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JP4427287B2 - Manufacturing method of wood cement board - Google Patents

Manufacturing method of wood cement board Download PDF

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JP4427287B2
JP4427287B2 JP2003295535A JP2003295535A JP4427287B2 JP 4427287 B2 JP4427287 B2 JP 4427287B2 JP 2003295535 A JP2003295535 A JP 2003295535A JP 2003295535 A JP2003295535 A JP 2003295535A JP 4427287 B2 JP4427287 B2 JP 4427287B2
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wood
mass
raw material
material mixture
cement board
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JP2005059513A (en
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浩之 矢野
秀雄 相澤
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Nichiha Corp
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Description

本発明は、例えば外壁材、屋根材等に使用される木質セメント板の製造方法に関するものである。   The present invention relates to a method for producing a wood cement board used for, for example, an outer wall material, a roof material and the like.

従来から木片、木質繊維束、木毛、木粉、木質パルプ等の木質補強材によって補強したセメント板である木質セメント板は、外壁材や屋根材のような建築板として多用されている。
該建築板を押出成形や抄造によって製造する場合、押出成形性や抄造性を考慮して最近では上記木質補強材として微小繊維状セルロースを含む木質セメント成形体が提供されている(例えば特許文献1、特許文献2参照)。
木質セメント板の製造方法としては、上記したように押出成形法、抄造法(湿式法)の他に型枠や搬送板上に原料混合物を撒布してマットをフォーミングし、該マットを圧締、養生、硬化せしめる乾式法あるいは半乾式法がある。
Conventionally, a wood cement board, which is a cement board reinforced with a wood reinforcing material such as a piece of wood, a wood fiber bundle, wood hair, wood powder, wood pulp, or the like, is often used as a building board such as an outer wall material or a roof material.
In the case where the building board is produced by extrusion molding or papermaking, recently, a wood cement molded body containing fine fibrous cellulose as the wood reinforcing material has been provided in consideration of extrusion moldability and papermaking properties (for example, Patent Document 1). , See Patent Document 2).
As described above, as a method for producing a wood cement board, in addition to the extrusion method and the papermaking method (wet method), the raw material mixture is spread on a formwork or a conveying plate, the mat is formed, and the mat is pressed. There are dry and semi-dry methods for curing and curing.

特開平10−29844号公報(〔請求項1〕)JP-A-10-29844 ([Claim 1]) 特公平6−99173号公報(〔請求項1〕)Japanese Patent Publication No. 6-99173 (Claim 1)

上記乾式法や半乾式法は押出成形法や抄造法に比べて生産性が非常に良く、木質セメント板の製造方法として望ましい方法であるが、木質補強材として上記微小繊維状セルロースを使用した木質セメント板の製造には、上記乾式法あるいは半乾式法は適用されていない。
本発明は、木質セメント板の木質補強材の使用量を減らしても、生産性が良く、強度が充分確保されるようにすることを課題とする。
The dry method and semi-dry method are very good in productivity compared with the extrusion method and papermaking method, and are desirable methods for producing a wood cement board. The dry method or semi-dry method is not applied to the production of cement board.
An object of the present invention is to ensure good productivity and sufficient strength even if the amount of wood reinforcing material used in the wood cement board is reduced.

