JP6782332B2 - 水分解酸素発生用のポリイミド／炭素繊維布電極及びその製造方法 - Google Patents
水分解酸素発生用のポリイミド／炭素繊維布電極及びその製造方法 Download PDFInfo
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- JP6782332B2 JP6782332B2 JP2019094755A JP2019094755A JP6782332B2 JP 6782332 B2 JP6782332 B2 JP 6782332B2 JP 2019094755 A JP2019094755 A JP 2019094755A JP 2019094755 A JP2019094755 A JP 2019094755A JP 6782332 B2 JP6782332 B2 JP 6782332B2
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- polyimide
- fiber cloth
- carbon fiber
- polyamic acid
- cloth electrode
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims description 79
- 239000004744 fabric Substances 0.000 title claims description 78
- 229920000049 Carbon (fiber) Polymers 0.000 title claims description 77
- 239000004917 carbon fiber Substances 0.000 title claims description 77
- 239000004642 Polyimide Substances 0.000 title claims description 68
- 229920001721 polyimide Polymers 0.000 title claims description 68
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims description 34
- 239000001301 oxygen Substances 0.000 title claims description 34
- 229910052760 oxygen Inorganic materials 0.000 title claims description 34
- 238000004519 manufacturing process Methods 0.000 title claims description 20
- 229920005575 poly(amic acid) Polymers 0.000 claims description 47
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 34
- 150000004985 diamines Chemical class 0.000 claims description 19
- 150000008064 anhydrides Chemical class 0.000 claims description 18
- GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 claims description 12
- 238000006068 polycondensation reaction Methods 0.000 claims description 11
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical group NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims description 8
- 239000011247 coating layer Substances 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical group C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 claims description 4
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 claims description 4
- BLYOXQBERINFDU-UHFFFAOYSA-N pyrene-1,8-diamine Chemical compound C1=C2C(N)=CC=C(C=C3)C2=C2C3=CC=C(N)C2=C1 BLYOXQBERINFDU-UHFFFAOYSA-N 0.000 claims description 4
- -1 Polyethylene Polymers 0.000 claims description 3
- 238000003618 dip coating Methods 0.000 claims description 3
- BBYQSYQIKWRMOE-UHFFFAOYSA-N naphthalene-1,2,6,7-tetracarboxylic acid Chemical compound C1=C(C(O)=O)C(C(O)=O)=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 BBYQSYQIKWRMOE-UHFFFAOYSA-N 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 3
- 238000000354 decomposition reaction Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 26
- 239000010410 layer Substances 0.000 description 11
- 239000012299 nitrogen atmosphere Substances 0.000 description 10
- 239000004952 Polyamide Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 229920002647 polyamide Polymers 0.000 description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 4
- HTXDPTMKBJXEOW-UHFFFAOYSA-N dioxoiridium Chemical compound O=[Ir]=O HTXDPTMKBJXEOW-UHFFFAOYSA-N 0.000 description 3
- 229910000457 iridium oxide Inorganic materials 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- OPDZOUPGXXSCNF-UHFFFAOYSA-N anthracene-1,2,8,9-tetracarboxylic acid Chemical compound C1=CC=C(C(O)=O)C2=C(C(O)=O)C3=C(C(O)=O)C(C(=O)O)=CC=C3C=C21 OPDZOUPGXXSCNF-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-naphthoquinone Chemical compound C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 1
- 229910015118 LiMO Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000012983 electrochemical energy storage Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000006798 ring closing metathesis reaction Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- 229910021642 ultra pure water Inorganic materials 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Inert Electrodes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810523786.3 | 2018-05-28 | ||
| CN201810523786.3A CN110541174B (zh) | 2018-05-28 | 2018-05-28 | 聚酰亚胺/碳纤维布分解水制氧电极及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2019206753A JP2019206753A (ja) | 2019-12-05 |
| JP6782332B2 true JP6782332B2 (ja) | 2020-11-11 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019094755A Active JP6782332B2 (ja) | 2018-05-28 | 2019-05-20 | 水分解酸素発生用のポリイミド／炭素繊維布電極及びその製造方法 |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP6782332B2 (zh) |
| CN (1) | CN110541174B (zh) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113337833B (zh) * | 2020-02-14 | 2024-08-06 | 丰田自动车株式会社 | 聚噻吩类化合物/碳纤维布分解水制氧电极及其制备方法 |
| CN113402288A (zh) * | 2021-06-16 | 2021-09-17 | 江苏集萃碳纤维及复合材料应用技术研究院有限公司 | 一种碳纤维增强的高强度、高导热复合膜制备方法 |
| CN113737213A (zh) * | 2021-09-01 | 2021-12-03 | 上海纳米技术及应用国家工程研究中心有限公司 | 一种柔性聚酰亚胺碳布复合电极材料的制备方法及其产品和应用 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11115117A (ja) * | 1997-10-16 | 1999-04-27 | Nitto Denko Corp | 複合管状物 |
| KR20010080532A (ko) * | 1999-09-22 | 2001-08-22 | 히라이 가쯔히꼬 | 다공질, 도전성시트 및 그 제조방법 |
| JP3589450B2 (ja) * | 2001-03-13 | 2004-11-17 | 独立行政法人 科学技術振興機構 | アミド脱水縮合触媒として有用なパーフルオロアルキルフェニルホウ酸 |
| DE102008048737A1 (de) * | 2007-10-31 | 2009-07-16 | Sigrid Dr. Obenland | Monolithisches Katalysatorsystem für die Photolyse von Wasser |
| CN101654518B (zh) * | 2009-09-23 | 2011-04-06 | 中国科学院化学研究所 | 一种热固性聚酰亚胺树脂及其制备方法与应用 |
| WO2016147720A1 (ja) * | 2015-03-13 | 2016-09-22 | 日本碍子株式会社 | 空気極、水電解アノード、金属空気電池及び水電解装置 |
| JP7093608B2 (ja) * | 2015-10-19 | 2022-06-30 | 三菱鉛筆株式会社 | フッ素系樹脂含有ポリイミド前駆体溶液組成物、それを用いたポリイミド、ポリイミドフィルム、およびそれらの製造方法 |
| JP6743483B2 (ja) * | 2016-05-24 | 2020-08-19 | 東洋インキＳｃホールディングス株式会社 | 水電解装置に用いられる触媒層形成用組成物、触媒層及び水電解装置 |
| CN106048650B (zh) * | 2016-08-04 | 2018-06-12 | 浙江大学 | 3d多孔电极的制备方法及其在电化学析氢反应中的应用 |
| CN106732649A (zh) * | 2017-02-20 | 2017-05-31 | 天津理工大学 | 一种碱性析氧反应电催化剂的制备方法 |
| CN107383872B (zh) * | 2017-07-27 | 2020-02-18 | 华南理工大学 | 一种聚苯四甲酰基对苯二胺/碳布材料及其制备方法与应用 |
| CN108048868B (zh) * | 2017-12-15 | 2020-04-24 | 南京大学 | 一种氮化钼纳米棒电极材料及其制备方法和应用 |
-
2018
- 2018-05-28 CN CN201810523786.3A patent/CN110541174B/zh active Active
-
2019
- 2019-05-20 JP JP2019094755A patent/JP6782332B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN110541174A (zh) | 2019-12-06 |
| CN110541174B (zh) | 2021-11-12 |
| JP2019206753A (ja) | 2019-12-05 |
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