JP5006540B2 - Slowly water soluble composition and cleaning method using the same - Google Patents
Slowly water soluble composition and cleaning method using the same Download PDFInfo
- Publication number
- JP5006540B2 JP5006540B2 JP2005366487A JP2005366487A JP5006540B2 JP 5006540 B2 JP5006540 B2 JP 5006540B2 JP 2005366487 A JP2005366487 A JP 2005366487A JP 2005366487 A JP2005366487 A JP 2005366487A JP 5006540 B2 JP5006540 B2 JP 5006540B2
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- Japan
- Prior art keywords
- water
- soluble composition
- mass
- acid
- aerosol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
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Landscapes
- Bidet-Like Cleaning Device And Other Flush Toilet Accessories (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Detergent Compositions (AREA)
Description
本発明は、水徐溶性組成物、及びそれを用いた洗浄方法に関し、詳しくは、流水と接触する任意の面に塗布し、該流水により徐溶させて洗浄を行うことができる水徐溶性組成物、及びそれを用いた洗浄方法に関する。 TECHNICAL FIELD The present invention relates to a water-slowly soluble composition and a cleaning method using the same, and more specifically, a water-slowly soluble composition that can be applied to an arbitrary surface that is in contact with running water and gradually dissolved with the running water for cleaning. And a cleaning method using the same.
一般に、水洗便器内面、台所や洗面台等のシンク表面や排水口、及び浴室の排水口などは、有機物汚れ（排泄物、食材、石鹸カス、垢等）が付着しやすく、かつ常に水と接触する場所であるため、ぬめりやカビが発生沈着しやすく、また悪臭等も発生しやすい。これらの洗浄は不快を伴い、負担が大きい作業である。
このため、近年、水洗便器や排水口等の洗浄効果を簡便かつ持続的に得ることを目的とした各種洗浄剤組成物が提案されている。
In general, organic dirt (excrement, foodstuffs, soap residue, dirt, etc.) is likely to adhere to the inner surface of the flush toilet, the sink surface and drain outlet of the kitchen and washstand, etc., and the drain outlet of the bathroom, and is always in contact with water. Therefore, slimming and mold are likely to be generated and deposited, and bad odor is also likely to occur. These cleaning operations are uncomfortable and burdensome.
For this reason, in recent years, various cleaning compositions have been proposed for the purpose of easily and continuously obtaining cleaning effects such as flush toilets and drain outlets.
例えば、水洗便器の洗浄剤組成物としては、水洗便器のタンク内の洗浄水に洗浄剤有効成分を溶出させて、持続的に便器の汚れを洗浄し、清潔な状態を保たせることを目的とした洗浄剤組成物が知られている。
具体的には、ノニオン界面活性剤をポリエチレングリコールの誘導体を用いて固化させた水洗トイレ用固形消臭洗浄剤（例えば、特許文献１参照）、溶出速度の水温依存性、効力の持続性を向上させるために、ポリエチレングリコールジステアレートにヒドロキシプロピルメチルセルロースを配合された固体状の芳香洗浄剤（例えば、特許文献２参照）などが知られている。更に、洗浄剤の有効成分を高濃度に配合できるものとして、ゲル化剤としてカラギーナンを用いて固形状に成形されたゲル状の水溶性洗浄剤組成物が提案されている（例えば、特許文献３参照）。
For example, as a cleaning composition of a flush toilet, the purpose is to elute detergent active ingredients in the washing water in the flush toilet tank to continuously wash the toilet bowl and keep it clean. Detergent compositions are known.
Specifically, a solid deodorant cleaning agent for flush toilets obtained by solidifying a nonionic surfactant with a polyethylene glycol derivative (see, for example, Patent Document 1), improving the water temperature dependence of elution rate, and sustainability of efficacy. For this purpose, a solid fragrance cleaner in which hydroxypropylmethylcellulose is blended with polyethylene glycol distearate (for example, see Patent Document 2) is known. Furthermore, a gel-like water-soluble detergent composition that has been molded into a solid form using carrageenan as a gelling agent has been proposed as an active ingredient of a detergent that can be blended at a high concentration (for example, Patent Document 3). reference).
しかしながら、前記特許文献１〜３の洗浄剤組成物は、水洗便器のタンク上部の手洗い部分に設置して使用すること、タンク内の貯水部分に投入して使用することを想定したものであり、その形態も固形状の成形体や、専用容器に組み込まれて提供されるものである。このため、便器の形態によっては使用が制限されることがあり、特に、近年増加しているタンクレス型の水洗便器には適用できないという問題がある。 However, the cleaning compositions of Patent Documents 1 to 3 are assumed to be installed and used in a hand-washing portion at the top of a tank of a flush toilet, and to be used by being put into a water storage portion in a tank, The form is also provided by being incorporated into a solid molded body or a dedicated container. For this reason, use may be restrict | limited depending on the form of a toilet bowl, and there exists a problem that it cannot apply to the tankless type flush toilet bowl which has increased especially in recent years.
一方、排水口用の洗浄剤組成物としては、例えば、機械力でこすることなく除去するために、５−クロロ−２−メチル−４−イソチアゾリン−３−オン等の抗菌成分を固体状にした錠剤を、プラスチック容器に収蔵させて、洗浄成分を徐々に放出する方法が知られている（例えば、特許文献４参照）。しかしながら、洗浄剤組成物を流水下に設置しておくために、容器を伴う場合には、該容器が様々な排水口の大きさや形状に適応する必要があり、すべての排水口に対応できない可能性がある。 On the other hand, as a detergent composition for a drain outlet, for example, an antibacterial component such as 5-chloro-2-methyl-4-isothiazolin-3-one is solidified to be removed without rubbing with mechanical force. A method is known in which a tablet is stored in a plastic container and a cleaning component is gradually released (see, for example, Patent Document 4). However, in order to keep the cleaning composition under running water, if it is accompanied by a container, the container needs to be adapted to the size and shape of various drains and may not be able to accommodate all drains. There is sex.
また、持続的な洗浄効果や殺菌効果等を得るためには、溶出した洗浄剤成分が排水口の被洗浄面に接触する必要があるが、容器の形態によっては排水口全体の洗浄が困難な場合があり、容器を伴わない場合は、流水により洗浄剤組成物の滞留が妨げられる場合がある。 In addition, in order to obtain a continuous cleaning effect and a sterilizing effect, it is necessary that the eluted cleaning agent components come into contact with the surface to be cleaned of the drain port, but it is difficult to clean the entire drain port depending on the form of the container. In some cases and without a container, the running water may prevent the cleaning composition from staying.
よって、流水と接触する任意の面に塗布することができ、塗布後流水によって剥離することがなく、該流水により徐溶させて洗浄、殺菌、防汚、消臭等を行うことができる水徐溶性組成物、及びそれを用いた洗浄方法は未だ提供されておらず、さらなる改良が望まれているのが現状である。 Therefore, it can be applied to any surface that is in contact with running water and can be washed, sterilized, antifouling, deodorized, etc. by being gradually dissolved by running water without being peeled off by running water after application. A soluble composition and a cleaning method using the soluble composition have not yet been provided, and the current situation is that further improvements are desired.
本発明は、前記従来における諸問題を解決し、以下の目的を達成することを課題とする。即ち、本発明は、水洗便器内面、台所や洗面台等のシンク表面や排水口、及び浴室の排水口などの流水と接触する任意の面に塗布することができ、塗布後流水によって剥離することがなく、該流水により洗浄剤成分を徐溶させて持続的に洗浄、殺菌、防汚、消臭等を行うことができる水徐溶性組成物、及びそれを用いた洗浄方法を提供することを目的とする。 An object of the present invention is to solve the conventional problems and achieve the following objects. That is, the present invention can be applied to any surface that comes into contact with running water such as the inner surface of a flush toilet, the sink surface of a kitchen or a wash basin, a drain outlet, and a drain outlet of a bathroom. And providing a water slow-dissolving composition capable of continuously washing, sterilizing, antifouling, deodorizing and the like by gradually dissolving the detergent component with the flowing water and a cleaning method using the same. Objective.
前記課題を解決するため、本発明者らが鋭意検討を重ねた結果、水に膨潤性乃至溶解性を示す高分子化合物であり、その分散液乃至水溶液が、粘着性及び徐溶性を示す高分子化合物を配合することにより、流水と接触する任意の面に塗布することができ、塗布後流水によって剥離することがなく、該流水により徐溶する組成物が得られ、前記課題を解決しうることを見出し、本発明を完成するに至った。 In order to solve the above-mentioned problems, the present inventors have conducted intensive studies, and as a result, the polymer is a polymer compound that swells or dissolves in water, and its dispersion or aqueous solution is a polymer that exhibits adhesiveness and slow solubility. By blending the compound, a composition that can be applied to any surface in contact with running water and is not peeled off by running water after application, and is gradually dissolved by the running water, can solve the above-mentioned problems As a result, the present invention has been completed.
本発明は、本発明者による前記知見に基づくものであり、前記課題を解決するための手段としては、以下の通りである。即ち、
＜１＞ （Ａ）水溶解遅延成分と、（Ｂ）薬剤成分と、（Ｃ）溶媒とを少なくとも含み、前記水溶解遅延成分（Ａ）が、水に膨潤乃至溶解し、前記水溶解遅延成分（Ａ）の分散液乃至水溶液が、粘着性及び徐溶性を示すことを特徴とする水徐溶性組成物である。
＜２＞ 水溶解遅延成分（Ａ）の含有量が１〜３０質量％、薬剤成分（Ｂ）の含有量が１〜５０質量％、溶媒（Ｃ）の含有量が２０〜９８質量％である前記＜１＞に記載の水徐溶性組成物である。
＜３＞ ０〜４０℃において、流動性を有する前記＜１＞から＜２＞のいずれかに記載の水徐溶性組成物である。
＜４＞ ０．１７ｇ／ｃｍ２となるように水徐溶性組成物を塗布した塗布面に、２５℃の水を流速６００ｍＬ／ｓで１０秒間流した時、前記水徐溶性組成物の残存率が９０％以上である前記＜１＞から＜３＞のいずれかに記載の水徐溶性組成物である。
＜５＞ 水溶解遅延成分（Ａ）が、その５％分散液及び５％水溶液のいずれか６ｇを１０ｃｍ×１０ｃｍのステンレス板に展着させた後乾燥し、０．３ｇの皮膜としたものを２５℃の水２Ｌ中に投入し、前記水を１００ｒｐｍで１０分間攪拌した時、前記皮膜からの溶出率が２０質量％未満である前記＜１＞から＜４＞のいずれかに記載の水徐溶性組成物である。
＜６＞ 水溶解遅延成分（Ａ）が、セルロースエーテル、ポリオキシエチレン脂肪酸エステル、及びポリビニルアルコールから選択される少なくとも１種である前記＜１＞から＜５＞のいずれかに記載の水徐溶性組成物である。
＜７＞ 薬剤成分（Ｂ）が、界面活性剤及び殺菌剤の少なくともいずれかである前記＜１＞から＜６＞のいずれかに記載の水徐溶性組成物である。
＜８＞ 前記＜１＞から＜７＞のいずれかに記載の水徐溶性組成物を、被洗浄物の表面であって、流水と接触する面に塗布し、該流水により前記水徐溶性組成物を徐溶させて、前記被洗浄物を洗浄することを特徴とする洗浄方法である。
＜９＞ 被洗浄物が、水洗便器、及び排水口のいずれかである前記＜８＞に記載の洗浄方法である。
This invention is based on the said knowledge by this inventor, and as a means for solving the said subject, it is as follows. That is,
<1> (A) A water dissolution delay component, (B) a drug component, and (C) a solvent, wherein the water dissolution delay component (A) swells or dissolves in water, and the water dissolution delay component The dispersion or aqueous solution of (A) is a water-slowly soluble composition characterized by exhibiting tackiness and slow solubility.
