄した後、80℃の温水を用いて2回同様に洗浄して洗剤を洗い落とした。AGI HOMO MIXERを使用しない場合(比較例1)は、60℃に加熱した菜種油をコンチング用のミキサーに加え、付着が落ちるまで菜種油を交換しながら洗浄した。これらの洗浄に要した時間に基づいて下記評価基準に基づいて洗浄性を評価した。
◎:洗浄時間が、比較例1に比べて70%以上短縮する
○:洗浄時間が、比較例1に比べて40%以上、70%未満短縮する
△:洗浄時間が、比較例1に比べて10%以上、40%未満短縮する
×:洗浄時間が、比較例1に比べて10%未満短縮、もしくは同等以上かかる
<Washability after conching (stirring and mixing)>
When AGI HOMO MIXER is used for the stirring operation, use warm water of 80°C with a small amount of neutral detergent added and wash with a homomixer twice at 10,000 rpm until the adhesion disappears. The detergent was washed off by washing twice with warm water in the same manner. When the AGI HOMO MIXER was not used (Comparative Example 1), rapeseed oil heated to 60°C was added to the mixer for conching, and washing was performed while changing the rapeseed oil until the adhesion was removed. Based on the time required for these washings, the washability was evaluated according to the following evaluation criteria.
◎: The cleaning time is shortened by 70% or more compared to Comparative Example 1 ○: The cleaning time is shortened by 40% or more and less than 70% compared to Comparative Example 1 △: The cleaning time is shortened compared to Comparative Example 1 Reduced by 10% or more and less than 40% ×: The cleaning time is reduced by less than 10% compared to Comparative Example 1, or it takes the same amount or more.

<チョコレート様食品の官能評価>
実施例及び比較例のチョコレート様食品を、熟練した10名のパネラーにそのまま食べてもらい、風味と食感に関して以下の基準により官能評価を実施し、各人の評価値の平均点を各表に記載した。なお、風味に関しては実施例1~7及び比較例1~6のみ以下の基準で評価した。
<Sensory evaluation of chocolate-like food>
The chocolate-like foods of Examples and Comparative Examples were eaten by 10 skilled panelists as they were, and the flavor and texture were sensory evaluated according to the following criteria. Described. Regarding the flavor, only Examples 1 to 7 and Comparative Examples 1 to 6 were evaluated according to the following criteria.

(風味)
5点:比較例1のチョコレート様食品よりも、風味素材の風味が強く感じられて大変良い
4点:比較例1のチョコレート様食品と同等で、風味素材の風味が感じられて良い
3点:比較例1のチョコレート様食品よりも、風味素材の風味が弱く感じられるが品質的に問題ない
2点:比較例1のチョコレート様食品よりも、風味素材の風味が明らかに弱く感じられて悪い
1点:比較例1のチョコレート様食品よりも、風味素材の風味が全く感じられず大変悪い
(flavor)
5 points: The flavor of the flavor material is felt stronger than the chocolate-like food of Comparative Example 1, and it is very good. 4 points: It is the same as the chocolate-like food of Comparative Example 1, and the flavor of the flavor material is good. 3 points: The flavor of the flavor material is felt to be weaker than that of the chocolate-like food of Comparative Example 1, but there is no quality problem. Point: Compared to the chocolate-like food of Comparative Example 1, the flavor of the flavor material is not felt at all, and it is very bad.

(食感)
5点:比較例1のチョコレート様食品と同等で、滑らかな口当たりで、ザラツキを全く感じず大変良い
4点:比較例1のチョコレート様食品よりも、滑らかな口当たりが若干劣るが、ザラツキは感じず良い
3点:比較例1のチョコレート様食品よりも、滑らかな口当たりが劣るが問題ない
2点:比較例1のチョコレート様食品よりも、口当たりが劣り、ザラツキが少し感じられて悪い
1点:比較例1のチョコレート様食品よりも、口当たりが明らかに劣り、ザラツキが感じられて大変悪い
(texture)
5 points: Equivalent to the chocolate-like food of Comparative Example 1, smooth mouthfeel, very good without feeling rough 4 points: Slightly inferior smooth mouthfeel than the chocolate-like food of Comparative Example 1, but feeling rough Poorly good 3 points: Smooth texture is inferior to the chocolate-like food of Comparative Example 1, but there is no problem 2 points: The texture is inferior to the chocolate-like food of Comparative Example 1, and the roughness is slightly felt 1 point: The mouthfeel is clearly inferior to the chocolate-like food of Comparative Example 1, and the texture is very bad.

