JP5544533B2 - 爪又は人工爪被覆用硬化性樹脂組成物 - Google Patents
爪又は人工爪被覆用硬化性樹脂組成物 Download PDFInfo
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- JP5544533B2 JP5544533B2 JP2009278268A JP2009278268A JP5544533B2 JP 5544533 B2 JP5544533 B2 JP 5544533B2 JP 2009278268 A JP2009278268 A JP 2009278268A JP 2009278268 A JP2009278268 A JP 2009278268A JP 5544533 B2 JP5544533 B2 JP 5544533B2
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- 239000005662 Paraffin oil Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 206010041349 Somnolence Diseases 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- XRMBQHTWUBGQDN-UHFFFAOYSA-N [2-[2,2-bis(prop-2-enoyloxymethyl)butoxymethyl]-2-(prop-2-enoyloxymethyl)butyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(CC)COCC(CC)(COC(=O)C=C)COC(=O)C=C XRMBQHTWUBGQDN-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- RFVHVYKVRGKLNK-UHFFFAOYSA-N bis(4-methoxyphenyl)methanone Chemical compound C1=CC(OC)=CC=C1C(=O)C1=CC=C(OC)C=C1 RFVHVYKVRGKLNK-UHFFFAOYSA-N 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- YLQWCDOCJODRMT-UHFFFAOYSA-N fluoren-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C2=C1 YLQWCDOCJODRMT-UHFFFAOYSA-N 0.000 description 1
- RMBPEFMHABBEKP-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2C3=C[CH]C=CC3=CC2=C1 RMBPEFMHABBEKP-UHFFFAOYSA-N 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000012949 free radical photoinitiator Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- FSPSELPMWGWDRY-UHFFFAOYSA-N m-Methylacetophenone Chemical compound CC(=O)C1=CC=CC(C)=C1 FSPSELPMWGWDRY-UHFFFAOYSA-N 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- RBQRWNWVPQDTJJ-UHFFFAOYSA-N methacryloyloxyethyl isocyanate Chemical compound CC(=C)C(=O)OCCN=C=O RBQRWNWVPQDTJJ-UHFFFAOYSA-N 0.000 description 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- UTSYWKJYFPPRAP-UHFFFAOYSA-N n-(butoxymethyl)prop-2-enamide Chemical compound CCCCOCNC(=O)C=C UTSYWKJYFPPRAP-UHFFFAOYSA-N 0.000 description 1