<2> The content of the water dissolution delay component (A) is 1 to 30% by mass, the content of the drug component (B) is 1 to 50% by mass, and the content of the solvent (C) is 20 to 98% by mass. It is a water-soluble composition as described in said <1>.
<3> The water-soluble composition according to any one of <1> to <2>, which has fluidity at 0 to 40 ° C.
<4> When 25 ° C. water is allowed to flow at a flow rate of 600 mL / s for 10 seconds on the coated surface on which the water-soluble composition is applied so as to be 0.17 g / cm 2 , the residual rate of the water-soluble composition is retained. The water-soluble composition according to any one of <1> to <3>, in which is 90% or more.
<5> Water dissolution delay component (A) is a 5 g dispersion and a 5% aqueous solution in which 6 g is spread on a 10 cm × 10 cm stainless steel plate and dried to form a 0.3 g film. The water solution according to any one of <1> to <4>, wherein the elution rate from the film is less than 20% by mass when charged in 2 L of water at 25 ° C. and stirred for 10 minutes at 100 rpm. It is a soluble composition.
<6> The water-slow solubility according to any one of <1> to <5>, wherein the water dissolution delay component (A) is at least one selected from cellulose ether, polyoxyethylene fatty acid ester, and polyvinyl alcohol. It is a composition.
<7> The water-soluble composition according to any one of <1> to <6>, wherein the drug component (B) is at least one of a surfactant and a bactericide.
<8> The water-soluble composition according to any one of <1> to <7> is applied to a surface of an object to be cleaned which is in contact with running water, and the water-soluble composition is applied with the running water. A cleaning method is characterized in that an object is gradually dissolved to clean the object to be cleaned.
<9> The cleaning method according to <8>, wherein the object to be cleaned is one of a flush toilet and a drain.
本発明によると、流水と接触する任意の面に塗布することができ、塗布後流水によって剥離することがなく、該流水により薬剤成分を徐溶させて持続的に洗浄、殺菌、防汚、消臭等を行うことができる水徐溶性組成物、及びそれを用いた洗浄方法を提供することができる。 According to the present invention, it can be applied to any surface that is in contact with running water and is not peeled off by running water after application. It is possible to provide a water-slowly soluble composition capable of performing odor and the like, and a cleaning method using the same.
（水徐溶性組成物）
本発明の水徐溶性組成物は、（Ａ）水溶解遅延成分と、（Ｂ）薬剤成分と、（Ｃ）溶媒とを少なくとも含み、更に必要に応じて、その他の成分を含有する。
本発明の水徐溶性組成物は、０〜４０℃において、流動性を有することが好ましく、被洗浄物の表面に塗布して使用し、塗布面上を通過する流水により流失することなく、前記被洗浄物の表面に剤型を保ちながら滞留し、前記流水により徐々に溶解する性状を有する。
具体的には、０．１７ｇ／ｃｍ２となるように前記水徐溶性組成物を塗布した塗布面に、２５℃の水を流速６００ｍＬ／ｓで１０分間流した時、前記水徐溶性組成物が剥離せずに残存し、その残存率が９０％以上であることが好ましく、９５％以上であることがより好ましい。
(Slow water-soluble composition)
The water-soluble composition of the present invention contains (A) a water dissolution delay component, (B) a drug component, and (C) a solvent, and further contains other components as necessary.
The water-slowly soluble composition of the present invention preferably has fluidity at 0 to 40 ° C., and is used by being applied to the surface of the object to be cleaned without being washed away by running water passing over the coated surface. It has the property of staying on the surface of the object to be cleaned while maintaining the dosage form and gradually dissolving with the flowing water.
Specifically, when water at 25 ° C. is allowed to flow at a flow rate of 600 mL / s for 10 minutes on the coated surface on which the water-soluble composition is applied so as to be 0.17 g / cm 2 , the water-soluble composition is obtained. However, the residual ratio is preferably 90% or more, more preferably 95% or more.
（Ａ）水溶解遅延成分
前記水溶解遅延成分は、水に膨潤乃至溶解し、その分散液乃至水溶液が、粘着性及び徐溶性を示すものであれば、特に制限は無く、目的に応じて適宜選択することができる。
具体的には、前記水溶解遅延成分の５％分散液及び５％水溶液のいずれか６ｇを１０ｃｍ×１０ｃｍのステンレス板に展着させた後乾燥させて前記水溶解遅延成分の皮膜を形成し、これをステンレス板とともに２５℃の水２Ｌ中に投入し、前記水を１００ｒｐｍで１０分間攪拌した時、前記水溶解遅延成分の皮膜の溶出率が２０質量％未満であることが好ましく、１０質量％未満であることがより好ましい。
(A) Water dissolution delay component The water dissolution delay component is not particularly limited as long as it swells or dissolves in water, and its dispersion or aqueous solution exhibits adhesiveness and slow solubility. You can choose.
Specifically, 6 g of any of the 5% dispersion and 5% aqueous solution of the water dissolution delay component is spread on a 10 cm × 10 cm stainless steel plate and then dried to form a film of the water dissolution delay component. When this is poured into 2 L of water at 25 ° C. together with a stainless steel plate, and the water is stirred at 100 rpm for 10 minutes, the elution rate of the water dissolution delay component film is preferably less than 20% by mass. More preferably, it is less.
前記水溶解遅延成分としては、ヒドロキシプロピルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルメチルセルロース等のセルロースエーテル、ポリエチレングリコールジステアレート等のポリオキシエチレン脂肪酸エステル、及びポリビニルアルコールなどが好ましく、ヒドロキシプロピルセルロース、ヒドロキシエチルセルロース、及びヒドロキシプロピルメチルセルロースがより好ましく、ヒドロキシプロピルセルロースが特に好ましい。
これらは、１種を単独で、又は２種以上を混合して使用することができる。
Examples of the water dissolution delay component include cellulose ethers such as hydroxypropyl cellulose, hydroxyethyl cellulose, hydroxypropyl methyl cellulose, polyoxyethylene fatty acid esters such as polyethylene glycol distearate, and polyvinyl alcohol. Hydroxypropyl cellulose, hydroxyethyl cellulose, And hydroxypropylmethylcellulose are more preferred, and hydroxypropylcellulose is particularly preferred.
These can be used individually by 1 type or in mixture of 2 or more types.
前記ヒドロキシプロピルセルロースとしては、特に制限はなく、目的に応じて適宜選択することができるが、徐溶性の観点から、置換基であるヒドロキシプロポキシル基の置換モル数が３．０〜４．０であるものが好ましい。ここで、前記置換モル数とは、セルロースのグルコース環単位当たりに付加した置換基の平均モル数を表す。
前記ヒドロキシプロピルセルロースの市販品としては、例えば、日曹ＨＰＣ（日本曹達社製）、ＫＬＵＣＥＬ（ＨＥＲＣＵＬＥＳ社製）等を用いることができる。
There is no restriction | limiting in particular as said hydroxypropyl cellulose, Although it can select suitably according to the objective, From the viewpoint of slow solubility, the substitution mole number of the hydroxypropoxyl group which is a substituent is 3.0-4.0. Are preferred. Here, the said substituted mole number represents the average mole number of the substituent added per glucose ring unit of cellulose.
As a commercial item of the said hydroxypropyl cellulose, Nisso HPC (made by Nippon Soda Co., Ltd.), KLUCEL (made by HERCULES) etc. can be used, for example.
前記ヒドロキシエチルセルロースとしては、特に制限はなく、目的に応じて適宜選択することができるが、徐溶性の観点から、置換基であるヒドロキシエチル基の置換度が１．０〜１．３であることが好ましく、ヒドロキシメチル基の置換モル数が１．８〜２．５であることが好ましい。ここで、前記置換度とは、セルロースのグルコース環単位当たり置換された水酸基の平均個数を表し、前記置換モル数とは、セルロースのグルコース環単位当たりに付加した置換基の平均モル数を表す。
また、前記ヒドロキシエチルセルロース水溶液の粘度としては、２５℃における１％水溶液の粘度として３００〜６，０００ｍＰａ・ｓであることが好ましく、１，０００〜３，０００ｍＰａ・ｓであることがさらに好ましい。
なお、粘度測定はＢＬ型粘度計、ローターＮｏ．３、回転数３０ｒｐｍにて測定を行い、前記範囲で適さない場合、例えば粘度が高すぎるときには、ローターＮｏ．４、回転数１２ｒｐｍとし、粘度が低すぎるときには、ローターＮｏ．２、回転数６０ｒｐｍなどというように、ローターと回転数とを適切に選択して測定することができる。
前記ヒドロキシエチルセルロースの市販品としては、例えば、ＨＥＣダイセル（ダイセル化学工業（株）製）等を用いることができる。
There is no restriction | limiting in particular as said hydroxyethyl cellulose, Although it can select suitably according to the objective, The substitution degree of the hydroxyethyl group which is a substituent is 1.0-1.3 from a slow solubility viewpoint. It is preferable that the number of moles of substitution of the hydroxymethyl group is 1.8 to 2.5. Here, the degree of substitution represents the average number of hydroxyl groups substituted per glucose ring unit of cellulose, and the number of substituted moles represents the average number of substituents added per glucose ring unit of cellulose.
