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JP6787666B2 - Confectionery Bread kneading oil and fat composition and method for manufacturing baked products using it - Google Patents

Confectionery Bread kneading oil and fat composition and method for manufacturing baked products using it Download PDF

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JP6787666B2
JP6787666B2 JP2015257421A JP2015257421A JP6787666B2 JP 6787666 B2 JP6787666 B2 JP 6787666B2 JP 2015257421 A JP2015257421 A JP 2015257421A JP 2015257421 A JP2015257421 A JP 2015257421A JP 6787666 B2 JP6787666 B2 JP 6787666B2
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晶 太田
晶 太田
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Miyoshi Oil and Fat Co Ltd
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Description

本発明は、焼成品の生地への練り込みに使用される製菓製パン練り込み用油脂組成物とそれを用いた焼成品の製造方法に関する。 The present invention relates to a confectionery bakery kneading oil / fat composition used for kneading a baked product into a dough, and a method for producing a baked product using the same.

従来、製パンにおけるソフトさ、口溶け、ヒキのない食感については長く検討されてきた。ソフトさを得るための技術としては、酵素、乳化剤、または食品素材を使用すること、あるいは油脂組成物の配合を調整することなどが行われている(特許文献1〜5)。 Conventionally, the softness, melting in the mouth, and texture without cracks in bread making have been studied for a long time. As a technique for obtaining softness, an enzyme, an emulsifier, or a food material is used, or the composition of an oil or fat composition is adjusted (Patent Documents 1 to 5).

特許文献1には、ソフトで団子にならず、喉ごしの良いパン等を得ることを目的として、油中水型乳化物の水相中にトレハロースを配合することが提案されている。しかし、トレハロースはイーストに分解されないため、特有の甘みがパン等に付加され、特に食パンに使用した場合には風味を損なうおそれがある。 Patent Document 1 proposes to add trehalose to the aqueous phase of a water-in-oil emulsion for the purpose of obtaining bread or the like that is soft and does not form dumplings and has a good throat. However, since trehalose is not decomposed into yeast, a peculiar sweetness is added to bread and the like, and there is a risk of spoiling the flavor especially when used for bread.

特許文献2には、製品のソフト化、老化防止に加えて食感面でのくちゃつきを改善することを目的として、グルコースオキシダーゼとαアミラーゼを含有する製パン改良剤が提案されている。しかし、くちゃつきは軽減できるが、ヒキのない食感については十分な改善効果がみられていない。 Patent Document 2 proposes a bakery improving agent containing glucose oxidase and α-amylase for the purpose of improving the texture of the product in addition to softening the product and preventing aging. However, although the fluffiness can be reduced, a sufficient improvement effect has not been seen for the texture without fluff.

特許文献1、2などに提案されている、酵素、乳化剤、または食品素材を使用した改良剤は、製品表示上の制約や、最終製品の味に影響を与える等の問題があった。 The improver using an enzyme, an emulsifier, or a food material proposed in Patent Documents 1 and 2 has problems such as restrictions on product labeling and affecting the taste of the final product.

特許文献3には、製パンの作業性、ソフトさ、歯切れを改善することを目的として、酵素、乳化剤、食品素材を使用せず、油脂配合のみの観点から、油脂の結晶を調整した油脂組成物が提案されている。しかし、構成脂肪酸の全てが炭素数16以上で構成される3飽和トリグリセリドの含有量については言及されておらず、ソフトさやヒキのない食感を得る技術には更なる改善の余地があった。 Patent Document 3 describes a fat composition in which crystals of fats and oils are adjusted from the viewpoint of blending fats and oils without using enzymes, emulsifiers, or food materials for the purpose of improving the workability, softness, and crispness of bread making. Things have been proposed. However, the content of trisaturated triglyceride in which all of the constituent fatty acids are composed of 16 or more carbon atoms is not mentioned, and there is room for further improvement in the technique for obtaining a soft and texture-free texture.

特許文献4には、生地に練り込む際の作業性、泡立ち、低温領域での可塑性などの改善を図ることを目的として、1位と2位または2位と3位にパルミチン酸、3位または1位にオレイン酸が結合されたトリグリセリドPPOと、1位と3位にパルミチン酸、2位にオレイン酸が結合されたトリグリセリドPOPとの質量比(PPO/POP)、PPOおよびPOPの合計量であるP2Oの含有量などの油脂組成を特定範囲とすることが提案されている。しかし、PPO/POPの数値が低く、またはP2Oの量が少ないため、油脂組成全体を考慮すると結晶量が少ない配合となっている。そのため、パンが口中で団子になりやすく、くちゃつきのある食感となりやすい。 Patent Document 4 describes palmitic acid at the 1st and 2nd positions or the 2nd and 3rd positions with palmitic acid at the 3rd position or 3rd position for the purpose of improving workability, foaming, plasticity in a low temperature region, etc. when kneading into the dough. The mass ratio (PPO / POP) of triglyceride PPO in which oleic acid is bound at the 1st position and palmitic acid in the 1st and 3rd positions, and triglyceride POP in which oleic acid is bound at the 2nd position, and the total amount of PPO and POP. It has been proposed to set a specific range of oil and fat composition such as the content of a certain P2O. However, since the value of PPO / POP is low or the amount of P2O is small, the amount of crystals is small when considering the entire fat and oil composition. Therefore, the bread tends to become dumplings in the mouth and has a fluffy texture.

特許文献5には、クロワッサン、パイ、デニッシュなどのペストリー食品の製造に使用するのに適した広い温度域における可塑性、伸展性を有し、かつ、得られるペストリー食品の浮きが良好で、かつ口溶けなどの食感も良好な実質的にトランス酸を含有しないロールイン用可塑性油中水型乳化物を目的として、可塑性油中水型乳化物中、ラウリン系ハードバターを5〜50質量%、パーム油起源の非選択的エステル交換油脂3質量%以上、乳脂肪を1質量%以上含有し、油相のSFCが10℃で40%以上、35℃で10%以下であり実質的にトランス酸を含まないロールイン用可塑性油中水型乳化物が提案されている。しかし、PPO/POPの数値が高いため、他の油脂組成も併せて考慮すると、焼成品のソフトさに影響し、口溶け、すなわち口中でのダマになりやすさに問題がある。あるいは、実施例によってはP2Oの量が少ないため結晶量が少なく、パンがくちゃつきのある食感となりやすい。また、用途についても生地と重ねて層状に折り込むロールイン用で、生地中に練り込んで分散させる練り込み用途については記載されていない。 Patent Document 5 describes that the pastry food obtained has plasticity and extensibility in a wide temperature range suitable for use in the production of pastry foods such as croissants, pies, and denishes, and the obtained pastry foods have good floating and melt in the mouth. For the purpose of a water-in-water emulsion of plastic oil for roll-in, which has a good texture and does not contain substantially trans-acid, 5 to 50% by mass of laurin-based hard butter in the water-in-water emulsion of plastic oil, palm It contains 3% by mass or more of non-selective ester-exchanged fats and oils of oil origin, 1% by mass or more of milk fat, and the SFC of the oil phase is 40% or more at 10 ° C. and 10% or less at 35 ° C. A water-in-water emulsion for roll-in that does not contain it has been proposed. However, since the value of PPO / POP is high, when other fat and oil compositions are also taken into consideration, it affects the softness of the baked product, and there is a problem that it melts in the mouth, that is, it easily becomes lumpy in the mouth. Alternatively, depending on the embodiment, the amount of P2O is small, so the amount of crystals is small, and the bread tends to have a crumpled texture. Further, the use is also for roll-in, which is folded in a layer by overlapping with the dough, and the kneading use for kneading and dispersing in the dough is not described.

特開2002−153208号公報JP-A-2002-153208 特開平9−135656号公報Japanese Unexamined Patent Publication No. 9-135656 特開2003−210107公報JP-A-2003-210107 国際公開第2010/26928号International Publication No. 2010/26928 特開2008−193974号公報JP-A-2008-193974

特許文献3〜5に記載の技術は、油脂配合の観点からパンのソフトさなどの特性の改良を図るものであるが、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量などについては触れられておらず、またPPO/POPやP2Oなどの数値および油脂組成全体を併せて考慮すると、ソフトさ、口溶け、ヒキのない食感がいずれも良好な製菓製パンを得るには更なる改善の余地があった。 The techniques described in Patent Documents 3 to 5 are intended to improve characteristics such as the softness of bread from the viewpoint of blending fats and oils, but the content of trisaturated triglyceride in which all of the constituent fatty acids have 16 or more carbon atoms, etc. Is not mentioned, and considering the values of PPO / POP and P2O and the overall oil and fat composition, it is more difficult to obtain confectionery bread with good softness, melting in the mouth, and texture without scratches. There was room for improvement.

本発明は、以上の通りの事情に鑑みてなされたものであり、可塑性油脂として生地に練り込むことで、ソフトさ、口溶け、ヒキのない食感に優れた製菓製パンを得ることができる、製菓製パン練り込み用油脂組成物とそれを用いた焼成品の製造方法を提供することを課題としている。 The present invention has been made in view of the above circumstances, and by kneading it into a dough as a plastic fat or oil, it is possible to obtain a confectionery bakery having excellent softness, melting in the mouth, and a texture without scratches. An object of the present invention is to provide an oil / fat composition for kneading a confectionery bakery and a method for producing a baked product using the composition.