- ULYOZOPEFCQZHH-UHFFFAOYSA-N n-(methoxymethyl)prop-2-enamide Chemical compound COCNC(=O)C=C ULYOZOPEFCQZHH-UHFFFAOYSA-N 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000035790 physiological processes and functions Effects 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000012673 precipitation polymerization Methods 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 230000008786 sensory perception of smell Effects 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 230000036620 skin dryness Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- RKBCYCFRFCNLTO-UHFFFAOYSA-N triisopropylamine Chemical compound CC(C)N(C(C)C)C(C)C RKBCYCFRFCNLTO-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/81—Preparation or application process involves irradiation
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Cosmetics (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Description
(1)(A)活性エネルギー線照射により重合反応し得る官能基を含む重合体の水性エマルジョン、(B)ポリエチレングリコール、及び(C)光ラジカル開始剤(但し、分子中に窒素原子を含むものを除く)を含む、爪又は人工爪被覆用硬化性樹脂組成物である。
(2)活性エネルギー線照射により重合反応し得る官能基が、(メタ)アクリロイル基である、上記(1)記載の爪又は人工爪被覆用硬化性樹脂組成物、
(3)活性エネルギー線照射により重合反応し得る官能基を含む重合体が、主鎖構造としてポリアクリル系骨格又はポリウレタン系骨格を有する、上記(1)又は(2)記載の爪又は人工爪被覆用硬化性樹脂組成物、
(4)活性エネルギー線照射により重合反応し得る官能基を含む重合体が、主鎖構造としてポリアクリル系骨格を有する、上記(1)又は(2)記載の爪又は人工爪被覆用硬化性樹脂組成物、
(5)活性エネルギー線照射により重合反応し得る官能基を含む重合体が、上記の水性エマルジョン(A)中に25〜55質量%含まれる、上記(1)〜(4)のいずれか一つに記載の爪又は人工爪被覆用硬化性樹脂組成物、
(6)活性エネルギー線照射により重合反応し得る官能基を含む重合体の数平均分子量が、10,000〜500,000である、上記(1)〜(5)のいずれか一つに記載の爪又は人工爪被覆用硬化性樹脂組成物、
(7)活性エネルギー線照射により重合反応し得る官能基を含む重合体が、該官能基を分子内に少なくとも2個含む、上記(1)〜(6)のいずれか一つに記載の爪又は人工爪被覆用硬化性樹脂組成物、
(8)(B)ポリエチレングリコールを、上記の水性エマルジョン(A)に含まれる、活性エネルギー線照射により重合反応し得る官能基を含む重合体100質量部に対して、0.1〜30質量部含む、上記(1)〜(7)のいずれか一つに記載の爪又は人工爪被覆用硬化性樹脂組成物、
(9)(B)ポリエチレングリコールを、上記の水性エマルジョン(A)に含まれる、活性エネルギー線照射により重合反応し得る官能基を含む重合体100質量部に対して、2〜20質量部含む、上記(1)〜(7)のいずれか一つに記載の爪又は人工爪被覆用硬化性樹脂組成物、
(10)(B)ポリエチレングリコールを、上記の水性エマルジョン(A)に含まれる、活性エネルギー線照射により重合反応し得る官能基を含む重合体100質量部に対して、3〜15質量部含む、上記(1)〜(7)のいずれか一つに記載の爪又は人工爪被覆用硬化性樹脂組成物、
(11)(B)ポリエチレングリコールの重量平均分子量が1,000〜2,000である、上記(1)〜(10)のいずれか一つに記載の爪又は人工爪被覆用硬化性樹脂組成物、
(12)(C)光ラジカル開始剤を、上記の水性エマルジョン(A)に含まれる、活性エネルギー線照射により重合反応し得る官能基を含む重合体100質量部に対して、1〜10質量部含む、上記(1)〜(11)のいずれか一つに記載の爪又は人工爪被覆用硬化性樹脂組成物、
(13)(C)光ラジカル開始剤が、2,4,6−トリメチルベンゾイルフェニルホスフィン酸エチル、1−ベンゾイル−1−シクロヘキサノール又はこれらの混合物である、上記(1)〜(12)のいずれか一つに記載の爪又は人工爪被覆用硬化性樹脂組成物、
(14)(D)天然物由来のワックスを更に含む、上記(1)〜(13)のいずれか一つに記載の爪又は人工爪被覆用硬化性樹脂組成物、
