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JP5055899B2 - Method for producing high-strength welded steel pipe excellent in weld heat-affected zone toughness and having tensile strength of 760 MPa or more, and high-strength welded steel pipe - Google Patents

Method for producing high-strength welded steel pipe excellent in weld heat-affected zone toughness and having tensile strength of 760 MPa or more, and high-strength welded steel pipe Download PDF

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JP5055899B2
JP5055899B2 JP2006233188A JP2006233188A JP5055899B2 JP 5055899 B2 JP5055899 B2 JP 5055899B2 JP 2006233188 A JP2006233188 A JP 2006233188A JP 2006233188 A JP2006233188 A JP 2006233188A JP 5055899 B2 JP5055899 B2 JP 5055899B2
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純二 嶋村
信行 石川
光浩 岡津
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Description

本発明は、天然ガスや原油の輸送用として好適な、管厚が6mm以上で、引張り強さが760MPa以上の、溶接熱影響部(以下、HAZ)の低温靭性に優れた高強度溶接鋼管およびその製造方法に関する。   The present invention is suitable for transportation of natural gas and crude oil, has a pipe thickness of 6 mm or more, a tensile strength of 760 MPa or more, a high strength welded steel pipe excellent in low temperature toughness of a weld heat affected zone (hereinafter referred to as HAZ), and It relates to the manufacturing method.

近年、天然ガスや原油の輸送用として使用される溶接鋼管は,高圧化による輸送効率の向上や薄肉化による現地溶接施工能率の向上のため、年々高強度化され、既にX100グレードの鋼管が実用化されている。また、引張強度900MPaを超えるX120グレードに対する要求についても具体化されつつある。   In recent years, welded steel pipes used for the transportation of natural gas and crude oil have been strengthened year by year in order to improve transport efficiency by increasing pressure and to improve local welding work efficiency by reducing wall thickness, and X100 grade steel pipes are already in practical use. It has become. Further, the demand for the X120 grade exceeding the tensile strength of 900 MPa is being realized.

このような高強度溶接鋼管の溶接熱影響部靭性に関し,例えば特許文献1には、最終溶接後、溶接部の冷却速度が600℃から400℃まで少なくとも1℃/s以上で冷却することによって、HAZ粗粒域の上部ベイナイト組織中のMA量を低減し、HAZの高靭性化を図ることが記載されている。   Regarding the heat-affected zone toughness of such a high-strength welded steel pipe, for example, in Patent Document 1, after the final welding, the cooling rate of the welded portion is cooled from 600 ° C to 400 ° C at least 1 ° C / s or more, It is described that the amount of MA in the upper bainite structure of the HAZ coarse-grained region is reduced to increase the toughness of the HAZ.

また、特許文献1で問題としているSCCGHAZやICCGHAZ部の再熱HAZ部分は,極微小領域であり、且つ欠陥の存在が考えにくい肉厚中心付近である。よって、この部分の低靭性が溶接鋼管の使用上、特に問題とならない場合も多いと考えられる。   In addition, the reheated HAZ part of the SCCGHAZ or ICCGHAZ part, which is a problem in Patent Document 1, is a very small area, and is near the thickness center where the existence of defects is unlikely. Therefore, it is considered that the low toughness of this part is not particularly problematic in the use of the welded steel pipe.

特許文献2には、HAZのミクロ組織を下部ベイナイトとして、靭性を向上させるため、シーム部の仮付けを除去した後外面側の溶接を行うことにより、溶接入熱を小入熱とした溶接鋼管の製造方法が記載されている。
特開2004−99930号公報 特許第3702216号公報
Patent Document 2 describes a welded steel pipe with a small heat input by performing welding on the outer surface side after removing the temporary attachment of the seam portion in order to improve the toughness using the HAZ microstructure as the lower bainite. The manufacturing method is described.
JP 2004-99930 A Japanese Patent No. 3702216

しかしながら、特許文献1が対象とする溶接鋼管は、PCMが低い成分を母材とするもので、引張り強さが760MPaを超える、PCMが高い成分を母材とする鋼管についての製造指針は得られない。 However, welded steel pipe Patent Document 1 is intended is for the P CM lower component as the base material, manufacturing guidelines for steel pipe tensile strength exceeds 760 MPa, the base material P CM is high component I can't get it.

また、特許文献2記載の方法は、HAZのミクロ組織を完全に下部ベイナイト組織とするため、PCMの範囲を非常に狭い範囲に限定することが必要で、製造安定性が懸念される。 Further, the method of Patent Document 2, in order to completely lower bainite structure the HAZ microstructure, is necessary to limit to a very narrow range of range of P CM, production stability is concerned.

そこで、本発明は上述した問題点を解決すべく、縦シーム溶接部のHAZ靭性に優れた引張り強さが760MPa以上の高強度溶接鋼管およびその製造方法を提供するものである。   Therefore, the present invention provides a high-strength welded steel pipe having a tensile strength of 760 MPa or more and a method for producing the same, which is excellent in HAZ toughness of a longitudinal seam welded part, in order to solve the above-described problems.

