JP7048267B2 - Oil composition for baked confectionery - Google Patents
Oil composition for baked confectionery Download PDFInfo
- Publication number
- JP7048267B2 JP7048267B2 JP2017218219A JP2017218219A JP7048267B2 JP 7048267 B2 JP7048267 B2 JP 7048267B2 JP 2017218219 A JP2017218219 A JP 2017218219A JP 2017218219 A JP2017218219 A JP 2017218219A JP 7048267 B2 JP7048267 B2 JP 7048267B2
- Authority
- JP
- Japan
- Prior art keywords
- oil
- mass
- fat
- baked confectionery
- oils
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Confectionery (AREA)
- Edible Oils And Fats (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
Description
本発明は、焼菓子生地製造時の作業性が良好であるとともに、表面の白色化現象が抑制されて外観が良好であり且つ食感も良好である焼菓子を製造することができる、焼菓子用油脂組成物に関する。 INDUSTRIAL APPLICABILITY According to the present invention, it is possible to produce a baked confectionery having good workability at the time of producing a baked confectionery dough, suppressing the whitening phenomenon of the surface, having a good appearance, and having a good texture. Regarding oil and fat compositions.
クッキーやビスケット、バターケーキ等の焼菓子と、チョコレート類やクリーム類等の油性菓子とを組合せて製造される複合菓子においては、製造・流通・保存中に、焼菓子の表面が白色化し、外観が損なわれる現象や、複合させたチョコレートの軟化現象・ブルーム現象が発生しやすいことが知られている。 In complex confectionery manufactured by combining baked confectionery such as cookies, biscuits and butter cake with oil-based confectionery such as chocolate and cream, the surface of the baked confectionery becomes white during manufacturing, distribution and storage, and the appearance It is known that the phenomenon of spoiling the chocolate and the softening phenomenon / blooming phenomenon of the complexed chocolate are likely to occur.
これらの現象の発生機序としては、焼菓子と油性菓子との間で発生する油脂移行(マイグレーション)が主因であると推定され、より詳細には、焼菓子から油性菓子への液状油成分(常温で液状の油脂成分を指す)の移行に伴って、焼菓子中の固形脂の結晶粗大化等が起こることにより焼菓子表面の白色化が発生し、またチョコレートの軟化やブルーム現象が発生すると推定されている。 It is presumed that the main cause of these phenomena is the migration of fats and oils between baked confectionery and oil-based confectionery, and more specifically, the liquid oil component from baked confectionery to oil-based confectionery (more specifically). Along with the transition of fats and oils that are liquid at room temperature), whitening of the surface of the baked confectionery occurs due to the coarsening of crystals of the solid fat in the baked confectionery, and softening of chocolate and the bloom phenomenon occur. It is estimated.
このような推定に基づき、焼菓子と油性菓子との間の油脂移行の抑制に着目した、複合菓子の品質改良手法が従来より検討されてきた。
特許文献1では、トランス脂肪酸含量が5重量%以下であり、特定のSFCを有する油脂A100重量部に対し、特定の乳化剤から選択される1種以上の乳化剤Bを0.05~3重量%含有する焼き菓子練り込み用油脂組成物が提案されている。
Based on such estimation, a method for improving the quality of complex confectionery, which focuses on suppressing the transfer of fats and oils between baked confectionery and oil-based confectionery, has been studied conventionally.
In Patent Document 1, the trans fatty acid content is 5% by weight or less, and 0.05 to 3% by weight of one or more emulsifiers B selected from specific emulsifiers is contained in 100 parts by weight of fats and oils A having a specific SFC. An oil / fat composition for kneading baked confectionery has been proposed.
特許文献2では、焼菓子用の油脂及び油性菓子用の油脂の双方からのアプローチにより、焼菓子の白色化現象及び油性菓子のブルーム現象の発生を抑制した複合菓子が提案されている。このうち、焼菓子に使用する油脂は、特定の炭素数を有するトリグリセリドを特定量含有すると共に、ジ飽和モノ不飽和トリグリセリド(S2U;Sは飽和脂肪酸、Uは不飽和脂肪酸)とモノ飽和ジ不飽和トリグリセリド(SU2)の和、及びS2UとSU2の和に対するSU2の比率が、それぞれ特定範囲にあることを特徴とするものである。 Patent Document 2 proposes a complex confectionery that suppresses the occurrence of whitening phenomenon of baked confectionery and bloom phenomenon of oil-based confectionery by an approach from both fats and oils for baked confectionery and oil-based confectionery. Of these, the fats and oils used for baked goods contain a specific amount of triglyceride having a specific carbon number, and are disaturated monounsaturated triglyceride (S2U; S is a saturated fatty acid and U is an unsaturated fatty acid) and monosaturated di-unsaturated. It is characterized in that the sum of saturated triglycerides (SU2) and the ratio of SU2 to the sum of S2U and SU2 are each within a specific range.
ここで、特許文献1の手法は、乳化剤の作用で油脂の固化温度を上昇させることによりマイグレーションを抑制するものであるところ、口溶けが不良となる場合があった。また、特許文献2の手法は、焼菓子と油性菓子との双方を調整する必要があるため汎用性に乏しく、焼菓子に含まれる油脂組成物だけではマイグレーションの発生を十分抑制できなかった。 Here, the method of Patent Document 1 suppresses migration by raising the solidification temperature of fats and oils by the action of an emulsifier, but there is a case where melting in the mouth becomes poor. Further, the method of Patent Document 2 is not versatile because it is necessary to adjust both the baked confectionery and the oil-based confectionery, and the oil and fat composition contained in the baked confectionery alone cannot sufficiently suppress the occurrence of migration.
ところで、トリグリセリドを構成する3個の脂肪酸残基のうち少なくとも1個が炭素数20~24の飽和脂肪酸であるS2Uを有効成分とするマイグレーション抑制用油脂が特許文献3及び4に開示されている。特許文献3は焼菓子中の油脂分から、特許文献4は油性菓子中の油脂分からのアプローチにより、マイグレーションの発生の抑制を図っている。
しかしながら、いずれの方法も、マイグレーション抑制効果は充分なもので無い上、上記有効成分は高融点成分であるため、このような成分を焼菓子用油脂組成物中に使用した場合には、焼菓子製造時の油脂調温やクリーミング作業等の作業性が劣りやすかった。さらに、特許文献3及び4に記載の油脂を使用すると、焼菓子や油性菓子の口溶けが悪化しやすく、複合菓子としての食感が悪化する等の問題が生じやすかった。
By the way, Patent Documents 3 and 4 disclose oils and fats for suppressing migration containing S2U, in which at least one of the three fatty acid residues constituting triglyceride is a saturated fatty acid having 20 to 24 carbon atoms, as an active ingredient. Patent Document 3 uses an approach from the oil and fat content in baked confectionery, and Patent Document 4 uses an approach from the oil and fat content in oil-based confectionery to suppress the occurrence of migration.
However, neither method has a sufficient effect of suppressing migration, and the active ingredient is a high melting point component. Therefore, when such a component is used in a confectionery oil / fat composition, the baked confectionery is used. Workability such as oil and fat temperature control and creaming work during manufacturing was apt to be inferior. Further, when the fats and oils described in Patent Documents 3 and 4 are used, the melting in the mouth of baked confectionery and oil-based confectionery tends to deteriorate, and the texture as a complex confectionery tends to deteriorate.
本発明は、以上の状況を鑑み、以下の点を目的とするものである。
(イ)口溶け、サクサクとした食感が良好な焼菓子が得られる油脂組成物を提供すること
(ロ)クリーミング性等の製造作業性が良好な油脂組成物を提供すること
(ハ)油脂移行を抑制でき、それに伴って、焼菓子の白色化現象等を抑制できる油脂組成物を提供すること
In view of the above circumstances, the present invention aims at the following points.
(A) To provide an oil / fat composition that melts in the mouth and obtains a baked confectionery with a good crispy texture (b) To provide an oil / fat composition having good manufacturing workability such as creaming property (c) Transfer to oil / fat To provide an oil / fat composition capable of suppressing the whitening phenomenon of baked confectionery and the like.
本発明者らは、検討の結果、トリグリセリド組成中に一定量のBO2(モノベヘニルジオレオイルグリセロール)を含む油脂組成物を焼菓子製造時に用いることで、食感を損なうことなく、焼菓子と油性菓子との間の油脂移行を抑制できることを知見した。 As a result of the study, the present inventors used an oil / fat composition containing a certain amount of BO2 (monobehenyl diole oil glycerol) in the triglyceride composition at the time of producing a baked confectionery, thereby producing a baked confectionery without impairing the texture. It was found that the transfer of fats and oils with oil-based confectionery can be suppressed.
本発明は、上記知見に基づくものであり、下記条件(1)~(3)を満たす焼菓子用油脂組成物を提供するものである。
(1)SFCが10℃で25~45%、20℃で10~30%、30℃で0~15%
(2)油相を構成するトリグリセリド組成中、BO2の含量が2~12質量%(Bはベヘン酸残基、Oはオレイン酸残基)
(3)油相を構成する脂肪酸組成中、ラウリン酸残基が1~10質量%
また、本発明は上記焼菓子用油脂組成物を含む焼菓子、及び該焼菓子を含む複合菓子を提供するものである。
The present invention is based on the above findings, and provides an oil / fat composition for baked confectionery that satisfies the following conditions (1) to (3).
(1) SFC is 25 to 45% at 10 ° C, 10 to 30% at 20 ° C, and 0 to 15% at 30 ° C.
(2) The content of BO2 in the triglyceride composition constituting the oil phase is 2 to 12% by mass (B is a behenic acid residue and O is an oleic acid residue).
(3) Lauric acid residue is 1 to 10% by mass in the fatty acid composition constituting the oil phase.
Further, the present invention provides a baked confectionery containing the above-mentioned oil and fat composition for baked confectionery, and a complex confectionery containing the baked confectionery.
本発明によれば、以下の効果を得ることができる。
(イ)口溶け、サクサクとした食感が良好な焼菓子が得られる
(ロ)良好な製造作業性(クリーミング性等)で焼菓子を製造することができる
(ハ)油脂移行を抑制でき、それに伴って、焼菓子の白色化現象等を抑制することができる
According to the present invention, the following effects can be obtained.
(B) A baked confectionery that melts in the mouth and has a crispy texture can be obtained. (B) A baked confectionery can be produced with good manufacturing workability (creaming properties, etc.). Along with this, it is possible to suppress the whitening phenomenon of baked confectionery.
以下、本発明の焼菓子用油脂組成物について、好ましい実施形態に基づいて詳述する。
本発明の焼菓子用油脂組成物は下記条件(1)~(3)を満たすものである。
(1)SFCが10℃で25~45%、20℃で10~30%、30℃で0~15%
(2)油相を構成するトリグリセリド組成中、BO2の含量が2~12質量%(Bはベヘン酸、Oはオレイン酸)
(3)油相を構成する脂肪酸組成中、ラウリン酸残基が1~10質量%
Hereinafter, the oil and fat composition for baked confectionery of the present invention will be described in detail based on a preferred embodiment.
The oil and fat composition for baked confectionery of the present invention satisfies the following conditions (1) to (3).
(1) SFC is 25 to 45% at 10 ° C, 10 to 30% at 20 ° C, and 0 to 15% at 30 ° C.
(2) The content of BO2 in the triglyceride composition constituting the oil phase is 2 to 12% by mass (B is behenic acid, O is oleic acid).
(3) Lauric acid residue is 1 to 10% by mass in the fatty acid composition constituting the oil phase.
<条件(1)>
本発明の焼菓子用油脂組成物は、SFC(Solid Fat Content、固体脂含量)が10℃で25~45%、20℃で10~30%、30℃で0~15%である。
SFC値が各測定温度における範囲の下限未満である場合、焼菓子用油脂組成物が過度に軟らかい物性となり、焼菓子の製造作業性が損なわれる。また、SFC値が各測定温度における範囲の上限超である場合、焼菓子の製造作業性が低下することに加えて、焼菓子の食感が、ガリガリとした硬く詰まった噛みだしとなる上、口溶けが悪化する。また、SFCが上記範囲内であることで、十分にコシのある焼菓子用油脂組成物となり、クリーミング性が良好なものとなる。
<Condition (1)>
The oil / fat composition for baked confectionery of the present invention has an SFC (Solid Fat Content) of 25 to 45% at 10 ° C., 10 to 30% at 20 ° C., and 0 to 15% at 30 ° C.
When the SFC value is less than the lower limit of the range at each measurement temperature, the oil / fat composition for baked confectionery becomes excessively soft and the manufacturing workability of the baked confectionery is impaired. Further, when the SFC value exceeds the upper limit of the range at each measurement temperature, the manufacturing workability of the baked confectionery is lowered, and the texture of the baked confectionery becomes crunchy, hard and clogged. Melting in the mouth worsens. Further, when the SFC is within the above range, the oil / fat composition for baked confectionery is sufficiently firm and the creaming property is good.
良好な製造作業性を有し、好ましい食感の焼菓子を得ることができる焼菓子用油脂組成物を得る観点から、本発明においては、焼菓子用油脂組成物のSFCが10℃で28~42%、20℃で15~30%、30℃で3~15%であることが好ましく、10℃で30~40%、20℃で15~25%、30℃で5~15%であることがより好ましい。 From the viewpoint of obtaining a baked confectionery oil / fat composition having good manufacturing workability and capable of obtaining a baked confectionery having a favorable texture, in the present invention, the SFC of the baked confectionery oil / fat composition is 28 to 28 at 10 ° C. It is preferably 42%, 15 to 30% at 20 ° C, 3 to 15% at 30 ° C, 30 to 40% at 10 ° C, 15 to 25% at 20 ° C, and 5 to 15% at 30 ° C. Is more preferable.
本発明において、SFCの値は、AOCS official methodのcd16b-93に記載のパルスNMR(ダイレクト法)にて、測定対象となる試料(油脂又は油脂組成物)のSFCを測定した後、測定値を油相量に換算した値を使用する。即ち、水相を含まない試料を測定した場合は、測定値がそのままSFCとなり、水相を含む試料を測定した場合は、測定値を油相量に換算した値をSFCとする。(以下、SFCの測定について同様である。)
上記SFCは、次のようにして測定する。即ち、測定対象となる試料を60℃に30分保持し、油脂を完全に融解し、そして0℃に30分保持して固化させる。さらに、25℃に30分保持し、テンパリングを行い、その後、0℃に30分保持する。これをSFCの各測定温度に順次30分保持後、SFCを測定する。
In the present invention, the value of SFC is measured after measuring the SFC of the sample (oil or fat or fat composition) to be measured by the pulse NMR (direct method) described in cd16b-93 of the AOCS official method. Use the value converted to the amount of oil phase. That is, when a sample not containing an aqueous phase is measured, the measured value becomes SFC as it is, and when a sample containing an aqueous phase is measured, a value obtained by converting the measured value into an oil phase amount is defined as SFC. (Hereinafter, the same applies to the measurement of SFC.)