Further, the viscosity of the aqueous hydroxyethyl cellulose solution is preferably 300 to 6,000 mPa · s, more preferably 1,000 to 3,000 mPa · s, as the viscosity of a 1% aqueous solution at 25 ° C.
The viscosity was measured using a BL type viscometer, rotor No. 3. When the measurement is performed at a rotation speed of 30 rpm and is not suitable within the above range, for example, when the viscosity is too high, the rotor No. 4, when the rotational speed is 12 rpm and the viscosity is too low, the rotor No. 2. It can be measured by appropriately selecting the rotor and the rotational speed, such as a rotational speed of 60 rpm.
As a commercially available product of the hydroxyethyl cellulose, for example, HEC Daicel (manufactured by Daicel Chemical Industries, Ltd.) can be used.
前記ヒドロキシプロピルメチルセルロースとしては、特に制限はなく、目的に応じて適宜選択することができるが、徐溶性の観点から、置換基であるメトキシル基の置換度が１．４〜１．９であり、ヒドロキシプロポキシル基の置換モル数が０．１５〜０．２５であることが好ましい。ここで、前記置換度とは、セルロースのグルコース環単位当たり置換された水酸基の平均個数を表し、前記置換モル数とは、セルロースのグルコース環単位当たりに付加した置換基の平均モル数を表す。
また、前記ヒドロキシプロピルメチルセルロース水溶液の粘度としては、２０℃における２％水溶液の粘度として１００〜３０，０００ｍＰａ・ｓであることが好ましく、４００〜５，０００ｍＰａ・ｓであることがさらに好ましい。
なお、粘度測定はＢＬ型粘度計、ローターＮｏ．３、回転数３０ｒｐｍにて測定を行い、前記範囲で適さない場合、例えば粘度が高すぎるときには、ローターＮｏ．４、回転数１２ｒｐｍとし、粘度が低すぎるときには、ローターＮｏ．２、回転数６０ｒｐｍなどというように、ローターと回転数とを適切に選択して測定することができる。
前記ヒドロキシプロピルメチルセルロースの市販品としては、例えば、メトローズ（信越化学工業（株）製）等を用いることができる。
The hydroxypropylmethylcellulose is not particularly limited and may be appropriately selected depending on the intended purpose. From the viewpoint of slow solubility, the substitution degree of the methoxyl group as a substituent is 1.4 to 1.9, The number of moles of substitution of the hydroxypropoxyl group is preferably 0.15 to 0.25. Here, the degree of substitution represents the average number of hydroxyl groups substituted per glucose ring unit of cellulose, and the number of substituted moles represents the average number of substituents added per glucose ring unit of cellulose.
Further, the viscosity of the aqueous hydroxypropyl methylcellulose solution is preferably 100 to 30,000 mPa · s, more preferably 400 to 5,000 mPa · s, as the viscosity of a 2% aqueous solution at 20 ° C.
The viscosity was measured using a BL type viscometer, rotor No. 3. When the measurement is performed at a rotation speed of 30 rpm and is not suitable within the above range, for example, when the viscosity is too high, the rotor No. 4, when the rotational speed is 12 rpm and the viscosity is too low, the rotor No. 2. It can be measured by appropriately selecting the rotor and the rotational speed, such as a rotational speed of 60 rpm.
As a commercial item of the said hydroxypropyl methylcellulose, Metroze (made by Shin-Etsu Chemical Co., Ltd.) etc. can be used, for example.
前記ポリビニルアルコールとしては、特に制限はなく、目的に応じて適宜選択することができるが、例えば、けん化度が７５〜９８ｍｏｌ％であるものが好ましく、８５〜９０ｍｏｌ％であるものがより好ましい。前記けん化度が７５ｍｏｌ％未満であると、溶解性が高くなり、徐溶性が得られないことがあり、９８ｍｏｌ％を超えると、溶解性が著しく低下し、良好な徐溶性が得られないことがある。
また、前記ポリビニルアルコールの重合度としては、１，７００〜３，５００が好ましい。
There is no restriction | limiting in particular as said polyvinyl alcohol, Although it can select suitably according to the objective, For example, what is saponification degree is 75-98 mol%, and what is 85-90 mol% is more preferable. If the degree of saponification is less than 75 mol%, the solubility may be high and the slow solubility may not be obtained. If the degree of saponification exceeds 98 mol%, the solubility may be significantly reduced and a good slow solubility may not be obtained. is there.
Moreover, as a polymerization degree of the said polyvinyl alcohol, 1,700-3,500 are preferable.
（Ｂ）薬剤成分
前記薬剤成分は、前記水徐溶性組成物中において、前記水溶解遅延成分中に均一に分散乃至溶解していることが好ましい。これにより、前記薬剤成分は、前記水徐溶性組成物と接触した流水によって前記水溶解遅延成分とともに徐溶し、前記被洗浄物に対して持続的に作用する。
(B) Drug component It is preferable that the drug component is uniformly dispersed or dissolved in the water dissolution delay component in the water-soluble composition. Thereby, the said chemical | medical agent component dissolves slowly with the said water dissolution delay component with the flowing water which contacted the said water-soluble composition, and it acts on the to-be-cleaned object continuously.
前記薬剤成分としては、特に制限は無く、洗浄、殺菌、防汚、消臭等の目的に応じて適宜選択することができ、例えば、界面活性剤、漂白剤、殺菌剤、抗菌剤、防カビ剤、消臭剤、芳香剤、酵素等が挙げられる。更に、本発明の効果を損なわない範囲で洗浄剤に一般的に使用されるその他の成分、例えば、着色剤、キレート剤、無機塩、有機酸塩などを配合してもよい。
これらは、１種を単独で、又は２種以上を混合して使用することができる。
The drug component is not particularly limited and can be appropriately selected depending on the purpose of washing, sterilization, antifouling, deodorization, etc. For example, surfactant, bleach, bactericidal agent, antibacterial agent, fungicide Agents, deodorants, fragrances, enzymes and the like. Furthermore, you may mix | blend the other components generally used for a washing | cleaning agent, for example, a coloring agent, a chelating agent, inorganic salt, organic acid salt etc. in the range which does not impair the effect of this invention.
These can be used individually by 1 type or in mixture of 2 or more types.
前記界面活性剤としては、例えば、アニオン性界面活性剤、非イオン性界面活性剤、カチオン性界面活性剤、両性界面活性剤が挙げられる。これらは、１種を単独で、又は２種以上を混合して使用することができる。 Examples of the surfactant include an anionic surfactant, a nonionic surfactant, a cationic surfactant, and an amphoteric surfactant. These can be used individually by 1 type or in mixture of 2 or more types.
前記アニオン系界面活性剤としては、例えば、ミリスチン酸、ステアリン酸、パルミチン酸、ベヘニン酸、イソステアリン酸、オレイン酸等の高級脂肪酸塩、アルキル基の炭素数８〜１８のアルキルベンゼンスルホン酸塩、アルカンスルホン酸塩、α−オレフィンスルホン酸塩、アルキル硫酸エステル塩、ポリオキシエチレン（平均付加モル数１〜１０）及びアルキルエーテル硫酸エステル塩を挙げることができ、中でもアルキル基の炭素数１４〜１８のα−オレフィンスルホン酸塩、アルキル基の炭素数１０〜１４のポリオキシエチレン（平均付加モル数１〜５）、アルキル硫酸エステル、アルキル基の炭素数１０〜１５のアルキルベンゼンスルホン酸塩が好ましい。また、上記塩としては、ナトリウム塩又はカリウム塩が好ましい。 Examples of the anionic surfactant include higher fatty acid salts such as myristic acid, stearic acid, palmitic acid, behenic acid, isostearic acid and oleic acid, alkylbenzene sulfonates having 8 to 18 carbon atoms in the alkyl group, and alkanesulfones. And acid salt, α-olefin sulfonate, alkyl sulfate ester salt, polyoxyethylene (average addition mole number 1 to 10) and alkyl ether sulfate ester salt. Among them, α of alkyl group having 14 to 18 carbon atoms. -Preferred are olefin sulfonates, polyoxyethylenes having an alkyl group of 10 to 14 carbon atoms (average addition mole number of 1 to 5), alkyl sulfates, and alkylbenzene sulfonates of an alkyl group having 10 to 15 carbon atoms. Moreover, as said salt, a sodium salt or potassium salt is preferable.
前記非イオン性界面活性剤としては、例えば、ポリオキシエチレンアルキルエーテル、脂肪酸アルカノールアミド、ソルビタン脂肪酸エステル、ポリオキシエチレン脂肪酸エステル、アルキルポリグリコシド、脂肪酸グリコシドエステル、脂肪酸メチルグリコシドエステル、及びアルキルメチルグルカミド等を挙げることができ、中でもアルキル基の炭素数が８〜１２であり、ポリオキシエチレン平均付加モル数が５〜４０のポリオキシエチレンアルキルエーテルが好ましい。 Examples of the nonionic surfactant include polyoxyethylene alkyl ether, fatty acid alkanolamide, sorbitan fatty acid ester, polyoxyethylene fatty acid ester, alkyl polyglycoside, fatty acid glycoside ester, fatty acid methyl glycoside ester, and alkyl methyl glucamide. Among them, a polyoxyethylene alkyl ether having an alkyl group with 8 to 12 carbon atoms and a polyoxyethylene average addition mole number of 5 to 40 is preferable.
前記カチオン性界面活性剤としては、例えば、アルキルトリメチルアンモニウム塩、ジアルキルジメチルアンモニウム塩、アルキルベンジルアンモニウム塩、塩化ベンゼトニウム等の第４級アンモニウム塩、アルキルピリニジウム塩、及びアルキルイミダゾリニウム塩などを挙げることができ、中でもアルキル基の炭素数が８〜１２のジアルキルジメチルアンモニウム塩が防汚効果の点から好ましい。また、対陰イオンとしては、ハロゲンイオン又は炭素数１〜３のアルキル硫酸イオンが好ましい。 Examples of the cationic surfactant include alkyl trimethyl ammonium salts, dialkyl dimethyl ammonium salts, alkyl benzyl ammonium salts, quaternary ammonium salts such as benzethonium chloride, alkyl pyrinidium salts, and alkyl imidazolinium salts. Among them, a dialkyldimethylammonium salt having an alkyl group having 8 to 12 carbon atoms is preferable from the viewpoint of the antifouling effect. Moreover, as a counter anion, a halogen ion or a C1-C3 alkyl sulfate ion is preferable.
