JP4431906B2 - Stretch knitted fabric for interior, manufacturing method thereof and sheet forming method - Google Patents
Stretch knitted fabric for interior, manufacturing method thereof and sheet forming method Download PDFInfo
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- JP4431906B2 JP4431906B2 JP05064599A JP5064599A JP4431906B2 JP 4431906 B2 JP4431906 B2 JP 4431906B2 JP 05064599 A JP05064599 A JP 05064599A JP 5064599 A JP5064599 A JP 5064599A JP 4431906 B2 JP4431906 B2 JP 4431906B2
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Description
【0001】
【発明の属する技術分野】
本発明はインテリア用伸縮性編地、その製造方法及びシート成形方法に関し、具体的にはウレタン等のクッション材を有せず良好なクッション性能と着座感、及び意匠性の付与された椅子張り用、若しくは車両用伸縮性編地シートに関する。
【0002】
【従来の技術】
現在、椅子用、車輌座席用シートのクッション材にはウレタンフォーム、ポリエステル繊維詰綿、ポリエステル繊維を接着した樹脂綿や固綿等が使用されている。しかしながらウレタンフォームは製造中に使用される薬品等の取り扱いが難しく且つフロンを排出する、リサイクルが困難である等の理由で問題が有り、またポリエステル繊維詰綿、ポリエステル繊維を接着した樹脂綿や固綿等に関しては、経日的な繊維構造上のへたりに伴うクッション性の低下という問題点があった。
【0003】
これらの問題を解決すべく最近、ポリエステル弾性糸とポリエステル加工糸を用いた織物が市場に出始めている。しかしこれらの織物は織物の構造上ポリエステル弾性糸が直接人体へ接触する割合が多く非常に固く感じられ、長時間の使用に耐えられる物ではなく意匠性の面からもかなりの制約があった。
【0004】
【発明が解決しようとする課題】
本発明は上記従来の椅子用、車輌座席用シートの有する問題点を解決し、クッション材を使用せずとも良好なクッション性能と、長時間の使用に耐えうるソフトな着座感、個々の嗜好に応じた意匠性の付与されたインテリア用伸縮性編地、その製造方法及びシート成形方法の提供に関するものである。
【0005】
【課題を解決するための手段】
上記課題を解決する為、本発明では以下の構成を成すことが必要となる。即ち、本発明の物にかかる発明は、破断伸度(DE)が50〜200%、トータルデニールが200〜6000デニール、160℃乾熱収縮率(SHD)が12〜60%であるポリエーテルエステル系弾性糸が後筬に、トータルデニールが100〜3000デニールのポリエステル系繊維糸が前筬に配されてなる編地であって、編地の経緯10%伸長時応力が30kgf/5cm以下、経緯両方向の破断強力が50kgf/5cm以上であることを特徴とするインテリア用伸縮性編地であって、好ましくはポリエーテルエステル系弾性糸が芯鞘型複合弾性糸であることを特徴とする上記記載のインテリア用伸縮性編地、ポリエーテルエステル系弾性糸が、隣接する糸と融着していることを特徴とする上記記載のインテリア用伸縮性編地、ポリエーテルエステル系弾性糸に難燃剤及び/又は耐光剤が付与されていることを特徴とする上記記載のインテリア用伸縮性編地、ポリエーテルエステル系弾性糸の160℃乾熱収縮率(SHD)がポリエステル系繊維糸条の160℃乾熱収縮率(SHD)よりも5〜50%高いことを特徴とする上記記載のインテリア用伸縮性編地である。
【0006】
また本発明の製造方法にかかる発明は、2枚筬以上からなる経編機の後筬にポリエーテルエステル系弾性糸を、前筬にポリエステル系繊維糸条を配して製編することを特徴とするインテリア用伸縮性編地の製造方法であり、好ましくは少なくとも前筬2枚にポリエステル加工糸からなる先染め糸を配して製編することを特徴とする上記記載のインテリア用伸縮性編地の製造方法、ポリエーテルエステル系弾性糸の一部乃至全部が一針振りの組織で挿入されていることを特徴とする上記記載のインテリア用伸縮性編地の製造方法、ポリエーテルエステル系弾性糸として芯鞘型の複合弾性糸と単成分の弾性糸とが交互に配して製編することを特徴とする上記記載のインテリア用伸縮性編地の製造方法、製編後ポリエーテルエステル系芯鞘型複合弾性糸の鞘側の融点以上、芯側の融点未満の温度で熱処理することを特徴とする上記記載のインテリア用伸縮性編地の製造方法である。