上記の課題を解決するために、本発明の製菓製パン練り込み用油脂組成物は、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量が15質量%以下である油脂のみを含有し、以下の(a)〜(d)の条件を満たすことを特徴としている:
(a)PPOとPOPとの質量比(PPO/POP)が1.0超2.2以下(PPOは、1位と2位または2位と3位にパルミチン酸、3位または1位にオレイン酸が結合されたトリグリセリドであり、POPは、1位と3位にパルミチン酸、2位にオレイン酸が結合されたトリグリセリドであり、Pはパルミチン酸、Oはオレイン酸を示す。);
(b)P2Oの含有量が油脂全量に対して6.5〜15.5質量%(P2Oの含有量は、PPOおよびPOPの合計量である。);
(c)構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量が油脂全量に対して0.1〜7.5質量%;および、
(d)トリグリセリドの2位に結合されたラウリン酸量が油脂全量に対して2.0〜25質量%。
In order to solve the above problems, the fat and oil composition for kneading confectionery and bakery of the present invention contains only fats and oils having a content of trisaturated triglyceride having 16 or more carbon atoms and 15% by mass or less. It is contained and is characterized by satisfying the following conditions (a) to (d):
(A) The mass ratio of PPO to POP (PPO / POP) is more than 1.0 and 2.2 or less (PPO is palmitic acid at the 1st and 2nd positions or 2nd and 3rd positions, and oleic acid at the 3rd or 1st position. It is an acid-bound triglyceride, POP is a triglyceride in which palmitic acid is bound at the 1- and 3-positions, and oleic acid is bound at the 2-position, P is palmitic acid, and O is oleic acid.);
(B) The content of P2O is 6.5 to 15.5% by mass based on the total amount of fats and oils (the content of P2O is the total amount of PPO and POP);
(C) The content of trisaturated triglyceride in which all of the constituent fatty acids have 16 or more carbon atoms is 0.1 to 7.5% by mass with respect to the total amount of fats and oils;
(D) The amount of lauric acid bound to the 2-position of triglyceride is 2.0 to 25% by mass with respect to the total amount of fats and oils.

本発明の焼成品の製造方法は、前記製菓製パン練り込み用油脂組成物を含有する可塑性油脂を生地に練り込み、この生地を焼成することを特徴としている。 The method for producing a baked product of the present invention is characterized in that a plastic fat or oil containing the fat or oil composition for kneading bread for confectionery is kneaded into a dough and the dough is baked.

本発明によれば、可塑性油脂として生地に練り込むことで、ソフトさ、口溶け、ヒキのない食感に優れた製菓製パンを得ることができる。 According to the present invention, by kneading into a dough as a plastic fat or oil, it is possible to obtain a confectionery bakery having excellent softness, melting in the mouth, and a texture without scratches.

以下の記述において、P2Oは、PPOおよびPOPを示す。PPOは、1位と2位または2位と3位にパルミチン酸、3位または1位にオレイン酸が結合されたトリグリセリドを示し、POPは、1位と3位にパルミチン酸、2位にオレイン酸が結合されたトリグリセリドを示し、Pはパルミチン酸、Oはオレイン酸を示す。LLLは、1位と2位と3位にラウリン酸が結合されたトリグリセリドを示し、MLLは、1位または3位にミリスチン酸、2位と3位または1位と2位にラウリン酸が結合されたトリグリセリドを示し、LMLは、1位と3位にラウリン酸、2位にミリスチン酸が結合されたトリグリセリドを示し、Lはラウリン酸、Mはミリスチン酸を示す。 In the following description, P2O refers to PPO and POP. PPO shows a triglyceride in which palmitic acid is bound at the 1st and 2nd positions or 2nd and 3rd positions, and oleic acid is bound at the 3rd or 1st position, and POP shows palmitic acid at the 1st and 3rd positions and oleic acid at the 2nd position. It represents an acid-bound triglyceride, where P is palmitic acid and O is oleic acid. LLL indicates triglyceride in which lauric acid is bound at the 1st, 2nd and 3rd positions, and MLL is myristic acid in the 1st or 3rd position or lauric acid in the 2nd and 3rd positions or 1st and 2nd positions. LML represents lauric acid at the 1st and 3rd positions, and myristic acid at the 2nd position, where L is lauric acid and M is myristic acid.

本明細書において「口溶け」とは、口中でのダマになりにくさを言う。「ヒキ」とは、焼成品を口中に含んだ際に、パン様の繋がりが残存する食感を言う。「パサつき」とは、パンを食べる際に、生地が乾燥してボソボソとしているように感じられ、咀嚼時に、飲み込みにくくなることを指す。 As used herein, the term "melting in the mouth" refers to the difficulty of becoming a lump in the mouth. "Hiki" refers to the texture in which a bread-like connection remains when the baked product is contained in the mouth. "Dry" means that when eating bread, the dough feels dry and lumpy, making it difficult to swallow when chewing.

以下に、本発明を詳細に説明する。 The present invention will be described in detail below.

本発明の製菓製パン練り込み用油脂組成物(A)は、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量が15質量%以下である油脂のみを含有し、(a)PPO/POP、(b)P2Oの含有量、(c)構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量、(d)トリグリセリドの2位に結合されたラウリン酸量を特定範囲としたことを特徴としている。このような油脂組成としたことにより、低融点であり、口に入れると油脂が素早く溶解する特性を持ち、かつ結晶量が適度にあることから、可塑性油脂(B)として生地に練り込むことで、ソフトさ、口溶け、ヒキのない食感に優れた製菓製パンを得ることができる。 The fat and oil composition (A) for kneading confectionery bread of the present invention contains only fats and oils in which all of the constituent fatty acids have 16 or more carbon atoms and the content of trisaturated triglyceride is 15% by mass or less, and (a) Specific range of PPO / POP, (b) P2O content, (c) content of trisaturated triglyceride in which all of the constituent fatty acids have 16 or more carbon atoms, and (d) amount of lauric acid bound to the 2-position of triglyceride. It is characterized by the fact that. With such a fat and oil composition, it has a low melting point, has a property that the fat and oil dissolves quickly when put in the mouth, and has an appropriate amount of crystals. Therefore, it can be kneaded into the dough as a plastic fat and oil (B). It is possible to obtain confectionery bakery with excellent softness, melting in the mouth, and texture without cracks.

また、このような特性を持つことから、本発明の製菓製パン練り込み用油脂組成物(A)を可塑性油脂(B)として生地に練り込んだ焼成品は、パサつき感がなく、トップのフレーバーリリースに優れている。また、本発明の製菓製パン練り込み用油脂組成物(A)を用いた可塑性油脂(B)は、10℃程度、例えば5〜10℃の低温における生地への分散性に優れている。 Further, since it has such characteristics, the baked product in which the oil / fat composition (A) for kneading bread of the present invention is kneaded into the dough as the plastic oil / fat (B) does not have a dry feeling and is the top. Excellent in flavor release. Further, the plastic fat (B) using the oil / fat composition (A) for kneading confectionery bread of the present invention is excellent in dispersibility in the dough at a low temperature of about 10 ° C., for example, 5 to 10 ° C.

1.油脂
本発明において、油脂中のトリグリセリドとは、1分子のグリセロールに3分子の脂肪酸がエステル結合した構造を有するものである。トリグリセリドの1位、2位、3位とは、脂肪酸が結合した位置を表す。なお、トリグリセリドの構成脂肪酸の略称として、S:飽和脂肪酸、U:不飽和脂肪酸、を用いる。
1. 1. Fats and oils In the present invention, the triglyceride in fats and oils has a structure in which one molecule of glycerol is ester-bonded with three molecules of fatty acids. The 1st, 2nd, and 3rd positions of triglyceride represent the positions where fatty acids are bound. As an abbreviation for the constituent fatty acids of triglyceride, S: saturated fatty acid and U: unsaturated fatty acid are used.

飽和脂肪酸Sは、油脂中に含まれるすべての飽和脂肪酸である。また、各トリグリセリド分子に結合している2つまたは3つの飽和脂肪酸Sは、同一の飽和脂肪酸であってもよいし、異なる飽和脂肪酸であってもよい。 Saturated fatty acid S is all saturated fatty acids contained in fats and oils. Further, the two or three saturated fatty acids S bound to each triglyceride molecule may be the same saturated fatty acid or different saturated fatty acids.

飽和脂肪酸Sとしては、特に限定されないが、例えば、酪酸(4)、カプロン酸(6)、カプリル酸(8)、カプリン酸(10)、ラウリン酸(12)、ミリスチン酸(14)、パルミチン酸(16)、ステアリン酸(18)、アラキジン酸(20)、ベヘン酸(22)、リグノセリン酸(24)などが挙げられる。なお、上記の数値表記は、脂肪酸の炭素数である。 The saturated fatty acid S is not particularly limited, but is, for example, butyric acid (4), caproic acid (6), caprylic acid (8), caproic acid (10), lauric acid (12), myristic acid (14), palmitic acid. (16), stearic acid (18), arachidic acid (20), behenic acid (22), lignoseric acid (24) and the like. The above numerical notation is the number of carbon atoms of the fatty acid.