本発明者等は、引張り強さが760MPa以上で、かつHAZ靭性に優れた高強度溶接鋼管を開発するため、鋭意研究を行い、以下の知見を得た。
1.HAZにおいて靭性が最も低下する部位は、HAZ粗粒域(Coarse−grain HAZ、以後CGHAZ)で、溶接ボンド部から少なくとも溶接ボンド+1mmの領域である。
2.CGHAZのミクロ組織は、母材のPCM値と、溶接後の冷却において、γ‐α相変
態する800℃から500℃の温度域の冷却速度の組合わせによって、硬質のMAを大量に含む上部ベイナイト組織や、強度の高いマルテンサイト組織を一定分率以下に抑制した、下部ベイナイト組織を主体とすると最も靭性が向上する。
本発明は上記知見を基に更に検討を加えてなされたもので、すなわち、本発明は、
1.質量%で、
C: 0.03〜0.12%
Si: 0.01〜0.5%
Mn: 1.5〜3.0%
Al: 0.01〜0.08%
Nb: 0.01〜0.08%
Ti: 0.005〜0.025%
N: 0.001〜0.010%
O: 0.003%以下
S: 0.003%以下
更に、
Cu: 0.01〜1%
Ni: 0.01〜1%
Cr: 0.01〜1%
Mo: 0.01〜1%
V: 0.01〜0.1%
の一種または二種以上を含有し、
CM値が0.19≦PCM≦0.30を満足し、残部Feおよび不可避的不純物からなる母材を冷間加工で管状に成形した後、縦シームサブマージアーク溶接を溶接ボンド部から溶接ボンド+1mmの領域のミクロ組織が面積率で少なくとも50%以上の下部ベイナイトと、残部が上部ベイナイトあるいはマルテンサイトあるいはそれらの混合組織となる溶接条件として、下記(1)式を満足し、かつ、800℃から500℃の冷却速度を5〜40℃/sの範囲内とする条件で行うことを特徴とする溶接熱影響部靭性に優れた引張り強さが760MPa以上の高強度溶接鋼管の製造方法
0.228≦P CM +0.0174×ln(v (800−500℃間) )≦0.350・・・(1)
但し、P CM は被溶接材の成分組成について求めたもので、P CM =C+Si/30+Mn/20+Cu/20+Ni/60+Cr/20+Mo/15+V/10+5×Bで各元素は含有量を示す。vは溶接部の800〜500℃間の冷却速度(℃/s)で(2)式で求める。
(800−500℃間)(℃/s) =300/t (800−500℃間)(s) ・・・(2)
(800−500℃間)(s) は溶接部(溶接ボンド部から溶接ボンド+1mm)に
おける800〜500℃までの冷却時間で数1で求める。
[数1]

Figure 0005055899
但し、数1において、h:板厚(mm)、θ :初期温度(℃)、Qは溶接入熱(J/cm)を示す。溶接入熱(kJ/mm)はΣ(I ×V )×60/v/1000とする。ここで、
:i番目の電極の電流(A)、V :i番目の電極の電圧(V)、v:溶接速度(mm/min)とする。
2.更に、質量%で、
Ca:0.0005〜0.01%
REM:0.0005〜0.02%
Zr:0.0005〜0.03%
Mg:0.0005〜0.01%
B:0.0001〜0.0010%
の一種または二種以上を含有することを特徴とする1記載の溶接熱影響部靭性に優れた引張り強さが760MPa以上の高強度溶接鋼管の製造方法。
3.縦シーム溶接後、拡管することを特徴とする1または2に記載の溶接熱影響部靭性に優れた引張り強さが760MPa以上の高強度溶接鋼管の製造方法。
4.溶接ボンド部から溶接ボンド+1mmの領域の溶接熱影響部硬さが、250≦HV(98N)≦350を満たすことを特徴とする1乃至3のいずれかに記載の製造方法で製造された溶接熱影響部靭性に優れた引張り強さが760MPa以上の高強度溶接鋼管。 In order to develop a high-strength welded steel pipe having a tensile strength of 760 MPa or more and excellent HAZ toughness, the present inventors have conducted intensive research and obtained the following knowledge.
1. The site where the toughness is most reduced in the HAZ is a HAZ coarse grain region (Coarse-grain HAZ, hereinafter referred to as CGHAZ), which is a region of at least a weld bond + 1 mm from the weld bond portion.
2. Microstructure of CGHAZ includes a P CM value of the base material, in cooling after welding, by a combination of cooling rate in temperature range of 500 ° C. from 800 ° C. to transformation gamma-alpha phase, the upper containing MA of the rigid large amount When the bainite structure or the lower bainite structure in which the high-strength martensite structure is suppressed to a certain fraction or less is mainly used, the toughness is most improved.
The present invention has been made by further study based on the above knowledge, that is, the present invention,
1. % By mass
C: 0.03-0.12%
Si: 0.01 to 0.5%
Mn: 1.5 to 3.0%
Al: 0.01 to 0.08%
Nb: 0.01 to 0.08%
Ti: 0.005 to 0.025%
N: 0.001 to 0.010%
O: 0.003% or less S: 0.003% or less
Cu: 0.01 to 1%
Ni: 0.01 to 1%
Cr: 0.01 to 1%
Mo: 0.01 to 1%
V: 0.01 to 0.1%
Containing one or more of
P CM value satisfies 0.19 ≦ P CM ≦ 0.30, welding base material and the balance Fe and unavoidable impurities was formed in the tubular by cold working, the longitudinal seam submerged arc welding from the welding-bonding unit As a welding condition in which the microstructure of the bond + 1 mm region is a lower bainite with an area ratio of at least 50% or more, and the balance is upper bainite, martensite, or a mixed structure thereof, the following formula (1) is satisfied, and 800 A method for producing a high-strength welded steel pipe having a tensile strength of 760 MPa or more excellent in weld heat-affected zone toughness, characterized in that the cooling rate is from 5 to 40 ° C./s within a range of 5 to 40 ° C./s.
0.228 ≦ P CM + 0.0174 × ln (v (between 800-500 ° C.) ) ≦ 0.350 (1)
However, P CM than those obtained for composition of the material to be welded, P CM = C + Si / 30 + Mn / 20 + Cu / 20 + Ni / 60 + Cr / 20 + Mo / 15 + V / 10 + 5 × each element in B indicates the content. “v” is a cooling rate (° C./s) between 800 to 500 ° C. of the welded portion and is obtained by the equation (2).
v (between 800-500 ℃) (℃ / s) = 300 / t ( between 800-500 ℃) (s) ··· ( 2)
t (between 800-500 ° C) (s) is the welded part (welded bond + 1mm from welded bond)
It calculates | requires by Formula 1 in the cooling time to 800-500 degreeC.
[Equation 1]
Figure 0005055899
In Equation 1, h: plate thickness (mm), θ 0 : initial temperature (° C.), and Q indicate welding heat input (J / cm). The welding heat input (kJ / mm) is Σ (I i × V i ) × 60 / v / 1000. here,
I i : current (A) of i-th electrode, V i : voltage (V) of i-th electrode, v: welding speed (mm / min).
2. Furthermore, in mass%,
Ca: 0.0005 to 0.01%
REM: 0.0005 to 0.02%
Zr: 0.0005 to 0.03%
Mg: 0.0005 to 0.01%
B: 0.0001 to 0.0010%
The method for producing a high-strength welded steel pipe having a tensile strength of 760 MPa or more and excellent in weld heat-affected zone toughness according to 1, characterized by containing one or more of the above.
3. 3. The method for producing a high-strength welded steel pipe having a tensile strength of 760 MPa or more excellent in weld heat-affected zone toughness according to 1 or 2 , wherein the pipe is expanded after longitudinal seam welding.
4). The welding heat produced by the production method according to any one of 1 to 3, wherein the hardness of the weld heat affected zone in the region from the weld bond portion to the weld bond + 1 mm satisfies 250 ≦ HV (98N) ≦ 350. High-strength welded steel pipe with a tensile strength of 760 MPa or more with excellent affected zone toughness.

