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JP5197113B2 - Stainless steel press-molded body and production method - Google Patents

Stainless steel press-molded body and production method Download PDF

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JP5197113B2
JP5197113B2 JP2008100880A JP2008100880A JP5197113B2 JP 5197113 B2 JP5197113 B2 JP 5197113B2 JP 2008100880 A JP2008100880 A JP 2008100880A JP 2008100880 A JP2008100880 A JP 2008100880A JP 5197113 B2 JP5197113 B2 JP 5197113B2
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JP2009249704A (en
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保利 秀嶋
聡 鈴木
弘泰 松林
廣 藤本
明 弘中
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Nippon Steel Nisshin Co Ltd
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Description

本発明は、加工により加工誘起マルテンサイトが生成する性質のオーステナイト系ステンレス鋼板を素材とした、中間製品のプレス成形体、およびそれを時効処理してなる高強度プレス成形体、並びにその製造方法に関する。この高強度プレス成形体は、例えばカメラ、携帯電話、ノート型パソコン、携帯用音楽機器などのケース部材やヒンジ部品などに好適なものである。   The present invention relates to an intermediate product press-molded body made of an austenitic stainless steel sheet having a property of generating work-induced martensite by processing, a high-strength press-molded body formed by aging treatment thereof, and a method for producing the same. . This high-strength press-molded body is suitable for case members and hinge parts of cameras, mobile phones, notebook computers, portable music devices, and the like.

従来、高強度が要求されるステンレス鋼製のプレス成形品には、SUS410、SUS420J2などのマルテンサイト系ステンレス鋼や、SUS301などの加工硬化の大きい高C型オーステナイト系ステンレス鋼が使用されてきた。しかし、マルテンサイト系ステンレス鋼はプレス成形後に焼入れ処理を施す必要があり、焼入れ温度が高いため生産性が悪く、焼入れ時の寸法変化が大きいという問題がある。一方、加工硬化の大きい高C型オーステナイト系ステンレス鋼は鋼板の段階で調質圧延により材料を硬化させるものであるが、素材鋼板が硬いためにプレス金型の負荷や摩耗が大きく、加工度の大きい成形品を作ることが難しい。また高い寸法精度を得ることも難しい。   Conventionally, martensitic stainless steels such as SUS410 and SUS420J2 and high C-type austenitic stainless steels such as SUS301 with high work hardening have been used for press-formed products made of stainless steel that require high strength. However, martensitic stainless steel needs to be subjected to a quenching treatment after press forming, and has a problem that productivity is poor due to a high quenching temperature, and a dimensional change during quenching is large. On the other hand, high C type austenitic stainless steel with high work hardening is a material that hardens the material by temper rolling at the stage of steel sheet. It is difficult to make large molded products. It is also difficult to obtain high dimensional accuracy.

特開昭56−77364号公報JP-A-56-77364 特開平4−168227号公報JP-A-4-168227 特開2000−63996号公報JP 2000-63996 A

本発明は、プレス金型への負荷が少ない鋼板材料を用いて、少なくとも加工部に350HV以上の硬化部分を有する高強度ステンレス鋼プレス成形体を提供しようというものである。   The present invention intends to provide a high strength stainless steel press-formed body having a hardened portion of 350 HV or higher in at least a processed portion using a steel plate material with a small load on a press die.

発明者らは研究の結果、Cuを含有するオーステナイト系ステンレス鋼において、加工誘起マルテンサイトの生成し易さを調整し、かつC含有量を低減したときに、
(i)素材鋼板の段階では比較的軟質でプレス金型への負荷が少なくなり、
(ii)プレス成形後には高強度が要求される加工部に少なくとも10体積%以上の加工誘起マルテンサイトが存在する部分を形成させることができ、
(iii)その後に時効処理を施すことによって10体積%以上の加工誘起マルテンサイトが存在する部分を顕著に高強度化させることが可能になること、
を見出した。本発明はこのような知見に基づいて完成したものである。
As a result of research, the inventors have adjusted the easiness of forming work-induced martensite and reduced the C content in the austenitic stainless steel containing Cu.
(I) At the material steel plate stage, it is relatively soft and reduces the load on the press die.
(Ii) After press molding, a portion where at least 10% by volume or more of processing-induced martensite is present can be formed in a processed portion requiring high strength,
(Iii) By performing an aging treatment thereafter, it becomes possible to remarkably increase the strength of a portion where 10% by volume or more of the processing-induced martensite exists,
I found. The present invention has been completed based on such findings.

すなわち本発明では、質量%で、C:0.03%以下、Si:0.5〜2%、Mn:0.5〜2%、Ni:6〜10%、Cr:15〜18%、Cu:1〜3.5%、N:0.03%以下であり、必要に応じてMo:3%以下を含有し、残部Feおよび不可避的不純物からなり、下記(1)式のMd値が10〜30である組成の鋼板を素材とするプレス成形体であって、加工誘起マルテンサイト量が10体積%以上かつ肉厚中央部の断面硬さが350HV未満である部分をプレス加工部に有する、未だ時効処理されていない中間製品のステンレス鋼プレス成形体が提供される。
Md=551−462(C+N)−9.2Si−8.1Mn−29(Ni+Cu)−13.7Cr−18.5Mo ……(1)
That is, in the present invention, by mass, C: 0.03% or less, Si: 0.5-2%, Mn: 0.5-2%, Ni: 6-10%, Cr: 15-18%, Cu : 1 to 3.5%, N: 0.03% or less, optionally containing Mo: 3% or less, consisting of the balance Fe and unavoidable impurities, Md value of the following formula (1) is 10 It is a press-molded body made of a steel plate having a composition of ~ 30, and has a portion where the processing induced martensite amount is 10% by volume or more and the cross-sectional hardness of the wall thickness central portion is less than 350 HV in the pressed portion. An intermediate stainless steel press-molded body that has not yet been aged is provided.
Md = 551-462 (C + N) -9.2 Si-8.1 Mn-29 (Ni + Cu) -13.7Cr-18.5Mo (1)

この中間製品のプレス成形体は、その後に時効処理に供することによって高強度化が可能な性質を有している。(1)式の元素記号の箇所には、それぞれ各元素の含有量(質量%の値)が代入される。Mo無添加の鋼では(1)式のMoの箇所には0(零)が代入される。プレス成形体は、プレス加工によって塑性変形を付与することにより得られた加工品であり、絞り加工や曲げ加工など、少なくとも打ち抜き(せん断加工)以外のプレス加工を受けたものである。もちろん一部に打ち抜き(せん断加工)部を有していても構わない。加工誘起マルテンサイト量は、フェライトスコープによる磁気的な測定手法で求めることができる。プレス加工部とは、プレスによって塑性変形を加えた部分(せん断加工部を有するものにおいては、せん断面付近の硬化部分を除く)である。   This press-formed product of the intermediate product has a property that can be increased in strength by subjecting it to an aging treatment thereafter. The content (% by mass) of each element is substituted for each element symbol in the formula (1). In steel containing no Mo, 0 (zero) is substituted into the Mo position in the equation (1). The press-formed body is a processed product obtained by imparting plastic deformation by press processing, and has been subjected to press processing other than punching (shear processing) such as drawing or bending. Of course, you may have a punching (shear process) part in part. The amount of processing-induced martensite can be determined by a magnetic measurement method using a ferrite scope. The press working part is a part to which plastic deformation is applied by pressing (excluding a hardened part in the vicinity of the shear surface in the case of having a shearing part).