(15)(D)天然物由来のワックスを、上記の水性エマルジョン(A)に含まれる、活性エネルギー線照射により重合反応し得る官能基を含む重合体100質量部に対して、0.1〜15質量部含む、上記(1)〜(13)のいずれか一つに記載の爪又は人工爪被覆用硬化性樹脂組成物、
(16)(D)天然物由来のワックスを、上記の水性エマルジョン(A)に含まれる、活性エネルギー線照射により重合反応し得る官能基を含む重合体100質量部に対して、5〜10質量部含む、上記(1)〜(13)のいずれか一つに記載の爪又は人工爪被覆用硬化性樹脂組成物、
(17)(D)天然物由来のワックスが、カルナバワックス、ミツロウ、パームロウ、漆ロウ及びイボタロウより成る群から選ばれる一つ以上である、上記(14)〜(16)のいずれか一つに記載の爪又は人工爪被覆用硬化性樹脂組成物
を挙げることができる。
実施例及び比較例において使用した物質は下記の通りである。
水性エマルジョン(1):アクリル系自己架橋性光硬化型エマルジョン、官能基:アクリロイル基、固形分含有量:約40質量%、重合体の数平均分子量:約100,000、Cray Valley社製CRAYMUL−2717(商標)
水性エマルジョン(2):ウレタン系非自己架橋性光硬化型エマルジョン、官能基:アクリロイル基、固形分含有量:約40質量%、重合体の数平均分子量:約100,000、Alberdingk社製LUX−2411(商標)
アクリレートモノマー:ジトリメチロールプロパンテトラアクリレート、UCB社製Ebecry140(商標)
ポリエーテルアクリレート:アミン変性ポリエーテルアクリレート、UCB社製Ebecry83(商標)
ウレタンアクリレート:ウレタンアクリレートオリゴマー、Cray Valley社製Craynor435(商標)
ポリエチレングリコール:Sasol社製LIPOXOL1500(商標)、重量平均分子量:約1,500
ヒドロキシエチルセルロース:ダウ(DOW)社製METHOCEL K4MSPCG(商標)
アルギン酸プロピレングリコール:エヴォニク(Evonik)社製TEGO COSMO PGA(商標)
カルボキシメチルセルロースナトリウム:CP Kelco社製Kecol2000(商標)
ポリアクリル酸ナトリウム:コグニス(Cognis)社製Cosmedia SP(商標)
シリカ:日本アエロジル株式会社製アエロジル200(商標)
Irgacure 184(商標、チバスペシャリティケミカルズ株式会社製、1−ベンゾイル−1−シクロヘキサノール)
Irgacure 500(商標、チバスペシャリティケミカルズ株式会社製、1−ベンゾイル−1−シクロヘキサノールとベンゾフェノンとの質量比で1:1の混合物)
Lucirin TPO−L(商標、BASF社製、2,4,6−トリメチルベンゾイルフェニルホスフィン酸エチル)
ベンゾフェノン(和光純薬製、試薬)
Irgacure 369(商標、チバスペシャリティケミカルズ株式会社製、2−ベンジル−2−ジメチルアミン−1−(4−モルフォリノフェニル)−ブタノン−1)
カルナバワックス:東亜化成株式会社製Carnaubawax(商標)
レベリング・消泡剤:破泡性ポリシロキサン、Byk Chemie社製BYK028(商標)、破泡性ポリシロキサン、疎水性粒子及びポリグリコールから成る混合物
実施例及び比較例において使用した試験法は下記の通りである。
実施例及び比較例において得られた各組成物を室温23℃で24時間静置した後、分離及び沈降の有無を目視観察することにより判定した。判定結果を下記の記号で示した。
◎:全く変化が見られなかった
×:分離及び沈降が見られた
実施例及び比較例において得られた各組成物をポリプロピレン製つけ爪[スーパーネイルセンター社製SNC nail tips(商標)]に塗布し、光硬化させた。ここで、光硬化は、36ワット(9ワット×4本)の紫外線照射装置を使用して2分間照射することにより実施した(以下の試験法において全て同じである)。次いで、40℃の温水に8時間浸漬した後、硬化物の剥離及び溶解の有無を目視にて判断した。判定結果を下記の記号で示した。
◎:全く変化が見られなかった
×:一部分にでも剥離及び溶解が見られた
実施例及び比較例において得られた各組成物を、耐水性と同一手順で光硬化させた。次いで、硬化物表面を爪で軽く擦り、このときの傷の有無を目視にて判断した。判定結果を下記の記号で示した。
◎:全く傷が見られなかった
×:小さな傷が見られた
実施例及び比較例において得られた各組成物を、耐水性と同一手順で硬化した。硬化前後における臭気を人間の嗅覚により判断した。判定結果を下記の記号で示した。
◎:全く又は殆ど臭気が無い
○:弱い臭気がある
Δ:臭気が有る
×:非常に強い臭気が有る
実施例及び比較例において得られた各組成物を、人間の爪上に約1mmφの大きさに塗布し、光硬化させた。30分間放置した後、硬化物を爪上から剥がし、剥がした爪の部分を目視にて観察した。判定結果を下記の記号で示した。
◎:爪表面に変化が生じていない
○:爪表面が僅かに白化した
×:爪表面が白化した