【0007】
更に本発明の成形方法にかかる発明は、上記の編地をフレームに四方を緊張固定し、その後ポリエーテルエステル系弾性糸の融点未満の熱を加えてセットすることを特徴とするインテリア用伸縮性編地のシート成形方法である。
以下、本発明を詳述する。
【0008】
本発明で用いるポリエーテルエステル系弾性糸は、芳香族ジカルボン酸とグリコールとを主原料として用いられる芳香族ポリエステルをハードセグメントとし、ポリアルキレングリコールをソフトセグメントとするブロックエーテルエステル系弾性体からなる糸であることが好ましい。特にテレフタル酸とエチレングリコール又はテレフタル酸とブタンジオールとからなるテレフタル酸系ポリエステルをハードセグメントとし、ポリエチレングリコール、ポリテトラメチレングリコール等のポリエーテルをソフトセグメントとする物が望ましい。更にポリブチレンテレフタレートとポリテトラメチレングリコールとを共重合させたポリエーテルエステル系弾性糸は、伸長回復性が良好でありより好ましい物となる。
【0009】
こうして得られたポリエーテルエステル系弾性糸の破断伸度(DE)は50%以上200%以下、トータルデニールは200デニール以上6000デニール以下、160℃乾熱収縮率(SHD)は12%以上60%以下であることが望ましい。破断伸度が50%未満である場合着座感が固く、逆に200%を越える物では伸長回復性が弱くなるので好ましくない。またトータルデニールが200デニール未満である場合編物の生産効率が悪く、逆に6000デニールを越えるものは汎用の編み機では扱えない太さとなり好ましくない。また160℃乾熱収縮率(SHD)が12%未満である場合成形時の弛みがとりにくく、逆に60%を越える場合意匠性を司るポリエステル糸条とのバランスが崩れ布帛物性が悪くなるので好ましくない。
【0010】
また、上記ポリエーテルエステル系弾性糸はトータルデニールが100デニール以上3000デニール以下であるポリエステル系繊維糸条と共に製編される。
ここで用いられるポリエステル系繊維糸条とは、ポリエチレンテレフタレートマルチフィラメント糸若しくはポリエチレンテレフタレートを主成分として5ーナトリウムスルホン酸金属塩やイソフタル酸等を共重合させたマルチフィラメント糸、更にはポリエチレンテレフタレートに微粉不活性物質を含ませたマルチフィラメント糸等からなる糸条のことである。
これが100デニール未満である場合生産効率が悪く、逆に3000デニールを越える場合汎用の編み機では扱えなくなるので好ましくない。尚、ポリエステル系繊維糸条には一般に取り扱い性を良好にする為各種仮撚加工、タスラン加工等の糸加工が施され、使用方法は白糸、先染糸どちらを用いても良い。以上の様にポリエステル系繊維糸条は適宜設計の目的により使い分けられるが使用の意図は着座感の向上、意匠性の向上、製品品質の向上にあることは言うまでもない。
【0011】
こうして得られた編地の経緯10%伸長時応力は30kgf/5cm以下、経緯両方向の破断強力は50kgf/5cm以上であることが望ましい。経緯10%伸長時応力が30kgf/5cmを越える場合着座感が固く好ましくなく、逆に10%伸長時応力が極端に低い場合にも沈み込み量が大きく良好な着座姿勢が保てないので好ましくない。よって10%伸長時の経緯各方向の応力は3〜20kgf/5cmの範囲にあることが望ましい。また、経緯両方向の破断強力が50kgf/5cm未満である場合、強力不足による生地破損の問題が発生しやすくなるので好ましくない。よって破断強力は高ければ高い程耐久性の面では好ましいが同時にコストも高くなる方向となるので使用目的に応じ適宜設計されるのが望ましい。
【0012】
また、ポリエーテルエステル系弾性糸が芯鞘型複合弾性糸であること、ポリエーテルエステル系弾性糸が隣接する糸と融着していること、ポリエーテルエステル系弾性糸に難燃剤及び/又は耐光剤が付与されていること、更にはポリエーテルエステル系弾性糸の160℃乾熱収縮率がポリエステル系繊維糸条の乾熱収縮率よりも5〜50%高いことが望ましい。ポリエーテルエステル系弾弾性糸が芯鞘型複合弾性糸であり、隣接する糸と融着していると編み地形態が安定し、更に難燃剤及び/又は耐光剤が付与されていると品質を向上させることが出来るので何れも好ましい方向となる。
【0013】
尚、ポリエーテルエステル系芯鞘型弾性糸の融点差は大きい方が熱接着の際の取り扱い性に優れるが、紡糸性の問題により60〜20℃、好ましくは50〜30℃の融点差を有する様、芯側の融点を高くするのが好ましい。また、ポリエーテルエステル系単成分型弾性糸を構成するポリエーテルエステル系弾性糸の融点は150〜200℃、芯鞘型複合弾性糸の場合は芯成分の融点を150〜200℃とし鞘成分の融点をそれよりも60〜20℃低めに設計する。また、芯鞘の構成比率は糸断面積比で芯成分50%以上、好ましくは70〜95%であり、熱融着処理は鞘側の融点よりも10〜40℃高い温度で行うことが好ましい。
