JP4558514B2 - Liquid detergent composition - Google Patents
Liquid detergent composition Download PDFInfo
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- JP4558514B2 JP4558514B2 JP2005003655A JP2005003655A JP4558514B2 JP 4558514 B2 JP4558514 B2 JP 4558514B2 JP 2005003655 A JP2005003655 A JP 2005003655A JP 2005003655 A JP2005003655 A JP 2005003655A JP 4558514 B2 JP4558514 B2 JP 4558514B2
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- JP
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- Prior art keywords
- triethanolamine
- ether
- propylene glycol
- hydroxydodecyl
- cleaning composition
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims description 32
- 239000003599 detergent Substances 0.000 title claims description 10
- 239000007788 liquid Substances 0.000 title claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 31
- 238000004140 cleaning Methods 0.000 claims description 22
- 239000002253 acid Substances 0.000 claims description 18
- 125000004442 acylamino group Chemical group 0.000 claims description 18
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 13
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 12
- 150000005846 sugar alcohols Polymers 0.000 claims description 10
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- -1 ether compound Chemical class 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 8
- HDRXPSPTZQVQIT-UHFFFAOYSA-N heptadecane-1,15,16-triol Chemical compound CC(O)C(O)CCCCCCCCCCCCCCO HDRXPSPTZQVQIT-UHFFFAOYSA-N 0.000 claims description 7
- 229960003237 betaine Drugs 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- JMVOSFXLSOMCRN-UHFFFAOYSA-N pentadecane-1,13,14-triol Chemical compound CC(O)C(O)CCCCCCCCCCCCO JMVOSFXLSOMCRN-UHFFFAOYSA-N 0.000 claims description 5
- ACCAIGJKLCJFHP-UQKRIMTDSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;(2s)-2-(dodecanoylamino)pentanedioic acid Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCC(O)=O ACCAIGJKLCJFHP-UQKRIMTDSA-N 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 239000003240 coconut oil Substances 0.000 claims description 4
- 235000019864 coconut oil Nutrition 0.000 claims description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 4
- 229940071124 cocoyl glutamate Drugs 0.000 claims description 3
- 239000005639 Lauric acid Substances 0.000 claims description 2
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- HEOMACOOWJVNQV-UHFFFAOYSA-N hexadecane-1,13,15-triol Chemical compound CC(O)CC(O)CCCCCCCCCCCCO HEOMACOOWJVNQV-UHFFFAOYSA-N 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- WDDRZGRENLQFMR-UHFFFAOYSA-N 15-methylhexadecane-1,13,15-triol Chemical compound CC(C)(O)CC(O)CCCCCCCCCCCCO WDDRZGRENLQFMR-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 239000006260 foam Substances 0.000 description 16
- 239000004094 surface-active agent Substances 0.000 description 13
- 230000000694 effects Effects 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 5
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 235000013922 glutamic acid Nutrition 0.000 description 5
- 239000004220 glutamic acid Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 235000001014 amino acid Nutrition 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 125000002252 acyl group Chemical group 0.000 description 3
- 150000001413 amino acids Chemical class 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 229940070765 laurate Drugs 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000003002 pH adjusting agent Substances 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- 229940105990 diglycerin Drugs 0.000 description 2
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000003346 palm kernel oil Substances 0.000 description 2
- 235000019865 palm kernel oil Nutrition 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 239000004471 Glycine Substances 0.000 description 1
- BIVBRWYINDPWKA-VLQRKCJKSA-L Glycyrrhizinate dipotassium Chemical compound [K+].[K+].O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@H]1CC[C@]2(C)[C@H]3C(=O)C=C4[C@@H]5C[C@](C)(CC[C@@]5(CC[C@@]4(C)[C@]3(C)CC[C@H]2C1(C)C)C)C(O)=O)C([O-])=O)[C@@H]1O[C@H](C([O-])=O)[C@@H](O)[C@H](O)[C@H]1O BIVBRWYINDPWKA-VLQRKCJKSA-L 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- SPRKGVQWXXNKKZ-UHFFFAOYSA-N OCCCCCCCCCCCCCC(CC(C)O)(O)C Chemical compound OCCCCCCCCCCCCCC(CC(C)O)(O)C SPRKGVQWXXNKKZ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229940101029 dipotassium glycyrrhizinate Drugs 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229940074358 magnesium ascorbate Drugs 0.000 description 1
- AIOKQVJVNPDJKA-ZZMNMWMASA-L magnesium;(2r)-2-[(1s)-1,2-dihydroxyethyl]-4-hydroxy-5-oxo-2h-furan-3-olate Chemical compound [Mg+2].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] AIOKQVJVNPDJKA-ZZMNMWMASA-L 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000037307 sensitive skin Effects 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Description
本発明は、安全性の高いアシルアミノ酸系界面活性剤を配合し、十分な洗浄効果と良好な使用感の泡が得られ、しかも長期間の使用においてもポンプの目詰まりを起こしにくいポンプフォーマー用の洗浄組成物に関するものである。 The present invention is a pump former that contains a highly safe acylamino acid surfactant, provides a foam having a sufficient cleaning effect and good usability, and is less likely to cause clogging of the pump even during long-term use. The present invention relates to a cleaning composition.
