JP6990341B2 - Foamable oil-in-water emulsified oil / fat composition - Google Patents
Foamable oil-in-water emulsified oil / fat composition Download PDFInfo
- Publication number
- JP6990341B2 JP6990341B2 JP2021512103A JP2021512103A JP6990341B2 JP 6990341 B2 JP6990341 B2 JP 6990341B2 JP 2021512103 A JP2021512103 A JP 2021512103A JP 2021512103 A JP2021512103 A JP 2021512103A JP 6990341 B2 JP6990341 B2 JP 6990341B2
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- Japan
- Prior art keywords
- oil
- weight
- fatty acid
- fat
- whipped cream
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 235000019813 microcrystalline cellulose Nutrition 0.000 description 1
- 239000008108 microcrystalline cellulose Substances 0.000 description 1
- 229940016286 microcrystalline cellulose Drugs 0.000 description 1
- 235000021239 milk protein Nutrition 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000010461 other edible oil Substances 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 229960000292 pectin Drugs 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- SHUZOJHMOBOZST-UHFFFAOYSA-N phylloquinone Natural products CC(C)CCCCC(C)CCC(C)CCCC(=CCC1=C(C)C(=O)c2ccccc2C1=O)C SHUZOJHMOBOZST-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 235000015277 pork Nutrition 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- 229960002635 potassium citrate Drugs 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- 235000011082 potassium citrates Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 229940086066 potassium hydrogencarbonate Drugs 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229940092258 rosemary extract Drugs 0.000 description 1
- 235000020748 rosemary extract Nutrition 0.000 description 1
- 239000001233 rosmarinus officinalis l. extract Substances 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000011083 sodium citrates Nutrition 0.000 description 1
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229940083466 soybean lecithin Drugs 0.000 description 1
- 239000008347 soybean phospholipid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000019156 vitamin B Nutrition 0.000 description 1
- 239000011720 vitamin B Chemical group 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 235000019166 vitamin D Nutrition 0.000 description 1
- 239000011710 vitamin D Substances 0.000 description 1
- 150000003710 vitamin D derivatives Chemical class 0.000 description 1
- 235000019168 vitamin K Nutrition 0.000 description 1
- 239000011712 vitamin K Substances 0.000 description 1
- 150000003721 vitamin K derivatives Chemical class 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 229940046008 vitamin d Drugs 0.000 description 1
- 229940046010 vitamin k Drugs 0.000 description 1
- 235000008939 whole milk Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
- A21D13/00—Finished or partly finished bakery products
- A21D13/20—Partially or completely coated products
- A21D13/24—Partially or completely coated products coated after baking
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
- A21D13/00—Finished or partly finished bakery products
- A21D13/20—Partially or completely coated products
- A21D13/28—Partially or completely coated products characterised by the coating composition
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
- A21D13/00—Finished or partly finished bakery products
- A21D13/80—Pastry not otherwise provided for elsewhere, e.g. cakes, biscuits or cookies
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
- A21D2/00—Treatment of flour or dough by adding materials thereto before or during baking
- A21D2/08—Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
- A21D2/14—Organic oxygen compounds
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
- A21D2/00—Treatment of flour or dough by adding materials thereto before or during baking
- A21D2/08—Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
- A21D2/14—Organic oxygen compounds
- A21D2/16—Fatty acid esters
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D7/00—Edible oil or fat compositions containing an aqueous phase, e.g. margarines
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L9/00—Puddings; Cream substitutes; Preparation or treatment thereof
- A23L9/20—Cream substitutes
Landscapes
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Nutrition Science (AREA)
- Grain Derivatives (AREA)
- Freezing, Cooling And Drying Of Foods (AREA)
- Edible Oils And Fats (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
- Dairy Products (AREA)
- Confectionery (AREA)
Description
本発明は、食用の起泡性水中油型乳化油脂組成物、並びに、該組成物がホイップされたホイップドクリーム及びそれを含む食品に関する。 The present invention relates to an edible foamable oil-in-water emulsified oil / fat composition, and a whipped cream to which the composition is whipped and a food containing the same.
ホイップドクリームは、起泡性水中油型乳化物を起泡させて製造される。該ホイップドクリームには、良好な風味や、シャープな口溶け、良好なコクが求められるが、近年では、これらに加えて、高い冷凍保存耐性も求められるようになっている。すなわち、ホイップドクリームを冷凍保存した後に解凍し食しても、良好な風味、シャープな口溶け、良好なコクが感じられ、みずみずしい食感を保持していることが求められている。 Whipped cream is produced by foaming a foamable oil-in-water emulsion. The whipped cream is required to have good flavor, sharp melting in the mouth, and good richness, but in recent years, in addition to these, high freezing storage resistance is also required. That is, even if the whipped cream is frozen and stored and then thawed and eaten, it is required to have a good flavor, a sharp melting in the mouth, a good richness, and a fresh texture.
ホイップドクリームに使用可能な原料油脂としてはラウリン系油脂やパーム系油脂等がある。ラウリン系油脂を多く配合すると、シャープな口溶けと良好なコクが得られ冷凍保存耐性が高くなる一方、飽和脂肪酸含有量が多くなり、健康面でのリスクが生じ、また、コストが上昇するという問題がある。片や、パーム系油脂を多く配合すると、コスト面ではメリットがあるものの、従来は冷凍保存耐性が低下し、冷凍及び解凍を経るとホイップドクリームの表面にひび割れや亀裂が生じやすくなり、また、風味や食感等が劣化してしまうという問題があった。 Raw material fats and oils that can be used for whipped cream include lauric-based fats and oils and palm-based fats and oils. When a large amount of lauric oil is added, sharp melting in the mouth and good richness are obtained, and the resistance to freezing storage is increased. On the other hand, the content of saturated fatty acids is increased, which poses a health risk and increases the cost. There is. Although there is a cost advantage when a large amount of whipped cream is added, the resistance to freezing and storage is reduced in the past, and after freezing and thawing, the surface of the whipped cream is liable to crack or crack. There was a problem that the flavor and texture deteriorated.
特許文献1では、冷凍保存と解凍を経た後の、ホイップドクリームの型崩れ、ひび割れ、又は組織の荒れ、及び風味の劣化を防止することを目的として、卵黄リゾレシチン及び/又は卵黄レシチンと、特定の飽和脂肪酸を有するポリグリセリン飽和脂肪酸エステルとを含む起泡性水中油型乳化油脂組成物が開示されている。 In Patent Document 1, egg yolk lysolecithin and / or egg yolk lecithin are specified for the purpose of preventing the whipped cream from losing its shape, cracking, or tissue roughness and deterioration of flavor after being frozen and thawed. A foamable oil-in-water emulsified oil / fat composition containing a polyglycerin saturated fatty acid ester having a saturated fatty acid of the above is disclosed.
しかし、特許文献1の全ての実施例では、構成脂肪酸の70重量%以上がパルミチン酸又はステアリン酸であるポリグリセリン脂肪酸エステルが使用されており、かつ、エステル交換油脂が使用されている。これらの実施例では、コストが高く、また、冷解凍後のホイップドクリームは口溶けが悪かったり、コクが不足する問題がある。さらに、該文献のほとんどの実施例に配合されている硬化油脂はトランス脂肪酸を多く含有するものであり、健康上好ましくない。 However, in all the examples of Patent Document 1, a polyglycerin fatty acid ester in which 70% by weight or more of the constituent fatty acids are palmitic acid or stearic acid is used, and transesterified fats and oils are used. In these examples, there are problems that the cost is high, and the whipped cream after cold thawing has poor melting in the mouth and lacks richness. Further, the cured fats and oils contained in most of the examples of the document contain a large amount of trans fatty acids, which is not preferable for health.
本発明の目的は、上記現状に鑑み、エステル交換油脂及びトランス脂肪酸を実質的に含有せず、飽和脂肪酸の含有量が少ないにも関わらず、ホイップドクリームを冷凍及び解凍後にもひび割れや亀裂が生じにくく、風味及び口溶けが良好で、コクがあり、みずみずしい食感が感じられるホイップドクリームを作製できる起泡性水中油型乳化油脂組成物を提供することである。 An object of the present invention is that, in view of the above situation, cracks and cracks occur even after the whipped cream is frozen and thawed, although it does not substantially contain ester-exchanged fats and oils and trans fatty acids and has a low content of saturated fatty acids. It is an object of the present invention to provide a foamable oil-in-water emulsified oil / fat composition capable of producing a whipped cream which is less likely to occur, has a good flavor and melts in the mouth, has a rich texture, and has a fresh texture.
本発明者らは上記課題を解決するために鋭意研究を重ねた結果、エステル交換油脂及びトランス脂肪酸を実質的に含有せず、飽和脂肪酸の含有量を抑制しても、油脂としてラウリン系油脂とS2Uを45~70重量%含むパーム系油脂をそれぞれ特定量使用し、さらに、特定の構成脂肪酸が結合したポリグリセリン脂肪酸エステルを特定量と、特定量の不飽和脂肪酸を構成脂肪酸とする乳化剤を特定量配合した起泡性水中油型乳化油脂組成物によると、これをホイップしたホイップドクリームを冷凍及び解凍した後にもひび割れや亀裂が生じにくく、風味及び口溶けが良好で、コクがあり、みずみずしい食感が感じられることを見出し、本発明を完成するに至った。
即ち、本発明の第一は、起泡性水中油型乳化油脂組成物全体中、油脂の含有量が25~50重量%で、水分量が45~70重量%であり、前記油脂全体中、ラウリン系油脂を3~50重量%と、S2Uを45~70重量%含むパーム系油脂を40~90重量%とを含有し、エステル交換油脂の含有量が1重量%未満であり、前記油脂の構成脂肪酸全体中、トランス脂肪酸の含有量は1重量%未満で、飽和脂肪酸の含有量は47~65重量%であり、ポリグリセリン脂肪酸エステルAの構成脂肪酸全体中、飽和脂肪酸の含有量は95~100重量%で、炭素数16及び炭素数18の飽和脂肪酸を6~25重量%と、炭素数20以上の飽和脂肪酸を55~85重量%とを含むポリグリセリン脂肪酸エステルAを、油相全体中0.1~1重量%含有し、不飽和脂肪酸の含有量が乳化剤の構成脂肪酸全体中60~100重量%の乳化剤を、起泡性水中油型乳化油脂組成物全体中0.05~0.5重量%含有する、起泡性水中油型乳化油脂組成物に関する。As a result of diligent research to solve the above problems, the present inventors have substantially not contained ester-exchanged fats and oils and trans fatty acids, and even if the content of saturated fatty acids is suppressed, laurin-based fats and oils are used as fats and oils. A specific amount of palm-based fat and oil containing 45 to 70% by weight of S2U is used, and a specific amount of polyglycerin fatty acid ester to which a specific constituent fatty acid is bound and an emulsifier containing a specific amount of unsaturated fatty acid as a constituent fatty acid are specified. According to the foaming oil-type emulsified fatty acid composition in a large amount, cracks and cracks are less likely to occur even after freezing and thawing the whipped cream that has been whipped, and the flavor and melting in the mouth are good, and the food is rich and fresh. We found that we could feel the feeling and completed the present invention.
That is, the first aspect of the present invention is that the content of fats and oils is 25 to 50% by weight and the water content is 45 to 70% by weight in the whole foamable oil-in-water emulsified fat and oil composition. It contains 3 to 50% by weight of laurin-based fat and oil and 40 to 90% by weight of palm-based fat and oil containing 45 to 70% by weight of S2U, and the content of ester-exchanged fat and oil is less than 1% by weight. The content of trans fatty acid is less than 1% by weight, the content of saturated fatty acid is 47 to 65% by weight, and the content of saturated fatty acid in the total constituent fatty acid of polyglycerin fatty acid ester A is 95 to 65% by weight. Polyglycerin fatty acid ester A containing 6 to 25% by weight of saturated fatty acids having 16 and 18 carbon atoms and 55 to 85% by weight of saturated fatty acids having 20 or more carbon atoms at 100% by weight is contained in the entire oil phase. An emulsifier containing 0.1 to 1% by weight and having an unsaturated fatty acid content of 60 to 100% by weight in the total constituent fatty acids of the emulsifier was added to the foamable oil-in-water emulsified oil / fat composition from 0.05 to 0. The present invention relates to a foamable oil-in-water emulsified oil / fat composition containing 5% by weight.
前記起泡性水中油型乳化油脂組成物は、さらに、炭素数が20以上の飽和脂肪酸の含有量がポリグリセリン脂肪酸エステルBの構成脂肪酸全体中90~100重量%であるポリグリセリン脂肪酸エステルBを、油相全体中0.05~1重量%含有することが好ましい。また、前記起泡性水中油型乳化油脂組成物は、さらに、乳脂肪を、前記油脂全体中5~50重量%含有することが好ましい。好ましくは、前記乳脂肪が、生クリーム由来の乳脂肪である。 The foamable oil-in-water emulsified oil / fat composition further comprises polyglycerin fatty acid ester B in which the content of saturated fatty acid having 20 or more carbon atoms is 90 to 100% by weight based on the total fatty acids constituting the polyglycerin fatty acid ester B. , It is preferable that the content is 0.05 to 1% by weight in the whole oil phase. Further, the foamable oil-in-water emulsified oil / fat composition preferably further contains milk fat in an amount of 5 to 50% by weight based on the total amount of the oil / fat. Preferably, the milk fat is a milk fat derived from fresh cream.