The above SFC is measured as follows. That is, the sample to be measured is held at 60 ° C. for 30 minutes to completely melt the fat and oil, and then held at 0 ° C. for 30 minutes to solidify. Further, it is held at 25 ° C. for 30 minutes, tempered, and then held at 0 ° C. for 30 minutes. After holding this at each measurement temperature of the SFC for 30 minutes in sequence, the SFC is measured.
<条件(2)>
本発明の焼菓子用油脂組成物は、その油相を構成するトリグリセリド組成中に、BO2(モノベヘニルジオレオイルグリセロール)を2~12質量%含有する。
<Condition (2)>
The oil and fat composition for baked confectionery of the present invention contains 2 to 12% by mass of BO2 (monobehenyl diole oil glycerol) in the triglyceride composition constituting the oil phase.
BO2には、1位にベヘン酸、2位と3位にオレイン酸が結合したトリグリセリド(所謂BOOの形式をとるもの)と、1位と3位にオレイン酸、2位にベヘン酸が結合したトリグリセリド(所謂OBOの形式をとるもの)の2種が存在するところ、本発明におけるBO2の含量は、BOOとOBOの双方のトリグリセリド組成中における含量の合計を示すものである。本発明においては、BOOとOBOの両者をあわせてBO2という。 In BO2, triglyceride (in the form of so-called BOO) in which behenic acid is bound at the 1st position and oleic acid is bound at the 2nd and 3rd positions, and oleic acid is bound at the 1st and 3rd positions, and behenic acid is bound at the 2nd position. Where there are two types of triglycerides (in the form of so-called OBO), the content of BO2 in the present invention indicates the total content of both BOO and OBO in the triglyceride composition. In the present invention, both BOO and OBO are collectively referred to as BO2.
本発明の焼菓子用油脂組成物において、その油相を構成するトリグリセリド組成中、BO2の含量が上記範囲にある場合に、得られる焼菓子の口溶けやサクサクとした食感を損なうことなく、焼菓子-油性菓子間の油脂移行が抑制される機序については、明らかになっていないが、以下の通り推定している。
一般に、SU2は油脂の液状油成分を主に構成することが知られており、BO2はSU2のなかでも融点が比較的高いことから、特定量含有させることで、保管中の焼菓子の液状油成分に「粘り」を生じさせることができ、結果として油脂移行を好ましく抑制できると推定される。そして、油脂移行が抑制されることに伴って、焼菓子の白色化が抑制され、また、油性菓子との複合菓子に用いた場合には油性菓子のブルーム発生についても抑制されると考えられる。
In the oil and fat composition for baked confectionery of the present invention, when the content of BO2 in the triglyceride composition constituting the oil phase is within the above range, the obtained baked confectionery is baked without impairing the melting in the mouth and the crispy texture. The mechanism by which the transfer of fats and oils between confectionery and oily confectionery is suppressed has not been clarified, but it is estimated as follows.
In general, it is known that SU2 mainly constitutes the liquid oil component of fats and oils, and BO2 has a relatively high melting point among SU2. Therefore, by containing a specific amount, liquid oil of baked confectionery during storage is used. It is presumed that "stickiness" can be generated in the components, and as a result, the transfer of oils and fats can be preferably suppressed. It is considered that the whitening of the baked confectionery is suppressed as the transfer of fats and oils is suppressed, and the bloom generation of the oil-based confectionery is also suppressed when used for the confectionery compounded with the oil-based confectionery.
本発明の焼菓子用油脂組成物の油相を構成するトリグリセリド組成中、BO2が2質量%以上であることにより、十分に油脂移行を抑制することができ、焼菓子の白色化現象の発生を抑制することができる。また、BO2が12質量%以下であることにより、製造作業性が良好なものとなり、口溶けが良好な焼菓子が得られる。 When BO2 is 2% by mass or more in the triglyceride composition constituting the oil phase of the oil and fat composition for baked confectionery of the present invention, the transfer of oil and fat can be sufficiently suppressed, and the whitening phenomenon of the baked confectionery occurs. It can be suppressed. Further, when BO2 is 12% by mass or less, the manufacturing workability is good, and a baked confectionery having good melting in the mouth can be obtained.
尚、ベヘン酸を構成脂肪酸として含有するSU2のうち、BO2の構成脂肪酸であるオレイン酸に代えて、オレイン酸以外の不飽和脂肪酸(例えばリノール酸(L))を含有するもの(例えば、BOL、BLL)であっても、焼菓子の白色化現象の発生を抑制し得るが、BO2含量が上記範囲にある場合に、油脂移行(マイグレーション)を抑制する効果が得られ、それに伴って焼菓子の白色化現象を抑制する効果が特に高く得られる。 Among SU2s containing behenic acid as a constituent fatty acid, those containing an unsaturated fatty acid other than oleic acid (for example, linoleic acid (L)) instead of oleic acid, which is a constituent fatty acid of BO2 (for example, BOL, Even with BLL), the occurrence of whitening phenomenon of baked confectionery can be suppressed, but when the BO2 content is within the above range, the effect of suppressing fat transfer (migration) can be obtained, and accordingly, the baked confectionery can be suppressed. The effect of suppressing the whitening phenomenon is particularly high.
白色化現象の発生が抑制され且つ良好な食感を有する焼菓子を得る観点から、本発明の焼菓子用油脂組成物の油相を構成するトリグリセリド組成中、BO2の含量が2~10質量%であることが好ましく、3~10質量%であることがより好ましい。 From the viewpoint of obtaining a baked confectionery having a good texture while suppressing the occurrence of whitening phenomenon, the content of BO2 in the triglyceride composition constituting the oil phase of the oil and fat composition for baked confectionery of the present invention is 2 to 10% by mass. It is preferably 3 to 10% by mass, and more preferably 3 to 10% by mass.
また、本発明の焼菓子用油脂組成物の油相を構成するトリグリセリド組成中、B2O(ジベヘニルモノオレオイルグリセロール)が好ましくは5質量%未満、より好ましくは3質量%未満、さらに好ましくは2質量%未満、最も好ましくは1.5質量%未満であると、焼菓子製造時の油脂調温やクリーミング作業等の作業性をより良好なものとし、より好ましい口溶けやサクサクとした食感を有する焼菓子が得られる。 Further, in the triglyceride composition constituting the oil phase of the oil and fat composition for baked confectionery of the present invention, B2O (dibehenylmonoole oil glycerol) is preferably less than 5% by mass, more preferably less than 3% by mass, still more preferably 2. When it is less than mass%, most preferably less than 1.5% by mass, the workability such as oil / fat temperature control and creaming work at the time of producing baked confectionery is improved, and a more preferable melting in the mouth and a crispy texture are obtained. You can get baked goods.
これらのトリグリセリド組成については、例えば逆相HPLCで行われるトリグリセリド分子種分析により分析することが可能である。この逆相HPLCは、日本油化学会制定「基準油脂分析試験法2.4.6.2」に則って、任意の条件で実施することができ、例えば、次のような条件で測定することが可能である。
・検出部:示差屈折検出器
・カラム:ドコシルカラム(DCS)
・移動相:アセトン:アセトニトリル=65:35(体積比)
・流速:1ml/min
・カラム温度:40℃
・背圧:3.8MPa
These triglyceride compositions can be analyzed, for example, by triglyceride molecular species analysis performed by reverse phase HPLC. This reverse phase HPLC can be carried out under any conditions in accordance with the "Standard Oil and Fat Analysis Test Method 2.4.6.2" established by the Japan Oil Chemists' Society. For example, measurement should be performed under the following conditions. Is possible.
-Detector: Differential refractometer-Column: Dococil column (DCS)
-Mobile phase: Acetone: Acetonitrile = 65:35 (volume ratio)
・ Flow velocity: 1 ml / min
-Column temperature: 40 ° C
・ Back pressure: 3.8 MPa
<条件(3)>
本発明の焼菓子用油脂組成物においては、その油相を構成する脂肪酸組成中、ラウリン酸残基が1~10質量%である。本発明の焼菓子用油脂組成物の油相を構成する脂肪酸組成中、ラウリン酸残基量が上記範囲内にあることで、焼菓子製造時の、焼菓子用油脂組成物のクリーミング性が良好となり、良好な食感の焼菓子を得ることができる。
<Condition (3)>
In the oil and fat composition for baked confectionery of the present invention, the lauric acid residue is 1 to 10% by mass in the fatty acid composition constituting the oil phase. When the amount of lauric acid residue in the fatty acid composition constituting the oil phase of the oil-and-fat composition for baked confectionery of the present invention is within the above range, the creaming property of the oil-and-fat composition for baked confectionery during the production of baked confectionery is good. Therefore, it is possible to obtain baked confectionery with a good texture.
本発明の焼菓子用油脂組成物の油相を構成する脂肪酸組成中、ラウリン酸残基は、好ましくは1~9質量%、より好ましくは1~8質量%、最も好ましくは1.5~7質量%である。 In the fatty acid composition constituting the oil phase of the oil and fat composition for baked confectionery of the present invention, the lauric acid residue is preferably 1 to 9% by mass, more preferably 1 to 8% by mass, and most preferably 1.5 to 7 by mass. It is mass%.
油相の構成脂肪酸組成中のラウリン酸残基量については、例えば、「日本油化学会制定 基準油脂分析試験法2.4.2.3-2013」や「日本油化学会制定 基準油脂分析試験法2.4.4.3-2013」を参考に、キャピラリーガスクロマトグラフ法により測定することができる。 Regarding the amount of lauric acid residue in the constituent fatty acid composition of the oil phase, for example, "Standard oil and fat analysis test method established by the Japan Oil Chemicals Society 2.4.2.3-2013" and "Standard oil and fat analysis test established by the Japan Oil Chemicals Society". It can be measured by the capillary gas chromatograph method with reference to "Method 2.4.4.3-2013".
さらに本発明においては、保管中の油脂移行を抑制しながら、より一層、好ましい製造作業性を有し、口溶けが良好でサクサクとした噛みだしの焼菓子を得る観点から、本発明の焼菓子用油脂組成物は上記条件(1)(2)(3)に加えて、次の条件(4)を満たすことが好ましい。
<条件(4)>
(4)油相を構成するトリグリセリド組成中、LLL(トリラウリン)の含量が5質量%以下(Lはラウリン酸)
Further, in the present invention, the present invention is used for baked confectionery from the viewpoint of obtaining a crispy, chewy baked confectionery that has more preferable manufacturing workability and has good melting in the mouth while suppressing the transfer of fats and oils during storage. The oil / fat composition preferably satisfies the following condition (4) in addition to the above conditions (1), (2) and (3).
<Condition (4)>
(4) The content of LLL (trilaurin) in the triglyceride composition constituting the oil phase is 5% by mass or less (L is lauric acid).
本発明においては、上記条件(3)の項で述べた通り、製造作業性を向上させると共に好ましい食感の焼菓子を得るために、焼菓子用油脂組成物の油相を構成する脂肪酸組成中、ラウリン酸残基を特定範囲で含有させるが、トリラウリンの含量が5質量%以下となるようにすることで、クリーミング性が一層向上すると共に、より好ましい口溶けとサクサクとした噛みだしが得られやすくなるため好ましい。
換言すると、本発明の焼菓子用油脂組成物の油相を構成するトリグリセリドのうち、ラウリン酸残基を含有するトリグリセリドは、トリグリセリドを構成する3つの脂肪酸残基のうち、ラウリン酸残基が好ましくは2つ以下、より好ましくは1つであると、本発明の効果、特に製造作業性向上の効果が、一層得られやすくなる。
In the present invention, as described in the above condition (3), in the fatty acid composition constituting the oil phase of the oil-and-fat composition for baked confectionery, in order to improve the manufacturing workability and obtain the baked confectionery having a preferable texture. , Lauric acid residue is contained in a specific range, but by setting the content of trilaurin to 5% by mass or less, the creaming property is further improved, and more preferable melting in the mouth and crispy chewing can be easily obtained. Therefore, it is preferable.
In other words, among the triglycerides constituting the oil phase of the oil and fat composition for baked confectionery of the present invention, the triglyceride containing a lauric acid residue is preferably a lauric acid residue among the three fatty acid residues constituting the triglyceride. When the number is two or less, more preferably one, the effect of the present invention, particularly the effect of improving the manufacturing workability, can be more easily obtained.
油相を構成するトリグリセリド組成中にトリラウリンを含有する場合、トリラウリンの含量は好ましくは3質量%以下、より好ましくは1質量%以下、最も好ましくは0.5質量%以下である。尚、好ましい下限は0質量%である。 When trilaurin is contained in the triglyceride composition constituting the oil phase, the content of trilaurin is preferably 3% by mass or less, more preferably 1% by mass or less, and most preferably 0.5% by mass or less. The preferable lower limit is 0% by mass.
次に、本発明で用いることのできる油脂について述べる。
本発明の焼菓子用油脂組成物の油相に用いることのできる油脂としては、例えば、大豆油、菜種油、ハイエルシン菜種油、コーン油、綿実油、オリーブ油、落花生油、米油、サフラワー油、ハイオレイックサフラワー油、からし油、ヒマワリ油、ハイオレイックヒマワリ油、パーム油、パーム核油、ヤシ油、サル脂、マンゴ脂、乳脂、牛脂、豚脂、カカオ脂、魚油、鯨油等の各種植物油脂、動物油脂、並びにこれらの油脂に水素添加、分別、エステル交換等の物理的又は化学的処理の1種又は2種以上の処理を施した油脂が挙げられ、これらから選択された2種又はそれ以上の油脂の混合物を使用することもできる。
Next, the fats and oils that can be used in the present invention will be described.
