JP5164960B2 - Method for producing acidic liquid food in a container - Google Patents
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- JP5164960B2 JP5164960B2 JP2009259438A JP2009259438A JP5164960B2 JP 5164960 B2 JP5164960 B2 JP 5164960B2 JP 2009259438 A JP2009259438 A JP 2009259438A JP 2009259438 A JP2009259438 A JP 2009259438A JP 5164960 B2 JP5164960 B2 JP 5164960B2
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- 235000021056 liquid food Nutrition 0.000 title claims description 56
- 230000002378 acidificating effect Effects 0.000 title claims description 50
- 238000004519 manufacturing process Methods 0.000 title claims description 23
- 235000003434 Sesamum indicum Nutrition 0.000 claims description 96
- 241000207961 Sesamum Species 0.000 claims description 92
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 89
- 239000000284 extract Substances 0.000 claims description 64
- 235000006886 Zingiber officinale Nutrition 0.000 claims description 62
- 235000008397 ginger Nutrition 0.000 claims description 62
- 241000234314 Zingiber Species 0.000 claims description 56
- 239000003205 fragrance Substances 0.000 claims description 51
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 claims description 43
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 claims description 43
- 229940043350 citral Drugs 0.000 claims description 41
- 235000020971 citrus fruits Nutrition 0.000 claims description 40
- 241000207199 Citrus Species 0.000 claims description 38
- 239000000463 material Substances 0.000 claims description 28
- 238000002156 mixing Methods 0.000 claims description 28
- 239000003513 alkali Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 3
- 239000000047 product Substances 0.000 description 46
- 239000000796 flavoring agent Substances 0.000 description 27
- 235000019634 flavors Nutrition 0.000 description 27
- 235000021419 vinegar Nutrition 0.000 description 23
- 239000000052 vinegar Substances 0.000 description 22
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 21
- 235000019645 odor Nutrition 0.000 description 19
- 230000000694 effects Effects 0.000 description 14
- 239000002994 raw material Substances 0.000 description 14
- 241000951471 Citrus junos Species 0.000 description 13
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- -1 polyethylene terephthalate Polymers 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
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- 235000005979 Citrus limon Nutrition 0.000 description 7
- 244000131522 Citrus pyriformis Species 0.000 description 7
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- 150000007524 organic acids Chemical class 0.000 description 7
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- 239000004278 EU approved seasoning Substances 0.000 description 6
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 6
- 244000273928 Zingiber officinale Species 0.000 description 6
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- 238000011156 evaluation Methods 0.000 description 5
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- 229940082509 xanthan gum Drugs 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
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- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
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- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 description 3
- 229940093915 gynecological organic acid Drugs 0.000 description 3
- 230000001771 impaired effect Effects 0.000 description 3
- 235000013923 monosodium glutamate Nutrition 0.000 description 3
- 235000005985 organic acids Nutrition 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 229940073490 sodium glutamate Drugs 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 240000000560 Citrus x paradisi Species 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
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- 240000008415 Lactuca sativa Species 0.000 description 2
- 244000070406 Malus silvestris Species 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 244000269722 Thea sinensis Species 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
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- 239000004615 ingredient Substances 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 235000015205 orange juice Nutrition 0.000 description 2
- HFPZCAJZSCWRBC-UHFFFAOYSA-N p-cymene Chemical compound CC(C)C1=CC=C(C)C=C1 HFPZCAJZSCWRBC-UHFFFAOYSA-N 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 235000012045 salad Nutrition 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
- 235000014347 soups Nutrition 0.000 description 2
- 238000000967 suction filtration Methods 0.000 description 2
- 235000018553 tannin Nutrition 0.000 description 2
- 229920001864 tannin Polymers 0.000 description 2
- 239000001648 tannin Substances 0.000 description 2
- 238000003809 water extraction Methods 0.000 description 2
- 235000013618 yogurt Nutrition 0.000 description 2
- ASWBNKHCZGQVJV-UHFFFAOYSA-N (3-hexadecanoyloxy-2-hydroxypropyl) 2-(trimethylazaniumyl)ethyl phosphate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(O)COP([O-])(=O)OCC[N+](C)(C)C ASWBNKHCZGQVJV-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 240000004784 Cymbopogon citratus Species 0.000 description 1
- 235000017897 Cymbopogon citratus Nutrition 0.000 description 1
- 235000002767 Daucus carota Nutrition 0.000 description 1
- 244000000626 Daucus carota Species 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- AANLCWYVVNBGEE-IDIVVRGQSA-L Disodium inosinate Chemical compound [Na+].[Na+].O[C@@H]1[C@H](O)[C@@H](COP([O-])([O-])=O)O[C@H]1N1C(NC=NC2=O)=C2N=C1 AANLCWYVVNBGEE-IDIVVRGQSA-L 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
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- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 240000006909 Tilia x europaea Species 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- 239000005862 Whey Substances 0.000 description 1
- 102000007544 Whey Proteins Human genes 0.000 description 1
- 108010046377 Whey Proteins Proteins 0.000 description 1
- 241000234299 Zingiberaceae Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 230000036528 appetite Effects 0.000 description 1
- 235000019789 appetite Nutrition 0.000 description 1
- 235000021016 apples Nutrition 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 235000007215 black sesame Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 235000014171 carbonated beverage Nutrition 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
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- 230000001747 exhibiting effect Effects 0.000 description 1
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- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
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- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 1
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- 229910052751 metal Inorganic materials 0.000 description 1
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- 235000013336 milk Nutrition 0.000 description 1
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- 239000011259 mixed solution Substances 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 125000004365 octenyl group Chemical group C(=CCCCCCC)* 0.000 description 1
- 239000007968 orange flavor Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
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- 239000011709 vitamin E Substances 0.000 description 1
Landscapes
- Seasonings (AREA)
- Non-Alcoholic Beverages (AREA)
Description
本発明は、柑橘類果皮、ショウガ、又はシトラール含有香料から選ばれる一種又は二種以上が配合された容器入り酸性液状食品の製造方法であって、前記柑橘類果皮、ショウガ、あるいは、シトラール含有香料の香りの変質が防止され、しかも、食味や色調が良好な容器入り酸性液状食品の製造方法に関する。 The present invention is a method for producing an acidic liquid food in a container containing one or more selected from citrus peel, ginger or citral-containing fragrance, wherein the citrus peel, ginger or citral-containing fragrance The present invention relates to a method for producing an acidic liquid food in a container that is prevented from being deteriorated and that has good taste and color.
柑橘類果皮やショウガのさわやかな香りは、食事の美味しさを引き立て、食欲を刺激するため、飲料や液状調味料等の香り付けに利用されている。このさわやかな香りはこれら柑橘類果皮やショウガに含まれるシトラール(3、7−ジメチル−2,6−オクタジエナール)によるものであり、シトラールを有効成分として含む柑橘系の香料等も市販されている。 The refreshing scent of citrus peel and ginger enhances the deliciousness of the meal and stimulates appetite, so it is used for scenting beverages and liquid seasonings. This refreshing fragrance is due to citral (3,7-dimethyl-2,6-octadienal) contained in these citrus peels and ginger, and citrus fragrances containing citral as an active ingredient are also commercially available. .