<コーティング性の評価>
実施例及び比較例のチョコレート様食品をクッキーにコーティングし、コーティング性を評価した。該コーティングは次のようにして行った。チョコレート様食品を45℃に加熱融解して200mlのステンレスビーカーに150g充填し、クッキーを2秒間浸して持ち上げ、チョコレート様食品がしたたり落ちなくなるまで保持し、その後室温で冷却して固化させた。
◎:比較例1のチョコレート様食品よりも、コーティングの厚みが非常に適切で、チョコレート様食品とクッキーの風味、食感のバランスが大変良い
〇:比較例1のチョコレート様食品と同等で、コーティングの厚みが適切で、チョコレート様食品とクッキーの風味、食感のバランスが良い
△:比較例1のチョコレート様食品よりも、コーティングが厚い、もしくは薄く、チョコレート様食品とクッキーの風味、食感のバランスがやや崩れていて悪い
×:比較例1のチョコレート様食品よりも、コーティングが厚すぎる、もしくは薄すぎるため、チョコレート様食品とクッキーの風味、食感のバランスが崩れていて大変悪い
<Evaluation of Coatability>
Cookies were coated with the chocolate-like food products of Examples and Comparative Examples, and coating properties were evaluated. The coating was carried out as follows. The chocolate-like food was melted by heating to 45° C., and 150 g of the chocolate-like food was filled in a 200-ml stainless steel beaker. The cookie was soaked for 2 seconds, lifted, held until the chocolate-like food stopped dripping, and then cooled at room temperature to solidify.
◎: The thickness of the coating is much more appropriate than the chocolate-like food of Comparative Example 1, and the balance between the flavor and texture of the chocolate-like food and the cookie is very good. The thickness is appropriate, and the flavor and texture of the chocolate-like food and cookie are well balanced. △: The coating is thicker or thinner than the chocolate-like food of Comparative Example 1, and the flavor and texture of the chocolate-like food and cookie are better The balance is slightly unbalanced and bad ×: The coating is too thick or too thin compared to the chocolate-like food of Comparative Example 1, so the chocolate-like food and the cookie flavor and texture are out of balance and very bad.

<実施例及び比較例で使用した原料>
1)Olam社製「デザーンココアパウダー」(油脂分:11重量%、無脂カカオ分85重量%)
2)三井製糖(株)製「スプーン印グラニュ糖」
3)松谷化学工業(株)製「タピオカスターチ」
4)(株)カネカ製「パーム核分別硬質部極度硬化油」(上昇融点35.9℃)
5)ADM社製「Yelkin TS」
6)塩野香料(株)製「バニリン」
7)愛国産業(株)製「全糖粉糖」
8)HILMAR CHEESE(株)製「ラクトース HILMAR FINE GRAIND」
9)松谷化学工業(株)製「パインデックス#1」
10)富田製薬(株)製「トミタソルト」
11)扶桑化学工業(株)製「酒石酸」
12)ジボダンジャパン(株)製「RF-C-DM」
13)日研フード(株)製「昆布エキスパウダーCN」
14)ライオンケミカル(株)製「ハイアルファSF」
<Raw materials used in Examples and Comparative Examples>
1) Olam's "Design Cocoa Powder" (oil content: 11% by weight, non-fat cacao content: 85% by weight)
2) Mitsui Sugar Co., Ltd. “Spoon Brand Granulated Sugar”
3) “Tapioca Starch” manufactured by Matsutani Chemical Industry Co., Ltd.
4) Kaneka Co., Ltd. “Extremely hardened palm kernel fraction hard part oil” (rising melting point 35.9°C)
5) "Yelkin TS" manufactured by ADM
6) "Vanillin" manufactured by Shiono Koryo Co., Ltd.
7) Aikoku Sangyo Co., Ltd. “whole sugar powdered sugar”
8) "Lactose HILMAR FINE GRAIN" manufactured by HILMAR CHEESE Co., Ltd.
9) Matsutani Chemical Industry Co., Ltd. "Paindex # 1"
10) "Tomita Salt" manufactured by Tomita Pharmaceutical Co., Ltd.
11) "Tartaric acid" manufactured by Fuso Chemical Industry Co., Ltd.
12) "RF-C-DM" manufactured by Givaudan Japan Co., Ltd.
13) “Konbu Extract Powder CN” manufactured by Nikken Foods Co., Ltd.
14) “High Alpha SF” manufactured by Lion Chemical Co., Ltd.