本発明によれば、縦シーム溶接部のHAZ靭性に優れた,引張強度760MPa以上の高強度溶接鋼管およびその製造方法が得られ、産業上極めて有用である。   According to the present invention, a high-strength welded steel pipe having a tensile strength of 760 MPa or more and a manufacturing method thereof excellent in HAZ toughness of a longitudinal seam welded portion and a method for producing the same can be obtained, which is extremely useful industrially.

本発明では、母材の成分組成、縦シーム溶接部の溶接ボンドから溶接ボンド+1mmまでの領域のミクロ組織および当該組織を得るために必要な溶接条件を規定する。   In the present invention, the composition of the base material, the microstructure in the region from the weld bond of the longitudinal seam weld to the weld bond + 1 mm, and the welding conditions necessary for obtaining the structure are defined.

[成分組成]%は質量%とする。
C:0.03〜0.12%
Cは低温変態組織においては過飽和固溶することで強度上昇に寄与する。この効果を得るためには0.03%以上の添加が必要であるが、0.12%を超えて添加すると、鋼管の円周溶接部の硬度上昇が著しくなり、溶接低温割れが発生しやすくなるため、上限を0.12%とする。
[Component composition]% is mass%.
C: 0.03-0.12%
C contributes to an increase in strength by being supersaturated in a low temperature transformation structure. In order to obtain this effect, 0.03% or more of addition is necessary, but if added over 0.12%, the hardness of the circumferential welded portion of the steel pipe is remarkably increased and cold cracking is likely to occur. Therefore, the upper limit is made 0.12%.

Si:0.01〜0.5%
Siは脱酸材として作用し、さらに固溶強化により鋼材の強度を増加させる元素であるが、0.01%未満ではその効果がなく、0.5%を超えて添加すると靱性が著しく低下するため上限を0.5%とする。
Si: 0.01 to 0.5%
Si is an element that acts as a deoxidizer and increases the strength of the steel by solid solution strengthening. However, if less than 0.01%, there is no effect, and if added over 0.5%, the toughness decreases significantly. Therefore, the upper limit is made 0.5%.

Mn:1.5〜3.0%
Mnは焼入性向上元素として作用する。1.5%以上の添加によりその効果が得られるが、連続鋳造プロセスでは中心偏析部での濃度上昇が著しく、3.0%を超える添加を行うと、中心偏析部での遅れ破壊の原因となるため、上限を3.0%とする。
Mn: 1.5 to 3.0%
Mn acts as a hardenability improving element. The effect can be obtained by addition of 1.5% or more, but in the continuous casting process, the concentration rises at the center segregation part, and if it exceeds 3.0%, it causes delayed fracture at the center segregation part. Therefore, the upper limit is made 3.0%.

Al:0.01〜0.08%
Alは脱酸元素として作用する。0.01%以上の添加で十分な脱酸効果が得られるが、0.08%を超えて添加すると鋼中の清浄度が低下し、靱性劣化の原因となるため、上限を0.08%とする。
Al: 0.01 to 0.08%
Al acts as a deoxidizing element. A sufficient deoxidation effect can be obtained with addition of 0.01% or more, but if added over 0.08%, the cleanliness in the steel is lowered and the toughness is deteriorated, so the upper limit is 0.08%. And

Nb:0.01〜0.08%
Nbは熱間圧延時のオーステナイト未再結晶領域を拡大する効果があり、950℃以下を未再結晶領域とするため、0.01%以上添加する。一方、0.08%を超えて添加すると、HAZの靱性を著しく損ねることから上限を0.08%とする。
Nb: 0.01 to 0.08%
Nb has an effect of expanding the austenite non-recrystallized region at the time of hot rolling, and 0.01% or more is added to make the non-recrystallized region at 950 ° C. or less. On the other hand, if added over 0.08%, the toughness of HAZ is significantly impaired, so the upper limit is made 0.08%.

Ti:0.005〜0.025%
Tiは窒化物を形成し、鋼中の固溶N量低減に有効で,析出したTiNはピンニング効果でオーステナイト粒の粗大化を抑制して、母材、HAZの靱性向上に寄与する。当該ピンニング効果を得るためには0.005%以上の添加が必要であるが、0.025%を超えて添加すると炭化物を形成するようになり、その析出硬化で靱性が著しく劣化するため、上限を0.025%とする。
Ti: 0.005-0.025%
Ti forms nitrides and is effective in reducing the amount of solute N in the steel. The precipitated TiN suppresses the coarsening of austenite grains by the pinning effect and contributes to the improvement of the toughness of the base material and HAZ. Addition of 0.005% or more is necessary to obtain the pinning effect, but if added over 0.025%, carbides are formed, and the toughness is significantly deteriorated by precipitation hardening. Is 0.025%.

N:0.001〜0.01%
Nは通常鋼中の不可避不純物として存在するが、Ti添加により、TiNを形成する。TiNによるピンニング効果で、オーステナイト粒の粗大化を抑制するために0.001%以上鋼中に存在することが必要であるが、0.01%を超える場合、溶接部、特に溶接ボンド近傍で1450℃以上に加熱された領域でTiNが分解し、固溶Nの悪影響が著しいため、上限を0.01%とする。
N: 0.001 to 0.01%
N usually exists as an inevitable impurity in steel, but TiN is formed by addition of Ti. In order to suppress the coarsening of the austenite grains due to the pinning effect by TiN, it is necessary to be present in the steel in an amount of 0.001% or more. Since TiN decomposes in a region heated to a temperature higher than or equal to 0 ° C. and the adverse effect of solute N is significant, the upper limit is made 0.01%.