しかしながら、上述したショウガ、柑橘類果皮、あるいは、柑橘系香料を飲料や調味料等の酸性の液状食品に配合した容器入り製品は、保存中にさわやかな香りが変質し刺激臭が発生する場合があった。特に、近年は、内容物が視認できるガラスやPET樹脂製等の透明容器入り製品の販売が増加しており、当該透明容器入り製品は店頭で長時間光を照射されるため、前記香りの変質が生じ易く問題となっていた。 However, the above-mentioned products containing containers containing ginger, citrus peel, or citrus flavors in acidic liquid foods such as beverages and seasonings may change the refreshing aroma during storage and generate irritating odors. It was. In particular, in recent years, sales of products containing transparent containers such as glass and PET resin, whose contents can be visually recognized, are increasing, and the products containing these transparent containers are irradiated with light for a long time at a store, so that the fragrance is altered. This was a problem.
前記香りの変質に関し、従来、シトラールが酸性水溶液中で熱や光により劣化し、異臭の原因となるp−サイメン等に変化することが知られている(非特許文献1)。 Regarding the alteration of the scent, it has been known that citral is deteriorated by heat or light in an acidic aqueous solution and is changed to p-cymene or the like that causes a strange odor (Non-Patent Document 1).
このようなシトラールの劣化を防止するための技術としては、例えば、特開2003−96486号(特許文献1)には、茶ポリフェノールを添加することが、また、特開2003−79335号(特許文献2)には、カキノキ科カキノキ属植物の果実又は未熟果由来のタンニン又は該タンニン精製物を添加することが記載されているが、これらの添加材はいずれも多価フェノール特有の呈味により添加した食品の風味を損なう場合があった。また、特開2005−171116号公報(特許文献3)には、テアフラビン類を添加することが記載されているが、当該添加材は色素であるため、添加した食品の色調を損なう場合があった。したがって、製品の風味や色調を損ない難い添加材により、上述した香りの変質が防止された容器入り製品を提供することが望まれる。 As a technique for preventing such deterioration of citral, for example, Japanese Patent Application Laid-Open No. 2003-96486 (Patent Document 1) may include addition of tea polyphenol, and Japanese Patent Application Laid-Open No. 2003-79335 (Patent Document). 2) describes the addition of tannins derived from the fruits of the genus Oysteraceae, or immature fruits, or purified tannins, all of which are added due to the unique taste of polyhydric phenols. In some cases, the flavor of the finished food was impaired. Japanese Patent Application Laid-Open No. 2005-171116 (Patent Document 3) describes that theaflavins are added. However, since the additive is a pigment, the color tone of the added food may be impaired. . Accordingly, it is desired to provide a containerized product in which the above-described fragrance alteration is prevented by an additive that does not easily impair the flavor and color of the product.
本発明の目的は、柑橘類果皮、ショウガ、又はシトラール含有香料を含む容器入り酸性液状食品の製造方法であって、前記柑橘類果皮、ショウガ、あるいは、シトラール含有香料の香りの変質が防止され、しかも、食味や色調が良好な容器入り酸性液状食品の製造方法を提供するものである。 An object of the present invention is a method for producing an acidic liquid food containing a citrus peel, ginger, or citral-containing fragrance, wherein the citrus peel, ginger, or citral-containing fragrance is prevented from being altered, and The present invention provides a method for producing an acidic liquid food in a container having a good taste and color.
本発明者等は、柑橘類果皮、ショウガ、あるいは、シトラール含有香料を含む容器入り酸性液状食品に、ゴマの熱水抽出液と、塩基性化合物等のアルカリ材とを配合するならば、意外にも前記柑橘類果皮、ショウガ、あるいは、シトラール含有香料に由来するさわやかな香りの変質が防止された容器入り酸性液状食品が得られることを見出し、遂に本発明を完成するに至った。 If the present inventors mix an acidic liquid food in a container containing citrus peel, ginger or citral-containing fragrance with a hot water extract of sesame and an alkaline material such as a basic compound, it is surprising. The inventors have found that an acidic liquid food in a container in which the refreshing fragrance derived from the citrus peel, ginger or citral-containing fragrance is prevented can be obtained, and finally the present invention has been completed.
すなわち、本発明は、
(1)、柑橘類果皮、ショウガ、又はシトラール含有香料から選ばれる一種又は二種以上と、
ゴマの熱水抽出液及びアルカリ材が配合されている容器入り酸性液状食品の製造方法であって、
ゴマを60〜100℃の熱水と接触させてゴマの熱水抽出液を製した後、
該ゴマの熱水抽出液と、柑橘類果皮、ショウガ、又はシトラール含有香料から選ばれる一種又は二種以上とを混合することを特徴とする容器入り酸性液状食品の製造方法、
(2)、品温0〜50℃に冷却したゴマの熱水抽出液と、柑橘類果皮、ショウガ、又はシトラール含有香料から選ばれる一種又は二種以上とを混合する(1)記載の容器入り酸性液状食品の製造方法、
である。
That is, the present invention
(1) one or more selected from citrus peel, ginger, or citral-containing fragrance, and
A method for producing an acidic liquid food in a container containing a hot water extract of sesame and an alkali material ,
After making sesame hot water extract by contacting sesame with hot water at 60-100 ° C,
A method for producing an acidic liquid food in a container, characterized by mixing the hot water extract of sesame and one or more selected from citrus peel, ginger, or citral-containing fragrance,
(2), goods and temperature 0 to 50 ° C. in a hot water extract of chilled sesame, citrus peel, ginger, or mixing the one or more selected from citral-containing fragrances (1) containers acidic described Liquid food manufacturing method,
It is.
本発明によれば、柑橘類果皮、ショウガ、又はシトラール含有香料から選ばれる一種又は二種以上が配合された容器入り酸性液状食品であって、前記柑橘類果皮、ショウガ、あるいは、シトラール含有香料の香りの変質が防止され、しかも、食味や色調が良好な容器入り酸性液状食品及びその製造方法を提供できる。特に、本発明によれば、光により前記香りの変質が生じ易い透明容器入りの製品において、前記香りの変質が防止された製品を提供できる。したがって、柑橘類果皮、ショウガ、あるいはシトラール含有香料が配合された容器入り酸性液状食品、特に、透明容器入りの製品について、更なる需要の拡大が期待される。 According to the present invention, an acidic liquid food in a container containing one or more selected from citrus peel, ginger, or citral-containing fragrance, the citrus peel, ginger, or citral-containing fragrance It is possible to provide an acidic liquid food in a container that is prevented from being altered and has a good taste and color and a method for producing the same. In particular, according to the present invention, it is possible to provide a product in which the fragrance is prevented from being deteriorated in a product in a transparent container in which the fragrance is easily deteriorated by light. Therefore, further expansion of demand is expected for acidic liquid foods in containers containing citrus peel, ginger, or citral-containing fragrances, particularly products in transparent containers.
以下、本発明の容器入り酸性液状食品及びその製造方法を詳述する。なお、本発明において「%」は「質量%」を、「部」は「質量部」を意味する。 Hereinafter, the acidic liquid food in a container of the present invention and the production method thereof will be described in detail. In the present invention, “%” means “mass%” and “part” means “part by mass”.
本発明の酸性液状食品とは、pHが4.6以下の液状食品である。液状食品の具体例としては、ドレッシング、たれ等の液状調味料、スープ、シチュー等のスープ類、果汁飲料、酢飲料、炭酸飲料、カクテル、乳清飲料等の飲料、ヨーグルト等が挙げられる。 The acidic liquid food of the present invention is a liquid food having a pH of 4.6 or less. Specific examples of the liquid food include liquid seasonings such as dressing and sauce, soups such as soup and stew, beverages such as fruit juice beverages, vinegar beverages, carbonated beverages, cocktails and whey beverages, yogurt and the like.