(実施例1) チョコレート様食品の作製
表1の配合に従いチョコレート様食品を作製した。即ち、まず、ココアパウダー、グラニュー糖、及びタピオカスターチを混合(コアパウダー、グラニュー糖、及びタピオカスターチの混合物100重量部に含まれる油脂含量:2.6重量%)し、ピンミル(ホソカワミクロン株式会社製「UPZ160」)を用いて18000rpmで粉砕して非油溶性固形分の粉砕物を調製した。
(Example 1) Preparation of chocolate-like food A chocolate-like food was prepared according to the composition shown in Table 1. That is, first, cocoa powder, granulated sugar, and tapioca starch are mixed (oil content in 100 parts by weight of mixture of core powder, granulated sugar, and tapioca starch: 2.6% by weight), and a pin mill (manufactured by Hosokawa Micron Corporation "UPZ160") was used to grind at 18000 rpm to prepare a ground product of non-oil-soluble solids.

得られた粉砕物に、60℃で溶融したパーム核分別硬質部の極度硬化油と、レシチン、及びバニリンを混合した。得られた混合物を、60℃の温度下で、コンビミクス(プライミクス株式会社製「AGI HOMO MIXER 2M-1」)を使用し、パドルの回転数は30rpm、ホモミキサーの回転数は6000rpmとして撹拌しながら、混合物の粘度が7.8Pa・sになった時点で、減圧を開始した。同じ条件で撹拌しながら、0.5kPaの圧力で60分間減圧処理を行った。減圧処理後の混合物を35℃に冷却した後、容器に充填し冷却固化して、チョコレート様食品を得た。得られたチョコレート様食品の評価結果を表1に示した。 The obtained pulverized material was mixed with extremely hardened oil of fractionated hard part of palm kernel melted at 60° C., lecithin, and vanillin. The resulting mixture was stirred at a temperature of 60° C. using Combimix (“AGI HOMO MIXER 2M-1” manufactured by Primix Co., Ltd.) at a paddle rotation speed of 30 rpm and a homomixer rotation speed of 6000 rpm. However, when the viscosity of the mixture reached 7.8 Pa·s, pressure reduction was started. While stirring under the same conditions, vacuum treatment was performed at a pressure of 0.5 kPa for 60 minutes. After cooling the mixture after the decompression treatment to 35° C., it was filled in a container and solidified by cooling to obtain a chocolate-like food. Table 1 shows the evaluation results of the obtained chocolate-like food.

Figure 0007265335000001
Figure 0007265335000001

(実施例2) チョコレート様食品の作製
表1の配合に従って、実施例1において、ココアパウダー、グラニュー糖、及びタピオカスターチの混合比率は同じで、これらの合計配合量を67.7重量部から55.0重量部に変更し、油脂の配合量を32.24重量部から44.98重量部に変更し、レシチンの配合量を0.05重量部から0.01重量部に変更した以外は、実施例1と同様にして、チョコレート様食品を得た。得られたチョコレート様食品の評価結果を表1に示した。
(Example 2) Preparation of chocolate-like food According to the formulation in Table 1, in Example 1, the mixing ratio of cocoa powder, granulated sugar, and tapioca starch was the same, and the total blending amount was changed from 67.7 parts by weight to 55 parts by weight. 0 parts by weight, the amount of fats and oils was changed from 32.24 parts by weight to 44.98 parts by weight, and the amount of lecithin was changed from 0.05 parts by weight to 0.01 parts by weight. A chocolate-like food was obtained in the same manner as in Example 1. Table 1 shows the evaluation results of the obtained chocolate-like food.

(比較例1) チョコレート様食品の作製
表1の配合に従って、実施例1において、レシチンの配合量を0.05重量部から0.3重量部に変更し、この増加分を油脂の配合量で調整した。まず、ココアパウダー、グラニュー糖、及びタピオカスターチと油脂21.0重量部を混合し、ロールミルを二回通して粉砕を行った。粉砕した混合物を55℃で4時間攪拌してコンチングを行った後、レシチン、及び残りの油脂10.99重量部を添加してチョコレート様食品を得た。得られたチョコレート様食品の評価結果を表1に示した。
(Comparative Example 1) Preparation of chocolate-like food According to the formulation in Table 1, in Example 1, the blending amount of lecithin was changed from 0.05 parts by weight to 0.3 parts by weight, and this increase was the blending amount of fats and oils. It was adjusted. First, cocoa powder, granulated sugar, tapioca starch, and 21.0 parts by weight of oil were mixed and pulverized by passing through a roll mill twice. After conching the pulverized mixture by stirring at 55° C. for 4 hours, lecithin and 10.99 parts by weight of the remaining oil were added to obtain a chocolate-like food. Table 1 shows the evaluation results of the obtained chocolate-like food.