アシルアミノ酸系界面活性剤は安全性が高く、適度な洗浄力を有するため、従来から皮膚用又は毛髪用洗浄料の配合成分として使用されている。一方ポンプフォーマーはノズル部を押し下げることにより、発泡性内容液と容器外部から取り入れた空気をディスペンサー内部に設けた泡生成部で混合し、発泡させ、ネットを通して均質化し、きめ細かな泡をノズル先端から一定量吐出するノンガス容器をいい（「食品と容器」Ｖｏｌ．３４、Ｎｏ．８ １９９３年）、環境にやさしく、便利性を備えた泡吐出容器として洗顔用、ボディー用、洗髪用などの用途に広く用いられている。 Acylamino acid-based surfactants are high in safety and have an appropriate detergency, so that they are conventionally used as ingredients for skin or hair cleansing agents. On the other hand, by pushing down the nozzle part, the pump former mixes the foamable liquid and the air taken from the outside of the container in the foam generation part provided inside the dispenser, foams it, homogenizes it through the net, and creates fine bubbles at the tip of the nozzle. Is a non-gas container that discharges a certain amount of water ("Food and Container" Vol. 34, No. 8 1993), and is an environmentally friendly and convenient foam discharge container for face washing, body use, hair washing, etc. Widely used in
さらにポンプフォーマー容器に充填するアシルアミノ酸系洗浄剤としては種々の提案がなされており、例えば以下のものがあげられる。 Furthermore, various proposals have been made for acylamino acid detergents to be filled in a pump former container. Examples include the following.
例えばアミノ酸系界面活性剤及び塩を配合して低温での使用性等の改良を目的とした洗浄剤組成物の技術が知られている（特許文献１参照）。またＮ−長鎖アシルアミノ酸界面活性剤にアルキルジメチルアミノ酢酸ベタイン、脂肪酸アルキロールアミド、多価アルコールを特定の割合で配合することにより感触やポンプの目詰まり改良とした洗浄剤組成物の技術が知られている（特許文献２参照）。さらにアシルアミノ酸系洗浄成分、多価アルコール、増粘剤を特定割合で配合することにより低温安定性と感触の改良を目的とした洗浄剤組成物の技術が知られている（特許文献３参照）。 For example, a technique of a cleaning composition for improving the usability at a low temperature by blending an amino acid surfactant and a salt is known (see Patent Document 1). In addition, there is a technique for a detergent composition that improves the feel and clogging of the pump by blending alkyldimethylaminoacetic acid betaine, fatty acid alkylolamide, and polyhydric alcohol in a specific ratio with N-long chain acylamino acid surfactant. It is known (see Patent Document 2). Furthermore, a technique of a detergent composition aimed at improving low-temperature stability and feel by blending an acylamino acid-based cleaning component, a polyhydric alcohol, and a thickener in specific ratios is known (see Patent Document 3). .
しかしながら、アシルアミノ酸系界面活性剤は一般的に起泡力が弱いため、アシルアミノ酸系界面活性剤を主体とする洗浄剤組成物ではきめが細かくクリィーミーで適度な弾力のある泡を十分な量得ることはできず、また泡質改善を試みたものでも、まだ泡質・泡量が十分でないことや、洗浄時及び洗浄後にぬめり感が残るといった問題点があった。 However, since acylamino acid surfactants generally have low foaming power, a detergent composition mainly composed of acylamino acid surfactants provides a sufficient amount of finely creamy and moderately elastic foam. However, even when the foam quality was tried to be improved, there were problems that the foam quality and the amount of foam were not yet sufficient, and that a slimy feeling remained during and after washing.