本発明において、容器入り酸性液状食品とは、前記酸性液状食品が容器に充填されたものである。容器としては、特に制限は無く、一般的に食品の保存に利用される種々の容器を使用することができ、例えば、ガラス、金属、樹脂、あるいは紙等からなる容器が挙げられる。なお、前記容器の中でも、ガラス、ポリエチレンテレフタレート(PET)、ポリプロピレン等からなる透明の成形容器や、ポリエチレン等からなる透明パウチ等の透明容器を用いた場合、当該透明容器入りの製品は店頭や流通中に長時間光を照射されるため、柑橘類果皮、ショウガ、あるいは、シトラール含有香料のさわやかな香りが変質する問題が生じやすい。しかしながら、本発明によれば、前記香りの変質が防止されることから、本発明は、このような透明容器入り酸性液状食品において特に好適に実施できる。 In the present invention, the acidic liquid food in a container is a container in which the acidic liquid food is filled. There is no restriction | limiting in particular as a container, The various container generally utilized for preservation | save of foodstuffs can be used, For example, the container which consists of glass, a metal, resin, paper etc. is mentioned. Of these containers, when a transparent molded container made of glass, polyethylene terephthalate (PET), polypropylene, or the like, or a transparent container such as a transparent pouch made of polyethylene or the like, the product in the transparent container is sold in stores or distributed. Since it is irradiated with light for a long time, there is a problem that the refreshing fragrance of the citrus peel, ginger, or citral-containing fragrance is altered. However, according to the present invention, since the fragrance is prevented from being altered, the present invention can be particularly preferably implemented in such an acidic liquid food in a transparent container.
本発明の容器入り酸性液状食品に用いる柑橘類果皮とは、柑橘類果実の果皮であり、例えば、ユズ、オレンジ、レモン、グレープフルーツ、ライム、スダチ、カボス等の果皮が挙げられる。これら柑橘類果皮を食品に添加する際の形態は、特に制限は無いが、液状食品に柑橘類果皮の風味を付与しやすい点から、大きさが好ましくは10mm以下、より好ましくは5mm以下の細片状物を用いることが好ましい。細片状物としては、例えば、截断、粉砕、すりおろし等の処理により得られたものが挙げられる。 The citrus peel used in the acidic liquid food in a container of the present invention is a citrus fruit peel, and examples thereof include peels such as yuzu, orange, lemon, grapefruit, lime, sudachi, kabosu. The form when adding these citrus peels to food is not particularly limited, but the size is preferably 10 mm or less, more preferably 5 mm or less from the viewpoint of easily imparting the flavor of citrus peel to liquid foods. It is preferable to use a product. Examples of the strip-shaped material include those obtained by processing such as cutting, pulverization, and grated.
柑橘類果皮の配合量としては、柑橘類果皮の香りを適度に食品に付与する点から、製品に対して、生換算で、好ましくは0.5〜10%、より好ましくは1〜5%である。 The blending amount of the citrus peel is preferably 0.5 to 10%, more preferably 1 to 5%, in terms of raw material, in terms of imparting the scent of the citrus peel appropriately to the food.
本発明で用いるショウガとは、一般的に食用に供されるショウガ科の多年草の根茎である。ショウガを食品に添加する際の形態は、特に制限は無いが、液状食品に柑橘類果皮の風味を付与しやすい点から、大きさが好ましくは10mm以下、より好ましくは5mm以下の細片状物を用いることが好ましい。細片状物としては、例えば、截断、粉砕、すりおろし等の処理により得られたものが挙げられる。 The ginger used in the present invention is a perennial rhizome of the ginger family that is generally used for food. The form when ginger is added to food is not particularly limited, but from the viewpoint of easily imparting the flavor of citrus peel to liquid food, the size is preferably 10 mm or less, more preferably 5 mm or less. It is preferable to use it. Examples of the strip-shaped material include those obtained by processing such as cutting, pulverization, and grated.
ショウガの配合量としては、ショウガの香りを程度に食品に付与する点から、製品に対して、生換算で、好ましくは0.5〜20%、より好ましくは1〜10%である。 The amount of ginger is preferably 0.5 to 20%, more preferably 1 to 10%, in terms of raw product, from the viewpoint of imparting the ginger aroma to food to the extent.
また、本発明で用いるシトラール含有香料とは、シトラール(3、7−ジメチル−2,6−オクタジエナール)を有効成分として含む香料であれば特に制限は無く、例えば、ユズフレーバー、オレンジフレーバー、レモンフレーバー、グレープフルーツフレーバー、ライムフレーバー、スダチフレーバー、レモングラスフレーバー、ショウガフレーバー等が挙げられる。なお、前記シトラールとしては、天然物由来、または、合成品のいずれであってもよい。 In addition, the citral-containing fragrance used in the present invention is not particularly limited as long as it is a fragrance containing citral (3,7-dimethyl-2,6-octadienal) as an active ingredient, for example, yuzu flavor, orange flavor, Lemon flavor, grapefruit flavor, lime flavor, sudachi flavor, lemongrass flavor, ginger flavor and the like. In addition, as said citral, any of a natural product origin or a synthetic product may be sufficient.
本発明の酸性液状食品は、上述した柑橘類果皮、ショウガ、又はシトラール含有香料から選ばれる一種又は二種以上が配合された容器入り酸性液状食品において、ゴマの熱水抽出液及びアルカリ材が配合されていることを特徴とする。柑橘類果皮、ショウガ、あるいは、シトラール含有香料が配合された酸性液状食品においては、保存中に、ショウガ、柑橘類果皮、あるいは、シトラール含有香料の香りが変質し刺激臭が発生する場合があるが、本発明においては、このようにゴマの熱水抽出液及びアルカリ材が配合されていることにより、前記香りの変質が防止される。しかも、ゴマの熱水抽出液及びアルカリ材はいずれも強い色調や風味が無いことから、液状食品に添加しても製品の風味や色調を損なわずに香りの変質が防止される。 The acidic liquid food of the present invention is a containerized acidic liquid food containing one or more selected from the above-mentioned citrus peel, ginger, or citral-containing fragrance, in which a hot water extract of sesame and an alkaline material are blended. It is characterized by. In acidic liquid foods containing citrus peel, ginger, or citral-containing fragrance, the scent of ginger, citrus peel or citral-containing fragrance may change during storage, resulting in an irritating odor. In the invention, the scent alteration is prevented by blending the hot water extract of sesame and the alkali material in this way. Moreover, since neither the hot water extract of sesame nor the alkaline material has a strong color tone or flavor, even if added to a liquid food, the scent is prevented from being altered without impairing the flavor and color tone of the product.
ここで、ゴマの熱水抽出液とは、ゴマを熱水と接触させてゴマ成分を抽出したものである。熱水抽出に使用するゴマとしては、その種類や産地は限定されるものではく、通常の白ゴマ、金ゴマ、黒ゴマ、茶ゴマ等を用いることができ、これらのゴマは焙煎処理されたものであってもよい。また、これらゴマの形態としては、特に制限はないが、ゴマ粉砕物を用いると熱水抽出液中で成分が抽出され易く好ましい。このようなゴマ粉砕物としては、ゴマをマスコロイダー、コミットロール、サイレントカッター等の粉砕処理装置等により粉砕処理して得ることができる。また、切りゴマ、すりゴマ等が市販されているのでこれらを用いてもよい。 Here, the sesame hot water extract is obtained by extracting sesame components by bringing sesame into contact with hot water. Sesame used for hot water extraction is not limited in its type and production area, and ordinary white sesame, gold sesame, black sesame, tea sesame, etc. can be used. These sesame are roasted. It may be. Moreover, there is no restriction | limiting in particular as a form of these sesame, but when a sesame ground material is used, a component will be easily extracted in a hot-water extract, and it is preferable. Such a sesame pulverized product can be obtained by pulverizing sesame with a pulverizing apparatus such as a mascolloider, a commit roll, or a silent cutter. In addition, since cut sesame and ground sesame are commercially available, these may be used.