【0014】
また、難燃剤としてはメラミンシアヌレートを添加したり燐共重合体を用いる方法が知られているがこれに限定されるものではなく、添加量はポリエーテルエステル系弾性糸構成成分100重量部に対し1〜30重量部の範囲が好ましい。また耐光剤もカーボンブラック等の添加による処方等が知られているがこれに限定されるものではなく、添加量はポリエーテルエステル系弾性糸構成成分100重量部に対し0.1〜5重量部の範囲が好ましい。尚、160℃乾熱収縮率がポリエステル系繊維糸条の乾熱収縮率よりも5〜50%高いと、後の成形性を向上させることが出来るので好ましい。
【0015】
また、これらの編地はポリエーテルエステル系弾性糸を2枚筬以上からなる経編機の後筬に、ポリエステル系繊維糸条が前筬に用いられて製編されること、望ましくは経編機の少なくとも前筬2枚にポリエステル加工糸からなる先染め糸が用いられ、意匠性が付与されて製造されていることが好ましい。このことによって長時間の使用に耐えうるソフトな着座感の向上、各人の嗜好にあった意匠性の提供が可能となる。
【0016】
そしてポリエーテルエステル系弾性糸の一部乃至全部が一針振りの組織で挿入されていること、ポリエーテルエステル系芯鞘型複合弾性糸とポリエーテルエステル系単成分弾性糸とが交互に配されて製編されること、そして製編後ポリエーテルエステル系芯鞘型複合弾性糸の鞘側の融点以上、芯側の融点未満の温度で熱処理し隣接する糸どうしを熱接着させること等、の製造方法を採用するとより編地形態が安定し品質が向上するので望ましい。
【0017】
ポリエーテルエステル系弾性糸の一部乃至全部が一針振りの組織で挿入されている事により弾性糸の伸縮特性が直接布帛特性に反映されやすくなり、回復性も良好になるので好ましい。また、場合によっては後筬に比較的細デニールのポリエーテルエステル系弾性糸を2針間以上の振り幅で挿入すれば面状の伸長回復特性を有する布帛となりより好ましい。また、ポリエーテルエステル系芯鞘型複合弾性糸とポリエーテルエステル系単成分弾性糸とが交互に配されて製編されることによって目止め効果が強くなりすぎず適当な範囲となりクッション性が良くなる。構成比率は交互配列が望ましいが3:1〜1:3の範囲であれば同様の効果が得られる。
【0018】
そしてこれららは製編後ポリエーテルエステル系芯鞘型複合弾性糸の鞘側の融点以上、芯側の融点未満の温度で熱処理し隣接する糸どうしを熱接着させる製造方法により形態の安定したクッション性の良い布帛を得ることが出来る。
尚、熱処理は鞘部の融点よりも10〜40℃高い温度で処理することが望ましい。
【0019】
また編地をフレームに四方を緊張固定し、その後ポリエーテルエステル系弾性糸の融点未満の熱を加えてセットする方法を用いると作業効率の大幅な向上が図られる。
尚、ここで言う編み地とはトリコット若しくはラッセル機等の経編機を用い作製された経編み地とするのが好ましいがこれに限定されるものでは無い。
また本発明に係わる布帛の伸長回復特性は10%伸長時、24時間経過後で90%以上、更に好ましくは95%以上回復する物であることが望ましい。
【0020】
【実施例】
以下、実施例によって本発明を詳細に説明する。尚、本発明中の物性、評価は以下の方法で求めた。
【0021】
1.布帛強伸度
オリエンテック社製テンシロン引張試験機を使用し試料長200mm、試験片の幅50mm、引張速度100mm/minで測定した。そして得られたチャートから破断時の強伸度及び10%伸長時の応力を求めた。更に定点をマーキングした新しい試料をセットしチャートから読み取られた10%伸長時の応力を加えた後常温で放置し、24時間経過後の伸長回復特性の評価を行った。
【0022】
2.沈み量(撓み量)測定
常温にて40cm角の鉄製フレームに弛みがない状態で試料を固定後、熱風乾燥機中170℃×1分の条件で熱処理を実施。その後、フレーム中心部とロードセルに固定されている半径10cmの円盤状圧縮治具との中心が一致する様位置決めを行った後、45kgfの応力をかけその時の沈み量を測定した。尚、良好な沈み量は20〜60mmの範囲内である。
【0023】
3.融点測定
セイコー電子工業社製のSSC5200型の示差走査熱量計を使用し、窒素流量40cc/分、昇温速度20℃/分で溶解ピーク温度を測定した。
【0024】
(実施例1)
カールマイヤー社製、5枚筬からなる9Gラッセル機(RMー6F)を用い、前筬3枚に表ー2記載のポリエステル糸条を用い意匠性の表現、着座感の向上を図り、後筬2枚に表ー1記載の弾性糸を用い伸長回復性の機能付与を狙った編物を作製し本文中に記載した方法で沈み量等の評価を実施した。尚、伸長回復性の向上を図る為L4の後筬には2000デニールの弾性糸を2本引き揃えで一針間の振り巾で挿入し、緯方向の伸長回復機能を付与する為、L5の後筬で比較的細デニールの弾性糸を四針間で振らす組織を組んだ。(図1、図2参照)得られた編物はインテリア用座席シートとして良好な外観と着座感を有する物であった。尚、回復特性評価は10%伸長後24時間で90%以上回復する物を良好とし、着座感は被験者の官能評価を以て評価した。(表3参照)
