JP5907083B2 - Manufacturing method and equipment for seamless steel pipe with excellent toughness - Google Patents

Description

  The present invention relates to a production method and production equipment for a seamless steel pipe excellent in toughness. This is particularly true for pipes that are in the process of manufacturing seamless steel pipes of steel grades where the Ms point (= martensite transformation start temperature) and Mf point (= martensite transformation end temperature) are low, such as stainless steel. It is preferably used for forming a product tube excellent in toughness by performing a quenching and tempering treatment which is a quality heat treatment.

Here, “excellent toughness” means, for example, those satisfying ISO standard 13680. That is, the absorbed energy (symbol: vE- ₁₀ ) at the test temperature = -10 ° C measured in the pipe circumferential direction (C direction) Charpy impact test at the center of the product wall thickness is 40J on average for three test pieces. This means that less than 40J is less than 1 out of 3 and the value is 27J or more (2/3 or more of the required value).

The following is mentioned as a prior art regarding manufacture of a seamless steel pipe.
Patent Document 1 discloses a technique for obtaining a high-strength and high-toughness product by defining a heating temperature and a cooling rate at the time of quenching heat treatment in the production of a seamless steel pipe of thick 13Cr stainless steel. .
Patent Document 2 discloses a facility for minimizing a decrease in production efficiency when processing a steel type that cannot increase the cooling rate of quenching. However, the order of heat treatment is first-in first-out unless there is a problem.

Patent Document 3 discloses a method of manufacturing a seamless steel pipe of martensite-ferrite duplex steel.
In Patent Document 4, in the quenching method in which the quenching liquid flows in one direction on the inner surface of the pipe, the longitudinal direction of the pipe after quenching is controlled by controlling the flow rate of the liquid based on the measured liquid temperature on the inflow side and the outflow side. It is disclosed that the variation in hardness of the resin is reduced.

JP 2008-189945 A JP 2009-242863 A JP 2005-336595 A JP 2001-032022 A

Pipes that are in the process of manufacturing seamless steel pipes of steel grades such as martensitic stainless steel are rolled to a predetermined shape by hot working and then subjected to quenching and tempering heat treatment to achieve the required strength and toughness level. Be controlled. In normal heat treatment, first, in the quenching process, the tube is heated to a temperature of Ac ₁ point or more and Ac ₃ point or less in a heating furnace, and then rapidly cooled to near room temperature by water cooling or the like. In the subsequent tempering process, the tube after the quenching is performed. The body is heated in a separate heating furnace to a temperature of Ac ₁ point or less and then allowed to cool (see, for example, Patent Document 1). Recently, equipment for performing such heat treatment has been made into a continuous line, and treatment conditions such as heating temperature and heating time are set for various product types.

  Steel types such as martensitic stainless steel (see Patent Document 1) and martensite-ferrite duplex steel (see Patent Document 3) obtain a desired amount of martensite phase by quenching and tempering, but the Ms point and Mf point are Depending on the steel composition that specifies the steel type, some steel types have an Ms point of less than 100 ° C. and an Mf point of less than room temperature. The temperature of the tube after quenching is normally confirmed by measuring the surface temperature. However, for the steel types with the low Ms point and the low Mf point as described above, the temperature difference between the surface of the tube and the internal thickness (= wall thickness). The influence of the non-uniform temperature distribution on the martensite transformation rate cannot be ignored. That is, even if the surface temperature of the tube body after quenching is near room temperature, if the tempering is started before the temperature distribution in the thickness direction reaches a uniform steady state, an unintended tissue distribution occurs, which is adjusted. This contributes to material variations (= mechanical properties, particularly toughness variations) after heat treatment.