不飽和脂肪酸Uは、油脂中に含まれるすべての不飽和脂肪酸である。また、各トリグリセリド分子に結合している2つまたは3つの不飽和脂肪酸Uは、同一の不飽和脂肪酸であってもよいし、異なる不飽和脂肪酸であってもよい。 Unsaturated fatty acid U is all unsaturated fatty acids contained in fats and oils. Further, the two or three unsaturated fatty acids U bound to each triglyceride molecule may be the same unsaturated fatty acid or different unsaturated fatty acids.

不飽和脂肪酸Uとしては、特に限定されないが、例えば、ミリストレイン酸(14:1)、パルミトレイン酸(16:1)、ヒラゴン酸(16:3)、オレイン酸(18:1)、リノール酸(18:2)、リノレン酸(18:3)、エイコセン酸(20:1)、エルカ酸(22:1)、セラコレイン酸(24:1)などが挙げられる。なお、上記不飽和脂肪酸についての括弧内の数値表記は、左側が脂肪酸の炭素数であり、右側が二重結合数を意味する。 The unsaturated fatty acid U is not particularly limited, but is, for example, myristoleic acid (14: 1), palmitoleic acid (16: 1), hiragonic acid (16: 3), oleic acid (18: 1), linoleic acid ( 18: 2), linolenic acid (18: 3), eicosenoic acid (20: 1), erucic acid (22: 1), ceracoleic acid (24: 1) and the like. In the numerical notation in parentheses for the unsaturated fatty acid, the left side means the carbon number of the fatty acid, and the right side means the number of double bonds.

本発明の製菓製パン練り込み用油脂組成物(A)に使用される油脂は、1位、2位、3位のすべてに飽和脂肪酸Sが結合した3飽和トリグリセリド(SSS)を含み、1分子のグリセロールに2分子の飽和脂肪酸Sと1分子の不飽和脂肪酸Uが結合した2飽和トリグリセリドとして、1位および3位に飽和脂肪酸Sが結合し、かつ2位に不飽和脂肪酸Uが結合した対称型トリグリセリド(SUS)と、1位と2位、または2位と3位に飽和脂肪酸Sが結合し、かつ3位または1位に不飽和脂肪酸Uが結合した非対称型トリグリセリド(SSU)とを含む。また、1分子のグリセロールに2分子の不飽和脂肪酸Uと1分子の飽和脂肪酸Sが結合した2不飽和トリグリセリド(UUS、USU)を含んでよく、1位、2位、3位のすべてに不飽和脂肪酸Uが結合した3不飽和トリグリセリド(UUU)を含んでよい。 The fat and oil used in the fat and oil composition (A) for kneading confectionery bread of the present invention contains trisaturated triglyceride (SSS) in which saturated fatty acid S is bound to all of the 1, 2, and 3 positions, and one molecule. As a di-saturated triglyceride in which two molecules of saturated fatty acid S and one molecule of unsaturated fatty acid U are bound to glycerol, saturated triglyceride S is bound to the 1st and 3rd positions, and unsaturated fatty acid U is bound to the 2nd position. Includes type triglyceride (SUS) and asymmetric triglyceride (SSU) in which saturated fatty acid S is bound at the 1st and 2nd positions, or 2nd and 3rd positions, and unsaturated fatty acid U is bound at the 3rd or 1st position. .. Further, it may contain two unsaturated triglycerides (UUS, USU) in which two unsaturated fatty acids U and one saturated fatty acid S are bound to one molecule of glycerol, and it is unsuitable for all of the 1, 2, and 3 positions. It may contain a triunsaturated triglyceride (UUU) to which the saturated fatty acid U is bound.

本発明の製菓製パン練り込み用油脂組成物(A)に使用される油脂としては、特に限定されないが、例えば、パーム油、パーム核油、ヤシ油、菜種油、大豆油、綿実油、ヒマワリ油、米油、サフラワー油、オリーブ油、ゴマ油、魚油、シア脂、サル脂、イリッペ脂、カカオ脂、豚脂(ラード)、牛脂、乳脂、それらの分別油またはそれらの加工油(硬化およびエステル交換反応のうち1つ以上の処理がなされたもの)などが挙げられる。本発明の製菓製パン練り込み用油脂組成物(A)における、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量が15質量%以下である油脂のみを含有すること、および(a)PPO/POP、(b)P2Oの含有量、(c)構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量、(d)トリグリセリドの2位に結合されたラウリン酸量を満たすために、これらの油脂は、2種以上を併用することが好ましい。 The fat and oil used in the fat and oil composition (A) for kneading confectionery bread of the present invention is not particularly limited, and for example, palm oil, palm kernel oil, coconut oil, rapeseed oil, soybean oil, cottonseed oil, sunflower oil, etc. Rice oil, safflower oil, olive oil, sesame oil, fish oil, shea butter, monkey fat, ilippe fat, cacao fat, pork fat (lard), beef tallow, milk fat, their fractionated oil or their processed oil (hardening and ester exchange reaction) Of these, one or more of them have been processed). In the oil / fat composition (A) for kneading confectionery bread of the present invention, all of the constituent fatty acids contain only the oil / fat having a content of trisaturated triglyceride having 16 or more carbon atoms and 15% by mass or less, and ( a) PPO / POP, (b) P2O content, (c) content of trisaturated triglyceride in which all of the constituent fatty acids have 16 or more carbon atoms, and (d) amount of lauric acid bound to the 2-position of triglyceride. In order to satisfy these fats and oils, it is preferable to use two or more kinds in combination.

2.製菓製パン練り込み用油脂組成物(A)
本発明の製菓製パン練り込み用油脂組成物(A)は、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量が15質量%以下である油脂のみを含有する。このような油脂のみを含有することで、低融点であり、口に入れると油脂が素早く溶解する特性を持ち、かつ結晶量が適度にあることから、本発明の製菓製パン練り込み用油脂組成物(A)における油脂組成の条件(a)〜(d)と相俟って、可塑性油脂(B)として生地に練り込むことで、ソフトさ、口溶け、ヒキのない食感に優れた製菓製パンを得ることができる。このような点を考慮すると、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量が12質量%以下である油脂のみを含有することが好ましい。
2. Oil and fat composition for kneading confectionery bread (A)
The fat and oil composition (A) for kneading confectionery and bread of the present invention contains only fats and oils in which all of the constituent fatty acids have 16 or more carbon atoms and the content of trisaturated triglyceride is 15% by mass or less. By containing only such fats and oils, it has a low melting point, has the property of quickly dissolving fats and oils when put in the mouth, and has an appropriate amount of crystals. Therefore, the fats and oils composition for kneading confectionery bread of the present invention. In combination with the conditions (a) to (d) of the oil and fat composition in the product (A), by kneading it into the dough as a plastic oil and fat (B), it is made into a confectionery product that is excellent in softness, melting in the mouth, and texture without scratches. You can get bread. Considering these points, it is preferable that all of the constituent fatty acids contain only fats and oils having a content of trisaturated triglyceride having 16 or more carbon atoms and 12% by mass or less.

(a)本発明の製菓製パン練り込み用油脂組成物(A)は、PPOとPOPとの質量比(PPO/POP)が1.0超2.2以下である。この範囲内であると、トリグリセリドの対称性が良く、本発明の製菓製パン練り込み用油脂組成物(A)における油脂配合および油脂組成の条件と相俟って、可塑性油脂(B)として生地に練り込むことで、ソフトさ、口溶け、ヒキのない食感に優れた製菓製パンを得ることができ、特に焼成品のソフトさが良好で、口溶けも良好である。 (A) The oil / fat composition (A) for kneading confectionery bread of the present invention has a mass ratio (PPO / POP) of PPO to POP of more than 1.0 and 2.2 or less. Within this range, the symmetry of the triglyceride is good, and in combination with the conditions of the fat and oil composition and the fat and oil composition in the fat and oil composition (A) for kneading bread of the present invention, the dough is used as the plastic fat and oil (B). By kneading into, it is possible to obtain a confectionery bakery having excellent softness, melting in the mouth, and a texture without scratches, and the baked product is particularly soft and melts in the mouth.

(b)本発明の製菓製パン練り込み用油脂組成物(A)は、P2Oの含有量が油脂全量に対して6.5〜15.5質量%である。P2Oの含有量をこの範囲内とすることで、結晶量が適度なものとなり、本発明の製菓製パン練り込み用油脂組成物(A)における油脂配合および油脂組成の条件と相俟って、可塑性油脂(B)として生地に練り込むことで、ソフトさ、口溶け、ヒキのない食感に優れた製菓製パンを得ることができ、特にヒキのない食感が良好である。 (B) The oil / fat composition (A) for kneading confectionery bread of the present invention has a P2O content of 6.5 to 15.5% by mass with respect to the total amount of the oil / fat. By setting the P2O content within this range, the crystal content becomes appropriate, and in combination with the conditions of the fat and oil composition and the fat and oil composition in the fat and oil composition (A) for kneading bread for confectionery of the present invention, By kneading it into the dough as a plastic fat (B), it is possible to obtain a confectionery bakery having excellent softness, melting in the mouth, and a texture without scratches, and the texture without scratches is particularly good.