【0025】
(実施例2)
同様にカールマイヤー社製、5枚筬からなる9Gラッセル機(RMー6F)を用い、前筬3枚に表ー2記載のポリエステル糸条を用い意匠性の表現、着座感の向上を図りつつ後筬2枚に表ー1記載の弾性糸を用い伸長回復性の機能付与を狙った編物を作製した後、本文中に記載した方法で沈み量等の評価を実施した。尚、伸長回復性の向上を図る為実施例1同様、L4の後筬には2000デニールの弾性糸を2本引き揃えで一針間の振り巾で挿入し、緯方向の伸長回復機能を付与する為、L5の後筬で比較的細デニールの弾性糸を四針間で振らす組織を組んだ。(図1、図2参照)
得られた編物を金属製のフレームに四方を緊張固定し、170℃×1分の熱処理を施した。得られたシートは安定した布帛形態を有しインテリア用座席シートとして良好な外観と着座感を有する物であった。(表3参照)
【0026】
(実施例3)
同様にカールマイヤー社製、5枚筬からなる12Gラッセル機(RMー6F)を用い、前筬3枚に表ー2記載のポリエステル糸条を用い意匠性の表現、着座感の向上を図りつつ後筬2枚に表ー1記載の弾性糸を用い伸長回復性の機能付与を狙った編物を作製した後、本文中に記載した方法で沈み量等の評価を実施した。尚、伸長回復性の向上を図る為実施例1同様、L4の後筬には2000デニールの弾性糸を2本引き揃えで一針間の振り巾で挿入し、緯方向の伸長回復機能を付与する為、L5の後筬で比較的細デニールの弾性糸を四針間で振らす組織を組んだ。(図1、図2参照)
得られた編物を金属製のフレームに四方を緊張固定し、170℃×1分の熱処理を施した。得られたシートは芯鞘型複合弾性糸が全面に挿入されている為、目ずれの無い安定した布帛形態を有しインテリア用座席シートとして良好な外観と着座感を有する物であった。(表3参照)
【0027】
(比較例1)
同じくカールマイヤー社製、5枚筬からなる9Gラッセル機(RMー6F)を用い前筬3枚に実施例同様のポリエステル糸条を用いた他、後筬2枚に表ー2記載の弾性糸同等のデニールを有するポリエステル糸条を実施例同様の組織で編製し、本文中に記載した方法で沈み量等の評価を実施した。
得られた編物はインテリア用座席シートとして良好な外観を有するものの弾性糸が挿入されておらず、ウレタン等のクッション材も使用していないので伸長回復性の無い、へたりの大きなシートとなってしまった。(表3参照)
【0028】
(比較例2)
同じくカールマイヤー社製、5枚筬からなる9Gラッセル機(RMー6F)を用い、前筬2枚に表1記載の弾性糸、後ろ筬3枚に表2記載のポリエステル糸条を配し編物を作製した後、本文中に記載した方法で沈み量等の評価を実施した。
尚、伸長回復特性を付与する為L2の弾性糸は一針間の振り巾で挿入し、緯方向の伸長回復特性を付与させる為L1の弾性糸は四針間の振り巾で挿入する組織とした。(図3、図4参照)
得られた編物はインテリア用座席シートとして意匠性に乏しく、直接弾性糸が人体に触れる割合が高い為、着座感の硬い長時間の使用に向かないシートとなった。(表3参照)
【0029】
【表1】
【0030】
【表2】
【0031】
【表3】
【0032】
【発明の効果】
本発明によると、近年環境汚染等で問題視されている従来型のウレタンクッション材を使用せずとも良好なクッション性能と着座感が得られ、個人の嗜好に合う意匠性の付与されたリサイクル可能な椅子張り用若しくは車両用伸縮性編地、その製造方法及びシート成形方法を提供することを可能とした。
【図面の簡単な説明】
【図1】本発明の編組織図の一例。
【図2】本発明の糸入れ配置図の一例。
【図3】比較例2の編組織図。
【図4】比較例2の糸入れ配置図。
【符号の説明】
L1:第1筬、L2:第2筬。[0001]
BACKGROUND OF THE INVENTION
TECHNICAL FIELD The present invention relates to a stretch knitted fabric for interior, a method for producing the same, and a sheet forming method, and specifically, for a chair upholstery having good cushioning performance and seating feeling and designability without having a cushioning material such as urethane. Or, it relates to a stretchable knitted fabric sheet for vehicles.