Cu、Ni、Cr、Mo、Vの一種または二種以上
Cu、Ni、Cr、Mo、Vはいずれも焼入性向上元素として作用するため、高強度化を目的に、これらの元素の一種,または二種以上を添加する。
One or more of Cu, Ni, Cr, Mo, and V Cu, Ni, Cr, Mo, and V all act as a hardenability improving element. Therefore, for the purpose of increasing the strength, Or two or more of them are added.

Cu:0.01〜1%
Cuは、0.01%以上添加することで鋼の焼入性向上に寄与する。しかし、1%以上の添加を行うと、靱性劣化が生じるため、上限を1%とする。
Cu: 0.01 to 1%
Cu contributes to the hardenability improvement of steel by adding 0.01% or more. However, if 1% or more is added, toughness deterioration occurs, so the upper limit is made 1%.

Ni:0.01〜1%
Niは、0.01%以上添加することで鋼の焼入性向上に寄与する。特に、多量に添加しても靱性劣化を生じないため、強靱化に有効であるが、高価な元素であり、かつ1%を超えて添加しても強度上昇が飽和するため、上限を1%とする。
Ni: 0.01 to 1%
Ni contributes to improving the hardenability of steel by adding 0.01% or more. In particular, even if added in a large amount, it does not cause toughness deterioration, so it is effective for toughening. However, it is an expensive element, and even if added over 1%, the increase in strength is saturated, so the upper limit is 1%. And

Cr:0.01〜1%
Crもまた0.01%以上添加することで鋼の焼入性向上に寄与する。一方、1%を超えて添加すると、靱性が劣化するため、上限を1%とする。
Mo:0.01〜1%
Moもまた0.01%以上添加することで鋼の焼入性向上に寄与する。一方、1%を超えて添加すると、靱性が劣化するため、上限を1%とする。
V:0.01〜0.1%
Vは炭窒化物を形成することで析出強化し、特に溶接熱影響部の軟化防止に寄与する。0.01%以上の添加によりこの効果が得られるが、0.1%を超えて添加すると、析出強化が著しく靱性が低下するため、上限を0.1%とする。
Cr: 0.01 to 1%
Cr also contributes to improving the hardenability of steel by adding 0.01% or more. On the other hand, if added over 1%, the toughness deteriorates, so the upper limit is made 1%.
Mo: 0.01 to 1%
Mo also contributes to improving the hardenability of steel by adding 0.01% or more. On the other hand, if added over 1%, the toughness deteriorates, so the upper limit is made 1%.
V: 0.01 to 0.1%
V forms precipitation strengthening by forming carbonitride, and contributes especially to the softening prevention of a weld heat affected zone. This effect can be obtained by addition of 0.01% or more, but if added over 0.1%, precipitation strengthening is remarkably reduced in toughness, so the upper limit is made 0.1%.

O:0.003%以下、S:0.003%以下
本発明でO、Sは不可避的不純物であり含有量の上限を規定する。Oは、粗大で靱性に悪影響を及ぼす介在物生成を抑制するため、0.003%以下とする。Sは、含有量が多いとMnSの生成量が著しく増加し、母材の靭性が劣化するため、0.003%以下とする。
O: 0.003% or less, S: 0.003% or less In the present invention, O and S are inevitable impurities and define the upper limit of the content. O is 0.003% or less in order to suppress the formation of inclusions that are coarse and adversely affect toughness. If the content of S is large, the amount of MnS produced increases remarkably and the toughness of the base material deteriorates.

CM:0.19〜0.30
CMはC+Si/30+Mn/20+Cu/20+Ni/60+Cr/20+Mo/15+V/10+5×Bで表す溶接割れ感受性指数で、各元素は含有量とし、含有しない元素は0とする。
P CM: 0.19~0.30
P CM in weld crack sensitivity index expressed by C + Si / 30 + Mn / 20 + Cu / 20 + Ni / 60 + Cr / 20 + Mo / 15 + V / 10 + 5 × B, each element and content elements that do not contain is 0.

本発明では、継手強度≧760MPaを達成するためPCM:0.19以上とする。図1は内外面1層サブマージアーク溶接を行った溶接鋼管の外面下1mmの位置における硬さ分布を示し、1サイクルの熱影響下において、鋼のオーステナイト化温度(Ac点)直上の温度に加熱された領域近傍がHAZ最軟化部となる。 In the present invention, in order to achieve joint strength ≧ 760 MPa, P CM : 0.19 or more. FIG. 1 shows the hardness distribution at a position 1 mm below the outer surface of a welded steel pipe subjected to inner / outer surface single-layer submerged arc welding, and shows the temperature just above the austenitizing temperature of steel (Ac 3 points) under the heat effect of one cycle. The vicinity of the heated region becomes the HAZ most softened portion.

FEM計算による解析結果から、HAZ部の強度が最軟化部強度で一定であると仮定して、継手強度≧760MPaを達成するためには、HAZ最軟化部の硬さを210(Hv(98N))以上とすればよいことが判った。   From the analysis result by FEM calculation, assuming that the strength of the HAZ part is constant at the softened part strength, in order to achieve the joint strength ≧ 760 MPa, the hardness of the HAZ softened part is 210 (Hv (98N) ) I understood that it should be enough.

そこで、種々のPCMの実験鋼塊から採取した再現熱サイクル試験片に、サブマージアーク溶接の一層溶接でHAZ最軟化部を生じる、Ac点直上を最高加熱温度とする熱サイクルを模した再現熱サイクルを付与して硬さ試験を行った。尚、加熱温度を900℃、800℃〜500℃間の冷却速度を5℃/sとした。 Therefore, reproduction in simulated heat cycle test pieces taken from the experimental steel ingot of various P CM, resulting in HAZ highest softening unit in more welding submerged arc welding, imitating a heat cycle of the immediately above Ac 3 point and maximum heating temperature A hardness test was conducted by applying a thermal cycle. The heating temperature was 900 ° C., and the cooling rate between 800 ° C. and 500 ° C. was 5 ° C./s.

図2に試験結果を示す。PCM:0.19以上で、継手強度≧760MPaを達成するために必要なHAZ最軟化部の硬さである210(Hv(98N))が得られる。 FIG. 2 shows the test results. When P CM is 0.19 or more, 210 (Hv (98 N)), which is the hardness of the HAZ most softened portion necessary to achieve joint strength ≧ 760 MPa, is obtained.