  On the other hand, a steel type (referred to as a specific steel type for convenience) to obtain a desired martensite phase by quenching and tempering has a cooling rate after quenching heating (= heating in the quenching process) even when the cooling rate is low. Since the martensitic transformation itself occurs, the material variation can be reduced by allowing it to stand at room temperature for a sufficient time after cooling to room temperature. However, if the heat treatment of a specific steel grade and other different steel grades is carried out in the same heat treatment line by first-in-first-out (see, for example, Patent Document 2), the standing time at room temperature of the specific steel grade becomes a bottleneck and the entire heat treatment line There is a problem of lowering productivity.

  After all, conventionally, there is known a quenching method and equipment for reducing the hardness variation in the longitudinal direction of the pipe body by controlling the quenching liquid flow rate (see, for example, Patent Document 4). In the heat treatment performed through the same heat treatment line and different steel grades, it is possible to achieve both reduction of material variation due to non-uniform structure in the tube thickness direction of a specific steel grade and maintenance of productivity of the entire heat treatment line There was a problem that it was difficult.

The present inventors diligently studied to solve the above-mentioned problems, and as a result, the tube was discriminated from a steel type having an Ms point of less than 200 ° C. and other steel types. The former was separately cooled after water cooling in quenching. In the case where it is placed in a room temperature environment until the temperature difference between the highest temperature portion and the lowest temperature portion in the cross section orthogonal to the tube axis direction is less than 2.0 ° C., the material variation is remarkably reduced and within the material variation range. We found that the average value of the data also improved. The latter may be processed by a normal quenching and tempering route. The present invention has been made based on these findings, and the gist thereof is as follows.
(1) In a method for manufacturing a seamless steel pipe having a step of quenching and tempering a pipe body that is an in-process product of a seamless steel pipe that is made by passing a plurality of steel types through the same heat treatment line, the pipe body has an Ms point: 200 in advance. It is discriminated whether it is a steel type less than ℃ or other steel types, and after the quenching, the discrimination result is Ms point: a steel type less than 200 ° C. , the discrimination result is Ms point: 200 ° C. or more. Move to the detainment floor, which is a different path from the pipe path of the steel grade , and keep it under a separate room temperature environment until the temperature difference between the hottest and coldest parts in the cross section perpendicular to the pipe axis is less than 2.0 ° C. A method for producing a seamless steel pipe excellent in toughness, characterized by being subjected to the tempering treatment after being left in place.
(2) In seamless steel pipe manufacturing equipment, including equipment for subjecting pipes that are in the process of manufacturing seamless steel pipes to quenching and tempering, the pipe body is a steel type with an Ms point of less than 200 ° C or other steel types in advance. Before determining whether the tube is a steel type of which the determination result is Ms point: less than 200 ° C. among the tube bodies after quenching, and before subjecting to the tempering, A facility for producing seamless steel pipes with excellent toughness, comprising a detained floor that is separately detained in a room temperature environment until the difference between the highest temperature part and the lowest temperature part is less than 2.0 ° C.

  According to the present invention, a steel tube having an Ms point of less than 200 ° C. is placed in an excellent toughness tube with a small variation in material by being kept in a separate room temperature environment until sufficiently uniform in the thickness direction after quenching and before tempering. Thus, other steel types are heat-treated in a first-in first-out manner as usual without being obstructed by the indwelling, so that it is possible to produce a seamless steel pipe excellent in toughness while maintaining the productivity of the entire heat treatment line.

It is a plane schematic diagram which shows an example of the heat processing line used for this invention.

  FIG. 1 is a schematic plan view showing an example of a heat treatment line used in the present invention. Among the pipes 1 that are in the process of manufacturing seamless steel pipes, pipes whose Ms point is determined to be 200 ° C. or higher (also referred to as “A pipe” for convenience) are heated to an appropriate heating temperature depending on the steel type in the quenching furnace 2. After that, it is immersed in cooling water in the quenching water tank 3 and water-cooled until the temperature of the outer peripheral surface of the tube body decreases to near room temperature, and then the appropriate temperature varies depending on the steel type in the tempering heating furnace 5 via the cooling floor 4. Tempering at tempering temperature. The Ms point is obtained by calculation using the formula (1) described later.

