JP5987288B2 - 半導体装置 - Google Patents
半導体装置 Download PDFInfo
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- JP5987288B2 JP5987288B2 JP2011213473A JP2011213473A JP5987288B2 JP 5987288 B2 JP5987288 B2 JP 5987288B2 JP 2011213473 A JP2011213473 A JP 2011213473A JP 2011213473 A JP2011213473 A JP 2011213473A JP 5987288 B2 JP5987288 B2 JP 5987288B2
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- layer
- aln
- intermediate layer
- gan
- high resistance
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- 239000004065 semiconductor Substances 0.000 title claims description 128
- 239000000758 substrate Substances 0.000 claims description 38
- 239000000463 material Substances 0.000 claims description 28
- 229910002704 AlGaN Inorganic materials 0.000 claims description 26
- 239000012535 impurity Substances 0.000 claims description 25
- 229910002601 GaN Inorganic materials 0.000 description 70
- JMASRVWKEDWRBT-UHFFFAOYSA-N Gallium nitride Chemical compound [Ga]#N JMASRVWKEDWRBT-UHFFFAOYSA-N 0.000 description 70
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 49
- 239000013078 crystal Substances 0.000 description 10
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- 239000001257 hydrogen Substances 0.000 description 4
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
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- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 3
- XCZXGTMEAKBVPV-UHFFFAOYSA-N trimethylgallium Chemical compound C[Ga](C)C XCZXGTMEAKBVPV-UHFFFAOYSA-N 0.000 description 3
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- 230000015556 catabolic process Effects 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
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- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 101000993059 Homo sapiens Hereditary hemochromatosis protein Proteins 0.000 description 1
- OTVPWGHMBHYUAX-UHFFFAOYSA-N [Fe].[CH]1C=CC=C1 Chemical compound [Fe].[CH]1C=CC=C1 OTVPWGHMBHYUAX-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- RNQKDQAVIXDKAG-UHFFFAOYSA-N aluminum gallium Chemical compound [Al].[Ga] RNQKDQAVIXDKAG-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 150000002500 ions Chemical group 0.000 description 1
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- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
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- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
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- Insulated Gate Type Field-Effect Transistor (AREA)
Description