本発明は上記従来の課題を解決するための手段として、搬送板としてベルトコンベア上に載置並列された基板上に、水硬性無機材料と木質補強材とを主体とする表裏層用原料混合物を、水分含有量が30〜50質量%になるように加水した上で、マット状に撒布し、次いでその上に、水硬性無機材料と木質補強材とを主体とする芯層用原料混合物を、水分含有量が30〜50質量%になるように加水した上で、マット状に撒布し、更にその上に、水硬性無機材料と木質補強材とを主体とする表裏層用原料混合物を、水分含有量が30〜50質量%になるように加水した上で、マット状に撒布して三層構造のマットをフォーミングし、該マットを圧締、養生、硬化せしめる三層構造の木質セメント板の製造方法であって、表裏層用原料混合物には、水硬性無機材料が30〜55質量%、木質補強材として目開き4.5mm以下のフレーク状の木片が12〜14質量%、目開き0.5〜1.5mmの粒径の木粉が2〜5質量%の量で含有されており、芯層用原料混合物には、水硬性無機材料が30〜55質量%、木質補強材として目開き4.5〜10mmのフレーク状の木片が2〜4質量%、木質繊維束が7〜10質量%の量で含有されており、表裏層用原料混合物と芯層用原料混合物のいずれか一方には、平均径0.01〜1μm、平均長さ100〜1000μmである微小繊維状セルロースが5質量%以下の量で含有されている木質セメント板の製造方法を提供するものである
更に上記微小繊維状セルロースは上記原料混合物に加水する時、水に分散して原料混合物に添加されることが好ましい。
As a means for solving the above-described conventional problems, the present invention provides a raw material mixture for front and back layers mainly composed of a hydraulic inorganic material and a wooden reinforcing material on a substrate placed on a belt conveyor as a conveying plate. Then, after adding water so that the water content becomes 30 to 50% by mass, it is spread in a mat shape, and then a core layer raw material mixture mainly composed of a hydraulic inorganic material and a wood reinforcing material is Water is added so that the water content becomes 30 to 50% by mass, and then spread in a mat shape. Further, a raw material mixture for front and back layers mainly composed of a hydraulic inorganic material and a wood reinforcing material is After adding water so that the content becomes 30 to 50% by mass, it is spread in a mat shape to form a three-layer mat, and the mat is pressed, cured, and hardened . It is a manufacturing method, and it is a raw material mixture for front and back layers 30 to 55% by mass of a hydraulic inorganic material, 12 to 14% by mass of flaky wood pieces having an opening of 4.5 mm or less as a wood reinforcing material, and wood powder having a particle size of 0.5 to 1.5 mm. It is contained in an amount of 2 to 5% by mass, and the raw material mixture for the core layer contains 30 to 55% by mass of a hydraulic inorganic material, and 2 pieces of flaky wood pieces having an opening of 4.5 to 10 mm as a wood reinforcing material. -4% by mass, wood fiber bundles are contained in an amount of 7-10% by mass, and either one of the front and back layer raw material mixture and the core layer raw material mixture has an average diameter of 0.01 to 1 μm and an average length The present invention provides a method for producing a wood cement board in which fine fibrous cellulose having a thickness of 100 to 1000 μm is contained in an amount of 5% by mass or less .
Furthermore, when the microfibrous cellulose is added to the raw material mixture, it is preferably dispersed in water and added to the raw material mixture.

〔作用〕
微小繊維状セルロースは非常に微小であり、かつ細いので原料混合物中に均一に分散し易く、また繊維間に粉体を取込みやすく、補強効果が大きいので、木質補強材全体の添加量を減らすことが出来る。
そして上記したように微小繊維状セルロースは非常に微小であり、かつ細いので該微小繊維状セルロースを混合した原料混合物はほぐれ易く、基板上に撒布し易く、均一な密度のマットをフォーミングすることが出来る。特に該微小繊維状セルロース以外の木質補強材として、木片や木質繊維束のような嵩高な絡みにくいものを使用すると、原料混合物の撒布作業性は一層良くなる。
更に該微小繊維状セルロースを使用すれば、板の表面が緻密になりかつ平滑になる。したがって吸湿吸水性が抑制され、耐クラック性、耐凍結安定性が向上する。
[Action]
Microfibrous cellulose is very fine and thin, so it is easy to disperse uniformly in the raw material mixture, and it is easy to take in powder between fibers, and the reinforcing effect is great, so the amount of added wood reinforcing material is reduced. I can do it.
As described above, since the microfibrous cellulose is very fine and thin, the raw material mixture in which the microfibrous cellulose is mixed is easy to loosen, spread on the substrate, and form a mat with a uniform density. I can do it. In particular, when a wood reinforcing material other than the microfibrous cellulose, such as a piece of wood or a bundle of wood fibers, which is not easily entangled, is used, the workability of the raw material mixture is further improved.
Furthermore, if the microfibrous cellulose is used, the surface of the plate becomes dense and smooth. Accordingly, moisture absorption is suppressed, and crack resistance and freeze resistance are improved.

〔効果〕
本発明にあっては、木質補強材の添加量を減らしても強度の充分ある木質セメント板が提供される。そして本発明では木質セメント板を乾式法で製造するから非常に生産性が良好で安価に提供出来る。
以下に本発明を詳細に説明する。
〔effect〕
In the present invention, a wood cement board having sufficient strength even if the amount of wood reinforcement added is reduced is provided. In the present invention, the wood cement board is produced by a dry method, so that the productivity is very good and it can be provided at low cost.
The present invention is described in detail below.