(比較例2) チョコレート様食品の作製
表1の配合に従って、実施例1において、ココアパウダー、グラニュー糖、及びタピオカスターチの混合比率は同じで、これらの合計配合量を67.7重量部から45.0重量部に変更し、油脂の配合量を32.24重量部から54.98重量部に変更し、レシチンの配合量を0.05重量部から0.01重量部に変更した以外は、実施例1と同様にして、チョコレート様食品を得た。得られたチョコレート様食品の評価結果を表1に示した。
(Comparative Example 2) Preparation of chocolate-like food According to the formulation in Table 1, the mixing ratio of cocoa powder, granulated sugar, and tapioca starch was the same as in Example 1, and the total blending amount was changed from 67.7 parts by weight to 45 parts by weight. 0 parts by weight, the amount of fats and oils was changed from 32.24 parts by weight to 54.98 parts by weight, and the amount of lecithin was changed from 0.05 parts by weight to 0.01 parts by weight. A chocolate-like food was obtained in the same manner as in Example 1. Table 1 shows the evaluation results of the obtained chocolate-like food.

(比較例3) チョコレート様食品の作製
表1の配合に従って、実施例1において、ココアパウダー、グラニュー糖、及びタピオカスターチの混合比率は同じで、これらの合計配合量を67.7重量部から75.7重量部に変更し、油脂の配合量を32.24重量部から24.24重量部に変更した以外は、実施例1と同様にして、チョコレート様食品を得ようと試みたが、撹拌混合物の粘度が高くなりすぎて製造できなかった。
(Comparative Example 3) Preparation of chocolate-like food According to the formulation in Table 1, the mixing ratio of cocoa powder, granulated sugar, and tapioca starch was the same as in Example 1, and the total blending amount was changed from 67.7 parts by weight to 75 parts by weight. An attempt was made to obtain a chocolate-like food in the same manner as in Example 1, except that the amount of oil was changed from 32.24 parts by weight to 24.24 parts by weight. The mixture became too viscous to manufacture.

表1から明らかなように、チョコレート様食品中の油脂の含有量が27~50重量%の範囲にあるチョコレート様食品(実施例1及び2)は、リファイニング後及びコンチング後の洗浄性、風味、食感、コーティング性の何れも良好であった。一方、チョコレート様食品中の油脂の含有量が56.2重量部のチョコレート様食品(比較例2)は、コーティング性が悪かった。また、チョコレート様食品中の油脂の含有量が26.3重量部で、非油溶性固形分の含有量が73.8重量部のチョコレート様食品(比較例3)は、撹拌混合物の粘度が高くなりすぎて製造できなかった。また、従来の製造方法で作製したチョコレート様食品(比較例1)は、風味、食感及びコーティング性は良好であったが、コンチングに時間がかかり、また、リファイニング後及びコンチング後の洗浄性が悪く、非常に時間がかかった。 As is clear from Table 1, the chocolate-like food (Examples 1 and 2) having a fat content in the chocolate-like food in the range of 27 to 50 wt. , texture and coating properties were all good. On the other hand, the chocolate-like food containing 56.2 parts by weight of oil and fat (Comparative Example 2) had poor coating properties. In addition, the chocolate-like food (Comparative Example 3) in which the content of oil and fat in the chocolate-like food is 26.3 parts by weight and the content of non-oil-soluble solids is 73.8 parts by weight, the viscosity of the stirred mixture is high. I couldn't manufacture it because it was too much. In addition, the chocolate-like food produced by the conventional production method (Comparative Example 1) had good flavor, texture and coating properties, but it took a long time to conching, and it was difficult to wash after refining and after conching. bad and very time consuming.

(実施例3) チョコレート様食品の作製
表2の配合に従い、実施例1において、ココアパウダー、グラニュー糖、及びタピオカスターチの混合物の粉砕方法を、ピンミルからボールミル(入江商会株式会社製「卓上型ボールミル回転架台V-2」、外寸法200×200mmのポットを使用)に変更した以外は、実施例1と同様にして、チョコレート様食品を得た。得られたチョコレート様食品の評価結果を表2に示した。
(Example 3) Preparation of chocolate-like food According to the formulation in Table 2, in Example 1, the method of pulverizing the mixture of cocoa powder, granulated sugar, and tapioca starch was changed from a pin mill to a ball mill (manufactured by Irie Shokai Co., Ltd. "Tabletop ball mill A chocolate-like food was obtained in the same manner as in Example 1, except that the rotation stand V-2" and a pot with an outer size of 200 × 200 mm was used). Table 2 shows the evaluation results of the obtained chocolate-like food.