また本発明では、上記組成の鋼板を素材とするプレス成形体であって、加工誘起マルテンサイト量が10体積%以上かつ肉厚中央部の断面硬さが350HV以上である部分をプレス加工部に有し、マルテンサイト中には時効析出したCuリッチ相が分散している高強度ステンレス鋼プレス成形体が提供される。   Further, in the present invention, a press-formed body made of a steel plate having the above composition, wherein a portion where the work-induced martensite amount is 10% by volume or more and the cross-sectional hardness of the wall thickness central part is 350 HV or more is used as the pressed part. And a high-strength stainless steel press-formed body in which an aged Cu-rich phase is dispersed in martensite.

さらに本発明では、このような高強度ステンレス鋼プレス成形体の製造方法として、上記組成を有し、マトリクスがオーステナイト単相組織または「オーステナイト+25体積%以下の加工誘起マルテンサイト」の複相組織に調整された鋼板に対して、プレス成形を施すことにより、「肉厚中央部の断面硬さが350HV未満であり、加工誘起マルテンサイト量が少なくとも10体積%以上である部分」をプレス加工部に有するプレス成形体を作る工程、
前記プレス成形体に、400〜500℃の温度域における時効温度T(K)と時効時間t(h)が下記(2)式を満たす条件で時効処理を施す工程、
を有する高強度ステンレス鋼プレス成形体の製造方法が提供される。
13000≦T(logt+20)≦16500 ……(2)
Furthermore, in the present invention, as a method for producing such a high-strength stainless steel press-formed body, the matrix has an austenite single-phase structure or a multiphase structure of “austenite + 25 volume% or less work-induced martensite”. By applying press forming to the adjusted steel sheet, "the portion where the cross-sectional hardness of the central wall portion is less than 350 HV and the amount of work-induced martensite is at least 10% by volume or more" A step of making a press-formed body having,
A step of subjecting the press-molded body to an aging treatment under a condition that an aging temperature T (K) and an aging time t (h) in a temperature range of 400 to 500 ° C. satisfy the following formula (2):
There is provided a method for producing a high-strength stainless steel press-formed body having the following.
13000 ≦ T (logt + 20) ≦ 16500 (2)

本発明によれば、比較的軟質な素材鋼板をプレス成形に供することができるため、高強度ステンレス鋼プレス製品を作る際に問題となりやすいプレス金型の負荷増大・寿命低下が回避される。寸法精度の向上にも有効となる。また、プレス成形品を時効処理に供することにより、特に高硬度が要求される加工部において顕著な硬化を図ることができる。時効処理は焼入れ処理と比べ加熱温度が低く急冷処理も不要であるため、プレス加工後の工程負荷は少なくてすむ。したがって本発明は高強度ステンレス鋼プレス成形品の大量生産により適している。   According to the present invention, since a relatively soft material steel plate can be used for press forming, it is possible to avoid an increase in load and a decrease in service life of a press die that are likely to be a problem when producing a high-strength stainless steel press product. It is also effective in improving dimensional accuracy. In addition, by subjecting the press-formed product to an aging treatment, remarkable hardening can be achieved particularly in a processed portion requiring high hardness. Since the aging treatment has a lower heating temperature than the quenching treatment and does not require a rapid cooling treatment, the process load after press working can be reduced. Therefore, the present invention is more suitable for mass production of high-strength stainless steel press-formed products.

《化学組成》
本発明では、鋼の化学組成を以下のように限定する。化学組成における「%」は特に断らない限り「質量%」を意味する。
<Chemical composition>
In the present invention, the chemical composition of steel is limited as follows. “%” In the chemical composition means “% by mass” unless otherwise specified.

〔C:0.03%以下〕
Cは加工誘起マルテンサイト相を硬質化させる作用を有する。このため、加工性を改善するためには低C化が有利となる。本発明では、プレス成形体の高硬度が必要な部位について後述のCuによる優れた時効硬化特性を利用するので、高強度化を目的としてC含有量を高くする必要はない。種々検討の結果、C含有量は0.03%以下に制限する。0.03%未満に制限することもできる。このようなC含有量の低減により、加工誘起マルテンサイト相の硬質化が抑制され、プレス金型に対する負荷の低減および寸法精度の向上に有利となる。また、時効処理後の耐食性低下に対しても有利となる。
[C: 0.03% or less]
C has the effect of hardening the work-induced martensite phase. For this reason, in order to improve workability, low C is advantageous. In the present invention, since an excellent age hardening property by Cu described later is used for a portion of the press-molded body that requires high hardness, it is not necessary to increase the C content for the purpose of increasing the strength. As a result of various studies, the C content is limited to 0.03% or less. It can also be limited to less than 0.03%. Such reduction of the C content suppresses the hardening of the work-induced martensite phase, which is advantageous for reducing the load on the press die and improving the dimensional accuracy. In addition, it is advantageous for reducing corrosion resistance after aging treatment.

〔Si:0.5〜2%〕
Siは脱酸剤として有効である。また、プレス成形によるマルテンサイト相の誘起に有効に作用し、Md点の調整のためにSiの含有が必要となる。さらにSiは時効処理による硬化にも有効である。種々検討の結果、時効処理による硬化作用を十分に発揮させるには0.5%以上のSi含有が必要である。しかし、Siをあまり多量に添加しても上記硬化作用は飽和し、不経済となる。一方、脱酸剤としての機能や、Md点の調整機能は0.5〜2%のSi含有量範囲で十分に発揮させることができる。したがってSi含有量は上記のとおりに規定する。
[Si: 0.5-2%]
Si is effective as a deoxidizer. Moreover, it acts effectively on the induction of the martensite phase by press molding, and it is necessary to contain Si for adjusting the Md point. Further, Si is effective for hardening by aging treatment. As a result of various studies, it is necessary to contain 0.5% or more of Si in order to fully exhibit the hardening action by the aging treatment. However, even if Si is added in a large amount, the curing action is saturated, which is uneconomical. On the other hand, the function as a deoxidizer and the function of adjusting the Md point can be sufficiently exerted in the Si content range of 0.5 to 2%. Accordingly, the Si content is defined as described above.