[0002]
[Prior art]
Currently, urethane foam, polyester fiber-filled cotton, resin cotton bonded with polyester fiber, solid cotton, and the like are used as cushion materials for seats for chairs and vehicle seats. However, urethane foam has problems because it is difficult to handle chemicals used during production, discharges chlorofluorocarbons, and is difficult to recycle. Polyester foam stuffed cotton, resin cotton bonded with polyester fiber, As for cotton and the like, there is a problem that the cushioning property is lowered due to the sag on the fiber structure over time.
[0003]
Recently, fabrics using polyester elastic yarns and polyester processed yarns have been put on the market in order to solve these problems. However, these woven fabrics have a large proportion of the polyester elastic yarn that directly contacts the human body due to the structure of the woven fabric, and are very hard, and are not capable of withstanding long-term use, and have considerable limitations in terms of design.
[0004]
[Problems to be solved by the invention]
The present invention solves the problems of the conventional seats for chairs and vehicle seats, provides good cushioning performance without using cushioning materials, soft seating feeling that can withstand long-term use, and individual preference. The present invention relates to the provision of a stretchable knitted fabric for interior to which a suitable design property is imparted, a manufacturing method thereof, and a sheet forming method.
[0005]
[Means for Solving the Problems]
In order to solve the above problems, the present invention requires the following configuration. That is, the invention according to the present invention is a polyether ester having a breaking elongation (DE) of 50 to 200%, a total denier of 200 to 6000 denier, and a 160 ° C. dry heat shrinkage (SHD) of 12 to 60%. A knitted fabric in which a polyester-based fiber yarn having a total denier of 100 to 3000 denier is arranged on the front heel, and a 10% elongation of the knitted fabric has an elongation stress of 30 kgf / 5 cm or less. A stretch knitted fabric for interiors having a breaking strength in both directions of 50 kgf / 5 cm or more, preferably the polyetherester elastic yarn is a core-sheath type composite elastic yarn The stretchable knitted fabric for interior according to the above, wherein the polyetherester elastic yarn is fused to the adjacent yarn, A stretch knitted fabric for interiors as described above, wherein a flame retardant and / or a light resistance agent is applied to the ether ester elastic yarn, and the polyether ester elastic yarn has a 160 ° C. dry heat shrinkage (SHD) of polyester The stretchable knitted fabric for interior according to the above, characterized in that it is 5 to 50% higher than the 160 ° C. dry heat shrinkage (SHD) of the system fiber yarn.
[0006]
The invention according to the production method of the present invention is characterized by knitting by placing a polyether ester elastic yarn on the back side of a warp knitting machine comprising two or more warps and a polyester fiber yarn on the front side. A stretchable knitted fabric for interiors according to the above, characterized in that the yarn is knitted by knitting with dyed yarns made of polyester-processed yarn on at least two front wings. A method for producing a stretch knitted fabric for interior according to the above, wherein a part or all of the polyether ester elastic yarn is inserted with a single stitch structure, and a polyether ester elastic The method for producing a stretch knitted fabric for interior as described above, wherein the core-sheath type composite elastic yarn and the single component elastic yarn are alternately knitted as the yarn, and the polyether ester type after knitting Core-sheath type compound bullet Yarn sheath side above the melting point, a method for interiors for stretchable knitted fabric prepared above, wherein the heat treatment at a temperature lower than the core side melting point.
[0007]
Further, the invention according to the molding method of the present invention is characterized in that the above-mentioned knitted fabric is tension-fixed on all sides to a frame and then set by applying heat less than the melting point of the polyetherester elastic yarn. This is a sheet forming method for a knitted fabric.
The present invention is described in detail below.
[0008]
The polyether ester-based elastic yarn used in the present invention is a yarn comprising a block ether ester-based elastic body having an aromatic polyester, which uses aromatic dicarboxylic acid and glycol as main raw materials, as a hard segment and polyalkylene glycol as a soft segment. It is preferable that In particular, a terephthalic acid polyester composed of terephthalic acid and ethylene glycol or terephthalic acid and butanediol is used as a hard segment, and a polyether such as polyethylene glycol or polytetramethylene glycol is used as a soft segment. Furthermore, a polyetherester elastic yarn obtained by copolymerizing polybutylene terephthalate and polytetramethylene glycol has a good elongation recovery and is more preferable.