Examples of the oil and fat that can be used in the oil phase of the oil and fat composition for baked confectionery of the present invention include soybean oil, rapeseed oil, hyelsin rapeseed oil, corn oil, cottonseed oil, olive oil, peanut oil, rice oil, saflower oil, and hyole. Various types of oil such as icsa flower oil, mustard oil, sunflower oil, hyoleic sunflower oil, palm oil, palm kernel oil, palm oil, monkey fat, mango fat, milk fat, beef fat, pork fat, cacao fat, fish oil, whale oil, etc. Examples thereof include vegetable fats and oils, animal fats and oils, and fats and oils obtained by subjecting these fats and oils to one or more physical or chemical treatments such as hydrogenation, separation, and ester exchange, and two kinds selected from these. Alternatively, a mixture of oils and fats higher than that can be used.
本発明においては、これらの油脂の中から、上記条件(1)~(3)、好ましくは条件(1)~(4)を満たすように、1種又は2種以上が使用される。とりわけ、油相を構成するトリグリセリド組成中に、BO2を一定量含有させる観点や、複雑なトリグリセリド組成とすることにより、クリーミング性が良好なものになりやすい細かな油脂結晶を得る観点から、エステル交換油脂を使用することが好ましく、ランダムエステル交換油脂を使用することがより好ましい。 In the present invention, one or more of these fats and oils are used so as to satisfy the above conditions (1) to (3), preferably conditions (1) to (4). In particular, transesterification is performed from the viewpoint of containing a certain amount of BO2 in the triglyceride composition constituting the oil phase and from the viewpoint of obtaining fine oil and fat crystals that tend to have good creaming property by making the triglyceride composition complicated. It is preferable to use fats and oils, and more preferably to use random transesterified fats and oils.
本発明の焼菓子用油脂組成物の油相を構成する油脂は、ランダムエステル交換油脂を好ましくは70質量%以上、より好ましくは80質量%以上、更に好ましくは90質量%以上含有し、最も好ましくは油相を構成する油脂がランダムエステル交換油脂のみからなる。 The oil and fat constituting the oil phase of the oil and fat composition for baked confectionery of the present invention preferably contains a random transesterified oil and fat in an amount of preferably 70% by mass or more, more preferably 80% by mass or more, still more preferably 90% by mass or more, and most preferably. The oils and fats constituting the oil phase consist only of random transesterified oils and fats.
ここで、本発明の焼菓子用油脂組成物に好ましく用いられるランダムエステル交換油脂について詳述する。本発明の焼菓子用油脂組成物においては、以下に示すエステル交換油脂(A)及びエステル交換油脂(B)を油相中に含有することが好ましい。 Here, the random transesterified fats and oils preferably used in the fats and oils composition for baked confectionery of the present invention will be described in detail. In the oil and fat composition for baked confectionery of the present invention, it is preferable that the transesterified oil and fat (A) and the transesterified oil and fat (B) shown below are contained in the oil phase.
エステル交換油脂(A):
構成脂肪酸組成中、オレイン酸残基を45~80質量%、炭素数20~22の脂肪酸残基を5~25質量%含有し、構成脂肪酸中の不飽和脂肪酸中におけるオレイン酸含量の質量比が0.80以上である、ランダムエステル交換油脂
エステル交換油脂(B):
構成脂肪酸組成中、オレイン酸残基を5~45質量%、ラウリン酸残基を1~40質量%含有し、構成脂肪酸中の飽和脂肪酸の含量に対するラウリン酸の質量比が0.05~0.45である、ランダムエステル交換油脂
Transesterified oil (A):
The constituent fatty acid composition contains 45 to 80% by mass of oleic acid residues and 5 to 25% by mass of fatty acid residues having 20 to 22 carbon atoms, and the mass ratio of the oleic acid content in the unsaturated fatty acids in the constituent fatty acids is Random transesterified fats and oils transesterified fats and oils (B): 0.80 or more:
The composition of the constituent fatty acids contains 5 to 45% by mass of oleic acid residues and 1 to 40% by mass of lauric acid residues, and the mass ratio of lauric acid to the content of saturated fatty acids in the constituent fatty acids is 0.05 to 0. 45, random ester exchange fats and oils
まず、エステル交換油脂(A)について述べる。
上記エステル交換油脂(A)は、構成脂肪酸組成中にオレイン酸残基を好ましくは45~80質量%、より好ましくは47~75質量%、最も好ましくは50~70質量%含有する。
また、上記エステル交換油脂(A)は、構成脂肪酸組成中に炭素数20~22の脂肪酸残基を好ましくは5~25質量%、より好ましくは5~20質量%、最も好ましくは10~20質量%含有する。
また、上記エステル交換油脂(A)は、構成脂肪酸組成の不飽和脂肪酸中におけるオレイン酸含量の質量比が0.80以上であることが好ましく、0.85以上であることがより好ましく、0.87以上であることが最も好ましい。
First, the transesterified fat (A) will be described.
The transesterified fat (A) contains oleic acid residues in the constituent fatty acid composition in an amount of preferably 45 to 80% by mass, more preferably 47 to 75% by mass, and most preferably 50 to 70% by mass.
Further, the transesterified fat (A) contains fatty acid residues having 20 to 22 carbon atoms in the constituent fatty acid composition, preferably 5 to 25% by mass, more preferably 5 to 20% by mass, and most preferably 10 to 20% by mass. %contains.
Further, in the transesterified fat (A), the mass ratio of the oleic acid content in the unsaturated fatty acid having the constituent fatty acid composition is preferably 0.80 or more, more preferably 0.85 or more, and 0. Most preferably, it is 87 or more.
オレイン酸残基の含量、炭素数20~22の脂肪酸残基の含量、及び構成脂肪酸組成の不飽和脂肪酸残基中におけるオレイン酸残基含量の質量比が、それぞれ上記範囲内にあるエステル交換油脂を用いることで、本発明の焼菓子用油脂組成物を用いて得られる焼菓子の食感が、一層好ましいものとなる上、本発明焼菓子用油脂組成物を用いて得られる焼菓子を用いた複合菓子において、一層効果的に油脂移行を抑制することができる。 The mass ratio of the oleic acid residue content, the fatty acid residue content of 20 to 22 carbon atoms, and the oleic acid residue content in the unsaturated fatty acid residue of the constituent fatty acid composition is within the above ranges, respectively. By using the above, the texture of the baked confectionery obtained by using the oil and fat composition for baked confectionery of the present invention becomes more preferable, and the baked confectionery obtained by using the oil and fat composition for baked confectionery of the present invention is used. In the compound confectionery that has been used, the transfer of fats and oils can be suppressed more effectively.
さらに、上記範囲を満たすとともに、上記エステル交換油脂(A)の構成脂肪酸組成中、炭素数12以下の脂肪酸の含量を2質量%未満とすることが好ましい。 Further, it is preferable that the content of the fatty acid having 12 or less carbon atoms in the constituent fatty acid composition of the transesterified fat (A) is less than 2% by mass while satisfying the above range.
上記エステル交換油脂(A)は、構成脂肪酸中にオレイン酸残基を多く含有する油脂と、構成脂肪酸中に炭素数20~22の脂肪酸残基を多く含有する油脂とを混合した油脂配合物(以下、単に油脂配合物(A)と記載する場合がある)をランダムエステル交換することによって得ることができる。 The transesterified fat (A) is a fat and oil mixture obtained by mixing a fat and oil containing a large amount of oleic acid residue in the constituent fatty acid and a fat and oil containing a large amount of fatty acid residue having 20 to 22 carbon atoms in the constituent fatty acid. Hereinafter, it may be simply referred to as an oil / fat compound (A)), which can be obtained by transesterification.
上記のオレイン酸残基を多く含有する油脂としては、コーン油、綿実油、大豆油、菜種油、米油、オリーブ油、落花生油、ヒマワリ油、サフラワー油、ハイオレイックヒマワリ油、ハイオレイックキャノーラ油、ハイオレイックサフラワー油等の、常温で液体である油脂に加え、パーム油、パーム核油、ヤシ油、サル脂、マンゴ脂、乳脂、牛脂、豚脂、カカオ脂、魚油、鯨油等の各種動植物油脂並びにこれらに水素添加、分別及びエステル交換から選択される1又は2以上の処理を施した加工油脂が挙げられ、これらの中から必要に応じて1種又は2種以上を使用することができる。尚、分別処理を施す場合は、分別軟部油を選択することが好ましい。 Examples of fats and oils containing a large amount of oleic acid residues include corn oil, cottonseed oil, soybean oil, rapeseed oil, rice oil, olive oil, peanut oil, sunflower oil, saflower oil, high oleic sunflower oil, and high oleic canola oil. In addition to fats and oils that are liquid at room temperature, such as high oleic saflower oil, palm oil, palm kernel oil, palm oil, monkey fat, mango fat, milk fat, beef fat, pork fat, cacao fat, fish oil, whale oil, etc. Examples include various animal and vegetable oils and fats and processed oils and fats that have been subjected to one or more treatments selected from hydrogenation, fractionation and ester exchange, and one or more of these should be used as needed. Can be done. When performing the separation treatment, it is preferable to select the separated soft tissue oil.
本発明においては、有効成分であるBO2の含量を特定の範囲まで高める観点から、油脂配合物(A)中に配合する油脂として、構成脂肪酸組成中にオレイン酸残基を70質量%以上含有する油脂を選択することが好ましく、オレイン酸残基を75質量%以上含有する油脂を選択することがより好ましい。そのため、上記に挙げた油脂群のうち、オレイン酸を多く含有するハイオレイックヒマワリ油、ハイオレイックサフラワー油、ハイオレイックキャノーラ油、及びそれらの加工油脂が好ましく選択される。 In the present invention, from the viewpoint of increasing the content of BO2, which is an active ingredient, to a specific range, the fat and oil to be blended in the fat and oil compound (A) contains 70% by mass or more of oleic acid residues in the constituent fatty acid composition. It is preferable to select a fat or oil, and it is more preferable to select a fat or oil containing 75% by mass or more of an oleic acid residue. Therefore, among the oils and fats listed above, high oleic sunflower oil, high oleic safflower oil, high oleic canola oil, and processed fats and oils thereof containing a large amount of oleic acid are preferably selected.
上記の炭素数20~22の脂肪酸残基を多く含有する油脂としては、ハイエルシン菜種油、魚油、サル脂、からし油、これらの油脂に水素添加、分別及びエステル交換から選択される1種又は2種以上の処理を施した加工油脂等が挙げられる。 Examples of the fats and oils containing a large amount of fatty acid residues having 20 to 22 carbon atoms include hyelsin rapeseed oil, fish oil, monkey fat, mustard oil, and one or two selected from hydrogenation, fractionation and transesterification of these fats and oils. Examples thereof include processed oils and fats that have been treated with more than seeds.
上記エステル交換油脂(A)は、上記油脂配合物(A)をランダムエステル交換することにより得られる。このエステル交換反応は、例えばナトリウムメトキシド等の化学的触媒を用いる手法であっても、例えば、アルカリゲネス(Alcaligenes)属、リゾープス(Rhizopus)属、アスペルギルス(Aspergillus)属、ムコール(Mucor)属、ペニシリウム(Penicillium)属等に由来するリパーゼ等の酵素を用いる手法であっても行うことができ、いずれも常法に従って行うことができる。 The transesterified oil (A) can be obtained by randomly transesterifying the oil / fat compound (A). This ester exchange reaction may be carried out using, for example, a chemical catalyst such as sodium methoxydo, for example, Alcaligenes, Rhizopus, Aspergillus, Mucor, Penicillium. It can also be carried out by a method using an enzyme such as lipase derived from the genus (Penicillium) or the like, and all of them can be carried out according to a conventional method.
上記エステル交換油脂(A)は、ヨウ素価が55以上であることが好ましく、より好ましくは57以上、さらに好ましくは59以上である。 The transesterified oil (A) preferably has an iodine value of 55 or more, more preferably 57 or more, and even more preferably 59 or more.
また、上記エステル交換油脂(A)は、SFC(固体脂含量)が、10℃で好ましくは5~35%、より好ましくは10~33%、さらに好ましくは20~30%、20℃で好ましくは1~20%、より好ましくは5~18%、さらに好ましくは9~15%、30℃で好ましくは1~15%、より好ましくは3~12%、さらに好ましくは5~10%である。 The transesterified fat (A) has an SFC (solid fat content) of preferably 5 to 35%, more preferably 10 to 33%, still more preferably 20 to 30%, and preferably 20 ° C. at 10 ° C. It is 1 to 20%, more preferably 5 to 18%, still more preferably 9 to 15%, preferably 1 to 15% at 30 ° C., more preferably 3 to 12%, still more preferably 5 to 10%.
また、上記エステル交換油脂(A)は、融点(上昇融点)が35℃以上であることが好ましく、より好ましくは37℃以上、さらに好ましくは40℃以上である。
上記融点は「日本油化学会制定 基準油脂分析試験法 2.2.4.2(1996)1996年版」に準じて測定することができる(以下、融点の測定について同様である)。
Further, the transesterified fat (A) preferably has a melting point (rising melting point) of 35 ° C. or higher, more preferably 37 ° C. or higher, still more preferably 40 ° C. or higher.
The above melting point can be measured according to the "Standard Oil and Fat Analysis Test Method Established by the Japan Oil Chemists' Society 2.2.4.2 (1996) 1996 Edition" (hereinafter, the same applies to the measurement of the melting point).
本発明の焼菓子用油脂組成物は、上記エステル交換油脂(A)を、油相基準で、5~70質量%含有することが好ましく、10~65質量%含有することがより好ましく、15~55質量%含有することがさらに好ましい。 The oil / fat composition for baked confectionery of the present invention preferably contains the transesterified oil / fat (A) in an amount of 5 to 70% by mass, more preferably 10 to 65% by mass, and 15 to 65% by mass based on the oil phase. It is more preferably contained in an amount of 55% by mass.
次に、エステル交換油脂(B)について述べる。
上記エステル交換油脂(B)は、構成脂肪酸組成中にオレイン酸残基を好ましくは5~45質量%、より好ましくは7~40質量%、最も好ましくは10~35質量%を含有する。
また、上記エステル交換油脂(B)は、構成脂肪酸組成中にラウリン酸残基を好ましくは1~40質量%、より好ましくは3~38質量%、最も好ましくは5~36質量%含有する。
また、上記エステル交換油脂(B)は、構成脂肪酸中の飽和脂肪酸の含量に対するラウリン酸の質量比が0.05~0.45であり、好ましくは0.07~0.45であり、より好ましくは0.09~0.45である。
Next, the transesterified fat (B) will be described.
The transesterified fat (B) contains oleic acid residues in the constituent fatty acid composition, preferably 5 to 45% by mass, more preferably 7 to 40% by mass, and most preferably 10 to 35% by mass.