抽出に用いる熱水としては、水系媒体であればよく、例えば、清水の他に液状食品、例えば、液状調味料、飲料等が挙げられるが、ゴマの有効成分が抽出されやすいことから、水分が90%以上のものが好ましい。また、前記熱水としては、より香りの変質防止効果が高いゴマ熱水抽出液が得られ易いことから、有機酸によりpH4.6以下に調整した熱水を用いることが好ましい。有機酸としては、食用に供することができる有機酸であれば特に制限は無く、例えば、乳酸、酢酸、酪酸、コハク酸、リンゴ酸、クエン酸、酒石酸等およびこれらの混合有機酸等が挙げられる。これら有機酸としては、有機酸を含む原料、例えば、酢酸を含む合成酢、米酢、リンゴ酢、果実酢、ワインビネガー等の醸造酢を使用してもよい。熱水中の有機酸の含有量は、pH4.6以下に調整する程度であればよく、熱水に対して好ましくは0.1〜20%、より好ましくは0.5〜10%である。 The hot water used for extraction may be an aqueous medium, and examples include liquid foods such as liquid seasonings, beverages, etc. in addition to fresh water. 90% or more is preferable. In addition, as the hot water, it is preferable to use hot water adjusted to pH 4.6 or less with an organic acid because a sesame hot water extract having a higher effect of preventing fragrance alteration can be easily obtained. The organic acid is not particularly limited as long as it is an edible organic acid, and examples thereof include lactic acid, acetic acid, butyric acid, succinic acid, malic acid, citric acid, tartaric acid, and mixed organic acids thereof. . As these organic acids, raw materials containing organic acids, for example, vinegars such as synthetic vinegar containing acetic acid, rice vinegar, apple vinegar, fruit vinegar and wine vinegar may be used. Content of the organic acid in hot water should just be a grade adjusted to pH 4.6 or less, Preferably it is 0.1-20% with respect to hot water, More preferably, it is 0.5-10%.
前記熱水の温度は、ゴマ有効成分が抽出されやすい点から、好ましくは60℃以上、より好ましくは65℃以上である。抽出温度の上限としては特に制限は無いがあまり温度が高すぎてもそれにともなって抽出効率が上昇するわけではなく食品工業的に製造し難くなることから、好ましくは100℃以下、より好ましくは98℃以下である。 The temperature of the hot water is preferably 60 ° C. or higher, more preferably 65 ° C. or higher, from the viewpoint that the sesame active ingredient is easily extracted. The upper limit of the extraction temperature is not particularly limited, but if the temperature is too high, the extraction efficiency does not increase and it is difficult to produce in the food industry. Therefore, it is preferably 100 ° C. or less, more preferably 98 It is below ℃.
ゴマの熱水抽出液は、ゴマを熱水と接触させその成分を熱水中に抽出することにより得ることができる。具体的には、例えば、ゴマを熱水に浸漬してその成分を熱水中に抽出すればよく、この際、より有効成分が抽出されやすいようにゴマを熱水中で撹拌しながら浸漬することがより好ましい。熱水抽出を行う際のゴマと熱水の割合は、ゴマ1部に対して、熱水が好ましくは2〜100部、より好ましくは2〜50部である。熱水が前記範囲よりも少ないと抽出がされ難く、一方、熱水が前記範囲よりも多くても抽出成分の収率は増加せず得られた熱水抽出液の濃度が低下するので製品に配合した際に香りの変質防止効果が得られ難くなる。また、ゴマと熱水を接触させる時間は、ゴマ有効成分を充分に抽出する点から、好ましくは3分以上、より好ましくは10分以上である。抽出時間はあまり長すぎても特に問題はないが、抽出時間が長くすればするほど抽出成分の収率が増加し続けるわけではないことから、製造コスト点から好ましくは24時間以下、より好ましくは6時間以下である。 The hot water extract of sesame can be obtained by bringing sesame into contact with hot water and extracting its components into hot water. Specifically, for example, sesame is immersed in hot water and its components are extracted into hot water. At this time, sesame is immersed in hot water while being stirred so that the active ingredient can be easily extracted. It is more preferable. The ratio of sesame to hot water when performing hot water extraction is preferably 2 to 100 parts, more preferably 2 to 50 parts, with respect to 1 part of sesame. If the amount of hot water is less than the above range, extraction is difficult. On the other hand, if the amount of hot water is more than the above range, the yield of the extracted component does not increase and the concentration of the obtained hot water extract decreases. When blended, it becomes difficult to obtain the effect of preventing fragrance alteration. Moreover, the time which makes sesame and hot water contact is preferably 3 minutes or more, more preferably 10 minutes or more from the viewpoint of sufficiently extracting the sesame active ingredient. The extraction time is not particularly problematic if it is too long. However, the longer the extraction time, the more the yield of the extracted component does not continue to increase. Therefore, it is preferably 24 hours or less, more preferably from the viewpoint of production cost. 6 hours or less.
本発明においては、前記ゴマの熱水抽出液、つまり、ゴマの成分を熱水に溶出して使用することが肝要であり、ゴマの水抽出液を使用した場合は、保存中にショウガ、柑橘類果皮又はシトラール含有香料の香りが変質を防止する効果が充分に得られ難い。 In the present invention, it is important to use the sesame hot water extract, that is, the sesame component eluted in the hot water, and when the sesame water extract is used, ginger and citrus fruits during storage. The effect of preventing alteration of the scent of pericarp or citral-containing fragrance is difficult to obtain.
本発明において、前記ゴマの熱水抽出液を配合する際には、ゴマの熱水抽出液を製した後、残渣であるゴマを取り除いてから熱水抽出液を酸性液状食品に配合してもよく、あるいは、ゴマの熱水抽出液を製し、当該ゴマ残渣を含む熱水抽出液をゴマ残渣を含んだまま配合してもよい。 In the present invention, when blending the hot water extract of sesame, after making the hot water extract of sesame, the hot water extract may be blended into the acidic liquid food after removing the sesame residue. Alternatively, a hot water extract of sesame may be produced, and the hot water extract containing the sesame residue may be blended with the sesame residue.
酸性液状食品に配合するゴマの熱水抽出液の量は、あまり少なすぎてもショウガ、柑橘類果皮又はシトラール含有香料の香りの変質防止効果が得られ難いことから、酸性液状食品に対して、好ましくは5%以上、より好ましくは10%以上である。一方、ゴマの熱水抽出液の配合量の上限としては、その他の配合原料等も配合することを考慮すると、好ましくは90%以下、より好ましくは50%以下である。 The amount of the hot water extract of sesame added to the acidic liquid food is preferable for the acidic liquid food because it is difficult to obtain the effect of preventing the fragrance of the ginger, citrus peel or citral-containing fragrance even if it is too small. Is 5% or more, more preferably 10% or more. On the other hand, the upper limit of the blending amount of the sesame hot water extract is preferably 90% or less, more preferably 50% or less in consideration of blending other blending raw materials and the like.