Figure 0007265335000002
Figure 0007265335000002

(実施例4) チョコレート様食品の作製
表2の配合に従い、実施例1において、グラニュー糖を粉糖に変更し、ピンミルによる粉砕を行わずにそのまま他の成分と混合した以外は、実施例1と同様にして、チョコレート様食品を得た。得られたチョコレート様食品の評価結果を表2に示した。
(Example 4) Preparation of chocolate-like food According to the formulation in Table 2, in Example 1, the granulated sugar was changed to powdered sugar, and it was mixed with other ingredients as it was without pulverizing with a pin mill. A chocolate-like food was obtained in the same manner. Table 2 shows the evaluation results of the obtained chocolate-like food.

(比較例4) チョコレート様食品の作製
表2の配合に従い、実施例3において、グラニュー糖を粉糖と乳糖に変更し、ピンミルによる粉砕を行わずにそのまま他の成分と混合した以外は、実施例3と同様にして、チョコレート様食品を得た。得られたチョコレート様食品の評価結果を表2に示した。
(Comparative Example 4) Preparation of chocolate-like food According to the formulation in Table 2, in Example 3, the granulated sugar was changed to powdered sugar and lactose, and the other ingredients were mixed as they were without being pulverized with a pin mill. A chocolate-like food was obtained in the same manner as in Example 3. Table 2 shows the evaluation results of the obtained chocolate-like food.

表2から明らかなように、チョコレート様食品中の非油溶性固形分の平均粒径が5~40μmの範囲にあるチョコレート様食品(実施例1、3及び4)は、リファイニング後及びコンチング後の洗浄性、風味、食感、及びコーティング性の何れも良好であった。一方、チョコレート様食品中の非油溶性固形分の平均粒径が43.8μmのチョコレート様食品(比較例3)は、食感にザラツキが感じられた。 As is clear from Table 2, the chocolate-like food (Examples 1, 3 and 4) having an average particle size of non-oil-soluble solids in the chocolate-like food in the range of 5 to 40 μm was after refining and after conching. All of the cleanability, flavor, texture, and coatability were good. On the other hand, the chocolate-like food (Comparative Example 3) in which the non-oil-soluble solid content in the chocolate-like food had an average particle size of 43.8 µm had a rough texture.

(実施例5) チョコレート様食品の作製
表3の配合に従い、実施例1において、減圧処理を開始する時の混合物の粘度を7.8Pa・sから15.0Pa・sに変更した以外は、実施例1と同様にして、チョコレート様食品を得た。得られたチョコレート様食品の評価結果を表3に示した。
(Example 5) Preparation of chocolate-like food According to the formulation in Table 3, in Example 1, except that the viscosity of the mixture when starting the decompression treatment was changed from 7.8 Pa s to 15.0 Pa s, A chocolate-like food was obtained in the same manner as in Example 1. Table 3 shows the evaluation results of the obtained chocolate-like food.

Figure 0007265335000003
Figure 0007265335000003

表3から明らかなように、減圧処理を開始する時の混合物の粘度が7.8Pa・s(実施例1)又は15.0Pa・s(実施例5)であったチョコレート様食品はいずれも、リファイニング後及びコンチング後の洗浄性、風味、食感、コーティング性の何れも良好であった。但し、減圧処理を開始する時の混合物の粘度が15.0Pa・sのチョコレート様食品(実施例5)は、減圧処理時に発泡が見られ、最終製品の水分量も1.0重量%と若干多くなった。 As is clear from Table 3, the viscosity of the mixture at the start of the reduced pressure treatment was 7.8 Pa s (Example 1) or 15.0 Pa s (Example 5). All of the detergency, flavor, texture, and coatability after refining and conching were good. However, in the chocolate-like food (Example 5) in which the viscosity of the mixture at the start of the reduced pressure treatment was 15.0 Pa s, foaming was observed during the reduced pressure treatment, and the water content of the final product was slightly 1.0% by weight. became many.