Further, the transesterified fat (B) contains lauric acid residues in the constituent fatty acid composition in an amount of preferably 1 to 40% by mass, more preferably 3 to 38% by mass, and most preferably 5 to 36% by mass.
Further, in the transesterified fat (B), the mass ratio of lauric acid to the content of the saturated fatty acid in the constituent fatty acids is 0.05 to 0.45, preferably 0.07 to 0.45, which is more preferable. Is 0.09 to 0.45.
上記エステル交換油脂(B)は、構成脂肪酸組成中のパルミチン酸残基含量が、好ましくは5~40質量%、より好ましくは10~35質量%であり、ステアリン酸残基含量が、好ましくは1~25質量%、より好ましくは5~20%である。これらの含量を満たすことで、本発明の焼菓子用油脂組成物を用いて焼菓子を製造する際に、適度なコシが得られ、クリーミング中のダレが抑制されるため、サクサクとした噛みだしを有する焼菓子が一層得られ易くなる。 The transesterified fat (B) has a palmitic acid residue content of preferably 5 to 40% by mass, more preferably 10 to 35% by mass, and a stearic acid residue content of preferably 1 in the constituent fatty acid composition. It is -25% by mass, more preferably 5 to 20%. By satisfying these contents, when producing a baked confectionery using the oil and fat composition for baked confectionery of the present invention, an appropriate elasticity is obtained and sagging during creaming is suppressed, so that the chewy texture is crispy. It becomes easier to obtain baked confectionery having the above.
構成脂肪酸組成中のオレイン酸残基の含量、ラウリン酸残基の含量、及び構成脂肪酸の飽和脂肪酸中におけるラウリン酸含量の比率が、上記範囲内にあるエステル交換油脂(B)を、本発明の焼菓子用油脂組成物中に含有させることで、本発明の焼菓子用油脂組成物を用いて焼菓子を製造する際のクリーミング性等の製造作業性が一層好ましいものとなる上、本発明の焼菓子用油脂組成物を用いて得られる焼菓子の口溶けや、サクサクとした噛みだしが一層良好なものとなる。 The transesterified fat (B) in which the ratio of the content of oleic acid residue in the constituent fatty acid composition, the content of lauric acid residue, and the content of lauric acid in the saturated fatty acid of the constituent fatty acid is within the above range is defined in the present invention. By containing it in the oil / fat composition for baked confectionery, the manufacturing workability such as creaming property when producing the oil / fat composition for baked confectionery of the present invention becomes more preferable, and the present invention also makes it more preferable. The melt-in-the-mouth of the baked confectionery obtained by using the oil-and-fat composition for baked confectionery and the crispy chewing are further improved.
さらに、上記範囲を満たすとともに、上記エステル交換油脂(B)の構成脂肪酸組成中、炭素数20以上の脂肪酸残基の含量を2質量%未満とすることが好ましい。 Further, it is preferable that the content of the fatty acid residue having 20 or more carbon atoms in the constituent fatty acid composition of the transesterified fat (B) is less than 2% by mass while satisfying the above range.
上記エステル交換油脂(B)は、構成脂肪酸組成中のオレイン酸残基とラウリン酸残基の含有量が上記範囲を満たすように、1種又は2種以上の油脂を配合した油脂配合物(以下、油脂配合物(B)ということもある)をランダムエステル交換することにより得ることができる。好ましくは、油脂配合物中に、ラウリン酸残基を多く含有する油脂と、パーム系油脂とを含有する。 The transesterified fat (B) is a fat or oil mixture containing one or more kinds of fats and oils so that the contents of oleic acid residues and lauric acid residues in the constituent fatty acid composition satisfy the above range (hereinafter,). , Also referred to as oil / fat compound (B)) can be obtained by transesterification. Preferably, the fat and oil formulation contains a fat and oil containing a large amount of lauric acid residue and a palm-based fat and oil.
上記のラウリン酸残基を多く含有する油脂としては、パーム核油、ヤシ油、ババス油、乳脂等を挙げることができるが、本発明においては、特にラウリン系油脂と称される、構成脂肪酸組成中にラウリン酸残基が40質量%を超える油脂を選択し使用することが好ましい。具体的には、ヤシ油、パーム核油、並びにこれらに水素添加、分別及びエステル交換から選択される1又は2以上の処理を施した加工油脂が挙げられ、これらの中から1種又は2種以上を使用することができる。 Examples of the above-mentioned fats and oils containing a large amount of lauric acid residues include palm kernel oil, coconut oil, babassu oil, milk fat and the like, but in the present invention, the constituent fatty acid composition particularly referred to as lauric acid-based fats and oils. It is preferable to select and use an oil or fat having a lauric acid residue of more than 40% by mass. Specific examples thereof include coconut oil, palm kernel oil, and processed fats and oils which have been subjected to one or more treatments selected from hydrogenation, fractionation and transesterification, and one or two of these. The above can be used.
上記油脂配合物(B)に含有されるパーム系油脂としては、パーム油、並びにパーム油に水素添加、分別及びエステル交換から選択される1又は2以上の処理を施した加工油脂が挙げられ、これらの中から必要に応じて1種又は2種以上を使用することができる。
尚、上記油脂配合物(B)は、上記ラウリン系油脂及び上記パーム系油脂の他に、構成脂肪酸組成や後述するSFC等を好ましい範囲に調整する観点から、エステル交換油脂(B)の好ましい構成脂肪酸組成を逸脱しない範囲で、他の油脂を含有することができる。他の油脂としては、例えば、大豆油、菜種油、コーン油、綿実油、オリーブ油、落花生油、米油、べに花油、ひまわり油、パーム油、パーム核油、ヤシ油、サル脂、マンゴ脂、乳脂、牛脂、豚脂、カカオ脂、魚油、鯨油等の各種動植物油脂、並びにこれらに水素添加、分別及びエステル交換から選択される1又は2以上の処理を施した加工油脂が挙げられ、これらの中から1種又は2種以上を使用することができる。
Examples of the palm-based oil and fat contained in the above-mentioned oil and fat mixture (B) include palm oil and processed oil and fat obtained by subjecting palm oil to one or more treatments selected from hydrogenation, fractionation and transesterification. From these, one kind or two or more kinds can be used as needed.
The oil / fat compound (B) has a preferable composition of the transesterified oil / fat (B) from the viewpoint of adjusting the constituent fatty acid composition, the SFC described later, and the like to a preferable range in addition to the lauric acid-based oil and the palm-based oil / fat. Other fats and oils can be contained within a range that does not deviate from the fatty acid composition. Other fats and oils include, for example, soybean oil, rapeseed oil, corn oil, cottonseed oil, olive oil, peanut oil, rice oil, beni flower oil, sunflower oil, palm oil, palm kernel oil, palm oil, monkey fat, mango fat, milk fat, etc. Examples thereof include various animal and vegetable fats and oils such as beef fat, pork fat, coconut fat, fish oil and whale oil, and processed fats and oils which have been subjected to one or more treatments selected from hydrogenation, fractionation and ester exchange. One kind or two or more kinds can be used.
上記エステル交換油脂(B)は、上記油脂配合物(B)をランダムエステル交換して得ることができる。ランダムエステル交換反応は、上記エステル交換油脂(A)を得る際と同様にして行うことができる。 The transesterified oil (B) can be obtained by randomly transesterifying the oil / fat compound (B). The random transesterification reaction can be carried out in the same manner as in obtaining the transesterified fat (A).
上記エステル交換油脂(B)は、SFC(固体脂含量)が、10℃で好ましくは50~80%、より好ましくは52~78%、さらに好ましくは54~75%であり、20℃で好ましくは25~60%、より好ましくは28~57%、さらに好ましくは30~55%であり、30℃で好ましくは10~30%、より好ましくは13~27%、さらに好ましくは15~25%である。 The transesterified fat (B) has an SFC (solid fat content) of preferably 50 to 80%, more preferably 52 to 78%, still more preferably 54 to 75% at 10 ° C, and preferably 20 ° C. It is 25 to 60%, more preferably 28 to 57%, still more preferably 30 to 55%, preferably 10 to 30% at 30 ° C., more preferably 13 to 27%, still more preferably 15 to 25%. ..
また、上記エステル交換油脂(B)は、焼菓子製造時の作業性と得られる焼菓子の食感を両立する観点から、融点が25~45℃であることが好ましく、より好ましくは30~40℃である。 Further, the transesterified fat (B) preferably has a melting point of 25 to 45 ° C., more preferably 30 to 40, from the viewpoint of achieving both workability during manufacturing of baked confectionery and texture of the obtained baked confectionery. ℃.
本発明の焼菓子用油脂組成物は、上記エステル交換油脂(B)を、油相基準で、5~30質量%含有することが好ましく、8~25質量%含有することがより好ましく、10~25質量%含有することがさらに好ましい。 The oil / fat composition for baked confectionery of the present invention preferably contains the transesterified oil / fat (B) in an amount of 5 to 30% by mass, more preferably 8 to 25% by mass, based on the oil phase. It is more preferably contained in an amount of 25% by mass.
本発明の焼菓子用油脂組成物は、上記エステル交換油脂(A)及びエステル交換油脂(B)以外の油脂(以下、その他の油脂ともいう)も含有することができる。尚、その他の油脂を含有する場合には、パーム系油脂が好ましく使用される。 The oil / fat composition for baked confectionery of the present invention may also contain oils / fats other than the transesterified oils / fats (A) and the transesterified oils / fats (B) (hereinafter, also referred to as other oils / fats). When other fats and oils are contained, palm-based fats and oils are preferably used.
本発明では、その他の油脂としてのパーム系油脂として、パーム油、パーム分別軟部油、パーム分別硬部油及びパームスーパーオレイン、パーム分別軟部油のランダムエステル交換油脂、パーム分別硬部油のランダムエステル交換油脂及びパームスーパーオレインのランダムエステル交換油脂、並びに、パーム油、パーム分別軟部油、パーム分別硬部油及びパームスーパーオレインの1種又は2種以上を75質量%以上含有する油脂配合物のランダムエステル交換油脂、のうちの1種又は2種以上を使用することが好ましい。このようなパーム系油脂を使用することで、トリグリセリド組成を複雑なものとし、クリーミング性を一層向上させ、焼菓子製造時の作業性を向上させることができるため、本発明の効果をより高く引き出すことができる。尚、その他の油脂として、パーム油、パーム分別軟部油、パーム分別硬部油、パームスーパーオレイン以外の油脂を使用する場合は、後に詳述する理由から、トランス脂肪酸が実質的に含有されない油脂を選択することが好ましい。
その他の油脂としてパーム系油脂を使用する場合、本発明の焼菓子用油脂組成物におけるその含量は、油相基準で5~60質量%が好ましく、5~50質量%がさらに好ましい。
In the present invention, as other palm-based oils and fats, palm oil, palm-separated soft part oil, palm-separated hard part oil and palm super olein, random ester exchange fats and oils of palm-separated soft part oil, and random esters of palm-separated hard part oil. Random ester of exchanged fats and oils and palm super olein Random oils and fats containing 75% by mass or more of one or more of palm oil, palm separated soft part oil, palm separated hard part oil and palm super olein. It is preferable to use one or more of the ester-exchanged oils and fats. By using such palm-based fats and oils, the triglyceride composition can be complicated, the creaming property can be further improved, and the workability during the production of baked confectionery can be improved, so that the effect of the present invention can be further enhanced. be able to. When oils other than palm oil, palm separated soft tissue oil, palm fractionated hard tissue oil, and palm super olein are used as other oils and fats, oils and fats that do not substantially contain trans fatty acids are used for the reasons described in detail later. It is preferable to select.
When palm-based oils and fats are used as other oils and fats, the content thereof in the oil and fat composition for baked confectionery of the present invention is preferably 5 to 60% by mass, more preferably 5 to 50% by mass based on the oil phase.
本発明の焼菓子用油脂組成物においては、上記エステル交換油脂(A)、エステル交換油脂(B)及びパーム系油脂の合計が、油相の70~100質量%を占めることが好ましく、80~100質量%を占めることがより好ましく、90~100質量%を占めることがさらに好ましい。 In the oil and fat composition for baked confectionery of the present invention, the total of the transesterified oil and fat (A), the transesterified oil and fat (B) and the palm-based oil and fat preferably occupy 70 to 100% by mass of the oil phase, and 80 to 80 to It is more preferable to occupy 100% by mass, and even more preferably to occupy 90 to 100% by mass.
本発明の焼菓子用油脂組成物は、実質的にトランス脂肪酸を含まないことが好ましい。ここでいう「実質的にトランス脂肪酸を含まない」とは、油相中、トリグリセリドを構成する脂肪酸残基としてのトランス脂肪酸の含量が好ましくは5質量%以下、より好ましくは3質量%以下、最も好ましくは2質量%以下であることを意味する。実質的にトランス脂肪酸を含まないことが好ましいのは以下の理由による。
水素添加は、油脂の融点を上昇させる典型的な方法であるが、水素添加油脂は、完全水素添加油脂を除いて、通常、トランス脂肪酸が10~50質量%程度含まれている。一方、天然油脂中にはトランス脂肪酸が殆ど存在せず、反芻動物由来の油脂に10質量%未満含まれているにすぎない。近年、化学的な処理、特に水素添加に付されていない油脂組成物、即ち実質的にトランス脂肪酸を含まない油脂組成物であって、適切なコンシステンシーを有するものが要求されている。
It is preferable that the oil and fat composition for baked confectionery of the present invention is substantially free of trans fatty acids. The term "substantially free of trans fatty acids" as used herein means that the content of trans fatty acids as fatty acid residues constituting triglyceride in the oil phase is preferably 5% by mass or less, more preferably 3% by mass or less, and most. It means that it is preferably 2% by mass or less. It is preferable that it contains substantially no trans fatty acid for the following reasons.
Hydrogenation is a typical method for raising the melting point of fats and oils, but hydrogenated fats and oils usually contain about 10 to 50% by mass of trans fatty acids, except for completely hydrogenated fats and oils. On the other hand, trans fatty acids are scarcely present in natural fats and oils, and are contained in less than 10% by mass in fats and oils derived from ruminants. In recent years, there has been a demand for oil and fat compositions that have not been chemically treated, particularly hydrogenated, that is, oil and fat compositions that are substantially free of trans fatty acids and have appropriate consistency.