一方,PCMの上限は円周溶接性確保の観点から0.30とする。再現熱サイクル試験を採取した実験鋼塊を用いてy形溶接割れ試験(試験雰囲気:30℃ー80%)を行い、100℃予熱で低温割れが防止されるPCMの上限として0.30を得た。 On the other hand, the upper limit of the P CM is 0.30 in terms of the circumferential weldability ensured. Simulated thermal cycle test the collected experimental steel ingot y-groove weld cracking test using: perform (test atmosphere 30 ° C. over 80%), 0.30 as the upper limit of P CM that cold cracking is prevented at 100 ° C. preheating Obtained.

以上が本発明に係る鋼の基本成分組成であるが、溶接部の靭性を更に向上させる場合、Ca、REM、Zr、Mgの一種または二種以上を添加する。
Ca、REM、Zr、Mg
Ca、REM、Zr、Mgは鋼中で酸硫化物あるいは炭窒化物を形成し、主に溶接熱影響部におけるオーステナイト粒粗大化をピンニング効果で抑制し、靱性を向上させる目的で添加する。
The above is the basic component composition of the steel according to the present invention. When the toughness of the weld is further improved, one or more of Ca, REM, Zr, and Mg are added.
Ca, REM, Zr, Mg
Ca, REM, Zr, and Mg form oxysulfides or carbonitrides in steel, and are mainly added for the purpose of suppressing the austenite grain coarsening in the weld heat affected zone by the pinning effect and improving toughness.

Ca:0.0005〜0.01%
製鋼プロセスにおいて、Ca添加量が0.0005%未満の場合、脱酸反応支配でCaSの確保が難しく靱性改善効果が得られないので、Caの下限を0.0005%とする。
Ca: 0.0005 to 0.01%
In the steelmaking process, when the Ca addition amount is less than 0.0005%, it is difficult to secure CaS due to the deoxidation reaction control, and a toughness improving effect cannot be obtained, so the lower limit of Ca is set to 0.0005%.

一方、Ca添加量が0.01%を超えた場合、粗大CaOが生成しやすくなり、母材を含めて靱性が低下するうえに、取鍋のノズル閉塞の原因となり、生産性を阻害するため、上限は0.01%とし、添加する場合は、0.0005〜0.01%とする。   On the other hand, when the amount of Ca added exceeds 0.01%, coarse CaO is likely to be generated, and the toughness including the base material is lowered, and the nozzle of the ladle is blocked and the productivity is hindered. The upper limit is 0.01%, and when added, 0.0005 to 0.01%.

REM:0.0005〜0.02%
REMは鋼中で酸硫化物を形成し、0.0005%以上添加することで溶接熱影響部の粗大化を防止するピンニング効果をもたらす。しかし、高価な元素であり、かつ0.02%を超えて添加しても効果が飽和するため、上限を0.02%とし、添加する場合は、0.0005〜0.02%とする。
REM: 0.0005 to 0.02%
REM forms an oxysulfide in steel and provides a pinning effect to prevent the weld heat affected zone from becoming coarse by adding 0.0005% or more. However, since it is an expensive element and the effect is saturated even if added over 0.02%, the upper limit is made 0.02%, and when added, it is made 0.0005 to 0.02%.

Zr:0.0005〜0.03%
Zrは鋼中で炭窒化物を形成し、とくに溶接熱影響部においてオーステナイト粒の粗大化を抑制するピンニング効果をもたらす。十分なピンニング効果を得るためには、0.0005%以上の添加が必要であるが、0.03%を超えて添加すると、鋼中の清浄度が著しく低下し、靱性が低下するようになるため、上限を0.03%とし、添加する場合は、0.0005〜0.03%とする。
Zr: 0.0005 to 0.03%
Zr forms carbonitrides in steel and brings about a pinning effect that suppresses the coarsening of austenite grains, particularly in the weld heat affected zone. In order to obtain a sufficient pinning effect, addition of 0.0005% or more is necessary. However, when the addition exceeds 0.03%, the cleanliness in the steel is remarkably lowered and the toughness is lowered. Therefore, the upper limit is made 0.03%, and when added, the content is made 0.0005 to 0.03%.

Mg:0.0005〜0.01%
Mgは製鋼過程で鋼中に微細な酸化物として生成し、特に、溶接熱影響部においてオーステナイト粒の粗大化を抑制するピンニング効果をもたらす。十分なピンニング効果を得るためには、0.0005%以上の添加が必要であるが、0.01%を超えて添加すると、鋼中の清浄度が低下し、靱性が低下するようになるため、上限を0.01%とし、添加する場合は、0.0005〜0.01%とする。
Mg: 0.0005 to 0.01%
Mg is produced as fine oxides in the steel during the steelmaking process, and in particular, has a pinning effect that suppresses the coarsening of austenite grains in the weld heat affected zone. In order to obtain a sufficient pinning effect, addition of 0.0005% or more is necessary, but if added over 0.01%, the cleanliness in the steel is lowered and the toughness is lowered. The upper limit is 0.01%, and when added, 0.0005 to 0.01%.

B:0.0001〜0.0010%
Bは溶接熱影響部においてオーステナイト粒界に偏析し、焼入れ性を高める効果があり、より低い成分での下部ベイナイトあるいはマルテンサイトの生成を容易にする。この効果は0.0010%以下の添加で顕著であり、0.0010%を超えて添加すると、靭性が低下するようになるため、上限を0.0010%とし、添加する場合は、0.0001〜0.0010%とする。
B: 0.0001 to 0.0010%
B segregates at the austenite grain boundaries in the weld heat affected zone, and has the effect of increasing the hardenability, and facilitates the formation of lower bainite or martensite with a lower component. This effect is prominent when added in an amount of 0.0010% or less, and if added over 0.0010%, the toughness decreases, so the upper limit is made 0.0010%. -0.0010%.

本発明では、上述した成分組成を有する鋼を、常法により熱間圧延、加速冷却後、焼き戻しを行って所定の板厚の鋼板とする。   In the present invention, the steel having the above-described component composition is hot-rolled and accelerated and cooled by a conventional method, and then tempered to obtain a steel plate having a predetermined plate thickness.