〔水硬性無機材料〕
本発明において使用される水硬性無機材料としては、ポルトランドセメント、高炉セメント、シリカセメント、フライアッシュセメント、アルミナセメント等のセメント類を用いる。該セメント類は水存在下において水和反応によって硬化する。
[Hydraulic inorganic material]
As the hydraulic inorganic material used in the present invention, cements such as Portland cement, blast furnace cement, silica cement, fly ash cement, and alumina cement are used. The cements are hardened by a hydration reaction in the presence of water.

〔木質補強材〕
本発明に使用する木質補強材としては、木片、木粉、木質繊維、パルプ、木質繊維束、木毛、竹繊維、麻繊維等が例示される。
特に望ましい木質補強材としては、木片および/または木質繊維束がある。該木片としては巾0.5〜2mm、長さ1〜20mm、アスペクト比(長さ/厚み)20〜30の木片が使用され、木質繊維束としては、通常主幹の径が約0.1〜2.0mm、主幹の実長が約2〜35mm、更に望ましくは10〜30mmの範囲にあり、該木質繊維束は分枝および/または弯曲および/または折曲させた形状のものが望ましい。上記木片や木質繊維束は原料混合物中でほぐれ易く、均一に混合することが出来、また撒布作業性を向上せしめる。
[Wood reinforcement]
Examples of the wood reinforcing material used in the present invention include wood chips, wood powder, wood fibers, pulp, wood fiber bundles, wood wool, bamboo fibers, hemp fibers and the like.
Particularly desirable wood reinforcements are wood chips and / or wood fiber bundles. As the piece of wood, a piece of wood having a width of 0.5 to 2 mm, a length of 1 to 20 mm, and an aspect ratio (length / thickness) of 20 to 30 is used, and the wood fiber bundle usually has a main trunk diameter of about 0.1 to 0.1 mm. The actual length of the main trunk is in the range of about 2 to 35 mm, more preferably 10 to 30 mm, and the wood fiber bundle is preferably branched and / or bent and / or bent. The above-mentioned pieces of wood and wood fiber bundles are easily loosened in the raw material mixture, can be mixed uniformly, and improve the workability of spreading.

本発明では更に微小繊維状セルロースを添加する。該微小繊維状セルロースは、例えば繊維状セルロースの懸濁液を高圧下小径オリフィスに高速度で通過させることによって該繊維状セルロースを剪断力によって切断することによって製造される(特公昭60−19921号公報)。
該微小繊維状セルロースは、通常平均径0.01〜1μm、平均長さ100〜1000μmである。
上記微小繊維状セルロースも原料混合物中に均一に分散し易くかつほぐれ易いので、撒布作業性を向上せしめる。
In the present invention, fine fibrous cellulose is further added. The microfibrous cellulose is produced, for example, by cutting the fibrous cellulose by shearing force by passing a suspension of fibrous cellulose through a small diameter orifice under high pressure at a high speed (Japanese Patent Publication No. 60-19921). Publication).
The fine fibrous cellulose usually has an average diameter of 0.01 to 1 μm and an average length of 100 to 1000 μm.
Since the above-mentioned microfibrous cellulose is also easily dispersed uniformly in the raw material mixture and is easily loosened, the workability for spreading is improved.

〔第三成分〕
上記原料の他に更にセメントの一部をケイ砂、ケイ石粉、シリカヒューム、高炉スラグ、フライアッシュ、シラスバルーン、パーライト、ベントナイト、ケイソウ土等のケイ酸含有物質および/またはポゾラン物質で置換してもよいし、あるいは塩化カルシウム、塩化マグネシウム、塩化鉄、塩化アルミニウム、塩化ナトリウム、塩化カリウム、塩化リチウム等の塩化物の無水物あるいは結晶化物、硫酸アルミニウム、ミョウバン、硫酸鉄、硫酸リチウム、硫酸ナトリウム、硫酸カリウム、硫酸マグネシウム等の硫酸塩の無水物あるいは結晶化物、硝酸カルシウム、亜硝酸カルシウム等の硝酸塩、亜硝酸塩の無水物あるいは結晶化物、蟻酸カルシウム、酢酸カルシウム等の蟻酸塩、酢酸塩の無水化物あるいは結晶化物、アルミン酸ソーダ、水ガラス等のセメント硬化促進剤やワックス、パラフィン、シリコン等の撥水剤、発泡性ポリスチレンビーズ等の発泡性熱可塑性プラスチックビーズ等を添加してもよい。
[Third component]
In addition to the above raw materials, a part of the cement is further replaced with silica-containing materials such as silica sand, silica stone powder, silica fume, blast furnace slag, fly ash, shirasu balloon, perlite, bentonite, diatomaceous earth and / or pozzolanic materials. Or, anhydrous or crystallized chloride such as calcium chloride, magnesium chloride, iron chloride, aluminum chloride, sodium chloride, potassium chloride, lithium chloride, aluminum sulfate, alum, iron sulfate, lithium sulfate, sodium sulfate, Anhydrous or crystallized sulfates such as potassium sulfate and magnesium sulfate, nitrates such as calcium nitrate and calcium nitrite, anhydrous or crystallized nitrites, formates such as calcium formate and calcium acetate, and anhydrous anhydrides of acetate Or crystallized product, sodium aluminate, water Cement accelerators or wax such lath, paraffin, water repellent agents such as silicon, a foamable thermoplastic plastic beads such as expandable polystyrene beads may be added.