本発明の第二は、前記起泡性水中油型乳化油脂組成物がホイップされたホイップドクリームに関し、また、前記ホイップドクリームがナッペ、トッピング、又はサンドされた食品に関する。前記食品は、-40℃~-10℃で冷凍されたものであってよい。 The second aspect of the present invention relates to a whipped cream in which the foamable oil-in-water emulsified oil / fat composition is whipped, and also relates to a food in which the whipped cream is napped, topping, or sanded. The food may be frozen at −40 ° C. to −10 ° C.
本発明に従えば、エステル交換油脂及びトランス脂肪酸を実質的に含有せず、飽和脂肪酸の含有量が少ないにも関わらず、ホイップドクリームを冷凍及び解凍した後にもひび割れや亀裂が生じにくく、風味及び口溶けが良好で、コクがあり、みずみずしい食感が感じられるホイップドクリームを作製できる起泡性水中油型乳化油脂組成物を提供することができる。 According to the present invention, the whipped cream is less likely to be cracked or cracked even after freezing and thawing, despite the fact that it contains substantially no transesterified oil and trans fatty acid and has a low content of saturated fatty acid, and has a flavor. Further, it is possible to provide a foaming oil-in-water emulsified oil / fat composition capable of producing a whipped cream having good melting in the mouth, richness and a fresh texture.
以下、本発明につき、さらに詳細に説明する。
本発明の起泡性水中油型乳化油脂組成物は、油脂と必要に応じて油脂以外の油溶性原料とを含む油相、及び、水と必要に応じて水溶性原料とを含む水相からなる、水中油型の乳化物である。当該起泡性水中油型乳化油脂組成物は、起泡性を示すものであり、これをホイップし、起泡させることにより、本発明のホイップドクリームを得ることができる。なお、油脂とは、1分子のグリセリンに対し3分子の脂肪酸がエステル結合してなるトリグリセリドのことをいう。トリグリセリドを構成している前記脂肪酸を、構成脂肪酸という。Hereinafter, the present invention will be described in more detail.
The foamable oil-in-water emulsified oil / fat composition of the present invention comprises an oil phase containing an oil and fat and, if necessary, an oil-soluble raw material other than the oil and fat, and an aqueous phase containing water and, if necessary, a water-soluble raw material. It is an oil-in-water emulsion. The foamable oil-in-water emulsified oil / fat composition exhibits foaming property, and the whipped cream of the present invention can be obtained by whipping and foaming the composition. The fat and oil refers to a triglyceride in which three molecules of fatty acid are ester-bonded to one molecule of glycerin. The fatty acid constituting the triglyceride is referred to as a constituent fatty acid.
本発明の起泡性水中油型乳化油脂組成物は、特定量の油脂と水を含有し、油脂として特定量のラウリン系油脂と、S2Uを特定量含むパーム系油脂を特定量使用し、さらに特定の構成脂肪酸が結合したポリグリセリン脂肪酸エステルAを油相中に特定量と、構成脂肪酸中の不飽和脂肪酸の含有量が特定量の乳化剤を特定量配合することを特徴とする。 The foamable oil-in-water emulsified oil / fat composition of the present invention contains a specific amount of oil and water, uses a specific amount of laurin-based oil and fat as oil and fat, and a specific amount of palm-based oil and fat containing S2U, and further. It is characterized by blending a specific amount of polyglycerin fatty acid ester A to which a specific constituent fatty acid is bound in an oil phase and a specific amount of an emulsifier having a specific amount of unsaturated fatty acid in the constituent fatty acid.
本発明の起泡性水中油型乳化油脂組成物は、油脂を、前記組成物全体中、合計で25~50重量%含有することが好ましく、25~45重量%がより好ましく、25~40重量%がさらに好ましい。油脂の含有量が25重量%より少ないと、ホイップドクリームにおいて油のコクを感じ難くなる場合がある。また、50重量%より多いと、起泡性水中油型乳化油脂組成物の乳化安定性が悪くなる場合がある。 The foamable oil-in-water emulsified oil / fat composition of the present invention preferably contains oil / fat in a total of 25 to 50% by weight, more preferably 25 to 45% by weight, and 25 to 40% by weight. % Is more preferable. If the content of oil and fat is less than 25% by weight, it may be difficult to feel the richness of oil in whipped cream. On the other hand, if it is more than 50% by weight, the emulsification stability of the foamable oil-in-water emulsified oil / fat composition may deteriorate.
また、本発明の起泡性水中油型乳化油脂組成物は、当該組成物全体に対する水分量が45~70重量%であることが好ましく、50~70重量%がより好ましく、55~70重量%がさらに好ましい。水分量が45重量%より少ないと、乳化安定性が悪くなる場合があり、70重量%より多いと、ホイップドクリームにおいて油のコクを感じ難くなる場合がある。 Further, the foamable oil-in-water emulsified oil / fat composition of the present invention preferably has a water content of 45 to 70% by weight, more preferably 50 to 70% by weight, and 55 to 70% by weight based on the entire composition. Is even more preferable. If the water content is less than 45% by weight, the emulsion stability may be deteriorated, and if it is more than 70% by weight, it may be difficult to feel the richness of oil in the whipped cream.
本発明の起泡性水中油型乳化油脂組成物に含まれる油脂は、少なくとも、ラウリン系油脂と、パーム系油脂を含有する。 The fat and oil contained in the foamable oil-in-water emulsified fat and oil composition of the present invention contains at least a lauric-based fat and oil and a palm-based fat and oil.
ラウリン系油脂とは、構成脂肪酸としてラウリン酸を多く含む油脂をいい、具体的には構成脂肪酸中のラウリン酸含有量が概ね35重量%以上の油脂であればよく、例えば、パーム核油、ヤシ油、及びこれらの分別油や極度硬化油等が挙げられる。本発明の起泡性水中油型乳化油脂組成物は、ラウリン系油脂を、前記組成物に含まれる油脂全体中3~50重量%含有することが好ましく、3~45重量%がより好ましく、5~40重量%が更に好ましく、5~30重量%が特に好ましい。ラウリン系油脂の含有量が3重量%より少ないと、ホイップドクリームを作製するのに要するホイップ時間が長くなり、適切な状態のホイップドクリームが得られない場合がある。また、50重量%より多いと、コストが高くなり過ぎるし、ホイップドクリームの表面がボソつく場合がある。 The lauric-based oil or fat refers to an oil or fat containing a large amount of lauric acid as a constituent fatty acid, and specifically, an oil or fat having a lauric acid content of approximately 35% by weight or more in the constituent fatty acid may be used, for example, palm kernel oil or coconut oil. Examples thereof include oils, fractionated oils thereof, and extremely hydrogenated oils. The foamable oil-in-water emulsified oil / fat composition of the present invention preferably contains laurin-based oil / fat in an amount of 3 to 50% by weight, more preferably 3 to 45% by weight, based on the total amount of the oil / fat contained in the composition. From 40% by weight is more preferable, and 5 to 30% by weight is particularly preferable. If the content of the lauric oil / fat is less than 3% by weight, the whipping time required to prepare the whipped cream becomes long, and the whipped cream in an appropriate state may not be obtained. On the other hand, if it is more than 50% by weight, the cost becomes too high and the surface of the whipped cream may be rough.
パーム系油脂は、パーム油由来の油脂のことであり、起泡性やホイップドクリームの口溶けの観点から、S2Uを、パーム系油脂全体中45~70重量%含むものであることが好ましい。より好ましくは50~60重量%である。ここで、S2Uとは、構成脂肪酸として、1分子のグリセリンに、炭素数12以上(好ましくは炭素数24以下)の飽和脂肪酸Sが2分子、炭素数16以上(好ましくは炭素数24以下)の不飽和脂肪酸Uが1分子結合しているトリグリセリドのことをいい、S及びUの結合位置は限定されない。S2Uを構成脂肪酸全体中45~70重量%含むパーム系油脂としては、例えば、パーム中融点部分別油、パームオレイン、パーム油などが挙げられる。これらのパーム系油脂を単独で使用してもよいし、パーム系油脂全体としてS2U含有量が45~70重量%の範囲に収まるように2種類以上のパーム系油脂を混合して使用してもよい。2種類以上のパーム系油脂を混合する場合、各々のパーム系油脂のS2U含有量は45~70重量%の範囲になくてもよい。 The palm oil is a fat derived from palm oil, and it is preferable that S2U is contained in 45 to 70% by weight of the whole palm oil from the viewpoint of foaming property and melting of whipped cream in the mouth. More preferably, it is 50 to 60% by weight. Here, S2U is a constituent fatty acid having two molecules of saturated fatty acid S having 12 or more carbon atoms (preferably 24 or less carbon atoms) and 16 or more carbon atoms (preferably 24 or less carbon atoms) in one molecule of glycerin. It refers to a triglyceride to which one molecule of unsaturated fatty acid U is bound, and the binding positions of S and U are not limited. Examples of palm-based oils and fats containing 45 to 70% by weight of S2U in the total constituent fatty acids include oils by melting point in palm, palm olein, palm oil and the like. These palm-based fats and oils may be used alone, or two or more types of palm-based fats and oils may be mixed and used so that the S2U content of the palm-based fats and oils as a whole falls within the range of 45 to 70% by weight. good. When two or more types of palm-based fats and oils are mixed, the S2U content of each palm-based fat and oil does not have to be in the range of 45 to 70% by weight.
本発明の起泡性水中油型乳化油脂組成物は、前記S2Uを45~70重量%含むパーム系油脂を、前記組成物に含まれる油脂全体中40~90重量%含有することが好ましく、より好ましくは45~90重量%、更に好ましくは55~90重量%、特に好ましくは55~80重量%である。前記パーム系油脂の含有量が40重量%より少ないと、ホイップドクリームの表面がボソつく場合がある。また、90重量%より多いと、ホイップドクリームを作製するのに要するホイップ時間が長くなり、適切な状態のホイップドクリームが得られない場合がある。 The foamable oil-in-water emulsified oil / fat composition of the present invention preferably contains the palm-based oil / fat containing 45 to 70% by weight of S2U in an amount of 40 to 90% by weight based on the total amount of the oil / fat contained in the composition. It is preferably 45 to 90% by weight, more preferably 55 to 90% by weight, and particularly preferably 55 to 80% by weight. If the content of the palm-based fat is less than 40% by weight, the surface of the whipped cream may be rough. On the other hand, if it is more than 90% by weight, the whipping time required for producing the whipped cream becomes long, and the whipped cream in an appropriate state may not be obtained.
油脂は、ラウリン系油脂と、パーム系油脂に加えて、ハイエルシン菜種極度硬化油を含むことが好ましい。ハイエルシン菜種極度硬化油とは、菜種の中でもエルシン酸(エルカ酸)含量が概ね40%以上の品種から搾油した油脂を極度硬化したものをいう。ハイエルシン菜種極度硬化油を配合することによって、ホイップドクリームの冷凍及び解凍後にひび割れや亀裂が生じるのを、より良く抑制することができる。 The fats and oils preferably contain lauric-based fats and oils and palm-based fats and oils, as well as high-elcin rapeseed extremely hydrogenated oils. High-erucine rapeseed extremely hydrogenated oil refers to oil and fat squeezed from varieties having an erucic acid (erucic acid) content of approximately 40% or more among rapeseed. By blending Hyelsin rapeseed extremely hydrogenated oil, cracks and cracks can be better suppressed after freezing and thawing of the whipped cream.
ハイエルシン菜種極度硬化油を用いる場合、その含有量は、本発明の起泡性水中油型乳化油脂組成物に含まれる油脂全体中0.5~1.5重量%であることが好ましく、1.0~1.5重量%がより好ましい。ハイエルシン菜種極度硬化油の含有量が0.5重量%より少ないと、これを配合することによる効果を十分に得ることができず、1.5重量%より多いと、起泡性水中油型乳化油脂組成物の乳化安定性が悪化する場合がある。 When the hyelcin rapeseed extremely hydrogenated oil is used, the content thereof is preferably 0.5 to 1.5% by weight based on the total amount of the oil and fat contained in the foamable oil-in-water emulsified oil and fat composition of the present invention. 0 to 1.5% by weight is more preferable. If the content of the extremely hydrogenated oil of high erucine rapeseed is less than 0.5% by weight, the effect of blending it cannot be sufficiently obtained, and if it is more than 1.5% by weight, the foamable oil-in-water emulsification is performed. The emulsification stability of the oil and fat composition may deteriorate.