本発明においては、上記のエステル交換油脂(A)、エステル交換油脂(B)、好ましくはパーム系油脂を含めた食用油脂として、天然油脂、並びに天然油脂に分別、完全水素添加及びエステル交換から選択される1又は2以上の処理を施した加工油脂から選択される1種又は2種以上を組合せて用いることにより、実質的にトランス脂肪酸を含まない焼菓子用油脂組成物を容易に得ることができる。 In the present invention, the edible fats and oils including the above-mentioned transesterified fats and oils (A) and transesterified fats and oils (B), preferably palm-based fats and oils, are selected from natural fats and oils, and separation, complete hydrogenation and transesterification into natural fats and oils. By using one or a combination of two or more selected from the processed fats and oils that have been subjected to one or more treatments, it is possible to easily obtain a fat and oil composition for baked confectionery that is substantially free of trans fatty acids. can.
本発明の焼菓子用油脂組成物には、その他の成分を含有させることができる。その他の成分としては、例えば、水、乳化剤、増粘安定剤、食塩や塩化カリウム等の塩味剤、クエン酸、酢酸、乳酸、グルコン酸等の酸味料、糖類や糖アルコール類、ステビア、アスパルテーム等の甘味料、β-カロチン、カラメル、紅麹色素等の着色料、トコフェロール、茶抽出物等の酸化防止剤、小麦蛋白や大豆蛋白等の植物蛋白、卵及び各種卵加工品、着香料、乳製品、調味料、pH調整剤、食品保存料、日持ち向上剤、果実、果汁、コーヒー、ナッツペースト、香辛料、カカオマス、ココアパウダー、穀類、豆類、野菜類、肉類、魚介類等の食品素材や食品添加物が挙げられる。 The oil and fat composition for baked confectionery of the present invention may contain other components. Other components include, for example, water, emulsifiers, thickening stabilizers, salting agents such as salt and potassium chloride, acidulants such as citric acid, acetic acid, lactic acid and gluconic acid, sugars and sugar alcohols, stevia, aspartame and the like. Sweeteners, β-carotene, caramel, coloring agents such as red koji pigment, tocopherols, antioxidants such as tea extracts, plant proteins such as wheat protein and soybean protein, eggs and various processed egg products, flavoring agents, milk Food materials and foods such as products, seasonings, pH adjusters, food preservatives, shelf life improvers, fruits, fruit juices, coffee, nut pastes, spices, cacao mass, cocoa powder, grains, beans, vegetables, meats, seafood, etc. Additives can be mentioned.
上記の乳化剤としては、例えば、グリセリン脂肪酸エステル、グリセリン酢酸脂肪酸エステル、グリセリン乳酸脂肪酸エステル、グリセリンコハク酸脂肪酸エステル、グリセリン酒石酸脂肪酸エステル、グリセリンクエン酸脂肪酸エステル、グリセリンジアセチル酒石酸脂肪酸エステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステル、ショ糖酢酸イソ酪酸エステル、ポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、プロピレングリコール脂肪酸エステル、ステアロイル乳酸カルシウム、ステアロイル乳酸ナトリウム及びポリオキシエチレンソルビタンモノグリセリド等の合成乳化剤や、例えば大豆レシチン、卵黄レシチン、大豆リゾレシチン、卵黄リゾレシチン、酵素処理卵黄、サポニン、植物ステロール類、乳脂肪球皮膜等の天然乳化成分が挙げられる。 Examples of the above emulsifier include glycerin fatty acid ester, glycerin acetic acid fatty acid ester, glycerin lactic acid fatty acid ester, glycerin succinic acid fatty acid ester, glycerin tartrate acid fatty acid ester, glycerin phenic acid fatty acid ester, glycerin diacetyl tartrate fatty acid ester, sorbitan fatty acid ester, and sho. Synthetic emulsifiers such as sugar fatty acid ester, sucrose acetate isobutyric acid ester, polyglycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester, propylene glycol fatty acid ester, stearoyl lactate calcium, stearoyl lactate sodium and polyoxyethylene sorbitan monoglyceride, for example, soybean lecithin. , Egg yolk lecithin, soybean lysolecithin, egg yolk lysolecithin, enzyme-treated egg yolk, saponin, plant sterols, natural emulsifying components such as milk fat globules.
本発明においては、次の条件(5)を満たすように、乳化剤を含有させると、焼菓子製造時の抱水性やクリーミング性が一層向上し、製造作業性が向上するため好ましい。
<条件(5)>
(5)炭素数16以上の飽和脂肪酸残基を有するモノグリセリドと、炭素数16以上の不飽和脂肪酸残基を有するモノグリセリドとを、前者:後者で、1:2~8の質量比で含有する。
In the present invention, it is preferable to contain an emulsifier so as to satisfy the following condition (5) because the water holding property and creaming property at the time of manufacturing baked confectionery are further improved and the manufacturing workability is improved.
<Condition (5)>
(5) A monoglyceride having a saturated fatty acid residue having 16 or more carbon atoms and a monoglyceride having an unsaturated fatty acid residue having 16 or more carbon atoms are contained in the former: the latter in a mass ratio of 1: 2 to 8.
炭素数16以上の飽和脂肪酸残基を有するモノグリセリド(以下単にSFA-MGと記載する場合がある)については、その構成脂肪酸鎖が炭素数16~22であることが好ましく、16~20であることがより好ましい。また、炭素数16以上の不飽和脂肪酸残基を有するモノグリセリド(以下単にUSFA-MGと記載する場合がある)については、その構成脂肪酸鎖が炭素数16~22であることが好ましく、16~20であることがより好ましい。 For monoglyceride having a saturated fatty acid residue having 16 or more carbon atoms (hereinafter, may be simply referred to as SFA-MG), the constituent fatty acid chain is preferably 16 to 22 carbon atoms, preferably 16 to 20 carbon atoms. Is more preferable. Further, for monoglyceride having an unsaturated fatty acid residue having 16 or more carbon atoms (hereinafter, may be simply referred to as USFA-MG), the constituent fatty acid chain is preferably 16 to 22 carbon atoms, and 16 to 20 carbon atoms. Is more preferable.
また、SFA-MGとUSFA-MGの質量比(以下単にSFA-MG:USFA-MGと記載する場合がある)が、前者:後者で、1:2~8となることが好ましく、1:2.5~7となることがより好ましく、1:3~7となることが最も好ましい。 Further, the mass ratio of SFA-MG and USFA-MG (hereinafter, may be simply referred to as SFA-MG: USFA-MG) is preferably 1: 2 to 8 in the former: the latter, preferably 1: 2. It is more preferably .5 to 7, and most preferably 1: 3 to 7.
尚、本発明の焼菓子用油脂組成物中、好ましい食感を得る観点から、乳化剤の含量は0.01~5質量%であることが好ましく、0.05~4質量%であることがより好ましく、0.1~3質量%であることが最も好ましい。 In the oil / fat composition for baked confectionery of the present invention, the content of the emulsifier is preferably 0.01 to 5% by mass, more preferably 0.05 to 4% by mass, from the viewpoint of obtaining a preferable texture. It is preferably 0.1 to 3% by mass, most preferably 0.1 to 3% by mass.
上記増粘安定剤としては、グアーガム、ローカストビーンガム、カラギーナン、アラビアガム、アルギン酸類、ペクチン、キサンタンガム、プルラン、タマリンドシードガム、サイリウムシードガム、結晶セルロース、カルボキシメチルセルロース、メチルセルロース、寒天、グルコマンナン、ゼラチン、澱粉、化工澱粉等が挙げられ、これらの中から選ばれた1種又は2種以上を用いることができる。 Examples of the thickening stabilizer include guar gum, locust bean gum, carrageenan, arabic gum, alginic acid, starch, xanthan gum, purulan, tamarind seed gum, psyllium seed gum, crystalline cellulose, carboxymethyl cellulose, methyl cellulose, agar, glucomannan, and gelatin. , Starch, chemical starch and the like, and one or more selected from these can be used.
本発明の焼菓子用油脂組成物は、可塑性を有することが好ましく、その形態は、水相を含有するマーガリンタイプとすることも、水相を含有しないショートニングタイプとすることもできる。水相を含有する場合には、水分含量は25質量%以下であることが好ましく、20質量%以下がより好ましい。また乳化物である場合には、その乳化形態は、油中水型及び二重乳化型のいずれでも構わない。 The oil / fat composition for baked confectionery of the present invention preferably has plasticity, and its form may be a margarine type containing an aqueous phase or a shortening type containing no aqueous phase. When the aqueous phase is contained, the water content is preferably 25% by mass or less, more preferably 20% by mass or less. When it is an emulsion, the emulsified form may be either a water-in-oil type or a double emulsified type.
また、本発明の焼菓子用油脂組成物中、上記条件(1)~(3)を満たすことができる油相を、75質量%以上含有することが好ましく、85質量%以上含有することがより好ましく、95質量%以上含有することが最も好ましい。 Further, in the oil / fat composition for baked confectionery of the present invention, it is preferable to contain 75% by mass or more of an oil phase capable of satisfying the above conditions (1) to (3), and more preferably 85% by mass or more. It is preferably contained in an amount of 95% by mass or more, most preferably 95% by mass or more.
次に、本発明の焼菓子用油脂組成物の製造方法について述べる。
本発明の焼菓子用油脂組成物は、上記条件(1)~(3)を満たすことができる油相を溶解した後、必要に応じ、水相を添加して乳化し、冷却し、結晶化させることにより製造される。
Next, a method for producing the oil / fat composition for baked confectionery of the present invention will be described.
The oil and fat composition for baked confectionery of the present invention dissolves an oil phase that can satisfy the above conditions (1) to (3), and then, if necessary, adds an aqueous phase to emulsify, cool, and crystallize. Manufactured by letting.
詳しくは、先ず、上記条件(1)~(3)、好ましくは(1)~(4)を満たすことができるように、各種油脂を1種又は2種以上選択して、加熱溶解し、混合・撹拌を行い、油相を調製する。尚、油溶性のその他の成分については、必要により油相に含有させることができる。また、必要に応じて、水に水溶性のその他の成分を添加した水相を調製した後、該水相を油相に添加し、乳化する。 Specifically, first, one or two or more kinds of various oils and fats are selected, heated and dissolved, and mixed so that the above conditions (1) to (3), preferably (1) to (4) can be satisfied.・ Stir to prepare the oil phase. Other oil-soluble components can be contained in the oil phase if necessary. If necessary, an aqueous phase is prepared by adding other water-soluble components to water, and then the aqueous phase is added to the oil phase to emulsify.
次に、殺菌処理を行うのが好ましい。尚、殺菌方法は、タンクでのバッチ式でも、プレート型熱交換機や掻き取り式熱交換機を用いた連続式でも構わない。
次に、冷却し、必要により可塑化する。本発明において、冷却条件は、好ましくは-0.5℃/分以上、さらに好ましくは-5℃/分以上とする。冷却に用いる機器としては、密閉型連続式チューブ冷却機、例えばボテーター、コンビネーター、パーフェクター等のマーガリン製造機やプレート型熱交換機等が挙げられ、また、開放型のダイアクーラーとコンプレクターの組み合わせ等が挙げられる。
尚、本発明の焼菓子用油脂組成物を製造する際のいずれかの製造工程で、任意に、窒素、空気等を含気させることができる。
Next, it is preferable to carry out a sterilization treatment. The sterilization method may be a batch type in a tank or a continuous type using a plate type heat exchanger or a scraping type heat exchanger.
It is then cooled and optionally plasticized. In the present invention, the cooling conditions are preferably −0.5 ° C./min or higher, more preferably −5 ° C./min or higher. Examples of the equipment used for cooling include a closed type continuous tube cooler, for example, a margarine making machine such as a botator, a combinator, and a perfector, a plate type heat exchanger, and the like, and a combination of an open type diacooler and a compactor. And so on.
It should be noted that nitrogen, air and the like can be optionally aerated in any of the production steps when producing the oil and fat composition for baked confectionery of the present invention.
次に、本発明の焼菓子について述べる。
本発明の焼菓子は、上述した本発明の焼菓子用油脂組成物を練込油脂や折込油脂として用いたものである。
上記焼菓子としては、例えば、パイやペストリー、パウンドケーキ、フルーツケーキ、マドレーヌ、バウムクーヘン、カステラ等のバターケーキ、アイスボックスクッキー、ワイヤーカットクッキー、サブレ、ラングドシャクッキー等のクッキー、ビスケット等が挙げられる。
Next, the baked confectionery of the present invention will be described.
The baked confectionery of the present invention uses the above-mentioned fat and oil composition for baked confectionery of the present invention as a kneaded fat and oil or a folded fat and oil.
Examples of the baked confectionery include butter cakes such as pies, pastries, pound cakes, fruit cakes, madeleines, baumkuchens and castella, ice box cookies, wire-cut cookies, sabres, cookie such as Langdosha cookies, and biscuits.
これらの焼菓子の生地は、シュガーバッター法、フラワーバッター法、オールインミックス法等、公知の方法によって製造することができ、常法に従って焼成される。
焼菓子生地を製造する際の本発明の焼菓子用油脂組成物の使用量は、選択した焼菓子の種類によって決定されるものであり、特に限定されないが、おおよそ焼菓子生地中に5~40質量%である。
The dough for these baked confectioneries can be produced by a known method such as a sugar batter method, a flower batter method, an all-in-mix method, etc., and is baked according to a conventional method.
The amount of the oil-and-fat composition for baked confectionery of the present invention used in producing the baked confectionery dough is determined by the type of baked confectionery selected, and is not particularly limited, but is approximately 5 to 40 in the baked confectionery dough. It is mass%.
次に、本発明の複合菓子について述べる。
本発明の複合菓子は、本発明の焼菓子用油脂組成物を用いた本発明の焼菓子と、ナッツ類、チョコレート等の油性菓子が組み合わさったものであり、本発明の焼菓子用油脂組成物の効果が顕著に得られることから、焼菓子とチョコレートとが組み合わさった複合菓子が好ましい。
Next, the complex confectionery of the present invention will be described.
The complex confectionery of the present invention is a combination of the baked confectionery of the present invention using the oil-and-fat composition for baked confectionery of the present invention and the oil-based confectionery such as nuts and chocolate, and the oil-and-fat composition for baked confectionery of the present invention. A complex confectionery that is a combination of baked confectionery and chocolate is preferable because the effect of the product can be remarkably obtained.