[ミクロ組織]
本発明では、縦シーム溶接部の溶接ボンドから溶接ボンド+1mmまでの領域のミクロ組織を、面積率で少なくとも50%以上の下部ベイナイトと、上部ベイナイトあるいはマルテンサイトあるいはそれらの混合組織とする。尚、ミクロ組織は表面下2mmにおいて規定する。
[Microstructure]
In the present invention, the microstructure in the region from the weld bond of the longitudinal seam weld to the weld bond + 1 mm is the lower bainite and the upper bainite, martensite, or a mixed structure thereof having an area ratio of at least 50%. The microstructure is defined at 2 mm below the surface.

上記ミクロ組織の場合、溶接ボンド部から溶接ボンド+1mmの領域は、250≦HV(98N)≦350の硬さとなり、優れた溶接部靭性が得られる。   In the case of the above microstructure, the region from the weld bond portion to the weld bond + 1 mm has a hardness of 250 ≦ HV (98N) ≦ 350, and excellent weld toughness is obtained.

図3は、溶接ボンド部の再現熱サイクルシャルピー試験結果に及ぼす硬さの影響を示し、250≦HV(98N)≦350で、優れた低温靭性が得られている。硬さ試験は、再現熱サイクルシャルピー試験と同じ再現熱サイクルを付与した試験片で行った。尚、ミクロ組織に関する規定は、CGHAZを対象とするもので、溶接ボンド+1mmを超えた領域がCGHAZの場合は適用する。   FIG. 3 shows the influence of hardness on the reproducible thermal cycle Charpy test result of the weld bond, and excellent low temperature toughness is obtained when 250 ≦ HV (98N) ≦ 350. The hardness test was performed on a test piece provided with the same reproducible thermal cycle as the reproducible thermal cycle Charpy test. It should be noted that the rules relating to the microstructure are intended for CGHAZ, and are applied when the area exceeding the weld bond + 1 mm is CGHAZ.

[縦シーム溶接条件]
本発明に係る鋼管の縦シーム溶接は、溶接ボンドから溶接ボンド+1mmまでの領域のミクロ組織が、面積率で少なくとも50%以上の下部ベイナイトと、上部ベイナイトあるいはマルテンサイトあるいはそれらの混合組織となるように、溶接条件を選定する。具体的溶接条件は予め試験材を用いて選定すれば良く、本発明では特に規定しない。
[Vertical seam welding conditions]
In the longitudinal seam welding of the steel pipe according to the present invention, the microstructure in the region from the weld bond to the weld bond + 1 mm becomes the lower bainite with an area ratio of at least 50% and the upper bainite, martensite, or a mixed structure thereof. Next, select the welding conditions. Specific welding conditions may be selected in advance using test materials, and are not particularly defined in the present invention.

本発明に係る鋼で、溶接法をサブマージアーク溶接とし、溶接条件を溶接部の800−500℃間の冷却速度で代表する場合、溶接条件を(1)式を満足するように選定すると上述したミクロ組織が得られる。
0.228≦PCM+0.0174×ln(v(800−500℃間))≦0.350・・・(1)
但し、PCMは被溶接材の成分組成について求めたもの、vは溶接部の800〜500℃間の冷却速度(℃/s)で(2)式で求める。
(800−500℃間)(℃/s)=300/t(800−500℃間)(s)・・・(2)
(800−500℃間)(s)は溶接部(溶接ボンド部から溶接ボンド+1mm)における800〜500℃までの冷却時間で数1で求めることが可能である。
In the steel according to the present invention, when the welding method is submerged arc welding and the welding condition is represented by the cooling rate between 800-500 ° C. of the welded part, the welding condition is selected so as to satisfy the expression (1). A microstructure is obtained.
0.228 ≦ P CM + 0.0174 × ln (v (between 800-500 ° C.) ) ≦ 0.350 (1)
However, P CM those obtained for composition of the material to be welded, v is at a cooling rate of between 800 to 500 ° C. of the weld (℃ / s) (2) determined by the equation.
v (between 800-500 ° C.) (° C./s)=300/t (between 800-500 ° C.) (s) (2)
t (between 800 and 500 ° C.) (s) can be obtained by Equation 1 in terms of the cooling time from 800 to 500 ° C. in the welded portion (weld bond portion to weld bond + 1 mm).

Figure 0005055899
Figure 0005055899

但し、数1において、h:板厚(mm)、θ:初期温度(℃)、Qは溶接入熱(J/cm)を示す。 In Equation 1 , h : plate thickness (mm), θ 0 : initial temperature (° C.), Q indicates welding heat input ( J / cm 2 ).

溶接入熱(kJ/mm)はΣ(I×V)×60/v/1000とする。ここで、
:i番目の電極の電流(A)、V:i番目の電極の電圧(V)、v:溶接速度(m
m/min)とする。
The welding heat input (kJ / mm) is Σ (I i × V i ) × 60 / v / 1000. here,
I i : current of the i-th electrode (A), V i : voltage of the i-th electrode (V), v: welding speed (m
m / min).

(1)式において、パラメータ:PCM+0.0174×ln(v(800−500℃間))が0.228未満の場合、多量のMAを含む上部ベイナイト組織の分率が50%を超え、HAZ靭性が劣化する。 In the formula (1), when the parameter: P CM + 0.0174 × ln (v (between 800-500 ° C.) ) is less than 0.228, the fraction of the upper bainite structure containing a large amount of MA exceeds 50%, HAZ toughness deteriorates.

一方、0.350を超えた場合、マルテンサイト組織の分率が50%を超え、HAZ靭性が劣化する。図4に(1)式を満足する範囲を図示する。
本発明に係る鋼管は、要求される真円度に応じて、縦シーム溶接後、拡管して製造する。
On the other hand, when it exceeds 0.350, the fraction of martensite structure exceeds 50%, and the HAZ toughness deteriorates. FIG. 4 illustrates a range satisfying the expression (1).
The steel pipe according to the present invention is manufactured by expanding the pipe after vertical seam welding according to the required roundness.