また、十分な泡を得るためにアシルアミノ酸系界面活性剤の濃度を濃くすると、洗浄剤組成物の粘度が上昇してポンプフォーマーから出にくくなることがあった。さらに洗浄剤組成物によっては、結晶等の析出やネット部に残った洗浄剤組成物の乾燥物の積み重ねにより、ポンプフォーマーのネット部が目詰まりを起こすおそれがあった。 Further, when the concentration of the acylamino acid surfactant is increased in order to obtain sufficient foam, the viscosity of the cleaning composition may increase and it may be difficult to get out of the pump former. Further, depending on the cleaning composition, there is a possibility that the net portion of the pump former may be clogged due to precipitation of crystals or the like and accumulation of dried cleaning composition remaining in the net portion.
本発明は、安全性の高いアシルアミノ酸系界面活性剤を配合して、ポンプフォーマーより押し出しやすく、目詰まりすることもなく、更に泡質に優れ使用感の良好なポンプフォーマー充填用洗浄剤組成物を提供することを目的とする。 The present invention contains a highly safe acylamino acid-based surfactant, is easier to extrude than a pump former, is not clogged, has excellent foam quality, and has a good feeling of use. An object is to provide a composition.
本発明者等は上記事項に鑑みて鋭意検討した結果、アシルアミノ酸系界面活性剤とヒドロキシアルキル多価アルコールエーテル化合物を組み合わせることにより、目詰まりすることなく、泡質や使用感に優れたポンプフォーマー用の洗浄剤組成物が得られることを見出し、本発明を完成させるに至った。 As a result of intensive studies in view of the above matters, the present inventors have found that a combination of an acyl amino acid surfactant and a hydroxyalkyl polyhydric alcohol ether compound can be used to provide a pump foam excellent in foam quality and feeling of use without clogging. The present inventors have found that a detergent composition for mer can be obtained and have completed the present invention.
すなわち、本発明は （Ａ）アシルアミノ酸トリエタノールアミン塩と、（Ｂ）下記一般式（１）及び／又は一般式（２）により示されるヒドロキシアルキル多価アルコールエーテル化合物、並びに（Ｃ）ラウリン酸アミドプロピルベタインを含有し、かつ（Ａ）＋（Ｂ）／（Ａ）＋（Ｂ）＋（Ｃ）の範囲が１０．５／２０．５〜１８／２１であり、さらに（Ｃ）／（Ａ）＋（Ｂ）の範囲が３／２１〜１０／２０．５であることを特徴とするポンプフォーマー容器充填用液状洗浄剤組成物（以下、本発明洗浄剤組成物という）を提供する発明である。
但し、上記式（１）及び（２）中、Ｒ１は８〜１８個の炭素原子を有するアルキル基又はアルケニル基を表し、Ｒ２、Ｒ３、Ｒ４、及びＲ５、はそれぞれ互いに独立に、水素又は１〜３個の炭素原子を有するアルキル基を表し、ｎは０〜３個の整数を表す。
That is, the present invention provides (A) an acylamino acid triethanolamine salt , (B) a hydroxyalkyl polyhydric alcohol ether compound represented by the following general formula (1) and / or general formula (2), and (C) lauric acid It contains amidopropyl betaine, and the range of (A) + (B) / (A) + (B) + (C) is from 10.5 / 20.5 to 18/21, and (C) / ( A) + (B) is in the range of 3/21 to 10 / 20.5 , and provides a liquid cleaning composition for filling a pump former container (hereinafter referred to as the present cleaning composition). It is an invention.
However, the above formula (1) and in (2), R 1 represents an alkyl or alkenyl group having 8 to 18 carbon atoms, R 2, R 3, R 4, and R 5, are each, independently of one another Represents hydrogen or an alkyl group having 1 to 3 carbon atoms, and n represents an integer of 0 to 3.
以下、本発明の構成について詳述する。 Hereinafter, the configuration of the present invention will be described in detail.