(c)本発明の製菓製パン練り込み用油脂組成物(A)は、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量が油脂全量に対して0.1〜7.5質量%である。この範囲内とすることで、低融点であり、口に入れると油脂が素早く溶解する特性を持ち、かつ結晶量が適度にあることから、本発明の製菓製パン練り込み用油脂組成物(A)における油脂配合および油脂組成の条件と相俟って、可塑性油脂(B)として生地に練り込むことで、ソフトさ、口溶け、ヒキのない食感に優れた製菓製パンを得ることができる。また、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量は、生地への分散性が向上する点から、油脂全量に対して1.0〜6.0質量%が好ましい。 (C) In the oil / fat composition (A) for kneading confectionery bread of the present invention, the content of trisaturated triglyceride in which all of the constituent fatty acids have 16 or more carbon atoms is 0.1 to 7.5 with respect to the total amount of the oil / fat. It is mass%. Within this range, the melting point is low, the fat and oil dissolves quickly when put in the mouth, and the amount of crystals is appropriate. Therefore, the fat and oil composition for kneading confectionery bread of the present invention (A). ), In combination with the conditions of the fat and oil composition and the fat and oil composition, by kneading the dough as the plastic fat and oil (B), it is possible to obtain a confectionery bakery having excellent softness, melting in the mouth, and a texture without scratches. The content of trisaturated triglyceride in which all of the constituent fatty acids have 16 or more carbon atoms is preferably 1.0 to 6.0% by mass with respect to the total amount of fats and oils from the viewpoint of improving dispersibility in the dough.

(d)本発明の製菓製パン練り込み用油脂組成物(A)は、トリグリセリドの2位に結合されたラウリン酸量が油脂全量に対して2.0〜25質量%である。2位にラウリン酸が結合されたトリグリセリドは、ラウリン酸の分子量が小さいことに起因し、分子運動がおこりやすい。そのため固化後に油脂中で、分子同士が離れやすい状態となり、その結果として、本発明の製菓製パン練り込み用油脂組成物(A)における油脂配合および油脂組成の条件と相俟って、可塑性油脂(B)として生地に練り込むことで、口溶け、ソフトさが良好となる。また、低温下での良好な物性を得ることができ、10℃程度の低温における生地への分散性に優れている。 (D) In the oil / fat composition (A) for kneading confectionery bread of the present invention, the amount of lauric acid bound to the 2-position of triglyceride is 2.0 to 25% by mass with respect to the total amount of oil / fat. Triglycerides in which lauric acid is bound at the 2-position are prone to molecular motion due to the small molecular weight of lauric acid. Therefore, after solidification, the molecules are easily separated from each other in the fat and oil, and as a result, the plastic fat and oil are combined with the conditions of the fat and oil composition and the fat and oil composition in the fat and oil composition (A) for kneading bread for confectionery of the present invention. By kneading it into the dough as (B), it melts in the mouth and has good softness. In addition, good physical properties can be obtained at a low temperature, and the dispersibility in the dough at a low temperature of about 10 ° C. is excellent.

2位にラウリン酸が結合されたトリグリセリドの1、3位の構成脂肪酸は、飽和脂肪酸または不飽和脂肪酸のいずれであってもよい。2位がラウリン酸であるトリグリセリドとしては、例えば、SLS型トリグリセリド、SLU型トリグリセリド(位置異性体も含む)、ULU型トリグリセリドなどが挙げられるが、特に限定されない。なお、「L」とは、トリグリセリドの構成脂肪酸であるラウリン酸を意味する。本発明の効果を得る点から、2位にラウリン酸が結合されたトリグリセリドの1位または3位の構成脂肪酸が飽和脂肪酸である場合、炭素数4〜20の飽和脂肪酸であることが好ましい。2位にラウリン酸が結合されたトリグリセリドの1位または3位の構成脂肪酸が不飽和脂肪酸である場合、炭素数16〜18の不飽和脂肪酸(パルミトレイン酸、オレイン酸、リノール酸、リノレン酸など)であることが好ましい。2位にラウリン酸が結合されたトリグリセリドの1位または3位の構成脂肪酸が飽和脂肪酸と不飽和脂肪酸である場合、上述の飽和脂肪酸(炭素数4〜20の飽和脂肪酸)と不飽和脂肪酸(炭素数16〜18の不飽和脂肪酸)であることが好ましい。 The constituent fatty acids at the 1st and 3rd positions of the triglyceride in which lauric acid is bonded at the 2-position may be either a saturated fatty acid or an unsaturated fatty acid. Examples of the triglyceride in which the 2-position is lauric acid include, but are not limited to, SLS-type triglyceride, SLU-type triglyceride (including position isomers), and ULU-type triglyceride. In addition, "L" means lauric acid which is a constituent fatty acid of triglyceride. From the viewpoint of obtaining the effect of the present invention, when the constituent fatty acid at the 1-position or the 3-position of the triglyceride in which lauric acid is bonded at the 2-position is a saturated fatty acid, it is preferably a saturated fatty acid having 4 to 20 carbon atoms. When the constituent fatty acid at the 1st or 3rd position of the triglyceride in which lauric acid is bound at the 2nd position is an unsaturated fatty acid, an unsaturated fatty acid having 16 to 18 carbon atoms (palmitoleic acid, oleic acid, linoleic acid, linolenic acid, etc.) Is preferable. When the constituent fatty acids at the 1- or 3-position of the triglyceride in which lauric acid is bound at the 2-position are saturated fatty acids and unsaturated fatty acids, the above-mentioned saturated fatty acids (saturated fatty acids having 4 to 20 carbon atoms) and unsaturated fatty acids (carbons) It is preferably an unsaturated fatty acid of number 16-18).

本発明の製菓製パン練り込み用油脂組成物(A)は、LLL、MLL、およびLMLの合計量が油脂全量に対して1.5〜7質量%であることが好ましい。LLL、MLL、およびLMLの合計量をこの範囲内とすることで、口溶けとソフトさのバランスが良好となり、口溶けが良くかつソフトさが良好となる。すなわち、飽和脂肪酸の中でもLLLやMLL、LMLといったトリグリセリドを含有することで、口溶けとソフトさのバランスが取れ、従ってフレーバーリリースが良好な製菓製パンを得ることができる。 In the oil / fat composition (A) for kneading confectionery bread of the present invention, the total amount of LLL, MLL, and LML is preferably 1.5 to 7% by mass with respect to the total amount of the oil / fat. By setting the total amount of LLL, MLL, and LML within this range, the balance between melting in the mouth and softness becomes good, and the melting in the mouth becomes good and the softness becomes good. That is, by containing triglycerides such as LLL, MLL, and LML among saturated fatty acids, it is possible to obtain a confectionery bakery that has a good balance between melting in the mouth and softness, and therefore has a good flavor release.

本発明の製菓製パン練り込み用油脂組成物(A)は、35℃における固体脂含量が8質量%以下の油脂のみを含有することが好ましい。このような油脂のみを含有することで、低融点であり、口に入れると油脂が素早く溶解する特性を持つことから、本発明の製菓製パン練り込み用油脂組成物(A)における油脂配合および油脂組成の条件と相俟って、可塑性油脂(B)として生地に練り込むことで、ソフトさ、口溶け、ヒキのない食感に優れた製菓製パンを得ることができる。特にヒキのない食感が良好となる。また、作業性の面では、10℃程度の低温における生地への分散性が良好となる。 The fat and oil composition (A) for kneading confectionery bread of the present invention preferably contains only fats and oils having a solid fat content of 8% by mass or less at 35 ° C. By containing only such fats and oils, the melting point is low and the fats and oils dissolve quickly when put in the mouth. Therefore, the fats and oils blended in the fats and oils composition (A) for kneading bread for confectionery of the present invention and By kneading it into the dough as a plastic fat (B) in combination with the condition of the fat composition, it is possible to obtain a confectionery bakery having excellent softness, melting in the mouth, and a texture without scratches. In particular, the texture without cracks is good. Further, in terms of workability, the dispersibility in the dough at a low temperature of about 10 ° C. is good.

本発明の製菓製パン練り込み用油脂組成物は、ヨウ素価が50〜60のエステル交換油脂を含有することが好ましい。このようなエステル交換油脂を含有することで、低融点であり、口に入れると油脂が素早く溶解する特性を持つことから、本発明の製菓製パン練り込み用油脂組成物(A)における油脂配合および油脂組成の条件と相俟って、後述の可塑性油脂(B)として生地に練り込むことで、ソフトさ、口溶け、ヒキのない食感に優れた製菓製パンを得ることができる。特にヒキのない食感が良好となる。 The oil / fat composition for kneading confectionery bread of the present invention preferably contains a transesterified oil / fat having an iodine value of 50 to 60. By containing such transesterified fats and oils, the melting point is low and the fats and oils dissolve quickly when put in the mouth. Therefore, the fats and oils compounded in the fats and oils composition (A) for kneading bread for confectionery of the present invention. In combination with the conditions of the oil and fat composition, by kneading the dough as the plastic oil and fat (B) described later, it is possible to obtain a confectionery bakery having excellent softness, melting in the mouth, and a texture without scratches. In particular, the texture without cracks is good.