〔Mn:0.5〜2%〕
Mnはオーステナイト相の安定化に大きく寄与する元素である。Si等の元素とのバランスを考慮して、オーステナイト相の安定化のためには0.5%以上のMn含有が必要である。ただし、その目的は2%以下の含有量範囲で十分達成できる。
[Mn: 0.5 to 2%]
Mn is an element that greatly contributes to the stabilization of the austenite phase. In consideration of the balance with elements such as Si, 0.5% or more of Mn content is necessary for stabilizing the austenite phase. However, the purpose can be sufficiently achieved within a content range of 2% or less.

〔Ni:6〜10%〕
Niは仕上焼鈍後にオーステナイト組織を得るために必須の元素であり、少なくとも6%以上の含有が必要である。しかし、あまり多量に添加する必要はなく、過剰添加はコスト増を招くので好ましくない。種々検討の結果、Ni含有量は10%以下の範囲とすればよい。
[Ni: 6 to 10%]
Ni is an essential element for obtaining an austenite structure after finish annealing, and at least 6% or more is necessary. However, it is not necessary to add too much, and excessive addition is not preferable because it causes an increase in cost. As a result of various studies, the Ni content may be in the range of 10% or less.

〔Cr:15〜18%〕
Crはステンレス鋼に要求される耐食性を付与するために必須の元素である。種々検討の結果、カメラ、携帯電話、ノート型パソコン、携帯用音楽機器などのケース部材やヒンジ部品等の用途を考慮すると、15%以上のCr含有量を確保することが望まれる。しかし、Cr含有量が増大するとδフェライト相が生成しやすくなり、熱間加工性を低下させる要因となるので、Cr含有量の上限は18%に制限される。
[Cr: 15-18%]
Cr is an essential element for imparting the corrosion resistance required for stainless steel. As a result of various investigations, it is desirable to secure a Cr content of 15% or more in consideration of applications such as case members and hinge parts of cameras, mobile phones, notebook computers, portable music devices, and the like. However, if the Cr content is increased, a δ ferrite phase is likely to be generated, which causes a decrease in hot workability, so the upper limit of the Cr content is limited to 18%.

〔Cu:1〜3.5%〕
Cuは時効処理によりマルテンサイト相中に析出し、プレス成形体の高強度化に寄与する。すなわち、Cuは仕上焼鈍によりオーステナイト相中に固溶し、加工中に生じた加工誘起マルテンサイト中では固溶限が低下するため、その後の時効処理でマルテンサイト相中にCuリッチ相として析出する。このCuリッチ相は、Cuが濃化した第2相であり、いわゆるε−Cu相と呼ばれるものもこれに該当するが、極めて微細なクラスターであっても構わない。マルテンサイト相中でのこのようなCuリッチ相の析出は、顕著な高強度化をもたらす。そのためには、1%以上のCu含有量を確保する必要があり、1.5%以上とすることがより好ましい。しかし、過剰のCu含有は熱間加工性を低下させる要因となるので、Cu含有量の上限は3.5%に制限される。
[Cu: 1 to 3.5%]
Cu precipitates in the martensite phase by aging treatment, and contributes to increasing the strength of the press-formed product. That is, Cu is solid-dissolved in the austenite phase by finish annealing, and the solid solubility limit is lowered in the processing-induced martensite generated during processing, so that it precipitates as a Cu-rich phase in the martensite phase in the subsequent aging treatment. . This Cu-rich phase is a second phase in which Cu is concentrated, and a so-called ε-Cu phase also corresponds to this, but it may be a very fine cluster. Precipitation of such a Cu-rich phase in the martensite phase results in a significant increase in strength. For that purpose, it is necessary to secure a Cu content of 1% or more, and it is more preferably 1.5% or more. However, since excessive Cu content causes a decrease in hot workability, the upper limit of Cu content is limited to 3.5%.

〔N:0.03%以下〕
NもCと同様に加工誘起マルテンサイト相の硬質化を招く。検討の結果、本発明ではN含有量を0.03%以下に制限する。
[N: 0.03% or less]
N, like C, leads to hardening of the work-induced martensite phase. As a result of the study, in the present invention, the N content is limited to 0.03% or less.

〔Mo:3%以下〕
Moは高Cr鋼において耐食性を向上させる作用を有し、また時効処理時に析出して高強度化にも寄与する。このため、本発明では必要に応じてMoを含有させることができる。0.04%以上のMo含有量を確保することがより効果的である。高い耐食性を得たい場合は0.5%以上とするのがより好ましい。ただし、Moを過剰に含有させても上記の作用の増大は期待できず、コスト上昇を招くので、Mo含有量は3%以下の範囲とする。
[Mo: 3% or less]
Mo has the effect of improving corrosion resistance in high Cr steel, and also precipitates during the aging treatment and contributes to high strength. For this reason, in this invention, Mo can be contained as needed. It is more effective to secure a Mo content of 0.04% or more. When it is desired to obtain high corrosion resistance, the content is more preferably 0.5% or more. However, even if Mo is contained excessively, an increase in the above effect cannot be expected and the cost is increased. Therefore, the Mo content is set to 3% or less.

〔Md値:10〜30〕
下記(1)式は、焼鈍された状態でのオーステナイト相の安定度を示す指標である。すなわち、(1)式の値が大きくなるほどオーステナイト相は不安定となり、加工誘起マルテンサイト相が生成しやすくなる。
Md=551−462(C+N)−9.2Si−8.1Mn−29(Ni+Cu)−13.7Cr−18.5Mo ……(1)
[Md value: 10-30]
The following formula (1) is an index indicating the stability of the austenite phase in the annealed state. That is, as the value of the formula (1) increases, the austenite phase becomes unstable, and a work-induced martensite phase is easily generated.
Md = 551-462 (C + N) -9.2 Si-8.1 Mn-29 (Ni + Cu) -13.7Cr-18.5Mo (1)

本発明では、このMd値が10〜30という狭い範囲に入るように各合金元素の含有量を厳密に調整する。Md値が10より小さいと仕上焼鈍後のオーステナイト相が安定になりすぎ、プレス成形体の加工部において時効硬化に大きく寄与する加工誘起マルテンサイト相の生成量を十分に確保するためには、調質圧延率をかなり高くした鋼板素材を使用する必要が生じる。この場合、プレス金型に対する負荷が増大し好ましくない。一方、Md値が30を超えて大きくなるとオーステナイト相が過度に不安定となり、プレス成形体における加工誘起マルテンサイト相の生成量にバラツキが生じやすくなり、最終的な製品においても特性がバラツキやすくなる。   In the present invention, the content of each alloy element is strictly adjusted so that the Md value falls within a narrow range of 10 to 30. If the Md value is less than 10, the austenite phase after finish annealing becomes too stable, and in order to sufficiently secure the amount of work-induced martensite phase generated that greatly contributes to age hardening in the processed part of the press-formed body, It is necessary to use a steel plate material having a considerably high quality rolling rate. In this case, the load on the press mold increases, which is not preferable. On the other hand, if the Md value exceeds 30 and the austenite phase becomes excessively unstable, the amount of work-induced martensite phase in the press-molded product tends to vary, and the properties of the final product also tend to vary. .