本発明の洗浄剤組成物に用いられる（Ａ）成分のアシルアミノ酸系界面活性剤は、アミノ酸と脂肪酸から作られた安全性に優れた洗浄成分である。本発明において、アシルアミノ酸のアシル基の部分については特に制限はなくヤシ油脂肪酸アシル基、パーム核油脂肪酸アシル基、ラウロイル、ミリストイルなどが例示できる。これらのうち、ヤシ油脂肪酸アシル基、ラウロイル、パーム核油脂肪酸アシル基が好ましい。またアミノ酸としては特に制限はなく、グリシン、アラニン、アスパラギン酸、グルタミン酸等が例示できる。対塩基としてはトリエタノールアミンが好ましい。（Ａ）成分として具体的にはヤシ油脂肪酸アシルグルタミン酸トリエタノールアミン、ココイルグルタミン酸トリエタノールアミン、ラウロイルグルタミン酸トリエタノールアミンが好ましい。これらは、市販されているものを使用することができ、例えば、ココイルグルタミン酸トリエタノールアミンとしてはフォームアップＤｏｕｃｅ’−ＧＭ（協和発酵社製）を使用することができる。 The acylamino acid surfactant of component (A) used in the cleaning composition of the present invention is a cleaning component with excellent safety made from an amino acid and a fatty acid. In the present invention, the acyl group portion of the acylamino acid is not particularly limited, and examples thereof include coconut oil fatty acid acyl group, palm kernel oil fatty acid acyl group, lauroyl and myristoyl. Of these, coconut oil fatty acid acyl group, lauroyl, and palm kernel oil fatty acid acyl group are preferred. Moreover, there is no restriction | limiting in particular as an amino acid, Glycine, alanine, aspartic acid, glutamic acid etc. can be illustrated. As the base, triethanolamine is preferable. Specifically, the component (A) is preferably coconut oil fatty acid acyl glutamic acid triethanolamine, cocoyl glutamic acid triethanolamine, or lauroyl glutamic acid triethanolamine. These may be used those commercially available, for example, as a cocoyl glutamate triethanolamine can be use forms up Douce '-GM (manufactured by Kyowa Hakko Co., Ltd.).
これらのアシルアミノ酸系界面活性剤は１種類または２種類以上を組み合わせて使用することができ、本発明の洗浄剤組成物における全組成中の配合量としては１〜２０重量％、好ましくは３〜１５重量％、さらに好ましくは５〜１３重量％である。１重量％未満では十分な効果は望みにくい場合があり、２０重量％を超えて配合した場合、効果の増強は認められにくく、不経済であり、ポンプフォーマーから出にくくなることがある。 These acylamino acid-based surfactants can be used alone or in combination of two or more, and the blending amount in the total composition in the cleaning composition of the present invention is 1 to 20% by weight, preferably 3 to 15% by weight, more preferably 5 to 13% by weight. If it is less than 1% by weight, a sufficient effect may not be desired, and if it exceeds 20% by weight, an increase in the effect is hardly recognized, it is uneconomical, and it may be difficult to get out of the pump former.
本発明の洗浄剤組成物に用いられる（Ｂ）成分の前記一般式（１）及び／又は一般式（２）により示されるヒドロキシアルキル多価アルコールエーテル化合物は特に制限されないが、前記一般式（１）及び一般式（２）中のＲ２及びＲ３基のいずれか一方がメチル基であり、かつＲ４及びＲ５基がともに水素原子である事が望ましい。（Ｂ）成分として具体的にはヒドロキシドデシル−１，２−プロピレングリコールエーテル、ヒドロキシテトラデシル−１，２−プロピレングリコールエーテル、ヒドロキシドデシル−１，３−ブタンジオールエーテル、ヒドロキシドデシル−３−メチル−１，３−ブタンジオールエーテル、ヒドロキシドデシル−２−メチル−２，４−ペンタンジオールエーテルが挙げられる。これらは、市販されているものを使用することができ、例えば、ヒドロキシドデシル−１，２−プロピレングリコールエーテルとヒドロキシテトラデシル−１，２−プロピレングリコールエーテルの混合物としてはビスコセーフ ＬＭＰＥ（川研ファインケミカル（株）社製）を使用することができる。 The hydroxyalkyl polyhydric alcohol ether compound represented by the general formula (1) and / or the general formula (2) of the component (B) used in the cleaning composition of the present invention is not particularly limited, but the general formula (1) ) And general formula (2), it is desirable that either one of R 2 and R 3 groups is a methyl group, and both R 4 and R 5 groups are hydrogen atoms. Specific examples of the component (B) include hydroxydodecyl-1,2-propylene glycol ether, hydroxytetradecyl-1,2-propylene glycol ether, hydroxydodecyl-1,3-butanediol ether, hydroxydodecyl-3-methyl- Examples include 1,3-butanediol ether and hydroxydodecyl-2-methyl-2,4-pentanediol ether. Commercially available products can be used. For example, as a mixture of hydroxydodecyl-1,2-propylene glycol ether and hydroxytetradecyl-1,2-propylene glycol ether, Viscosafe LMPE (Kawaken Fine Chemical ( Co., Ltd.) can be used.