ホイップドクリームのコクの観点から、エステル交換油脂の含有量は少ないほど好ましい。ここで、エステル交換油脂とは、食用油脂をエステル交換反応して得られる油脂を指す。前記食用油脂としては菜種油、コーン油、綿実油、パーム油、パーム核油、ヤシ油、大豆油、ひまわり油、サフラワー油、オリーブ油等の植物性油脂や、乳脂肪、牛脂、豚脂、魚油等の動物性油脂が例示でき、これらを硬化、分別、エステル交換等の加工処理を行ったものも用いることができる。前記エステル交換油脂の製法については特に限定なく、常法を用いて製造することができる。例えば、ナトリウムメチラートまたはナトリウムエチラートを原料油脂に対して0.01~1.0重量%添加してランダムエステル交換反応を起こす化学法や、リパーゼなどの酵素を用いてエステル交換を行なう酵素法などを適用できる。 From the viewpoint of the richness of the whipped cream, the smaller the content of the transesterified fat and oil, the more preferable. Here, the transesterified fat and oil refers to a fat and oil obtained by transesterifying an edible fat and oil. Examples of the edible oils and fats include vegetable oils and fats such as rapeseed oil, corn oil, cottonseed oil, palm oil, palm kernel oil, palm oil, soybean oil, sunflower oil, safflower oil and olive oil, milk fat, beef fat, pork fat, fish oil and the like. Examples of animal oils and fats from the above can be used, and those which have been processed by curing, sorting, ester exchange, etc. can also be used. The method for producing the transesterified fat and oil is not particularly limited, and the transesterified oil and fat can be produced by a conventional method. For example, a chemical method in which 0.01 to 1.0% by weight of sodium methylate or sodium ethylate is added to a raw material fat and oil to cause a random transesterification reaction, or an enzymatic method in which an enzyme such as lipase is used to perform transesterification. Etc. can be applied.
具体的には、エステル交換油脂は、本発明の起泡性水中油型乳化油脂組成物に含まれる油脂全体中1重量%未満の範囲で含まれるか、又は全く含まれないことが好ましく、全く含まれないことがより好ましい。エステル交換油脂の含有量が1重量%以上であると、コストがアップしたり、起泡性が低下したり、ホイップドクリームのコクが不足する場合がある。 Specifically, the transesterified oil / fat is preferably contained in the range of less than 1% by weight or not contained in the total amount of the oil / fat contained in the foamable oil-in-water emulsified oil / fat composition of the present invention, and is not contained at all. It is more preferable that it is not contained. If the content of the transesterified fat is 1% by weight or more, the cost may increase, the foaming property may decrease, or the richness of the whipped cream may be insufficient.
健康上の観点から、本発明の起泡性水中油型乳化油脂組成物に含まれる油脂の構成脂肪酸として、トランス脂肪酸を多量に含有しないことが好ましい。ここで、トランス脂肪酸とは、トランス型の二重結合を持つ不飽和脂肪酸のことをいう。具体的には、トランス脂肪酸は、前記油脂の構成脂肪酸全体中1重量%未満の範囲を占めるように構成脂肪酸として含まれるか、又は含まれないことが好ましく、全く含まれないことがより好ましい。なお、トランス脂肪酸の含有量を少なくするには、本発明の起泡性水中油型乳化油脂組成物に配合する部分硬化油の量を低減すればよい。 From the viewpoint of health, it is preferable that the constituent fatty acids of the fats and oils contained in the foamable oil-in-water emulsified fat and oil composition of the present invention do not contain a large amount of trans fatty acids. Here, the trans fatty acid refers to an unsaturated fatty acid having a trans-type double bond. Specifically, the trans fatty acid is preferably contained or not contained as a constituent fatty acid so as to occupy a range of less than 1% by weight in the total constituent fatty acids of the fat and oil, and more preferably not contained at all. In order to reduce the content of trans fatty acid, the amount of partially hydrogenated oil to be blended in the foamable oil-in-water emulsified oil / fat composition of the present invention may be reduced.
同じく健康上の観点から、前記油脂の構成脂肪酸として、飽和脂肪酸の含有量はできるだけ減らすことが好ましい。具体的には、飽和脂肪酸は、前記油脂の構成脂肪酸全体中47~65重量%であることが好ましく、50~60重量%がより好ましい。飽和脂肪酸の含有量が47重量%より少ないと、起泡性水中油型乳化油脂組成物の起泡性が悪化する場合があり、65重量%より多いと健康上好ましくない場合がある。 Similarly, from the viewpoint of health, it is preferable to reduce the content of saturated fatty acids as the constituent fatty acids of the fats and oils as much as possible. Specifically, the saturated fatty acid is preferably 47 to 65% by weight, more preferably 50 to 60% by weight, based on the total constituent fatty acids of the fat and oil. If the content of the saturated fatty acid is less than 47% by weight, the foaming property of the foamable oil-in-water emulsified oil / fat composition may be deteriorated, and if it is more than 65% by weight, it may be unfavorable for health.
本発明の起泡性水中油型乳化油脂組成物は、風味の観点から、油脂として乳脂肪をさらに含有することが好ましい。該乳脂肪の含有量は、起泡性水中油型乳化油脂組成物に含まれる油脂全体中5~50重量%であることが好ましく、10~50重量%がより好ましく、20~50重量%が更に好ましい。乳脂肪の含有量が5重量%未満であると、これを配合することにより得られる乳風味が十分に感じられない場合があり、50重量%を超えると、冷凍及び解凍後のホイップドクリームのみずみずしさが悪化する場合がある。なお、前記乳脂肪は、バターオイルまたは生クリーム、バター、バターミルク、バターミルクパウダー、生乳、牛乳、全粉乳、濃縮乳、チーズ、サワークリーム、無糖練乳、加糖練乳などの乳原料から得られるもの、又は、前記乳原料に含まれる乳脂肪分を意味する。 The foamable oil-in-water emulsified oil / fat composition of the present invention preferably further contains milk fat as the oil / fat from the viewpoint of flavor. The content of the milk fat is preferably 5 to 50% by weight, more preferably 10 to 50% by weight, and 20 to 50% by weight, based on the total amount of fat and oil contained in the foamable oil-in-water emulsified fat and oil composition. More preferred. If the content of milk fat is less than 5% by weight, the milk flavor obtained by blending it may not be sufficiently felt, and if it exceeds 50% by weight, the whipped cream after freezing and thawing may not be sufficiently felt. Freshness may worsen. The milk fat is obtained from milk raw materials such as butter oil or fresh cream, butter, butter milk, butter milk powder, raw milk, milk, whole milk powder, concentrated milk, cheese, sour cream, sugar-free milk, and sweetened milk. Or, it means the milk fat content contained in the milk raw material.
前記乳脂肪は、風味の観点から、生クリーム由来の乳脂肪であることがより好ましい。本発明の起泡性水中油型乳化油脂組成物が生クリームを含有する場合には、前記生クリームの含有量は、起泡性水中油型乳化油脂組成物全体中5~50重量%であることが好ましく、10~50重量%がより好ましく、20~50重量%が更に好ましい。前記生クリームは、乳等省令で定義される「生乳、牛乳または特別牛乳から乳脂肪分以外の成分を除去し、乳脂肪分が18.0%以上にしたもの」をいい、本発明においては、乳脂肪分が30~48%のものを使用することが、良好なホイップ性を得る上で好ましい。 From the viewpoint of flavor, the milk fat is more preferably milk fat derived from fresh cream. When the foamable oil-in-water emulsified oil / fat composition of the present invention contains fresh cream, the content of the fresh cream is 5 to 50% by weight in the entire foamable oil-in-water emulsified oil / fat composition. It is preferable, 10 to 50% by weight is more preferable, and 20 to 50% by weight is further preferable. The fresh cream refers to "a cream obtained by removing components other than milk fat from raw milk, milk or special milk so that the milk fat content is 18.0% or more" defined by the Ordinance of the Ministry of Milk, etc., and in the present invention. , It is preferable to use one having a milk fat content of 30 to 48% in order to obtain good whipping property.
本発明の起泡性水中油型乳化油脂組成物に含まれる油脂は、本発明の効果を阻害しない範囲において、上述したラウリン系油脂、S2Uを45~70重量%含むパーム系油脂、ハイエルシン菜種極度硬化油、及び、乳脂肪以外の他の食用油脂を含有するものであってもよい。そのような他の食用油脂としては、ホイップドクリームに用いられ得るものであれば特に限定はなく、例えば、菜種油、大豆油、サフラワー油、コーン油、米油、綿実油などの植物油脂や、ラードなどの動物油脂、および、これらの油脂の分別油、硬化油やそれらの混合油などが挙げられる。 The fats and oils contained in the foamable oil-in-water emulsified fat and oil composition of the present invention are the above-mentioned lauric-based fats and oils, palm-based fats and oils containing 45 to 70% by weight of S2U, and hyelcin rapeseed extremely, as long as the effects of the present invention are not impaired. It may contain hydrogenated oil and edible oils and fats other than milk fat. Such other edible oils and fats are not particularly limited as long as they can be used for whipped cream, and include, for example, vegetable oils and fats such as rapeseed oil, soybean oil, safflower oil, corn oil, rice oil, and cottonseed oil. Examples thereof include animal fats and oils such as lard, fractionated oils of these fats and oils, hydrogenated oils and mixed oils thereof.
本発明の起泡性水中油型乳化油脂組成物は、特定の構成脂肪酸組成を有するポリグリセリン脂肪酸エステルAを含有する。当該ポリグリセリン脂肪酸エステルAは、構成脂肪酸として炭素数16及び18の飽和脂肪酸と、炭素数20以上の飽和脂肪酸とを含むものであり、具体的には、その構成脂肪酸全体中において飽和脂肪酸の含有量が95~100重量%で、炭素数16及び炭素数18の飽和脂肪酸の含有量が6~25重量%で、炭素数20以上(好ましくは炭素数24以下)の飽和脂肪酸の含有量が55~85重量%である。飽和脂肪酸の含有量は98~100重量%であることが好ましく、炭素数16及び炭素数18の飽和脂肪酸の含有量は6~20重量%であることが好ましく、炭素数20以上の飽和脂肪酸の含有量は60~85重量%であることが好ましい。炭素数16及び炭素数18の飽和脂肪酸の含有量が6重量%より少ないと、冷凍及び解凍後のホイップドクリームの口溶けやみずみずしさが悪化する場合があり、25重量%より多いと、冷凍及び解凍後のホイップドクリームにひび割れや亀裂が発生する場合がある。また、炭素数20以上の飽和脂肪酸の含有量が55重量%より少ないと、冷凍及び解凍後のホイップドクリームにひび割れや亀裂が発生する場合があり、85重量%より多いと、冷凍及び解凍後のホイップドクリームの口溶けやみずみずしさが悪化する場合がある。 The foamable oil-in-water emulsified oil / fat composition of the present invention contains a polyglycerin fatty acid ester A having a specific constituent fatty acid composition. The polyglycerin fatty acid ester A contains saturated fatty acids having 16 and 18 carbon atoms and saturated fatty acids having 20 or more carbon atoms as constituent fatty acids, and specifically, the saturated fatty acids are contained in the entire constituent fatty acids. The amount is 95 to 100% by weight, the content of saturated fatty acid having 16 and 18 carbon atoms is 6 to 25% by weight, and the content of saturated fatty acid having 20 or more carbon atoms (preferably 24 or less carbon atoms) is 55. It is ~ 85% by weight. The content of the saturated fatty acid is preferably 98 to 100% by weight, the content of the saturated fatty acid having 16 carbon atoms and 18 carbon atoms is preferably 6 to 20% by weight, and the content of the saturated fatty acid having 20 or more carbon atoms is preferable. The content is preferably 60 to 85% by weight. If the content of saturated fatty acids having 16 and 18 carbon atoms is less than 6% by weight, the melting and freshness of the whipped cream after freezing and thawing may worsen, and if it is more than 25% by weight, frozen and thawed creams may be deteriorated. The whipped cream after thawing may crack or crack. Further, if the content of saturated fatty acid having 20 or more carbon atoms is less than 55% by weight, cracks or cracks may occur in the whipped cream after freezing and thawing, and if it is more than 85% by weight, after freezing and thawing. The melting and freshness of the whipped cream may worsen.
前記ポリグリセリン脂肪酸エステルAの含有量は、本発明の起泡性水中油型乳化油脂組成物の油相全体中0.1~1重量%が好ましく、0.2~0.9重量%がより好ましく、0.3~0.8重量%が更に好ましい。前記ポリグリセリン脂肪酸エステルAの含有量が0.1重量%より少ないと、冷凍及び解凍後のホイップドクリームにひび割れや亀裂が発生する場合があり、1重量%より多いと、ホイップドクリームの口溶けが悪くなったり、ホイップ時にオーバーランが上がらない場合がある。前記ポリグリセリン脂肪酸エステルAの市販品としては、「SYグリスター CV-23」(阪本薬品工業(株)製)、「SYグリスター CV-1L」(阪本薬品工業(株)製)などを例示できる。 The content of the polyglycerin fatty acid ester A is preferably 0.1 to 1% by weight, more preferably 0.2 to 0.9% by weight, based on the entire oil phase of the foamable oil-in-water emulsified oil / fat composition of the present invention. It is preferable, and more preferably 0.3 to 0.8% by weight. If the content of the polyglycerin fatty acid ester A is less than 0.1% by weight, cracks or cracks may occur in the whipped cream after freezing and thawing, and if it is more than 1% by weight, the whipped cream melts in the mouth. May get worse or the overrun may not go up when whipping. Examples of commercially available products of the polyglycerin fatty acid ester A include "SY Glycer CV-23" (manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.) and "SY Glycer CV-1L" (manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.).