《中間製品である時効処理前のプレス成形体》
この段階のプレス成形体は、加工誘起マルテンサイト量が10体積%以上である部分をプレス加工部に有していることが必要である。前述のように、マトリクス中に過飽和に固溶しているCuは、後工程で時効処理を施したときに、より固溶限の小さいマルテンサイト相において析出しやすく、特に加工誘起マルテンサイト相を顕著に硬化させる。加工誘起マルテンサイト相は、その生成量が同じでも、引張り、張り出し、深絞り、曲げ等の加工様式によって加工硬化特性が多少異なってくる。ところが、発明者らの検討によれば、どのような加工様式で生成した加工誘起マルテンサイト相であっても、プレス成形体の加工部に10体積%以上の加工誘起マルテンサイト相が存在する部分があれば、その部分において後述の時効処理により顕著な硬化をもたらすことが可能である。加工誘起マルテンサイト量が10体積%に満たない部分については、時効処理により安定して顕著な時効硬化を得ることは難しい。ただし、プレス成形体を用いた部品においては、通常その全体が顕著に硬化している必要はなく、高強度が要求される加工部のみが十分に硬化していれば足りる。したがって、本発明の中間製品であるプレス成形体においては、少なくとも加工部に、加工誘起マルテンサイト量が10体積%以上である部分を有していることが重要である。
《Press-formed body before aging treatment as an intermediate product》
The press-molded body at this stage needs to have a portion where the amount of work-induced martensite is 10% by volume or more in the press-worked portion. As described above, Cu that is supersaturated in the matrix is likely to precipitate in the martensite phase having a lower solid solubility limit when aging treatment is performed in a later step, and in particular, the processing-induced martensite phase is reduced. Harden significantly. The work-induced martensite phase has a slightly different work-hardening characteristic depending on the processing mode such as tension, stretching, deep drawing, bending, etc., even if the amount of the work-induced martensite phase is the same. However, according to the study by the inventors, a part in which a processing induced martensite phase of 10% by volume or more exists in the processed part of the press-molded body, regardless of the processing induced martensite phase generated by any processing mode. If there is, it is possible to bring about remarkable hardening by the later-described aging treatment. For portions where the amount of work-induced martensite is less than 10% by volume, it is difficult to stably obtain significant age hardening by aging treatment. However, in the case of a part using a press-molded body, it is usually not necessary that the whole is significantly hardened, and it is sufficient that only a processed part requiring high strength is sufficiently hardened. Therefore, in the press-formed body which is an intermediate product of the present invention, it is important that at least the processed portion has a portion where the amount of processing-induced martensite is 10% by volume or more.

また、この中間製品であるプレス成形体は、上記の加工誘起マルテンサイト量が10体積%以上である部分において、肉厚中央部の断面硬さが350HV未満である箇所を有している必要がある。プレス成形されたまま(時効処理前)の段階で、10体積%以上の加工誘起マルテンサイト相が生成している全ての部分が350HV以上の硬さになっているようなプレス成形体は、例えばC含有量の高い鋼種を用いたり、調質圧延率の高い素材鋼板を用いたりする手法によって作製できるが、その場合はプレス金型に多大な負荷をかけており、結果的にコストの高い中間製品となる。   Moreover, the press-molded body which is this intermediate product needs to have a portion where the cross-sectional hardness of the central thickness portion is less than 350 HV in the portion where the amount of work-induced martensite is 10% by volume or more. is there. A press-molded body in which all portions where a work-induced martensite phase of 10% by volume or more is generated at a stage of being pressed (before aging treatment) has a hardness of 350 HV or more is, for example, It can be produced by using a steel type with a high C content or using a steel plate with a high temper rolling ratio, but in that case, a heavy load is applied to the press die, resulting in a high cost intermediate. Become a product.

《時効処理後のプレス成形体》
時効処理を受けたプレス成形体としては、肉厚中央部の断面硬さが350HV以上である部分をプレス加工部に有しているものが対象となる。前述のように、プレス成形体を用いた部品においては、通常、高強度が要求される加工部のみが顕著に硬化していればよい。カメラ、携帯電話、ノート型パソコン、携帯用音楽機器などのケース部材やヒンジ部品等をはじめ、従来、高強度ステンレス鋼プレス成形体が適用されている多くの用途では、高強度が要求される部位の材料硬さは350HV以上であることが望まれる。本発明の高強度ステンレス鋼プレス成形体は加工誘起マルテンサイト相中におけるCuリッチ相の析出を利用して、高強度化を実現している。このため、当該プレス成形体は、350HV以上に硬化している部分の加工誘起マルテンサイト量が10体積%以上であり、かつ、その部分のマルテンサイト中には時効析出したCuリッチ相が分散していることに特徴がある。
<Press-formed product after aging treatment>
As a press-molded body that has undergone an aging treatment, one having a portion having a cross-sectional hardness of 350 HV or more in the center of the thickness in the press-worked portion is an object. As described above, in a part using a press-molded body, normally only a processed part requiring high strength needs to be significantly hardened. In many applications where high-strength stainless steel press-molded bodies have been used in the past, such as case members and hinge parts for cameras, mobile phones, notebook computers, portable music devices, etc., parts that require high strength The material hardness is desirably 350 HV or more. The high-strength stainless steel press-formed body of the present invention achieves high strength by utilizing precipitation of a Cu-rich phase in the work-induced martensite phase. For this reason, in the press-molded body, the amount of work-induced martensite in a portion cured to 350 HV or more is 10% by volume or more, and an aging-precipitated Cu-rich phase is dispersed in the martensite in that portion. There is a feature.

《製造方法》
〔製造工程〕
上記のような高強度ステンレス鋼プレス成形体は、所定厚さの鋼板(熱延鋼板または冷延鋼板)に溶体化処理を施すことによりオーステナイト単相組織とし、必要に応じて調質圧延を行って素材鋼板とし、その素材鋼板をプレス成形に供し、その後、時効処理を施す工程によって得ることができる。
"Production method"
〔Manufacturing process〕
The above high-strength stainless steel press-formed bodies are made into austenite single-phase structure by subjecting a steel plate (hot rolled steel plate or cold rolled steel plate) with a predetermined thickness to solution treatment, and temper rolling is performed as necessary. It can be obtained by a step of forming a raw steel plate, subjecting the raw steel plate to press forming, and then performing an aging treatment.