実施例及び比較例において得られた各組成物を、人間の爪付近の皮膚上に一滴垂らした。そのまま1時間放置した後、石けん水で洗浄して、皮膚の外観変化を目視にて判断した。判定結果を下記の記号で示した。
◎:皮膚の外観に全く変化がない
×:皮膚が少しでも赤く変化した
実施例及び比較例において得られた各組成物を、人間の爪上に塗布し、硬化前の外観を判定した。次いで、各組成物を光硬化して硬化後の外観を判定した。判定結果を下記の記号で示した。また、下記の記号に該当せず、着色のあったものは着色状態を示した。実施例1〜12及び比較例1〜6については、硬化後の外観のみを評価した。
◎:表面に明確に光沢が残り、天井の蛍光灯がはっきり映った
○:表面にある程度の光沢が残り、天井の蛍光灯が映った
Δ:表面に僅かに光沢が認められた
×:塗膜表面に光沢が認められなかった
実施例及び比較例において得られた各組成物について、GHS(「化学品の分類及び表示に関する世界調和システム(Globally Harmonized System of Classification and Labeling of Chemicals)」)に基づく危険表示の必要性の有無を判断した。判定結果を下記の記号で示した。
◎:製品ラベル中に危険表示不要
Xi:刺激性表示の義務あり
Xn:有害性表示の義務あり
C:腐食性表示の義務あり
N:環境危険性表示の義務あり
実施例及び比較例において得られた各組成物について、欧州連合で制定された有害性化学物質のリスクの内容を表す分類番号のいずれに該当するかを判断した。判定結果及び分類番号の内容は下記の通りである。
◎:リスクフレーズ不要
R10:引火性がある
R36:眼に刺激性がある
R50:水生生物に強い毒性がある
R52:水生生物に有害性がある
R53:水生環境中で長期悪影響を引き起こすおそれがある
R66:暴露の繰り返しにより皮膚の乾燥又はひび割れを引き起こすことがある
R67:気体は眠気やめまいを引き起こすおそれがある
実施例及び比較例において得られた各組成物について、クリーブランド開放式引火点測定により引火性の有無を調べた。判定結果を下記の記号で示した。
◎:引火性なし
×:引火性有り
周囲を遮光した調合用容器を準備した。次いで、表1及び2に示した量(質量部)の各成分を該調合用容器に取り、次いで、室温で十分に攪拌混合することにより均一な組成物を得た。次いで、該組成物に関して、上記の各試験を実施して評価した。評価結果を表1及び2に示す。
上記と同一にして、表3に示した量(質量部)の各成分を使用して基本組成物を製造した。次いで、表4に示した量(質量部)の基本組成物と、成分(B)又は比較成分(B)とを使用して、均一な組成物を得た。次いで、該組成物に関して、硬化前後の外観を評価した。評価結果を表4に示す。
Claims (9)
- (A)活性エネルギー線照射により重合反応し得る官能基を含む重合体の水性エマルジョン、(B)ポリエチレングリコール、及び(C)光ラジカル開始剤(但し、分子中に窒素原子を含むものを除く)を含む、爪又は人工爪被覆用硬化性樹脂組成物。
- 活性エネルギー線照射により重合反応し得る官能基が、(メタ)アクリロイル基である、請求項1記載の爪又は人工爪被覆用硬化性樹脂組成物。
- 活性エネルギー線照射により重合反応し得る官能基を含む重合体が、主鎖構造としてポリアクリル系骨格又はポリウレタン系骨格を有する、請求項1又は2記載の爪又は人工爪被覆用硬化性樹脂組成物。
- 活性エネルギー線照射により重合反応し得る官能基を含む重合体が、上記の水性エマルジョン(A)中に25〜55質量%含まれる、請求項1〜3のいずれか一つに記載の爪又は人工爪被覆用硬化性樹脂組成物。
- 活性エネルギー線照射により重合反応し得る官能基を含む重合体の数平均分子量が、10,000〜500,000である、請求項1〜4のいずれか一つに記載の爪又は人工爪被覆用硬化性樹脂組成物。
- (B)ポリエチレングリコールを、上記の水性エマルジョン(A)に含まれる、活性エネルギー線照射により重合反応し得る官能基を含む重合体100質量部に対して、0.1〜30質量部含む、請求項1〜5のいずれか一つに記載の爪又は人工爪被覆用硬化性樹脂組成物。
- (C)光ラジカル開始剤を、上記の水性エマルジョン(A)に含まれる、活性エネルギー線照射により重合反応し得る官能基を含む重合体100質量部に対して、1〜10質量部含む、請求項1〜6のいずれか一つに記載の爪又は人工爪被覆用硬化性樹脂組成物。
- (D)天然物由来のワックスを更に含む、請求項1〜7のいずれか一つに記載の爪又は人工爪被覆用硬化性樹脂組成物。
- (D)天然物由来のワックスを、上記の水性エマルジョン(A)に含まれる、活性エネルギー線照射により重合反応し得る官能基を含む重合体100質量部に対して、0.1〜15質量部含む、請求項1〜7のいずれか一つに記載の爪又は人工爪被覆用硬化性樹脂組成物。
Priority Applications (7)