前記両性界面活性剤としては、例えば、アルキルカルボベタイン、アルキルスルホベタイン、アルキルヒドロキシスルホベタイン、アルキルアミドヒドロキシスルホベタイン、アルキルアミドアミン型ベタイン、及びアルキルイミダゾリン型ベタインなどが挙げられる。 Examples of the amphoteric surfactant include alkylcarbobetaines, alkylsulfobetaines, alkylhydroxysulfobetaines, alkylamidohydroxysulfobetaines, alkylamidoamine-type betaines, and alkylimidazoline-type betaines.
なお、上記界面活性剤としては、特に制限はなく、目的に応じて適宜選択することができるが、高い洗浄効果および起泡性による洗浄実感を得るためには、アニオン性界面活性剤、非イオン性界面活性剤、両性界面活性剤を用いることが好ましく、また、持続的な防汚効果を得るためにはカチオン性活性剤を用いることが好ましい。 The surfactant is not particularly limited and may be appropriately selected depending on the purpose. However, in order to obtain a high cleaning effect and a feeling of cleaning due to foaming properties, anionic surfactants, nonionic surfactants It is preferable to use an ionic surfactant or an amphoteric surfactant. In order to obtain a continuous antifouling effect, it is preferable to use a cationic surfactant.
前記漂白剤としては、特に制限はなく、目的に応じて適宜選択することができるが、例えば、次亜塩素酸カルシウム等の次亜塩素酸塩；亜塩素酸ナトリウム等の亜塩素酸塩；トリクロロイソシアヌル酸等のハロゲン化シアヌル酸；ジクロロイソシアヌル酸ナトリウム、ジクロロイソシアヌル酸カリウム等のハロゲン化シアヌル酸塩；１，３−ジクロロ−５，５−ジメチルヒダントイン、１，３−ジブロモ−５，５−ジメチルヒダントイン、１，３−ジクロロ−５−メチル−５−エチルヒダントイン、１，３−ジブロモ−５−メチル−５−エチルヒダントイン等のハロゲン化ヒダントイン；などが好ましく、これらの中でも、トリクロロイソシアヌル酸、ジクロロイソシアヌル酸ナトリウム、ジクロロイソシアヌル酸カリウム、１，３−ジクロロ−５，５−ジメチルヒダントイン、１，３−ジブロモ−５，５−ジメチルヒダントインがより好ましい。これらは、１種を単独で、又は２種以上を混合して使用することができる。 The bleaching agent is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include hypochlorites such as calcium hypochlorite; chlorites such as sodium chlorite; trichloro Halogenated cyanuric acid such as isocyanuric acid; Halogenated cyanuric acid salts such as sodium dichloroisocyanurate and potassium dichloroisocyanurate; 1,3-dichloro-5,5-dimethylhydantoin, 1,3-dibromo-5,5-dimethyl Preferred are halogenated hydantoins such as hydantoin, 1,3-dichloro-5-methyl-5-ethylhydantoin, and 1,3-dibromo-5-methyl-5-ethylhydantoin; among these, trichloroisocyanuric acid, dichloro Sodium isocyanurate, potassium dichloroisocyanurate, 1,3-dichloro 5,5, more preferably 1,3-dibromo-5,5-dimethylhydantoin. These can be used individually by 1 type or in mixture of 2 or more types.
前記殺菌剤としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、１，２−ベンゾイソチアゾリン−３−オン、トリクロロカルバニリド、及び塩化ベンゼトニウム等の四級アンモニウム塩などが挙げられる。 The bactericide is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include quaternary ammonium salts such as 1,2-benzisothiazolin-3-one, trichlorocarbanilide, and benzethonium chloride. Is mentioned.
前記防カビ剤としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、チアベンダゾール、有機ヨウ素系化合物、及び安息香酸ナトリウムなどが挙げられる。 There is no restriction | limiting in particular as said antifungal agent, According to the objective, it can select suitably, For example, a thiabendazole, an organic iodine type compound, sodium benzoate, etc. are mentioned.
前記消臭剤としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、植物抽出物、有機化合物、及び無機化合物から選ばれる１種又は２種以上の消臭成分を使用することができる。具体的には、水酸化ナトリウム、水酸化カリウム、水酸化カルシウム、炭酸ナトリウム、炭酸水素ナトリウム、硫酸、塩酸、燐酸、スルファミン酸、シュウ酸、ソルビン酸、フミン酸、アスコルビン酸、リンゴ酸、メチルリンゴ酸、マロン酸、コハク酸、アルケニルコハク酸、グルタル酸、アジピン酸、ピメリン酸、フマル酸、マレイン酸、メチルフマル酸、メチルマレイン酸、イタコン酸、シトラコン酸、メサコン酸、アセチレン酸、クエン酸、イソクエン酸、グリコール酸、酒石酸、木酢、次亜塩素酸塩、二酸化塩素、塩素、過酸化水素、過酸化物、過マンガン酸カリウム、ホルマリン、グリオキサール、重亜硫酸ナトリウム、亜硫酸ナトリウム、硫酸第一鉄、塩化第二鉄、ジヒドロキシ−アセトン、３，５，５−トリメチルヘキサノール、β−エトキシプロピオンアルデヒド、グルタロアルデヒド、メタアクリル酸エステル、マレイン酸エステル、マレイン酸モノエステル、マレイン酸モノアミド、マレイン酸イミド、フマル酸ジアルキル、フマル酸エステル、β−アシルアクリル酸、β−アシルアクリル酸塩、セネシオン酸シトロネリル、１，３−ペンタジエン−１−カルボン酸アルキルエステル、ピナンハイドロパーオキサイド、ｐ−サイメンパーオキサイド、１，２−プロピレンオキサイド、１，２−ブチレンオキサイド、グリシジルエーテル、β−シクロデキストリン、ヒドロキシプロピルシクロデキストリン、オクタアセチルサッカロース、Ｆｅ（ＩＩＩ）−オクタカルボキシフタロシアニン、Ｆｅ（ＩＩＩ）−テトラカルボキシフタロシアニン、５−メチル−２−イソプロピル−２−ヘキセナール、オイゲノール、ｐ−ブトキシフェノール、カテコール、ハイドロキノン、４−メチルカテコール、１，２，４−トリハイドロキシベンゼン、３−メチルカテコール、３−メトキシカテコール、没食子酸、カルノソール、ロズマノール、ブラジリン、ヘマトキシリン、シコニン、ミリセチン、バイカレイン、バイカリン、フラボノイド、タンニン、シトラール、バニリン、クマリン、マツ科植物の抽出物、モクセイ科植物の抽出物、シソエキス、茶エキス、柿抽出エキス、及び亜鉛化合物（酸化亜鉛、硫酸亜鉛、塩化亜鉛、リン酸亜鉛、硝酸亜鉛、炭酸亜鉛、酢酸亜鉛、シュウ酸亜鉛、クエン酸亜鉛、フマル酸亜鉛、ギ酸亜鉛、乳酸亜鉛、グルコン酸亜鉛、リシノール酸亜鉛等）などが挙げられる。
また、植物抽出物消臭剤の市販品として、「ピュリエール」（松下電工（株）製）、「スメラル」（環境科学開発（株）製）、「パンシル」（リリース科学工業（株）製）を用いることができる。
これらは、１種を単独で、又は２種以上を混合して使用することができる。
There is no restriction | limiting in particular as said deodorizer, According to the objective, it can select suitably, For example, 1 type, or 2 or more types of deodorizing components chosen from a plant extract, an organic compound, and an inorganic compound are used. can do. Specifically, sodium hydroxide, potassium hydroxide, calcium hydroxide, sodium carbonate, sodium bicarbonate, sulfuric acid, hydrochloric acid, phosphoric acid, sulfamic acid, oxalic acid, sorbic acid, humic acid, ascorbic acid, malic acid, methyl apple Acid, malonic acid, succinic acid, alkenyl succinic acid, glutaric acid, adipic acid, pimelic acid, fumaric acid, maleic acid, methyl fumaric acid, methyl maleic acid, itaconic acid, citraconic acid, mesaconic acid, acetylenic acid, citric acid, isocitrate Acid, glycolic acid, tartaric acid, wood vinegar, hypochlorite, chlorine dioxide, chlorine, hydrogen peroxide, peroxide, potassium permanganate, formalin, glyoxal, sodium bisulfite, sodium sulfite, ferrous sulfate, chloride Ferric, dihydroxy-acetone, 3,5,5-trimethylhexano , Β-ethoxypropionaldehyde, glutaraldehyde, methacrylic ester, maleic ester, maleic monoester, maleic monoamide, maleic imide, dialkyl fumarate, fumaric ester, β-acyl acrylic acid, β-acyl Acrylate, citronellyl senesioate, 1,3-pentadiene-1-carboxylic acid alkyl ester, pinane hydroperoxide, p-cymene peroxide, 1,2-propylene oxide, 1,2-butylene oxide, glycidyl ether, β -Cyclodextrin, hydroxypropyl cyclodextrin, octaacetyl saccharose, Fe (III) -octacarboxyphthalocyanine, Fe (III) -tetracarboxyphthalocyanine, 5-methyl-2-y Sopropyl-2-hexenal, eugenol, p-butoxyphenol, catechol, hydroquinone, 4-methylcatechol, 1,2,4-trihydroxybenzene, 3-methylcatechol, 3-methoxycatechol, gallic acid, carnosol, rosmanol, bradylin , Hematoxylin, shikonin, myricetin, baicalein, baicalin, flavonoid, tannin, citral, vanillin, coumarin, pine family plant extract, oleaceae plant extract, perilla extract, tea extract, persimmon extract, and zinc compounds (zinc oxide Zinc sulfate, zinc chloride, zinc phosphate, zinc nitrate, zinc carbonate, zinc acetate, zinc oxalate, zinc citrate, zinc fumarate, zinc formate, zinc lactate, zinc gluconate, zinc ricinoleate, etc.) It is done.
In addition, as a commercial product of plant extract deodorant, “Purier” (manufactured by Matsushita Electric Works), “Smeral” (manufactured by Environmental Science Development Co., Ltd.), “Pancil” (manufactured by Release Science Industrial Co., Ltd.) Can be used.