〔素材鋼板〕
プレス成形に供する素材鋼板としては、上述の化学組成を有し、マトリクスがオーステナイト単相組織または「オーステナイト+25体積%以下の加工誘起マルテンサイト」の複相組織に調整された鋼板を用いる。プレス成形体の形状によっては、オーステナイト単相組織の素材鋼板を用いたときに、高強度が要求される部位において「オーステナイト+10体積%以上の加工誘起マルテンサイト」の複相組織が得られないことがある。例えば浅い絞り加工や、比較的軽度の曲げ加工を施して得られるプレス成形体などでは、そのようなことになりやすい。また、プレス加工部で特に高い硬さが要求される場合や、プレス加工部以外の部位も高強度化したい場合も想定される。このようなときには、予め調質圧延によって10体積%以上の加工誘起マルテンサイト相を生成させた素材鋼板を使用することが有効である。どの程度の加工誘起マルテンサイト相を生成させた素材鋼板を用意するかは、組成、プレス成形の加工度などに応じて決定される。加工誘起マルテンサイト相の生成量は調質圧延率によって調整できる。ただし、素材鋼板の段階での加工誘起マルテンサイト相の量が25体積%を超えるとプレス金型に与える負荷が過大となりやすい。
[Material steel plate]
As a material steel plate used for press forming, a steel plate having the above-described chemical composition and having a matrix adjusted to austenite single phase structure or a multiphase structure of “austenite + 25% by volume or less work-induced martensite” is used. Depending on the shape of the press-formed body, when using austenite single-phase structure steel sheet, it is not possible to obtain a multiphase structure of “austenite + 10% by volume or more of work-induced martensite” at the site where high strength is required. There is. For example, such a situation tends to occur in a press-molded body obtained by performing a shallow drawing process or a relatively light bending process. Moreover, the case where especially high hardness is requested | required in a press work part, and the case where it is wished to also strengthen parts other than a press work part are assumed. In such a case, it is effective to use a raw steel plate in which a work-induced martensite phase of 10% by volume or more has been generated in advance by temper rolling. How much work-induced martensite phase is produced depends on the composition, the degree of press forming, and the like. The amount of work-induced martensite phase produced can be adjusted by the temper rolling rate. However, if the amount of the work-induced martensite phase at the stage of the raw steel plate exceeds 25% by volume, the load applied to the press die tends to be excessive.

〔プレス成形〕
プレス成形は、従来一般的な種々の方法が適用できる。プレス成形に際しては、上述したように、「肉厚中央部の断面硬さが350HV未満であり、加工誘起マルテンサイト量が少なくとも10体積%以上である部分」をプレス加工部に有するプレス成形体を作ることが重要である。もちろん、特に高強度を必要とする部分は350HVを超える硬さになっていて構わない。
〔Press molding〕
Various conventional methods can be applied to press molding. In press molding, as described above, a press-molded body having, as described above, “a portion where the cross-sectional hardness of the central thickness portion is less than 350 HV and the amount of work-induced martensite is at least 10% by volume or more” It is important to make. Of course, the portion requiring particularly high strength may have a hardness exceeding 350 HV.

〔時効処理〕
プレス成形後には時効処理を施して、加工誘起マルテンサイト中にCuリッチ相を分散析出させることにより高強度ステンレス鋼プレス成形体が得られる。種々検討の結果、時効温度は400〜500℃の温度域とし、かつ、時効温度T(K)と時効時間t(h)が下記(2)式を満たす条件とすることが有効である。T(logt+20)の値が小さすぎるとCuリッチ相の析出物サイズが小さくなり、転位運動を十分に阻害する作用が発揮されにくくなる。一方、T(logt+20)の値が過大になるとCuリッチ相の粒子が粗大化し、転位が析出粒子を迂回しやすくなり、また析出粒子間距離も長くなるので硬化現象が発揮されにくくなる。なお、(2)式に替えて(2)’式を満たす範囲とすることが一層好ましい。
13000≦T(logt+20)≦16500 ……(2)
14000≦T(logt+20)≦16000 ……(2)’
[Aging treatment]
After press forming, an aging treatment is performed to disperse and precipitate the Cu-rich phase in the work-induced martensite, thereby obtaining a high-strength stainless steel press-formed body. As a result of various studies, it is effective that the aging temperature is in a temperature range of 400 to 500 ° C. and that the aging temperature T (K) and the aging time t (h) satisfy the following formula (2). If the value of T (logt + 20) is too small, the precipitate size of the Cu-rich phase becomes small, and the effect of sufficiently inhibiting dislocation movement is hardly exhibited. On the other hand, if the value of T (logt + 20) is excessive, Cu-rich phase particles become coarse, dislocations easily bypass the precipitated particles, and the distance between the precipitated particles becomes longer, so that the hardening phenomenon is hardly exhibited. In addition, it is more preferable to set the range satisfying the formula (2) ′ instead of the formula (2).
13000 ≦ T (logt + 20) ≦ 16500 (2)
14000 ≦ T (logt + 20) ≦ 16000 (2) ′

時効処理を窒化可能な雰囲気で行うことにより、高強度ステンレス鋼プレス成形体の表面を硬化させること可能であり、更なる広範囲の用途展開が期待される。   By performing the aging treatment in an atmosphere capable of nitriding, the surface of the high-strength stainless steel press-molded body can be cured, and further widespread application development is expected.

表1に示す鋼を溶製し、オーステナイト単相組織を有する板厚0.8mmの仕上げ焼鈍材を得た。   The steel shown in Table 1 was melted to obtain a finish annealed material having a thickness of 0.8 mm and having an austenite single phase structure.

Figure 0005197113
Figure 0005197113

上記仕上げ焼鈍材から採取した板材を素材鋼板に用いて、下記の条件で深絞りカップ(中間製品のプレス成形体)を作製した。
ブランク直径:76mm、パンチ直径:40mm、パンチ肩半径:6mm、ダイス直径:42mm、ダイス肩半径:6mm、シワ押さえ力:1ton
この深絞りカップを、大気中450℃で1時間保持する時効処理に供した。この場合、前述のT(logt+20)の値は14460であり、(2)式および(2)’式を満たしている。
A deep drawn cup (a press-formed product of an intermediate product) was produced under the following conditions using a plate material collected from the finish annealing material as a raw steel plate.
Blank diameter: 76 mm, punch diameter: 40 mm, punch shoulder radius: 6 mm, die diameter: 42 mm, die shoulder radius: 6 mm, wrinkle holding force: 1 ton
The deep-drawn cup was subjected to an aging treatment that was held at 450 ° C. for 1 hour in the atmosphere. In this case, the value of T (logt + 20) described above is 14460, which satisfies the expressions (2) and (2) ′.