本発明の起泡性水中油型乳化油脂組成物は、ポリグリセリン脂肪酸エステルAに加えて、構成脂肪酸として炭素数が20以上の飽和脂肪酸を多く含むポリグリセリン脂肪酸エステルBをさらに含有することが好ましい。ポリグリセリン脂肪酸エステルBを配合することによって、ホイップドクリームの冷凍及び解凍後にひび割れや亀裂が生じるのを、より良く抑制することができる。当該ポリグリセリン脂肪酸エステルBは、具体的には、その構成脂肪酸全体中における炭素数が20以上の飽和脂肪酸の含有量が90~100重量%のものである。当該炭素数が20以上の飽和脂肪酸の含有量は95~100重量%であることが好ましい。前記ポリグリセリン脂肪酸エステルBの市販品としては、「SYグリスター DDB-750」(阪本薬品工業(株)製)、「ポエムJ-46B」(理研ビタミン(株)製)などを例示できる。 The foamable oil-in-water emulsified oil / fat composition of the present invention preferably further contains polyglycerin fatty acid ester B containing a large amount of saturated fatty acid having 20 or more carbon atoms as a constituent fatty acid in addition to the polyglycerin fatty acid ester A. .. By blending the polyglycerin fatty acid ester B, cracks and cracks can be better suppressed after freezing and thawing of the whipped cream. Specifically, the polyglycerin fatty acid ester B has a content of a saturated fatty acid having 20 or more carbon atoms in the total constituent fatty acids of 90 to 100% by weight. The content of the saturated fatty acid having 20 or more carbon atoms is preferably 95 to 100% by weight. Examples of commercially available products of the polyglycerin fatty acid ester B include "SY Glycer DDB-750" (manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.) and "Poem J-46B" (manufactured by Riken Vitamin Co., Ltd.).
前記ポリグリセリン脂肪酸エステルBの含有量は、本発明の起泡性水中油型乳化油脂組成物の油相全体中0.05~1重量%であることが好ましく、0.1~0.9重量%がより好ましく、0.3~0.8重量%がさらに好ましい。ポリグリセリン脂肪酸エステルBの含有量が0.05重量%より少ないと、これを配合することによる効果を十分に得ることができず、1重量%より多いとホイップドクリームの口溶けが悪くなる場合がある。 The content of the polyglycerin fatty acid ester B is preferably 0.05 to 1% by weight, preferably 0.1 to 0.9% by weight, based on the entire oil phase of the foamable oil-in-water emulsified oil / fat composition of the present invention. % Is more preferable, and 0.3 to 0.8% by weight is even more preferable. If the content of the polyglycerin fatty acid ester B is less than 0.05% by weight, the effect of blending the polyglycerin fatty acid ester B cannot be sufficiently obtained, and if it is more than 1% by weight, the whipped cream may not melt in the mouth. be.
本発明の起泡性水中油型乳化油脂組成物は、構成脂肪酸として不飽和脂肪酸を多く含む乳化剤を含有するものである。具体的には、該乳化剤の構成脂肪酸全体中における不飽和脂肪酸の含有量は60~100重量%であり、好ましくは80~100重量%である。該乳化剤としては、例えば、大豆レシチン、卵黄レシチン、これらの分画レシチン、これらを酵素分解したリゾレシチン等の改質レシチンなどの各種レシチンや、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル等が挙げられる。前記乳化剤の市販品としては、各種レシチンの他、ポリグリセリン脂肪酸エステルである「SYグリスター MO-5S」(阪本薬品工業(株)製)などを例示できる。 The foamable oil-in-water emulsified oil / fat composition of the present invention contains an emulsifier containing a large amount of unsaturated fatty acids as constituent fatty acids. Specifically, the content of unsaturated fatty acids in the total constituent fatty acids of the emulsifier is 60 to 100% by weight, preferably 80 to 100% by weight. Examples of the emulsifier include various lecithin such as soybean lecithin, egg yolk lecithin, fractionated lecithin thereof, modified lecithin such as lysolecithin obtained by enzymatically decomposing these, polyglycerin fatty acid ester, sucrose fatty acid ester, and sorbitan fatty acid ester. Examples thereof include propylene glycol fatty acid ester. Examples of commercially available emulsifiers include various lecithins, as well as "SY Glycer MO-5S" (manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.), which is a polyglycerin fatty acid ester.
前記構成脂肪酸として不飽和脂肪酸を多く含む乳化剤の含有量は、本発明の起泡性水中油型乳化油脂組成物全体中0.05~0.5重量%であり、0.1~0.4重量%が好ましく、0.1~0.3重量%がより好ましい。前記乳化剤の含有量が0.05重量%未満であると、起泡性水中油型乳化油脂組成物のホイップ性が劣る場合があり、0.5重量%を超えると、ホイップドクリームの風味が損なわれる場合がある。 The content of the emulsifier containing a large amount of unsaturated fatty acid as the constituent fatty acid is 0.05 to 0.5% by weight in the entire foamable oil-in-water emulsified oil / fat composition of the present invention, and is 0.1 to 0.4% by weight. The weight is preferably%, more preferably 0.1 to 0.3% by weight. If the content of the emulsifier is less than 0.05% by weight, the whipping property of the foamable oil-in-water emulsified oil / fat composition may be inferior, and if it exceeds 0.5% by weight, the flavor of the whipped cream may be deteriorated. It may be damaged.
本発明の起泡性水中油型乳化油脂組成物は、本発明の効果を損なわない範囲で、必要に応じて、前述したもの以外の他の乳化剤、増粘剤、糖類、乳原料、呈味剤、着色料、香料、塩類、ビタミン類、ミネラル類、油溶性酸化防止剤、その他の食品成分を含有してもよい。 The foamable oil-in-water emulsified oil / fat composition of the present invention is, if necessary, other emulsifiers, thickeners, sugars, dairy raw materials, and tastes other than those described above, as long as the effects of the present invention are not impaired. It may contain agents, colorants, flavors, salts, vitamins, minerals, oil-soluble antioxidants, and other food ingredients.
前記他の乳化剤としては、炭素数16及び炭素数18の飽和脂肪酸の含有量が構成脂肪酸全体中6重量%未満又は25重量%を超えるポリグリセリン脂肪酸エステル、炭素数20以上の飽和脂肪酸の含有量が構成脂肪酸全体中55重量%未満又は85重量%を超えて90重量%未満であるポリグリセリン脂肪酸エステル、不飽和脂肪酸の含有量が構成脂肪酸全体中60重量%未満のポリグリセリン脂肪酸エステル、不飽和脂肪酸の含有量が構成脂肪酸全体中60重量%未満のショ糖脂肪酸エステル、不飽和脂肪酸の含有量が構成脂肪酸全体中60重量%未満のソルビタン脂肪酸エステル、不飽和脂肪酸の含有量が構成脂肪酸全体中60重量%未満のプロピレングリコール脂肪酸エステル等の合成乳化剤などが挙げられる。これらの中から1種のみを用いてもよいし、2種以上を用いてもよい。 Examples of the other emulsifier include polyglycerin fatty acid esters in which the content of saturated fatty acids having 16 and 18 carbon atoms is less than 6% by weight or more than 25% by weight in the total constituent fatty acids, and the content of saturated fatty acids having 20 or more carbon atoms. Polyglycerin fatty acid ester in which is less than 55% by weight or more than 85% by weight and less than 90% by weight in the total constituent fatty acids, polyglycerin fatty acid ester in which the content of unsaturated fatty acid is less than 60% by weight in the total constituent fatty acids, unsaturated Sucrose fatty acid ester with a fatty acid content of less than 60% by weight in the total fatty acid, sorbitan fatty acid ester with an unsaturated fatty acid content of less than 60% by weight in the total fatty acid, and unsaturated fatty acid content in the total fatty acid Examples thereof include synthetic emulsifiers such as propylene glycol fatty acid ester of less than 60% by weight. Only one of these may be used, or two or more thereof may be used.
前記増粘剤としては、例えば、ジェランガム、グアガム、キサンタンガム、寒天、ペクチン、アルギン酸ナトリウム、カラギーナン、ローカストビーンガム、アラビアガム、カルボキシメチルセルロース、ヒドロキシメチルセルロース、結晶セルロース、微結晶セルロース、澱粉、デキストリン等を挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 Examples of the thickener include gellan gum, guar gum, xanthan gum, agar, pectin, sodium alginate, carrageenan, locust bean gum, arabic gum, carboxymethyl cellulose, hydroxymethyl cellulose, crystalline cellulose, microcrystalline cellulose, starch, dextrin and the like. And at least one selected from these groups can be used.
前記糖類としては、例えば、ブドウ糖、砂糖、果糖、異性化糖、澱粉糖化物、デキストリン、澱粉又は糖アルコール等を挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 Examples of the saccharide include glucose, sugar, fructose, isomerized sugar, starch saccharified product, dextrin, starch, sugar alcohol and the like, and at least one selected from these groups can be used.
前記乳原料としては、カゼイン、ホエイパウダー、蛋白質濃縮ホエイパウダー、脱脂粉乳、乳糖、トータルミルクプロテイン、脱脂乳、脱脂濃縮乳、ホエー等を用いてもよく、さらに、UF膜やイオン交換樹脂処理等により蛋白質を分離、分画したものや、カゼインナトリウムやカゼインカリウムのようなカゼイン塩が挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 As the milk raw material, casein, whey powder, protein concentrated whey powder, skim milk powder, lactose, total milk protein, skim milk, skim concentrated milk, whey and the like may be used, and further, a UF film, ion exchange resin treatment, etc. may be used. Examples thereof include those obtained by separating and fractionating a protein according to the above, and casein salts such as casein sodium and casein potassium, and at least one selected from these groups can be used.
前記呈味剤としては、前記乳原料を酵素分解、加熱、分離、分画等をしたものが挙げられ、これらの群より少なくとも1種を使用することができる。 Examples of the taste agent include those obtained by enzymatically decomposing, heating, separating, fractionating, etc. the milk raw material, and at least one of these groups can be used.
前記着色料としては、天然成分や人工成分に関わらず、食品用途として使用できるものが挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 Examples of the colorant include those that can be used for food purposes regardless of natural ingredients or artificial ingredients, and at least one selected from these groups can be used.
前記香料としては、天然成分や人工成分に関わらず、食品用途として使用できるものが挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 Examples of the flavor include those that can be used for food purposes regardless of natural ingredients or artificial ingredients, and at least one selected from these groups can be used.
前記塩類としては、一般に食品に用いられている塩類であれば特に制限はなく、例えば、塩化ナトリウム、クエン酸ナトリウム、クエン酸カリウム、乳酸ナトリウム、水酸化ナトリウム、炭酸ナトリウム、炭酸カリウム、炭酸アンモニウム、炭酸水素ナトリウム、炭酸水素カリウム、リン酸3ナトリウム、リン酸水素2ナトリウムなどが挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 The salts are not particularly limited as long as they are salts generally used in foods, and for example, sodium chloride, sodium citrate, potassium citrate, sodium lactate, sodium hydroxide, sodium carbonate, potassium carbonate, ammonium carbonate, etc. Examples thereof include sodium hydrogen carbonate, potassium hydrogen carbonate, trisodium phosphate, disodium hydrogen phosphate and the like, and at least one selected from these groups can be used.
前記ビタミン類としては、ビタミンA、ビタミンB群、ビタミンC、ビタミンD、ビタミンE、ビタミンKを主成分とする食品用途として使用できるものが挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 Examples of the vitamins include those that can be used for foods containing vitamin A, vitamin B group, vitamin C, vitamin D, vitamin E, and vitamin K as main components, and at least one selected from these groups is used. can do.
前記ミネラル類としては、亜鉛、カリウム、カルシウム、クロム、セレン、鉄、銅、ナトリウム、マグネシウム、マンガン、モリブデン、ヨウ素、リンが挙げられ、これらの成分を含む食品及び食品添加物に分類されるものを少なくとも1種使用することができる。 Examples of the minerals include zinc, potassium, calcium, chromium, selenium, iron, copper, sodium, magnesium, manganese, molybdenum, iodine and phosphorus, which are classified into foods and food additives containing these components. Can be used at least one kind.
前記油溶性酸化防止剤としては、ビタミンE、ローズマリー抽出物等の抗酸化成分を主成分とする食品用途として使用できるものが挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 Examples of the oil-soluble antioxidant include those that can be used for foods containing antioxidant components such as vitamin E and rosemary extract as main components, and at least one selected from these groups may be used. can.