上記ナッツ類としては、ピーナッツ、アーモンド、カシューナッツ、ピスタチオ、ヘーゼルナッツ、ピーカンナッツ、オーナッツ、マカデミアナッツ、ブラジルナッツ、ココナッツ、松、けし、ひまわり等の種実や堅果、それらのホール品・割物品・スライス品、それらを用いたペースト・ピューレ等の加工品等が挙げられる。 The above nuts include peanuts, almonds, cashew nuts, pistachios, hazelnuts, pecan nuts, onuts, macadamia nuts, brazil nuts, coconuts, pine, keshi, sunflowers and other seeds and nuts, their wholes, splits and slices. Examples thereof include processed products such as pastes and purees using them.
上記チョコレートとは、カカオマスやココアパウダー等のカカオ成分を含有し、カカオ成分にさらに粉乳等の各種粉末食品、油脂類、糖類、乳化剤、香料、色素等の中から選択した原料を任意の割合で混合し、常法によりロール掛け、コンチング処理して得たものを意味する。もちろん、気相や水相を含有するものも使用することができる。 The above chocolate contains cacao components such as cacao mass and cocoa powder, and in addition to the cacao components, various powdered foods such as milk powder, fats and oils, sugars, emulsifiers, fragrances, pigments and the like are selected in an arbitrary ratio. It means the product obtained by mixing, rolling by a conventional method, and conching. Of course, those containing a gas phase or an aqueous phase can also be used.
上記各種粉末食品としては、例えば、脱脂粉乳、全粉乳、果実粉末、果汁粉末、生クリーム粉末、チーズ粉末、コーヒー粉末、ヨーグルト粉末等が例示される。各種粉末食品を使用する場合、その配合量は、チョコレート中、好ましくは0.5~60質量%、さらに好ましくは1~50質量%である。 Examples of the various powdered foods include defatted milk powder, whole milk powder, fruit powder, fruit juice powder, fresh cream powder, cheese powder, coffee powder, yogurt powder and the like. When various powdered foods are used, the blending amount thereof is preferably 0.5 to 60% by mass, more preferably 1 to 50% by mass in chocolate.
上記油脂類としては、カカオバター、その他の動植物性油脂、及びこれらの分別油、硬化油、エステル交換油脂等が挙げられ、これらは単独で又は混合して使用することができ、好ましくはテンパリング型のものを使用する。油脂類の配合量は、チョコレート中、好ましくは20~80質量%、さらに好ましくは30~60質量%である。 Examples of the above-mentioned fats and oils include cocoa butter, other animal and vegetable fats and oils, fractionated oils thereof, hydrogenated oils, transesterified fats and oils, etc., which can be used alone or in combination, preferably tempering type. Use the one. The blending amount of the fats and oils is preferably 20 to 80% by mass, more preferably 30 to 60% by mass in the chocolate.
上記乳化剤としては、特に限定されず、必要に応じて粘度上昇を抑制する目的で、レシチン、ポリグリセリン縮合リシノレイン酸エステル、蔗糖脂肪酸エステル等を添加することができる。乳化剤の配合量は、チョコレート中、好ましくは0.01~10質量%、さらに好ましくは0.1~5質量%である。 The emulsifier is not particularly limited, and lecithin, polyglycerin condensed ricinoleic acid ester, citrus fatty acid ester and the like can be added for the purpose of suppressing an increase in viscosity, if necessary. The blending amount of the emulsifier is preferably 0.01 to 10% by mass, more preferably 0.1 to 5% by mass in chocolate.
本発明の複合菓子における複合方法の例としては、チョコレートの場合は、チョコレートをフィリング用、サンド用、トッピング用、コーティング用、エンローバー用等として焼菓子と組み合わせたり、砕いた焼菓子をチョコレート中に埋め込む方法が挙げられる。ナッツ類の場合についても、これに準じて複合することができる。 As an example of the compounding method in the compound confectionery of the present invention, in the case of chocolate, the chocolate is combined with the baked confectionery for filling, sanding, topping, coating, enrober, etc., or the crushed baked confectionery is contained in the chocolate. There is a method of embedding in. In the case of nuts, it can be compounded in the same manner.
以下、実施例に基づいて、本発明を更に詳述する。 Hereinafter, the present invention will be described in more detail based on Examples.
(製造例1:ランダムエステル交換油脂(1)の製造)
沃素価が3以下となるまで水素添加を行い、極度硬化油としたハイエルシン菜種油30質量部、ハイオレイックヒマワリ油(構成脂肪酸組成中のオレイン酸残基量が86.3質量%)70質量部を、それぞれ加熱溶解した状態で混合して、油脂配合物(1)を得、この油脂配合物(1)に対し、ナトリウムメトキシドを触媒として用い常法に従ってランダムエステル交換反応を行った。
この後、常法に従って、漂白(白土量は対油3質量%、処理温度85℃)及び脱臭(250℃、60分間、吹込み水蒸気量は対油5質量%)の精製処理を行い、ランダムエステル交換油脂(1)(以下、単に、IE-1と記載する場合がある)を得た。
(Production Example 1: Production of Random Transesterified Oil (1))
30 parts by mass of hyelsin rapeseed oil and 70 parts by mass of hyoleic sunflower oil (the amount of oleic acid residue in the constituent fatty acid composition is 86.3% by mass), which was hydrogenated until the iodine value became 3 or less. Was mixed in a state of being heated and dissolved to obtain an oil / fat mixture (1), and a random transesterification reaction was carried out with the oil / fat mixture (1) using sodium methoxydo as a catalyst according to a conventional method.
After that, according to a conventional method, bleaching (the amount of white clay is 3% by mass with respect to oil, the treatment temperature is 85 ° C.) and deodorization (250 ° C., 60 minutes, the amount of water vapor blown is 5% by mass with respect to oil) are refined at random. A transesterified oil (1) (hereinafter, may be simply referred to as IE-1) was obtained.
(製造例2:ランダムエステル交換油脂(2)の製造)
沃素価が55のパーム分別軟部油100質量部に対し、製造例1と同様に、常法に従って、ナトリウムメトキシドを触媒とするランダムエステル交換反応、漂白・脱臭の精製処理を行い、ランダムエステル交換油脂(2)(以下、単にIE-2と記載する場合がある)を得た。
(Production Example 2: Production of Random Transesterified Oil (2))
100 parts by mass of palm fractionated soft oil having an iodine value of 55 is subjected to random transesterification reaction catalyzed by sodium methoxide, bleaching / deodorizing purification treatment, and random transesterification according to a conventional method, as in Production Example 1. Oils and fats (2) (hereinafter, may be simply referred to as IE-2) were obtained.
(製造例3:ランダムエステル交換油脂(3)の製造)
沃素価が60のパームスーパーオレイン100質量部に対し、製造例1と同様に、常法に従って、ナトリウムメトキシドを触媒とするランダムエステル交換反応、漂白・脱臭の精製処理を行い、ランダムエステル交換油脂(3)(以下、単にIE-3と記載する場合がある)を得た。
(Production Example 3: Production of Random Transesterified Oil (3))
Similar to Production Example 1, 100 parts by mass of palm superolein having an iodine value of 60 is subjected to a random transesterification reaction catalyzed by sodium methoxide and a purification treatment for bleaching and deodorization according to a conventional method, and then a random transesterification fat or oil is performed. (3) (hereinafter, may be simply referred to as IE-3) was obtained.
(製造例4:ランダムエステル交換油脂(4)の製造)
沃素価が55のパーム分別軟部油を80質量部と、沃素価が3以下となるまで水素添加を行い、極度硬化油としたハイエルシン菜種油20質量部とを、それぞれ加熱溶解した状態で混合して、油脂配合物(4)を得た。この油脂配合物(4)に対し、製造例1と同様に、常法に従って、ナトリウムメトキシドを触媒とするランダムエステル交換反応、漂白・脱臭の精製処理を行い、ランダムエステル交換油脂(4)(以下、単にIE-4と記載する場合がある)を得た。
(Production Example 4: Production of Random Transesterified Oil (4))
80 parts by mass of palm-separated soft oil having an iodine value of 55 and 20 parts by mass of hyelcin rapeseed oil, which was made into an extremely hydrogenated oil by hydrogenating until the iodine value became 3 or less, were mixed in a heated and dissolved state. , The oil and fat compound (4) was obtained. The oil / fat mixture (4) is subjected to a random transesterification reaction catalyzed by sodium methoxide and a refining treatment for bleaching / deodorization according to a conventional method in the same manner as in Production Example 1, and the random transesterification oil / fat (4) ( Hereinafter, it may be simply referred to as IE-4).
(製造例5:ランダムエステル交換油脂(5)の製造)
パーム油60質量部、パーム核油(構成脂肪酸組成中のラウリン酸残基量50.1質量%)20質量部及び菜種油20質量部を、それぞれ加熱溶解した状態で混合して、油脂配合物(5)を得た。この油脂配合物(5)に対し、製造例1と同様に、常法に従って、ナトリウムメトキシドを触媒とするランダムエステル交換反応、漂白・脱臭の精製処理を行い、ランダムエステル交換油脂(5)(以下、単にIE-5と記載する場合がある)を得た。
(Production Example 5: Production of Random Transesterified Oil (5))
60 parts by mass of palm oil, 20 parts by mass of palm kernel oil (50.1% by mass of lauric acid residue in the constituent fatty acid composition) and 20 parts by mass of rapeseed oil are mixed in a state of being heated and dissolved to prepare an oil and fat mixture (fat and oil mixture). 5) was obtained. The oil / fat mixture (5) is subjected to a random transesterification reaction catalyzed by sodium methoxide and a refining treatment for bleaching / deodorization according to a conventional method in the same manner as in Production Example 1, and the random transesterification oil / fat (5) ( Hereinafter, it may be simply referred to as IE-5).
(製造例6:エステル交換油脂(6)の製造)
沃素価が3以下となるまで水素添加を行い極度硬化油としたパーム油25質量部、及びヤシ油(構成脂肪酸組成中のラウリン酸残基量50.3質量%)75質量部を、それぞれ加熱溶解した状態で混合して、油脂配合物(6)を得た。この油脂配合物(6)に対し、製造例1と同様に、常法に従って、ナトリウムメトキシドを触媒とするランダムエステル交換反応、漂白・脱臭の精製処理を行い、ランダムエステル交換油脂(6)(以下、単にIE-6と記載する場合がある)を得た。
(Manufacturing Example 6: Production of transesterified oil (6))
Heat 25 parts by mass of palm oil and 75 parts by mass of coconut oil (50.3% by mass of lauric acid residue in the constituent fatty acid composition), which were made into extremely hydrogenated oil by hydrogenating until the iodine value became 3 or less. The oil and fat mixture (6) was obtained by mixing in a dissolved state. The oil / fat mixture (6) is subjected to a random transesterification reaction catalyzed by sodium methoxide and a refining treatment for bleaching / deodorization according to a conventional method in the same manner as in Production Example 1, and the random transesterification oil / fat (6) ( Hereinafter, it may be simply referred to as IE-6).
得られたIE-1~6のSFC、トリグリセリド組成中のBO2、B2O及びLLLの含量、並びに構成脂肪酸組成中のラウリン酸残基量を表1に示す。
尚、IE-1は、上記エステル交換油脂(A)に該当し、IE-2~4はパーム系油脂、IE-5及びIE-6は上記エステル交換油脂(B)に該当する。
IE-1は、構成脂肪酸組成中、オレイン酸残基を60.4質量%、炭素数20~22の脂肪酸残基を17.4質量%含有し、構成脂肪酸中の不飽和脂肪酸中におけるオレイン酸含量の質量比が0.93であった。
IE-5は、構成脂肪酸組成中、オレイン酸残基を31.1質量%、ラウリン酸残基を7.3質量%含有し、構成脂肪酸中の飽和脂肪酸の含量に対するラウリン酸の質量比が0.12であり、構成脂肪酸組成中のパルミチン酸含量が29.4質量%、ステアリン酸含量が9.5質量%であった。
IE-6は、構成脂肪酸組成中、オレイン酸残基を4.5質量%、ラウリン酸残基を37.8質量%含有し、構成脂肪酸中の飽和脂肪酸の含量に対するラウリン酸の質量比が0.40であり、構成脂肪酸組成中のパルミチン酸含量が17.4質量%、ステアリン酸含量が15.5質量%であった。
Table 1 shows the SFC of IE-1 to 6 obtained, the contents of BO2, B2O and LLL in the triglyceride composition, and the amount of lauric acid residue in the constituent fatty acid composition.
IE-1 corresponds to the transesterified fat (A), IE-2 to 4 correspond to palm-based fats and oils, and IE-5 and IE-6 correspond to the transesterified fats and oils (B).
IE-1 contains 60.4% by mass of oleic acid residues and 17.4% by mass of fatty acid residues having 20 to 22 carbon atoms in the constituent fatty acid composition, and oleic acid in the unsaturated fatty acids in the constituent fatty acids. The mass ratio of content was 0.93.
IE-5 contains 31.1% by mass of oleic acid residue and 7.3% by mass of lauric acid residue in the constituent fatty acid composition, and the mass ratio of lauric acid to the content of saturated fatty acid in the constituent fatty acid is 0. It was .12, and the palmitic acid content in the constituent fatty acid composition was 29.4% by mass, and the stearic acid content was 9.5% by mass.
IE-6 contains 4.5% by mass of oleic acid residue and 37.8% by mass of lauric acid residue in the constituent fatty acid composition, and the mass ratio of lauric acid to the content of saturated fatty acid in the constituent fatty acid is 0. It was .40, and the palmitic acid content in the constituent fatty acid composition was 17.4% by mass and the stearic acid content was 15.5% by mass.
(実施例1)
IE-1の60質量部及びIE-5の40質量部を、それぞれ65℃に加熱溶解された状態で混合し、更に酸化防止剤(トコフェロール)0.15質量部及びレシチン0.1質量部を加えて撹拌し、得られた油相を急冷可塑化し、焼菓子用油脂組成物Iを得た。
(Example 1)
60 parts by mass of IE-1 and 40 parts by mass of IE-5 are mixed in a state of being heated and dissolved at 65 ° C., and further, 0.15 parts by mass of an antioxidant (tocopherol) and 0.1 parts by mass of lecithin are added. In addition, the mixture was stirred and the obtained oil phase was rapidly cooled and plasticized to obtain an oil / fat composition I for baked confectionery.