一方、本発明で用いる前記アルカリ材とは、清水に溶解した状態でアルカリ性を呈する添加材である。前記アルカリ材としては、食用に供することができるアルカリ材であれば特に制限は無く、具体的には、例えば、塩基性化合物が挙げられる。塩基性化合物としては、クエン酸塩、酢酸塩、炭酸ナトリウム等の有機酸塩、グルタミン酸ナトリウム、イノシン酸ナトリウム等のアミノ酸塩、水酸化カリウム等が挙げられる。 On the other hand, the alkali material used in the present invention is an additive exhibiting alkalinity when dissolved in fresh water. The alkali material is not particularly limited as long as it is an edible alkali material, and specific examples include basic compounds. Examples of the basic compound include organic acid salts such as citrate, acetate and sodium carbonate, amino acid salts such as sodium glutamate and sodium inosinate, potassium hydroxide and the like.
酸性液状食品に配合する前記アルカリ材の配合量は、あまり少なすぎてもショウガ、柑橘類果皮又はシトラール含有香料の香りの変質防止効果が得られ難く、一方、あまり多すぎてもそれにともなって香りの変質防止効果が高まるわけではなく、酸性液状食品のpHが上昇して風味に影響がでる場合があることから、酸性液状食品に対して、好ましくは0.1〜2%、より好ましくは0.5〜5%である。 If the amount of the alkaline material to be blended in the acidic liquid food is too small, it is difficult to obtain the effect of preventing the fragrance of the ginger, citrus peel or citral-containing fragrance from being changed. The alteration preventing effect does not increase, and the pH of the acidic liquid food may increase to affect the flavor. Therefore, the acid liquid food is preferably 0.1 to 2%, more preferably 0.8%. 5 to 5%.
なお、本発明の容器入り酸性液状食品には、上述した柑橘類果皮、ショウガ、シトラール含有香料、ゴマ熱水抽出液及びアルカリ材の他に、本発明の効果を損なわない範囲で酸性液状食品に通常用いられている各種原料を適宜選択し配合することができる。このような原料としては、例えば、ニンジン、リンゴ等の野菜・果実類、牛乳、生クリームヨーグルト等の乳製品、食酢、食塩、砂糖、動植物のエキス類などの各種調味料、焼酎、リキュール等の酒類、澱粉分解物、デキストリン、デキストリンアルコール等の糖類、澱粉、キサンタンガム、ローカストビーンガム等の増粘材、レシチン、リゾレシチン、グリセリン脂肪酸エステル、オクテニルコハク酸化澱粉等の乳化材、アスコルビン酸、ビタミンE等の酸化防止剤等が挙げられる。 The acidic liquid food in a container of the present invention is usually an acidic liquid food as long as the effects of the present invention are not impaired in addition to the citrus peel, ginger, citral-containing fragrance, sesame hot water extract and alkaline material. Various raw materials used can be appropriately selected and blended. Examples of such raw materials include vegetables and fruits such as carrots and apples, dairy products such as milk and fresh cream yogurt, various seasonings such as vinegar, salt, sugar and animal and plant extracts, shochu, liqueur and the like. Liquors, starch degradation products, sugars such as dextrin and dextrin alcohol, thickeners such as starch, xanthan gum and locust bean gum, emulsifiers such as lecithin, lysolecithin, glycerin fatty acid ester, octenyl succinylated starch, ascorbic acid, vitamin E, etc. An antioxidant etc. are mentioned.
次に、本発明の容器入り酸性液状食品の製造方法を説明する。 Next, the manufacturing method of the acidic liquid food containing a container according to the present invention will be described.
本発明の容器入り酸性液状食品は、上述したゴマの熱水抽出液及びアルカリ材を配合する他は、柑橘類果皮、ショウガ、又はシトラール含有香料から選ばれる一種又は二種以上を配合する従来の一般的な容器入り酸性液状食品の製造方法に準じ、配合原料を略均一に混合することにより製造することができる。 The acidic liquid food in a container according to the present invention contains one or more selected from citrus peel, ginger, or citral-containing fragrance, in addition to the above-mentioned hot water extract of sesame and an alkali material. According to a typical method for producing an acidic liquid food in a container, it can be produced by mixing the blended raw materials substantially uniformly.
ここで、配合原料の混合順序に関し、本発明においては、上述したゴマの熱水抽出液を得る際の熱水に柑橘類果皮、ショウガ、又はシトラール含有香料を配合してもよいが、これら柑橘類果皮、ショウガ、又はシトラール含有香料は、できるだけ製造工程時に受ける熱が少ないほうが本発明の変質防止効果がより得られやすい。したがって、本発明においては、ゴマを熱水と接触させてゴマの熱水抽出液を製した後、好ましくは品温0〜50℃、より好ましくは品温0〜40℃に冷却したゴマの熱水抽出液と、柑橘類果皮、ショウガ、又はシトラール含有香料から選ばれる一種又は二種以上とを撹拌タンク等で混合して製造することが好ましく、また、この混合時の雰囲気温度は0〜40℃とすることが好ましい。 Here, regarding the mixing order of the blended raw materials, in the present invention, the citrus peel, ginger, or citral-containing fragrance may be blended in the hot water when obtaining the above-described hot water extract of sesame, but these citrus peels As for the perfume containing ginger or citral, the alteration prevention effect of the present invention is more easily obtained when the heat received during the production process is as small as possible. Therefore, in the present invention, after making sesame hot water extract by bringing sesame into contact with hot water, the heat of sesame is preferably cooled to 0 to 50 ° C, more preferably 0 to 40 ° C. It is preferable to produce a mixture of a water extract and one or more selected from citrus peel, ginger or citral-containing fragrance in a stirring tank or the like, and the ambient temperature during mixing is 0 to 40 ° C. It is preferable that
柑橘類果皮、ショウガ、又はシトラール含有香料と、ゴマの熱水抽出液以外の原料であるアルカリ材や、その他、必要に応じて配合する果汁、食酢、調味料等の原料については、その混合順序によりに特に風味等に影響は無いことから、製造工程中の任意の段階で、これら配合原料を適宜加え、撹拌装置等で全体が略均一になるように混合すればよい。 For citrus peel, ginger, or citral-containing fragrance and raw materials such as alkali materials that are ingredients other than the hot water extract of sesame, and other ingredients such as fruit juice, vinegar, and seasonings, depending on the order of mixing Since there is no particular influence on the flavor and the like, these blended raw materials may be appropriately added at any stage in the production process and mixed so that the whole becomes substantially uniform with a stirrer or the like.
以上のようにして配合原料を混合して得られた酸性液状食品は、上述した透明容器等の容器に充填することにより容器入り製品とすることができる。また、必要により容器に充填する前、あるいは、充填後に殺菌処理を施してもよい。 The acidic liquid food obtained by mixing the blended raw materials as described above can be made into a product in a container by filling the container such as the transparent container described above. If necessary, sterilization may be performed before filling the container or after filling.
次に、本発明を実施例、比較例及び試験例に基づき、更に説明する。 Next, this invention is further demonstrated based on an Example, a comparative example, and a test example.
[試験例1]
ゴマ抽出液の種類が、ショウガが配合された酸性液状食品の香りの変質に与える影響を調べるために以下の試験を行った。
[Test Example 1]
In order to examine the effect of the type of sesame extract on the alteration of the scent of an acidic liquid food containing ginger, the following test was conducted.