中間製品のプレス成形体サンプルおよび時効処理後のプレス成形体サンプルについて、カップの中心軸を含む平面で切断した。図1に切断した断面における測定位置を模式的に示す。a、b、c、dの4箇所において肉厚中央部の硬さを測定した。中間製品のプレス成形体サンプルについては、さらにフェライトスコープを用いて断面の加工誘起マルテンサイト量を測定した。加工誘起マルテンサイト量の値は板厚補正を適用して求めた。結果を表2に示す。なお、時効処理後の加工誘起マルテンサイト量は、時効処理前(中間製品)と同等である。   The press-molded body sample of the intermediate product and the press-molded body sample after the aging treatment were cut along a plane including the center axis of the cup. FIG. 1 schematically shows a measurement position in the cut section. The hardness at the center of the wall thickness was measured at four locations a, b, c, and d. About the press-molded body sample of the intermediate product, the processing induced martensite amount of the cross section was further measured using a ferrite scope. The value of the processing induced martensite amount was obtained by applying plate thickness correction. The results are shown in Table 2. The amount of processing-induced martensite after aging treatment is equivalent to that before aging treatment (intermediate product).

Figure 0005197113
Figure 0005197113

別途測定した素材鋼板の断面硬さは、本発明対象鋼のA鋼が135HV、比較鋼のB鋼が155HVであった。表2からわかるように、A鋼、B鋼いずれの場合も、加工誘起マルテンサイト量が10体積%、かつ断面硬さが350HV以下の部分をプレス加工部に有しており、時効処理後には350HVの部分が形成された。ただし、本発明対象鋼であるA鋼を用いた場合には、B鋼の場合より中間製品での各測定箇所の硬さが低いにもかかわらず、時効処理後には10体積%以上の加工誘起マルテンサイト相を生成させたb、c、dの箇所においてB鋼を上回る顕著な硬化が認められた。また、B鋼の場合には中間製品において400HVを超えるような硬化箇所が生じており、これはプレス金型にとって負荷が大きく、金型寿命の低下に繋がるので好ましくない。   The material hardness measured separately was 135 HV for steel A of the subject steel of the present invention and 155 HV for steel B of the comparative steel. As can be seen from Table 2, in both cases of steel A and steel B, the press-worked portion has a portion where the amount of work-induced martensite is 10% by volume and the cross-sectional hardness is 350 HV or less. A 350 HV portion was formed. However, when the steel A, which is the subject steel of the present invention, is used, the work induction of 10% by volume or more after the aging treatment is performed even though the hardness of each measurement point in the intermediate product is lower than in the case of the steel B. Remarkable hardening exceeding B steel was recognized in the locations of b, c, and d where the martensite phase was generated. Further, in the case of B steel, a hardened portion exceeding 400 HV is generated in the intermediate product, which is not preferable because it imposes a heavy load on the press mold and leads to a decrease in the mold life.

実施例1と同じA鋼、B鋼を用いて、ここでは仕上げ焼鈍後に31%の調質圧延を施した板厚1mmの素材鋼板を用意した。素材鋼板中の加工誘起マルテンサイト量は、A鋼:8体積%、B鋼:5体積%であった。
これらの素材鋼板を用いて、下記の条件で深絞りカップ(中間製品のプレス成形体)の作製を試みた。
ブランク直径:80mm、パンチ直径:40mm、パンチ肩半径:6mm、ダイス直径:42.5mm、ダイス肩半径:6mm、シワ押さえ力:1ton
Using the same A steel and B steel as in Example 1, a raw steel plate having a thickness of 1 mm prepared by 31% temper rolling after finish annealing was prepared. The amount of work-induced martensite in the material steel plate was A steel: 8% by volume and B steel: 5% by volume.
Using these steel sheets, an attempt was made to produce a deep drawn cup (intermediate product press-formed product) under the following conditions.
Blank diameter: 80 mm, punch diameter: 40 mm, punch shoulder radius: 6 mm, die diameter: 42.5 mm, die shoulder radius: 6 mm, wrinkle holding force: 1 ton

その結果、A鋼では良好な深絞りが可能であったが、B鋼では絞り抜ける前に材料の破断が生じたので絞り加工を途中で中止した。
A鋼の深絞りカップを、実施例1と同じ条件で時効処理に供した。
A鋼の中間製品のプレス成形体サンプルおよび時効処理後のプレス成形体サンプルについて、実施例1と同様の測定を行った。測定位置も実施例1と同様、図1のa、b、c、dである。結果を表3に示す。
As a result, the steel A was able to be deep-drawn satisfactorily, but the steel B was broken before it was drawn, so the drawing process was stopped halfway.
A deep drawn cup of steel A was subjected to an aging treatment under the same conditions as in Example 1.
About the press-molded body sample of the intermediate product of A steel and the press-molded body sample after the aging treatment, the same measurement as in Example 1 was performed. The measurement positions are a, b, c, and d in FIG. The results are shown in Table 3.

Figure 0005197113
Figure 0005197113

表3からわかるように、素材鋼板として調質圧延材を用いることにより、プレス成形での加工度が小さいカップ底部(aの位置)においても、時効処理後により350HV以上の硬さに硬質化させることが可能であった。中間製品においては断面硬さが350HV以下の部分をプレス加工部に有しており、また400HVを超える硬化箇所も生じていないことから、プレス金型に対する負荷が著しく増大することはなく、低コストで大量生産が可能であると考えられる。   As can be seen from Table 3, by using a temper rolled material as the raw steel plate, even at the bottom of the cup (position a) where the degree of processing in press molding is small, it is hardened to a hardness of 350 HV or higher after aging treatment. It was possible. The intermediate product has a portion with a cross-sectional hardness of 350 HV or less in the press-processed portion, and since there is no hardened portion exceeding 400 HV, the load on the press mold does not increase significantly, and the cost is low. It is thought that mass production is possible.

実施例1と同じA鋼を用いて、ここではオーステナイト単相組織を有する板厚2mmの仕上げ焼鈍材を素材鋼板として、張り出し要素を含む絞り加工を行うことにより、実施例1、2では実現できなかったプレス成形体カップの底部での顕著な硬化を試みた。絞り加工では、上記素材鋼板を下記の条件で絞り高さ25mmまで絞って中間製品のプレス成形体を得た。
ブランク直径:80mm、パンチ直径:27.5mm、パンチ肩半径:5mm、ダイス直径:32.5mm、ダイス肩半径:6mm、シワ押さえ力:0.5ton、絞り高さ:25mm
It can be realized in Examples 1 and 2 by using the same steel A as in Example 1 and using a 2 mm-thick finish annealed material having an austenite single-phase structure as a raw steel sheet and performing drawing processing including an overhanging element. Attempted significant cure at the bottom of the pressed cup that was not present. In drawing, the material steel plate was drawn to a drawing height of 25 mm under the following conditions to obtain a press-formed product of an intermediate product.
Blank diameter: 80 mm, punch diameter: 27.5 mm, punch shoulder radius: 5 mm, die diameter: 32.5 mm, die shoulder radius: 6 mm, wrinkle holding force: 0.5 ton, drawing height: 25 mm

得られた中間製品であるプレス成形体を、実施例1と同じ条件で時効処理に供した。
中間製品のプレス成形体サンプルおよび時効処理後のプレス成形体サンプルについて、カップの中心軸を含む平面で切断した。図2に切断した断面における測定位置を模式的に示す。a、b、c、dの4箇所において実施例1と同様の測定を行った。結果を表4に示す。
The obtained intermediate product, a press-molded product, was subjected to an aging treatment under the same conditions as in Example 1.
The press-molded body sample of the intermediate product and the press-molded body sample after the aging treatment were cut along a plane including the center axis of the cup. FIG. 2 schematically shows the measurement position in the cut section. The same measurement as in Example 1 was performed at four locations a, b, c, and d. The results are shown in Table 4.