これらの（Ｂ）成分である前記一般式（１）及び／又は一般式（２）により示されるヒドロキシアルキル多価アルコールエーテル化合物は１種類または２種類以上を組み合わせて使用することができ、本発明の洗浄剤組成物における全組成中の配合量としては０．１〜２０重量％、好ましくは０．３〜１５重量％、さらに好ましくは０．５〜１０重量％である。０．１重量％未満では十分な効果は望みにくい場合があり、２０重量％を超えて配合した場合、効果の増強は認められにくく、不経済である。 These hydroxyalkyl polyhydric alcohol ether compounds represented by the general formula (1) and / or the general formula (2) as the component (B) can be used alone or in combination of two or more thereof. The blending amount in the total composition of the detergent composition is 0.1 to 20% by weight, preferably 0.3 to 15% by weight, and more preferably 0.5 to 10% by weight. If the amount is less than 0.1% by weight, a sufficient effect may not be desired. If the amount exceeds 20% by weight, the enhancement of the effect is hardly recognized, which is uneconomical.
本発明の洗浄剤組成物は上記必須成分の他に、通常の化粧料、医薬部外品、医薬品等に用いられる各種成分、例えば他の界面活性剤、油性成分、保湿剤、増粘剤、キレート剤、薬効成分、防腐剤、色素、顔料、粉体、ｐＨ調整剤、紫外線吸収剤、抗酸化剤、香料等を適宜配合することができる。 In addition to the essential components described above, the cleaning composition of the present invention includes various components used in ordinary cosmetics, quasi drugs, pharmaceuticals, etc., such as other surfactants, oily components, moisturizers, thickeners, Chelating agents, medicinal ingredients, preservatives, dyes, pigments, powders, pH adjusters, ultraviolet absorbers, antioxidants, fragrances, and the like can be appropriately blended.
本発明の洗浄剤組成物は常法に従って液状の水性製剤として調製され、従来のポンプフォーマーに用いられる洗浄液と同様にして使用でき、例えば、シャンプー、ボディソープ、ハンドソープ、洗顔料等として用いることができる。 The cleaning composition of the present invention is prepared as a liquid aqueous preparation according to a conventional method, and can be used in the same manner as the cleaning liquid used in conventional pump formers. For example, it is used as a shampoo, body soap, hand soap, face wash, etc. be able to.
本発明の洗浄剤組成物におけるポンプフォーマーとしては、ノズル部を押し下げることにより、本発明の内容液と容器外部から取り入れた空気をディスペンサー内部に設けた泡生成部で混合し、発泡させ、ネットやスポンジ等を通して均質化し、きめ細かな泡をノズル先端から一定量吐出する機構を有するものを使用することができる。 As the pump former in the cleaning composition of the present invention, the content liquid of the present invention and the air taken from the outside of the container are mixed in the foam generating unit provided inside the dispenser by pushing down the nozzle part, foamed, It is possible to use one having a mechanism for homogenizing through a sponge or the like and discharging a predetermined amount of fine bubbles from the nozzle tip.
以上説明したように、本発明はアシルアミノ酸系界面活性剤とヒドロキシアルキル多価アルコールエーテル化合物を組み合わせることにより、ポンプフォーマーが目詰まりすることなく、泡質や使用感に優れたポンプフォーマー用の洗浄剤組成物である。
以下にその実施例及び比較例を挙げ、本発明を具体的に説明するが、本発明は下記実施例において制限されるものではない。なお、処方中の各成分の配合量は、重量％とする。
As described above, the present invention is for a pump former having excellent foam quality and feeling of use without clogging the pump former by combining an acylamino acid surfactant and a hydroxyalkyl polyhydric alcohol ether compound. The cleaning composition.