These can be used individually by 1 type or in mixture of 2 or more types.
前記芳香剤としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、天然植物精油、動物性香料、合成香料等の香料などが挙げられ、具体的には、特開２００２−１４６３９９号公報の表１１〜１８に記載の香料成分Ａ〜Ｄが挙げられる。 There is no restriction | limiting in particular as said fragrance | flavor, According to the objective, it can select suitably, For example, natural plant essential oil, animal fragrance | flavor, a fragrance | flavor, etc. are mentioned, Specifically, Unexamined-Japanese-Patent No. 2002 The fragrance | flavor component AD of Tables 11-18 of -146399 gazette is mentioned.
前記無機塩としては、特に制限は無く、目的に応じて適宜選択することができ、例えば、硫酸ナトリウム、塩化ナトリウム、パラトルエンスルホン酸ナトリウム、酢酸ナトリウム、及び硫酸マグネシウムなどが挙げられ、これらの中でも、硫酸ナトリウム、塩化ナトリウム、及び硫酸マグネシウムが好ましく、硫酸ナトリウムがより好ましい。 The inorganic salt is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include sodium sulfate, sodium chloride, sodium paratoluenesulfonate, sodium acetate, and magnesium sulfate. Among these, Sodium sulfate, sodium chloride, and magnesium sulfate are preferable, and sodium sulfate is more preferable.
前記着色剤は、前記水徐溶性組成物の残留量の確認を容易にするために、また前記水徐溶性組成物に清涼感や衛生感を付与するために、前記水徐溶性組成物中に０．００１〜５質量％含有させることが好ましい。
前記着色剤としては、特に制限は無く、目的に応じて適宜選択することができ、顔料、及び染料のいずれでもよいが、具体的には、メチレンブルー、シアニンブルー、青色１号、黄色４号、黄色５号、黄色２０２号、赤色１０６号、及び緑色３号などの水溶性色素が好ましい。
The colorant is contained in the water-slowly soluble composition in order to facilitate the confirmation of the residual amount of the water-slowly soluble composition, and to give a refreshing feeling and hygiene to the water-slowly soluble composition. It is preferable to contain 0.001-5 mass%.
The colorant is not particularly limited and may be appropriately selected depending on the purpose, and may be any of a pigment and a dye. Specifically, methylene blue, cyanine blue, blue No. 1, yellow No. 4, Water-soluble dyes such as yellow No. 5, yellow No. 202, red No. 106, and green No. 3 are preferred.
前記酵素としては、例えば、タンパク汚れを分解するためのプロテアーゼ等のタンパク質分解酵素が挙げられる。
前記キレート剤としては、例えば、グルコン酸ソーダ、ＥＤＴＡ、ＮＴＡ等が挙げられる。
Examples of the enzyme include a proteolytic enzyme such as a protease for decomposing protein soil.
Examples of the chelating agent include sodium gluconate, EDTA, NTA and the like.
（Ｃ）溶媒
前記溶媒としては、水（例えば、精製水、蒸留水、イオン交換水、純水、及び超純水等）が好ましく、更に、炭素数１〜４のアルコール、炭素数２〜８のジオール、炭素数３〜８のポリオール、及びエアゾール噴射剤から選択される少なくとも１種を含んでいてもよい。
前記炭素数１〜４のアルコールとしては、例えば、メタノール、エタノール、プロパノール、ブタノール等が挙げられる。
前記炭素数２〜８のジオールとしては、例えば、エチレングリコール、プロピレングリコール、ブチレングリコール、へキシレングリコール等が挙げられる。
前記炭素数３〜８のポリオールとしては、例えば、グリセリン、トリメチロールプロパン、ソルビトール、アルキルグリセリルエーテル等が挙げられる。
前記エアゾール噴射剤としては、例えば、液化石油ガス（ＬＰＧ）、ジメチルエーテル（ＤＭＥ）等が挙げられる。
これらの中でも、使用時の操作性及び安全性の観点から、エタノール、イソプロパノール、ＬＰＧ、ＤＭＥ、及びＬＰＧとＤＭＥとの混合溶媒が好ましい。
(C) Solvent As said solvent, water (For example, purified water, distilled water, ion-exchange water, pure water, ultrapure water, etc.) is preferable, Furthermore, C1-C4 alcohol, C2-C8 And at least one selected from polyols having 3 to 8 carbon atoms, and aerosol propellants.
Examples of the alcohol having 1 to 4 carbon atoms include methanol, ethanol, propanol, butanol and the like.
Examples of the diol having 2 to 8 carbon atoms include ethylene glycol, propylene glycol, butylene glycol, hexylene glycol and the like.
Examples of the polyol having 3 to 8 carbon atoms include glycerin, trimethylolpropane, sorbitol, alkyl glyceryl ether and the like.
Examples of the aerosol propellant include liquefied petroleum gas (LPG) and dimethyl ether (DME).
Among these, ethanol, isopropanol, LPG, DME, and a mixed solvent of LPG and DME are preferable from the viewpoints of operability and safety during use.
前記水徐溶性組成物の処方としては、前記水溶解遅延成分１〜３０質量％、前記薬剤成分１〜５０質量％、及び前記溶媒２０〜９８質量％が好ましい。
前記水溶解遅延成分の含有量が、１質量％未満であると、十分な粘着性が得られず、塗布面が傾斜面である場合等、流水により流失してしまうことがあり、３０質量％を超えると、流動性が低くなり、塗布が困難となる場合がある。
前記薬剤成分の含有量が、１質量％未満であると、十分な洗浄効果及び防汚効果が得られないことがあり、５０質量％を超えると、他の成分の含有量が減少することにより、均一に分散乃至溶解させることが困難となることがある。
前記水徐溶性組成物の処方は、上記の範囲内であれば、使用目的に応じて適宜調整することができ、例えば、高い洗浄効果を得るための処方としては、前記水溶解遅延成分１〜２０質量％、前記薬剤成分２〜５０質量％、前記溶媒３０〜９７質量％が好ましく、前記水溶解遅延成分５〜１５質量％、前記薬剤成分５〜３０質量％、前記溶媒５５〜９０質量％がより好ましい。また、持続的な防汚効果を得るための処方としては、前記水溶解遅延成分５〜３０質量％、前記薬剤成分１〜１０質量％、前記溶媒６０〜９４質量％がより好ましく、前記水溶解遅延成分１０〜２０質量％、前記薬剤成分２〜５質量％、前記溶媒７５〜８８質量％がより好ましい。
The prescription of the water-soluble composition is preferably 1-30% by mass of the water dissolution delay component, 1-50% by mass of the drug component, and 20-98% by mass of the solvent.
When the content of the water dissolution retarding component is less than 1% by mass, sufficient tackiness cannot be obtained, and the coated surface may be washed away by flowing water. If it exceeds 1, the fluidity will be low and application may be difficult.
When the content of the drug component is less than 1% by mass, a sufficient cleaning effect and antifouling effect may not be obtained. When the content exceeds 50% by mass, the content of other components decreases. It may be difficult to uniformly disperse or dissolve.
The formulation of the water-soluble composition can be appropriately adjusted depending on the purpose of use within the above range. For example, as a formulation for obtaining a high cleaning effect, the water dissolution delay component 1 to 20% by mass, 2 to 50% by mass of the drug component, and 30 to 97% by mass of the solvent are preferable, 5 to 15% by mass of the water dissolution delay component, 5 to 30% by mass of the drug component, and 55 to 90% by mass of the solvent. Is more preferable. The prescription for obtaining a continuous antifouling effect is more preferably 5-30% by mass of the water dissolution delay component, 1-10% by mass of the drug component, and 60-94% by mass of the solvent. More preferably, the delay component is 10 to 20 mass%, the drug component is 2 to 5 mass%, and the solvent is 75 to 88 mass%.
本発明の水徐溶性組成物の製法としては、特に制限はなく、常法に準じて調製することができる。調製する装置としては、例えば、剪断力の付与及び全体混合ができる複数の攪拌羽根、例えば、プロペラ、タービン、ディスパーなどを備えた攪拌装置などが挙げられ、アジホモミキサー、逆流ミキサー、ハイブロッドミキサーなどが好適に挙げられる。 There is no restriction | limiting in particular as a manufacturing method of the water-soluble composition of this invention, It can prepare according to a conventional method. Examples of the device to be prepared include a plurality of stirring blades capable of applying shear force and mixing the whole, for example, a stirring device equipped with a propeller, a turbine, a disper, and the like. Etc. are preferable.
本発明の水徐溶性組成物の剤型としては、０〜４０℃において流動性を有するものであれば、特に制限はなく、目的に応じて適宜選択することができ、例えば、液状（水溶液状、水分散液状）、ゲル状、ゾル状、ペースト状等が挙げられる。また、前記水徐溶性組成物を、吸湿性を有する任意の支持体に含有させてシート状としてもよく、加熱してシート状に成形してもよい。前記支持体としては、例えば、不織布、織布、編布、紙、及びフィルムなどが挙げられる。 The dosage form of the water-slowly soluble composition of the present invention is not particularly limited as long as it has fluidity at 0 to 40 ° C., and can be appropriately selected according to the purpose. , Water dispersion liquid), gel, sol, paste and the like. In addition, the water-slowly soluble composition may be contained in any hygroscopic support to form a sheet, or heated to be formed into a sheet. Examples of the support include nonwoven fabric, woven fabric, knitted fabric, paper, and film.