(1)ゴマ抽出液の調製
(1−1)ゴマの熱水抽出液の調製
清水100部にすりゴマ10部を加えた混合液1000gをステンレス製鍋に入れ、へらでゆるやかに撹拌しながら電磁調理器で加熱し90℃で1時間保持した後、品温20℃に冷却し、吸引ろ過(桐山ロート、ろ紙:No.5A)により残渣のすりゴマを取り除くことにより、ゴマの熱水抽出液を調製した。
(1) Preparation of sesame extract (1-1) Preparation of hot water extract of sesame 1000 g of a mixed solution obtained by adding 10 parts of ground sesame to 100 parts of fresh water is placed in a stainless steel pan and electromagnetically stirred gently with a spatula. Heat in a cooker and hold at 90 ° C. for 1 hour, cool to 20 ° C., and remove residual ground sesame by suction filtration (Kiriyama funnel, filter paper: No. 5A). Was prepared.
(1−2)ゴマの冷水抽出液の調製
(1−1)に準じて冷水抽出液を調製した。つまり、(1−1)同様にして得たすりゴマと清水の混合液1000gをステンレス製容器に入れ、20℃で1時間保存した後、吸引ろ過により残渣のすりゴマを取り除くことにより、ゴマの冷水抽出液を調製した。
(1-2) Preparation of cold water extract of sesame A cold water extract was prepared according to (1-1). That is, (1-1) 1000 g of a mixture of ground sesame and fresh water obtained in the same manner was put in a stainless steel container and stored at 20 ° C. for 1 hour, and then the residual ground sesame was removed by suction filtration. A cold water extract was prepared.
(2)試験品の製造
表1に示す配合割合の原料を室温下(20℃)でそれぞれ撹拌混合することにより、酸性液状食品の試験品a〜d及び対照品を調製した。表中の熱水抽出液は(1−1)で調製した品温20℃のものを、冷水抽出液は(1−2)で調製した品温20℃のものである。
(2) Manufacture of test products The test products a to d and the control product of the acidic liquid food were prepared by stirring and mixing the raw materials having the blending ratios shown in Table 1 at room temperature (20 ° C). The hot water extract in the table is the one with the product temperature of 20 ° C. prepared in (1-1), and the cold water extract is the one with the product temperature of 20 ° C. prepared in (1-2).
(3)劣化促進試験
(2)で調製した試験品a〜d及び対照品をそれぞれ鍋に入れて加熱し微沸状態を保ちながら3時間加熱処理することにより香気成分の劣化促進試験を行った。次に、促進試験後の刺激臭の強さを評価した。刺激臭の強さは、1〜7の7段階で評価し、この際、変質防止材を配合していない対照品の刺激臭の強さが5であり、数字が少ないほど刺激臭が弱いことを、数字が大きいほど刺激臭が強いことを示す。また、評価は、訓練されたパネラー4人で行いその平均値を評価結果とした。結果を表2に示す。
(3) Deterioration promotion test The deterioration promotion test of aroma components was performed by heating the test products a to d and the control product prepared in (2), respectively, in a pan and heating them for 3 hours while maintaining a slight boiling state. . Next, the strength of the irritating odor after the acceleration test was evaluated. The strength of the irritating odor is evaluated on a scale of 1 to 7, and the strength of the irritating odor of the control product that is not blended with the anti-altering material is 5, and the smaller the number, the weaker the irritating odor is. The larger the number, the stronger the irritating odor. The evaluation was performed by four trained panelists, and the average value was used as the evaluation result. The results are shown in Table 2.
表2より、アルカリ材とゴマ熱水抽出液を併用した場合(試験品d)は、変質防止材を添加していない対照品に比べて大幅に刺激臭が弱くなっていることが理解される。ここで、ゴマの熱水抽出液のみを用いた試験品b、アルカリ材のみを用いた試験品c、アルカリ材とゴマ熱水抽出液を併用した試験品dの刺激臭の評価結果から、ゴマの熱水抽出液のみを用いた場合は、刺激臭の低減効果が得られるもののその低減効果はわずかであったのに対して熱水抽出液をアルカリ材と併用することにより、アルカリ材のみを用いた場合及びゴマの熱水抽出液のみを用いた場合に比べて刺激臭を大幅に低減する効果が得られることが理解される。また、ゴマの冷水抽出液のみを用いた試験品aにおいては、低減効果は見られなかった。 From Table 2, it is understood that when the alkali material and sesame hot water extract are used in combination (test product d), the irritating odor is significantly weaker than the control product to which no alteration preventing material is added. . Here, from the evaluation result of the pungent odor of the test product b using only the sesame hot water extract, the test product c using only the alkali material, and the test product d using both the alkali material and sesame hot water extract, When using only the hot water extract of this product, although the effect of reducing the irritating odor was obtained, the effect of reducing the effect was slight, but by using the hot water extract together with the alkali material, It is understood that the effect of significantly reducing the irritating odor can be obtained as compared with the case where only the hot water extract of sesame is used. Further, in the test product a using only the sesame cold water extract, no reduction effect was observed.
[実施例1]
(1)ゴマの熱水抽出液の製造
ステンレス製の撹拌装置付きの抽出釜に、白ゴマ(すりゴマ)10部と酢酸水溶液(酢酸濃度13%)90部を投入し、白ゴマが酢酸水溶液中に分散するようにゆるやかに撹拌しながら品温60℃で1時間保持した。この際、熱水のpHは4.6以下であった。次いで、内容物を品温20℃になるまで冷却し、目開き0.1mmのフィルターを用いて残渣であるゴマを分離し、ゴマの熱水抽出液を製した。
[Example 1]
(1) Manufacture of hot water extract of sesame 10 kg of white sesame (ground sesame) and 90 parts of acetic acid aqueous solution (13% acetic acid concentration) are put into an extraction kettle with a stainless steel stirring device. The product temperature was maintained at 60 ° C. for 1 hour with gentle stirring to disperse it inside. At this time, the pH of the hot water was 4.6 or less. Next, the contents were cooled to a product temperature of 20 ° C., sesame as a residue was separated using a filter having an opening of 0.1 mm, and a sesame hot water extract was produced.
(2)容器入り分離液状ユズドレッシングの製造
下記の配合割合に準じ、本発明の容器入り酸性液状食品として容器入り分離液状ユズドレッシングを製した。すなわち、まず、(1)で調製した品温20℃のゴマ熱水抽出液、ユズ果皮、醤油、ユズ果汁、食酢、砂糖、食塩、キサンタンガム、酢酸ナトリウム、ユズフレーバー及び清水を撹拌タンクに投入して室温下(20℃)で均一に混合することにより、水相を調製した。そして、分離液状調味料の容量が250mLとなるように250mL容量の蓋付き樹脂製透明容器(容器材質:ポリエチレンテレフタレート(PET))に上記水相を充填した後に、残りの油相であるサラダ油を充填して水相の上に油相を積載させ、次いで密栓し、透明容器入り分離液状ユズドレッシングを製した。
(2) Manufacture of separated liquid yuzu dressing in a container According to the following blending ratio, a separated liquid yuzu dressing in a container was manufactured as an acidic liquid food in a container of the present invention. That is, first, the sesame hot water extract of 20 ° C. prepared in (1), yuzu peel, soy sauce, yuzu juice, vinegar, sugar, salt, xanthan gum, sodium acetate, yuzu flavor and fresh water are put into a stirring tank. The aqueous phase was prepared by uniformly mixing at room temperature (20 ° C.). And after filling the said aqueous phase into the resin transparent container (container material: polyethylene terephthalate (PET)) with a capacity | capacitance of 250 mL so that the capacity | capacitance of a separation liquid seasoning may be 250 mL, salad oil which is the remaining oil phase is filled. Filled and loaded the oil phase on top of the water phase, and then sealed to produce a separate liquid Yuzu dressing in a transparent container.