Figure 0005197113
Figure 0005197113

表4からわかるように、カップの底部において顕著な硬化が実現できた。この場合でも、中間製品においては断面硬さが350HV以下の部分をプレス加工部に有しており、また400HVを超える硬化箇所も生じていないことから、プレス金型に対する負荷が著しく増大することはなく、低コストで大量生産が可能であると考えられる。   As can be seen from Table 4, significant curing was achieved at the bottom of the cup. Even in this case, the intermediate product has a portion having a cross-sectional hardness of 350 HV or less in the press-processed portion, and since there is no hardened portion exceeding 400 HV, the load on the press die is significantly increased. It is considered that mass production is possible at low cost.

表5に示す鋼を真空溶解炉で溶製し、鋳片を熱間鍛造にて厚さ40mmとし、熱間圧延にて板厚3.6mmの熱延鋼板とし、焼鈍および酸洗を行い、冷間圧延にて板厚0.8mmの冷延鋼板とし、仕上焼鈍を1150℃で行い、酸洗を行うことによって、オーステナイト単相組織を有する板厚0.8mmの素材鋼板を得た。   The steel shown in Table 5 was melted in a vacuum melting furnace, the slab was hot forged to a thickness of 40 mm, hot rolled to a hot rolled steel plate with a thickness of 3.6 mm, annealed and pickled, A cold rolled steel sheet having a thickness of 0.8 mm was formed by cold rolling, finish annealing was performed at 1150 ° C., and pickling was performed to obtain a raw steel sheet having a thickness of 0.8 mm having an austenite single phase structure.

Figure 0005197113
Figure 0005197113

これらの素材鋼板を用いて、下記の条件で深絞りカップ(中間製品のプレス成形体)を作製した。
ブランク直径:76mm、パンチ直径:40mm、パンチ肩半径:6mm、ダイス直径:42mm、ダイス肩半径:6mm、シワ押さえ力:1ton
Using these material steel plates, deep drawn cups (press-formed bodies of intermediate products) were produced under the following conditions.
Blank diameter: 76 mm, punch diameter: 40 mm, punch shoulder radius: 6 mm, die diameter: 42 mm, die shoulder radius: 6 mm, wrinkle holding force: 1 ton

得られた中間製品であるプレス成形体を、実施例1と同じ条件で時効処理に供した。
中間製品のプレス成形体サンプルおよび時効処理後のプレス成形体サンプルについて、実施例1と同様の測定を行った。測定位置は図1のaからdまでの区間とし、約2.5mm間隔で細かく調べた。
The obtained intermediate product, a press-molded product, was subjected to an aging treatment under the same conditions as in Example 1.
The same measurement as in Example 1 was performed for the press-formed sample of the intermediate product and the press-formed sample after the aging treatment. The measurement position was a section from a to d in FIG. 1 and examined in detail at intervals of about 2.5 mm.

その結果、鋼No.23、24を除き、いずれも中間製品において加工誘起マルテンサイト量が10体積%、かつ断面硬さが350HV以下の部分をプレス加工部に有しており、時効処理後には350HVの部分が形成された。ただし、比較鋼No.21はC含有量が高すぎ、No.22はN含有量が高すぎたので、これらは加工誘起マルテンサイト相の硬化が著しく、中間製品において断面硬さが400HVを超える部分が生じた。また、No.25はMd値が高すぎたことにより加工誘起マルテンサイトの生成量が多く、中間製品において断面硬さが400HVを超える部分が生じた。このように中間製品で400HVを超えるような硬化箇所が生じたものは、プレス金型にとって負荷が大きく、金型寿命の低下に繋がるので好ましくない。No.23はCu含有量が低すぎたことにより時効処理後の硬化が不十分であった。No.24はMd値が低すぎたことにより加工誘起マルテンサイト相の生成量が不足し、高強度化が達成されなかった。
表6に、参考のため図1のbとcの間でbから2.5mm位置における結果を例示する。
As a result, except for steel Nos. 23 and 24, both of the intermediate products have a portion with a work-induced martensite amount of 10% by volume and a cross-sectional hardness of 350 HV or less in the press working part. A 350 HV portion was formed. However, since the comparative steel No. 21 has too high C content and No. 22 has too high N content, these are markedly hardened in the work-induced martensite phase, and the cross-sectional hardness of the intermediate product exceeds 400 HV. Part occurred. In No. 25, since the Md value was too high, a large amount of processing-induced martensite was generated, and a portion having a cross-sectional hardness exceeding 400 HV was generated in the intermediate product. In this way, the intermediate product having a hardened portion exceeding 400 HV is not preferable because the load on the press die is large and the life of the die is shortened. No. 23 was insufficiently cured after the aging treatment because the Cu content was too low. In No. 24, since the Md value was too low, the amount of work-induced martensite phase produced was insufficient, and high strength was not achieved.
Table 6 illustrates the result at a position 2.5 mm from b between b and c in FIG. 1 for reference.

Figure 0005197113
Figure 0005197113

実施例1のプレス成形体(深絞りカップ)における測定位置を模式的に示した断面図。Sectional drawing which showed typically the measurement position in the press molding body (deep drawing cup) of Example 1. FIG. 実施例3のプレス成形体(張り出し加工の絞りカップ)における測定位置を模式的に示した断面図。Sectional drawing which showed typically the measurement position in the press-molding body of Example 3 (drawing cup for overhanging).