本発明の水徐溶性組成物は、通常の容器に充填することができる。前記容器としては、例えば、アルミニウムラミネートチューブ、ＥＶＡＬチューブ、アルミチューブ、ガラス蒸着プラスチックチューブ等のチューブ、機械的又は差圧によるディスペンサー容器、エアゾール容器、トリガー容器、スクイーズ容器、ラミネートフィルム容器、スポイト容器、スティック容器、ジャー容器、ボトル容器などが挙げられる。前記ラミネートフィルム容器の材質は、ポリエチレン、ポリエチレンテレフタレート、ポリエステル、二軸延伸ポリプロピレン、無延伸ポリプロピレン、ポリアクリロニトリル、及びエチレン酢酸ビニル共重合体等の合成樹脂、紙、アルミ蒸着プラスチック等から適宜選択される。また、前記ラミネートフィルム容器の構造は、強度、柔軟性、耐候性等を考慮し、２〜５層構造とすることが好ましい。前記ボトル容器の材質は、ポリエチレン、ポリプロピレン、ポリエチレンテレフタレート、ポリスチレン、ポリ塩化ビニル、エチレン−ビニルアルコール樹脂、アクリロニトリル−スチレン樹脂、ＡＢＳ樹脂、ポリアミド等の樹脂容器、及びガラス容器から適宜選択される。また、前記ボトル容器の構造は、単層又は２層以上の層構造とすることが好ましい。 The water-soluble composition of the present invention can be filled in a normal container. Examples of the containers include aluminum laminated tubes, EVAL tubes, aluminum tubes, glass-deposited plastic tubes, dispenser containers by mechanical or differential pressure, aerosol containers, trigger containers, squeeze containers, laminate film containers, dropper containers, A stick container, a jar container, a bottle container, etc. are mentioned. The material of the laminated film container is appropriately selected from polyethylene, polyethylene terephthalate, polyester, biaxially stretched polypropylene, unstretched polypropylene, polyacrylonitrile, synthetic resin such as ethylene vinyl acetate copolymer, paper, aluminum vapor deposited plastic, and the like. . The laminate film container preferably has a 2-5 layer structure in consideration of strength, flexibility, weather resistance and the like. The material of the bottle container is appropriately selected from polyethylene, polypropylene, polyethylene terephthalate, polystyrene, polyvinyl chloride, ethylene-vinyl alcohol resin, acrylonitrile-styrene resin, ABS resin, polyamide resin container, and glass container. Further, the bottle container preferably has a single layer structure or a layer structure of two or more layers.
（洗浄方法）
本発明の水徐溶性組成物を用いた洗浄方法は、前記水徐溶性組成物を、被洗浄物の表面であって、流水と接触する面に塗布し、該流水により前記水徐溶性組成物を徐溶させて、前記被洗浄物を洗浄する方法である。前記水徐溶性組成物中に配合した前記薬剤成分に応じて、洗浄、殺菌、防汚、消臭等の効果が得られる。
(Cleaning method)
In the cleaning method using the water-slowly soluble composition of the present invention, the water-slowly soluble composition is applied to the surface of the object to be cleaned and in contact with the flowing water, and the water-slowly soluble composition is applied by the flowing water. Is a method in which the object to be cleaned is cleaned. Effects such as washing, sterilization, antifouling, and deodorizing can be obtained according to the drug component blended in the water-soluble composition.
前記水徐溶性組成物の塗布方法としては、特に制限は無く、目的に応じて適宜選択することができるが、例えば、（１）チューブ容器に充填された前記水徐溶性組成物を、チューブ容器から適量押し出して直接被洗浄物表面に塗布する方法、（２）前記水徐溶性組成物を任意の塗布用具（スパチュラ、たわし、ブラシ、スポンジ等）にとり、被洗浄物表面に塗布する方法、及び（３）トリガー容器やエアゾール容器等のスプレーヤーに充填された前記水徐溶性組成物を、直接面被洗浄物表面に噴射して塗布する方法等が挙げられる。 There is no restriction | limiting in particular as the application | coating method of the said water-soluble composition, According to the objective, it can select suitably, For example, (1) The said water-soluble composition filled in the tube container is made into a tube container. A method of extruding a proper amount directly from the surface of the object to be cleaned, (2) a method of applying the water-dissolving composition to an arbitrary application tool (spatula, scrubber, brush, sponge, etc.) (3) A method in which the water-slowly soluble composition filled in a sprayer such as a trigger container or an aerosol container is directly sprayed onto the surface of the surface to be cleaned and applied.
前記水徐溶性組成物は、被洗浄物の表面に塗布した後１分間〜６時間、流水と接触させずに放置することにより、溶媒成分を蒸発させて粘着性を向上させてもよい。 The water-slowly soluble composition may be allowed to evaporate the solvent component for 1 minute to 6 hours after being applied to the surface of the object to be cleaned, without leaving it in contact with running water, thereby improving the adhesiveness.
前記被洗浄物としては、流水と接触する面を有し、該流水により前記水徐溶性組成物が徐溶し、洗浄されるものであれば、特に制限はないが、例えば、水洗便器、台所や洗面台等のシンク表面及び排水口、浴室の排水口、排水管、ストレーナー、三角コーナーなどが挙げられる。 The object to be cleaned is not particularly limited as long as it has a surface in contact with running water, and the water-soluble composition is gradually dissolved and washed by the running water. And sink surfaces such as sinks and sinks, drains in bathrooms, drains in bathrooms, drain pipes, strainers, and triangular corners.
本発明の水徐溶性組成物は、流水と接触する任意の面に塗布することができ、塗布後流水によって剥離することがなく、該流水により徐溶することによって、持続的に洗浄を行うことができる。また、本発明の水徐溶性組成物を用いた洗浄方法は、前記水徐溶性組成物を、被洗浄物の流水と接触する面に塗布することにより、該流水により前記薬剤成分を含む前記水徐溶性組成物が徐溶するため、持続的に洗浄が行われる。 The water-slowly soluble composition of the present invention can be applied to any surface that comes into contact with running water, and is not peeled off by running water after coating, and is continuously washed by dissolving slowly with running water. Can do. Further, in the cleaning method using the water-slowly soluble composition of the present invention, the water-slowly soluble composition is applied to the surface of the article to be cleaned which is in contact with the flowing water, so that the water containing the drug component is contained in the flowing water. Since the gradually soluble composition dissolves gradually, washing is performed continuously.
以下、本発明の実施例について説明するが、本発明はこの実施例に何ら限定されるものではない。 Hereinafter, although the Example of this invention is described, this invention is not limited to this Example at all.
（試験例）
〔水溶解遅延成分の徐溶性試験〕
前記水溶解遅延成分として、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース、ヒドロキシエチルセルロース、ポリエチレングリコールジステアレート、及びポリビニルアルコールについて、５％分散液又は５％水溶液を調製し、下記の方法により、その徐溶性を調べた。結果を表１に示す。
(Test example)
[Slow solubility test of water dissolution delay component]
Prepare 5% dispersion or 5% aqueous solution of hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, polyethylene glycol distearate, and polyvinyl alcohol as the water dissolution delay component, and gradually dissolve it by the following method. Examined. The results are shown in Table 1.
１０×１０ｃｍ２のステンレス板上に、前記水溶解遅延成分の５％分散液又は５％水溶液６ｇを６×６ｃｍ２に展着させた後、乾燥させ、０．３ｇの皮膜を形成した試験片を調製した。３Ｌビーカー中に用意した２５℃の水２Ｌ中に前記試験片を浸漬し、メカニカルスターラーを用いて１００ｒｐｍで攪拌した。
１０分後、前記試験片を取り出し、室温にて２４時間風乾させて重量を測定し、下記計算式に従い、前記水溶解遅延成分の溶出率（％）を求めた。
Ten minutes later, the test piece was taken out, air-dried at room temperature for 24 hours, weighed, and the elution rate (%) of the water dissolution delay component was determined according to the following formula.
＊２：メトローズ９０ＳＨ−４０００（信越化学工業（株）製）
＊３：ＨＥＣ ＳＥ−９００（ダイセル化学工業（株）製）
＊４：リオノンＤＴ−６００Ｓ（ライオン（株）製）
＊５：クラレポバールＰＶＡ−２３５（クラレ（株）製）
* 2: Metroz 90SH-4000 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 3: HEC SE-900 (manufactured by Daicel Chemical Industries, Ltd.)
* 4: Lionon DT-600S (Lion Corporation)
* 5: Kuraray Poval PVA-235 (manufactured by Kuraray Co., Ltd.)
表１の結果から、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース、ヒドロキシエチルセルロース、ポリエチレングリコールジステアレート、及びポリビニルアルコールは徐溶性を示し、本発明の水徐溶性組成物の水溶解遅延成分として好適であることがわかった。 From the results in Table 1, hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, polyethylene glycol distearate, and polyvinyl alcohol exhibit a slow solubility, and are suitable as a water dissolution delay component of the water slow solubility composition of the present invention. I understood.
（参考例１〜７、比較例１〜３）
下記表２に示す各成分を、１００ｍＬビーカー中で均一になるまでメカニカルスターラーを用いて攪拌した後、常温（２５℃）下に１日静置して水徐溶性組成物を得た。
得られた前記水徐溶性組成物について、下記の方法により、塗布性、粘着性、徐溶性（洗浄持続性）を評価した。結果を表２にあわせて示す。
( Reference Examples 1-7, Comparative Examples 1-3)
Each component shown in Table 2 below was stirred using a mechanical stirrer until uniform in a 100 mL beaker, and then allowed to stand at room temperature (25 ° C.) for 1 day to obtain a water-slowly soluble composition.
About the obtained said water soluble composition, the applicability | paintability, adhesiveness, and slow solubility (washing persistence) were evaluated with the following method. The results are shown in Table 2.
〔塗布性の評価〕
前記水徐溶性組成物６．０ｇをスパチュラにとり、１０×１０ｃｍ２のステンレス板、及び１０×１０ｃｍ２の陶製タイル表面に、それぞれ６×６ｃｍ２となるように塗布して展着させた時の、塗布のしやすさを下記の基準に従い評価した。
−評価基準−
○：塗布しやすい
△：やや塗布しにくい
×：塗布しにくい
[Evaluation of coating properties]
When 6.0 g of the water-slowly soluble composition was taken in a spatula and applied and spread on a 10 × 10 cm 2 stainless steel plate and a 10 × 10 cm 2 ceramic tile surface so as to be 6 × 6 cm 2 , respectively. The ease of application was evaluated according to the following criteria.
-Evaluation criteria-
○: Easy to apply △: Slightly difficult to apply ×: Difficult to apply
〔粘着性及び徐溶性の評価〕
上記塗布性の評価と同様にして各試験片を調製した。前記試験片を４５度の角度に傾斜させた状態で、前記水徐溶性組成物の塗布面に対し、２５℃の水道水を６００ｍＬ／秒の流速で１０秒間流した後、前記水徐溶性組成物の塗布領域の状態を観察し、下記の基準に従い粘着性を評価した。
−評価基準−
○：変化なし
△：流水の方向に沿って塗布領域のズレがみられる
×：流失している
[Evaluation of adhesiveness and slow solubility]
Each test piece was prepared in the same manner as in the evaluation of the coating property. In a state where the test piece is inclined at an angle of 45 degrees, tap water at 25 ° C. is allowed to flow at a flow rate of 600 mL / second for 10 seconds with respect to the application surface of the water-soluble composition, and then the water-soluble composition is obtained. The state of the coated area of the product was observed, and the tackiness was evaluated according to the following criteria.