なお、本実施例においては、ゴマ熱水抽出液の配合量が20%、アルカリ材の配合量が0.1%であり、製品のpHは4.6以下である。 In addition, in a present Example, the compounding quantity of a sesame hot-water extract is 20%, the compounding quantity of an alkali material is 0.1%, and pH of a product is 4.6 or less.
<分離液状ユズドレッシングの配合割合>
(油相原料)
サラダ油 35%
(水相原料)
ゴマ熱水抽出液 20%
ユズ果皮(2mm各の截断物) 1%
醤油 10%
ユズ果汁 10%
食酢(酢酸濃度4%) 10%
砂糖 5%
食塩 2%
キサンタンガム 0.1%
酢酸ナトリウム 0.1%
ユズフレーバー※ 0.1%
清水 6.7%
―――――――――――――――――――――
合計 100%
※シトラールを含むユズ水溶性香料
<Combination ratio of separated liquid yuzu dressing>
(Oil phase raw material)
Salad oil 35%
(Water phase raw material)
Sesame hot water extract 20%
Yuzu peel (2mm cut pieces) 1%
10% soy sauce
Yuzu juice 10%
Vinegar (acetic acid concentration 4%) 10%
5% sugar
Salt 2%
Xanthan gum 0.1%
Sodium acetate 0.1%
Yuzu Flavor * 0.1%
Shimizu 6.7%
―――――――――――――――――――――
Total 100%
* Yuzu water-soluble fragrance containing citral
[実施例2]
下記の配合割合に準じ、本発明の容器入り酸性液状食品として容器入り黒酢飲料を製した。すなわち、品温20℃のゴマ熱水抽出液(実施例1(1)で調製したものと同じ)、黒酢、ショウガ、はちみつ、酢酸ナトリウム、ショウガフレーバー及び清水を撹拌タンクに投入して室温下(20℃)で均一に混合することにより、黒酢飲料を製した。次いで、得られた黒酢飲料200mLを蓋付きガラス瓶に充填した後に、密栓し、透明容器入り黒酢飲料を製した。
[Example 2]
According to the following blending ratio, a black vinegar beverage in a container was produced as the acidic liquid food in a container of the present invention. That is, a sesame hot water extract (same as that prepared in Example 1 (1)), black vinegar, ginger, honey, sodium acetate, ginger flavor and fresh water were put into a stirring tank at room temperature. A black vinegar drink was produced by mixing uniformly at (20 ° C.). Subsequently, after filling 200 mL of obtained black vinegar drinks into the glass bottle with a lid, it sealed and produced the black vinegar drink with a transparent container.
なお、本実施例においては、ゴマ熱水抽出液の配合量が10%、アルカリ材の配合量が0.2%であり、製品のpHは4.6以下である。 In addition, in a present Example, the compounding quantity of a sesame hot-water extract is 10%, the compounding quantity of an alkali material is 0.2%, and the pH of a product is 4.6 or less.
<容器入り黒酢飲料の配合割合>
ゴマ熱水抽出液 10%
黒酢 4%
ショウガ(おろし) 7.5%
はちみつ 4%
酢酸ナトリウム 0.2%
ショウガフレーバー※ 0.1%
清水 74.2%
―――――――――――――――――――――
合計 100%
※シトラールを含むショウガ水溶性香料
<Combination ratio of black vinegar beverage in container>
Sesame hot water extract 10%
4% black vinegar
Ginger 7.5%
Honey 4%
Sodium acetate 0.2%
Ginger flavor * 0.1%
Shimizu 74.2%
―――――――――――――――――――――
Total 100%
* Ginger water-soluble fragrance containing citral
[実施例3]
下記の配合割合に準じ、本発明の容器入り酸性液状食品として容器入り果汁飲料を製した。すなわち、品温20℃のゴマ熱水抽出液(実施例1(1)で調製したものと同じ)、オレンジ果汁、レモン果皮、砂糖、クエン酸ナトリウム、レモンフレーバー及び清水を撹拌タンクに投入して室温下(20℃)で均一に混合することにより、果汁飲料を製した。得られた果汁飲料500mLを蓋付き樹脂製透明容器(容器材質:ポリエチレンテレフタレート(PET))に充填した後に、密栓し、透明容器入り果汁飲料を製した。
[Example 3]
According to the following blending ratio, a fruit juice beverage in a container was produced as the acidic liquid food in a container of the present invention. That is, sesame hot water extract (same as that prepared in Example 1 (1)), orange juice, lemon peel, sugar, sodium citrate, lemon flavor and fresh water were put into a stirring tank. A fruit juice drink was produced by mixing uniformly at room temperature (20 ° C.). After filling 500 mL of the obtained fruit juice beverage into a transparent resin container with a lid (container material: polyethylene terephthalate (PET)), it was tightly sealed to produce a fruit juice beverage in a transparent container.
なお、本実施例においては、ゴマ熱水抽出液の配合量が10%、アルカリ材の配合量が0.1%であり、製品のpHは4.6以下である。 In addition, in a present Example, the compounding quantity of a sesame hot-water extract is 10%, the compounding quantity of an alkali material is 0.1%, and the pH of a product is 4.6 or less.
<容器入り果汁飲料の配合割合>
ゴマ熱水抽出液 10%
オレンジ果汁 40%
レモン果皮(おろし) 3%
砂糖 5%
クエン酸ナトリウム 0.1%
レモンフレーバー※ 0.1%
清水 41.8%
―――――――――――――――――――――
合計 100%
※シトラールを含むレモン水溶性香料
<Combination ratio of fruit juice beverage in container>
Sesame hot water extract 10%
Orange juice 40%
Lemon peel (grated) 3%
5% sugar
Sodium citrate 0.1%
Lemon flavor * 0.1%
Shimizu 41.8%
―――――――――――――――――――――
Total 100%
* Lemon water-soluble fragrance containing citral
[実施例4]
下記の配合割合に準じ、本発明の容器入り酸性液状食品として容器入りノンオイルショウガドレッシングを製した。まず、二重釜に、金ゴマ、食酢、食塩及び清水を投入して混合し、金ゴマが酢酸水溶液中に分散するようにゆるやかに撹拌しながら品温80℃で30分間保持した。この際、熱水のpHは4.6以下であった。次いで、前記金ゴマ、食酢、食塩及び清水の混合物を品温20℃になるまで冷却した。続いて、撹拌タンクに、金ゴマ、食酢及び清水からなる前記品温20℃の混合物、ショウガ、醤油、砂糖、食塩、キサンタガム、グルタミン酸ナトリウム、酢酸ナトリウム及びショウガフレーバーを投入し室温下(20℃)で全体を均一に混合することにより、ノンオイルショウガドレッシングを製した。更に、得られたノンオイルショウガドレッシング200mLを蓋付きガラス瓶に充填した後に、密栓し、透明容器入りノンオイルショウガドレッシングを製した。
[Example 4]
In accordance with the following blending ratio, a non-oil ginger dressing in a container was produced as the acidic liquid food in a container of the present invention. First, gold sesame, vinegar, salt and fresh water were added to a double kettle and mixed, and the mixture was held at a product temperature of 80 ° C. for 30 minutes with gentle stirring so that the gold sesame was dispersed in the acetic acid aqueous solution. At this time, the pH of the hot water was 4.6 or less. Next, the mixture of gold sesame, vinegar, salt and fresh water was cooled to a product temperature of 20 ° C. Subsequently, a mixture of gold sesame, vinegar, and fresh water at a temperature of 20 ° C., ginger, soy sauce, sugar, salt, xantham gum, sodium glutamate, sodium acetate, and ginger flavor are charged into a stirring tank at room temperature (20 ° C.). A non-oil ginger dressing was made by uniformly mixing the whole. Furthermore, after filling 200 mL of the obtained non-oil ginger dressing into a glass bottle with a lid, it was sealed and a non-oil ginger dressing in a transparent container was manufactured.