(実施例6) チョコレート様食品の作製
表3の配合に従い、実施例1において、まずグラニュー糖だけをピンミルで粉砕した。別途、油脂とココアパウダーを混合したものを、あらかじめ120℃で4分の加熱処理を行った。加熱処理した油脂とココアパウダーの混合物と、粉砕したグラニュー糖、レシチン、タピオカスターチ及びバニリンを混合し、実施例1と同様に、60℃の温度下で、コンビミクス(プライミクス株式会社製「AGI HOMO MIXER 2M-1」)を使用し、パドルの回転数は30rpm、ホモミキサーの回転数は6000rpmとして撹拌しながら、混合物の粘度が8.0Pa・sになった時点で、減圧を開始した。同じ条件で撹拌しながら、60分間減圧処理を行った。減圧処理後の混合物を35℃に冷却した後、容器に充填し冷却固化して、チョコレート様食品を得た。得られたチョコレート様食品の評価結果を表3に示した。
(Example 6) Production of Chocolate-Like Food According to the composition shown in Table 3, in Example 1, first, only granulated sugar was pulverized with a pin mill. Separately, a mixture of oil and cocoa powder was preheated at 120° C. for 4 minutes. A mixture of heat-treated fat and cocoa powder was mixed with pulverized granulated sugar, lecithin, tapioca starch and vanillin. MIXER 2M-1") was used, and the mixture was stirred at a paddle rotation speed of 30 rpm and a homomixer rotation speed of 6000 rpm. Vacuum treatment was performed for 60 minutes while stirring under the same conditions. After cooling the mixture after the decompression treatment to 35° C., it was filled in a container and solidified by cooling to obtain a chocolate-like food. Table 3 shows the evaluation results of the obtained chocolate-like food.

(実施例7) チョコレート様食品の作製
表3の配合に従い、実施例6において、あらかじめ加熱処理する温度を120℃から95℃に、時間を4分間から15分間に変更した以外は、実施例6と同様にして、チョコレート様食品を得た。得られたチョコレート様食品の評価結果を表3に示した。
(Example 7) Preparation of chocolate-like food According to the formulation in Table 3, in Example 6, except that the temperature for heat treatment was changed from 120 ° C. to 95 ° C. and the time was changed from 4 minutes to 15 minutes. A chocolate-like food was obtained in the same manner. Table 3 shows the evaluation results of the obtained chocolate-like food.

表3から明らかなように、油脂とココアパウダーの混合物を90~150℃の温度下で1~60分間加熱処理して得た原料を使用し作製したチョコレート様食品(実施例6及び7)はいずれも、リファイニング後及びコンチング後の洗浄性、風味、食感、及びコーティング性が良好であった。特に、前記加熱処理をしていないチョコレート様食品(実施例1)に比べて、カカオ感が強く感じられて風味がより良好であった。 As is clear from Table 3, chocolate-like foods (Examples 6 and 7) prepared using raw materials obtained by heat-treating a mixture of fat and cocoa powder at a temperature of 90 to 150°C for 1 to 60 minutes All of them were excellent in washability, flavor, texture, and coatability after refining and conching. In particular, compared with the chocolate-like food (Example 1) which was not heat-treated, the cacao feeling was stronger and the flavor was better.

(実施例8)チョコレート様食品の作製
表3の配合に従い、実施例1において、減圧処理中の攪拌時間を60分から15分に変更した以外は実施例1と同様にしてチョコレート様食品を得た。得られたチョコレート様食品の評価結果を表3に示した。
(Example 8) Preparation of chocolate-like food A chocolate-like food was obtained in the same manner as in Example 1, except that the stirring time during the decompression treatment was changed from 60 minutes to 15 minutes according to the formulation shown in Table 3. . Table 3 shows the evaluation results of the obtained chocolate-like food.

表3から明らかなように、攪拌時間を60分から15分にして作製したチョコレート様食品は、リファイニング後及びコンチング後の洗浄性、風味、食感、及びコーティング性が良好であった。しかし、コンチング時間が短いため、実施例1で作製したチョコレート様食品と比べると、カカオの雑味が残って風味がやや低く、また食感にもややざらつきが残ったが、問題のないレベルであった。 As is clear from Table 3, the chocolate-like foods prepared with stirring times of 60 minutes to 15 minutes had good washability, flavor, texture, and coatability after refining and conching. However, since the conching time was short, compared to the chocolate-like food prepared in Example 1, the cacao taste remained slightly low, and the texture remained slightly rough, but it was at a level that did not pose a problem. there were.