〔木質セメント板廃材粉砕物〕
本発明では更に木質セメント板廃材粉砕物を添加してもよい。該木質セメント板廃材粉砕物とは、木片、木質繊維束、木粉、木質パルプ等の木質補強材を使用した木質セメント板の廃材粉砕物であって、例えば外壁材や屋根材等に使用した建築物の取壊し、改修等の際に発生する廃材、あるいは該木質セメント板を製造する際に発生する切屑、端切れ等である。これらの廃材を粉砕物として木質セメント板原料に混合して木質セメント板の製造に再利用するものである。
上記木質セメント板廃材はハンマーミルによって通常0.5〜2.0mmの粒径の一次粉砕物に粉砕され、該一次粉砕物は木質セメント板原料の一部として再利用することが出来るが、更に該一次粉砕物をローラミルによって二次粉砕した二次粉砕物を原料として使用してもよい。本発明に使用される木質セメント板廃材粉砕物は比表面積が4000〜8000 cm2/g の程度とされることが望ましい。
[Wood cement board waste pulverized product]
In the present invention, a wood cement board waste material pulverized product may be further added. The wood cement board waste material pulverized material is a wood cement board waste material pulverized material using wood reinforcing material such as wood fragments, wood fiber bundles, wood powder, wood pulp, etc., for example, used for outer wall materials, roofing materials, etc. Waste materials generated when a building is demolished, repaired, or the like, or chips or cuts generated when the wood cement board is manufactured. These waste materials are mixed as a pulverized product with a wood cement board raw material and reused in the production of a wood cement board.
The wood cement board waste material is pulverized into a primary pulverized product having a particle size of 0.5 to 2.0 mm by a hammer mill, and the primary pulverized product can be reused as a part of the wood cement board raw material. A secondary pulverized product obtained by secondary pulverizing the primary pulverized product with a roller mill may be used as a raw material. The wood cement board waste material pulverized product used in the present invention preferably has a specific surface area of about 4000 to 8000 cm 2 / g.

〔原料調合〕
本発明にあっては、上記水硬性無機材料と上記木質補強材とを主体とする原料混合物中に水硬性無機材料は30〜80質量%、木質補強材は通常10〜40質量%添加される。上記原料混合物には所望なれば、上記第三成分を若干量添加され、それから上記原料混合物は水分含有量が30〜50質量%になるように加水される。
上記微小繊維状セルロースは上記原料混合物中に通常5質量%以下の量、望ましくは0.05質量%以上の量で添加されるが、該微小繊維状セルロースは他の木質補強材とは別に、加水時に水に分散して原料混合物に添加される。前記したように、該微小繊維状セルロースは水に均一に分散し易く、したがって水に分散させた状態で該微小繊維状セルロースを原料混合物に添加すれば、該微小繊維状セルロースを原料混合物に均一混合することが出来る。
[Raw material preparation]
In the present invention, 30-80% by mass of the hydraulic inorganic material and usually 10-40% by mass of the wooden reinforcing material are added to the raw material mixture mainly composed of the hydraulic inorganic material and the wooden reinforcing material. . If desired, a slight amount of the third component is added to the raw material mixture, and then the raw material mixture is hydrated so that the water content is 30 to 50% by mass.
The microfibrous cellulose is usually added to the raw material mixture in an amount of 5% by mass or less, preferably 0.05% by mass or more, but the microfibrous cellulose is separate from other wood reinforcing materials, At the time of hydration, it is dispersed in water and added to the raw material mixture. As described above, the microfibrous cellulose is easy to uniformly disperse in water. Therefore, if the microfibrous cellulose is added to the raw material mixture in a state of being dispersed in water, the microfibrous cellulose is uniformly added to the raw material mixture. Can be mixed.