本発明の起泡性水中油型乳化油脂組成物の製造方法は、特に限定されないが、以下に例示する。まず、50~70℃に加温溶融した油脂に、ポリグリセリン脂肪酸エステルA、必要に応じてポリグリセリン脂肪酸エステルB、必要に応じて前記不飽和脂肪酸の含有量が構成脂肪酸全体中60~100重量%である乳化剤であって油溶性のもの、及び、必要に応じてこれら以外の油溶性乳化剤、油溶性香料等の油溶性原料を混合し、該混合物を50~70℃に維持しながら攪拌し、油相を調製する。 The method for producing the foamable oil-in-water emulsified oil / fat composition of the present invention is not particularly limited, but is exemplified below. First, the content of polyglycerin fatty acid ester A, if necessary polyglycerin fatty acid ester B, and if necessary, the unsaturated fatty acid is 60 to 100% by weight in the whole constituent fatty acids in the fat and oil heated and melted at 50 to 70 ° C. %, An oil-soluble one, and other oil-soluble emulsifiers, oil-soluble fragrances, and other oil-soluble raw materials are mixed, and the mixture is stirred while maintaining the temperature at 50 to 70 ° C. , Prepare the oil phase.
また、50~70℃の温水に、必要に応じて前記不飽和脂肪酸の含有量が構成脂肪酸全体中60~100重量%である乳化剤であって水溶性のもの、必要に応じてこれ以外の水溶性乳化剤、蛋白質、塩類、香料、増粘剤、呈味剤、糖類、乳原料、着色料、ビタミン類、ミネラル類などの水溶性原料を混合し、50~70℃に維持しながら攪拌し、水相を調製する。 Further, an emulsifier having an unsaturated fatty acid content of 60 to 100% by weight in the total constituent fatty acids in warm water at 50 to 70 ° C. and water-soluble, if necessary, other water-soluble ones. Mix water-soluble raw materials such as sex emulsifiers, proteins, salts, flavors, thickeners, flavoring agents, sugars, dairy raw materials, coloring agents, vitamins, minerals, etc., and stir while maintaining at 50-70 ° C. Prepare the aqueous phase.
そして、水相を攪拌しながらそこへ油相を添加して、予備乳化する。その後、微細化、均質化、予備加熱、殺菌、1次冷却、均質化、2次冷却、3次冷却、エージングなど、起泡性水中油型乳化油脂組成物の製造時に常法として行われる各処理を行うことにより、本発明の起泡性水中油型乳化油脂組成物を得ることができる。なお、原材料に生クリームを使用する場合、生クリームを前記水相に添加してから、前記のように常法に従って起泡性水中油型乳化油脂組成物を作製しても良いし、前記のように常法に従って作製した水中油型乳化油脂組成物と生クリームを混合して、本発明の起泡性水中油型乳化油脂組成物を作製しても良い。 Then, while stirring the aqueous phase, the oil phase is added thereto to pre-emulsify. After that, each of the usual methods for producing a foamable oil-in-water emulsified oil / fat composition such as micronization, homogenization, preheating, sterilization, primary cooling, homogenization, secondary cooling, tertiary cooling, and aging is performed. By performing the treatment, the foamable oil-in-water emulsified oil / fat composition of the present invention can be obtained. When fresh cream is used as a raw material, the fresh cream may be added to the aqueous phase, and then a foamable oil-in-water emulsified oil / fat composition may be prepared according to a conventional method as described above. As described above, the oil-in-water emulsified oil / fat composition prepared according to a conventional method and fresh cream may be mixed to prepare a foamable oil-in-water emulsified oil / fat composition of the present invention.
そして、得られた起泡性水中油型乳化油脂組成物を、オープン式ホイッパーや密閉式連続ホイップマシンを用いて、トッピング、ナッペ、サンド等の使用目的に沿った適度な硬さに到達するまでホイップすることで、本発明のホイップドクリームが得られる。 Then, the obtained foamable oil-in-water emulsified oil / fat composition is used with an open type whipper or a closed type continuous whipping machine until it reaches an appropriate hardness according to the purpose of use such as toppings, nappes, and sands. By whipping, the whipped cream of the present invention can be obtained.
本発明のホイップドクリームは、スポンジケーキ、ブッセ、クッキー、ビスケット等の菓子類に代表される食品のナッペ用、トッピング用、又はサンド用等のホイップドクリームとして好適に使用することができる。 The whipped cream of the present invention can be suitably used as a whipped cream for nappes, toppings, sands and the like of foods typified by confectioneries such as sponge cakes, busses, cookies and biscuits.
本発明のホイップドクリームは冷凍及び解凍後にもひび割れや亀裂が生じにくく、風味及び口溶けが良好で、コクがあり、みずみずしい食感が得られることから、本発明のホイップドクリームを含む食品は、冷凍食品として好適に用いることができる。該食品を冷凍する時の温度は、特に限定されないが、例えば-40℃~-10℃であってよく、好ましくは-30~-15℃であり、より好ましくは-25℃~-15℃である。冷凍して保存する際の時間も特に限定されないが、1日~180日程度であってよい。 The whipped cream of the present invention is less likely to crack or crack even after freezing and thawing, has a good flavor and melts in the mouth, has a rich texture, and has a fresh texture. It can be suitably used as a frozen food. The temperature at which the food is frozen is not particularly limited, but may be, for example, −40 ° C. to −10 ° C., preferably −30 ° C. to −15 ° C., and more preferably −25 ° C. to −15 ° C. be. The time for freezing and storing is not particularly limited, but may be about 1 to 180 days.
以下に実施例を示し、本発明をより具体的に説明するが、本発明はこれらの実施例に何ら限定されるものではない。なお、実施例において「部」や「%」は重量基準である。 Examples are shown below and the present invention will be described in more detail, but the present invention is not limited to these examples. In the examples, "part" and "%" are based on weight.
<実施例及び比較例で使用した原料>
1)(株)カネカ製「パーム核油」(上昇融点:27℃、トランス脂肪酸:0重量%、炭素数12の飽和脂肪酸:44.9重量%、総飽和脂肪酸:79.5重量%)
2)(株)カネカ製「パーム油中融点部」(S2U型トリグリセリド:65.8重量%、トランス脂肪酸:0.1重量%、炭素数12の飽和脂肪酸:0.2重量%、総飽和脂肪酸:54.9重量%)
3)(株)カネカ製「パームオレイン」(S2U型トリグリセリド:47.4重量%、トランス脂肪酸:0.2重量%、総飽和脂肪酸:45.9重量%)
4)(株)カネカ製「ハイエルシン菜種極度硬化油」(トランス脂肪酸:0重量%、総飽和脂肪酸:99.9重量%)
5)阪本薬品工業(株)製「CV-23」(構成脂肪酸全体中、飽和脂肪酸:99.9重量%、炭素数16及び炭素数18の飽和脂肪酸:8.8重量%、炭素数20以上の飽和脂肪酸:80.3重量%)
6)阪本薬品工業(株)製「CV-1L」(構成脂肪酸全体中、飽和脂肪酸:99.9重量%、炭素数16及び炭素数18の飽和脂肪酸:19.9重量%、炭素数20以上の飽和脂肪酸:63.9重量%)
7)ADM(株)製「Yelkin TS」(構成脂肪酸全体中の不飽和脂肪酸:78.9重量%)
8)阪本薬品工業(株)製「SYグリスターMS-3S」
9)よつ葉乳業(株)製「脱脂粉乳」
10)FrieslandCampina DMV社製「カゼインカリウムSPRAY」
11)HILMAR社製「ラクトースHILMAR FINE GRAIND」
12)阪本薬品工業(株)製「SYグリスターMS-5S」
13)阪本薬品工業(株)製「SYグリスターMO-5S」(構成脂肪酸全体中の不飽和脂肪酸:70重量%)
14)阪本薬品工業(株)製「DDB-750」(構成脂肪酸全体中の炭素数20以上の飽和脂肪酸:95.7重量%)
15)理研ビタミン(株)製「ポエムJ-46B」(構成脂肪酸全体中の炭素数20以上の飽和脂肪酸:97.7重量%)
16)理研ビタミン(株)製「ポエムDS100A]
17)理研ビタミン(株)製「ポエムDP-95RF」
18)阪本薬品工業(株)製「SYグリスターMS-3S」
19)阪本薬品工業(株)製「SYグリスターTS-3S」
20)よつ葉乳業(株)製「無塩バター」(よつ葉バター(食塩不使用)を溶解し、遠心分離して水相部を除去して得たバターオイル、上昇融点:30℃)
21)明治乳業(株)製「明治フレッシュクリーム45(乳脂肪含量45%)」<Raw materials used in Examples and Comparative Examples>
1) "Palm kernel oil" manufactured by Kaneka Co., Ltd. (rising melting point: 27 ° C., trans fatty acid: 0% by weight, saturated fatty acid with 12 carbon atoms: 44.9% by weight, total saturated fatty acid: 79.5% by weight)
2) "Middle melting point of palm oil" manufactured by Kaneka Co., Ltd. (S2U type triglyceride: 65.8% by weight, trans fatty acid: 0.1% by weight, saturated fatty acid having 12 carbon atoms: 0.2% by weight, total saturated fatty acid : 54.9% by weight)
3) "Palm olein" manufactured by Kaneka Corporation (S2U type triglyceride: 47.4% by weight, trans fatty acid: 0.2% by weight, total saturated fatty acid: 45.9% by weight)
4) "High Elsin Rapeseed Extremely Hydrogenated Oil" manufactured by Kaneka Corporation (trans fatty acid: 0% by weight, total saturated fatty acid: 99.9% by weight)
5) "CV-23" manufactured by Sakamoto Yakuhin Kogyo Co., Ltd. (Saturated fatty acids: 99.9% by weight, 16 and 18 carbon atoms: 8.8% by weight, 20 or more carbon atoms in all constituent fatty acids) Saturated fatty acids: 80.3% by weight)
6) "CV-1L" manufactured by Sakamoto Yakuhin Kogyo Co., Ltd. (Saturated fatty acids: 99.9% by weight, 16 and 18 carbons of saturated fatty acids: 19.9% by weight, 20 or more carbon atoms in the total constituent fatty acids) Saturated fatty acids: 63.9% by weight)
7) "Yelkin TS" manufactured by ADM Co., Ltd. (unsaturated fatty acids in all constituent fatty acids: 78.9% by weight)
8) "SY Glister MS-3S" manufactured by Sakamoto Pharmaceutical Co., Ltd.
9) "Skim milk powder" manufactured by Yotsuba Dairy Co., Ltd.
10) "Casein Potassium SPRAY" manufactured by Friesland Campina DMV
11) "Lactose HILMAR FINE GRAIND" manufactured by HILMAR
12) "SY Glister MS-5S" manufactured by Sakamoto Pharmaceutical Co., Ltd.
13) "SY Glister MO-5S" manufactured by Sakamoto Yakuhin Kogyo Co., Ltd. (unsaturated fatty acids in all constituent fatty acids: 70% by weight)
14) "DDB-750" manufactured by Sakamoto Yakuhin Kogyo Co., Ltd. (Saturated fatty acids with 20 or more carbon atoms in the total constituent fatty acids: 95.7% by weight)
15) "Poem J-46B" manufactured by Riken Vitamin Co., Ltd. (Saturated fatty acids with 20 or more carbon atoms in the total constituent fatty acids: 97.7% by weight)
16) "Poem DS100A" manufactured by Riken Vitamin Co., Ltd.
17) "Poem DP-95RF" manufactured by Riken Vitamin Co., Ltd.
18) "SY Glister MS-3S" manufactured by Sakamoto Pharmaceutical Co., Ltd.
19) "SY Glister TS-3S" manufactured by Sakamoto Pharmaceutical Co., Ltd.
20) "Unsalted butter" manufactured by Yotsuba Dairy Co., Ltd. (Butter oil obtained by dissolving yotsuba butter (without salt) and centrifuging to remove the aqueous phase, melting point: 30 ° C)
21) "Meiji Fresh Cream 45 (milk fat content 45%)" manufactured by Meiji Dairy Co., Ltd.
<ホイップドクリームの解凍後の外観評価>
実施例および比較例で得られた各ホイップドクリームをスポンジケーキにナッペ及びトッピングし、全体を冷凍した後に解凍したスポンジケーキにおけるホイップドクリームの外観を目視で観察し、ヒビ割れのなさを評価した。その際の評価基準は、以下の通りであった。<Appearance evaluation after thawing of whipped cream>
Each whipped cream obtained in Examples and Comparative Examples was napped and topping on a sponge cake, and the appearance of the whipped cream in the sponge cake thawed after freezing the whole was visually observed to evaluate the absence of cracks. .. The evaluation criteria at that time were as follows.
(ヒビ割れのなさ)
5点:実施例4のホイップドクリームよりも非常に良好で、解凍後にナッペ表面、トッピングどちらにもヒビ割れ・亀裂がない。解凍前と比較して状態変化がない。
4点:実施例4のホイップドクリームよりも良好で、解凍後にナッペ表面、トッピングどちらかに微細なヒビ割れ・亀裂がある。
3点:実施例4のホイップドクリームと同等で、解凍後にナッペ表面、トッピングどちらにも微細なヒビ割れ・亀裂がある。
2点:実施例4のホイップドクリームよりも悪く、解凍後にナッペ表面、トッピングどちらかに大きなヒビ割れ・亀裂がある。
1点:実施例4のホイップドクリームよりも非常に悪く、解凍後にナッペ表面にスポンジが露出するほどのヒビ割れがある。トッピングに大きな亀裂が生じ、形状が崩壊している。(No cracks)
5 points: Very good than the whipped cream of Example 4, and there are no cracks or cracks on either the nappe surface or the topping after thawing. There is no change in state compared to before thawing.