-Evaluation criteria-
○: No change △: Deviation of the coating area is observed along the direction of running water.
また、前記試験において流水処理後、残存している前記水徐溶性組成物の重量を測定し、下記式から残存率を求め、下記の基準に従い、徐溶性を評価した。
○：残存率が９０％以上
△：残存率が８９〜２１％
×：残存率が２０％以下
In addition, the weight of the water-soluble composition remaining after running water treatment in the test was measured, the residual rate was determined from the following formula, and the slow solubility was evaluated according to the following criteria.
○: Residual rate is 90% or more Δ: Residual rate is 89-21%
X: Residual rate is 20% or less
〔徐溶性（洗浄持続性）の評価〕
前記水徐溶性組成物３．０ｇをスパチュラにとり、１０×１０ｃｍ２の陶製タイル表面に、６×３ｃｍ２となるように塗布して展着させ、さらに塗布領域の１辺の１ｃｍ外側部分に、下記の組成からなるモデル汚垢を３滴（１滴あたり約０．０３ｇ）付着させて試験片を調製した。前記モデル汚垢の付着させた辺が、流水の下流側となるように前記試験片を４５度の角度に傾斜させて設置し、前記水徐溶性組成物の塗布面に対し、２５℃の水道水を６００ｍＬ／秒の流速で１０秒間流した。その後、前記モデル汚垢のみを同様にして付着させ、２５℃の水道水を６００ｍＬ／秒の流速で１０秒間流した。これを繰り返し行い、前記モデル汚垢を洗浄できた回数から、下記の基準に従い、徐溶性（洗浄持続性）を評価した。
−評価基準−
◎：４０回以上
○：３０回以上
△：１０回〜２９回
×：９回以下
[Evaluation of slow solubility (sustainability of washing)]
Take 3.0 g of the water-slowly soluble composition in a spatula and apply and spread it on the surface of a 10 × 10 cm 2 ceramic tile so as to be 6 × 3 cm 2. Further, on the 1 cm outer part of one side of the application region, A test piece was prepared by adhering 3 drops (about 0.03 g per drop) of model soil having the following composition. The test piece is installed at an angle of 45 degrees so that the side to which the model dirt is attached is on the downstream side of running water, and a 25 ° C. tap water is applied to the application surface of the water-soluble composition. Water was allowed to flow for 10 seconds at a flow rate of 600 mL / second. Thereafter, only the model dirt was adhered in the same manner, and 25 ° C. tap water was allowed to flow for 10 seconds at a flow rate of 600 mL / second. This was repeated, and from the number of times that the model soil was washed, the slow solubility (washing durability) was evaluated according to the following criteria.
-Evaluation criteria-
◎: 40 times or more ○: 30 times or more △: 10 times to 29 times ×: 9 times or less
−モデル汚垢の組成−
オレイン酸 ４７．５質量％
トリオレイン ４０．０質量％
Ｎａ２ＣＯ３ ０．２質量％
水 １０．０質量％
メチレンブルー ２．３質量％
-Composition of model dirt-
Oleic acid 47.5% by mass
Triolein 40.0% by mass
Na 2 CO 3 0.2% by mass
10.0% by mass of water
Methylene blue 2.3 mass%
＊２：メトローズ９０ＳＨ−４０００（信越化学工業（株）製）
＊３：ＨＥＣ ＳＥ−９００（ダイセル化学工業（株）製）
＊４：リオノンＤＴ−６００Ｓ（ライオン（株）製）
＊５：クラレポバールＰＶＡ−２３５（クラレ（株）製）
＊６：アロンビスＳ（三晶（株）製）
＊７：ＫＥＬＺＡＮ ＡＳＸＴ（三晶（株）製）
＊８：ポリエチレングリコール、平均分子量１５０〜２００万（和光純薬工業社製）
＊９：リボランＬＢ−４４０（ライオン（株）製）
＊１０：ポリオキシエチレン（ｐ＝５）ラウリルエーテル硫酸ナトリウム
＊１１：ポリオキシエチレンラウリルエーテル（２０Ｅ．Ｏ．）（日本エマルジョン社製）
＊１２：Ｍｉｎｔ Ｏｉｌ（曽田香料社製）
＊１３：エチレンジアミン四酢酸四ナトリウム四水和物（関東化学製）
* 2: Metroz 90SH-4000 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 3: HEC SE-900 (manufactured by Daicel Chemical Industries, Ltd.)
* 4: Lionon DT-600S (Lion Corporation)
* 5: Kuraray Poval PVA-235 (manufactured by Kuraray Co., Ltd.)
* 6: Aronbis S (manufactured by Sanki Co., Ltd.)
* 7: KELZAN ASXT (manufactured by Sanki Co., Ltd.)
* 8: Polyethylene glycol, average molecular weight 1.5-2 million (manufactured by Wako Pure Chemical Industries, Ltd.)
* 9: Ribolan LB-440 (manufactured by Lion Corporation)
* 10: Sodium polyoxyethylene (p = 5) lauryl ether sulfate * 11: Polyoxyethylene lauryl ether (20E.O.) (manufactured by Nippon Emulsion)
* 12: Mint Oil (manufactured by Iwata Inc.)
* 13: Ethylenediaminetetraacetic acid tetrasodium tetrahydrate (manufactured by Kanto Chemical)
（参考例８〜１２、比較例４〜６）
下記表３に示す各成分を、１００ｍＬビーカー中で均一になるまでメカニカルスターラーを用いて攪拌した後、常温（２５℃）下に１日静置して水徐溶性組成物を得た。
得られた前記水徐溶性組成物について、参考例１と同様にして、塗布性、粘着性及び徐溶性を評価し、下記の方法により流水耐性及び殺菌持続性を評価した。結果を表３にあわせて示す。
( Reference Examples 8-12, Comparative Examples 4-6)
Each component shown in Table 3 below was stirred using a mechanical stirrer until uniform in a 100 mL beaker, and then allowed to stand at room temperature (25 ° C.) for 1 day to obtain a water-slowly soluble composition.
About the obtained said water-slowly-soluble composition, it carried out similarly to the reference example 1, and evaluated applicability | paintability, adhesiveness, and slow-solubility, and evaluated flowing water tolerance and bactericidal persistence with the following method. The results are shown in Table 3.
〔流水耐性及び殺菌持続性の評価〕
前記水徐溶性組成物１０．０ｇを、一般家庭（４人家族）の浴室の排水口縁部に塗布した。浴室を通常通りに使用し、前記水徐溶性組成物が残存した日数を計測し、下記の基準に従い、流水耐性を評価し、さらに、７日目に排水口の状態を観察し、殺菌持続性を評価した。
−流水耐性評価基準−
◎：１０日以上
○：５日以上
△：１日以上
×：１日未満
−殺菌持続性評価基準−
○：ぬめりや悪臭がない
×：ぬめりや悪臭がある
[Evaluation of running water resistance and sterilization durability]
10.0 g of the water-slow-soluble composition was applied to the drain outlet edge of the bathroom of a general household (family of 4). Use the bathroom as usual, measure the number of days that the water-dissolving composition remains, evaluate the resistance to running water according to the following criteria, and observe the state of the drainage outlet on the 7th day, sterilization sustainability Evaluated.
-Evaluation criteria for running water resistance-
◎: 10 days or more ○: 5 days or more △: 1 day or more ×: less than 1 day-Bactericidal durability evaluation criteria-
○: There is no slimy or bad odor ×: There is slimy or bad odor
＊１４：ライオン（株）製、ジデシルジメチルアンモニウムクロリド
＊１５：関東化学製（１．０質量％水溶液）
表２及び３の結果から、参考例１〜１２の本発明の水徐溶性組成物は、被洗浄物としてステンレス、陶製タイルに塗布が容易であり、良好な粘着性及び徐溶性を示し、持続的な洗浄効果、抗菌効果を示すことがわかった。一方、比較例１〜６の洗浄剤組成物は、水溶解遅延成分として配合した高分子化合物が、粘着性を示さず、さらに曳糸性を有するため塗布性が悪化し、徐溶性も劣るため、洗浄持続性や殺菌持続性が得られないことがわかった。 From the results of Tables 2 and 3, the water-slowly soluble compositions of the present invention of Reference Examples 1 to 12 can be easily applied to stainless steel and ceramic tiles as objects to be cleaned, exhibit good adhesiveness and slow solubility, and are sustained. It has been found that it exhibits effective cleaning and antibacterial effects. On the other hand, in the detergent compositions of Comparative Examples 1 to 6, the polymer compound blended as a water dissolution delay component does not exhibit tackiness, and further has spinnability, so that applicability is deteriorated and slow solubility is also inferior. As a result, it was found that the cleaning durability and the sterilization durability could not be obtained.
（参考例１３、実施例１４、比較例７、８）
下記表４に示す各成分を、エアゾール容器（内容量１００ｍＬ）内に配合・混合し、軽く振とうした後、常温にて一日放置した。得られた前記水徐溶性組成物について、下記の方法により吐出性、粘着性及び徐溶性、徐溶性（洗浄持続性）を評価した。結果を表４にあわせて示す。
( Reference Example 13, Example 14, Comparative Examples 7 and 8)
Each component shown in Table 4 below was blended and mixed in an aerosol container (with an internal volume of 100 mL), shaken lightly, and then allowed to stand at room temperature for one day. About the obtained said water-slowly-soluble composition, discharge property, adhesiveness and slow-solubility, and slow-solubility (washing persistence) were evaluated by the following method. The results are shown in Table 4.
〔吐出性の評価〕
前記水徐溶性組成物を、１０×１０ｃｍ２の陶製タイル表面に、６×３ｃｍ２となるように３秒間プッシュして吐出させた時の吐出性を、下記評価基準により評価した。
評価基準
○：簡単に吐出できた。
△：はじめは吐出できたが、途中でつまりが生じた。
×：吐出できない。
(Evaluation of ejection properties)
The discharge property when the water-slowly soluble composition was discharged onto a 10 × 10 cm 2 ceramic tile surface by pushing for 3 seconds to be 6 × 3 cm 2 was evaluated according to the following evaluation criteria.
Evaluation criteria ○: Easily discharged.
Δ: Ejection was possible at the beginning, but clogging occurred midway.