表1に示す化学組成の鋼を転炉で溶製し、連続鋳造によって220mm厚の鋳片とした後、表2に示す熱間圧延、加速冷却、再加熱条件で鋼板A〜Hを作製した。なお,再加熱は焼戻し処理が目的で、加速冷却設備と同一ライン上に設置した誘導加熱型の加熱装置を用いて行った。   Steel having the chemical composition shown in Table 1 was melted in a converter and made into a slab of 220 mm thickness by continuous casting, and then steel plates A to H were produced under the hot rolling, accelerated cooling, and reheating conditions shown in Table 2. . Reheating was performed for the purpose of tempering, and was performed using an induction heating type heating device installed on the same line as the accelerated cooling equipment.

更に、これらの鋼板をUプレス、Oプレスによって成形した後、内面および外面よりサブマージアーク溶接した。その後、拡管して外径400〜1626mmの鋼管にした。   Furthermore, after forming these steel plates by U press and O press, they were submerged arc welded from the inner surface and the outer surface. Thereafter, the pipe was expanded to obtain a steel pipe having an outer diameter of 400 to 1626 mm.

Figure 0005055899
Figure 0005055899

Figure 0005055899
Figure 0005055899

得られた鋼管の継手強度を評価するため,API−5Lに準拠した全厚引張試験片を採取し、引張試験を実施した。   In order to evaluate the joint strength of the obtained steel pipe, a full-thickness tensile test piece based on API-5L was sampled and a tensile test was performed.

更に、鋼管の溶接継手部の板厚中央位置からJIS Z2202(1980)のVノッチシャルピー衝撃試験片を採取し、シャルピー衝撃試験を実施した。なお、ノッチはCGHAZにおいて板厚中央部における母材と溶接金属が1:1の割合で存在する位置とした(図5)。CGHAZの硬度、CGHAZの靱性(以下HAZ靭性)の試験結果をまとめて表3に示す。   Furthermore, a V-notch Charpy impact test piece of JIS Z2202 (1980) was sampled from the center position of the thickness of the welded joint of the steel pipe, and a Charpy impact test was performed. The notch was located at a position where the base metal and the weld metal exist at a ratio of 1: 1 in the center of the plate thickness in CGHAZ (FIG. 5). Table 3 summarizes the test results of the hardness of CGHAZ and the toughness of CGHAZ (hereinafter referred to as HAZ toughness).

鋼管の継手強度が760MPa以上、溶接ボンド部の試験温度−30℃でのシャルピー吸収エネルギ−100J以上を本発明範囲内とする。   The joint strength of the steel pipe is 760 MPa or more, and the Charpy absorbed energy at the test temperature of the welded bond portion at −30 ° C. −100 J or more is within the scope of the present invention.

Figure 0005055899
Figure 0005055899

化学組成から計算されるPCMとHAZ部冷却速度の組合わせが本発明の範囲内である、発明例No.1〜18は所望のミクロ組織を有し、高HAZ靭性を示した。 The combination of P CM and the HAZ cooling rate calculated from the chemical composition is within the scope of the present invention, invention example No. 1-18 had the desired microstructure and exhibited high HAZ toughness.

一方,HAZ部冷却速度が低く、PCMとHAZ部冷却速度の組合わせが本発明の下限を下回った比較例No.19〜23は,上部ベイナイト組織の分率が高くなったために,CGHAZ硬さが低下するとともに、HAZ靭性が低下した。 On the other hand, low HAZ portion cooling rate, comparing the combination of P CM and HAZ portion cooling rate falls below the lower limit of the present invention example No. In 19-23, since the fraction of the upper bainite structure was increased, the CGHAZ hardness decreased and the HAZ toughness decreased.

また,HAZ部冷却速度が高く、PCMとHAZ部冷却速度の組合わせが本発明の上限を上回った比較例No.24は,マルテンサイト組織の分率が高くなったために,CGHAZ硬さが上昇するとともに、HAZ靭性が低下した。 Also, high the HAZ cooling rate, Comparative Example a combination of P CM and HAZ portion cooling rate exceeds the upper limit of the present invention No. In No. 24, the fraction of martensite structure increased, so the CGHAZ hardness increased and the HAZ toughness decreased.

また,PCMが本発明の下限を下回った比較例No.25は,母材強度が760MPaを下回り,加えて,PCMとHAZ部冷却速度の組合わせが本発明の下限を下回ったため,CGHAZ組織が上部ベイナイト組織となり,CGHAZ硬さが低下するとともに,HAZ靭性が低下した。 In Comparative Example P CM is below the lower limit of the present invention No. 25, the base metal strength is below 760 MPa, in addition, since the combination of P CM and HAZ portion cooling rate falls below the lower limit of the present invention, together with CGHAZ tissue becomes upper bainite, CGHAZ hardness decreases, HAZ Toughness decreased.

また,PCM値が本発明の上限を上回った比較例No.26は,母材靭性が劣化し,加えて,PCM値とHAZ部冷却速度の組合わせが本発明の上限を上回ったため,CGHAZ組織がマルテンサイト組織となり,CGHAZ硬さが上昇するとともに,HAZ靭性が低下した。 In Comparative Example P CM value exceeds the upper limit of the present invention No. 26, the base material toughness is degraded, in addition, since the combination of P CM value and a HAZ cooling rate exceeds the upper limit of the present invention, together with CGHAZ structure becomes martensite, CGHAZ hardness increases, HAZ Toughness decreased.

溶接継手部の硬度分布(外側表面下1mm)の一例を示す図。The figure which shows an example of the hardness distribution (1 mm under an outer surface) of a welded joint part. 溶接熱影響部の最軟化硬さに及ぼすPCMの影響を示す図。It shows the effect of P CM on top softening the hardness of the weld heat affected zone. 再現熱サイクルによる溶接ボンド部の低温靭性と硬さの関係を示す図。The figure which shows the relationship between the low temperature toughness and hardness of the weld bond part by a reproduction thermal cycle. CGHAZにおいて下部ベイナイト組織分率を50%以上とするための、PCMとHAZ冷却速度の範囲を示す図。The lower bainite structure fraction to 50% or more in CGHAZ, shows a range of P CM and HAZ cooling rate. 溶接継手シャルピー試験におけるノッチ位置を説明する図。The figure explaining the notch position in a welded joint Charpy test.