(比較例5) チョコレート様食品の作製
表3の配合に従い、実施例1において、攪拌時の温度を60℃から30℃に変更した以外は、実施例1と同様にして、チョコレート様食品を得ようと試みたが、撹拌混合物の粘度が高くなりすぎて製造できなかった。
(Comparative Example 5) Preparation of chocolate-like food A chocolate-like food was obtained in the same manner as in Example 1, except that the temperature during stirring was changed from 60°C to 30°C according to the composition shown in Table 3. However, the stirred mixture became too viscous to produce.

(比較例6) チョコレート様食品の作製
表3の配合に従い、実施例1において、攪拌時にホモミキサーを使用せず、パドルのみを回転数150rpmで作動させて攪拌した以外は実施例1と同様にしてチョコレート様食品を得た。得られたチョコレート様食品の評価結果を表3に示した。
(Comparative Example 6) Preparation of chocolate-like food According to the composition shown in Table 3, the procedure of Example 1 was repeated except that the homomixer was not used during stirring, and only the paddle was operated at a rotation speed of 150 rpm for stirring. and obtained a chocolate-like food. Table 3 shows the evaluation results of the obtained chocolate-like food.

表3から明らかなように、撹拌混合時の回転数が150rpmと小さかった比較例6で得られたチョコレート様食品は、食感にザラツキが感じられた。 As is clear from Table 3, the chocolate-like food obtained in Comparative Example 6, in which the number of revolutions during stirring and mixing was as low as 150 rpm, had a rough texture.

(比較例7) チョコレート様食品の作製
表3の配合に従い、実施例1において、攪拌時に減圧を行わずに常圧で行った以外は実施例1と同様にしてチョコレート様食品を得た。得られたチョコレート様食品の評価結果を表3に示した。
(Comparative Example 7) Preparation of chocolate-like food A chocolate-like food was obtained in the same manner as in Example 1 according to the composition shown in Table 3, except that the stirring was carried out under normal pressure without reducing the pressure during stirring. Table 3 shows the evaluation results of the obtained chocolate-like food.

表3から明らかなように、減圧を行わずにチョコレート様食品を作製したため、水分が残存してチョコレート様食品の融解時の粘度が上がることからコーティング性が悪化した。また、カカオ成分の雑味が残るため風味もやや低くなった。 As is clear from Table 3, since the chocolate-like food was produced without reducing the pressure, moisture remained and the viscosity of the chocolate-like food when melted increased, resulting in poor coating properties. In addition, since the cacao component left a rough taste, the flavor was slightly lowered.

(実施例9) チョコレート様食品の作製(バター風味)
表4の配合に従い、チョコレート様食品を作製した。即ち、まず、乳糖及び塩をボールミルで粉砕して非油溶性固形分の粉砕物を調製した後、該粉砕物に、60℃で溶融したパーム核分別硬質部の極度硬化油と、レシチン、着色料、及びバターフレーバーを混合した以外は、実施例1と同様にしてバター風味のチョコレート様食品を得た。得られたチョコレート様食品の評価結果を表4に示した。
(Example 9) Preparation of chocolate-like food (butter flavor)
According to the composition of Table 4, a chocolate-like food was produced. That is, first, lactose and salt are pulverized in a ball mill to prepare a pulverized product of non-oil-soluble solids, and then the pulverized product is added with extremely hardened oil of hard part fractionated palm kernel melted at 60 ° C., lecithin, and coloring. A butter-flavored chocolate-like food was obtained in the same manner as in Example 1, except that the ingredients and butter flavor were mixed. Table 4 shows the evaluation results of the obtained chocolate-like food.

Figure 0007265335000004
Figure 0007265335000004

(実施例10) チョコレート様食品の作製(レモン風味)
表4の配合に従い、チョコレート様食品を作製した。即ち、まず、乳糖、デキストリン、及び酒石酸をボールミルで粉砕して非油溶性固形分の粉砕物を調製した後、60℃で溶融したパーム核分別硬質部の極度硬化油と、レシチン、着色料、及びレモンフレーバーを混合した以外は、実施例1と同様にしてレモン風味のチョコレート様食品を得た。得られたチョコレート様食品の評価結果を表4に示した。
(Example 10) Preparation of chocolate-like food (lemon flavor)
According to the composition of Table 4, a chocolate-like food was produced. That is, first, lactose, dextrin, and tartaric acid are pulverized in a ball mill to prepare a pulverized product of non-oil-soluble solids, and then the extremely hardened oil of the hard part of palm kernel fraction melted at 60 ° C., lecithin, a coloring agent, And a lemon-flavored chocolate-like food was obtained in the same manner as in Example 1 except that lemon flavor was mixed. Table 4 shows the evaluation results of the obtained chocolate-like food.