Claims (7)

質量%で、C:0.03%以下、Si:0.5〜2%、Mn:0.5〜2%、Ni:6〜10%、Cr:15〜18%、Cu:1〜3.5%、N:0.03%以下、残部Feおよび不可避的不純物からなり、下記(1)式のMd値が10〜30である組成の鋼板を素材とするプレス成形体であって、加工誘起マルテンサイト量が10体積%以上かつ肉厚中央部の断面硬さが350HV未満である部分をプレス加工部に有する、未だ時効処理されていない中間製品のステンレス鋼プレス成形体。
Md=551−462(C+N)−9.2Si−8.1Mn−29(Ni+Cu)−13.7Cr−18.5Mo ……(1)
By mass%, C: 0.03% or less, Si: 0.5-2%, Mn: 0.5-2%, Ni: 6-10%, Cr: 15-18%, Cu: 1-3. 5%, N: 0.03% or less, balance Fe and inevitable impurities, a press-molded body made of a steel sheet having a composition having an Md value of 10 to 30 in the following formula (1), An intermediate product stainless steel press-molded body that has a martensite content of 10% by volume or more and has a portion having a cross-sectional hardness of less than 350 HV at the center of the thickness in the press-worked portion yet to be aged.
Md = 551-462 (C + N) -9.2 Si-8.1 Mn-29 (Ni + Cu) -13.7Cr-18.5Mo (1)
さらにMo:3%以下を含有する組成を有する請求項1に記載の中間製品のステンレス鋼プレス成形体。   Furthermore, the stainless steel press-molded body of the intermediate product according to claim 1, which has a composition containing Mo: 3% or less. 質量%で、C:0.03%以下、Si:0.5〜2%、Mn:0.5〜2%、Ni:6〜10%、Cr:15〜18%、Cu:1〜3.5%、N:0.03%以下、残部Feおよび不可避的不純物からなり、下記(1)式のMd値が10〜30である組成の鋼板を素材とするプレス成形体であって、加工誘起マルテンサイト量が10体積%以上かつ肉厚中央部の断面硬さが350HV以上である部分をプレス加工部に有し、マルテンサイト中には時効析出したCuリッチ相が分散している高強度ステンレス鋼プレス成形体。
Md=551−462(C+N)−9.2Si−8.1Mn−29(Ni+Cu)−13.7Cr−18.5Mo ……(1)
By mass%, C: 0.03% or less, Si: 0.5-2%, Mn: 0.5-2%, Ni: 6-10%, Cr: 15-18%, Cu: 1-3. 5%, N: 0.03% or less, balance Fe and inevitable impurities, a press-molded body made of a steel sheet having a composition having an Md value of 10 to 30 in the following formula (1), High-strength stainless steel with a martensite content of 10% by volume or more and a section with a cross-sectional hardness of 350 HV or more at the center of the wall thickness in the press-worked part, in which aging-precipitated Cu-rich phase is dispersed. Steel press-molded body.
Md = 551-462 (C + N) -9.2 Si-8.1 Mn-29 (Ni + Cu) -13.7Cr-18.5Mo (1)
さらにMo:3%以下を含有する組成を有する請求項3に記載の高強度ステンレス鋼プレス成形体。   Furthermore, the high-strength stainless steel press-formed body according to claim 3, which has a composition containing Mo: 3% or less. 質量%で、C:0.03%以下、Si:0.5〜2%、Mn:0.5〜2%、Ni:6〜10%、Cr:15〜18%、Cu:1〜3.5%、N:0.03%以下、残部Feおよび不可避的不純物からなり、下記(1)式のMd値が10〜30である組成を有し、マトリクスがオーステナイト単相組織または「オーステナイト+10体積%未満の加工誘起マルテンサイト」の複相組織に調整された鋼板に対して、プレス成形を施すことにより、加工誘起マルテンサイト量が10体積%以上かつ肉厚中央部の断面硬さが350HV未満である部分をプレス加工部に有するプレス成形体を作る工程、
前記プレス成形体に、400〜500℃の温度域における時効温度T(K)と時効時間t(h)が下記(2)式を満たす条件で時効処理を施す工程、
を有する高強度ステンレス鋼プレス成形体の製造方法。
Md=551−462(C+N)−9.2Si−8.1Mn−29(Ni+Cu)−13.7Cr−18.5Mo ……(1)
13000≦T(logt+20)≦16500 ……(2)
By mass%, C: 0.03% or less, Si: 0.5-2%, Mn: 0.5-2%, Ni: 6-10%, Cr: 15-18%, Cu: 1-3. 5%, N: 0.03% or less, balance Fe and inevitable impurities, having a composition in which the Md value of the following formula (1) is 10 to 30, and the matrix is an austenite single phase structure or “austenite + 10 volume” By applying press forming to a steel sheet adjusted to a multiphase structure of “working-induced martensite of less than 10%”, the work-induced martensite content is 10% by volume or more and the cross-sectional hardness at the center of the wall is less than 350 HV A process of making a press-molded body having a part that is
A step of subjecting the press-molded body to an aging treatment under a condition that an aging temperature T (K) and an aging time t (h) in a temperature range of 400 to 500 ° C. satisfy the following formula (2):
A method for producing a high-strength stainless steel press-formed body having:
Md = 551-462 (C + N) -9.2 Si-8.1 Mn-29 (Ni + Cu) -13.7Cr-18.5Mo (1)
13000 ≦ T (logt + 20) ≦ 16500 (2)
質量%で、C:0.03%以下、Si:0.5〜2%、Mn:0.5〜2%、Ni:6〜10%、Cr:15〜18%、Cu:1〜3.5%、N:0.03%以下、残部Feおよび不可避的不純物からなり、下記(1)式のMd値が10〜30である組成を有し、「オーステナイト+10超え〜25体積%の加工誘起マルテンサイト」の複相組織に調整された鋼板に対して、プレス成形を施すことにより、肉厚中央部の断面硬さが350HV未満である部分をプレス加工部に有するプレス成形体を作る工程、
前記プレス成形体に、400〜500℃の温度域における時効温度T(K)と時効時間t(h)が下記(2)式を満たす条件で時効処理を施す工程、
を有する高強度ステンレス鋼プレス成形体の製造方法。
Md=551−462(C+N)−9.2Si−8.1Mn−29(Ni+Cu)−13.7Cr−18.5Mo ……(1)
13000≦T(logt+20)≦16500 ……(2)
By mass%, C: 0.03% or less, Si: 0.5-2%, Mn: 0.5-2%, Ni: 6-10%, Cr: 15-18%, Cu: 1-3. 5%, N: 0.03% or less, balance Fe and inevitable impurities, and has a composition in which the Md value of the following formula (1) is 10-30, “working induction of austenite + more than 10-25% by volume A step of producing a press-molded body having a press-processed portion having a cross-sectional hardness of less than 350 HV at the thickness center by applying press molding to a steel sheet adjusted to a multi-phase structure of “martensite”;
A step of subjecting the press-molded body to an aging treatment under a condition that an aging temperature T (K) and an aging time t (h) in a temperature range of 400 to 500 ° C. satisfy the following formula (2):
A method for producing a high-strength stainless steel press-formed body having:
Md = 551-462 (C + N) -9.2 Si-8.1 Mn-29 (Ni + Cu) -13.7Cr-18.5Mo (1)
13000 ≦ T (logt + 20) ≦ 16500 (2)
前記鋼板が、さらにMo:3%以下を含有するものである請求項5または6に記載の高強度ステンレス鋼プレス成形体の製造方法。   The method for producing a high-strength stainless steel press-formed body according to claim 5 or 6, wherein the steel sheet further contains Mo: 3% or less.
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