[0009]
The polyether ester elastic yarn thus obtained has a breaking elongation (DE) of 50% to 200%, a total denier of 200 to 6000 denier, and a 160 ° C. dry heat shrinkage (SHD) of 12% to 60%. The following is desirable. When the elongation at break is less than 50%, the seating feeling is hard, and when it exceeds 200%, the stretch recovery is weak, which is not preferable. Further, when the total denier is less than 200 denier, the production efficiency of the knitted fabric is poor, and conversely, when the total denier exceeds 6000 denier, the thickness cannot be handled by a general-purpose knitting machine. In addition, when the 160 ° C. dry heat shrinkage (SHD) is less than 12%, it is difficult to loosen during molding. Conversely, when it exceeds 60%, the balance with the polyester yarn controlling the design property is lost, and the physical properties of the fabric deteriorate. It is not preferable.
[0010]
The polyetherester elastic yarn is knitted together with a polyester fiber yarn having a total denier of 100 denier or more and 3000 denier or less.
The polyester fiber yarn used here is a polyethylene terephthalate multifilament yarn or a multifilament yarn obtained by copolymerizing polyethylene terephthalate with 5-sodium sulfonic acid metal salt or isophthalic acid as a main component. It is a yarn made of multifilament yarn containing an inert substance.
If this is less than 100 denier, the production efficiency is poor. Conversely, if it exceeds 3000 denier, it cannot be handled by a general-purpose knitting machine. Polyester fiber yarns are generally subjected to various yarn processing such as false twisting and taslan processing in order to improve the handleability, and either white yarn or pre-dyed yarn may be used. As described above, polyester fiber yarns are properly used depending on the purpose of design, but it is needless to say that the purpose of use is to improve the seating feeling, the design, and the product quality.
[0011]
The knitted fabric thus obtained preferably has a 10% weft elongation stress of 30 kgf / 5 cm or less and a breaking strength in both the weft directions of 50 kgf / 5 cm or more. When the stress at the time of 10% elongation exceeds 30 kgf / 5 cm, the seating feeling is hard and unfavorable. On the contrary, even when the stress at the time of 10% elongation is extremely low, the sinking amount is large and a good seating posture cannot be maintained. . Therefore, it is desirable that the stress in each direction at the time of 10% elongation is in the range of 3 to 20 kgf / 5 cm. Further, if the breaking strength in both directions is less than 50 kgf / 5 cm, it is not preferable because a problem of fabric breakage due to insufficient strength is likely to occur. Therefore, the higher the breaking strength, the better from the viewpoint of durability, but at the same time the cost increases. Therefore, it is desirable to design appropriately according to the purpose of use.
[0012]
In addition, the polyetherester elastic yarn is a core-sheath type composite elastic yarn, the polyetherester elastic yarn is fused with the adjacent yarn, the polyetherester elastic yarn is flame retardant and / or light resistant. It is desirable that the agent is applied, and that the 160 ° C. dry heat shrinkage of the polyetherester elastic yarn is 5 to 50% higher than the dry heat shrinkage of the polyester fiber yarn. Polyether ester-based elastic elastic yarn is a core-sheath type composite elastic yarn. When it is fused with an adjacent yarn, the knitted fabric form is stable, and when a flame retardant and / or a light-proofing agent are added, the quality is improved. Since both can be improved, both are preferable directions.
[0013]
The larger the melting point difference of the polyetherester-based core-sheath type elastic yarn, the better the handleability at the time of thermal bonding, but due to the problem of spinnability, the melting point difference is 60 to 20 ° C, preferably 50 to 30 ° C. Thus, it is preferable to increase the melting point on the core side. The melting point of the polyether ester elastic yarn constituting the polyether ester single component elastic yarn is 150 to 200 ° C., and in the case of the core-sheath type composite elastic yarn, the melting point of the core component is 150 to 200 ° C. The melting point is designed to be 60 to 20 ° C. lower than that. The core sheath has a core cross-sectional area ratio of 50% or more, preferably 70 to 95%, and the heat fusion treatment is preferably performed at a temperature 10 to 40 ° C. higher than the melting point on the sheath side. .
[0014]
Further, as a flame retardant, a method of adding melamine cyanurate or using a phosphorus copolymer is known, but the method is not limited to this, and the addition amount is 100 parts by weight of a polyether ester elastic yarn constituent. The range of 1 to 30 parts by weight is preferred. Further, the light-resistant agent is also known to be formulated by adding carbon black or the like, but is not limited thereto, and the addition amount is 0.1 to 5 parts by weight with respect to 100 parts by weight of the polyetherester-based elastic yarn component. The range of is preferable. In addition, it is preferable for the 160 ° C. dry heat shrinkage to be 5 to 50% higher than the dry heat shrinkage of the polyester fiber yarn, since the subsequent moldability can be improved.
[0015]
In addition, these knitted fabrics are knitted using a polyester-based elastic yarn on the back side of a warp knitting machine comprising two or more pieces of polyester ester-based elastic yarn, and polyester fiber yarns on the front side, preferably warp knitting. It is preferable that a dyed yarn made of polyester-processed yarn is used for at least two front ridges of the machine, and the design is given. This makes it possible to improve the soft seating feeling that can withstand long-term use and to provide a design that suits each person's preference.