〔木質セメント板の製造〕
本発明では木質セメント板の製造は一層あるいは三層構造の乾式法(半乾式法)が適用される。
本発明の一層構造の木質セメント板は原料混合物を基板上に散布してマットをフォーミングし、該マットを圧締養生硬化せしめることによって製造される。上記原料混合物は、通常上記水硬性無機材料30〜80質量%、木片および/または木質繊維束の木質補強材10〜40質量%、このようにして調製された原料混合物には更に、平均径0.01〜1μm、平均繊維長100〜1000μmの微小繊維状セルロース5質量%以下添加された水が30〜50質量%以下となるように添加され、セメント硬化促進剤が数質量%以下の量で添加調製される。このように調製された原料混合物は上記したように基板上に散布してマットをフォーミングし、該マットを圧締養生硬化せしめることによって製造される。
[Manufacture of wood cement board]
In the present invention, a dry method (semi-dry method) having a single layer or a three-layer structure is applied to the production of the wood cement board.
The single-layer wood cement board of the present invention is manufactured by spreading a raw material mixture on a substrate to form a mat, and then curing the mat by pressing and curing. The raw material mixture is usually 30 to 80% by mass of the hydraulic inorganic material, 10 to 40% by mass of the wood reinforcing material of wood pieces and / or wood fiber bundles, and the raw material mixture thus prepared further has an average diameter of 0. 0.01 to 1 μm, average fiber length of 100 to 1000 μm of microfibrous cellulose added in an amount of 5% by mass or less, added so that the amount of water is 30 to 50% by mass or less, and the cement hardening accelerator is an amount of several mass% or less. It is prepared by addition. The raw material mixture thus prepared is produced by spraying on a substrate as described above, forming a mat, and curing the mat by pressing and curing.

連続製造法においては、上記基板は搬送板として多数個ベルトコンベア上に載置並列せしめられる。
基板上に散布された原料混合物は所望なればロール等によって若干押圧されることによって厚みを調節され、かつ表面を平滑化されてマットとされ、該マットはそれから水分存在下で工程2の圧締予備硬化され、所望の形状に成形される。
In the continuous manufacturing method, a large number of the substrates are placed and placed on a belt conveyor as a transport plate.
If desired, the raw material mixture spread on the substrate is slightly pressed by a roll or the like to adjust the thickness, and the surface is smoothed to form a mat, which is then pressed in step 2 in the presence of moisture. It is pre-cured and formed into a desired shape.

圧締条件は通常圧締圧1〜3MPa 、温度60〜80℃、圧締時間6〜20時間程度で行われ、加熱は通常蒸気にて行われる。圧締は二つの基板間に上記マットを挟圧することによって行われるが、該基板面には所定の形状、凹凸模様等が施されてもよい。上記工程2の圧締予備硬化によって得られた予備硬化物は工程3においてオートクレーブ中にて養生される。   The pressing conditions are usually a pressing pressure of 1 to 3 MPa, a temperature of 60 to 80 ° C., a pressing time of about 6 to 20 hours, and heating is usually performed with steam. The pressing is performed by sandwiching the mat between two substrates, but a predetermined shape, uneven pattern, or the like may be applied to the substrate surface. The precured material obtained by the pressure precuring in Step 2 is cured in an autoclave in Step 3.

養生条件は通常圧力0.6〜1MPa 、温度160〜180℃、時間5〜10時間程度である。上記オートクレーブ養生によりセメントとケイ酸含有物質とのケイ酸カルシウム反応が行われる。
また工程3においては25℃の常温で7日間養生してもよい。ただしこの場合はケイ酸含有物質の配合比を下げて、セメントを増やした配合とすることが望ましい。
このようにして本発明の一層構造の木質セメント板が製造されるが、該木質セメント板の比重は通常0.8〜1.2である。
The curing conditions are usually a pressure of 0.6 to 1 MPa, a temperature of 160 to 180 ° C., and a time of about 5 to 10 hours. The autoclave curing causes a calcium silicate reaction between the cement and the silicate-containing substance.
Further, in step 3, curing may be performed at room temperature of 25 ° C. for 7 days. However, in this case, it is desirable to lower the mixing ratio of the silicic acid-containing substance and increase the cement.
In this way, the single-layered wood cement board of the present invention is produced, and the specific gravity of the wood cement board is usually 0.8 to 1.2.