ヨウ素価が50〜60のエステル交換油脂としては、パーム系油脂を原料に含むエステル交換油脂が好ましい。パーム系油脂としては、例えば、パーム油、パーム分別油、これらの硬化油などが挙げられ、これらはエステル交換油脂の原料として1種単独で使用してもよく2種以上を併用してもよい。パーム分別油としては、硬質部、軟質部、中融点部などを用いることができる。 As the transesterified fats and oils having an iodine value of 50 to 60, transesterified fats and oils containing palm-based fats and oils as raw materials are preferable. Examples of palm-based fats and oils include palm oil, fractionated palm oil, and hydrogenated oils thereof, and these may be used alone or in combination of two or more as raw materials for transesterified fats and oils. .. As the palm fractionating oil, a hard portion, a soft portion, a medium melting point portion and the like can be used.

上記エステル交換油脂のエステル交換反応には、エステル交換触媒として化学触媒や酵素触媒が用いられる。化学触媒としてはナトリウムメチラートや水酸化ナトリウムなどが用いられ、酵素触媒としてはリパーゼなどが用いられる。リパーゼとしてはアスペルギルス属、アルカリゲネス属などのリパーゼが挙げられ、イオン交換樹脂、ケイ藻土、セラミックなどの担体上に固定し固定化したものを用いても、粉末の形態として用いても良い。また位置選択性のあるリパーゼ、位置選択性のないリパーゼのいずれも用いることができるが、位置選択性のないリパーゼを用いることが好ましい。 A chemical catalyst or an enzyme catalyst is used as the transesterification catalyst in the transesterification reaction of the transesterification fats and oils. Sodium methylate, sodium hydroxide, or the like is used as the chemical catalyst, and lipase or the like is used as the enzyme catalyst. Examples of the lipase include lipases of the genus Aspergillus and the genus Alcaligenes, which may be fixed on a carrier such as an ion exchange resin, diatomaceous earth, or ceramic, or may be used in the form of powder. Further, both a lipase having regioselectivity and a lipase having no regioselectivity can be used, but it is preferable to use a lipase having no regioselectivity.

エステル交換反応に化学触媒を用いる場合、触媒を油脂質量の0.05〜0.15質量%添加し、減圧下で80〜120℃に加熱し、0.5〜1.0時間攪拌することでエステル交換反応が平衡状態となって完了し、エステル交換油脂を得ることができる。また酵素触媒を用いる場合、リパーゼなどの酵素触媒を油脂質量の0.01〜10質量%添加し、40〜80℃でエステル交換反応を行うことによりエステル交換反応が平衡状態となって完了し、エステル交換油脂を得ることができる。エステル交換反応はカラムによる連続反応、バッチ反応のいずれの方法で行うこともできる。エステル交換反応後、必要に応じて脱色、脱臭などの精製を行うことができる。 When a chemical catalyst is used for the transesterification reaction, the catalyst is added in an amount of 0.05 to 0.15% by mass based on the amount of oil and lipid, heated to 80 to 120 ° C. under reduced pressure, and stirred for 0.5 to 1.0 hours. The transesterification reaction is completed in an equilibrium state, and the transesterification fat and oil can be obtained. When an enzyme catalyst is used, the transesterification reaction is completed in an equilibrium state by adding 0.01 to 10% by mass of an enzyme catalyst such as lipase and performing a transesterification reaction at 40 to 80 ° C. Transesterified fats and oils can be obtained. The transesterification reaction can be carried out by either a continuous column reaction or a batch reaction. After the transesterification reaction, purification such as decolorization and deodorization can be performed as needed.

本発明の製菓製パン練り込み用油脂組成物(A)は、油脂の構成脂肪酸としてトランス酸を含んでもよく、含まなくてもよいが、トランス酸の摂取量が多くなると、人体に摂取された際のLDLコレステロールが増加しうる。よって、これを抑制しやすい点から、本発明においては、油脂の構成脂肪酸中のトランス酸の含有量は、油脂の構成脂肪酸全体の質量に対して10質量%未満であることが好ましく、5質量%未満であることがより好ましく、3質量%未満であることが最も好ましい。 The fat and oil composition (A) for kneading confectionery bread of the present invention may or may not contain trans acid as a constituent fatty acid of fat and oil, but when the intake of trans acid is large, it is ingested by the human body. LDL cholesterol can be increased. Therefore, from the viewpoint of easily suppressing this, in the present invention, the content of trans acid in the constituent fatty acids of the fat and oil is preferably less than 10% by mass with respect to the total mass of the constituent fatty acids of the fat and oil, and is 5% by mass. It is more preferably less than%, and most preferably less than 3% by mass.

2.可塑性油脂(B)
本発明の製菓製パン練り込み用油脂組成物(A)は、油相中に本発明の製菓製パン練り込み用油脂組成物(A)を含有する可塑性油脂(B)を調製し、これを原材料とする生地を用いて焼成品を得ることができる。
2. Thermoplastic fat (B)
In the oil / fat composition (A) for kneading confectionery bread of the present invention, a plastic oil / fat (B) containing the oil / fat composition (A) for kneading confectionery bread of the present invention in the oil phase is prepared, and this is used. A baked product can be obtained by using the dough as a raw material.

この可塑性油脂(B)は、油相中に本発明の製菓製パン練り込み用油脂組成物(A)を含有するものである。 This plastic fat (B) contains the fat composition (A) for kneading confectionery bread of the present invention in the oil phase.

可塑性油脂(B)における本発明の製菓製パン練り込み用油脂組成物(A)の含有量としては、好ましくは50〜100質量%、より好ましくは70〜100質量%である。 The content of the oil / fat composition (A) for kneading confectionery bread of the present invention in the plastic oil / fat (B) is preferably 50 to 100% by mass, more preferably 70 to 100% by mass.

この可塑性油脂(B)は、水相を実質的に含有しない形態と、水相を含有する形態をとることができる。水相を含有する形態としては油中水型、水中油型、油中水中油型、水中油中水型が挙げられ、油相の含有量は、好ましくは60〜99.4質量%、より好ましくは65〜98質量%であり、水相の含有量は、好ましくは0.6〜40質量%、より好ましくは2〜35質量%である。水相を含有する形態としては油中水型が好ましく、例えばマーガリンが挙げられる。 The plastic fat (B) can take a form in which the aqueous phase is substantially not contained and a form in which the aqueous phase is contained. Examples of the form containing the aqueous phase include water-in-oil type, oil-in-water type, oil-in-oil-in-oil type, and water-in-oil-in-water type, and the content of the oil phase is preferably 60 to 99.4% by mass. It is preferably 65 to 98% by mass, and the content of the aqueous phase is preferably 0.6 to 40% by mass, more preferably 2 to 35% by mass. The water-in-oil type is preferable as the form containing an aqueous phase, and examples thereof include margarine.

また水相を実質的に含有しない形態としてはショートニングが挙げられる。ここで「実質的に含有しない」とは日本農林規格のショートニングに該当する、水分(揮発分を含む。)の含有量が0.5質量%以下のことである。 Moreover, shortening is mentioned as a form which does not substantially contain an aqueous phase. Here, "substantially free" means that the content of water (including volatile matter), which corresponds to the shortening of the Japanese Agricultural Standard, is 0.5% by mass or less.

この可塑性油脂(B)には、水以外に、従来の公知の成分を含んでもよい。公知の成分としては、特に限定されないが、例えば、乳、乳製品、蛋白質、糖質、塩類、酸味料、pH調整剤、抗酸化剤、香辛料、着色成分、フレーバー、乳化剤、酒類、酵素、粉末油脂などが挙げられる。乳としては、牛乳などが挙げられる。乳製品としては、脱脂乳、生クリーム、チーズ(ナチュラルチーズ、プロセスチーズなど)、発酵乳、濃縮乳、脱脂濃縮乳、無糖れん乳、加糖れん乳、無糖脱脂れん乳、加糖脱脂れん乳、全脂粉乳、脱脂粉乳、クリームパウダー、ホエイパウダー、蛋白濃縮ホエイパウダー、ホエイ蛋白コンセントレート(WPC)、ホエイ蛋白アイソレート(WPI)、バターミルクパウダー、トータルミルクプロテイン、カゼインナトリウム、カゼインカリウムなどが挙げられる。蛋白質としては、大豆蛋白、エンドウ豆蛋白、小麦蛋白などの植物蛋白などが挙げられる。糖質としては、単糖(グルコース、フルクトース、ガラクトース、マンノースなど)、二糖類(ラクトース、スクロース、マルトース、トレハロースなど)、オリゴ糖、糖アルコール、ステビア、アスパルテームなどの甘味料、デンプン、デンプン分解物、多糖類などが挙げられる、抗酸化剤としては、L−アスコルビン酸、L−アスコルビン酸誘導体、トコフェロール、トコトリエノール、リグナン、ユビキノン類、キサンチン類、オリザノール、植物ステロール、カテキン類、ポリフェノール類、茶抽出物などが挙げられる。香辛料としては、カプサイシン、アネトール、オイゲノール、シネオール、ジンゲロンなどが挙げられる。着色成分としては、カロテン、アナトー、アスタキサンチンなどが挙げられる。フレーバーとしては、バターフレーバー、ミルクフレーバーなどが挙げられる。乳化剤としては、レシチン、グリセリン脂肪酸エステル、有機酸グリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、プロピレングリコール脂肪酸エステル、ステアロイル乳酸カルシウム、ステアロイル乳酸ナトリウム、ポリオキシエチレンソルビタン脂肪酸エステルなどが挙げられる。 In addition to water, the plastic fat (B) may contain conventionally known components. Known ingredients are not particularly limited, but are, for example, milk, dairy products, proteins, sugars, salts, acidulants, pH adjusters, antioxidants, spices, coloring ingredients, flavors, emulsifiers, alcoholic beverages, enzymes, powders. Examples include fats and oils. Examples of milk include milk. Dairy products include defatted milk, fresh cream, cheese (natural cheese, process cheese, etc.), fermented milk, concentrated milk, defatted concentrated milk, unsweetened milk, sweetened milk, unsweetened defatted milk, sweetened defatted milk. , Full-fat milk powder, non-fat milk powder, cream powder, whey powder, protein-concentrated whey powder, whey protein concentrate (WPC), whey protein isolate (WPI), butter milk powder, total milk protein, sodium caseinate, potassium casein, etc. Can be mentioned. Examples of the protein include plant proteins such as soybean protein, pea protein, and wheat protein. Carbohydrates include monosaccharides (glucose, fructose, galactose, mannose, etc.), disaccharides (lactoose, sucrose, maltose, trehalose, etc.), oligosaccharides, sugar alcohols, stevia, sweeteners such as aspartame, starch, starch decomposition products. , Polysaccharides, etc. Examples of antioxidants include L-ascorbic acid, L-ascorbic acid derivative, tocopherol, tocotrienol, lignan, ubiquinones, xanthins, oryzanol, plant starch, catechins, polyphenols, tea extraction. Things can be mentioned. Examples of spices include capsaicin, anethole, eugenol, cineole, zingerone and the like. Examples of the coloring component include carotene, annatto, and astaxanthin. Examples of flavors include butter flavor and milk flavor. As emulsifiers, lecithin, glycerin fatty acid ester, organic acid glycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, polyglycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester, propylene glycol fatty acid ester, stearoyl calcium lactate, sodium stearoyl lactate, Examples thereof include polyoxyethylene sorbitan fatty acid ester.