  On the other hand, the tube (which is also referred to as “B tube” for convenience) whose Ms point is determined to be less than 200 ° C. is processed along the same route as the A tube until it reaches the cooling bed 4. Is moved to a detention floor (also referred to as a buffer line) 6, which is another path, and a temperature difference (denoted by ΔT) between the highest temperature portion and the lowest temperature portion in the cross section orthogonal to the tube axis direction is 2 on the buffer line 6. It is left in a room temperature environment until it becomes less than 0 ° C., then returned to the cooling bed 4 and thereafter tempered by the same route as the A tube.

In this example, the cooling floor 4 and the detainment floor 6 are provided as separate facilities. However, if the cooling floor 4 has a sufficient space, a part thereof may be used as the detention floor.
In this example, the above-mentioned specific steel type (steel type to obtain a desired amount of martensite phase by quenching and tempering) is, for example, mass%, C: 0.005 to 0.05%, Si: 0.05 to 1.0%, Mn: 0.2 to 1.8%, P: 0.03% or less, S: 0.005% or less, Cr: 11 to 20%, Ni: 1.5 to 10%, Mo: 1 to 5%, N: 0.15% or less, with the balance being Fe and inevitable impurities. In this composition, instead of a part of Fe, in mass%, Al: 0.002 to 0.05%, Cu: 3.5% or less, Nb: 0.5% or less, V: 0.5 %, Ti: 0.3% or less, Zr: 0.2% or less, W: 3% or less, B: 0.01% or less, Ca: 0.01% or less, REM: 0.01% or less The composition may contain one or more selected from the above.

  As described above, in a steel type in which the Mf point is less than room temperature (this is one of the specific steel types), the temperature distribution in the tube thickness direction at the start of tempering (cross section perpendicular to the tube axis) The martensite transformation rate at each position in the thickness direction, in other words, the amount of retained austenite is substantially determined by the temperature distribution in the inner wall. In such a temperature distribution, even if ΔT is less than 10 ° C., the difference (variation) in the amount of retained austenite depending on the tube thickness direction position cannot be ignored. This variation in the amount of retained austenite is one of the causes of the material variation of the product.

  On the other hand, in this invention, B pipe | tube is detained in room temperature environment until (DELTA) T will be less than 2.0 degreeC. As a result, the variation in the amount of retained austenite in the tube thickness direction at the start of tempering is greatly reduced, the material variation of the product after tempering is greatly reduced, and the average value of data within the material variation range is improved. The effect is obtained. If tempering is started before ΔT is reduced to less than 2.0 ° C., such an effect cannot be obtained. It should be noted that the determination condition for the B tube is that the Ms point: less than 200 ° C. may be considered practically equivalent to the fact that this is almost equivalent to the Mf point: less than room temperature. This is based on the results of experiments conducted by the inventors.

In this embodiment, the Ms point is obtained in advance by collecting experimental data of the Ms point from the thermal expansion curve measured in a continuous cooling transformation experiment using thermal expansion test pieces of various compositions for the specific steel type in advance. It is calculated using the following formula (1) obtained by regression analysis with the amount of composition component [% by mass].
Ms [° C] = 502-810 [% C] -1230 [% N] -13 [% Mn] -30 [% Ni] -12 [% Cr] -54 [% Cu] -6 [Mo] (1 )
In addition, in Formula (1), when there exists a component element which is not contained in steel, 0 shall be substituted to the component element term.

  As a specific preferred implementation means, a waiting time (lead time) from the completion of quenching (water cooling completion) to the start of tempering is set for each steel type entering the heat treatment. In this setting, it is preferable to prepare a lead time calculation tool that combines the prior grasp of the Ms point according to the formula (1), the measurement of the ambient temperature and the tube surface temperature, and the heat transfer calculation. In the case of a steel type tube body (B tube) having an Ms point of less than 200 ° C., in the normal first-in-first-out, the time required to equalize the temperature until the lead time on the cooling bed 4 becomes ΔT <2.0 ° C. Those that do not reach are temporarily released to the buffer line 6 and placed in a room temperature environment until ΔT <2.0, and then subjected to tempering again.