最初に、AlN層を設けられている場合と、設けられていない場合において、電子走行層へのFeの入り込み量について説明する。図2に示されHEMTを形成するための半導体積層膜において、AlN層が設けられているものとAlNが設けられていないものとを作製し、SIMS(Secondary Ion-microprobe Mass Spectrometer:2次イオン質量分析)による測定を行なった。図3には、これらの半導体積層膜におけるSIMSにより測定された深さ方向におけるFe濃度のプロファイルを示す。図2(a)は、AlN層が設けられていない半導体積層膜(AlNなし半導体積層膜)の構造を示すものであり、基板911上に、核形成層912、バッファ層913、高抵抗層914、電子走行層915、電子供給層916が形成されているものである。図2(b)は、AlN層が設けられている半導体積層膜(AlNあり半導体積層膜)の構造を示すものであり、基板911上に、核形成層912、バッファ層913、高抵抗層914、中間層930、電子走行層915、電子供給層916が形成されているものである。尚、高抵抗層914は、不純物元素としてFeがドープされているGaNにより形成されており、膜厚が約300nmであり、ドープされているFeの濃度は、約1×1018cm−3である。また、電子走行層915は、膜厚が約600nmのGaNにより形成されており、電子供給層916は、膜厚が約20nmのAlGaNにより形成されている。また、図2(b)に示されるAlNあり半導体積層膜の場合には、中間層930は、約5nmのAlNにより形成されている。図3は、電子走行層916からバッファ層913までの間において、深さ方向にSIMSにより測定した結果を示すものである。尚、図3において図示はされていないが、AlNあり半導体積層膜の場合においては、高抵抗層914と電子走行層915との間に中間層930が形成されている。
次に、第1の実施の形態における半導体装置について説明する。本実施の形態における半導体装置は、AlGaN/GaNシングルへテロ構造のHEMTである。
次に、第2の実施の形態における半導体装置について説明する。本実施の形態における半導体装置は、AlGaN/GaNシングルへテロ構造のHEMTである。
次に、第3の実施の形態について説明する。本実施の形態における半導体装置は、第1の実施の形態における多層中間層15に代えて、AlNとGaNとの混晶により形成された混晶中間層を有するものである。
次に、第3の実施の形態における半導体装置について、図9に基づき説明する。本実施の形態における半導体装置は、電子供給層17上にゲート絶縁膜となる絶縁膜330が形成されている構造のものである。このような絶縁膜330を形成することにより、ゲートリーク電流を減らすことができる。絶縁膜330としては、例えば、Al2O3(酸化アルミニウム)等が用いられる。
次に、第5の実施の形態について説明する。本実施の形態は、半導体デバイス、電源装置及び高周波増幅器である。
(付記1)
基板の上に形成された半導体材料に高抵抗となる不純物元素がドープされた高抵抗層と、
前記高抵抗層の上に形成された多層中間層と、
前記多層中間層の上に半導体材料により形成された電子走行層と、
前記電子走行層の上に半導体材料により形成された電子供給層と、
を有し、
前記多層中間層は、GaN層とAlN層とが交互に積層された多層膜により形成されていることを特徴とする半導体装置。
(付記2)
前記多層中間層において、GaN層の膜厚はAlN層の膜厚よりも厚いことを特徴とする付記1に記載の半導体装置。
(付記3)
前記多層中間層において、GaN層の膜厚が20〜50nmであり、AlN層の膜厚が2〜5nmであることを特徴とする付記1または2に記載の半導体装置。
(付記4)
前記多層中間層において、GaN層とAlN層とを積層することにより形成される周期は、20周期以上であることを特徴とする付記1から3のいずれかに記載の半導体装置。
(付記5)
前記多層中間層の膜厚は、500〜1000nmであることを特徴とする付記1から4のいずれかに記載の半導体装置。
(付記6)
基板の上に形成された半導体材料に高抵抗となる不純物元素がドープされた高抵抗層と、
前記高抵抗層の上に形成された中間層と、
前記中間層の上に半導体材料により形成された電子走行層と、
前記電子走行層の上に半導体材料により形成された電子供給層と、
を有し、
前記中間層はAlGaNにより形成されており、AlXGa1−XNとした場合、0<X<0.3であることを特徴とする半導体装置。
(付記7)
前記高抵抗層、前記多層中間層または前記中間層、前記電子走行層及び前記電子供給層は、MOVPEにより形成されたものであることを特徴とする付記1から6のいずれかに記載の半導体装置。
(付記8)
前記高抵抗層は、GaN、AlN、AlGaNのうちから選ばれるいずれか1つを含む材料に、高抵抗となる不純物元素がドープされているものにより形成されていることを特徴とする付記1から7のいずれかに記載の半導体装置。
(付記9)
前記高抵抗層は第1の高抵抗層であり、前記多層中間層は第1の多層中間層であって、
前記第1の多層中間層の上に形成された半導体材料に高抵抗となる不純物元素がドープされた第2の高抵抗層と、
前記第2の高抵抗層の上に形成された第2の多層中間層と、
を有し、前記電子走行層は、前記第2の多層中間層の上に形成されるものであって、
前記第2の多層中間層は、GaN層とAlN層とが交互に積層された多層膜により形成されていることを特徴とする付記1から5のいずれかに記載の半導体装置。
(付記10)
前記第2の高抵抗層における高抵抗となる不純物元素のドーピング濃度は、前記第1の高抵抗層における高抵抗となる不純物元素のドーピング濃度よりも低いことを特徴とする付記9に記載の半導体装置。
(付記11)
前記第2の高抵抗層の膜厚は、前記第1の高抵抗層の膜厚よりも薄いことを特徴とする付記10に記載の半導体装置。
(付記12)
前記第2の多層中間層の膜厚は、前記第1の多層中間層の膜厚の膜厚よりも薄いことを特徴とする付記9から11のいずれかに記載の半導体装置。
(付記13)
前記第2の多層中間層における(GaN層の膜厚)/(AlN層の膜厚)の膜厚比は、前記第1の多層中間層における(GaN層の膜厚)/(AlN層の膜厚)の膜厚比よりも大きいことを特徴とする付記9から12のいずれかに記載の半導体装置。
(付記14)
前記高抵抗となる不純物元素は、Feであることを特徴とする付記1から13のいずれかに記載の半導体装置。