この可塑性油脂(B)は、公知の方法により製造することができる。例えば水相を含有する形態のものは、本発明の製菓製パン練り込み用油脂組成物(A)を含む油相と水相とを適宜に加熱し混合して乳化した後、コンビネーター、パーフェクター、ボテーター、ネクサスなどの冷却混合機により急冷捏和し得ることができる。水相を含有しない形態のものは、本発明の製菓製パン練り込み用油脂組成物(A)を含む油相を加熱した後、コンビネーター、パーフェクター、ボテーター、ネクサスなどの冷却混合機により急冷捏和し得ることができる。冷却混合機において、必要に応じて窒素ガスなどの不活性ガスを吹き込むこともできる。また急冷捏和後に熟成(テンパリング)してもよい。 This plastic fat (B) can be produced by a known method. For example, in the form containing an aqueous phase, the oil phase containing the oil / fat composition (A) for kneading confectionery bread of the present invention and the aqueous phase are appropriately heated, mixed and emulsified, and then a combinator and perfect. It can be rapidly cooled and kneaded by a cooling mixer such as a tar, a botator, or a nexus. In the form containing no aqueous phase, the oil phase containing the oil / fat composition (A) for kneading confectionery bread of the present invention is heated and then rapidly cooled by a cooling mixer such as a combinator, a perfector, a botator, or a nexus. It can be reconciled. In the cooling mixer, an inert gas such as nitrogen gas can be blown as needed. Further, it may be aged (tempered) after quenching and kneading.

3.生地および焼成品
本発明の製菓製パン練り込み用油脂組成物(A)は、可塑性油脂(B)としてパンや菓子などの焼成品の生地に練り込んで使用することができる。可塑性油脂(B)を含有する生地を焼成することによってパンや菓子などの焼成品が得られる。生地への可塑性油脂(B)の練り込みや、焼成は、例えば公知の条件および方法に従って行うことができる。
3. 3. Dough and baked product The oil / fat composition (A) for kneading confectionery bread of the present invention can be used as a plastic oil / fat (B) by kneading it into the dough of a baked product such as bread or confectionery. By baking the dough containing the thermoplastic fat (B), baked products such as bread and confectionery can be obtained. The plastic fat (B) can be kneaded into the dough and baked according to, for example, known conditions and methods.

生地は穀粉を主成分とし、穀粉としては、通常、焼成品の生地に配合されるものであれば、特に限定されないが、例えば、小麦粉(強力粉、中力粉、薄力粉など)、大麦粉、米粉、とうもろこし粉、ライ麦粉、そば粉、大豆粉などが挙げられる。 The dough is mainly composed of flour, and the flour is not particularly limited as long as it is usually blended in the dough of a baked product, but for example, wheat flour (strong flour, medium-strength flour, weak flour, etc.), barley flour, rice flour, etc. , Corn flour, rye flour, buckwheat flour, soybean flour and the like.

生地における可塑性油脂(B)の配合量は、焼成品の種類によっても異なり特に限定されないが、生地に配合される穀粉100質量部に対して、好ましくは2〜40質量部であり、より好ましくは2〜30質量部である。 The amount of the plastic fat (B) blended in the dough varies depending on the type of baked product and is not particularly limited, but is preferably 2 to 40 parts by mass, more preferably 2 to 40 parts by mass, based on 100 parts by mass of the flour blended in the dough. It is 2 to 30 parts by mass.

生地には、穀粉と可塑性油脂(B)以外にも、通常、焼成品の生地に配合されるものであれば、特に制限なく配合することができる。また、これらの配合量も、通常、焼成品の生地に配合される範囲を考慮して特に制限なく配合することができる。具体的には、例えば、水や、前述したような乳、乳製品、蛋白質、糖質の他、卵、卵加工品、澱粉、塩類、乳化剤、乳化起泡剤(乳化油脂)、イースト、イーストフード、カカオマス、ココアパウダー、チョコレート、コーヒー、紅茶、抹茶、野菜類、果物類、果実、果汁、ジャム、フルーツソース、肉類、魚介類、豆類、きな粉、豆腐、豆乳、大豆蛋白、膨張剤、甘味料、調味料、香辛料、着色料、フレーバー、酵素などが挙げられる。 In addition to the flour and the plastic fat (B), the dough can be blended without particular limitation as long as it is usually blended in the dough of the baked product. Further, these blending amounts can also be blended without particular limitation in consideration of the range to be blended in the dough of the baked product. Specifically, for example, water, milk, dairy products, proteins, sugars as described above, eggs, processed egg products, starches, salts, emulsifiers, emulsified foaming agents (emulsified fats and oils), yeast, yeast. Food, cacao mass, cocoa powder, chocolate, coffee, tea, matcha, vegetables, fruits, fruits, fruit juice, jam, fruit sauce, meat, seafood, beans, kin flour, tofu, soy milk, soy protein, swelling agent, sweetness Examples include ingredients, seasonings, spices, coloring agents, flavors, enzymes and the like.

可塑性油脂(B)を添加した生地を用いた焼成品のパンや菓子としては、例えば、食パン、テーブルロール、菓子パン、調理パン、フランスパン、ライブレッドなどのパン類、シュトーレン、パネトーネ、クグロフ、ブリオッシュ、ドーナツなどのイースト菓子、デニッシュ、クロワッサン、パイなどのペストリー、バターケーキ、パウンドケーキ、スポンジケーキ、ビスケット、クッキー、ドーナツ、ブッセ、ホットケーキ、ワッフルなどのケーキなどが挙げられる。 Breads and confectioneries that are baked products using dough to which plastic fat (B) is added include, for example, breads such as bread, table rolls, confectionery bread, cooked bread, French bread, and live red, stolen, panelone, kuglov, and brioche. , East confectionery such as donuts, pastries such as Danish pastry, croissants and pies, butter cakes, pound cakes, sponge cakes, biscuits, cookies, donuts, busses, hot cakes, waffles and other cakes.

以下に、実施例により本発明をさらに詳しく説明するが、本発明はこれらの実施例に何ら限定されるものではない。
(1)測定方法
油脂のヨウ素価は、基準油脂分析試験法(公益社団法人日本油化学会)の「2.3.4.1−2013ヨウ素価(ウィイス−シクロヘキサン法)」で測定した。
Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to these Examples.
(1) Measurement method The iodine value of fats and oils was measured by the standard fats and oils analysis test method (Japan Oil Chemists' Society) "2.3.4.1-2013 iodine value (Wiiss-cyclohexane method)".

油脂の固体脂含量(SFC)は、基準油脂分析試験法(公益社団法人日本油化学会)の「2.2.9−2013 固体脂含量(NMR法)」で測定した。 The solid fat content (SFC) of fats and oils was measured by the standard fat and oil analysis test method (Japan Oil Chemicals Society) "2.2.9-2013 solid fat content (NMR method)".