4 points: It is better than the whipped cream of Example 4, and there are fine cracks / cracks on either the nappe surface or the topping after thawing.
3 points: Same as the whipped cream of Example 4, and there are fine cracks and cracks on both the nappe surface and the topping after thawing.
2 points: It is worse than the whipped cream of Example 4, and there are large cracks / cracks on either the nappe surface or the topping after thawing.
1 point: Very worse than the whipped cream of Example 4, and there are cracks enough to expose the sponge on the surface of the nappe after thawing. A large crack has occurred in the topping and the shape has collapsed.
<ホイップドクリームの官能評価>
実施例および比較例で得られた各ホイップドクリームをスポンジケーキにナッペ及びトッピングし、全体を冷凍した後に解凍したスポンジケーキにおけるホイップドクリームを、熟練した10人のパネラーに試食してもらい、風味、口溶け、コク、及びみずみずしさの観点で各人が官能評価を行い、その評価点の平均値を官能評価の評価値として各表に記載した。その際の評価基準は以下の通りであった。なお、風味に関しては、冷凍する前のスポンジケーキにおけるホイップドクリームについても同様に試食してもらい、冷解凍前後での風味の変化を評価した。<Sensory evaluation of whipped cream>
Each whipped cream obtained in Examples and Comparative Examples was napped and topping on a sponge cake, and the whipped cream in the sponge cake thawed after freezing the whole was tasted by 10 skilled panelists and flavored. Each person performed a sensory evaluation from the viewpoints of melting in the mouth, richness, and freshness, and the average value of the evaluation points was described in each table as the evaluation value of the sensory evaluation. The evaluation criteria at that time were as follows. Regarding the flavor, the whipped cream in the sponge cake before freezing was also tasted in the same manner, and the change in flavor before and after cold thawing was evaluated.
(風味)
5点:実施例4のホイップドクリームよりも非常に良好で、冷解凍前後で乳風味の変化を感じない。
4点:実施例4のホイップドクリームより良好で、冷解凍前後で乳風味の変化を僅かに感じる。
3点:実施例4のホイップドクリームと同等で、冷解凍前後で乳風味の変化を感じる。
2点:実施例4のホイップドクリームよりも悪く、解凍後は乳風味を僅かにしか感じない。
1点:実施例4のホイップドクリームよりも非常に悪く、解凍後は乳風味を感じない。(Flavor)
5 points: Very good than the whipped cream of Example 4, and no change in milk flavor is felt before and after cold thawing.
4 points: Better than the whipped cream of Example 4, and a slight change in milk flavor is felt before and after cold thawing.
3 points: Same as the whipped cream of Example 4, and the change in milk flavor is felt before and after cold thawing.
2 points: It is worse than the whipped cream of Example 4, and the milk flavor is slightly felt after thawing.
1 point: Very worse than the whipped cream of Example 4, and does not feel milky flavor after thawing.
(口溶け)
5点:実施例4のホイップドクリームよりも非常に良好で、冷凍による水分の昇華や劣化を感じず、また油っぽさがなく口溶けが極めて良好である。
4点:実施例4のホイップドクリームよりも良好で、冷凍による水分の昇華や劣化を僅かに感じるが、口溶けは良好である。
3点:実施例4のホイップドクリームと同等で、冷凍による水分の昇華や劣化を感じるが、口溶けの悪さは感じない。
2点:実施例4のホイップドクリームよりも悪く、冷凍による水分の昇華や劣化を感じ、更に油っぽさがあり、口溶けの悪さを感じる。
1点:実施例4のホイップドクリームよりも非常に悪く、冷凍による水分の昇華や劣化を強く感じ、更に油っぽく、口溶けが極めて悪く感じる。(Melting in the mouth)
5 points: Very good than the whipped cream of Example 4, no sublimation or deterioration of water due to freezing is felt, no oiliness is observed, and melting in the mouth is extremely good.
4 points: It is better than the whipped cream of Example 4, and the sublimation and deterioration of water due to freezing are slightly felt, but the melting in the mouth is good.
3 points: Similar to the whipped cream of Example 4, the sublimation and deterioration of water due to freezing are felt, but the bad melting in the mouth is not felt.
2 points: It is worse than the whipped cream of Example 4, and the sublimation and deterioration of water due to freezing are felt, and the creaminess is further felt, and the melting in the mouth is felt.
1 point: Very worse than the whipped cream of Example 4, the sublimation and deterioration of water due to freezing are strongly felt, and the oily feeling is extremely poor in melting in the mouth.
(コク)
5点:実施例4のホイップドクリームよりも良好で、コクを強く感じる。
4点:実施例4のホイップドクリームと同等で、コクを感じる。
3点:実施例4のホイップドクリームよりもやや悪く、コクがやや弱く感じる。
2点:実施例4のホイップドクリームよりも悪く、コクが弱く感じる。
1点:実施例4のホイップドクリームよりも非常に悪く、コクを感じない。(Koku)
5 points: Better than the whipped cream of Example 4, and feels strong.
4 points: Same as the whipped cream of Example 4, and feels rich.
3 points: Slightly worse than the whipped cream of Example 4, and the richness feels a little weak.
2 points: It is worse than the whipped cream of Example 4, and the body feels weak.
1 point: Very worse than the whipped cream of Example 4, and does not feel rich.
(みずみずしさ)
5点:実施例4のホイップドクリームよりも非常に良好で、冷凍による水分昇華を感じず、食感が極めて滑らかで、みずみずしい。
4点:実施例4のホイップドクリームよりも良好で、冷凍による水分昇華を僅かに感じるが、食感は滑らかで、みずみずしい。
3点:実施例4のホイップドクリームと同等で、冷凍による水分昇華を感じ、食感は滑らかではないが、みずみずしく感じる。
2点:実施例4のホイップドクリームよりも悪く、冷凍による水分昇華を感じ、更に食感にパサつきがあり、みずみずしさに欠ける。
1点:実施例4のホイップドクリームよりも非常に悪く、冷凍による水分昇華を強く感じ、更に食感にパサつきがあり、みずみずしくない。(Freshness)
5 points: Very good than the whipped cream of Example 4, no water sublimation due to freezing is felt, the texture is extremely smooth, and it is fresh.
4 points: Better than the whipped cream of Example 4, the water sublimation due to freezing is slightly felt, but the texture is smooth and fresh.
3 points: Similar to the whipped cream of Example 4, the water sublimation due to freezing is felt, and the texture is not smooth, but it feels fresh.
2 points: Worse than the whipped cream of Example 4, the water sublimation due to freezing is felt, the texture is dry, and the freshness is lacking.
1 point: Very worse than the whipped cream of Example 4, the water sublimation due to freezing is strongly felt, and the texture is dry and not fresh.
(総合評価)
A:ホイップドクリームのヒビ割れのなさ、風味、コク、口溶け、みずみずしさの評価値が全て4.0点以上5.0点以下を満たすもの。
B:ホイップドクリームのヒビ割れのなさ、風味、コク、口溶け、みずみずしさの評価値が全て3.5点以上5.0点以下であって、且つ3.5以上4.0未満が少なくとも一つあるもの。
C:ホイップドクリームのヒビ割れのなさ、風味、コク、口溶け、みずみずしさの評価値が全て3.0点以上5.0点以下であって、且つ3.0以上3.5未満が少なくとも一つあるもの。
D:ホイップドクリームのヒビ割れのなさ、風味、コク、口溶け、みずみずしさの評価値が全て2.0点以上5.0点以下であって、且つ2.0以上3.0未満が少なくとも一つあるもの。
E:ホイップドクリームのヒビ割れのなさ、風味、コク、口溶け、みずみずしさの評価において、2.0未満が少なくとも一つあるもの。(Comprehensive evaluation)
A: The whipped cream has no cracks, flavor, richness, melting in the mouth, and freshness, all of which satisfy 4.0 points or more and 5.0 points or less.
B: The evaluation values of whipped cream without cracks, flavor, richness, melting in the mouth, and freshness are all 3.5 points or more and 5.0 points or less, and 3.5 or more and less than 4.0 are at least one. There are two things.
C: The evaluation values of whipped cream without cracks, flavor, richness, melting in the mouth, and freshness are all 3.0 points or more and 5.0 points or less, and 3.0 or more and less than 3.5 are at least one. There are two things.
D: The evaluation values of whipped cream without cracks, flavor, richness, melting in the mouth, and freshness are all 2.0 points or more and 5.0 points or less, and 2.0 or more and less than 3.0 are at least one. There are two things.
E: At least one whipped cream with less than 2.0 in the evaluation of cracklessness, flavor, richness, melting in the mouth, and freshness.
(製造例1)パーム油とパーム核オレインのランダムエステル交換油の作製
パーム油(株式会社カネカ製):50重量部及びパーム核オレイン(株式会社カネカ製):50重量部を混合し、90℃、真空下で脱水を行った。そこへナトリウムメチラート(東ソー株式会社製):0.3重量部を加え、90℃、窒素気流下で30分間ランダムエステル交換反応を行い、水を加えて反応停止後、水洗した。次に、活性白土(水澤化学工業株式会社製):3.0重量部を加え、減圧下で攪拌して20分後に全量濾過してエステル交換油脂Aを得た。(Production Example 1) Preparation of random transesterified oil of palm oil and palm kernel olein Palm oil (manufactured by Kaneka Corporation): 50 parts by weight and palm kernel olein (manufactured by Kaneka Corporation): 50 parts by weight are mixed and 90 ° C. , Dehydration was performed under vacuum. Sodium methylate (manufactured by Tosoh Corporation): 0.3 parts by weight was added thereto, a random transesterification reaction was carried out at 90 ° C. under a nitrogen stream for 30 minutes, water was added to stop the reaction, and then the reaction was washed with water. Next, activated clay (manufactured by Mizusawa Industrial Chemicals Co., Ltd.): 3.0 parts by weight was added, stirred under reduced pressure, and after 20 minutes, the whole amount was filtered to obtain transesterified fat A.
(実施例1)起泡性水中油型乳化物及びホイップドクリームの作製
表1の配合に従い、パーム核油3.65重量部、パーム中融点部分別油20.0重量部、パームオレイン12.85重量部およびハイエルシン菜種極度硬化油0.5重量部を配合してなる油脂成分に、大豆レシチン0.20重量部、テトラグリセリンモノステアリン酸エステル0.06重量部、及び、ポリグリセリン脂肪酸エステルA1(構成脂肪酸全体中、飽和脂肪酸:99.9重量%、炭素数16及び炭素数18の飽和脂肪酸:8.8重量%、炭素数20以上の飽和脂肪酸:80.3重量%)0.037重量部を添加し、65℃で溶解して油相部を作製した。このとき、油相部の油脂の構成脂肪酸全体中の含有量は、トランス脂肪酸:0.1重量%、総飽和脂肪酸:54.5重量%であった。(Example 1) Preparation of foamable oil-in-water emulsion and whipped cream According to the formulation shown in Table 1, 3.65 parts by weight of palm kernel oil, 20.0 parts by weight of oil by melting point in palm, palm olein 12. 0.20 parts by weight of soy lecithin, 0.06 parts by weight of tetraglycerin monostearic acid ester, and polyglycerin fatty acid ester A1 in the oil and fat component composed of 85 parts by weight of Hyelsin rapeseed extremely hardened oil. (Saturated fatty acid: 99.9% by weight, saturated fatty acid having 16 carbon atoms and 18 carbon atoms: 8.8% by weight, saturated fatty acid having 20 or more carbon atoms: 80.3% by weight) 0.037 weight A portion was added and dissolved at 65 ° C. to prepare an oil phase portion. At this time, the content of the fats and oils in the oil phase portion in the total constituent fatty acids was trans fatty acid: 0.1% by weight and total saturated fatty acid: 54.5% by weight.
一方、脱脂粉乳3.7重量部、カゼインカリウム0.5重量部、乳糖1.5重量部、ヘキサグリセリンモノステアリン酸エステル0.05重量部、ヘキサグリセリンモノオレイン酸エステル0.02重量部を、表1の配合と最終的に同じになるように60℃以上の温水に溶解して水相部を作製した。 On the other hand, 3.7 parts by weight of defatted milk powder, 0.5 part by weight of casein potassium, 1.5 parts by weight of lactose, 0.05 part by weight of hexaglycerin monostearic acid ester, 0.02 parts by weight of hexaglycerin monooleic acid ester, An aqueous phase portion was prepared by dissolving in warm water at 60 ° C. or higher so as to have the same final composition as in Table 1.