The present invention will be specifically described below with reference to examples and comparative examples, but the present invention is not limited to the following examples. In addition, the compounding quantity of each component in prescription shall be weight%.
表１に示すボディソープを常法にて調製し、ポンプフォーマー容器（吉野工業所（株）社製、ネット２００メッシュ×２）に充填して実際に使用した。このときの使用性を以下の評価方法にて評価した。 The body soap shown in Table 1 was prepared by a conventional method, and was actually used after being filled into a pump former container (Yoshino Kogyo Co., Ltd., Net 200 mesh × 2). The usability at this time was evaluated by the following evaluation method.
評価方法
専門評価パネラー１０人に実施例１及び比較例１〜４の各試料を６０日間（１日一回）使用してもらい、下記項目について評価してもらった。評価は各項目について５段階（良好：５、やや良い：４、普通：３、やや悪い：２、悪い：１）で数値化し、パネラー全体の平均点が４．５〜５．５を◎、４．０〜４．４を○、３．５〜３．９を△、２．９以下を×とした。
（評価項目）
１．泡質の良さ（クリィーミィーで弾力がある）
２．洗浄力
３．洗浄中のヌルつきのなさ
４．洗浄後のきしみ・ヌルつきのなさ
５．ポンプからの出やすさ（６０日間使用時の状態での目詰まり確認）
Evaluation Method Ten professional evaluation panelists used each sample of Example 1 and Comparative Examples 1 to 4 for 60 days (once a day) and evaluated the following items. Evaluation is quantified in five stages (good: 5, slightly good: 4, normal: 3, slightly bad: 2, bad: 1) for each item, and the average score of the entire panel is 4.5 to 5.5. 4.0 to 4.4 was evaluated as ◯, 3.5 to 3.9 as Δ, and 2.9 or less as X.
(Evaluation item)
1. Good foam quality (creamy and elastic)
2. 2. Detergency 3. No null during washing 4. No squeak or null after cleaning Ease of getting out of the pump (confirmation of clogging when used for 60 days)
表１から明らかなように本発明品は全ての項目において比較例より高い評価が得られた。 As is clear from Table 1, the products of the present invention were evaluated higher than the comparative examples in all items.
以下に本発明を、詳細に説明するための実施例を挙げるが、本発明はこれらに限定されるものではない。 Examples for describing the present invention in detail are given below, but the present invention is not limited thereto.
実施例２ 洗顔料
配合成分 配合量（重量％）
（１）ココイルグルタミン酸トリエタノールアミン（Ａ） １０．０
（２）ヒドロキシドデシル−１，２−プロピレングリコールエーテル（Ｂ） ０．５
（３）ヒドロキシテトラデシル−１，２−プロピレングリコールエーテル（Ｂ）３．０
（４）プロピレングリコール ５．０
（５）ラウリン酸アミドプロピルベタイン ２．５
（６）キレート剤 適 量
（７）防腐剤 適 量
（８）ｐＨ調整剤 適 量
（９）精製水 残 余
Example 2 Facial Cleanser Formulation Components Formulation amount (% by weight)
(1) Cocoyl glutamic acid triethanolamine (A) 10.0
(2) Hydroxydodecyl-1,2-propylene glycol ether (B) 0.5
(3) Hydroxytetradecyl-1,2-propylene glycol ether (B) 3.0
(4) Propylene glycol 5.0
(5) Amidopropyl betaine laurate 2.5
(6) Chelating agent appropriate amount (7) Preservative appropriate amount (8) pH adjuster appropriate amount (9) Purified water residue
実施例３ 美白洗顔料
配合成分 配合量（重量％）
（１）ヤシ油脂肪酸アシルグルタミン酸トリエタノールアミン（Ａ） ５．０
（２）ラウロイルグルタミン酸トリエタノールアミン（Ａ） ５．５
（３）ヒドロキシテトラデシル−１，２−プロピレングリコールエーテル（Ｂ）３．０
（４）１．３−ブチレングリコール ５．０
（５）ジグリセリン ５．０
（６）ラウリン酸アミドプロピルベタイン ２．５
（７）アスコルビン酸リン酸マグネシウム １．０
（８）防腐剤 適 量
（９）ｐＨ調整剤 適 量
（１０）精製水 残 余
Example 3 Whitening Face Washing Formulation Ingredient Ingredient Amount (wt%)