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JP2009278268A JP5544533B2 (ja) | 2009-12-08 | 2009-12-08 | 爪又は人工爪被覆用硬化性樹脂組成物 |
EP10835949.8A EP2510920A4 (en) | 2009-12-08 | 2010-12-07 | HARDENABLE RESIN COMPOSITION FOR COATING A FINGERAGAIL OR AN ARTIFICIAL FINGERAGUS |
CN201080055682.6A CN102770119B (zh) | 2009-12-08 | 2010-12-07 | 指甲或人工指甲被覆用硬化性树脂组合物 |
PCT/JP2010/071862 WO2011071029A1 (ja) | 2009-12-08 | 2010-12-07 | 爪又は人工爪被覆用硬化性樹脂組成物 |
US13/514,818 US8846011B2 (en) | 2009-12-08 | 2010-12-07 | Curable resin composition for covering a fingernail or artificial fingernail |
KR1020127017492A KR20120103682A (ko) | 2009-12-08 | 2010-12-07 | 손발톱 또는 인공 손발톱 피복용 경화성 수지 조성물 |
TW99142756A TW201132362A (en) | 2009-12-08 | 2010-12-08 | Curable resin composition for fingernail or artificial fingernail coating |
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JP2009278268A JP5544533B2 (ja) | 2009-12-08 | 2009-12-08 | 爪又は人工爪被覆用硬化性樹脂組成物 |
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US (1) | US8846011B2 (ja) |
EP (1) | EP2510920A4 (ja) |
JP (1) | JP5544533B2 (ja) |
KR (1) | KR20120103682A (ja) |
CN (1) | CN102770119B (ja) |
TW (1) | TW201132362A (ja) |
WO (1) | WO2011071029A1 (ja) |
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US9044405B2 (en) | 2013-02-27 | 2015-06-02 | O P I Products, Inc. | Composition having a reduced exotherm in actinic curing of urethane (meth)acrylate oligomers on fingernails |
EP3006515B1 (en) * | 2013-05-27 | 2019-08-28 | DIC Corporation | Active energy ray-curable composition, and ink composition for inkjet recording use which is prepared using said composition |
US20170049684A1 (en) * | 2014-04-30 | 2017-02-23 | Arkema France | Curable aqueous polyurethane dispersions made from renewable resources |
US9820931B2 (en) | 2014-10-13 | 2017-11-21 | L'oreal | Latex nail compositions having low amounts of photo-initiator |
US9649272B2 (en) | 2014-10-13 | 2017-05-16 | L'oréal | Latex nail compositions having low amounts of photo-initiator |
US9636293B2 (en) * | 2014-10-13 | 2017-05-02 | L'oréal | Latex nail compositions having low amounts of photo-initiator |
CN107072924B (zh) * | 2014-11-05 | 2020-08-14 | 三键有限公司 | 指甲或人工指甲的面漆用光固化性组合物 |