三層構造の木質セメント板の場合、表裏層用の原料混合物Aの組成は、通常セメント30〜55質量%、ケイ酸含有物質15〜35質量%、木片の木質補強材5〜20質量%、木粉1〜8質量%、木質セメント板廃材粉砕物5〜30質量%、平均径0.01〜1μm、平均繊維長100〜1000μmの微小繊維状セルロース5質量%以下添加された水が30〜50質量%添加されて調製される。
芯層用の原料混合物Bの組成は、通常セメント30〜55質量%、フライアッシュ0〜25質量%、木片の木質補強材2〜15質量%、木質繊維束の木質補強材5〜20質量%、発泡ポリスチレンビーズ2〜3質量%、木質セメント板廃材粉砕物5〜40質量%、このようにして調製された原料混合物には、更に平均径0.01〜1μm、平均繊維長100〜1000μmの微小繊維状セルロース5質量%以下添加された水が30〜50質量%以下となるように添加されて調製される。
上記原料混合物A、Bには通常さらにセメント硬化促進剤が数質量%以下の量で添加される。
In the case of a three-layer structure wood cement board, the composition of the raw material mixture A for the front and back layers is usually 30 to 55% by mass of cement, 15 to 35% by mass of a silicic acid-containing substance, 5 to 20% by mass of wood reinforcing material of wood pieces, 1 to 8% by weight of wood powder, 5 to 30% by weight of pulverized wood cement board waste, 30 to 30% water added with 5% by weight or less of microfibrous cellulose having an average diameter of 0.01 to 1 μm and an average fiber length of 100 to 1000 μm It is prepared by adding 50% by mass.
The composition of the raw material mixture B for the core layer is usually 30 to 55% by mass of cement, 0 to 25% by mass of fly ash, 2 to 15% by mass of wood reinforcing material of wood pieces, and 5 to 20% by mass of wooden reinforcing material of wood fiber bundle. In addition, the polystyrene foam beads 2-3% by mass, the wood cement board waste material pulverized material 5-40% by mass, the raw material mixture thus prepared further has an average diameter of 0.01-1 μm and an average fiber length of 100-1000 μm. It is prepared by adding water so that 5% by mass or less of microfibrous cellulose is added to 30 to 50% by mass or less.
A cement hardening accelerator is usually added to the raw material mixtures A and B in an amount of several mass% or less.

上記表裏層の原料混合物Aの場合には、木質補強材として通常目開き4.5mm以下のフレーク状の木片や緻密構造を与えるために目開き0.5〜1.5mmの粒径の木粉等の微細木質補強材を使用し、また上記芯層の原料混合物Bの場合には粗構造を与えるために木質補強材として通常目開き4.5〜10mmのフレーク状の木片や平均径1.0mm、長さ20mm程度の木質繊維束等の粗大木質補強材を使用することが望ましい。   In the case of the above-mentioned raw material mixture A for the front and back layers, a wood powder having a particle size of 0.5 to 1.5 mm is usually used as a wood reinforcing material to give a flaky wood piece having a mesh size of 4.5 mm or less or a dense structure. In the case of the raw material mixture B for the core layer, a flaky wood piece having an opening of 4.5 to 10 mm or an average diameter of 1. It is desirable to use a coarse wood reinforcing material such as a wood fiber bundle of about 0 mm and a length of 20 mm.

三層構造の木質セメント板の製造方法としては、基板上に上記原料混合物Aをマット状に散布し、次いでその上に上記原料混合物Bをマット状に散布し、更にその上に上記原料混合物Aをマット状に散布するものである。木質補強材として木片と木質繊維束、特に上記分枝および/または弯曲および/または折曲させることによって嵩高くされた木質繊維束を用いると、原料混合物がほぐれ易くなり、型板上に均一に散布し易くなる。   As a method for producing a three-layer structure wood cement board, the raw material mixture A is spread in a mat shape on a substrate, and then the raw material mixture B is spread in a mat shape thereon, and further, the raw material mixture A is further formed thereon. Is sprayed in a mat shape. When wood fragments and wood fiber bundles, especially wood fiber bundles made bulky by bending and / or bending and / or bending, are used as the wood reinforcing material, the raw material mixture becomes easy to loosen and uniformly on the template. Easy to spread.