(実施例2)
IE-1の50質量部、IE-5の30質量部及びIE-6の20質量部を、それぞれ65℃に加熱溶解された状態で混合し、更に酸化防止剤(トコフェロール)0.15質量部及びレシチン0.1質量部を加えて撹拌し、得られた油相を急冷可塑化し、焼菓子用油脂組成物IIを得た。
(Example 2)
50 parts by mass of IE-1, 30 parts by mass of IE-5, and 20 parts by mass of IE-6 are mixed in a state of being heated and dissolved at 65 ° C., and further 0.15 parts by mass of an antioxidant (tocopherol) is added. And 0.1 part by mass of lecithin was added and stirred, and the obtained oil phase was rapidly cooled and plasticized to obtain an oil / fat composition II for baked confectionery.
(実施例3)
IE-1の40質量部、IE-3の40質量部及びIE-5の20質量部を、それぞれ65℃に加熱溶解された状態で混合し、更に酸化防止剤(トコフェロール)0.15質量部及びレシチン0.1質量部を加えて撹拌し、得られた油相を急冷可塑化し、焼菓子用油脂組成物IIIを得た。
(Example 3)
40 parts by mass of IE-1, 40 parts by mass of IE-3, and 20 parts by mass of IE-5 are mixed in a state of being heated and dissolved at 65 ° C., and further 0.15 parts by mass of an antioxidant (tocopherol) is added. And 0.1 part by mass of lecithin was added and stirred, and the obtained oil phase was rapidly cooled and plasticized to obtain an oil / fat composition III for baked confectionery.
(実施例4)
IE-1の40質量部、IE-2の20質量部、IE-3の20質量部及びIE-5の20質量部を、それぞれ65℃に加熱溶解された状態で混合し、更に酸化防止剤(トコフェロール)0.15質量部及びレシチン0.1質量部を加えて撹拌し、得られた油相を急冷可塑化し、焼菓子用油脂組成物IVを得た。
(Example 4)
40 parts by mass of IE-1, 20 parts by mass of IE-2, 20 parts by mass of IE-3 and 20 parts by mass of IE-5 are mixed in a state of being heated and dissolved at 65 ° C., and further an antioxidant is added. (Tocopherol) 0.15 part by mass and lecithin 0.1 part by mass were added and stirred, and the obtained oil phase was rapidly cooled and plasticized to obtain an oil / fat composition IV for baked confectionery.
(実施例5)
IE-1の40質量部、IE-3の35質量部、IE-4の10質量部及びIE-6の15質量部を、それぞれ65℃に加熱溶解された状態で混合し、更に酸化防止剤(トコフェロール)0.15質量部及びレシチン0.1質量部を加えて撹拌し、得られた油相を急冷可塑化し、焼菓子用油脂組成物Vを得た。
(Example 5)
40 parts by mass of IE-1, 35 parts by mass of IE-3, 10 parts by mass of IE-4 and 15 parts by mass of IE-6 are mixed in a state of being heated and dissolved at 65 ° C., and further an antioxidant is added. (Tocopherol) 0.15 part by mass and lecithin 0.1 part by mass were added and stirred, and the obtained oil phase was rapidly cooled and plasticized to obtain an oil / fat composition V for baked confectionery.
(実施例6)
IE-1の30質量部、IE-2の20質量部、IE-3の20質量部及びIE-5の30質量部を、それぞれ65℃に加熱溶解された状態で混合し、更に酸化防止剤(トコフェロール)0.15質量部及びレシチン0.1質量部を加えて撹拌し、得られた油相を急冷可塑化し、焼菓子用油脂組成物VIを得た。
(Example 6)
30 parts by mass of IE-1, 20 parts by mass of IE-2, 20 parts by mass of IE-3 and 30 parts by mass of IE-5 are mixed in a state of being heated and dissolved at 65 ° C., and further an antioxidant is added. (Tocopherol) 0.15 part by mass and lecithin 0.1 part by mass were added and stirred, and the obtained oil phase was rapidly cooled and plasticized to obtain an oil / fat composition VI for baked confectionery.
(実施例7)
IE-1の60質量部、IE-3の10質量部及びIE-5の30質量部を、それぞれ65℃に加熱溶解された状態で混合し、更に酸化防止剤(トコフェロール)0.15質量部及びレシチン0.1質量部を加えて撹拌し、得られた油相を急冷可塑化し、焼菓子用油脂組成物VIIを得た。
(Example 7)
60 parts by mass of IE-1, 10 parts by mass of IE-3, and 30 parts by mass of IE-5 are mixed in a state of being heated and dissolved at 65 ° C., and further 0.15 parts by mass of an antioxidant (tocopherol) is added. And 0.1 part by mass of lecithin was added and stirred, and the obtained oil phase was rapidly cooled and plasticized to obtain an oil / fat composition VII for baked confectionery.
(実施例8)
レシチン0.1質量部に代えて、SFA-MG(エマルジーMP、理研ビタミン社製)0.1質量部及びUSFA-MG(エマルジーMO、理研ビタミン社製)0.4質量部(SFA-MG:USFA-MG=1:4)を加えた他は実施例4と同様にして、焼菓子用油脂組成物VIIIを得た。
(Example 8)
Instead of 0.1 parts by mass of lecithin, 0.1 parts by mass of SFA-MG (Emulgie MP, manufactured by Riken Vitamin Co., Ltd.) and 0.4 parts by mass of USFA-MG (Emulgy MO, manufactured by Riken Vitamin Co., Ltd.) (SFA-MG: An oil / fat composition VIII for baked confectionery was obtained in the same manner as in Example 4 except that USFA-MG = 1: 4) was added.
(実施例9)
レシチン0.1質量部に代えて、SFA-MG(エマルジーMP、理研ビタミン社製)0.17質量部及びUSFA-MG(エマルジーMO、理研ビタミン社製)0.34質量部(SFA-MG:USFA-MG=1:2)を加えた他は実施例4と同様にして、焼菓子用油脂組成物IXを得た。
(Example 9)
Instead of 0.1 parts by mass of lecithin, 0.17 parts by mass of SFA-MG (Emulgie MP, manufactured by Riken Vitamin Co., Ltd.) and 0.34 parts by mass of USFA-MG (Emulgy MO, manufactured by Riken Vitamin Co., Ltd.) (SFA-MG: The oil and fat composition IX for baked confectionery was obtained in the same manner as in Example 4 except that USFA-MG = 1: 2) was added.
(比較例1)
IE-1の40質量部、IE-2の45質量部及びIE-4の15質量部を、それぞれ65℃に加熱溶解された状態で混合し、更に酸化防止剤(トコフェロール)0.15質量部及びレシチン0.1質量部を加えて撹拌し、得られた油相を急冷可塑化し、焼菓子用油脂組成物Xを得た。
(Comparative Example 1)
40 parts by mass of IE-1, 45 parts by mass of IE-2, and 15 parts by mass of IE-4 are mixed in a state of being heated and dissolved at 65 ° C., and further 0.15 parts by mass of an antioxidant (tocopherol) is added. And 0.1 part by mass of lecithin was added and stirred, and the obtained oil phase was rapidly cooled and plasticized to obtain an oil / fat composition X for baked confectionery.
(比較例2)
IE-1の95質量部及びIE-5の5質量部を、それぞれ65℃に加熱溶解された状態で混合し、更に酸化防止剤(トコフェロール)0.15質量部及びレシチン0.1質量部を加えて撹拌し、得られた油相を急冷可塑化し、焼菓子用油脂組成物XIを得た。
(Comparative Example 2)
95 parts by mass of IE-1 and 5 parts by mass of IE-5 are mixed in a state of being heated and dissolved at 65 ° C., and further, 0.15 part by mass of an antioxidant (tocopherol) and 0.1 part by mass of lecithin are added. In addition, the mixture was stirred and the obtained oil phase was rapidly cooled and plasticized to obtain an oil / fat composition XI for baked confectionery.
(比較例3)
IE-3の20質量部、IE-4の50質量部及び菜種油30質量部を、それぞれ65℃に加熱溶解された状態で混合し、更に酸化防止剤(トコフェロール)0.15質量部及びレシチン0.1質量部を加えて撹拌し、得られた油相を急冷可塑化し、焼菓子用油脂組成物XIIを得た。
(Comparative Example 3)
20 parts by mass of IE-3, 50 parts by mass of IE-4 and 30 parts by mass of rapeseed oil are mixed in a state of being heated and dissolved at 65 ° C., and further, 0.15 part by mass of antioxidant (tocopherol) and 0 part of lecithin are mixed. .1 part by mass was added and stirred, and the obtained oil phase was rapidly cooled and plasticized to obtain an oil / fat composition XII for baked confectionery.
得られた焼菓子用油脂組成物I~XIIの詳細を表2に示す。 Table 2 shows the details of the obtained oil and fat compositions for baked confectionery I to XII.
<チョコレート複合クッキーの製造及び評価>
得られた焼菓子用油脂組成物I~XIIを用いて、下記の製造方法により、チョコレート複合クッキーを製造し、後述の各種評価を行った。
<Manufacturing and evaluation of chocolate compound cookies>
Using the obtained oil and fat compositions for baked confectionery I to XII, chocolate composite cookies were produced by the following production methods, and various evaluations described later were performed.
(チョコレート複合クッキーの製造方法)
15℃に調温した焼菓子用油脂組成物(上記焼菓子用油脂組成物I~XIIのいずれか)45質量部と上白糖45質量部をミキサーボウルに投入して卓上ミキサーにセットし、軽く混合した後、高速で7分間クリーミングした。次いで、低速で混合しながら、30秒かけて水15質量部を添加し、さらに1分混合した。さらに、予め混合して篩っておいた小麦粉100質量部とベーキングパウダー1質量部の混合物を添加し、低速で1分混合して、ワイヤーカットクッキー生地を得た。得られたクッキー生地を、厚さ7ミリ、直径48ミリの丸型にワイヤーカット成型した。成型したクッキー生地をオーブン(フジサワ社製)で190℃にて13分焼成後、25℃にて40分冷却し、ワイヤーカットクッキーI~XII(英字は使用した焼菓子用油脂組成物に対応)を得た。
(Manufacturing method of chocolate compound cookie)
Put 45 parts by mass of a baked confectionery oil / fat composition (any of the above baked confectionery oil / fat compositions I to XII) and 45 parts by mass of fine white sugar into a mixer bowl and set them in a tabletop mixer, and lightly. After mixing, it was creamed at high speed for 7 minutes. Then, while mixing at a low speed, 15 parts by mass of water was added over 30 seconds, and the mixture was further mixed for 1 minute. Further, a mixture of 100 parts by mass of wheat flour and 1 part by mass of baking powder that had been mixed and sieved in advance was added and mixed at a low speed for 1 minute to obtain a wire-cut cookie dough. The obtained cookie dough was wire-cut and molded into a round shape having a thickness of 7 mm and a diameter of 48 mm. The molded cookie dough is baked in an oven (manufactured by Fujisawa) at 190 ° C for 13 minutes, then cooled at 25 ° C for 40 minutes, and wire-cut cookies I to XII (English letters correspond to the oil and fat composition for baked confectionery used). Got
一方、砂糖44.6質量部、カカオマス25質量部、カカオバター30質量部及びレシチン0.4質量部からなる配合にて、常法に従い、溶解、ロール掛け、コンチング処理し、テンパー型チョコレートを得た。
続いて、テンパリングしたチョコレートを、クッキーの重量に対して3倍量をカップに量り、ここに上記ワイヤーカットクッキーI~XIIを表面が出るように浸して複合し、チョコレート複合クッキーI~XII(英字は使用した焼菓子用油脂組成物に対応)を製造した。
On the other hand, a mixture consisting of 44.6 parts by mass of sugar, 25 parts by mass of cocoa mass, 30 parts by mass of cocoa butter and 0.4 parts by mass of lecithin was melted, rolled and conched according to a conventional method to obtain a tempered chocolate. rice field.
Subsequently, the tempered chocolate is weighed in a cup in an amount three times the weight of the cookie, and the above wire-cut cookies I to XII are dipped in the cup so that the surface is exposed and compounded. Corresponds to the oil and fat composition for baked confectionery used).
得られた焼菓子用油脂組成物を用いたクッキー生地製造時の作業性(クリーミング時の作業性・コシ)、チョコレート複合クッキーのクッキー部分の保存安定性(白色化現象の発生の有無)及びチョコレート部分の保存安定性(ブルーム現象の発生の有無)、チョコレート複合クッキーのクッキー部分の食感、並びにチョコレート複合クッキーの保存中の油脂移行について、下記評価基準に則って評価を行った。評価結果を表3に示す。 Workability during manufacturing of cookie dough using the obtained oil and fat composition for baked confectionery (workability during creaming), storage stability of the cookie portion of the chocolate composite cookie (presence or absence of whitening phenomenon), and chocolate The storage stability of the portion (presence or absence of bloom phenomenon), the texture of the cookie portion of the chocolate composite cookie, and the transfer of fats and oils during storage of the chocolate composite cookie were evaluated according to the following evaluation criteria. The evaluation results are shown in Table 3.
(クッキー生地製造時の作業性)
クッキー生地の製造時の作業性として、焼菓子用油脂組成物と上白糖とのクリーミング時の作業性及びコシを、以下の評価基準に従って4段階で評価した。
・評価基準
◎:クリーミングした際に、非常にコシが良好であり、ダレが生じない。
○:クリーミングした際に、コシが良好であり、ダレがほとんど生じない。
△:クリーミングした際に、コシが弱く、ややダレが生じる。
×:クリーミングした際に、コシが非常に弱く、ダレが生じる。
(Workability when manufacturing cookie dough)
As the workability during the production of the cookie dough, the workability and stiffness during creaming of the oil and fat composition for baked confectionery and white sugar were evaluated on a four-point scale according to the following evaluation criteria.
-Evaluation criteria ◎: When creamed, it is very firm and does not sag.
◯: When creaming, the elasticity is good and almost no sagging occurs.
Δ: When creaming, the stiffness is weak and some sagging occurs.
×: When creaming, the stiffness is very weak and sagging occurs.
(チョコレート複合クッキーの保存安定性)
得られたチョコレート複合クッキーを25℃で保存し、保存開始から14日後、28日後及び60日後の各段階において、クッキー部分の保存安定性(白色化現象の発生の有無)及びチョコレート部分の保存安定性(ブルーム現象の発生の有無)について、下記評価基準に従って4段階で評価した。
・クッキー部分の保存安定性の評価基準
◎:白色化なし
〇:表面にやや色ムラあり
△:若干白色化
×:白色化あり
・チョコレート部分の保存安定性の評価基準
◎:ブルームなし
○:やや艶がない
△:若干ブルームあり
×:ブルームあり
(Chocolate composite cookie storage stability)
The obtained chocolate composite cookie is stored at 25 ° C., and at each stage 14 days, 28 days, and 60 days after the start of storage, the storage stability of the cookie portion (presence or absence of whitening phenomenon) and the storage stability of the chocolate portion. The sex (presence or absence of bloom phenomenon) was evaluated on a 4-point scale according to the following evaluation criteria.