WO2016152546A1 (ja) * | 2015-03-25 | 2016-09-29 | 富士フイルム株式会社 | 人工爪組成物、人工爪、人工爪の除去方法、及び、ネイルアートキット |
WO2017082057A1 (ja) * | 2015-11-09 | 2017-05-18 | 株式会社スリーボンド | 爪または人工爪用光硬化性組成物、これらを含むベースコート剤、これらの硬化物、これらの硬化物の製造方法、およびこれらの硬化物の剥離方法、これらを用いた被覆方法、ならびにこれらの使用方法 |
TWI595890B (zh) * | 2016-05-09 | 2017-08-21 | 穗曄實業股份有限公司 | 光固化甲油膠組成物 |
CN106074219B (zh) * | 2016-06-07 | 2018-09-28 | 杭州淳浠化妆品有限公司 | 一种耐水水性指甲油及其制备方法 |
TW201829537A (zh) * | 2016-07-29 | 2018-08-16 | 日商東亞合成股份有限公司 | 硬化型組成物 |
US11406585B2 (en) | 2016-12-19 | 2022-08-09 | Threebond Co., Ltd. | Photocurable resin composition for nail or artificial nail |
US10362850B2 (en) | 2017-01-10 | 2019-07-30 | L'oréal | Dye-free nail varnish compositions and methods thereof |
CN109008156A (zh) * | 2018-07-02 | 2018-12-18 | 李东洪 | 一种无痕甲片 |
JP7178206B2 (ja) | 2018-08-09 | 2022-11-25 | 花王株式会社 | インクジェット記録用水性組成物 |
JP7217106B2 (ja) * | 2018-08-09 | 2023-02-02 | 花王株式会社 | インクジェット記録用水性組成物 |
JPWO2022163248A1 (ja) * | 2021-01-28 | 2022-08-04 | ||
US20240269055A1 (en) * | 2021-06-08 | 2024-08-15 | Threebond Co., Ltd. | Photocurable resin composition for nail or artificial nail |
KR102384577B1 (ko) * | 2021-09-23 | 2022-04-08 | 이미숙 | 내향성 손발톱 교정용 조성물 |
CN115444371B (zh) * | 2022-09-27 | 2024-09-13 | 中山大学附属第三医院 | 一种嗅觉测试装置 |
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- 2010-12-07 CN CN201080055682.6A patent/CN102770119B/zh active Active
- 2010-12-07 KR KR1020127017492A patent/KR20120103682A/ko not_active Application Discontinuation
- 2010-12-07 EP EP10835949.8A patent/EP2510920A4/en not_active Withdrawn
- 2010-12-07 US US13/514,818 patent/US8846011B2/en active Active
- 2010-12-08 TW TW99142756A patent/TW201132362A/zh unknown
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TW201132362A (en) | 2011-10-01 |
KR20120103682A (ko) | 2012-09-19 |
EP2510920A4 (en) | 2015-07-22 |
US8846011B2 (en) | 2014-09-30 |
JP2011121867A (ja) | 2011-06-23 |
WO2011071029A1 (ja) | 2011-06-16 |
US20120276028A1 (en) | 2012-11-01 |
CN102770119B (zh) | 2015-04-08 |
EP2510920A1 (en) | 2012-10-17 |
CN102770119A (zh) | 2012-11-07 |
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LAPS | Cancellation because of no payment of annual fees |