Claims (4)

質量%で、
C: 0.03〜0.12%
Si: 0.01〜0.5%
Mn: 1.5〜3.0%
Al: 0.01〜0.08%
Nb: 0.01〜0.08%
Ti: 0.005〜0.025%
N: 0.001〜0.010%
O: 0.003%以下
S: 0.003%以下
更に、
Cu: 0.01〜1%
Ni: 0.01〜1%
Cr: 0.01〜1%
Mo: 0.01〜1%
V: 0.01〜0.1%
の一種または二種以上を含有し、
CM値が0.19≦PCM≦0.30を満足し、残部Feおよび不可避的不純物からなる母材を冷間加工で管状に成形した後、縦シームサブマージアーク溶接を、溶接ボンド部から溶接ボンド+1mmの領域のミクロ組織が面積率で少なくとも50%以上の下部ベイナイトと、残部が上部ベイナイトあるいはマルテンサイトあるいはそれらの混合組織となる溶接条件として、下記(1)式を満足し、かつ、800℃から500℃の冷却速度を5〜40℃/sの範囲内とする条件で行うことを特徴とする、溶接熱影響部靭性に優れた引張り強さが760MPa以上の高強度溶接鋼管の製造方法。
0.228≦PCM+0.0174×ln(v(800−500℃間))≦0.350・・・(1)
但し、PCMは被溶接材の成分組成について求めたもので、PCM=C+Si/30+Mn/20+Cu/20+Ni/60+Cr/20+Mo/15+V/10+5×Bで各元素は含有量を示す。vは溶接部の800〜500℃間の冷却速度(℃/s)で(2)式で求める。
(800−500℃間)(℃/s)=300/t(800−500℃間)(s)・・・(2)
(800−500℃間)(s)は溶接部(溶接ボンド部から溶接ボンド+1mm)に
おける800〜500℃までの冷却時間で数1で求める。
Figure 0005055899
但し、数1において、h:板厚(mm)、θ:初期温度(℃)、Qは溶接入熱(J/cm)を示す。溶接入熱(kJ/mm)はΣ(I×V)×60/v/1000とする。ここで、
:i番目の電極の電流(A)、V:i番目の電極の電圧(V)、v:溶接速度(m
m/min)とする。
% By mass
C: 0.03-0.12%
Si: 0.01 to 0.5%
Mn: 1.5 to 3.0%
Al: 0.01 to 0.08%
Nb: 0.01 to 0.08%
Ti: 0.005 to 0.025%
N: 0.001 to 0.010%
O: 0.003% or less S: 0.003% or less
Cu: 0.01 to 1%
Ni: 0.01 to 1%
Cr: 0.01 to 1%
Mo: 0.01 to 1%
V: 0.01 to 0.1%
Containing one or more of
P CM value satisfies 0.19 ≦ P CM ≦ 0.30, after the base material and the balance Fe and unavoidable impurities was formed into a tubular by cold working, the longitudinal seam submerged arc welding, from the weld bond portion As welding conditions in which the microstructure of the weld bond + 1 mm region is a lower bainite with an area ratio of at least 50% or more, and the balance is an upper bainite, martensite or a mixed structure thereof, the following formula (1) is satisfied, and Production of a high-strength welded steel pipe having a tensile strength of 760 MPa or more excellent in weld heat-affected zone toughness, characterized in that the cooling rate is from 800 ° C to 500 ° C within a range of 5 to 40 ° C / s. Method.
0.228 ≦ P CM + 0.0174 × ln (v (between 800-500 ° C.) ) ≦ 0.350 (1)
However, P CM than those obtained for composition of the material to be welded, P CM = C + Si / 30 + Mn / 20 + Cu / 20 + Ni / 60 + Cr / 20 + Mo / 15 + V / 10 + 5 × each element in B indicates the content. “v” is a cooling rate (° C./s) between 800 to 500 ° C. of the welded portion and is obtained by the equation (2).
v (between 800-500 ° C.) (° C./s)=300/t (between 800-500 ° C.) (s) (2)
t (between 800-500 ° C.) (s) is determined by Equation 1 in terms of the cooling time from 800 to 500 ° C. in the welded portion (weld bond portion to weld bond + 1 mm).
Figure 0005055899
In Equation 1, h: plate thickness (mm), θ 0 : initial temperature (° C.), and Q indicate welding heat input (J / cm). The welding heat input (kJ / mm) is Σ (I i × V i ) × 60 / v / 1000. here,
I i : current of the i-th electrode (A), V i : voltage of the i-th electrode (V), v: welding speed (m
m / min).
更に、質量%で、
Ca:0.0005〜0.01%
REM:0.0005〜0.02%
Zr:0.0005〜0.03%
Mg:0.0005〜0.01%
B:0.0001〜0.0010%
の一種または二種以上を含有することを特徴とする請求項1記載の溶接熱影響部靭性に優れた引張り強さが760MPa以上の高強度溶接鋼管の製造方法。
Furthermore, in mass%,
Ca: 0.0005 to 0.01%
REM: 0.0005 to 0.02%
Zr: 0.0005 to 0.03%
Mg: 0.0005 to 0.01%
B: 0.0001 to 0.0010%
The method for producing a high-strength welded steel pipe having a tensile strength of 760 MPa or more excellent in weld heat-affected zone toughness according to claim 1, comprising one or more of the following.
縦シーム溶接後、拡管することを特徴とする請求項1または2に記載の溶接熱影響部靭性に優れた引張り強さが760MPa以上の高強度溶接鋼管の製造方法。   3. The method for producing a high-strength welded steel pipe having a tensile strength of 760 MPa or more excellent in weld heat-affected zone toughness according to claim 1 or 2, wherein the pipe is expanded after longitudinal seam welding. 溶接ボンド部から溶接ボンド+1mmの領域の溶接熱影響部硬さが、250≦HV(98N)≦350を満たすことを特徴とする請求項1乃至3のいずれかに記載の製造方法で製造された溶接熱影響部靭性に優れた引張り強さが760MPa以上の高強度溶接鋼管。   4. The heat-affected zone hardness in a region from the weld bond portion to the weld bond + 1 mm satisfies 250 ≦ HV (98N) ≦ 350, and is manufactured by the manufacturing method according to claim 1. A high-strength welded steel pipe with a tensile strength of 760 MPa or more with excellent weld heat-affected zone toughness.
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