前記の油相部と水相部とを混合して20分以上予備乳化した後、高周速回転式乳化機(エム・テクニック(株)製「クレアミックス」)を用いて周速31.4m/sの回転速度で微細化した。次いで、高圧ホモジナイザーを用いて1段目:2.0MPa/2段目:1.0MPaの圧力で処理した後に、プレート式加熱機を用いて90℃まで予備加熱した後、UHT殺菌機(スチームインジェクション)を用いて142℃で4秒間殺菌処理した。次に、蒸発冷却せずにプレート式冷却機を用いて60℃まで冷却し、再び高圧ホモジナイザーを用いて1段目9.0MPa/2段目3.0MPaの圧力で処理し、その後、プレート式冷却機で5℃まで冷却したものを容器に充填し、5℃の冷蔵庫で24時間保管し、起泡性水中油型乳化物を得た。 After mixing the oil phase part and the aqueous phase part and pre-emulsifying for 20 minutes or more, a peripheral speed of 31.4 m is used using a high peripheral speed rotary emulsifier (“Clearmix” manufactured by M-Technique Co., Ltd.). It was miniaturized at a rotation speed of / s. Next, after treating with a high-pressure homogenizer at a pressure of 1st stage: 2.0 MPa / 2nd stage: 1.0 MPa, preheating to 90 ° C. using a plate-type heater, and then a UHT sterilizer (steam injection). ) Was sterilized at 142 ° C. for 4 seconds. Next, the mixture was cooled to 60 ° C. using a plate-type cooler without evaporative cooling, treated again with a high-pressure homogenizer at a pressure of 9.0 MPa for the first stage / 3.0 MPa for the second stage, and then plate-type. A container cooled to 5 ° C. with a cooler was filled in a container and stored in a refrigerator at 5 ° C. for 24 hours to obtain a foamable oil-in-water emulsion.
得られた起泡性水中油型乳化物4kgとグラニュー糖400gをボールに入れ、カントーミキサー(関東混合機工業(株)製「CS型20」)を用いて、高速撹拌条件(380rpm)でホイップし、最大荷重が0.30Nのホイップドクリームを調製した。 Put 4 kg of the obtained foaming oil-in-water emulsion and 400 g of granulated sugar in a bowl, and whip them under high-speed stirring conditions (380 rpm) using a canto mixer (“CS type 20” manufactured by Kanto Mixer Industry Co., Ltd.). Then, a whipped cream having a maximum load of 0.30 N was prepared.
6号スポンジケーキにホイップドクリームをナッペの厚さ1~2mmに塗布し、上面にトッピングを施し、ホールケーキを作製した。作製したホールケーキを紙製装飾箱に梱包し、ビニール袋で密閉したものを-20℃の冷凍庫にて14日間保管し、冷凍ケーキを作製した。解凍前の冷凍ケーキにおけるホイップドクリームの表面にヒビ割れがないことを確認し、15℃にて12時間静置してケーキの解凍を実施した。得られた解凍後のケーキにおけるホイップドクリームの外観評価及び官能評価を行った。得られた評価結果は、表1に示した。 Whipped cream was applied to a No. 6 sponge cake to a thickness of 1 to 2 mm of nappe, and a topping was applied to the upper surface to prepare a whole cake. The prepared whole cake was packed in a paper decorative box, sealed in a plastic bag, and stored in a freezer at −20 ° C. for 14 days to prepare a frozen cake. It was confirmed that there were no cracks on the surface of the whipped cream in the frozen cake before thawing, and the cake was thawed by allowing it to stand at 15 ° C. for 12 hours. The appearance and sensory evaluation of the whipped cream in the obtained thawed cake were performed. The evaluation results obtained are shown in Table 1.
(実施例2及び3、比較例1及び2)起泡性水中油型乳化物及びホイップドクリームの作製
表1の配合に従い、実施例1において、ポリグリセリン脂肪酸エステルA1の配合量を変更し、添加水で全体量を調整した以外は、実施例1と同様にして起泡性水中油型乳化物を得た。得られた起泡性水中油型乳化物を用いて、実施例1と同様にして、ホイップドクリームを調製し、次いで冷凍ケーキを作製した。解凍前の冷凍ケーキにおけるホイップドクリームの表面の外観を確認し、実施例1と同様に、解凍後のケーキにおけるホイップドクリームの外観評価及び官能評価を行った。得られた評価結果は、表1に示した。(Examples 2 and 3, Comparative Examples 1 and 2) Preparation of foamable oil-in-water emulsion and whipped cream In Example 1, the amount of polyglycerin fatty acid ester A1 was changed according to the formulation shown in Table 1. A foamable oil-in-water emulsion was obtained in the same manner as in Example 1 except that the total amount was adjusted with the added water. Using the obtained foamable oil-in-water emulsion, a whipped cream was prepared in the same manner as in Example 1, and then a frozen cake was prepared. The appearance of the surface of the whipped cream in the frozen cake before thawing was confirmed, and the appearance evaluation and the sensory evaluation of the whipped cream in the cake after thawing were performed in the same manner as in Example 1. The evaluation results obtained are shown in Table 1.
表1から明らかなように、ポリグリセリン脂肪酸エステルA1の含有量が油相全体中0.1~1.0重量%の範囲にあるホイップドクリーム(実施例1~3)は、解凍前の冷凍ケーキにおけるホイップドクリームの表面のヒビ割れがなく、冷解凍後のケーキにおけるホイップドクリームのヒビ割れのなさ、風味、口溶け、コク、みずみずしさは、何れも良好であった。一方、ポリグリセリン脂肪酸エステルA1を添加しなかったホイップドクリーム(比較例1)は、冷凍後で解凍前のケーキにおけるホイップドクリームにヒビ割れがあって、トッピングに大きな亀裂が生じ、形状が崩壊しており、解凍後はさらにひどくなった。また解凍後においては、乳風味を殆んど感じず、食感もパサつきがあってみずみずしさがなかった。また、ポリグリセリン脂肪酸エステルA1の含有量が油相全体中1.47重量%のホイップドクリーム(比較例2)は、解凍後の口溶けが悪かった。 As is clear from Table 1, the whipped cream (Examples 1 to 3) in which the content of the polyglycerin fatty acid ester A1 is in the range of 0.1 to 1.0% by weight in the whole oil phase is frozen before thawing. There was no cracking on the surface of the whipped cream in the cake, and the cracking, flavor, melting in the mouth, richness, and freshness of the whipped cream in the cake after cold thawing were all good. On the other hand, in the whipped cream to which the polyglycerin fatty acid ester A1 was not added (Comparative Example 1), the whipped cream in the cake before thawing after freezing had cracks, large cracks were generated in the topping, and the shape collapsed. It became even worse after thawing. In addition, after thawing, almost no milk flavor was felt, and the texture was dry and not fresh. In addition, the whipped cream containing 1.47% by weight of the polyglycerin fatty acid ester A1 in the whole oil phase (Comparative Example 2) had poor melting in the mouth after thawing.
(実施例4)起泡性水中油型乳化物及びホイップドクリームの作製
表1の配合に従い、実施例2において、ポリグリセリン脂肪酸エステルA1を、構成脂肪酸全体中の飽和脂肪酸の含有量が99.9重量%、炭素数16及び炭素数18の飽和脂肪酸の合計含有量が19.9重量%、炭素数20以上の飽和脂肪酸の含有量が63.9重量%のポリグリセリン脂肪酸エステルA2に変更した以外は、実施例2と同様にして起泡性水中油型乳化物を得た。得られた起泡性水中油型乳化物を用いて、実施例2と同様にして、ホイップドクリームを調製し、次いで冷凍ケーキを作製した。解凍前の冷凍ケーキにおけるホイップドクリームの表面のヒビ割れがないことを確認し、実施例2と同様に、解凍後のケーキにおけるホイップドクリームの外観評価及び官能評価を行った。得られた評価結果は、表1に示した。(Example 4) Preparation of foamable oil-in-water emulsion and whipped cream According to the formulation shown in Table 1, in Example 2, the content of saturated fatty acid in the total constituent fatty acid of polyglycerin fatty acid ester A1 was 99. The total content of saturated fatty acids having 9% by weight, 16 carbon atoms and 18 carbon atoms was changed to 19.9% by weight, and the content of saturated fatty acids having 20 or more carbon atoms was changed to 63.9% by weight of polyglycerin fatty acid ester A2. A foamable oil-in-water emulsion was obtained in the same manner as in Example 2. Using the obtained foamable oil-in-water emulsion, a whipped cream was prepared in the same manner as in Example 2, and then a frozen cake was prepared. It was confirmed that there were no cracks on the surface of the whipped cream in the frozen cake before thawing, and the appearance and sensory evaluation of the whipped cream in the cake after thawing were performed in the same manner as in Example 2. The evaluation results obtained are shown in Table 1.
表1から明らかなように、ポリグリセリン脂肪酸エステルA2を添加したホイップドクリーム(実施例4)は、ポリグリセリン脂肪酸エステルA1を用いた実施例2の結果よりは劣るものの、比較例1の結果と比べると、冷解凍後のケーキにおけるホイップドクリームのヒビ割れのなさ、風味、口溶け、コク、みずみずしさは、何れも良好であった。 As is clear from Table 1, the whipped cream to which the polyglycerin fatty acid ester A2 was added (Example 4) was inferior to the result of Example 2 using the polyglycerin fatty acid ester A1, but was inferior to the result of Comparative Example 1. By comparison, the whipped cream in the cake after cold thawing had good cracklessness, flavor, melting in the mouth, richness, and freshness.
(実施例5~8)起泡性水中油型乳化物及びホイップドクリームの作製
表2の配合に従い、実施例2において、構成脂肪酸全体中に炭素数20以上の飽和脂肪酸を95.7重量%含有するデカグリセリンドデカベヘン酸エステル(ポリグリセリン脂肪酸エステルB)を、添加量を変えて配合し、その配合量に合わせて添加水で全体量を調整した以外は、実施例2と同様にして起泡性水中油型乳化物を得た。得られた起泡性水中油型乳化物を用いて、実施例2と同様にして、ホイップドクリームを調製し、次いで冷凍ケーキを作製した。解凍前の冷凍ケーキにおけるホイップドクリームの表面のヒビ割れがないことを確認し、実施例2と同様に、解凍後のケーキにおけるホイップドクリームの外観評価及び官能評価を行った。得られた評価結果は、表2に示した。(Examples 5 to 8) Preparation of foamable oil-in-water emulsion and whipped cream According to the formulation shown in Table 2, in Example 2, 95.7% by weight of saturated fatty acids having 20 or more carbon atoms were added to the total constituent fatty acids. The contained decaglycerin dedecavechenic acid ester (polyglycerin fatty acid ester B) was blended in different amounts, and the total amount was adjusted with the added water according to the blended amount. A foamy oil-in-water emulsion was obtained. Using the obtained foamable oil-in-water emulsion, a whipped cream was prepared in the same manner as in Example 2, and then a frozen cake was prepared. It was confirmed that there were no cracks on the surface of the whipped cream in the frozen cake before thawing, and the appearance and sensory evaluation of the whipped cream in the cake after thawing were performed in the same manner as in Example 2. The evaluation results obtained are shown in Table 2.
表2から明らかなように、デカグリセリンドデカベヘン酸エステル(ポリグリセリン脂肪酸エステルB)を油相全体中に0.05~1.0重量%の範囲で配合したホイップドクリーム(実施例5~8)は、冷解凍後のケーキにおけるホイップドクリームのヒビ割れのなさ、風味、口溶け、コク、みずみずしさは、何れも非常に良好であった。 As is clear from Table 2, a whipped cream containing decaglycerin dedecavehenic acid ester (polyglycerin fatty acid ester B) in the range of 0.05 to 1.0% by weight in the entire oil phase (Examples 5 to 8). ) Was very good in the cracklessness, flavor, melting in the mouth, richness, and freshness of the whipped cream in the cake after cold thawing.
(実施例9)起泡性水中油型乳化物及びホイップドクリームの作製
表2の配合に従い、実施例8において、デカグリセリンドデカベヘン酸エステル(ポリグリセリン脂肪酸エステルB)を、構成脂肪酸全体中に炭素数20以上の飽和脂肪酸を97.7重量%含有するテトラグリセリンヘキサベヘン酸エステル(ポリグリセリン脂肪酸エステルB)に変更した以外は、実施例8と同様にして起泡性水中油型乳化物を得た。得られた起泡性水中油型乳化物を用いて、実施例8と同様にして、ホイップドクリームを調製し、次いで冷凍ケーキを作製した。解凍前の冷凍ケーキにおけるホイップドクリームの表面のヒビ割れがないことを確認し、実施例8と同様に、解凍後のケーキにおけるホイップドクリームの外観評価及び官能評価を行った。得られた評価結果は、表2に示した。(Example 9) Preparation of foamable oil-in-water emulsion and whipped cream In Example 8, decaglycerin dedecavechenic acid ester (polyglycerin fatty acid ester B) was added to the whole constituent fatty acids according to the formulation shown in Table 2. A foamable oil-in-water emulsion was prepared in the same manner as in Example 8 except that the tetraglycerin hexabechenic acid ester (polyglycerin fatty acid ester B) containing 97.7% by weight of saturated fatty acid having 20 or more carbon atoms was changed. Obtained. Using the obtained foamable oil-in-water emulsion, whipped cream was prepared in the same manner as in Example 8, and then a frozen cake was prepared. It was confirmed that there were no cracks on the surface of the whipped cream in the frozen cake before thawing, and the appearance and sensory evaluation of the whipped cream in the cake after thawing were performed in the same manner as in Example 8. The evaluation results obtained are shown in Table 2.