[0016]
A part or all of the polyether ester elastic yarn is inserted in a single-swing structure, and the polyether ester core-sheath composite elastic yarn and the polyether ester single component elastic yarn are alternately arranged. Knitting, and heat-bonding the adjacent yarns by heat treatment at a temperature above the melting point of the sheath side of the polyetherester core-sheath type composite elastic yarn after knitting and below the melting point of the core side, etc. It is desirable to employ the manufacturing method because the knitted fabric form is more stable and the quality is improved.
[0017]
It is preferable that a part or all of the polyether ester elastic yarn is inserted in a single-waving structure because the elastic yarn's stretch properties are easily reflected directly on the fabric properties and the recoverability is improved. Further, in some cases, it is more preferable to insert a relatively fine denier polyetherester elastic yarn with a swing width of 2 stitches or more into the back heel to obtain a fabric having a planar stretch recovery characteristic. In addition, the polyetherester core-sheath type composite elastic yarn and the polyetherester single component elastic yarn are alternately arranged and knitted, so that the sealing effect is not too strong and the cushioning property is good. Become. The composition ratio is preferably an alternating arrangement, but the same effect can be obtained if it is in the range of 3: 1 to 1: 3.
[0018]
These are cushions having a stable form by a manufacturing method in which heat treatment is performed at a temperature not lower than the melting point of the sheath side of the polyetherester core-sheath type composite elastic yarn after knitting but lower than the melting point of the core side, and the adjacent yarns are thermally bonded. A fabric with good properties can be obtained.
The heat treatment is preferably performed at a temperature 10 to 40 ° C. higher than the melting point of the sheath.
[0019]
Further, if the method of setting the knitted fabric to the frame in tension on all sides and then applying the heat below the melting point of the polyetherester elastic yarn is set, the working efficiency can be greatly improved.
The knitted fabric mentioned here is preferably a warp knitted fabric produced by using a warp knitting machine such as a tricot or a Russell machine, but is not limited thereto.
Further, it is desirable that the stretch recovery characteristics of the fabric according to the present invention is a product that recovers 90% or more, more preferably 95% or more after elapse of 24 hours, when 10% stretches.
[0020]
【Example】
Hereinafter, the present invention will be described in detail by way of examples. In addition, the physical property in this invention and evaluation were calculated | required with the following method.
[0021]
1. The tensile strength of the fabric was measured using a Tensilon tensile tester manufactured by Orientec Co., Ltd., with a sample length of 200 mm, a test piece width of 50 mm, and a tensile speed of 100 mm / min. And the strong elongation at the time of a fracture | rupture and the stress at the time of 10% elongation were calculated | required from the obtained chart. Further, a new sample marked with a fixed point was set, applied with a stress at the time of 10% elongation read from the chart, and then allowed to stand at room temperature, and the elongation recovery characteristics after 24 hours were evaluated.
[0022]
2. Measurement of sinking amount (deflection) After fixing the sample in a 40cm square steel frame without slack at room temperature, heat treatment was performed in a hot air dryer at 170 ° C for 1 minute. Then, after positioning so that the center of a frame center part and the disk-shaped compression jig | tool with a radius of 10 cm fixed to the load cell may correspond, the stress of 45 kgf was applied and the amount of sinking at that time was measured. A good sinking amount is in a range of 20 to 60 mm.
[0023]
3. Melting | fusing point measurement The melt | dissolution peak temperature was measured with the nitrogen flow rate of 40 cc / min and the temperature increase rate of 20 degree-C / min using the SSC5200 type | mold differential scanning calorimeter by Seiko Denshi Kogyo.