上記三層構造のマットは前記一層構造のマットと同様に圧締養生硬化される。オートクレーブ養生にあっては、一層構造のマットと同様、セメントとケイ酸含有物質とのケイ酸カルシウム反応が完全に行われるが、更に芯層に発泡性熱可塑性プラスチックビーズを添加した場合には該発泡性熱可塑性プラスチックビーズは完全に発泡し、発泡体粒は溶融してその後急速に収縮して芯層内部に多数の空孔が形成される。そして該空孔内壁面には熱可塑性プラスチックコーティング層が形成される。   The three-layer mat is pressed and cured in the same manner as the single-layer mat. In the autoclave curing, the calcium silicate reaction between the cement and the silicic acid-containing substance is completely carried out as in the case of the single-layer structure mat. However, when foaming thermoplastic beads are added to the core layer, The foamable thermoplastic beads are completely foamed and the foam particles melt and then rapidly shrink to form a number of pores within the core layer. A thermoplastic coating layer is formed on the inner wall surface of the hole.

このようにして製造された三層構造の木質セメント板の表裏層の厚みは通常全体の厚みの10〜30%、比重は0.8〜1.2である。   The thickness of the front and back layers of the three-layered wood cement board thus produced is usually 10 to 30% of the total thickness, and the specific gravity is 0.8 to 1.2.

前記したように微小繊維状セルロースはほぐれ易く、更に木質補強材として木片および/または木質繊維束を用いた場合には、該木片および/または木質繊維束もほぐれ易いので、結果として原料混合物が非常にほぐれ易くなり、基板上への撒布が容易であり、均一なマットをフォーミングすることが出来る。
以下に本発明を更に具体的に説明する。
As described above, the microfibrous cellulose is easily loosened, and further, when a piece of wood and / or a wood fiber bundle is used as a wood reinforcing material, the wood piece and / or the wood fiber bundle is also easily loosened. It is easy to loosen, it can be easily spread on the substrate, and a uniform mat can be formed.
The present invention will be described more specifically below.

[実施例1〜5、比較例1、2]
表1に示すように、セメント75質量%、木質補強材として木片20〜25質量%以下、微小繊維状セルロースを0.1〜5.0質量%添加した水45質量%を添加調製した実施例1〜5、また該微小繊維状セルロース無添加、7.0質量%添加した比較例1、2の各組成によって、板厚14.0mmの一層構造の木質セメント板試料を作成した。
[Examples 1 to 5, Comparative Examples 1 and 2]
As shown in Table 1, 75% by mass of cement, 20-25% by mass or less of wood pieces as a wood reinforcing material, and 45% by mass of water to which 0.1 to 5.0% by mass of fine fibrous cellulose was added were prepared. A single-layer wood cement board sample having a board thickness of 14.0 mm was prepared according to the compositions of Comparative Examples 1 and 2 to which 1 to 5 and no microfibrous cellulose were added and 7.0% by mass was added.

Figure 0004427287
Figure 0004427287

表1に示すように、微小繊維状セルロースを原料混合物中に5質量%以下の量で添加した実施例1〜5の試料は、曲げ強度は充分あり、かつクラックも発生しないが、微小繊維状セルロースが5質量%以上の量(7質量%)で添加されている比較例2の試料は逆に分散性が悪くなる傾向にあり、クラックが発生する。また木質補強材として木片を含んでも微小繊維状セルロースを含まない比較例1は曲げ強度が低い。   As shown in Table 1, the samples of Examples 1 to 5 in which microfibrous cellulose was added to the raw material mixture in an amount of 5% by mass or less had sufficient bending strength and cracks did not occur. On the contrary, the sample of Comparative Example 2 in which cellulose is added in an amount of 5% by mass or more (7% by mass) tends to have poor dispersibility, and cracks are generated. Moreover, even if it includes a piece of wood as a wood reinforcing material, Comparative Example 1 which does not contain fine fibrous cellulose has low bending strength.

[実施例6〜8、比較例3]
表2に示すように、セメント、ケイ砂、木質補強材として木片、木粉、微小繊維状セルロース、木質セメント板廃材粉砕物であるリジェクトを添加した表裏層用原料混合物、木片の一部と木粉に代えて木質繊維束、発泡ポリスチレンビーズを添加した芯層用原料混合物を用いた実施例6〜8、また表裏層、芯層共に微小繊維状セルロースを無添加とした比較例3の各組成によって、板厚16.0mmの三層構造の木質セメント板試料を作成した。
[Examples 6 to 8, Comparative Example 3]
As shown in Table 2, raw material mixture for front and back layers to which cement, quartz sand, wood chips, wood powder, fine fibrous cellulose, rejects that are pulverized wood cement board waste materials are added, part of wood and wood Each composition of Examples 6-8 which used the raw material mixture for core layers which added the wood fiber bundle and the expanded polystyrene bead instead of powder, and the comparative example 3 which did not add microfibrous cellulose to the front and back layers and the core layer Thus, a wood cement board sample of a three-layer structure having a board thickness of 16.0 mm was prepared.