なお、本実施例においては、ゴマ熱水抽出液の配合量が81.6%、アルカリ材の配合量が0.2%であり、製品のpHは4.6以下である。 In addition, in a present Example, the compounding quantity of a sesame hot-water extract is 81.6%, the compounding quantity of an alkali material is 0.2%, and the pH of a product is 4.6 or less.
<ノンオイルショウガドレッシングの配合割合>
金ゴマ(ホール) 2%
ショウガ(2mm各の截断物) 1%
醤油 10%
食酢(酸度4%) 16%
砂糖 5%
食塩 2%
キサンタンガム 0.1%
グルタミン酸ナトリウム 0.1%
酢酸ナトリウム 0.1%
ショウガフレーバー※ 0.1%
清水 63.6%
―――――――――――――――――――――
合計 100%
※シトラールを含むショウガ水溶性香料
<Non-oil ginger dressing ratio>
Gold sesame (hole) 2%
Ginger (2mm cut pieces) 1%
10% soy sauce
Vinegar (acidity 4%) 16%
5% sugar
Salt 2%
Xanthan gum 0.1%
Sodium glutamate 0.1%
Sodium acetate 0.1%
Ginger flavor * 0.1%
Shimizu 63.6%
―――――――――――――――――――――
Total 100%
* Ginger water-soluble fragrance containing citral
[実施例5]
実施例4において、ゴマの熱水抽出液を製造する際の熱水抽出液にショウガ及びショウガフレーバーを配合した以外は同様にして、ノンオイルショウガドレッシングを製した。つまり、まず、二重釜に、金ゴマ、食酢、食塩、ショウガ、ショウガフレーバー及び清水を投入して混合し、金ゴマが酢酸水溶液中に分散するようにゆるやかに撹拌しながら品温80℃で30分間保持した後、混合物を品温20℃になるまで冷却した。次に、撹拌タンクに、その他の原料を投入し室温下(20℃)で全体を均一に混合することにより、ノンオイルショウガドレッシングを製した。次いで、得られたノンオイルショウガドレッシング200mLを蓋付きガラス瓶に充填した後に、密栓し、透明容器入りノンオイルショウガドレッシングを製した。
[Example 5]
In Example 4, a non-oil ginger dressing was produced in the same manner except that ginger and ginger flavor were added to the hot water extract when producing the sesame hot water extract. That is, first, add gold sesame, vinegar, salt, ginger, ginger flavor and fresh water to a double kettle, mix, and gently stir so that the gold sesame is dispersed in the acetic acid aqueous solution at a product temperature of 80 ° C. After holding for 30 minutes, the mixture was cooled to a product temperature of 20 ° C. Next, a non-oil ginger dressing was manufactured by putting other raw materials into the stirring tank and uniformly mixing the whole at room temperature (20 ° C.). Next, after filling 200 mL of the obtained non-oil ginger dressing into a glass bottle with a lid, it was sealed and a non-oil ginger dressing in a transparent container was manufactured.
なお、本実施例においては、ゴマ熱水抽出液の配合量が81.7%、アルカリ材の配合量が0.2%であり、製品のpHは4.6以下である。 In addition, in a present Example, the compounding quantity of a sesame hot-water extract is 81.7%, the compounding quantity of an alkali material is 0.2%, and the pH of a product is 4.6 or less.
[試験例2]
実施例1乃至5で得られた容器入り酸性液状食品について、試験例1の方法に準じて香気成分の劣化促進試験を行った。つまり、実施例1乃至5で得られた酸性液状食品をそれぞれ鍋に入れて加熱し微沸状態を保ちながら3時間加熱処理することにより香りの変質の促進試験を行った。次に、促進試験後の各酸性液状食品における香りを下記の評価基準で評価した。結果を表3に示す。
[Test Example 2]
The acidic liquid foods in containers obtained in Examples 1 to 5 were subjected to an aroma component deterioration promotion test according to the method of Test Example 1. That is, the acidic liquid food obtained in Examples 1 to 5 was put in a pan, heated, and heat-treated for 3 hours while maintaining a slight boiling state, thereby conducting a fragrance alteration promotion test. Next, the fragrance in each acidic liquid food after the acceleration test was evaluated according to the following evaluation criteria. The results are shown in Table 3.
<香りの評価基準>
A:刺激臭がほとんど感じられず製品として問題ない。
B:刺激臭がわずかに感じられるが製品として問題ない。
C:刺激臭がやや強く製品としてやや問題となる。
D:刺激臭が強く製品として問題となる。
<Evaluation criteria for fragrance>
A: The irritating odor is hardly felt and there is no problem as a product.
B: Slight irritating odor is felt, but there is no problem as a product.
C: The irritating odor is slightly strong and becomes a problem as a product.
D: Strong pungent odor causes a problem as a product.
表3より、アルカリ材とゴマ熱水抽出液が配合された実施例1乃至5の容器入り酸性液状食品は、いずれも刺激臭が問題のない程度であり好ましいことが理解できる。また、製造方法が刺激臭に与える影響に関し、品温20℃に冷却したゴマの熱水抽出液と、ショウガ及びシトラール含有香料とを混合して製造した実施例4の容器入り酸性液状食品は、ゴマを熱水抽出する際の熱水に、ショウガ及びシトラール含有香料を配合して製造した実施例5の容器入り酸性液状食品に比べて、刺激臭が弱くより好ましかった。 From Table 3, it can be understood that the acidic liquid foods in containers of Examples 1 to 5 in which the alkaline material and the sesame hot water extract are blended are preferable because the irritating odor has no problem. In addition, regarding the effect of the production method on the pungent odor, the acidic liquid food in a container of Example 4 produced by mixing a hot water extract of sesame cooled to a product temperature of 20 ° C. with a ginger and citral-containing fragrance, Compared to the acidic liquid food in a container of Example 5 produced by blending ginger and citral-containing fragrance into hot water when extracting sesame with hot water, the pungent odor was weaker and more preferable.
Claims (2)
ゴマの熱水抽出液及びアルカリ材が配合されている容器入り酸性液状食品の製造方法であって、
ゴマを60〜100℃の熱水と接触させてゴマの熱水抽出液を製した後、
該ゴマの熱水抽出液と、柑橘類果皮、ショウガ、又はシトラール含有香料から選ばれる一種又は二種以上とを混合することを特徴とする容器入り酸性液状食品の製造方法。 One or more selected from citrus peel, ginger, or citral-containing fragrance, and
A method for producing an acidic liquid food in a container containing a hot water extract of sesame and an alkali material ,
After making sesame hot water extract by contacting sesame with hot water at 60-100 ° C,
A method for producing an acidic liquid food in a container, comprising mixing the hot water extract of sesame and one or more selected from citrus peel, ginger, or citral-containing fragrance.
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