P2Oの含有量(PPOおよびPOPの合計量)、PPOとPOPとの質量比(PPO/POP)、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量、LLL、MLL、およびLMLの合計量は、ガスクロマトグラフ法(基準油脂分析試験法(公益社団法人日本油化学会)の「2.4.2.2−2013 脂肪酸組成(FID昇温ガスクロマトグラフ法)」と「奨2−2013 2位脂肪酸組成」)で測定し、それぞれ脂肪酸量を用いて計算にて求めた。トリグリセリドの2位に結合されたラウリン酸量は、ガスクロマトグラフ法(基準油脂分析試験法(公益社団法人日本油化学会)の「2.4.2.2−2013 脂肪酸組成(FID昇温ガスクロマトグラフ法)」と「奨2−2013 2位脂肪酸組成」で測定した。なお、P2Oの含有量、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量、トリグリセリドの2位に結合されたラウリン酸量、LLL、MLL、およびLMLの合計量は、油脂全量を基準としている。 P2O content (total amount of PPO and POP), mass ratio of PPO to POP (PPO / POP), content of trisaturated triglycerides in which all of the constituent fatty acids have 16 or more carbon atoms, LLL, MLL, and LML. The total amount of is the gas chromatograph method (standard oil and fat analysis test method (Japan Oil Chemists' Society) "2.4.2.2-2013 fatty acid composition (FID temperature rising gas chromatograph method)" and "Sho 2- 2013 2-position fatty acid composition ”), and calculated using the amount of each fatty acid. The amount of lauric acid bound to the 2-position of triglyceride is determined by the gas chromatograph method (reference oil and fat analysis test method (Japan Oil Chemists' Society) "2.4.2.2-2013 fatty acid composition (FID temperature rising gas chromatograph)". Method) ”and“ Recommended 2-2013 2-position fatty acid composition ”. The P2O content, the content of trisaturated triglyceride in which all of the constituent fatty acids have 16 or more carbon atoms, and the 2-position of triglyceride are bound. The total amount of lauric acid, LLL, MLL, and LML is based on the total amount of fats and oils.

(2)評価
<製菓製パン練り込み用油脂組成物(A)および可塑性油脂(B)の作製>
表1および表2に示す配合比にて各油脂を混合し、実施例および比較例の製菓製パン練り込み用油脂組成物(A)を得た。なお、各油脂の35℃における固体脂含量(%)、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量(質量%)は表3に示すとおりである。
(2) Evaluation <Preparation of fat composition (A) and plastic fat (B) for kneading confectionery bread>
Each fat and oil was mixed at the blending ratios shown in Tables 1 and 2 to obtain a fat and oil composition (A) for kneading confectionery bread in Examples and Comparative Examples. Table 3 shows the solid fat content (%) of each fat and oil at 35 ° C. and the content (mass%) of trisaturated triglyceride in which all of the constituent fatty acids have 16 or more carbon atoms.

製菓製パン練り込み用油脂組成物(A)81.2質量部を75℃に調温し、乳化剤0.2質量部を添加後、溶解させ油相とした。一方、水16.5質量部に脱脂粉乳1.0質量部および食塩1.0質量部を添加し、80℃で加熱殺菌して水相を得た。 The temperature of 81.2 parts by mass of the oil / fat composition (A) for kneading confectionery bread was adjusted to 75 ° C., 0.2 parts by mass of an emulsifier was added, and then dissolved to prepare an oil phase. On the other hand, 1.0 part by mass of skim milk powder and 1.0 part by mass of salt were added to 16.5 parts by mass of water and sterilized by heating at 80 ° C. to obtain an aqueous phase.

次に、該油相に該水相を添加し、プロペラ攪拌機で撹拌して、油中水型に乳化した後、ミルクフレーバーを0.1質量部添加し、撹拌後、コンビネーターによって急冷捏和して、下記の配合割合のマーガリンを可塑性油脂(B)として得た。得られたマーガリンは熟成(テンパリング)後に5℃で保管した。
〈マーガリンの配合〉
製菓製パン練り込み用油脂組成物(A) 81.2質量部
乳化剤 0.2質量部
水 16.5質量部
脱脂粉乳 1.0質量部
食塩 1.0質量部
ミルクフレーバー 0.1質量部
Next, the aqueous phase is added to the oil phase, stirred with a propeller stirrer to emulsify into a water-in-oil mold, 0.1 parts by mass of milk flavor is added, and after stirring, quenching and kneading is performed by a combinator. Then, margarine having the following blending ratio was obtained as a plastic fat (B). The obtained margarine was stored at 5 ° C. after aging (tempering).
<Mixing of margarine>
Oil and fat composition for kneading bread for confectionery (A) 81.2 parts by mass Emulsifier 0.2 parts by mass Water 16.5 parts by mass Skim milk powder 1.0 parts by mass Salt 1.0 parts by mass Milk flavor 0.1 parts by mass

<食パンの作製>
イーストを分散させた水、イーストフード、および強力粉をミキサーボールに投入しフックを使用して、下記条件にてミキシング、発酵を行い、中種生地を得た。
<Making bread>
Water in which yeast was dispersed, yeast food, and strong flour were put into a mixer bowl and mixed and fermented under the following conditions using a hook to obtain a medium seed dough.

その後、本捏配合のマーガリン以外の全材料および中種生地を添加し低速3分、中低速3分でミキシングした後、マーガリンを投入し、さらに低速3分、中低速4分でミキシングしパン生地を得た。捏上温度は28℃であった。 After that, all the ingredients other than the margarine mixed in this kneading and the medium-sized dough are added and mixed at low speed 3 minutes and medium-low speed 3 minutes, then margarine is added, and then mixed at low-speed 3 minutes and medium-low speed 4 minutes to prepare the bread dough. Obtained. The kneading temperature was 28 ° C.

その後、20分のフロアータイムをとった後、生地を分割し、再度20分のベンチタイムをとった。生地の成型は、モルダーで伸展し、ロール型に成型後、ワンローフ型に入れ、38℃、湿度80%で45分間のホイロをとり、その後200℃で30分焼成した。
〈食パン配合〉
・中種配合
強力粉 70質量部
イースト 2.5質量部
イーストフード 0.1質量部
水 40質量部
・本捏配合
強力粉 30質量部
上白糖 6質量部
食塩 1.8質量部
脱脂粉乳 2質量部
マーガリン(可塑性油脂(B)) 5質量部
水 25質量部
Then, after taking a floor time of 20 minutes, the dough was divided and a bench time of 20 minutes was taken again. The dough was formed by stretching it with a mulder, molding it into a roll mold, putting it in a one loaf mold, taking a proof at 38 ° C. and 80% humidity for 45 minutes, and then baking it at 200 ° C. for 30 minutes.
<Bread combination>
・ Medium seed compounded strong flour 70 parts by mass yeast 2.5 parts by mass yeast food 0.1 parts by mass water 40 parts by mass ・ main kneaded strong flour 30 parts by mass fine white sugar 6 parts by mass salt 1.8 parts by mass defatted milk powder 2 parts by mass margarine (Plastic fat (B)) 5 parts by mass Water 25 parts by mass

<評価>
以下の各評価において、パネルは、五味(甘味、酸味、塩味、苦味、うま味)の識別テスト、味の濃度差識別テスト、食品の味の識別テスト、基準嗅覚テストを実施し、その各々のテストで適合と判断された20〜40代の男性4名、女性6名を選抜した。
<Evaluation>
In each of the following evaluations, the panel conducted a five-flavor (sweetness, sourness, saltiness, bitterness, umami) identification test, a taste concentration difference identification test, a food taste identification test, and a standard olfactory test, each of which was tested. We selected 4 men and 6 women in their 20s and 40s who were judged to be suitable.

[ヒキ]
焼成した食パンを放冷後、20℃で2日保存し、試食したときにヒキ(パン様の繋がりが残存する食感)を感じるかをパネル10名で以下の基準により評価した。
評価基準
◎:パネル10名中8名以上が、ヒキがないと評価した。
○:パネル10名中5〜7名が、ヒキがないと評価した。
△:パネル10名中3〜4名が、ヒキがないと評価した。
×:パネル10名中ヒキがないと評価したのは2名以下であった。
[Hiki]
After allowing the baked bread to cool, it was stored at 20 ° C. for 2 days, and whether or not the bread felt hiki (texture in which the bread-like connection remained) was evaluated by 10 panels according to the following criteria.
Evaluation Criteria ⊚: 8 or more out of 10 panels evaluated that there was no hiki.
◯: 5 to 7 out of 10 panels evaluated that there was no hiki.
Δ: 3 to 4 out of 10 panels evaluated that there was no hiki.
X: Of the 10 panels, 2 or less evaluated that there was no hiki.

[口中でのダマになりやすさ]
焼成した食パンを放冷後、20℃で2日保存し、試食したときに口中でのダマになりやすさを感じるかをパネル10名で以下の基準により評価した。
評価基準
◎:パネル10名中8名以上が、口中でダマになりにくいと評価した。
○:パネル10名中5〜7名が、口中でダマになりにくいと評価した。
△:パネル10名中3〜4名が、口中でダマになりにくいと評価した。
×:パネル10名中、口中でダマになりにくいと評価したのは2名以下であった。
[Easy to get lumpy in the mouth]
After allowing the baked bread to cool, it was stored at 20 ° C. for 2 days, and 10 panels evaluated whether or not they felt liable to get lumpy in the mouth when tasting.
Evaluation Criteria ⊚: Eight or more of the 10 panels evaluated that they were less likely to get lumpy in the mouth.
◯: 5 to 7 out of 10 panels evaluated that they were less likely to get lumpy in the mouth.
Δ: 3 to 4 out of 10 panels evaluated that they were less likely to get lumpy in the mouth.
X: Of the 10 panels, 2 or less evaluated that they were less likely to get lumpy in the mouth.