(付記15)
前記基板の上にはバッファ層が形成されており、前記バッファ層の上には前記高抵抗層が形成されているものであって、
前記バッファ層は、AlNまたはAlGaNにより形成されているものであることを特徴とする付記1から14のいずれかに記載の半導体装置。
(付記16)
前記電子走行層は、GaNを含む材料により形成されていることを特徴とする付記1から15のいずれかに記載の半導体装置。
(付記17)
前記電子供給層は、AlGaNを含む材料により形成されていることを特徴とする付記1から16のいずれかに記載の半導体装置。
(付記18)
前記電子供給層の上には、ゲート電極、ソース電極及びドレイン電極が形成されているものであることを特徴とする付記1から17のいずれかに記載の半導体装置。
(付記19)
付記1から18のいずれかに記載の半導体装置を有することを特徴とする電源装置。
(付記20)
付記1から18のいずれかに記載の半導体装置を有することを特徴とする増幅器。
12 核形成層
13 バッファ層
14 高抵抗層
15 多層中間層
16 電子走行層
16a 2DEG
17 電子供給層
21 ゲート電極
22 ソース電極
23 ドレイン電極
Claims (5)
- 基板の上に形成された半導体材料に高抵抗となる不純物元素がドープされた高抵抗層と、
前記高抵抗層の上に形成された多層中間層と、
前記多層中間層の上に半導体材料により形成された電子走行層と、
前記電子走行層の上に半導体材料により形成された電子供給層と、
を有し、
前記多層中間層は、GaN層とAlN層とが交互に積層された多層膜により形成されており、
前記高抵抗層は第1の高抵抗層であり、前記多層中間層は第1の多層中間層であって、
前記第1の多層中間層の上に形成された半導体材料に高抵抗となる不純物元素がドープされた第2の高抵抗層と、
前記第2の高抵抗層の上に形成された第2の多層中間層と、
を有し、前記電子走行層は、前記第2の多層中間層の上に形成されるものであって、
前記第2の多層中間層は、GaN層とAlN層とが交互に積層された多層膜により形成されており、
前記第2の多層中間層における(GaN層の膜厚)/(AlN層の膜厚)の膜厚比は、前記第1の多層中間層における(GaN層の膜厚)/(AlN層の膜厚)の膜厚比よりも大きいことを特徴とする半導体装置。 - 前記第1の多層中間層において、GaN層の膜厚が20〜50nmであり、AlN層の膜厚が2〜5nmであることを特徴とする請求項1に記載の半導体装置。
- 前記第2の高抵抗層における高抵抗となる不純物元素のドーピング濃度は、前記第1の高抵抗層における高抵抗となる不純物元素のドーピング濃度よりも低いことを特徴とする請求項1または2に記載の半導体装置。
- 前記高抵抗となる不純物元素は、Feであることを特徴とする請求項1から3のいずれかに記載の半導体装置。
- 前記基板の上にはバッファ層が形成されており、前記バッファ層の上には前記高抵抗層が形成されているものであって、
前記バッファ層は、AlNまたはAlGaNにより形成されているものであることを特徴とする請求項1から4のいずれかに記載の半導体装置。
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JP5013218B2 (ja) * | 2009-02-05 | 2012-08-29 | 日立電線株式会社 | 半導体エピタキシャルウェハの製造方法、並びに電界効果トランジスタの製造方法 |
JP2010232297A (ja) * | 2009-03-26 | 2010-10-14 | Sumitomo Electric Device Innovations Inc | 半導体装置 |
JP5631034B2 (ja) * | 2009-03-27 | 2014-11-26 | コバレントマテリアル株式会社 | 窒化物半導体エピタキシャル基板 |
JP5334057B2 (ja) * | 2009-11-04 | 2013-11-06 | Dowaエレクトロニクス株式会社 | Iii族窒化物積層基板 |
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2011
- 2011-09-28 JP JP2011213473A patent/JP5987288B2/ja active Active
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- 2012-07-12 US US13/547,349 patent/US20130075786A1/en not_active Abandoned
- 2012-07-13 TW TW101125302A patent/TWI482279B/zh not_active IP Right Cessation
- 2012-07-27 CN CN201210265578.0A patent/CN103035698B/zh active Active
- 2012-07-31 KR KR1020120083856A patent/KR101340142B1/ko not_active IP Right Cessation
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US20150034967A1 (en) | 2015-02-05 |
KR101340142B1 (ko) | 2013-12-10 |
US20130075786A1 (en) | 2013-03-28 |
JP2013074211A (ja) | 2013-04-22 |
CN103035698A (zh) | 2013-04-10 |
TW201314889A (zh) | 2013-04-01 |
KR20130034582A (ko) | 2013-04-05 |
TWI482279B (zh) | 2015-04-21 |
CN103035698B (zh) | 2015-11-25 |
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