X: Cannot be discharged.
〔粘着性および徐溶性の評価〕
上記吐出性の評価と同様にして各試験片を調製し、乾燥させた。前記試験片を４５度の角度に傾斜させた状態で、前記水徐溶性組成物の塗布面に対し、２５℃の水道水を６００ｍＬ／秒の流速で１０秒間流した後、前記水徐溶性組成物の塗布領域の状態を観察し、下記の基準にしたがい、粘着性を評価した。
―評価基準―
○：変化なし
△：流出部分が見られる
×：全て流出している
また、前記試験において流水処理後、残存している前記水徐溶性組成物の重量を測定し、下記式から残存率を求め、下記基準に従い、徐溶性を評価した。
残存率（％）＝（流水処理後の試験片重量（ｇ））／（流水処理前の試験片重量（ｇ））×１００
―評価基準―
○：残存率が９０％以上
△：残存率が８９〜２１％
×：残存率が２０％以下
[Evaluation of adhesiveness and slow solubility]
Each test piece was prepared and dried in the same manner as in the evaluation of the dischargeability. In a state where the test piece is inclined at an angle of 45 degrees, tap water at 25 ° C. is allowed to flow at a flow rate of 600 mL / second for 10 seconds with respect to the application surface of the water-soluble composition, and then the water-soluble composition is obtained. The state of the coated area of the product was observed, and the tackiness was evaluated according to the following criteria.
-Evaluation criteria-
○: No change △: Outflow portion is observed ×: All outflow is observed Further, after treatment with running water in the test, the weight of the water-soluble composition remaining is measured, and the residual ratio is obtained from the following formula. The slow solubility was evaluated according to the following criteria.
Residual rate (%) = (weight of test piece after running water treatment (g)) / (weight of test piece before running water treatment (g)) × 100
-Evaluation criteria-
○: Residual rate is 90% or more Δ: Residual rate is 89-21%
X: Residual rate is 20% or less
〔徐溶性（洗浄持続性）の評価〕
上記吐出性の評価と同様にして各試験片を調製し、乾燥させた。塗布領域の一辺の１ｃｍ外側部分に、前記モデル汚垢を３滴（１滴あたり約０．０３ｇ）付着させて試験片を調製した。前記モデル汚垢を付着させた辺が、流水の下流側となるように前記試験片を４５度の角度に傾斜させて設置し、前記水徐溶性組成物の塗布面に対し、２５℃の水道水を６００ｍL／秒の流速で１０秒間流した。その後、前記モデル汚垢のみを同様にして付着させ、２５℃の水道水を６００ｍL／秒の流速で１０秒間流した。これを繰り返し行い、前記モデル汚垢を洗浄できた回数から、下記の基準に従い、徐溶性（洗浄持続性）を評価した。
−評価基準−
○：３０回以上
△：１０〜２９回
×：９回以下
[Evaluation of slow solubility (sustainability of washing)]
Each test piece was prepared and dried in the same manner as in the evaluation of the dischargeability. A test piece was prepared by adhering 3 drops (about 0.03 g per drop) of the model dirt to a 1 cm outer portion on one side of the coating area. The test piece was installed at an angle of 45 degrees so that the side to which the model dirt was adhered was on the downstream side of running water, and a 25 ° C. tap water was applied to the application surface of the water-soluble composition. Water was allowed to flow for 10 seconds at a flow rate of 600 mL / second. Thereafter, only the model dirt was adhered in the same manner, and 25 ° C. tap water was allowed to flow for 10 seconds at a flow rate of 600 mL / second. This was repeated, and from the number of times that the model soil was washed, the slow solubility (washing durability) was evaluated according to the following criteria.
-Evaluation criteria-
○: 30 times or more Δ: 10 to 29 times ×: 9 times or less
＊１７：アシッドブルー９ １．０質量％水溶液（東京化成（株）製）
＊４、＊７〜＊９、＊１２：表２と同様
* 17: Acid Blue 9 1.0 mass% aqueous solution (manufactured by Tokyo Chemical Industry Co., Ltd.)
* 4, * 7 to * 9, * 12: Same as Table 2
本発明の水徐溶性組成物は、流水と接触する任意の面に塗布することができ、塗布後流水によって剥離することがなく、該流水により徐溶して前記水徐溶性組成物中の薬剤成分が徐々に放出されることにより、持続的に洗浄を行うことができるため、水洗便器、台所や洗面台のシンク及び排水口、浴室の排水口等の水回りの洗浄剤組成物等として好適である。また、本発明の水徐溶性組成物を用いた洗浄方法は、前記水徐溶性組成物を、被洗浄物の流水と接触する面に塗布することにより、該流水により前記水徐溶性組成物が徐溶し、持続的に洗浄効果が得られるため、水洗便器、台所や洗面台のシンク及び排水口、浴室の排水口等の水回りに対し、容易に、持続的な洗浄、殺菌、防汚、消臭効果等を付与することができる。
The water-slowly soluble composition of the present invention can be applied to any surface that is in contact with running water, and is not peeled off by running water after coating. Since the components are gradually released, it can be washed continuously, so it is suitable as a cleaning composition for water around toilets, sinks and drains in kitchens and washstands, drains in bathrooms, etc. It is. Further, in the cleaning method using the water-slowly soluble composition of the present invention, the water-slowly soluble composition is applied to the surface of the article to be cleaned that is in contact with the flowing water, so Since it dissolves slowly and provides a continuous cleaning effect, it can be easily and continuously cleaned, sterilized, and antifouling for water around toilets, sinks and drains in kitchens and sinks, and bathroom drains. , Deodorizing effect and the like can be imparted.
Claims (6)
前記水溶解遅延成分（Ａ）の含有量が、５質量％〜１５質量％であり、
前記アニオン性界面活性剤（Ｂ）の含有量が、５質量％〜３０質量％であり、
前記溶媒（Ｃ）の含有量が、５５質量％〜９０質量％であり、
前記水溶解遅延成分（Ａ）が、水に膨潤乃至溶解し、
前記水溶解遅延成分（Ａ）の分散液乃至水溶液が、粘着性及び徐溶性を示し、
前記水溶解遅延成分（Ａ）が、ポリオキシエチレン脂肪酸ジエステル、及びポリビニルアルコールから選択される少なくとも１種であることを特徴とするエアゾール用水徐溶性組成物。 Including at least a water dissolution delay component (A), an anionic surfactant (B), and a solvent (C),
The content of the water dissolution delay component (A) is 5 % by mass to 15 % by mass,
The content of the anionic surfactant (B) is 5 % by mass to 30 % by mass,
The content of the solvent (C) is 55 % by mass to 90 % by mass,
The water dissolution delay component (A) swells or dissolves in water,
The dispersion or aqueous solution of the water dissolution delay component (A) exhibits adhesiveness and slow solubility,
The water solution retarding component (A), polyoxyethylene fatty acid di-esters, and aerosol water gradually soluble composition, wherein the at least one selected from polyvinyl alcohol.
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| WO2007141873A1 (en) * | 2006-06-09 | 2007-12-13 | Toto Ltd. | Coating composition and process for producing coating film thereform |
| US7709433B2 (en) * | 2007-02-12 | 2010-05-04 | S.C. Johnson & Son, Inc. | Self-sticking disintegrating block for toilet or urinal |
| WO2009105232A1 (en) * | 2008-02-21 | 2009-08-27 | S. C. Johnson & Son, Inc. | Cleaning composition that provides residual benefits |
| AU2009215861C1 (en) * | 2008-02-21 | 2016-01-21 | S. C. Johnson & Son, Inc. | Cleaning composition having high self-adhesion and providing residual benefits |
| KR101622943B1 (en) * | 2008-02-29 | 2016-05-23 | 벅-케미 게엠베하 | Adhesive agent for application on a sanitary object |
| JP5697124B2 (en) * | 2009-09-08 | 2015-04-08 | アース製薬株式会社 | Gel detergent composition for toilet |
| JP5419760B2 (en) * | 2010-03-12 | 2014-02-19 | 花王株式会社 | Cleaning composition for hard surface |
| JP5530788B2 (en) * | 2010-04-12 | 2014-06-25 | 花王株式会社 | Toilet bowl cleaning composition |
| JP5926482B2 (en) * | 2010-09-28 | 2016-05-25 | 小林製薬株式会社 | Biofilm removing agent and biofilm removing composition |
| JP5726011B2 (en) * | 2011-08-02 | 2015-05-27 | 花王株式会社 | Toilet bowl cleaning composition |
| JP6144543B2 (en) * | 2013-06-07 | 2017-06-07 | 株式会社ダイゾー | Aerosol composition |
| JP6371336B2 (en) | 2015-06-17 | 2018-08-08 | 花王株式会社 | Odor suppressor for polysulfide compounds |
| JP6122181B2 (en) | 2015-06-17 | 2017-04-26 | 花王株式会社 | Method for evaluating or selecting an inhibitor of sulfide compound odor |
| JP7357429B2 (en) * | 2017-03-10 | 2023-10-06 | 小林製薬株式会社 | Sanitary products for toilet bowls |
| JP7168347B2 (en) * | 2017-05-31 | 2022-11-09 | アース製薬株式会社 | Method for improving shape retention of solid preparation and solid preparation |
| EP4089159B1 (en) * | 2021-05-10 | 2024-09-18 | The Procter & Gamble Company | Liquid hand dishwashing detergent composition |
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| JPS57162799A (en) * | 1981-03-31 | 1982-10-06 | Fumakilla Ltd | Water-soluble fragrant detergent gel composition |
| JPH05262621A (en) * | 1992-03-24 | 1993-10-12 | Lion Corp | Aerosol composition |
| JP3558393B2 (en) * | 1994-08-29 | 2004-08-25 | 株式会社ダイゾー | Foamable aerosol composition |
| US5562850A (en) * | 1995-07-26 | 1996-10-08 | The Procter & Gamble Company | Toilet bowl detergent system |
| JP3542305B2 (en) * | 1999-07-07 | 2004-07-14 | 小林製薬株式会社 | Slowly soluble gel composition |
| JP4741780B2 (en) * | 2001-08-31 | 2011-08-10 | ライオン株式会社 | Resin foam aerosol for capturing insects, and method for capturing and killing insects using the resin foam aerosol |
| JP2003096493A (en) * | 2001-09-19 | 2003-04-03 | Kao Corp | Disinfectant antifouling detergent for hard surfaces |
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