(実施例11) チョコレート様食品の作製(チーズ風味)
表4の配合に従い、チョコレート様食品を作製した。即ち、まず、乳糖、デキストリン、塩、酵母エキス、及び昆布エキスをボールミルで粉砕して非油溶性固形分の粉砕物を調製した後、60℃で溶融したパーム核分別硬質部の極度硬化油と、レシチン、着色料、及びチーズフレーバーを混合した以外は、実施例1と同様にしてチーズ風味のチョコレート様食品を得た。得られたチョコレート様食品の評価結果を表4に示した。
(Example 11) Preparation of chocolate-like food (cheese flavor)
According to the composition of Table 4, a chocolate-like food was produced. That is, first, lactose, dextrin, salt, yeast extract, and kelp extract are pulverized in a ball mill to prepare a pulverized product of non-oil-soluble solids, and then the extremely hardened oil of the hard part of palm kernel fraction melted at 60 ° C. , lecithin, colorant, and cheese flavor were mixed in the same manner as in Example 1 to obtain a cheese-flavored chocolate-like food. Table 4 shows the evaluation results of the obtained chocolate-like food.

表4から明らかなように、実施例9~11のチョコレート様食品はいずれも、リファイニング後及びコンチング後の洗浄性、食感、及びコーティング性が良好であった。また、いずれのチョコレート様食品も、配合した風味素材由来の風味が十分に感じられて良好であった。
As is clear from Table 4, all of the chocolate-like food products of Examples 9 to 11 had good washability, texture, and coatability after refining and conching. Moreover, all the chocolate-like foodstuffs were good because the flavor derived from the blended flavoring material was felt sufficiently.

Claims (3)

チョコレート様食品全体中、油脂を27~50重量%と、非油溶性固形分49.5~72.5重量%とを含み、油脂と非油溶性固形分とを合計で90重量%以上含むチョコレート様食品の製造方法であって、
油脂を溶融させて溶融物とし、
前記油脂の溶融物と前記非油溶性固形分を、40~80℃の温度下、500~30000rpmの回転数で攪拌混合によりコンチングしながら、水分量が2重量%以下になるまで減圧処理する工程を含み、
前記非油溶性固形分は、乾式粉砕されたものであり、
チョコレート様食品中の非油溶性固形分の平均粒径が5~40μmであることを特徴とする、チョコレート様食品の製造方法。
A chocolate containing 27 to 50% by weight of fat and 49.5 to 72.5% by weight of non-oil-soluble solids in the entire chocolate-like food, and a total of 90% by weight or more of fats and oils and non-oil-soluble solids. A method for producing a similar food,
Melting fats and oils to form a melt,
A step of depressurizing the melted oil and fat and the non-oil-soluble solid content by stirring and mixing at a temperature of 40 to 80 ° C. and a rotation speed of 500 to 30000 rpm, while reducing the water content to 2% by weight or less. including
The oil-insoluble solid content is dry-pulverized,
A method for producing a chocolate-like food, wherein the oil-insoluble solid content in the chocolate-like food has an average particle size of 5 to 40 μm.
前記油脂の溶融物と前記非油溶性固形分を混合し、40~80℃の温度下、500~30000rpmの回転数で攪拌混合によりコンチングして、撹拌混合物の粘度が10Pa・s以下になってから、前記減圧処理を開始する、請求項1に記載のチョコレート様食品の製造方法。 The melted fat and oil and the non-oil-soluble solids are mixed and conched by stirring and mixing at a temperature of 40 to 80° C. and a rotation speed of 500 to 30000 rpm until the viscosity of the stirred mixture becomes 10 Pa s or less. 2. The method for producing a chocolate-like food according to claim 1, wherein the reduced pressure treatment is started from. 前記非油溶性固形分の乾式粉砕が、ピンミル、ハンマーミル、ボールミル、ジェットミルから選ばれる少なくとも1以上の粉砕装置を用いる粉砕である、請求項1又は2に記載のチョコレート様食品の製造方法。 The method for producing a chocolate-like food according to claim 1 or 2, wherein the dry pulverization of the oil-insoluble solids is pulverization using at least one pulverizer selected from pin mills, hammer mills, ball mills, and jet mills.
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