Figure 0004427287
Figure 0004427287

実施例6〜8、比較例3の木質セメント板試料の物性を表3に示す。   Table 3 shows the physical properties of the wood cement board samples of Examples 6 to 8 and Comparative Example 3.

Figure 0004427287
Figure 0004427287

表3に示すように微小繊維状セルロースを含まない比較例3は実施例6,7,8よりも曲げ強度に劣る。   As shown in Table 3, Comparative Example 3 containing no fine fibrous cellulose is inferior in bending strength to Examples 6, 7, and 8.

本発明の木質セメント板は木質補強材の添加量を減らすことが出来、外壁材や屋根材等の建築材料に有用である。   The wood cement board of the present invention can reduce the amount of wood reinforcement added, and is useful for building materials such as outer wall materials and roof materials.

Claims (2)

搬送板としてベルトコンベア上に載置並列された基板上に、水硬性無機材料と木質補強材とを主体とする表裏層用原料混合物を、水分含有量が30〜50質量%になるように加水した上で、マット状に撒布し、次いでその上に、水硬性無機材料と木質補強材とを主体とする芯層用原料混合物を、水分含有量が30〜50質量%になるように加水した上で、マット状に撒布し、更にその上に、水硬性無機材料と木質補強材とを主体とする表裏層用原料混合物を、水分含有量が30〜50質量%になるように加水した上で、マット状に撒布して三層構造のマットをフォーミングし、該マットを圧締、養生、硬化せしめる三層構造の木質セメント板の製造方法であって、
表裏層用原料混合物には、水硬性無機材料が30〜55質量%、木質補強材として目開き4.5mm以下のフレーク状の木片が12〜14質量%、目開き0.5〜1.5mmの粒径の木粉が2〜5質量%の量で含有されており、
芯層用原料混合物には、水硬性無機材料が30〜55質量%、木質補強材として目開き4.5〜10mmのフレーク状の木片が2〜4質量%、木質繊維束が7〜10質量%の量で含有されており、
表裏層用原料混合物と芯層用原料混合物のいずれか一方には、平均径0.01〜1μm、平均長さ100〜1000μmである微小繊維状セルロースが5質量%以下の量で含有されている
ことを特徴とする木質セメント板の製造方法。
A substrate mixture placed on a belt conveyor as a transport plate and juxtaposed is mixed with a raw material mixture for front and back layers mainly composed of a hydraulic inorganic material and a wood reinforcement so that the water content is 30 to 50% by mass. Then, it was spread in a mat shape, and then a core layer raw material mixture mainly composed of a hydraulic inorganic material and a wood reinforcing material was added thereto so that the water content was 30 to 50% by mass. On top of the above, it is spread in a mat shape, and further, a raw material mixture for front and back layers mainly composed of a hydraulic inorganic material and a wood reinforcing material is added thereto so that the water content becomes 30 to 50% by mass. A method for producing a three-layered wood cement board which is distributed in a mat shape to form a three-layered mat, and the mat is pressed, cured and hardened .
The raw material mixture for the front and back layers is 30 to 55% by mass of a hydraulic inorganic material, 12 to 14% by mass of flaky wood pieces having an aperture of 4.5 mm or less as a wood reinforcing material, and an aperture of 0.5 to 1.5 mm. Containing 2 to 5% by weight of wood powder of
The raw material mixture for the core layer includes 30 to 55% by mass of a hydraulic inorganic material, 2 to 4% by mass of flaky wood pieces having an opening of 4.5 to 10 mm as a wood reinforcing material, and 7 to 10% by mass of a wooden fiber bundle. % Content,
Either one of the raw material mixture for the front and back layers and the raw material mixture for the core layer contains microfibrous cellulose having an average diameter of 0.01 to 1 μm and an average length of 100 to 1000 μm in an amount of 5% by mass or less. <br/> A method for producing a wood cement board characterized by the above.
上記微小繊維状セルロースは上記原料混合物に加水する時、水に分散して原料混合物に添加される請求項に記載の木質セメント板の製造方法。
The method for producing a wood cement board according to claim 1 , wherein when the fine fibrous cellulose is added to the raw material mixture, the fine fibrous cellulose is dispersed in water and added to the raw material mixture.
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