A steel billet showing the chemical composition and Ms point calculated by the formula (1) in Table 1 is formed by hot working, and after the tube forming, it is air-cooled from 100 ° C. to room temperature, and an outer diameter of 195.0 mm × meat Ten pipe bodies were formed as a material for a seamless steel pipe having a thickness of 27.0 mm.
As an example of the present invention, the following heat treatment (quenching-tempering) was performed on five randomly extracted pipes (P1 to P5). The heat treatment line shown in FIG. 1 was used. Quenching was performed by heating at 950 ° C. and then water cooling. The tube surface temperature (measured value) at the time of completion of recuperation after water cooling was 30 to 36 ° C. The tube was left at room temperature (in the atmosphere) for 8 hours or longer, and when ΔT (calculated value) reached 1.2 to 1.8 ° C., it was charged into a tempering furnace and tempered at 600 ° C. .

As a comparative example, the remaining five pipe bodies (P6 to P10) were quenched under the same conditions as in the present invention example, and then timed control at ΔT <2.0 ° C. was not performed. The tempering furnace was first charged and tempered at 600 ° C. In this case, ΔT (calculated value) at the time of charging the tempering furnace was 6.0 ° C.
From each tube after tempering treatment, V-notch test piece (collection position = tube thickness center, test piece thickness = 10 mm, test piece length direction = pipe circumference direction (C direction) in accordance with JIS Z 2202 regulations. ), V notch depth direction = pipe length direction (L direction) was sampled three by three, and Charpy impact test was performed according to JIS Z 2242, and _v E _-10 was determined.

The obtained results are shown in Table 2. From Table 2, in the present invention example, the average value = 87.7J for _v E _-10 data (N number = 15), no test pieces less than 40 J. In addition, the standard deviation = 3.8 J, and results with very little variation were obtained. On the other hand, in the comparative example, _v is a mean value = 82.7J of E _-10 data (N number = 15), a test piece of less than 40J occurs two. The standard deviation was 17.9 J, indicating a decrease in average value and an increase in variation. Looking at the results for each tube, in the comparative examples, there were some _v E _-10 values that were comparable to those of the present invention example, while the _v E _-10 values were greatly reduced, The average value is lowered and the variation is increased.

  Thus, according to the present invention, stable mechanical properties can be obtained.

DESCRIPTION OF SYMBOLS 1 Tube 2 Quenching heating furnace 3 Quenching water tank 4 Cooling floor 5 Tempering heating furnace 6 Detention floor (buffer line)

Claims (2)

In a method for producing a seamless steel pipe having a step of quenching and tempering a tubular body that is an in-process product of a seamless steel pipe that is made by passing a plurality of steel types through the same heat treatment line, the pipe body has an Ms point of less than 200 ° C in advance. It is discriminated whether it is a steel type or a steel type other than that, and after the quenching, the discrimination result is a steel type whose Ms point is less than 200 ° C. Moved to the detainment floor, which is a different route from that of the tube body, and left in a separate room temperature environment until the temperature difference between the highest temperature part and the lowest temperature part in the cross section perpendicular to the tube axis is less than 2.0 ° C. A method for producing a seamless steel pipe excellent in toughness, characterized by being subjected to a subsequent tempering treatment. In seamless steel pipe manufacturing equipment, including equipment for quenching and tempering pipes that are in the process of manufacturing seamless steel pipes, whether the pipe body is a steel type with an Ms point of less than 200 ° C or other steel types in advance And determining the maximum temperature in the cross section perpendicular to the axis of the tube before subjecting only to the tube body of which the determination result is a steel type whose Ms point is less than 200 ° C. A facility for producing seamless steel pipes with excellent toughness, characterized by comprising a detained floor that is separately detained in a room temperature environment until the difference between the section and the lowest temperature section is less than 2.0 ° C.

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