表2から明らかなように、テトラグリセリンヘキサベヘン酸エステル(ポリグリセリン脂肪酸エステルB)を添加したホイップドクリーム(実施例9)は、実施例8のホイップドクリームと同様に、冷解凍後のケーキにおけるホイップドクリームのヒビ割れのなさ、風味、口溶け、コク、みずみずしさは、何れも非常に良好であった。 As is clear from Table 2, the whipped cream (Example 9) to which the tetraglycerin hexabechenic acid ester (polyglycerin fatty acid ester B) was added is a cake after cold thawing, similar to the whipped cream of Example 8. The whipped cream in the above was very good in terms of no cracking, flavor, melting in the mouth, richness, and freshness.
(比較例3~6) 起泡性水中油型乳化物及びホイップドクリームの作製
表2の配合に従い、実施例2において、油相部に溶解しているポリグリセリン脂肪酸エステルA1を、構成脂肪酸の70重量%以上がステアリン酸又はパルミチン酸のポリグリセリン脂肪酸エステルに変更し、これを水相部に溶解した以外は、実施例2と同様にして起泡性水中油型乳化物を得た。得られた起泡性水中油型乳化物を用いて、実施例2と同様にして、ホイップドクリームを調製し、次いで冷凍ケーキを作製した。解凍前の冷凍ケーキにおけるホイップドクリームの表面のヒビ割れがないことを確認し、実施例2と同様に、解凍後のケーキにおけるホイップドクリームの外観評価及び官能評価を行った。得られた評価結果は、表2に示した。(Comparative Examples 3 to 6) Preparation of foamable oil-in-water emulsion and whipped cream According to the formulation shown in Table 2, in Example 2, the polyglycerin fatty acid ester A1 dissolved in the oil phase portion was used as a constituent fatty acid. A foamable oil-in-water emulsion was obtained in the same manner as in Example 2 except that 70% by weight or more was changed to a polyglycerin fatty acid ester of stearic acid or palmitic acid and this was dissolved in the aqueous phase portion. Using the obtained foamable oil-in-water emulsion, a whipped cream was prepared in the same manner as in Example 2, and then a frozen cake was prepared. It was confirmed that there were no cracks on the surface of the whipped cream in the frozen cake before thawing, and the appearance and sensory evaluation of the whipped cream in the cake after thawing were performed in the same manner as in Example 2. The evaluation results obtained are shown in Table 2.
表2から明らかなように、ポリグリセリン脂肪酸エステルA1を配合した実施例2のホイップドクリームは、冷解凍後のケーキにおけるホイップドクリームのヒビ割れのなさ、風味、口溶け、コク、みずみずしさが何れも非常に良好であったのに対して、構成脂肪酸の70重量%以上がステアリン酸又はパルミチン酸のポリグリセリン脂肪酸エステルを配合したホイップドクリーム(比較例3~6)は、何れも冷解凍後のケーキにおけるホイップドクリームに大きなヒビ割れと亀裂が見られた。特に、ポリグリセリン脂肪酸エステルA1を配合した実施例2のホイップドクリームでは冷解凍後にも十分なコクが感じられたが、構成脂肪酸の70重量%以上がステアリン酸又はパルミチン酸のジグリセリン脂肪酸エステルを配合したホイップドクリーム(比較例3及び4)は、冷解凍後のコクも不足していた。また、ポリグリセリン脂肪酸エステルA1を配合した実施例2のホイップドクリームでは十分なみずみずしさが感じられたが、構成脂肪酸の70重量%以上がステアリン酸のテトラグリセリン脂肪酸エステルを配合したホイップドクリーム(比較例5及び6)は、冷解凍後の食感にパサつきがあり、みずみずしさにも欠けていた。 As is clear from Table 2, the whipped cream of Example 2 containing the polyglycerin fatty acid ester A1 has no cracks, flavor, melting in the mouth, richness, and freshness of the whipped cream in the cake after cold thawing. The whipped cream (Comparative Examples 3 to 6) containing a polyglycerin fatty acid ester in which 70% by weight or more of the constituent fatty acids were stearic acid or palmitic acid was very good, after cooling and thawing. Large cracks and cracks were found in the whipped cream in the cake. In particular, in the whipped cream of Example 2 containing the polyglycerin fatty acid ester A1, sufficient richness was felt even after cold thawing, but 70% by weight or more of the constituent fatty acids contained stearic acid or palmitic acid diglycerin fatty acid ester. The blended whipped cream (Comparative Examples 3 and 4) lacked the richness after cold thawing. In addition, the whipped cream of Example 2 containing the polyglycerin fatty acid ester A1 was found to have sufficient freshness, but the whipped cream containing a tetraglycerin fatty acid ester in which 70% by weight or more of the constituent fatty acids were stearic acid ( In Comparative Examples 5 and 6), the texture after cold thawing was dry and lacked in freshness.
(実施例10) 起泡性水中油型乳化物及びホイップドクリームの作製
表3の配合に従い、実施例2において、4種類の油脂の配合比率は同じで、合計の配合量を37.0重量%から18.5重量%に減らし、その代わりに乳脂肪(バターオイル)を18.5重量%配合した以外は、実施例2と同様にして起泡性水中油型乳化物を得た。得られた起泡性水中油型乳化物を用いて、実施例2と同様にして、ホイップドクリームを調製し、次いで冷凍ケーキを作製した。解凍前の冷凍ケーキにおけるホイップドクリームの表面のヒビ割れがないことを確認し、実施例2と同様に、解凍後のケーキにおけるホイップドクリームの外観評価及び官能評価を行った。得られた評価結果は、表3に示した。(Example 10) Preparation of foamable oil-in-water emulsion and whipped cream According to the formulation in Table 3, in Example 2, the compounding ratios of the four types of fats and oils are the same, and the total compounding amount is 37.0 weight. A foamable oil-in-water emulsion was obtained in the same manner as in Example 2 except that the content was reduced from% to 18.5% by weight and 18.5% by weight of milk fat (butter oil) was added instead. Using the obtained foamable oil-in-water emulsion, a whipped cream was prepared in the same manner as in Example 2, and then a frozen cake was prepared. It was confirmed that there were no cracks on the surface of the whipped cream in the frozen cake before thawing, and the appearance and sensory evaluation of the whipped cream in the cake after thawing were performed in the same manner as in Example 2. The evaluation results obtained are shown in Table 3.
(実施例11) 起泡性水中油型乳化物及びホイップドクリームの作製
表3の配合に従い、実施例2において、4種類の油脂の配合比率は同じで、合計の配合量を37.0重量%から18.5重量%に減らし、その代わりに乳脂肪が18.5重量%になるように生クリームを水相部に配合し、水分量を調整した以外は、実施例2と同様にして起泡性水中油型乳化物を得た。得られた起泡性水中油型乳化物を用いて、実施例2と同様にして、ホイップドクリームを調製し、次いで冷凍ケーキを作製した。解凍前の冷凍ケーキにおけるホイップドクリームの表面のヒビ割れがないことを確認し、実施例2と同様に、解凍後のケーキにおけるホイップドクリームの外観評価及び官能評価を行った。得られた評価結果は、表3に示した。(Example 11) Preparation of foamable oil-in-water emulsion and whipped cream According to the formulation in Table 3, in Example 2, the compounding ratios of the four types of fats and oils are the same, and the total compounding amount is 37.0 weight. The same as in Example 2 except that the amount of fresh cream was reduced from% to 18.5% by weight, and instead, fresh cream was added to the aqueous phase portion so that the milk fat was 18.5% by weight, and the water content was adjusted. A foamable oil-in-water emulsion was obtained. Using the obtained foamable oil-in-water emulsion, a whipped cream was prepared in the same manner as in Example 2, and then a frozen cake was prepared. It was confirmed that there were no cracks on the surface of the whipped cream in the frozen cake before thawing, and the appearance and sensory evaluation of the whipped cream in the cake after thawing were performed in the same manner as in Example 2. The evaluation results obtained are shown in Table 3.
表3から明らかなように、乳脂肪を配合したホイップドクリーム(実施例10及び11)は、冷解凍後のケーキにおけるホイップドクリームのヒビ割れのなさ、風味、口溶け、コク、みずみずしさが何れも極めて良好であった。特に乳脂肪を含む成分として生クリームを配合したホイップドクリーム(実施例11)の風味は最も優れていた。 As is clear from Table 3, the whipped cream containing milk fat (Examples 10 and 11) has no cracks, flavor, melting in the mouth, richness, and freshness of the whipped cream in the cake after cold thawing. Was also extremely good. In particular, the flavor of the whipped cream (Example 11) containing fresh cream as a component containing milk fat was the best.
(比較例7) 起泡性水中油型乳化物及びホイップドクリームの作製
表3の配合に従い、実施例2において、油脂の組成を、パーム核油3.70重量部、パーム中融点部分別油20.35重量部、及び、製造例1で得たエステル交換油脂12.95重量部に変更した以外は、実施例2と同様にして起泡性水中油型乳化物を得た。得られた起泡性水中油型乳化物を用いて、実施例2と同様にして、ホイップドクリームを調製し、次いで冷凍ケーキを作製した。解凍前の冷凍ケーキにおけるホイップドクリームの表面のヒビ割れがないことを確認し、実施例2と同様に、解凍後のケーキにおけるホイップドクリームの外観評価及び官能評価を行った。得られた評価結果は、表3に示した。(Comparative Example 7) Preparation of foamable oil-in-water emulsion and whipped cream According to the formulation in Table 3, in Example 2, the composition of the oil and fat was adjusted to 3.70 parts by weight of palm kernel oil and oil by melting point in palm. A foamable oil-in-water emulsion was obtained in the same manner as in Example 2 except that it was changed to 20.35 parts by weight and 12.95 parts by weight of the ester-exchanged oil and fat obtained in Production Example 1. Using the obtained foamable oil-in-water emulsion, a whipped cream was prepared in the same manner as in Example 2, and then a frozen cake was prepared. It was confirmed that there were no cracks on the surface of the whipped cream in the frozen cake before thawing, and the appearance and sensory evaluation of the whipped cream in the cake after thawing were performed in the same manner as in Example 2. The evaluation results obtained are shown in Table 3.
表3から明らかなように、エステル交換油脂を配合していないホイップドクリーム(実施例2)は、冷解凍後のケーキにおけるホイップドクリームの口溶けが良好で、コクが十分に感じられたのに対して、エステル交換油脂を配合したホイップドクリーム(比較例7)は、冷解凍後のケーキにおけるホイップドクリームの口溶けが悪く、コクが弱かった。 As is clear from Table 3, the whipped cream (Example 2) containing no ester-exchanged fats and oils had good melting in the mouth of the whipped cream in the cake after cold thawing, and the richness was sufficiently felt. On the other hand, the whipped cream containing the ester-exchanged fat and oil (Comparative Example 7) had poor melting in the mouth of the whipped cream in the cake after cold thawing and had a weak body.
Claims (7)
前記油脂全体中、ラウリン系油脂を3~50重量%と、S2Uを45~70重量%含むパーム系油脂を40~90重量%とを含有し、エステル交換油脂の含有量が1重量%未満であり、
前記油脂の構成脂肪酸全体中、トランス脂肪酸の含有量は1重量%未満で、飽和脂肪酸の含有量は47~65重量%であり、
ポリグリセリン脂肪酸エステルAの構成脂肪酸全体中、飽和脂肪酸の含有量は95~100重量%で、炭素数16及び炭素数18の飽和脂肪酸を6~25重量%と、炭素数20以上の飽和脂肪酸を55~85重量%とを含むポリグリセリン脂肪酸エステルAを、油相全体中0.1~1重量%含有し、
不飽和脂肪酸の含有量が乳化剤の構成脂肪酸全体中60~100重量%の乳化剤を、起泡性水中油型乳化油脂組成物全体中0.05~0.5重量%含有する、起泡性水中油型乳化油脂組成物。The content of oil and fat is 25 to 50% by weight and the water content is 45 to 70% by weight in the whole foamable oil-in-water emulsified oil and fat composition.
The total content of the transesterified fats and oils is less than 1% by weight, containing 3 to 50% by weight of lauric fats and oils and 40 to 90% by weight of palm-based fats and oils containing 45 to 70% by weight of S2U. can be,
The content of trans fatty acid is less than 1% by weight, and the content of saturated fatty acid is 47 to 65% by weight in the total constituent fatty acids of the fats and oils.
The content of saturated fatty acid is 95 to 100% by weight, 6 to 25% by weight of saturated fatty acid having 16 carbon atoms and 18 carbon atoms, and saturated fatty acid having 20 or more carbon atoms in the total constituent fatty acids of polyglycerin fatty acid ester A. Polyglycerin fatty acid ester A containing 55 to 85% by weight is contained in 0.1 to 1% by weight in the entire oil phase.
Emulsifying water containing 60 to 100% by weight of an emulsifier having an unsaturated fatty acid content of 60 to 100% by weight based on the constituent fatty acids of the emulsifier, and 0.05 to 0.5% by weight of the emulsifying oil-type emulsified oil-and-fat composition. Oil-type emulsified oil / fat composition.
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