・ Evaluation criteria for storage stability of cookie part ◎: No whitening 〇: Slightly whitened on the surface △: Slightly whitened ×: Whitened ・ Evaluation criteria for storage stability of chocolate part ◎: No bloom ○: Slightly Matte △: Slightly blooming ×: Blooming
(チョコレート複合クッキーのクッキー部分の食感)
得られたチョコレート複合クッキーを25℃で保存し、保存開始から14日後の段階において、クッキーの食感(口中での崩壊性)について、同一の品を喫食した際に同一の評価点を付すことができるように訓練された10人のパネラーにより、下記評価基準に従って4段階で官能評価を行った。尚、評価の際には、チョコレート複合クッキーと同一の保存条件で保存された、複合化されていないクッキーを対照品として用いた。
表3においては、パネラー10名の合計点を評価点数として、評価点数が32~40点を◎、23~31点を○、14~22点を△、13点以下を×として示した。
・評価基準
4点:非常に口溶けやバラけがよく、良好なサクサクとした噛みだしを有している。
3点:口溶け・バラけが良く、やや詰まった食感を有するが、サクサクとした噛みだしを有している。
2点:口溶けやバラけがやや悪く、詰まった食感を有し、固い噛みだしを有している。若しくは、口溶け・バラけは良いが、軟らかく、サクサクとした噛みだしが乏しかった。
1点:口どけ・バラけが悪い上、噛みだしが固く、ガリガリとした食感を有している。若しくは、口溶け・バラけは良いが、軟らかく、サクサクとした噛みだしが感じられなかった。
(Texture of the cookie part of the chocolate compound cookie)
The obtained chocolate composite cookie is stored at 25 ° C., and at the stage 14 days after the start of storage, the same evaluation score is given to the texture (disintegration in the mouth) of the cookie when the same product is eaten. A sensory evaluation was performed on a 4-point scale according to the following evaluation criteria by 10 panelists trained to perform the above. In the evaluation, a non-composited cookie stored under the same storage conditions as the chocolate complex cookie was used as a control product.
In Table 3, the total score of 10 panelists is shown as an evaluation score, the evaluation score is shown as ⊚ for 32 to 40 points, ◯ for 23 to 31 points, Δ for 14 to 22 points, and × for 13 points or less.
-Evaluation criteria 4 points: Very good melting and loosening in the mouth, and has a good crispy bite.
3 points: It melts in the mouth and loosens well, and has a slightly clogged texture, but has a crispy bite.
2 points: Melting in the mouth and looseness are a little bad, it has a clogged texture, and it has a hard bite. Or, it melted in the mouth and loosened well, but it was soft and had little crispy bite.
1 point: It has a bad mouthfeel and looseness, and has a firm bite and a crunchy texture. Or, although it melted in the mouth and loosened well, it was soft and did not feel a crispy bite.
(チョコレート複合クッキーの保存中の油脂移行)
チョコレート複合クッキーの製造直後に、得られたチョコレート複合クッキーのクッキー部分について、SMART System5(CEM Japan社製)を使用して油分を測定した。チョコレート複合クッキーを25℃で保存し、保存開始から28日後と60日後において、チョコレート複合クッキーのクッキー部分について、製造直後と同様にして油分を測定した。製造直後及び保存後の油分の値から、油分移行率を次式により求めた。
〔(A-B)/A〕×100 (%)
(A:製造直後のクッキーの油分、B:保存後のクッキーの油分)
表3においては、油分移行率が30%以下を-、30%超35%以下を±、35%超45%以下を+、45%超を++として示した。油分移行率が高いほど、チョコレート複合クッキーにおけるクッキーからチョコレートへの油分の移行が多いことを示す。
(Transfer of fats and oils during storage of chocolate complex cookie)
Immediately after the production of the chocolate composite cookie, the oil content of the cookie portion of the obtained chocolate composite cookie was measured using SMART System5 (manufactured by CEM Japan). The chocolate composite cookie was stored at 25 ° C., and the oil content of the cookie portion of the chocolate composite cookie was measured 28 days and 60 days after the start of storage in the same manner as immediately after production. The oil content transfer rate was calculated from the oil content values immediately after production and after storage by the following formula.
[(AB) / A] x 100 (%)
(A: cookie oil immediately after production, B: cookie oil after storage)
In Table 3, the oil transfer rate of 30% or less is shown as −, more than 30% and 35% or less is shown as ±, more than 35% and 45% or less is shown as +, and more than 45% is shown as ++. The higher the oil transfer rate, the more the oil transfer from the cookie to the chocolate in the chocolate complex cookie.
尚、チョコレート複合クッキーの保存中の油脂移行の評価については、-又は±の評点が得られたものを合格として取り扱った。それ以外の評価については、◎又は○の評点が得られたものを合格として取り扱った。 Regarding the evaluation of fat transfer during storage of chocolate complex cookies, those with a negative or ± score were treated as acceptable. For other evaluations, those with a score of ◎ or ○ were treated as passing.
焼菓子用油脂組成物に一定量以上BO2トリグリセリドが含有されている場合に、油脂移行は抑制され、焼菓子の白色化現象や、複合させたチョコレートのブルーム現象の発生が抑制されることが分かった。一方で、比較例2の結果から、単にBO2含量を高めただけでは、食感や製造作業性が低下してしまうため、適切な範囲があることが示唆された。
尚、食感については、比較例1では硬く詰まった食感となり、口溶け・バラけが不良であった。逆に、比較例2では口溶け・バラけは良好であるが、噛みだしが軟らかくサクサクとした食感が得られなかった。
また、製造作業性については、本発明の焼菓子用油脂組成物の油相の構成脂肪酸中に、ラウリン酸残基を一定量以上含有することで製造作業性が向上することが、特に実施例5と比較例1を対比することにより示唆される。
また、SFA-MGとUSFA-MGを特定比率で含有させることで、クリーミング時の比重の減少が早まり、より一層、製造作業性が高まることが確認された。
It was found that when the oil / fat composition for baked confectionery contains a certain amount or more of BO2 triglyceride, the transfer of oil / fat is suppressed, and the whitening phenomenon of the baked confectionery and the bloom phenomenon of the complexed chocolate are suppressed. rice field. On the other hand, from the results of Comparative Example 2, it was suggested that there is an appropriate range because the texture and manufacturing workability are deteriorated simply by increasing the BO2 content.
As for the texture, in Comparative Example 1, the texture was hard and clogged, and the texture was poorly melted in the mouth and loosened. On the contrary, in Comparative Example 2, although the mouth melted and loosened well, the chewing was soft and the texture was not crispy.
Further, regarding the manufacturing workability, it is particularly exemplified that the manufacturing workability is improved by containing a certain amount or more of a lauric acid residue in the constituent fatty acids of the oil phase of the oil and fat composition for baked confectionery of the present invention. It is suggested by comparing 5 with Comparative Example 1.
Further, it was confirmed that by containing SFA-MG and USFA-MG in a specific ratio, the reduction of the specific gravity at the time of creaming is accelerated, and the manufacturing workability is further improved.
Claims (5)
(1)SFCが10℃で25~45%、20℃で10~30%、30℃で0~15%
(2)油相を構成するトリグリセリド組成中、BO2の含量が2~12質量%
(3)油相を構成する脂肪酸組成中、ラウリン酸残基が1~10質量% A confectionery oil / fat composition satisfying the following conditions (1) , (2) and (3) , wherein the content of B2O in the triglyceride composition constituting the oil phase is less than 2% by mass. (B is a behenic acid residue, O is an oleic acid residue).
(1) SFC is 25 to 45% at 10 ° C, 10 to 30% at 20 ° C, and 0 to 15% at 30 ° C.
(2) The content of BO2 in the triglyceride composition constituting the oil phase is 2 to 12 % by mass.
(3) Lauric acid residue is 1 to 10% by mass in the fatty acid composition constituting the oil phase.
(4)油相を構成するトリグリセリド組成中、LLLの含量が5質量%以下(Lはラウリン酸残基) The oil / fat composition for baked confectionery according to claim 1, further satisfying the following condition (4).
(4) The content of LLL in the triglyceride composition constituting the oil phase is 5% by mass or less (L is a lauric acid residue).
(5)炭素数16以上の飽和脂肪酸残基を有するモノグリセリドと、炭素数16以上の不飽和脂肪酸残基を有するモノグリセリドとを、前者:後者で1:2~8の質量比で含有する The oil / fat composition for baked confectionery according to claim 1 or 2, further satisfying the following condition (5).
(5) A monoglyceride having a saturated fatty acid residue having 16 or more carbon atoms and a monoglyceride having an unsaturated fatty acid residue having 16 or more carbon atoms are contained in a mass ratio of 1: 2 to 8 in the former: the latter.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2017218219A JP7048267B2 (en) | 2017-11-13 | 2017-11-13 | Oil composition for baked confectionery |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2017218219A JP7048267B2 (en) | 2017-11-13 | 2017-11-13 | Oil composition for baked confectionery |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2019088208A JP2019088208A (en) | 2019-06-13 |
JP7048267B2 true JP7048267B2 (en) | 2022-04-05 |
Family
ID=66835115
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2017218219A Active JP7048267B2 (en) | 2017-11-13 | 2017-11-13 | Oil composition for baked confectionery |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP7048267B2 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP7372137B2 (en) * | 2019-12-25 | 2023-10-31 | 太陽油脂株式会社 | Oil and fat composition for baked confectionery |
KR20230058394A (en) * | 2020-09-02 | 2023-05-03 | 가부시키가이샤 아데카 | No Tempered Hard Butter Composition |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007143433A (en) | 2005-11-25 | 2007-06-14 | Adeka Corp | Oil and fat composition for being mixed with oil and fat raw material-blended baked confectionery |
JP2010004806A (en) | 2008-06-27 | 2010-01-14 | Kaneka Corp | Oil-and-fat composition for baked confectionery |
JP2010213637A (en) | 2009-03-18 | 2010-09-30 | Nisshin Oillio Group Ltd | Emulsified oil and fat composition containing soymilk having sprouted soybean as raw material |
JP2015202099A (en) | 2014-04-16 | 2015-11-16 | 株式会社Adeka | composite confectionery fat composition |
JP2015228810A (en) | 2014-06-04 | 2015-12-21 | 不二製油グループ本社株式会社 | Water-in-oil emulsion |
JP2017093310A (en) | 2015-11-18 | 2017-06-01 | 不二製油株式会社 | Oil composition for kneading baked confectionery |
JP2017169468A (en) | 2016-03-22 | 2017-09-28 | 不二製油株式会社 | Oil composition for foamable oil-in-water type emulsion, and foamable oil-in-water type emulsion |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63126457A (en) * | 1986-11-17 | 1988-05-30 | Kao Corp | Migration inhibitor for fats and oils for baked confectionery and method for producing composite baked confectionery using the same |
GB2297760A (en) * | 1995-02-09 | 1996-08-14 | Loders Croklaan Bv | Behenic acid containing fats |
-
2017
- 2017-11-13 JP JP2017218219A patent/JP7048267B2/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007143433A (en) | 2005-11-25 | 2007-06-14 | Adeka Corp | Oil and fat composition for being mixed with oil and fat raw material-blended baked confectionery |
JP2010004806A (en) | 2008-06-27 | 2010-01-14 | Kaneka Corp | Oil-and-fat composition for baked confectionery |
JP2010213637A (en) | 2009-03-18 | 2010-09-30 | Nisshin Oillio Group Ltd | Emulsified oil and fat composition containing soymilk having sprouted soybean as raw material |
JP2015202099A (en) | 2014-04-16 | 2015-11-16 | 株式会社Adeka | composite confectionery fat composition |
JP2015228810A (en) | 2014-06-04 | 2015-12-21 | 不二製油グループ本社株式会社 | Water-in-oil emulsion |
JP2017093310A (en) | 2015-11-18 | 2017-06-01 | 不二製油株式会社 | Oil composition for kneading baked confectionery |
JP2017169468A (en) | 2016-03-22 | 2017-09-28 | 不二製油株式会社 | Oil composition for foamable oil-in-water type emulsion, and foamable oil-in-water type emulsion |
Also Published As
Publication number | Publication date |
---|---|
JP2019088208A (en) | 2019-06-13 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4606406B2 (en) | Oil composition for confectionery | |
KR20150138224A (en) | Oil/fat composition and baked goods using oil/fat composition | |
JP6505979B2 (en) | Compound confectionery oil composition | |
JP2005350660A (en) | Plastic oil composition | |
JP5917262B2 (en) | Oil composition | |
KR20220152236A (en) | Water-in-oil emulsion composition for dough | |
JP6113942B1 (en) | Oily food | |
JP4493585B2 (en) | Oil and fat composition for kneading baked confectionery with oily ingredients | |
JP2016189773A (en) | Oil and fat composition for filling and/or topping, water-in-oil type emulsified oil and fat composition for filling and/or topping and food containing the water-in-oil type emulsified oil and fat composition | |
JP6827282B2 (en) | Thermoplastic fat composition | |
JP7048267B2 (en) | Oil composition for baked confectionery | |
JP4841136B2 (en) | Plastic oil composition | |
JP6767160B2 (en) | Oil and fat composition for complex confectionery | |
JP2009240220A (en) | Plastic fat composition | |
JP7203555B2 (en) | fat composition | |
JP5191083B2 (en) | Plastic oil composition with long-term bloom suppressed | |
JP2005320445A (en) | Palm stearin-containing plastic oil composition | |
JP7226925B2 (en) | Oil and fat composition with oil and fat as a continuous phase | |
JP6189016B2 (en) | Plastic oil / fat composition containing improved creaming / fat | |
JP5496300B2 (en) | Method for suppressing long-term bloom of oil and fat composition | |
JP6679207B2 (en) | Plastic fat composition | |
JP7376226B2 (en) | Oil and fat composition for baked confectionery | |
JP6947516B2 (en) | Oil and fat composition for confectionery | |
JP2017216894A (en) | Oil and fat composition for kneading into baked sweets | |
JP4376171B2 (en) | Oil composition |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20200902 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20210623 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20210629 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20210816 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20211011 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20220308 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20220324 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 7048267 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |