JP5782268B2 - Reflective polarizing film for stereoscopic glasses, polarizing plate comprising the same, and stereoscopic glasses - Google Patents

Description

  The present invention relates to a reflective polarizing film having a high transmittance and a high degree of polarization suitable for stereoscopic glasses for allowing an observer to recognize stereoscopic images, a polarizing plate comprising the same, and stereoscopic glasses. Reflective polarizing film for stereoscopic glasses having a high transmittance and a high degree of polarization using a uniaxially stretched multilayer laminated film, suitable for stereoscopic glasses for allowing an observer to recognize an image, a polarizing plate comprising the same, and stereoscopic glasses About.

  Conventionally, right-eye video and left-eye video are alternately displayed on the screen at a constant cycle. In stereoscopic glasses worn by an observer, the right-eye liquid crystal and the left eye are synchronized with the fixed cycle. A three-dimensional video display system is known in which transmission and non-transmission in an ophthalmic liquid crystal are alternately performed to allow an observer to view stereoscopically. This system is called a shutter system, and stereoscopic glasses used for the shutter system are called liquid crystal shutter glasses.

  As another type of three-dimensional image display system, a polarization method is known. In this polarization method, light from a light source is transmitted through a first liquid crystal panel on which a right-eye image is formed to obtain right-eye image light, which is projected on a screen and a left-eye image is formed. 2 The light from the light source is transmitted through the liquid crystal panel to obtain the left-eye image light, which is projected onto the screen, and the polarization directions of the light transmitted through the first liquid crystal panel and the second liquid crystal panel are mutually In the stereoscopic glasses worn by the observer in correspondence with this, the polarization directions of the transmitted light are mutually different in the right-eye polarizing plate and the left-eye polarizing plate. By making the angle different by approximately 90 °, the right eye image is guided to the observer's right eye and the left eye image is guided to the observer's left eye, respectively, so that stereoscopic viewing is performed.

  In the polarization method, when the observer's stereoscopic glasses are tilted, the polarization axis shifts. Therefore, as an improvement measure, the first liquid crystal panel in which the right eye image is formed and the first liquid crystal panel in which the left eye image is formed are used. (2) A λ / 2 plate or λ / 4 plate is provided in front of the liquid crystal panel, and a λ / 2 plate or λ / 4 plate is provided in front of the right-eye polarizing plate and the left-eye polarizing plate as different circularly polarized lights. A circular polarization system provided is known (for example, Patent Document 1).

  In any of the methods, the stereoscopic spectacles generally use an absorption type polarizing plate called a light absorption type dichroic linear polarizing plate as a polarizing plate, and PVA containing iodine is triacetylcellulose (TAC). The polarizing plate protected with) is widely used. Such an absorption-type polarizing plate transmits polarized light in the direction of the transmission axis and absorbs polarized light in the direction orthogonal to the transmission axis. However, absorption also occurs in polarized light in the direction of the transmission axis, and the transmittance is low. There was a problem that it decreased.

  On the other hand, as an example of a reflective polarizer, a configuration in which a reflective polarizer called a brightness enhancement film is used between a light source and a liquid crystal panel in order to effectively use polarized light orthogonal to the transmission axis has been studied. Therefore, a polymer type film using optical interference has been studied (for example, Patent Document 2).

However, the reflective polarizing polymer film (for example, Patent Documents 3 to 5) using a birefringent multilayer structure as studied conventionally reflects polarized light in a direction orthogonal to the transmission axis, and polarized light in the transmission axis direction. Although it has a function of transmitting light, its degree of polarization has not reached the same level as that of the absorption polarizing plate.
Similarly, polyethylene-2,6-naphthalene dicarboxylate (hereinafter sometimes referred to as 2,6-PEN) described in Patent Document 4 is used for the high refractive index layer, and a thermoplastic elastomer or isophthalic acid is used. A multilayer laminated film using 30 mol% copolymerized PEN as a low refractive index layer is polarized parallel to the X direction (perpendicular to the transmission axis) by increasing the refractive index difference between the stretching directions (X direction) by stretching. While increasing the transmittance of polarized light parallel to the Y direction (transmission axis direction) by reducing the difference in refractive index between layers in the direction perpendicular to the X direction (Y direction) in the in-plane direction of the film. Although it exhibits a level of polarization performance, the degree of polarization has not reached the same level as that of the absorption polarizing plate.

  For this reason, it is difficult to use such a multilayer polymer film alone as a polarizing plate in place of the absorbing polarizing plate, and it has not yet been put to practical use as a polarizing plate for stereoscopic glasses.

Japanese Patent Laid-Open No. 10-232365 JP-T 09-507308 JP 04-268505 A JP-T 09-506837 WO01 / 47711 pamphlet

  The object of the present invention is a reflective polarizing film using a uniaxially stretched multilayer laminated film, but has a higher polarization performance than a conventional reflective polarizing plate, and more parallel to the transmission axis than an absorptive polarizing plate. An object of the present invention is to provide a reflective polarizing film suitable for stereoscopic glasses for allowing an observer to recognize a stereoscopic image, which has a high transmittance with respect to various polarized light, and a polarizing plate and stereoscopic glasses comprising the same.

As a result of intensive studies to solve the above problems, the present inventors have obtained the following knowledge. That is, in the conventional multilayer laminated reflective polarizing film, the refractive index in the X direction is changed by uniaxial stretching instead of polyethylene-2,6-naphthalenedicarboxylate, which has been used as a resin constituting the high refractive index layer. On the other hand, by using a thermoplastic resin having a characteristic that the refractive index in both the Y direction and the Z direction decreases, the refractive index difference between the X direction and the Y direction of the first layer after uniaxial stretching can be made larger than before. It becomes possible to enlarge. As a result, higher reflection performance can be obtained for polarized light parallel to the X direction, that is, polarized light perpendicular to the transmission axis, as compared to a multilayer laminated reflective polarizing film using conventional polyethylene-2,6-naphthalenedicarboxylate. In addition, polarized light in the orthogonal direction (transmission axis direction, Y direction in the present invention) can be selectively transmitted, and higher polarization performance can be obtained than the conventional reflective polarizing film, and absorption polarization in the transmission axis direction. It has been found that a higher permeability than the plate can be obtained.
Based on this knowledge, the present inventors, when using a reflective polarizing plate made of a multilayer laminated film alone for stereoscopic glasses as a polarizing plate instead of an absorbing polarizing plate, than the conventional reflective polarizing plate. High polarization performance and high transparency in the direction of the transmission axis compared to the absorption type polarizing plate, so the field of view is bright when used for stereoscopic glasses, and the visibility of stereoscopic images and other than stereoscopic images The present inventors have found that it is excellent in visibility and have completed the present invention.

That is, an object of the present invention is a reflective polarizing film made of a uniaxially stretched multilayer laminate film, and the uniaxially stretched multilayer laminate film has a multilayer structure in which first layers and second layers are alternately laminated. The first layer comprises a polyester of a dicarboxylic acid component and a diol component,
(I) The dicarboxylic acid component contains a component represented by the following formula (A) of 5 mol% to 50 mol% and a component represented by the following formula (B) of 50 mol% to 95 mol%. ,
(In the formula (A), R ^A represents an alkylene group having 2 to 10 carbon atoms)
(In the formula (B), R ^B represents a phenylene group or a naphthalenediyl group)
(Ii) The diol component contains 90 to 100 mol% of a component represented by the following formula (C),
(In the formula (C), R ^C represents an alkylene group having 2 to 10 carbon atoms)
The uniaxially stretched multilayer laminated film is stretched only in the uniaxial direction, the number of laminated layers is 251 to 501 layers, and the film thickness is 15 to 40 μm,
With the film surface of the uniaxially stretched multilayer laminated film as a reflective surface, the polarization component parallel to the incident surface including the uniaxially stretched direction (X direction) has a wavelength of 400 to 800 nm with respect to the incident polarized light at an incident angle of 0 degree. With respect to a polarized light component having an average reflectance of 98% or more, a film surface as a reflecting surface, and perpendicular to the incident surface including the X direction, an average reflectance with a wavelength of 400 to 800 nm with respect to the incident polarized light at an incident angle of 0 degree. Is achieved by the reflective polarizing film for stereoscopic glasses (item 1) having a ratio of 12% or less.

Moreover, the uniaxially stretched multilayer laminated film of the present invention includes a film having at least one of the following as a preferred embodiment .

Item 2 . Item 2. The reflective polarizing film for stereoscopic glasses according to Item 1 , wherein the thermoplastic resin forming the second layer is a polyester mainly comprising an ethylene terephthalate component copolymerized with isophthalic acid or 2,6-naphthalenedicarboxylic acid.
Item 3 . Item 1 or 2 wherein the average reflectance at a wavelength of 400 to 800 nm with respect to the incident polarized light at an incident angle of 0 degree is 98.9% or more for a polarized light component parallel to the incident surface including the uniaxial stretching direction (X direction) The reflective polarizing film for stereoscopic glasses described in 1.
Item 4 . Item 4. The reflective polarizing film for stereoscopic glasses according to any one of Items 1 to 3, wherein the ratio of the average layer thickness of the second layer to the average layer thickness of the first layer is in the range of 1.5 to 5.0.
Item 5 . Item 5. A polarizing plate comprising the reflective polarizing film for stereoscopic glasses according to any one of Items 1 to 4 .
Item 6 . Item 6. The polarizing plate according to Item 5 , further comprising a λ / 4 wavelength film.
Item 7. Item 7. The polarizing plate according to Item 6 , which has an antireflection layer between air and the λ / 4 wavelength film at least on the λ / 4 wavelength film side.
Item 8. Item 8. Stereoscopic glasses using the polarizing plate according to any one of items 5 to 7 .

  According to the present invention, although it is a reflective polarizing film using a uniaxially stretched multilayer laminated film, it has sufficiently high polarization performance as stereoscopic glasses, and further has a transmission axis direction as compared with an absorptive polarizing plate. Because of its high transparency, it has a bright field of view when used for stereoscopic glasses and has excellent visibility of 3D images and non-stereoscopic images. Therefore, it is possible to provide a reflective polarizing film for stereoscopic glasses, a polarizing plate comprising the same, and stereoscopic glasses.

FIG. 1 shows refractive indexes (n _X , n _Y , respectively) in the stretching direction (X direction) after uniaxial stretching of 2,6-PEN, the direction orthogonal to the stretching direction (Y direction), and the thickness direction (Z direction). n _Z ). FIG. 2 shows the refractive index in the stretching direction (X direction) after uniaxial stretching of the aromatic polyester (I) for the first layer in the present invention, the direction orthogonal to the stretching direction (Y direction), and the thickness direction (Z direction). (Represented as n _X , n _Y , and n _Z , respectively). FIG. 3 shows a film surface of the uniaxially stretched multilayer laminated film of the present invention as a reflective surface, a polarization component (p light component) parallel to the incident surface including the stretching direction (X direction), and the stretching direction (X direction). Is an example of a graph of the reflectance at an incident angle of 0 ° with respect to the wavelength of a polarized light component (s light component) perpendicular to the incident surface. FIG. 4 is a schematic cross-sectional view of a circularly polarizing plate. FIG. 5 is a schematic view of stereoscopic glasses using a circularly polarizing plate, FIG. 5 (a) is a schematic front view of the stereoscopic glasses, and FIG. 5 (b) is a schematic top view of the stereoscopic glasses. FIG. 6 is a schematic cross-sectional view of a circularly polarizing plate including an antireflection layer on one side. FIG. 7 is a schematic cross-sectional view of a circularly polarizing plate including antireflection layers on both sides.

The present invention will be described in detail below.
[Uniaxially stretched multilayer laminated film]
(Average reflectance)
The reflective polarizing film for stereoscopic glasses of the present invention is a reflective polarizing film made of a uniaxially stretched multilayer laminated film, and includes a uniaxially stretched direction (X direction) with the film surface of the uniaxially stretched multilayer laminated film as a reflective surface. With respect to the polarized light component parallel to the incident surface, the average reflectance at a wavelength of 400 to 800 nm with respect to the incident polarized light at an incident angle of 0 degree is 95% or more, the film surface is the reflective surface, and the incident surface includes the X direction. With respect to a vertical polarization component, the average reflectance at a wavelength of 400 to 800 nm with respect to the incident polarized light at an incident angle of 0 degree is 12% or less.

  Here, the incident surface refers to a surface that is perpendicular to the reflecting surface and includes the incident light beam and the reflected light beam. In addition, in the present invention, the polarized light component parallel to the incident surface including the stretching direction (X direction) of the uniaxially stretched film is p-polarized light, polarized light orthogonal to the transmission axis, and extinction axis direction. Sometimes referred to as polarized light or polarized light in the direction of the reflection axis. Further, in the present invention, the polarization component perpendicular to the incident surface including the stretching direction (X direction) of the uniaxially stretched film with the film surface as the reflective surface may be referred to as s-polarized light and polarized light in the transmission axis direction. Furthermore, the incident angle represents an incident angle with respect to a direction perpendicular to the film surface.

  With respect to the polarization component parallel to the incident surface including the stretching direction (X direction) of the uniaxially stretched film with the film surface as the reflecting surface, the average reflectance at a wavelength of 400 to 800 nm with respect to the incident polarized light at an incident angle of 0 degree is More preferably, it is 98% or more and 100% or less. Since the average reflectance with respect to the p-polarized component is thus high, the transmission amount of the p-polarized light is suppressed as compared with the conventional one, and a high polarization performance for selectively transmitting the s-polarized light is exhibited, which is higher than the conventional reflective polarizing plate. Polarization performance is obtained.

In addition, with respect to the polarization component parallel to the incident surface including the stretching direction (X direction) of the uniaxially stretched film with the film surface as the reflecting surface, the average reflection at a wavelength of 400 to 800 nm with respect to the incident polarized light at an incident angle of 50 degrees. The rate is preferably 95% or more, more preferably 96% or more and 99% or less. Since the average reflectance of p-polarized light at an incident angle of 50 degrees is high in this way, high polarization performance is obtained, and transmission of light incident in an oblique direction is highly suppressed. Is suppressed.
The average of the wavelength of 400 to 800 nm with respect to the incident polarized light at an incident angle of 0 degree with respect to the polarization component (s-polarized light) perpendicular to the incident surface including the stretching direction (X direction) of the uniaxially stretched film with the film surface as the reflecting surface. The reflectance is more preferably 5% or more and 12% or less, further preferably 8% or more and 12% or less, and particularly preferably 9% or more and 11% or less.
Further, with the film surface as a reflection surface, a wavelength component of 400 to 800 nm with respect to the incident polarized light at an incident angle of 50 degrees with respect to a polarization component (s-polarized light) perpendicular to the incident surface including the stretching direction (X direction) of the uniaxially stretched film. The average reflectance is preferably 12% or less, more preferably 5% or more and 10% or less, and particularly preferably 8% or more and 10% or less.

By limiting the average reflectance of the wavelength 400 to 800 nm with respect to the s-polarized component within this range, the amount of s-polarized light transmitted to the side opposite to the light source increases, and the transmittance for s-polarized light increases. On the other hand, when the average reflectance with respect to the s-polarized component exceeds the upper limit, the polarization transmittance as a reflective polarizing film is lowered, so that it is not possible to obtain an improved polarization performance as compared with the conventional reflective polarizing plate, A clear image cannot be visually recognized as a polarizing plate or a circular polarizing plate of stereoscopic glasses. Furthermore, since the transmittance is not high in the transmission axis direction, the field of view becomes dark, and thus the visibility of the stereoscopic video and the visibility other than the stereoscopic video are not sufficient.
On the other hand, although the transmittance of the s-polarized component is higher when the polarization reflectance is lower than the above range, it may be difficult to lower the lower limit than the lower limit.

The average of the wavelength of 400 to 800 nm with respect to the incident polarized light at an incident angle of 0 degree with respect to the polarization component (s-polarized light) perpendicular to the incident surface including the stretching direction (X direction) of the uniaxially stretched film with the film surface as the reflecting surface. The transmittance is preferably 88% or more, more preferably 88% or more and 95% or less, further preferably 88% or more and 92% or less, and particularly preferably 89% or more and 91% or less.
Further, with the film surface as a reflection surface, a wavelength component of 400 to 800 nm with respect to the incident polarized light at an incident angle of 50 degrees with respect to a polarization component (s-polarized light) perpendicular to the incident surface including the stretching direction (X direction) of the uniaxially stretched film. The average transmittance is preferably 88% or more, more preferably 90% or more and 95% or less, and particularly preferably 90% or more and 92% or less.

When the average transmittance at a wavelength of 400 to 800 nm with respect to the s-polarized component is within such a range, the amount of s-polarized light transmitted to the side opposite to the light source increases. On the other hand, when the average transmittance for the s-polarized component is less than the lower limit, the polarization transmittance as a reflective polarizing film is lowered, and it is not possible to obtain an improved polarization performance as compared with the conventional reflective polarizing plate. A clear image cannot be viewed as a polarizing plate or a circular polarizing plate of stereoscopic glasses. Furthermore, since the transmittance is not high in the transmission axis direction, the field of view becomes dark, and thus the visibility of the stereoscopic video and the visibility other than the stereoscopic video are not sufficient.
On the other hand, the higher the average transmittance within this range, the higher the transmittance of the s-polarized component, but it may be difficult to make it lower than the lower limit because of the composition and stretching.

  In order to obtain such an average reflectance characteristic for the p-polarized light component, the uniaxially stretched multilayer laminated film constituted by alternately laminating the first layer and the second layer has a refractive index characteristic described later as a polymer constituting each layer. The first layer and the second layer in the stretching direction (X direction) are formed by using a polymer and stretching the film in-plane direction of the first layer in the stretching direction (X direction) at a constant stretching ratio. This is achieved by increasing the refractive index difference. Moreover, in order to obtain this average reflectance in a wavelength range of 400 to 800 nm, a method of adjusting the thicknesses of the first layer and the second layer can be mentioned.

  In addition, in order to obtain such an average reflectance characteristic or average transmittance characteristic for the s-polarized component, in the uniaxially stretched multilayer laminated film constituted by alternately laminating the first layer and the second layer, the polymer component constituting each layer As the first in the orthogonal direction (Y direction) by using a polymer having a refractive index characteristic to be described later and not stretching in the direction perpendicular to the stretching direction (Y direction) or only stretching at a low stretching ratio. This is achieved by making the refractive index difference between the layer and the second layer extremely small. Moreover, in order to obtain this average reflectance in a wavelength range of 400 to 800 nm, a method of adjusting the thicknesses of the first layer and the second layer can be mentioned.

[First layer]
The uniaxially stretched multilayer laminated film of the present invention has a multilayer structure in which first layers and second layers are alternately laminated. In the present invention, the first layer represents a layer having a higher refractive index than the second layer, and the second layer represents a layer having a lower refractive index than the first layer. Further, the refractive index in the stretching direction (X direction) may be described as n _X , the refractive index in the direction orthogonal to the stretching direction (Y direction) as n _Y , and the refractive index in the film thickness direction (Z direction) as _NZ. is there.

In the present invention, the thermoplastic resin constituting the first layer has an average refractive index of 1.60 or more and 1.70 or less, and the refractive index n _{X in the} uniaxial stretching direction (X direction) is increased by stretching, and the film surface refractive index n _Y and film refractive index n _Z in the thickness direction (Z direction) in a direction perpendicular inner in the uniaxial stretching direction (Y-direction) is a thermoplastic resin having a characteristic to decrease by stretching.

Polyethylene-2,6-naphthalene dicarboxylate has hitherto been known as the most suitable material as the first layer of the multilayer laminated film having a reflective polarization function. refractive index n _Y in the Y direction before and after stretching is mostly unchanging material. On the other hand, the thermoplastic resin constituting the first layer of the present invention is most characterized in that the refractive index nY in the _Y direction decreases with stretching, as with the refractive index nZ in the _Z direction, due to stretching.
In the multilayer laminated film having the reflective polarization function, the thermoplastic resin having the refractive index characteristic of the present invention, which has not been conventionally known as the resin constituting the first layer, is used for the first layer, and the second layer thermoplastic, which will be described later. By combining with a resin to form a multilayer laminated film, high polarization performance that has been difficult with conventional multilayer laminated films is manifested. Therefore, it can be used as a reflective polarizing film suitable for stereoscopic glasses for making an observer recognize a stereoscopic image, and can be suitably used as a polarizing plate for stereoscopic glasses.

  Here, the average refractive index in the present invention means that the thermoplastic resin constituting the first layer is melted alone, extruded from a die to create an unstretched film, and the obtained film in the X direction, Y direction, Z The refractive index in each direction is measured at a wavelength of 633 nm using a Metricon prism coupler, and the average value thereof is defined as the average refractive index.

Moreover, about the refractive index change of each direction by extending | stretching, it can obtain | require by the following method. That is, the thermoplastic resin constituting the first layer is melted alone and extruded from a die to produce an unstretched film. For each of the X direction, Y direction, and Z direction of the obtained film, the refractive index at a wavelength of 633 nm is measured using a metricon prism coupler, the average refractive index is obtained from the average value of the refractive indexes in three directions, and stretched. The previous refractive index.
Next, for the refractive index after stretching, the thermoplastic resin constituting the first layer is melted alone and extruded from a die to create a uniaxially stretched film by applying 5 times at 135 ° C. in the uniaxial direction, For each of the X direction, Y direction, and Z direction of the obtained film, the refractive index at a wavelength of 633 nm is measured using a metricon prism coupler to obtain the refractive index in each direction after stretching.
By comparing the refractive index before stretching obtained by such a method with the refractive index in each direction after stretching, the change in the refractive index due to stretching can be confirmed.

  The lower limit value of the average refractive index of the thermoplastic resin of the first layer is more preferably 1.61, and still more preferably 1.62. The upper limit of the average refractive index of the thermoplastic resin of the first layer is more preferably 1.69, and still more preferably 1.68. When the average refractive index of the thermoplastic resin of the first layer is within such a range, the refractive index difference in each direction between the stretched second layer and the second layer can be set to a desired range. On the other hand, when the average refractive index of the thermoplastic resin of the first layer is less than the lower limit value, the refractive index difference with the second layer is close, and the refractive index difference in the X direction after stretching cannot be sufficiently increased. . When the average refractive index of the thermoplastic resin of the first layer exceeds the upper limit value, the refractive index difference with the second layer after stretching becomes large, and the refractive index difference between the layers in the Y direction and Z direction after stretching becomes small. It is hard to do.

The refractive index n _X in the X direction of the thermoplastic resin of the first layer is preferably increased by 0.20 or more by stretching, more preferably 0.25 or more, and further preferably 0.27 or more. The larger the change in the refractive index, the higher the polarization performance can be improved, but the upper limit value is limited to 0.35 and further 0.30 because the film breaks when the draw ratio is too high. .

The refractive index n _Y in the Y direction of the thermoplastic resin of the first layer is preferably lowered in the range of 0.05 or more and 0.20 or less by stretching, more preferably 0.06 or more and 0.15 or less, and still more preferably. Is 0.07 or more and 0.10 or less. When the amount of decrease in the refractive index is less than the lower limit, if the resins in both layers are selected so that the interlayer refractive index in the Y direction matches, the difference in the refractive index between the layers in the X direction increases. The refractive index shift between the layers increases, and a hue shift of transmitted polarized light with respect to obliquely incident light may occur. When used as stereoscopic glasses, a hue shift may occur depending on the incident angle of the image light. On the other hand, when the amount of decrease in the refractive index exceeds the upper limit, the orientation is too high and the mechanical strength may not be sufficient.

The refractive index n _Z in the Z direction of the thermoplastic resin of the first layer is preferably lowered in the range of 0.05 to 0.20 by stretching, more preferably 0.06 to 0.15, and still more preferably. Is 0.07 or more and 0.10 or less. In order to make the amount of decrease in the refractive index less than the lower limit, the X direction must be lowly oriented, and the refractive index difference between the layers in the X direction may not be sufficiently large. On the other hand, when the amount of decrease in the refractive index exceeds the upper limit, the orientation is too high and the mechanical strength may not be sufficient.

The difference in refractive index between the Y-direction refractive index n _Y after stretching of the first layer and the Z-direction refractive index n _Z after stretching is preferably 0.05 or less, more preferably 0.03 or less, particularly preferably. 0.01 or less. Since the difference in refractive index between these two directions is very small, there is an effect that no hue shift occurs even when polarized light is incident at an oblique incident angle. Such polarized light is particularly effective in resolving the hue shift for the polarization component (s-polarized light) perpendicular to the incident surface including the stretching direction (X direction) of the uniaxially stretched film with the film surface as the reflecting surface. When used as stereoscopic glasses, hue reproducibility due to the incident angle of the image light does not occur, and the reproducibility of the image light is excellent.
As the thermoplastic resin having such refractive index characteristics, specifically, an aromatic polyester having a copolymer component having a specific structure as described below as a dicarboxylic acid component (hereinafter sometimes referred to as aromatic polyester (I)). Is exemplified.

<Aromatic polyester (I)>
Examples of the thermoplastic resin forming the first layer include aromatic polyester (I) having a copolymer component having a specific structure as a dicarboxylic acid component. Such a polyester is obtained by polycondensation of a dicarboxylic acid component and a diol component described in detail below.
(Dicarboxylic acid component)
As a dicarboxylic acid component (i) constituting the aromatic polyester (I) of the present invention, a component represented by the following formula (A) of 5 mol% or more and 50 mol% or less, and 50 mol% or more and 95 mol% or less of At least two kinds of aromatic dicarboxylic acid components or derivatives thereof, which are components represented by the following formula (B), are used. Here, the content of each aromatic dicarboxylic acid component is a content based on the total number of moles of the dicarboxylic acid component.

(In the formula (A), R ^A represents an alkylene group having 2 to 10 carbon atoms)

(In the formula (B), R ^B represents a phenylene group or a naphthalenediyl group)

About the component represented by Formula (A), in formula, ^RA is a C2-C10 alkylene group. Examples of the alkylene group include an ethylene group, a propylene group, an isopropylene group, a tetramethylene group, a hexamethylene group, and an octamethylene group.

The lower limit of the content of the component represented by the formula (A) is preferably 7 mol%, more preferably 10 mol%, still more preferably 15 mol%. Moreover, the upper limit of the content of the component represented by the formula (A) is preferably 45 mol%, more preferably 40 mol%, still more preferably 35 mol%, and particularly preferably 30 mol%.
Therefore, the content of the component represented by the formula (A) is preferably 5 mol% or more and 45 mol% or less, more preferably 7 mol% or more and 40 mol% or less, and further preferably 10 mol% or more and 35 mol% or less. Especially preferably, it is 15 mol% or more and 30 mol% or less.

The component represented by the formula (A) is preferably 6,6 ′-(ethylenedioxy) di-2-naphthoic acid, 6,6 ′-(trimethylenedioxy) di-2-naphthoic acid, and 6,6 ′-(ethylenedioxy) di-2-naphthoic acid. Components derived from 6 ′-(butyleneoxy) di-2-naphthoic acid are preferred. Among these, those having an even number of carbon atoms of R ^A in formula (A) are preferable, particularly derived from 6,6 ′-(ethylenedioxy) di-2-naphthoic acid represented by the following formula (A-1). Are preferred.

Such aromatic polyester (I) is characterized in that the dicarboxylic acid component contains a component represented by the formula (A) in an amount of 5 mol% to 50 mol%. When the ratio of the acid component represented by the formula (A) is less than the lower limit value, it is difficult for the refractive index in the Y direction to decrease due to uniaxial stretching.
The difference in refractive index n _Z of the refractive index n _Y and Z direction Y direction in the stretched film is increased, which may hue shift due polarized light incident at an incident angle of an oblique direction is generated. Further, if the proportion of the component represented by the formula (A) exceeds the upper limit value, amorphous characteristics becomes large, the difference between the refractive index n _Y in refractive index n _X and Y direction of the X-direction in the stretched film Therefore, sufficient reflection performance as a reflective polarizing film cannot be obtained.

Thus, by using the polyester containing the component represented by the formula (A), it is possible to produce a uniaxially stretched multilayer laminated film having higher polarization performance as a reflective polarizing film than in the past, and further in an oblique direction. Hue shift due to the incident angle can be suppressed.
Further, the acid component of the formula (B), wherein, R ^B is a phenylene group or naphthalene-diyl group.
Examples of the component represented by the formula (B) include components derived from terephthalic acid, isophthalic acid, 2,6-naphthalenedicarboxylic acid, 2,7-naphthalenedicarboxylic acid, or combinations thereof. -Preferred examples include components derived from naphthalenedicarboxylic acid.

The lower limit of the content of the component represented by the formula (B) is preferably 55 mol%, more preferably 60 mol%, still more preferably 65 mol%, and particularly preferably 70 mol%. Moreover, the upper limit of the content of the component represented by the formula (B) is preferably 93 mol%, more preferably 90 mol%, and still more preferably 85 mol%.
Therefore, the content of the component represented by the formula (B) is preferably 55 mol% or more and 95 mol% or less, more preferably 60 mol% or more and 93 mol% or less, and further preferably 65 mol% or more and 90 mol% or less. Particularly preferred is 70 mol% or more and 85 mol% or less.

If the proportion of the component represented by the formula (B) is less than the lower limit value, amorphous characteristics becomes large, the difference between the refractive index n _Y in refractive index n _X and Y direction of the X-direction in the stretched film Since it becomes small, sufficient performance as a reflective polarizing film is not exhibited. Moreover, when the ratio of the component shown by Formula (B) exceeds an upper limit, since the ratio of the component shown by Formula (A) becomes relatively small, the refractive indexes n _Y and Z in the Y direction in the stretched film The difference in refractive index _{NZ in} the direction becomes large, and a hue shift may occur due to polarized light incident at an oblique incident angle.
Thus, by using the polyester containing the component represented by the formula (B), it is possible to realize a birefringence characteristic having a high uniaxial orientation while exhibiting a high refractive index in the X direction.

(Diol component)
As the diol component (ii) constituting the aromatic polyester (I) of the present invention, a diol component represented by the following formula (C) of 90 mol% or more and 100 mol% or less is used. Here, the content of the diol component is a content based on the total number of moles of the diol component.

(In the formula (C), R ^C represents an alkylene group having 2 to 10 carbon atoms)

The content of the diol component represented by the formula (C) is preferably 95 mol% to 100 mol%, more preferably 98 mol% to 100 mol%.
In the formula (C), R ^C is an alkylene group having 2 to 10 carbon atoms, and examples of the alkylene group include an ethylene group, a propylene group, an isopropylene group, a tetramethylene group, a hexamethylene group, and an octamethylene group. . Among these, a component derived from ethylene glycol, trimethylene glycol, tetramethylene glycol, cyclohexane dimethanol, or the like is preferable as the diol component represented by the formula (C). Particularly preferred is a component derived from ethylene glycol. When the ratio of the diol component represented by the formula (C) is less than the lower limit, the above-described uniaxial orientation is impaired.

(Aromatic polyester (I))
In the aromatic polyester (I), the content of the ester unit (-(A)-(C)-) composed of the acid component represented by the formula (A) and the diol component represented by the formula (C) is , 5 mol% or more and 50 mol% or less of all repeating units, preferably 5 mol% or more and 45 mol% or less, more preferably 10 mol% or more and 40 mol% or less.

  As other ester units constituting the aromatic polyester (I), alkylene terephthalate units such as ethylene terephthalate, trimethylene terephthalate, butylene terephthalate, ethylene-2,6-naphthalene dicarboxylate, trimethylene-2,6-naphthalene dicarboxylate And alkylene-2,6-naphthalenedicarboxylate units such as butyl and butylene-2,6-naphthalenedicarboxylate. Among these, ethylene terephthalate units and ethylene-2,6-naphthalenedicarboxylate units are preferable, and ethylene-2,6-naphthalenedicarboxylate units are particularly preferable from the viewpoint of high refractive index.

As the aromatic polyester (I), in particular, the dicarboxylic acid component represented by the formula (A) is a dicarboxylic acid component represented by the formula (A-1),
A polyester in which the dicarboxylic acid component represented by the formula (B) is an aromatic dicarboxylic acid component derived from 2,6-naphthalenedicarboxylic acid and the diol component is ethylene glycol is preferred.

  The aromatic polyester (I) has an intrinsic viscosity of 0.4 to 3 dl / measured at 35 ° C. using a mixed solvent of P-chlorophenol / 1,1,2,2-tetrachloroethane (weight ratio 40/60). It is preferable that it is g, More preferably, it is 0.4-1.5 dl / g, Most preferably, it is 0.5-1.2 dl / g.

The melting point of the aromatic polyester (I) is preferably in the range of 200 to 260 ° C, more preferably in the range of 205 to 255 ° C, and still more preferably in the range of 210 to 250 ° C. The melting point can be determined by measuring with DSC.
If the melting point of the polyester exceeds the upper limit value, fluidity may be inferior when melt-extruded and molded, and discharge and the like may be made uneven. On the other hand, if the melting point is less than the lower limit, the film forming property is excellent, but the mechanical properties of the polyester are easily impaired, and the refractive index properties of the present invention are hardly exhibited.

  In general, a copolymer has a lower melting point than a homopolymer and tends to decrease mechanical strength. However, the polyester of the present invention is a copolymer containing the component of the formula (A) and the component of the formula (B), and has a lower melting point than the homopolymer having only the component of the formula (A). The mechanical strength is excellent.

The glass transition temperature (hereinafter sometimes referred to as Tg) of the aromatic polyester (I) is preferably 80 to 120 ° C, more preferably 82 to 118 ° C, and still more preferably 85 to 118 ° C. When Tg is within this range, a film having excellent heat resistance and dimensional stability can be obtained. Such melting point and glass transition temperature can be adjusted by controlling the kind and copolymerization amount of the copolymerization component and dialkylene glycol as a by-product.
The method for producing the aromatic polyester (I) can be produced, for example, according to the method described on page 9 of the pamphlet of WO2008 / 153188.

(Refractive index characteristics of aromatic polyester (I))
FIG. 2 shows an example of changes in the refractive index in each direction when the aromatic polyester (I) is uniaxially stretched. As shown in FIG. 2, the refractive index n _X in the X direction is in a direction that increases by stretching, the refractive index n _{Y in the Y} direction and the refractive index n _{Z in the} Z direction are both in a direction that decreases with stretching, and refractive index difference regardless of the draw ratio n _Y and n _Z is characterized by very small.

In addition, the first layer is uniaxially stretched using the aromatic polyester (I) containing the specific copolymer component, so that the refractive index n _{X in the} X direction is 1.80 to 1.90. Has characteristics. When the refractive index in the X direction in the first layer is within such a range, the refractive index difference from the second layer becomes large, and sufficient reflective polarization performance can be exhibited.

On the other hand, when the polyester constituting the first layer is polyethylene-2,6-naphthalenedicarboxylate, as shown in FIG. 1, the refractive index n _{Y in the} Y direction is constant regardless of the stretching ratio in the uniaxial direction. In contrast, the refractive index n _{Z in} the Z direction decreases as the uniaxial stretching ratio increases. For this reason, the difference between the refractive index n _{Y in the Y} direction and the refractive index n _{Z in} the Z direction becomes large, and when the polarized light is incident at an oblique incident angle, a hue shift is likely to occur. The original color of the image light may not be sufficiently reproduced depending on the incident angle of the image light.

[Second layer]
<Thermoplastic resin>
In the second layer of the present invention, the average refractive index in the X direction, Y direction, and Z direction before stretching is 1.50 or more and 1.60 or less, and the average refractive index before stretching and the X direction after stretching, It consists of a thermoplastic resin in which the difference between the refractive index in the Y direction and the Z direction is 0.05 or less in all three directions.
Here, the average refractive index in the X direction, Y direction, and Z direction before stretching in the second layer means that the thermoplastic resin constituting the second layer is melted alone and extruded from a die to create an unstretched film. The refractive index in each of the X direction, Y direction and Z direction of the obtained film was measured at a wavelength of 633 nm using a metricon prism coupler, and the average value thereof was defined as the average refractive index.

Regarding the refractive indices in the X direction, Y direction, and Z direction after stretching in the second layer, the thermoplastic resin constituting the second layer is melted alone and extruded from a die, and is 5 at 135 ° C. in a uniaxial direction. A uniaxially stretched film is prepared by stretching the film twice, and after stretching by measuring the refractive index at a wavelength of 633 nm using a metricon prism coupler in each of the X direction, Y direction, and Z direction of the obtained film. The refractive index in each direction is obtained.
The difference between the average refractive index before stretching determined in this way and the refractive index in the X direction, Y direction, and Z direction after stretching is obtained, and the difference is 0.05 or less in absolute value in all three directions. A thermoplastic resin having a refractive index characteristic is used for the second layer.
The average refractive index of the thermoplastic resin constituting the second layer is preferably from 1.53 to 1.60, more preferably from 1.55 to 1.60, and even more preferably from 1.58 to 1.60. is there. Since the second layer is an isotropic material having such an average refractive index and a small difference in refractive index before and after stretching, the refractive index difference in the X direction after stretching between the first layer and the second layer is reduced. As a result, high polarization performance can be obtained. Further, it is possible to obtain a refractive index characteristic in which both the refractive index difference in the Y direction and the refractive index difference in the Z direction are extremely small, and the hue deviation due to the incident angle in the oblique direction is favorable.

  Among thermoplastic resins having such a refractive index characteristic, a crystalline polyester is preferable from the viewpoint of film forming property in uniaxial stretching. As crystalline polyesters having such refractive index characteristics, copolymerized polyesters such as copolymerized polyethylene terephthalate and copolymerized polyethylene naphthalene dicarboxylate, blends of crystalline copolymerized polyesters, crystalline copolymerized polyesters and amorphous polyesters A blend with is preferably exemplified.

  Among the crystalline copolyesters, copolyethylene terephthalate is preferable, and polyesters mainly composed of an ethylene terephthalate component copolymerized with isophthalic acid or 2,6-naphthalenedicarboxylic acid are preferable, and particularly isophthalic acid or 2,6- A polyester having an ethylene terephthalate component copolymerized with naphthalenedicarboxylic acid as a main component and having a melting point of 220 ° C. or lower is preferable.

  In the case of copolymerized polyethylene terephthalate, the copolymer components other than the above components may be isophthalic acid or 2,6-naphthalene within a range of 10 mol% or less based on all repeating units constituting the polyester of the second layer. Aromatic carboxylic acids other than the main copolymer component among dicarboxylic acids and 2,7-naphthalenedicarboxylic acids; aliphatic dicarboxylic acids such as adipic acid, azelaic acid, sebacic acid and decanedicarboxylic acid; fats such as cyclohexanedicarboxylic acid Preferable examples include acid components such as cyclic dicarboxylic acids, aliphatic diols such as butanediol and hexanediol; and glycol components such as alicyclic diols such as cyclohexanedimethanol.

In addition, the aromatic polyester (I) used in the first layer of the present invention can be used as the copolymerized polyethylene naphthalene dicarboxylate. In such a case, in order to obtain the refractive index characteristic of the second layer of the present invention, It is preferably used by blending with a crystalline copolymerized polyester. Examples of other crystalline copolyesters include polycyclohexanedimethylene terephthalate copolymers.
In addition, the melting point of the thermoplastic resin constituting the second layer does not have to be low from the stage before forming the film, and may be low after the stretching treatment. For example, two or more kinds of polyesters may be blended and transesterified at the time of melt kneading.

[Laminated structure]
(Number of layers)
In the uniaxially stretched multilayer laminated film of the present invention, it is preferable that the above-mentioned first layer and second layer are alternately laminated in a total of 251 layers. When the number of stacked layers is less than 251 layers, the average reflectance characteristics of the polarization component parallel to the incident surface including the stretching direction (X direction) may satisfy a certain average reflectance over a wavelength range of 400 to 800 nm. There are things that cannot be done.
The upper limit of the number of layers is limited to 2001 layers from the viewpoints of productivity and film handling. As long as the average reflectance characteristic of the present invention is obtained, the upper limit value of the number of layers may be further reduced from the viewpoint of productivity and handling properties, and may be, for example, 1001, 501 and 301 layers.

(Each layer thickness)
Since the first layer and the second layer selectively reflect light by optical interference between layers, the thickness of each layer is 0.01 μm or more and 0.5 μm or less. The thickness of each layer of the first layer is preferably 0.01 μm or more and 0.1 μm or less, and the thickness of each layer of the second layer is preferably 0.01 μm or more and 0.3 μm or less. The thickness of each layer can be determined based on a photograph taken using a transmission electron microscope.

  Since the reflection wavelength band shown by the uniaxially stretched multilayer laminated film of the present invention is from the visible light region to the near infrared region, it is efficiently visible by setting the thickness of each layer to such a range for the first layer and the second layer. The reflectance characteristics from the light region to the near infrared region can be obtained. When the layer thickness exceeds 0.5 μm, the reflection band is in the infrared region. On the other hand, when the layer thickness is less than 0.01 μm, the polyester component absorbs light and the reflection performance cannot be obtained.

(Ratio of maximum layer thickness to minimum layer thickness)
In the uniaxially stretched multilayer laminated film of the present invention, the ratio between the maximum layer thickness and the minimum layer thickness in each of the first layer and the second layer is 2.0 or more and 5.0 or less, more preferably 2.0. It is 4.0 or more, more preferably 2.0 or more and 3.5 or less, and particularly preferably 2.0 or more and 3.0 or less.
That is, the ratio between the maximum layer thickness and the minimum layer thickness in the first layer is 2.0 or more and 5.0 or less, and the ratio between the maximum layer thickness and the minimum layer thickness in the second layer is 2.0 or more and 5.0 or less. It is.

For example, in a multilayer stretched film having 126 first layers and 125 second layers, the maximum layer thickness of the first layer is the thickness of the largest layer among the first layers of 126 layers. is there. The minimum layer thickness of the first layer is the thickness of the smallest layer among the 126 first layers.
The ratio of the layer thickness is specifically represented by the ratio of the maximum layer thickness to the minimum layer thickness. The maximum layer thickness and the minimum layer thickness in each of the first layer and the second layer can be obtained based on a photograph taken using a transmission electron microscope.

In the multilayer laminated film, the wavelength to be reflected is determined by the difference in refractive index between layers, the number of layers, and the thickness of the layer. However, when each of the laminated first and second layers has a constant thickness, only a specific wavelength is reflected. The average reflectance of the polarization component parallel to the incident surface including the stretching direction (X direction) cannot be increased uniformly over a wide wavelength range of 400 to 800 nm. In addition, when the ratio between the maximum layer thickness and the minimum layer thickness exceeds the upper limit value, the reflection band is too wide, and the reflectivity of the polarization component parallel to the incident surface including the stretching direction (X direction) is decreased. There is.
The layer thicknesses of the first layer and the second layer may change stepwise or may change continuously. By changing each of the first layer and the second layer laminated in this way, light in a wider wavelength range can be reflected.

  The method for laminating the multilayer structure in the uniaxially stretched multilayer laminated film of the present invention is not particularly limited. For example, the first layer is obtained by branching 137 layers of polyester for the first layer and 138 layers of thermoplastic resin for the second layer. And a second layer are alternately laminated, and a method of using a multilayer feed block device in which the flow path continuously changes by 2.0 to 5.0 times is mentioned.

(Average layer thickness ratio of the first layer and the second layer)
In the uniaxially stretched multilayer laminated film of the present invention, the ratio of the average layer thickness of the second layer to the average layer thickness of the first layer is preferably in the range of 1.5 to 5.0 times. The lower limit value of the ratio of the average layer thickness of the second layer to the average layer thickness of the first layer is more preferably 2.0. The upper limit of the ratio of the average layer thickness of the second layer to the average layer thickness of the first layer is more preferably 4.0, and even more preferably 3.5.

Since the ratio of the average layer thickness of the second layer to the average layer thickness of the first layer is in such a range, secondary reflection occurring at a half wavelength of the reflection wavelength can be effectively used. Therefore, each of the first layer and the second layer The ratio of the maximum layer thickness to the minimum layer thickness can be minimized, which is preferable from the viewpoint of optical characteristics. In addition, by changing the thickness ratio of the first layer and the second layer in this way, the mechanical properties of the obtained film are also adjusted while maintaining the adhesion between the layers and without changing the resin used. And has an effect of making the film difficult to tear.
On the other hand, when the ratio of the average layer thickness of the second layer to the average layer thickness of the first layer deviates from this range, the secondary reflection that occurs at the half wavelength of the reflection wavelength becomes small, and the reflectance may decrease. .

(Thickness adjustment layer)
In addition to the first layer and the second layer, the uniaxially stretched multilayer laminated film of the present invention has a thickness adjusting layer having a layer thickness of 2 μm or more in a part of the alternately laminated structure of the first layer and the second layer. May be. By having the thickness adjusting layer having such a thickness as a part of the alternately laminated structure of the first layer and the second layer, the thickness of each layer constituting the first layer and the second layer can be made uniform without affecting the polarization function. Easy to adjust. The thickness adjusting layer having such a thickness may be the same composition as either the first layer or the second layer, or a composition partially including these compositions. Since the layer thickness is thick, the thickness adjusting layer does not contribute to the reflection characteristics.

[Uniaxially stretched film]
The uniaxially stretched multilayer laminated film of the present invention is stretched in at least a uniaxial direction in order to satisfy the optical properties as the target reflective polarizing film. The uniaxial stretching in the present invention includes not only a film stretched only in a uniaxial direction but also a film stretched in a biaxial direction and further stretched in one direction. The uniaxial stretching direction (X direction) may be either the film longitudinal direction or the width direction. Further, in the case of a film stretched in a biaxial direction and stretched in one direction, the direction (X direction) that is more stretched may be either the film longitudinal direction or the width direction. In the direction where the draw ratio is low, it is preferable that the draw ratio is about 1.05 to 1.20 times from the viewpoint of improving the polarization performance. In the case of a film stretched in a biaxial direction and stretched in one direction, the “stretch direction” in relation to polarized light and refractive index refers to a more stretched direction.
As the stretching method, known stretching methods such as heat stretching with a rod heater, roll heat stretching, and tenter stretching can be used, but tenter stretching is preferable from the viewpoint of reducing scratches due to contact with the roll and stretching speed.

[Refractive index characteristics between the first layer and the second layer]
The X-direction refractive index difference between the first layer and the second layer is preferably 0.10 to 0.45, more preferably 0.20 to 0.40, and particularly preferably 0.25 to 0.30. is there. When the refractive index difference in the X direction is within such a range, the reflection characteristics can be improved efficiently, and a high reflectance can be obtained with a smaller number of layers.
Moreover, it is preferable that the difference in refractive index in the Y direction between the first layer and the second layer and the difference in refractive index in the Z direction between the first layer and the second layer are 0.05 or less, respectively. Since the refractive index difference between the layers in the Y direction and the Z direction is both in the above-described range, hue deviation can be suppressed when polarized light is incident at an oblique incident angle.

[Film thickness]
The uniaxially stretched multilayer laminated film of the present invention preferably has a film thickness of 15 μm or more and 40 μm or less. The conventional multilayer laminated film having a reflective polarization function needs to increase the number of layers in order to increase the average reflectance of p-polarized light, and the thickness of about 100 μm is necessary. The present invention constitutes the first layer. By using a resin whose refractive index in the Y direction decreases as a result of stretching as a thermoplastic resin, and combining it with the above-mentioned second layer thermoplastic resin, a multilayer multilayer film having a constant layer thickness is obtained. The film thickness can be made thinner.

[Method for producing uniaxially stretched multilayer laminated film]
Below, the manufacturing method of the uniaxially stretched multilayer laminated film of this invention is explained in full detail.
The uniaxially stretched multilayer laminated film of the present invention is extruded in a state in which the thermoplastic resin constituting the first layer and the thermoplastic resin constituting the second layer are alternately superposed in the molten state, and the multilayer unstretched film (sheet) Process). At this time, the laminate is laminated so that the thickness of each layer changes stepwise or continuously within a range of 2.0 times or more, preferably 5.0 times or less.

  The multilayer unstretched film thus obtained is stretched in the film forming direction or at least one axial direction (direction along the film surface) in the width direction perpendicular thereto. The stretching temperature is preferably in the range of the temperature (Tg) to Tg + 50 ° C. of the glass transition point of the thermoplastic resin of the first layer. The draw ratio at this time is preferably 2 to 10 times, more preferably 2.5 to 7 times, further preferably 3 to 6 times, and particularly preferably 4.5 to 5.5 times. The larger the draw ratio, the smaller the variations in the plane direction of the individual layers in the first layer and the second layer, and the light interference of the multilayer stretched film is made uniform in the plane direction. This is preferable because the difference in refractive index between the layers and the second layer in the stretching direction becomes large. As the stretching method at this time, known stretching methods such as heat stretching with a rod heater, roll heating stretching, and tenter stretching can be used. From the viewpoints of reducing scratches due to contact with the roll and stretching speed, tenter stretching is performed. preferable. Moreover, when performing a extending | stretching process also in the direction (Y direction) orthogonal to this extending | stretching direction and performing biaxial stretching, it is preferable to limit to a draw ratio of about 1.05-1.20 times. If the stretch ratio in the Y direction is further increased, the polarization performance may be deteriorated. Moreover, it is preferable to perform a heat setting process after extending | stretching.

[Reflective polarizing film for stereoscopic glasses]
Since the uniaxially stretched multilayer laminated film of the present invention has a higher polarization performance than a conventional reflective polarizing plate and has a higher transmittance in the transmission axis direction than an absorptive polarizing plate, the stereoscopic glasses It can be used as a reflective polarizing film. Further, since the hue shift of the transmitted light with respect to the light incident in the oblique direction is small, the hue shift due to the incident angle of the image light does not occur when used as stereoscopic glasses, and the reproducibility of the image light is excellent.

  When the uniaxially stretched multilayer laminated film of the present invention is used for stereoscopic glasses, the conventional reflective polarization using polyethylene-2,6-naphthalenedicarboxylate as the first layer by having such high polarization performance. Compared to the plate, contrast, for example, contrast comparing brightness of white display and black display becomes higher. Therefore, when used as a polarizing plate for stereoscopic glasses, the image can be viewed more clearly. In addition, since it has higher transparency in the direction of the transmission axis than an absorptive polarizing plate, it has a bright field of view when used for stereoscopic glasses. Are better. Further, when the uniaxially stretched multilayer laminated film of the present invention is used, stereoscopic vision glasses have a polarization performance higher than that of a conventional reflective polarizing plate but a small hue shift of transmitted light with respect to light incident in an oblique direction. When used as an image, the color of the image can be viewed with high reproducibility.

[Polarizing plate and stereoscopic glasses]
(Linear polarizing plate and stereoscopic glasses using linear polarizing plate)
When the reflective polarizing film for stereoscopic glasses of the present invention is used as a polarizing plate for stereoscopic glasses, the stereoscopic glasses having an aspect in which the linearly polarized light polarized by the polarizing plate is visually recognized as it is without attaching a λ / 4 wavelength film. Can be used as Such a type of stereoscopic glasses may be referred to as a linearly polarizing system, and in the present invention, such a type of polarizing plate may be referred to as a linearly polarizing plate.

  The linearly polarized stereoscopic glasses include a right-eye image transmitting unit disposed on the viewer's right eye side and a left-eye image transmitting unit disposed on the viewer's left eye side. The lens is disposed on the right eye side of normal glasses. And the lens arranged on the left eye side. The right-eye image transmitting unit is provided with the reflective polarizing film for stereoscopic glasses of the present invention so as to transmit light having a polarization direction parallel to the polarization axis of the image light of the right-eye image emitted from the stereoscopic image display device. The reflective polarizing film for stereoscopic glasses of the present invention is arranged so that the image transmitting portion transmits light having a polarization direction parallel to the polarization axis of the image light of the left-eye image emitted from the stereoscopic image display device. Further, the stereoscopic glasses according to the present invention are arranged so that the polarization axes of the right-eye image transmission unit and the left-eye image transmission unit are orthogonal to each other.

  Since the polarizing plate using the reflective polarizing film for stereoscopic glasses of the present invention has improved polarization performance compared to the conventional reflective polarizing plate, the conventional polarizing performance is insufficient. When it is difficult to use the plate for stereoscopic glasses, when a reflective polarizing plate is used for stereoscopic glasses instead of the absorbing polarizing plate, a clear image can be visually recognized. In addition, the polarizing plate using the reflective polarizing film for stereoscopic glasses of the present invention is more transparent than the conventional absorption polarizing plate in the transmission axis direction, so there is no reduction in the brightness of the field of view caused by wearing stereoscopic glasses. Therefore, the visibility of the stereoscopic video and the visibility other than the stereoscopic video are improved. In particular, sufficient visibility can be obtained when a stereoscopic image is viewed in a darkened environment such as a movie theater.

(Circularly polarizing glasses and stereoscopic glasses using circularly polarizing plates)
As the polarizing plate of the present invention, in addition to the above-mentioned linear polarizing plate, it can also be used for a circular polarizing plate of stereoscopic glasses including a reflective polarizing film for stereoscopic glasses and a λ / 4 wavelength film. Here, the λ / 4 wavelength film refers to a stretched film that gives a phase difference of ¼ wavelength to monochromatic light.
Such a circularly polarizing plate is obtained by laminating the reflective polarizing film for stereoscopic glasses of the present invention and the λ / 4 wavelength film at an inclination of 45 degrees with respect to the orientation axis. When used as a circularly polarizing plate, in addition to the effect of using the reflective polarizing film for stereoscopic glasses of the present invention, the polarization axis does not shift even if the observer's stereoscopic glasses are tilted. The same visibility as the direction can be obtained.

  The λ / 4 wavelength film used in the present invention can be obtained, for example, by a method of stretching a polymer film uniaxially or biaxially, and a known λ / 4 wavelength film can be used. There is no limitation in particular about the kind of polymer | macromolecule which forms a stretched film, What is excellent in transparency is used preferably. Examples include polycarbonate polymers, polyester polymers, polysulfone polymers, polyethersulfone polymers, polystyrene polymers, polyolefin polymers, polyvinyl alcohol polymers, cellulose acetate polymers, poly Examples thereof include vinyl chloride polymers and polymethyl methacrylate polymers.

The circular polarization method means that circularly polarized light with different rotation directions is emitted from the stereoscopic image display device as a left-eye image and a right-eye image, and only the left eye is displayed on the left eye and the right eye is displayed on the right eye with the circularly-polarized stereoscopic glasses. This is a method of transmitting only an image.
The circularly polarized stereoscopic glasses include a right-eye image transmission unit arranged on the right eye side of the observer and a left-eye image transmission unit on the left-eye side of the observer, and the right-eye image transmission unit and the left-eye image transmission unit. A circularly polarizing plate including the above-described reflective polarizing film for stereoscopic glasses and a λ / 4 wavelength film is used for the part.

  The reflective polarizing film for stereoscopic glasses in such a circularly polarizing plate has a transmission axis direction orthogonal to the transmission axis direction of the polarizing plate closer to the viewer among the two polarizing plates arranged in the liquid crystal module of the stereoscopic image display device. Arranged to be in the direction. The transmission axis direction of the reflective polarizing film for stereoscopic glasses disposed in the image transmission part for the right eye is parallel to the transmission axis direction of the reflective polarizing film for stereoscopic glasses disposed in the image transmission part for the left eye. Be placed.

  Furthermore, the λ / 4 wavelength film disposed in the right-eye image transmissive portion and the λ / 4 wavelength film disposed in the left-eye image transmissive portion are 45 with respect to the orientation axis of the reflective polarizing film for stereoscopic glasses to be bonded, respectively. It is pasted so that the laminating angle of the left and right λ / 4 wavelength films with respect to the orientation axis of the reflective polarizing film for stereoscopic glasses is in the right direction or the reverse direction of the left direction. Here, the left and right directions are appropriately selected depending on the display format of the stereoscopic image display device.

  Since the circularly polarizing plate using the reflective polarizing film for stereoscopic glasses of the present invention has improved polarization performance compared to the conventional reflective polarizing plate, like the linearly polarizing plate, It was difficult to use a reflective polarizing plate for stereoscopic glasses due to insufficient polarization performance. When a reflective polarizing plate was used for stereoscopic glasses instead of an absorbing polarizing plate, a clear image was obtained. Can be visually recognized. In addition, the polarizing plate using the reflective polarizing film for stereoscopic glasses of the present invention is more transparent than the conventional absorption polarizing plate in the transmission axis direction, so there is no reduction in the brightness of the field of view caused by wearing stereoscopic glasses. Therefore, the visibility of the stereoscopic video and the visibility other than the stereoscopic video are improved. In particular, sufficient visibility can be obtained when a stereoscopic image is viewed in a darkened environment such as a movie theater.

  When used as a circularly polarizing plate comprising the reflective polarizing film of the present invention and a λ / 4 wavelength film, the circularly polarizing plate having an antireflection layer between air and the λ / 4 wavelength film at least on the λ / 4 wavelength film side It is more preferable to use as.

  When the reflective polarizing film of the present invention is used as a circularly polarizing plate together with a λ / 4 wavelength film, the reflected polarized light reflected by the reflective polarizing film is rereflected at the interface between the λ / 4 wavelength film and air, and the polarization angle is changed. It may be transmitted as polarized light parallel to the transmission axis of the reflective polarizing film, and as a result, polarized light to be blocked may be transmitted. As a result, the degree of polarization as a circularly polarizing film may be reduced. Therefore, by providing an antireflection layer between air and the λ / 4 wavelength film at least on the λ / 4 wavelength film side, such re-reflected light is provided. Thus, a reflective circularly polarizing plate having a high degree of polarization comparable to that of the absorbing polarizing plate can be obtained.

The antireflection layer used in the present invention is not particularly limited, and is a layer composed of only one low refractive index layer, two layers of (λ / 4 wavelength film /) high refractive index layer / low refractive index layer, and (λ / 4 wavelength). The film /) may have any one of three layers such as a medium refractive layer / a high refractive layer / a low refractive layer.
The antireflection layer may be formed by any of a wet coating method in which a solution is applied on a film and then dried and laminated, or a dry method by sputtering, vapor deposition, etc. Also good.

  Moreover, the base material which forms an antireflection layer will not be specifically limited if it is a range in which an optical characteristic is not impaired by bonding etc. The antireflection layer may be formed directly on the above-mentioned λ / 4 wavelength film, or the antireflection layer may be formed after applying a known hard coat layer on the λ / 4 wavelength film. Furthermore, after forming on an isotropic film (triacetyl cellulose etc.) with a small phase difference, you may bond with a (lambda) / 4 wavelength film.

  Among them, a low refractive index layer consisting of one layer is preferable because of the simplicity of the process. As an example of a preferable low refractive index, for example, a low refractive index obtained by polymerizing a monomer composition containing a fluorine-containing polyfunctional (meth) acrylate having a specific structure described in JP-A-10-182745. Materials can be used. Further, the fluorine-containing (meth) acrylic acid ester described in JP-A-2001-262011, a silane coupling agent having a (meth) acryloxy group, and colloidal silica knitted with the fluorine-containing silane coupling agent are specified. You may use the fluorine-containing curable coating liquid contained in a ratio. In addition, a hydrolyzable organosilane partial hydrolyzate and / or a silicone resin comprising the hydrolyzate described in JP-A-2003-202406, an average particle diameter of 5 nm to 2 μm, and voids in the outer shell A cured coating layer of a coating agent composition comprising hollow silica fine particles formed with an essential component may be used as an antireflection layer.

Hereinafter, the present invention will be described with reference to examples, but the present invention is not limited to the examples shown below.
In addition, the physical property and characteristic in an Example were measured or evaluated by the following method.

(1) Reflectance, reflection wavelength, transmittance Using a spectrophotometer (manufactured by Shimadzu Corp., MPC-3100), a polarizing filter is attached to the light source side, and the relative specular reflectance with the aluminum-deposited mirror at each wavelength is calculated. Measurement is performed in the wavelength range of 400 nm to 800 nm. In this case, the measured value when the transmission axis of the polarizing filter is aligned with the stretching direction (X direction) of the film is p-polarized light, and the transmission axis of the polarizing filter is disposed so as to be orthogonal to the stretching direction of the film Was measured as s-polarized light. For each polarization component, the average value of the reflectance in the range of 400 to 800 nm was defined as the average reflectance, and the average value of the transmittance in the range of 400 to 800 nm was defined as the average transmittance.
In addition, the case where the measuring light was incident from the direction perpendicular to the film surface of the film sample was defined as 0 degree incidence.

(2) Refractive index and average refractive index before stretching in each direction and average refractive index Each resin constituting each layer was melted and extruded from a die, and a film cast on a casting drum was prepared. Further, a stretched film was prepared by stretching the obtained film at 135 ° C. in a uniaxial direction 5 times. About the obtained cast film and stretched film, the respective refractive indexes in the stretching direction (X direction), the orthogonal direction (Y direction), and the thickness direction (Z direction) (referred to as n _X , n _Y , and n _Z respectively). Was determined by measuring the refractive index at a wavelength of 633 nm using a metricon prism coupler, and the refractive index was determined before and after stretching. About the average refractive index before extending | stretching of each layer, the average value of the refractive index of 3 directions before extending | stretching was made into the average refractive index.

(3) Melting point (Tm) and glass transition point (Tg) of thermoplastic resin and film
10 mg of a polymer sample or a film sample was sampled, and a DSC (manufactured by TA Instruments, trade name: DSC2920) was used. The melting point and the glass transition point are measured at a temperature rising rate of.

(4) Identification of thermoplastic resin and identification of copolymer component and amount of each component For each layer of the film sample, the component of the thermoplastic resin, the copolymer component and the amount of each component were identified from ¹ H-NMR measurement.

(5) Thickness and number of layers of each layer A film sample was cut into a film length direction of 2 mm and a width direction of 2 cm, fixed to an embedding capsule, and then embedded with an epoxy resin (Epomount manufactured by Refine Tech Co., Ltd.). The embedded sample was cut perpendicularly in the width direction with a microtome (LETRAC ULCT UCT manufactured by LEICA) to form a thin film slice having a thickness of 5 nm. Using a transmission electron microscope (Hitachi S-4300), the film was observed and photographed at an acceleration voltage of 100 kV, and the thickness of each layer and the number of layers were measured from the photograph.
Moreover, based on the thickness of each obtained layer, the ratio of the maximum layer thickness to the minimum layer thickness in the first layer and the ratio of the maximum layer thickness to the minimum layer thickness in the second layer were determined.
Moreover, based on the thickness of each obtained layer, the average layer thickness of the first layer and the average layer thickness of the second layer were determined, respectively, and the average layer thickness of the second layer relative to the average layer thickness of the first layer was calculated. .
The outermost heat seal layer was excluded from the first layer and the second layer. Further, when a thickness adjusting layer having a thickness of 2 μm or more exists in the alternate lamination, such a layer was also excluded from the first layer and the second layer.

(6) Total film thickness A film sample was sandwiched between spindle detectors (K107C manufactured by Anritsu Electric Co., Ltd.), and 10 points of thickness were measured at different positions using a digital differential electronic micrometer (K351 manufactured by Anritsu Electric Co., Ltd.). And the average value was calculated | required and it was set as the film thickness.

(7) Brightness and contrast When using a personal computer (Fujitsu “ESPRIMO FH550 / AN”) equipped with stereoscopic glasses and a circularly polarized 3D liquid crystal display device created by the method described later, Measure the front luminance of the screen of the liquid crystal display device through the right-eye image transmission part and the left-eye image transmission part of the stereoscopic glasses when displayed on a white screen with an FPD viewing angle measurement evaluation device (ErgoScope 88) manufactured by Opto Design, Find the bright brightness from the white screen and the dark brightness from the black screen,
The brightness was evaluated according to the following criteria.
i) Brightness ◎: Bright brightness is 85% or more when stereoscopic glasses are not used ○: Bright brightness is 75% or more and less than 85% when stereoscopic glasses are not used ×: Bright brightness is using stereoscopic glasses Less than 75%
ii) Contrast The contrast obtained from the brightness / dark brightness was also evaluated according to the following criteria.
A: Contrast (bright luminance / dark luminance) 15 or more B: Contrast (bright luminance / dark luminance) 10 or more, less than 15 X: Contrast (bright luminance / dark luminance) Less than 10
iii) Hue Further, the hue x or y at the time of bright luminance was measured, and the hue was evaluated according to the following criteria.
○: The maximum change of either x or y based on the case where the stereoscopic glasses are not used is less than 0.15 Δ: The maximum change of any of x or y based on the case where the stereoscopic glasses are not used 0.15 or more, less than 0.25 x: Maximum change in both x and y based on the case where stereoscopic glasses are not used is 0.25 or more

[Comparative Example 1]
(Creating a polarizer)
Dyeing a polymer film composed mainly of polyvinyl alcohol [Kuraray's trade name “9P75R (thickness: 75 μm, average polymerization degree: 2,400, saponification degree 99.9 mol%)”] between rolls having different peripheral speeds While being stretched and conveyed. First, it was immersed in a 30 ° C. water bath for 1 minute to swell the polyvinyl alcohol film and stretched 1.2 times in the conveying direction, and then a 30 ° C. potassium iodide concentration of 0.03% by weight and an iodine concentration of 0.3 By immersing in a weight% aqueous solution for 1 minute, the film was stretched 3 times in the transport direction while dyeing, based on a film that was not stretched at all (original length). Next, the film was stretched 6 times in the conveying direction on the basis of the original length while being immersed in an aqueous solution having a boric acid concentration of 4% by weight and a potassium iodide concentration of 5% by weight for 30 seconds. Next, the obtained stretched film was dried at 70 ° C. for 2 minutes to obtain a polarizer. The polarizer had a thickness of 30 μm and a moisture content of 14.3% by weight.

(Create adhesive)
Polyvinyl alcohol resin having an acetoacetyl group (average polymerization degree 1200, saponification degree 98.5 mol%, acetoacetylation degree 5 mol%) 100 parts by weight 50 parts by weight of methylol melamine at 30 ° C. Then, it was dissolved in pure water to prepare an aqueous solution having a solid content concentration of 3.7% by weight. An aqueous adhesive solution was prepared by adding 18 parts by weight of an aqueous solution containing alumina colloid having a positive charge (average particle diameter of 15 nm) at a solid content concentration of 10% by weight to 100 parts by weight of this aqueous solution. The viscosity of the adhesive solution was 9.6 mPa · s, the pH was in the range of 4 to 4.5, and the compounding amount of the alumina colloid was 74 parts by weight with respect to 100 parts by weight of the polyvinyl alcohol resin.

(Creation of absorption type polarizing plate)
An optically isotropic element having a thickness of 80 μm, a front retardation of 0.1 nm, and a thickness direction retardation of 1.0 nm (the Fuji Colloid product name “Fujitack ZRF80S”) Was applied to one side of the polarizer by roll-to-roll so that the conveying direction of both was parallel, and the same was applied to the opposite side of the polarizer. Then, the above-mentioned alumina colloid-containing adhesive is applied to one side of an optical isotropic element (Fuji Film product name “Fujitack ZRF80S”) so that the thickness after drying is 80 nm. Then, the film was laminated by roll-to-roll, and then dried at 55 ° C. for 6 minutes to obtain a polarizing plate, which will be referred to as “polarizing plate X”.

(Creation of λ / 4 wave plate)
A polycarbonate film having a thickness of 50 μm was stretched by 2.5% at 150 ° C. to obtain a λ / 4 stretched film that gives a phase difference of ¼ wavelength to light having a wavelength of 550 nm based on birefringent light.

(Creation of circularly polarized film)
The “polarizing plate X” and the λ / 4 stretched film were bonded with an adhesive so that the optical axis was 45 degrees to obtain a circularly polarizing film.

(Creation of stereoscopic glasses)
Two pieces of the obtained circularly polarizing film are cut into a size corresponding to a spectacle lens, and are installed in the right-eye image transmitting portion and the left-eye image transmitting portion so that the polarizing axes of the polarizing plate X are parallel to each other. The λ / 4 stretched film was placed on the side of the stereoscopic image display device to produce stereoscopic glasses. Brightness evaluation, contrast evaluation, and hue evaluation through the obtained stereoscopic glasses were performed.
When this absorptive polarizing plate is used as a polarizing plate for stereoscopic glasses, the average transmittance of the s-polarized light at an incident angle of 0 ° is 70%. Luminance was less than 75% when stereoscopic glasses were not used, and the field of view became dark.

[Example 1]
Dimethyl 2,6-naphthalenedicarboxylate, 6,6 ′-(ethylenedioxy) di-2-naphthoic acid, and ethylene glycol are subjected to esterification and transesterification in the presence of titanium tetrabutoxide, and Subsequently, a polycondensation reaction was performed, and the intrinsic viscosity was 0.62 dl / g, 65 mol% of the acid component was 2,6-naphthalenedicarboxylic acid component (described as PEN in the table), and 35 mol% of the acid component was 6 mol%. , 6 ′-(ethylenedioxy) di-2-naphthoic acid component (denoted as ENA in the table), an aromatic polyester whose glycol component is ethylene glycol is obtained as a thermoplastic resin for the first layer, 20-mol% isophthalic acid copolymerized polyethylene terephthalate having an intrinsic viscosity (orthochlorophenol, 35 ° C.) of 0.62 dl / g as a thermoplastic resin for two layers It was prepared the door (IA20PET).
The prepared thermoplastic resin for the first layer and the thermoplastic resin for the second layer are each dried at 170 ° C. for 5 hours, then supplied to the first and second extruders, heated to 300 ° C. to be in a molten state, After branching the polyester for the first layer into 137 layers and the polyester for the second layer into 138 layers, the first layer and the second layer are alternately laminated, and the maximum layer thickness in each of the first layer and the second layer Using a multi-layer feedblock device in which the minimum layer thickness continuously changes up to 2.2 times at the maximum / minimum, a total of 275 layers in which the first layer and the second layer are alternately stacked While the laminated state is maintained, the same polyester as the second layer polyester is led from the third extruder to the three-layer die on both sides of the melt, and heat is applied to both sides of the total number of 275 layers of the melt. A seal layer was further laminated. The supply amount of the third extruder was adjusted so that both end layers (heat seal layers) were 18% of the whole. The laminated state is led to a die, cast on a casting drum, adjusted so that the average layer thickness ratio of the first layer and the second layer is 1.0: 2.6, and a total of 277 layers. An unstretched multilayer laminated film was prepared.
This multilayer unstretched film was stretched 5.2 times in the width direction at a temperature of 135 ° C., and heat-set at 140 ° C. for 3 seconds. The thickness of the obtained reflective polarizing film was 33 μm.

(Creation of circularly polarized film)
Using the obtained reflective polarizing film and the λ / 4 stretched film used in Comparative Example 1, these optical axes were bonded with an adhesive so as to be 45 degrees to obtain a circularly polarizing plate.

(Creation of stereoscopic glasses)
Two pieces of the obtained circularly polarizing film are cut into a size corresponding to a spectacle lens, and are installed in the right-eye image transmitting portion and the left-eye image transmitting portion so that the polarization axes of the respective reflecting polarizing films are parallel to each other. The λ / 4 stretched film was placed on the side of the stereoscopic image display device to produce stereoscopic glasses. Brightness evaluation, contrast evaluation, and hue evaluation through the obtained stereoscopic glasses were performed.
Table 1 shows the resin configuration of each layer of the obtained uniaxially stretched multilayer laminated film and the characteristics of each layer, and Table 2 shows the characteristics of the uniaxially stretched multilayer laminated film and the characteristics of stereoscopic glasses.
By using the multilayer laminated film of this example for stereoscopic glasses, the average transmission at an incident angle of 0 ° of s-polarized light is obtained as compared with Comparative Example 2 in which polyethylene-2,6-naphthalenedicarboxylate is used for the first layer. The characteristics of brightness, contrast, and hue, which were evaluated for brightness with and without stereoscopic glasses, were improved, and bright and clear visibility was obtained.

[Examples 2 to 6]
As shown in Table 1, a reflective polarizing film composed of a uniaxially stretched multilayer laminated film was obtained in the same manner as in Example 1 except that the resin composition or the layer thickness of each layer was changed.
In addition, NDC20PET used as the second layer polyester in Example 2 is a copolymer component of 20 mol% isophthalic acid copolymerized polyethylene terephthalate (IA20PET) used as the second layer polyester in Example 1 with 2,6- It is a copolyester changed to naphthalenedicarboxylic acid.
Further, the ENA21PEN / PCT blend used as the polyester for the second layer in Example 4 is ENA21PEN which is the polyester for the first layer of Example 4 (79 mol% of the acid component is a 2,6-naphthalenedicarboxylic acid component, 21 mol% of the acid component is 6,6 ′-(ethylenedioxy) di-2-naphthoic acid component, aromatic polyester whose glycol component is ethylene glycol, and PCTA AN004 (polycyclohexanedimethylene terephthalate manufactured by Eastman Chemical) -Isophthalate copolymer) is mixed at a weight ratio of 2: 1.
Using the obtained reflective polarizing film and the λ / 4 stretched film used in Comparative Example 1, similarly to Example 1, these optical axes were bonded with an adhesive so as to be 45 degrees, and a circularly polarizing film and did.
Further, the obtained circularly polarizing film is cut into two pieces corresponding to the size of a spectacle lens, and is installed in the right-eye image transmitting portion and the left-eye image transmitting portion so that the respective polarization axes are parallel to each other. Visual glasses were created. The obtained stereoscopic glasses were evaluated for brightness, contrast, and hue.
Table 1 shows the resin configuration of each layer of the obtained uniaxially stretched multilayer laminated film and the characteristics of each layer, and Table 2 shows the characteristics of the uniaxially stretched multilayer laminated film and the characteristics of stereoscopic glasses.

[Example 7]
Fluorine-based coating agent DS-5300 (manufactured by Harves Co., Ltd.) is applied on the λ / 4 stretched film used in Example 1 with Meyer bar # 5 and air-dried to obtain a λ / 4 stretched film with an antireflection layer. It was. The obtained λ / 4 stretched film with an antireflection layer and the uniaxially stretched multilayer laminated film prepared in Example 1 are arranged so that their optical axes are 45 degrees, following the antireflection layer. The same operation as in Example 1 was repeated except that the surface on which no is applied was bonded with an adhesive to obtain a circularly polarizing film. The obtained stereoscopic glasses were evaluated for brightness, contrast, and hue, and the characteristics of the stereoscopic glasses are shown in Table 2. The obtained stereoscopic glasses have a contrast comparable to that of the stereoscopic glasses using the absorbing polarizing plate, and the brightness and hue are better than the stereoscopic glasses using the absorbing polarizing plate. there were.

[Example 8]
Fluorine-based coating agent DS-5300 (manufactured by Harves Co., Ltd.) was also applied to the uniaxially stretched multilayer laminate film used in Example 1 with Mayer Bar # 5 and air-dried, and the uniaxially stretched multilayer laminate with antireflection layer A film was obtained. The obtained uniaxially stretched multilayer laminated film with antireflection layer and the λ / 4 stretched film with antireflection layer obtained in Example 7 have an optical axis of 45 degrees as in Example 1. Thus, the same operation as in Example 1 was repeated except that the surface on which the antireflection layer was not applied was bonded with an adhesive to obtain a circularly polarizing film. The obtained stereoscopic glasses were evaluated for brightness, contrast, and hue, and the characteristics of the stereoscopic glasses are shown in Table 2. The obtained stereoscopic glasses have a contrast comparable to that of the stereoscopic glasses using the absorbing polarizing plate, and the brightness and hue are better than the stereoscopic glasses using the absorbing polarizing plate. there were.

[Comparative Example 2]
The thermoplastic resin for the first layer is made of polyethylene-2,6-naphthalenedicarboxylate (PEN) having an intrinsic viscosity (orthochlorophenol, 35 ° C.) of 0.62 dl / g, and the thermoplastic resin for the second layer is made of intrinsic viscosity (ortho Chlorophenol, 35 ° C.) Example 1 with the exception of changing to 0.62 dl / g terephthalic acid 64 mol% copolymerized polyethylene-2,6-naphthalenedicarboxylate (TA64PEN) and changing to the production conditions shown in Table 1. Similarly, a uniaxially stretched multilayer laminated film was obtained, and this film was used as a polarizing plate and bonded to the λ / 4 stretched film used in Comparative Example 1 to form a circularly polarizing film, thereby producing stereoscopic glasses.
The obtained uniaxially stretched multilayer laminated film has an average reflectance of p-polarized light of less than 95%, an average reflectance of s-polarized light of more than 12%, and a polarization performance lower than that of the examples, so that sufficient contrast is obtained. Was not obtained. In addition, brightness and hue were also reduced as compared to the examples.

[Comparative Examples 3 to 7]
As shown in Table 1, a uniaxially stretched multilayer laminated film was prepared in the same manner as in Example 1 except that any of the resin composition, layer thickness, and production conditions was changed. A circularly polarizing film was formed by laminating with the used λ / 4 stretched film to prepare stereoscopic glasses.
As for the obtained film, the polarization performance was falling compared with the Example, and sufficient contrast was not acquired. In addition, brightness and hue were also reduced as compared to the examples.

  In addition, the composition of polyester in Table 1 is as follows.

NDC: 2,6-naphthalenedicarboxylic acid ENA: 6,6 ′-(ethylenedioxy) di-2-naphthoic acid EG: ethylene glycol IA: isophthalic acid TA: terephthalic acid PEN: polyethylene-2,6-naphthalenedicarboxy Rate PET: Polyethylene terephthalate

  Although it is a reflective polarizing film using a uniaxially stretched multilayer laminated film, it has sufficiently high polarization performance as stereoscopic glasses, and also has a higher transparency in the transmission axis direction than an absorptive polarizing plate. Therefore, when used for stereoscopic glasses, the field of view is bright, and the stereoscopic video and the visibility other than the stereoscopic video are excellent. Reflective polarizing film, polarizing plate comprising the same, and stereoscopic glasses can be provided.

DESCRIPTION OF SYMBOLS 1 Polarizing plate 2 (lambda) / 4 wavelength film 3 Stereoscopic glasses 3L Left-eye image transmission part 3R using a circular polarizing film Right-eye image transmission part 4 using a circular polarizing film Antireflection layer

Claims (8)

It is a reflective polarizing film consisting of a uniaxially stretched multilayer laminated film,
The uniaxially stretched multilayer laminated film has a multilayer structure in which first layers and second layers are alternately laminated, and the first layer is made of a polyester of a dicarboxylic acid component and a diol component,
(I) The dicarboxylic acid component contains a component represented by the following formula (A) of 5 mol% to 50 mol% and a component represented by the following formula (B) of 50 mol% to 95 mol%. ,
(In the formula (A), R ^A represents an alkylene group having 2 to 10 carbon atoms)
(In the formula (B), R ^B represents a phenylene group or a naphthalenediyl group)
(Ii) The diol component contains 90 to 100 mol% of a component represented by the following formula (C),
(In the formula (C), R ^C represents an alkylene group having 2 to 10 carbon atoms)
The uniaxially stretched multilayer laminated film is stretched only in the uniaxial direction, the number of laminated layers is 251 to 501 layers, and the film thickness is 15 to 40 μm,
With the film surface of the uniaxially stretched multilayer laminated film as a reflective surface, the polarization component parallel to the incident surface including the uniaxially stretched direction (X direction) has a wavelength of 400 to 800 nm with respect to the incident polarized light at an incident angle of 0 degree. With respect to a polarized light component having an average reflectance of 98% or more, a film surface as a reflecting surface, and perpendicular to the incident surface including the X direction, an average reflectance with a wavelength of 400 to 800 nm with respect to the incident polarized light at an incident angle of 0 degree. Is a reflective polarizing film for stereoscopic glasses.   The reflective polarizing film for stereoscopic glasses according to claim 1, wherein the thermoplastic resin forming the second layer is a polyester mainly comprising an ethylene terephthalate component copolymerized with isophthalic acid or 2,6-naphthalenedicarboxylic acid.   The average reflectance at a wavelength of 400 to 800 nm with respect to the incident polarized light at an incident angle of 0 degree with respect to a polarized light component parallel to the incident surface including the uniaxial stretching direction (X direction) is 98.9% or more. The reflective polarizing film for stereoscopic glasses according to 2.   The reflective polarizing film for stereoscopic glasses according to any one of claims 1 to 3, wherein the ratio of the average layer thickness of the second layer to the average layer thickness of the first layer is in the range of 1.5 to 5.0. .   A polarizing plate comprising the reflective polarizing film for stereoscopic glasses according to claim 1.   The polarizing plate according to claim 5, further comprising a λ / 4 wavelength film.   The polarizing plate according to claim 6, further comprising an antireflection layer between air and the λ / 4 wavelength film at least on the λ / 4 wavelength film side.   Stereoscopic glasses using the polarizing plate according to any one of claims 5 to 7.