[パサつき感]
焼成した食パンを放冷後、20℃で2日保存し、試食したときのパサつきをパネル10名で以下の基準により評価した。
評価基準
◎:パネル10名中8名以上が、パサつきが無いと評価した。
○:パネル10名中5〜7名が、パサつきが無いと評価した。
△:パネル10名中3〜4名が、パサつきが無いと評価した。
×:パネル10名中パサつきが無いと評価したのは2名以下であった。
[Dry feeling]
After allowing the baked bread to cool, it was stored at 20 ° C. for 2 days, and the dryness at the time of tasting was evaluated by 10 panels according to the following criteria.
Evaluation Criteria ⊚: 8 or more out of 10 panels evaluated that there was no dryness.
◯: 5 to 7 out of 10 panels evaluated that there was no dryness.
Δ: 3 to 4 out of 10 panels evaluated that there was no dryness.
X: Of the 10 panels, 2 or less evaluated that there was no dryness.

[口あたりのソフトさ]
焼成した食パンを放冷後、20℃で2日保存し、試食したときの口あたりのソフトさをパネル10名で以下の基準により評価した。
評価基準
◎:パネル10名中8名以上が、ソフトさがあると評価した。
○:パネル10名中5〜7名が、ソフトさがあると評価した。
△:パネル10名中3〜4名が、ソフトさがあると評価した。
×:パネル10名中ソフトさがあると評価したのは2名以下であった。
[Softness of mouth]
After allowing the baked bread to cool, it was stored at 20 ° C. for 2 days, and the softness of the mouth when tasting was evaluated by 10 panels according to the following criteria.
Evaluation Criteria ⊚: 8 or more out of 10 panels evaluated that they were soft.
◯: 5 to 7 out of 10 panels evaluated that they were soft.
Δ: 3 to 4 out of 10 panels evaluated that they were soft.
X: Of the 10 panels, 2 or less evaluated that they were soft.

[トップのフレーバーリリース]
焼成した食パンを20℃で2日保存し、試食したときのトップのフレーバーリリースをパネル10名で以下の基準で評価し、その平均点により評価した。
評価基準
点数
4点:トップのフレーバーリリースが非常に速く、風味を強く感じる。
3点:トップのフレーバーリリースが速く、風味を強く感じる。
2点:トップのフレーバーリリースがやや遅く、風味が若干薄れる。
1点:トップのフレーバーリリースが遅く、風味が弱い。
平均点
◎:平均点が3.5以上
〇:平均点が3以上3.5未満
△:平均点が2以上3未満
×:平均点が2未満
[Top flavor release]
The baked bread was stored at 20 ° C. for 2 days, and the top flavor release at the time of tasting was evaluated by 10 panels according to the following criteria, and the average score was used for evaluation.
Evaluation criteria 4 points: The top flavor release is very fast and the flavor is strong.
3 points: The top flavor is released quickly and the flavor is strong.
2 points: The top flavor release is a little late, and the flavor is slightly diminished.
1 point: The top flavor release is slow and the flavor is weak.
Average score ◎: Average score is 3.5 or more 〇: Average score is 3 or more and less than 3.5 △: Average score is 2 or more and less than 3 ×: Average score is less than 2

[10℃での生地への分散性]
食パン作製時に10℃でマーガリンを生地に添加したときのマーガリンの塊がなくなる時間を目視により評価した。
評価基準
◎:1分超〜1分45秒以内で分散した。
○:1分45秒超〜2分30秒以内で分散した。
△:2分30秒超〜3分30秒以内で分散した。
×:3分30秒超で分散した。
[Dispersibility in dough at 10 ° C]
The time during which the margarine lumps disappeared when margarine was added to the dough at 10 ° C. during the preparation of bread was visually evaluated.
Evaluation Criteria ⊚: Dispersed within 1 minute to 1 minute and 45 seconds.
◯: Dispersed within 1 minute 45 seconds to 2 minutes 30 seconds.
Δ: Dispersed within 2 minutes and 30 seconds to 3 minutes and 30 seconds.
X: Dispersed in more than 3 minutes and 30 seconds.

上記の評価結果を表1および表2に示す。また製菓製パン用油脂組成物(A)の組成等も併せてこれらの表に示し、各油脂の35℃における固体脂含量(%)、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量(質量%)は表3に示した。 The above evaluation results are shown in Tables 1 and 2. The composition of the oil / fat composition (A) for confectionery / bakery is also shown in these tables, and the solid fat content (%) of each oil / fat at 35 ° C. and the trisaturated triglyceride in which all of the constituent fatty acids have 16 or more carbon atoms. The content (% by mass) of is shown in Table 3.

Figure 0006787666
Figure 0006787666

Figure 0006787666
Figure 0006787666

Figure 0006787666
Figure 0006787666

Claims (5)

構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量が15質量%以下である油脂のみを含有し、かつ、ヨウ素価が50〜60のエステル交換油脂を25質量%〜55質量%含有し、以下の(a)〜(d)の条件を満たす製菓製パン練り込み用油脂組成物:
(a)PPOとPOPとの質量比(PPO/POP)が1.0超2.2以下(PPOは、1位と2位または2位と3位にパルミチン酸、3位または1位にオレイン酸が結合されたトリグリセリドであり、POPは、1位と3位にパルミチン酸、2位にオレイン酸が結合されたトリグリセリドであり、Pはパルミチン酸、Oはオレイン酸を示す。);
(b)P2Oの含有量が油脂全量に対して6.5〜15.5質量%(P2Oの含有量は、PPOおよびPOPの合計量である。);
(c)構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量が油脂全量に対して2.8〜7.5質量%;および、
(d)トリグリセリドの2位に結合されたラウリン酸量が油脂全量に対して2.0〜25質量%。
25% by mass to 55% by mass of transesterified fats and oils containing only fats and oils having a trisaturated triglyceride content of 15% by mass or less in which all of the constituent fatty acids have 16 or more carbon atoms and having an iodine value of 50 to 60%. Confectionery bakery kneading oil / fat composition containing and satisfying the following conditions (a) to (d):
(A) The mass ratio of PPO to POP (PPO / POP) is more than 1.0 and 2.2 or less (PPO is palmitic acid at the 1st and 2nd positions or 2nd and 3rd positions, and oleic acid at the 3rd or 1st position. It is an acid-bound triglyceride, POP is a triglyceride in which palmitic acid is bound at the 1- and 3-positions, and oleic acid is bound at the 2-position, P is palmitic acid, and O is oleic acid.);
(B) The content of P2O is 6.5 to 15.5% by mass based on the total amount of fats and oils (the content of P2O is the total amount of PPO and POP);
(C) The content of trisaturated triglyceride in which all of the constituent fatty acids have 16 or more carbon atoms is 2.8 to 7.5% by mass with respect to the total amount of fats and oils;
(D) The amount of lauric acid bound to the 2-position of triglyceride is 2.0 to 25% by mass with respect to the total amount of fats and oils.
LLL、MLL、およびLMLの合計量が油脂全量に対して1.5〜7質量%である、請求項1に記載の製菓製パン練り込み用油脂組成物(LLLは、1位と2位と3位にラウリン酸が結合されたトリグリセリドであり、MLLは、1位または3位にミリスチン酸、2位と3位または1位と2位にラウリン酸が結合されたトリグリセリドであり、LMLは、1位と3位にラウリン酸、2位にミリスチン酸が結合されたトリグリセリドであり、Lはラウリン酸、Mはミリスチン酸を示す。)。 The oil and fat composition for confectionery bread kneading according to claim 1, wherein the total amount of LLL, MLL, and LML is 1.5 to 7% by mass based on the total amount of oil and fat (LLL is ranked 1st and 2nd. MLL is a triglyceride in which lauric acid is bound at the 3-position, and MLL is a triglyceride in which myristic acid is bound at the 1-position or 3-position, or lauric acid is bound at the 2-position and 3-position or 1-position and 2-position. It is a triglyceride in which lauric acid is bonded to the 1st and 3rd positions and myristic acid is bonded to the 2nd position. L indicates lauric acid and M indicates myristic acid). 35℃における固体脂含量が8質量%以下の油脂のみを含有する、請求項1または2に記載の製菓製パン練り込み用油脂組成物。 The oil / fat composition for kneading confectionery bread according to claim 1 or 2, which contains only the oil / fat having a solid fat content of 8% by mass or less at 35 ° C. 構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量が12質量%以下である油脂のみを含有する、請求項1から3のいずれかに記載の製菓製パン練り込み油脂組成物。 The confectionery bakery kneaded fat / oil composition according to any one of claims 1 to 3, which contains only fats and oils having a content of trisaturated triglyceride having 16 or more carbon atoms and 12% by mass or less of all of the constituent fatty acids. 請求項1から4のいずれかに記載の製菓製パン練り込み用油脂組成物を含有する可塑性油脂を生地に練り込み、この生地を焼成する焼成品の製造方法。
A method for producing a baked product in which a plastic fat or oil containing the fat or oil composition for kneading confectionery bread according to any one of claims 1 to 4 is kneaded into a dough and the dough is baked.
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