(1) Palm oil fatty acid acyl glutamic acid triethanolamine (A) 5.0
(2) Lauroylglutamate triethanolamine (A) 5.5
(3) Hydroxytetradecyl-1,2-propylene glycol ether (B) 3.0
(4) 1.3-butylene glycol 5.0
(5) Diglycerin 5.0
(6) Amidopropyl betaine laurate 2.5
(7) Magnesium ascorbate phosphate 1.0
(8) Preservative appropriate amount (9) pH adjuster appropriate amount (10) Purified water residue
実施例４ 敏感肌用ボディソープ
配合成分 配合量（重量％）
（１）ラウロイルグルタミン酸トリエタノールアミン（Ａ） １５．０
（２）ヒドロキシテトラデシル−１，２−プロピレングリコールエーテル（Ｂ）３．０
（３）ラウリン酸アミドプロピルベタイン ３．０
（４）１．３−ブチレングリコール ３０．０
（５）ジグリセリン １５．０
（６）グリチルリチン酸ジカリウム ０．０５
（７）ｐＨ調整剤 適 量
（８）精製水 残 余
Example 4 Body Soap for Sensitive Skin Ingredients Ingredient Amount (% by weight)
(1) Lauroyl glutamic acid triethanolamine (A) 15.0
(2) Hydroxytetradecyl-1,2-propylene glycol ether (B) 3.0
(3) Amidopropyl betaine laurate 3.0
(4) 1.3-butylene glycol 30.0
(5) Diglycerin 15.0
(6) Dipotassium glycyrrhizinate 0.05
(7) pH adjuster appropriate amount (8) Purified water residue
実施例２〜４は常法により調製し、実施例１と同様のポンプフォーマー容器に充填し使用したところ、きめ細かな適度な弾力のある泡が得られ、使用時にぬめりやきしみ感がなく、目詰まりも見られない、優れた効果を示すものが得られた。 Examples 2 to 4 were prepared by a conventional method and filled into a pump former container similar to that used in Example 1. As a result, fine, moderately elastic bubbles were obtained, and there was no slimy or squeaky feeling during use. The thing which shows the outstanding effect in which clogging is not seen was obtained.
以上説明したように、本発明は、きめ細かで適度な弾力のある泡が得られ、使用感にも優れた、安全性の高いアシルアミノ酸系洗浄成分を配合したポンプフォーマー用液状洗浄剤組成物を提供する。
As described above, the present invention provides a liquid detergent composition for pump formers, which is capable of producing fine, moderately elastic foams, is excellent in feeling of use, and contains a highly safe acylamino acid detergent. I will provide a.
Claims (4)
但し、上記式（１）及び（２）中、Ｒ１は８〜１８個の炭素原子を有するアルキル基又はアルケニル基を表し、Ｒ２、Ｒ３、Ｒ４、及びＲ５はそれぞれ互いに独立に、水素又は１〜３個の炭素原子を有するアルキル基を表し、ｎは０〜３個の整数を表す。
(A) Acylamino acid triethanolamine salt , (B) hydroxyalkyl polyhydric alcohol ether compound represented by the following general formula (1) and / or general formula (2) , and (C) lauric acid amidopropyl betaine And the range of (A) + (B) / (A) + (B) + (C) is 10.5 / 20.5-18 / 21, and (C) / (A) + (B ) In the range of 3/21 to 10 / 20.5 . A liquid detergent composition for filling a pump former container.
However, the above formula (1) and in (2), R 1 represents an alkyl or alkenyl group having 8 to 18 carbon atoms, R 2, R 3, R 4, and R 5 are each, independently of one another , Hydrogen or an alkyl group having 1 to 3 carbon atoms, and n represents an integer of 0 to 3.
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| JP2005350438A (en) * | 2004-06-08 | 2005-12-22 | Kanebo Cosmetics Inc | Liquid skin cleanser |
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| JP2006193549A (en) | 2006-07-27 |
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