[0024]
Example 1
Using a 9G Russell machine (RM-6F) made of KARL MAYER, and using the polyester yarns listed in Table-2 on the three foreheads, the design is improved and the seating feeling is improved. Two elastic yarns listed in Table-1 were used to produce a knitted fabric aimed at imparting a function of elongation recovery, and the amount of sinking was evaluated by the method described in the text. In addition, in order to improve the stretch recovery performance, the L4's rear heel has two 2000 denier elastic yarns aligned and inserted with a swing width between one stitch, and in order to provide a weft stretch recovery function, A structure was created in which a relatively fine denier elastic yarn was swung between four needles at the back end. (Refer to FIG. 1 and FIG. 2) The obtained knitted fabric had a good appearance and a feeling of sitting as an interior seat. In the evaluation of recovery characteristics, a product recovering 90% or more in 24 hours after 10% elongation was considered good, and the sitting feeling was evaluated by sensory evaluation of the subject. (See Table 3)
[0025]
(Example 2)
In the same way, using a 9G Russell machine (RM-6F) made of KARL MAYER, and using the polyester yarns listed in Table-2 on the front 3 sheets, while improving the design and the feeling of sitting After producing a knitted fabric aiming at providing a function of stretch recovery using the elastic yarns shown in Table-1 on the two back heels, the amount of sinking and the like were evaluated by the method described in the text. In order to improve the stretch recovery performance, as in Example 1, two 2000-denier elastic yarns are inserted into the rear end of L4 with a swing width between one stitch, giving a weft stretch recovery function. In order to do this, a structure in which a relatively fine denier elastic yarn was swung between four needles at the back of L5 was assembled. (See Figs. 1 and 2)
The obtained knitted fabric was tension-fixed on four sides to a metal frame and subjected to heat treatment at 170 ° C. for 1 minute. The obtained sheet had a stable fabric form and had a good appearance and seating feeling as an interior seat. (See Table 3)
[0026]
(Example 3)
Similarly, using a 12G Russell machine (RM-6F) made of 5 pieces of KARL MAYER, and using the polyester yarns listed in Table-2 on the front 3 sheets, while improving the expression of design and the feeling of sitting After producing a knitted fabric aiming at providing a function of stretch recovery using the elastic yarns shown in Table-1 on the two back heels, the amount of sinking and the like were evaluated by the method described in the text. In order to improve the stretch recovery performance, as in Example 1, two 2000-denier elastic yarns are inserted into the rear end of L4 with a swing width between one stitch, giving a weft stretch recovery function. In order to do this, a structure in which a relatively fine denier elastic yarn was swung between four needles at the back of L5 was assembled. (See Figs. 1 and 2)
The obtained knitted fabric was tension-fixed on four sides to a metal frame and subjected to heat treatment at 170 ° C. for 1 minute. Since the core-sheath type composite elastic yarn was inserted over the entire surface, the obtained sheet had a stable fabric form without misalignment, and had a good appearance and seating feeling as an interior seat sheet. (See Table 3)
[0027]
(Comparative Example 1)
Also using a 9G Russell machine (RM-6F) made of 5 pieces of KARL MAYER, using the same polyester yarn as the example on the front fore, and elastic yarns listed in Table 2 on the back fore Polyester yarn having an equivalent denier was knitted with the same structure as in the examples, and the amount of sinking was evaluated by the method described in the text.
The resulting knitted fabric has a good appearance as an interior seating sheet, but no elastic yarn is inserted, and since cushion materials such as urethane are not used, there is no stretch recovery and a large seat Oops. (See Table 3)
[0028]
(Comparative Example 2)
Similarly, using a 9G Russell machine (RM-6F) made of 5 pieces of KARL MAYER, elastic yarns listed in Table 1 are arranged on the front two pieces and polyester yarns shown in Table 2 on the three rear pieces, and knitted. Then, the amount of sinking and the like were evaluated by the method described in the text.
The elastic yarn of L2 is inserted with a swing width between one needle in order to give an extension recovery characteristic, and the elastic yarn of L1 is inserted with a swing width between four needles in order to give an extension recovery characteristic in the weft direction. did. (See Figs. 3 and 4)
The obtained knitted fabric has poor design as an interior seat, and the elastic yarn has a high ratio of direct contact with the human body. Therefore, the seat has a hard seat and is not suitable for long-term use. (See Table 3)
[0029]
[Table 1]
[0030]
[Table 2]
[0031]
[Table 3]
[0032]
【The invention's effect】
According to the present invention, good cushioning performance and seating feeling can be obtained without using a conventional urethane cushion material, which has been regarded as a problem in recent years due to environmental pollution, etc., and recyclable with a design that suits individual tastes. It is possible to provide a stretchable knitted fabric for chair upholstery or vehicle, a manufacturing method thereof, and a sheet forming method.
[Brief description of the drawings]
FIG. 1 is an example of a knitting organization chart of the present invention.
FIG. 2 is an example of a thread placement layout according to the present invention.
3 is a knitting structure diagram of Comparative Example 2. FIG.
FIG. 4 is a layout view of thread insertions in Comparative Example 2;
[Explanation of symbols]
L1: 1st cage, L2: 2nd cage.
Claims (11)
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US6688143B2 (en) * | 2001-12-05 | 2004-02-10 | Milliken & Company | Elastomeric knit fabric with antiflame properties |
AU2003254800A1 (en) * | 2002-08-07 | 2004-02-25 | Kawashimaorimono Co., Ltd. | Elastic fabric and elastic face material |
JP4736087B2 (en) * | 2002-08-07 | 2011-07-27 | 株式会社川島織物セルコン | Elastic fabric |
JP3928179B2 (en) * | 2002-09-09 | 2007-06-13 | 株式会社川島織物セルコン | Elastic warp knitted fabric |
JP7305974B2 (en) * | 2018-02-22 | 2023-07-11 | 東レ株式会社 | Fabric body manufacturing method |
EP4273312A1 (en) * | 2021-01-29 | 2023-11-08 | Toray Industries, Inc. | Fabric, fabric object, and sheet |
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