JP4424694B2 - Paint finishing method - Google Patents
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- JP4424694B2 JP4424694B2 JP2004047656A JP2004047656A JP4424694B2 JP 4424694 B2 JP4424694 B2 JP 4424694B2 JP 2004047656 A JP2004047656 A JP 2004047656A JP 2004047656 A JP2004047656 A JP 2004047656A JP 4424694 B2 JP4424694 B2 JP 4424694B2
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- resin emulsion
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- 239000003973 paint Substances 0.000 title claims description 22
- 238000000034 method Methods 0.000 title description 15
- 238000000576 coating method Methods 0.000 claims description 20
- 239000011248 coating agent Substances 0.000 claims description 18
- 239000000839 emulsion Substances 0.000 claims description 18
- 239000007921 spray Substances 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 17
- 239000011347 resin Substances 0.000 claims description 17
- 229920003002 synthetic resin Polymers 0.000 claims description 14
- 239000000057 synthetic resin Substances 0.000 claims description 14
- 238000005507 spraying Methods 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 6
- 239000010410 layer Substances 0.000 description 22
- 239000002585 base Substances 0.000 description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000000945 filler Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 239000000049 pigment Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 4
- 241000041388 Wallacea Species 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000012615 aggregate Substances 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 238000007665 sagging Methods 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 239000010455 vermiculite Substances 0.000 description 2
- 229910052902 vermiculite Inorganic materials 0.000 description 2
- 235000019354 vermiculite Nutrition 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- -1 acrylic ester Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
Description
本発明は意匠性に優れる塗装仕上げ方法に関し、詳しくは吹き付けガンを使用して仕上げる、意匠性に優れた塗装仕上げ方法に関するものである。 The present invention relates to a paint finishing method having excellent design properties, and more particularly to a paint finishing method having excellent design properties, which is finished using a spray gun.
従来、建築物の内外装の塗装仕上げ方法として、スプレー、ローラー、刷毛、鏝等の手段による意匠性に優れた塗装仕上げが採用されている。具体例としては、合成樹脂エマルジョンを主成分とするベース塗料を塗布してベース層を形成したのち、合成樹脂エマルジョン、軟質骨材、骨材等からなる上塗り塗料を鏝で引き延ばしながら塗布する際に該軟質骨材を鏝で潰しながら塗布仕上げする塗装仕上げ方法が開示されている(特許文献1参照)。さらに、合成樹脂エマルジョンを主成分とするベース塗料を塗布してベース層を形成したのち、合成樹脂エマルジョン、バーミキュライト、骨材等からなる上塗り塗料を鏝で塗布し、ついで上塗り層が乾燥しないうちに上塗り層の表面を水を含む刷毛で削り落とし、バーミキュライトの少なくとも一部を露出させる塗装仕上げ方法が開示されている(特許文献2参照)。
しかしながら、これら従来の塗装仕上げ方法は既に一般化された方法であるため、これまでにない意匠性を実現するためには更なる新規に塗装方法の開発が待たれていた。
反面、高度の熟練度を要する職人が年々減少して、熟練度を持たない作業者でも意匠性の高い塗装仕上げ方法が求められるような状況になっている。
However, since these conventional paint finishing methods are already generalized methods, development of a new coating method has been awaited in order to realize unprecedented design.
On the other hand, the number of craftsmen who require a high degree of skill is decreasing year by year, and even a worker who does not have the skill level is demanding a paint finishing method with a high design.
このような状況に鑑み、鋭意開発検討した結果、吹き付けガンによる塗装仕上げ方法により特有の風合いを持つ意匠性に優れた塗装仕上げ方法を確立するに至った。 In view of such a situation, as a result of earnest development and examination, it has come to establish a paint finishing method excellent in design with a unique texture by a paint finishing method using a spray gun.
第一工程として、合成樹脂エマルジョンを主成分とするベース樹脂を口径4〜6mmの吹き付けガンで0.5〜1.0kg/m2吹き付け、第二工程として、ベース樹脂と同一の合成樹脂エマルジョン、該樹脂固形分10重量部に対して、長さ0.5〜15mmのワラスサ0.1〜0.5重量部、骨材を含み、粘度250〜500Pa・s/30℃の上塗り塗料を、口径4〜6mmの吹き付けガンにより0.5〜2.0kg/m2吹き付け、表面仕上げする方法からなるものである。尚、コンクリート、モルタル等の下地からのアルカリ、しみ等を遮断するためにウレタン樹脂、エポキシ樹脂等の樹脂を有機溶剤に溶解した溶剤系シーラー若しくはウレタン樹脂、エポキシ樹脂等をエマルジョン化した水系のシーラーを適宜、これら下地に塗布してシーラー層を設けることがなされても良い。
As a first step, a base resin mainly composed of a synthetic resin emulsion is sprayed at 0.5 to 1.0 kg / m 2 with a spray gun having a diameter of 4 to 6 mm. As a second step, the same synthetic resin emulsion as the base resin is used . with respect to the resin solid content 10 parts by weight, Warasusa 0.1 to 0.5 parts by weight of length 0.5 to 15 mm, includes the aggregate, the top coat paint of viscosity 250~500 Pa · s / 30 ℃, It consists of a method of spraying 0.5 to 2.0 kg / m 2 with a spray gun having a diameter of 4 to 6 mm and finishing the surface. In addition, a solvent-based sealer in which a resin such as urethane resin or epoxy resin is dissolved in an organic solvent or an aqueous sealer in which urethane resin or epoxy resin is emulsified in order to block alkali, stains, etc. from the ground such as concrete and mortar. The sealer layer may be provided by appropriately applying to the undercoat.
ベース層上に上塗り層を吹き付けて仕上げる際に、口径4〜6mmの吹き付けガンにて、塗布量0.5〜2.0kg/m 2 程度吹付け、上塗り層を形成すると、ワラスサが露出した特有の風合いを持つ意匠性に優れた塗装仕上げに形成される。
When finish by blowing overcoat layer on the base layer at spray gun caliber 4 to 6 mm, coating weight 0.5~2.0kg / m 2 about spraying, to form a topcoat layer, specific to Warasusa is exposed It is formed into a paint finish with an excellent design with a texture of.
本発明における第一工程のベース層は合成樹脂エマルジョンを吹付けにより塗布することにより下地の不陸を調整し、上塗り層の付着性を確保するために形成させる。
ベース層のベース塗料には主成分の合成樹脂エマルジョンに骨材、充填材、顔料、増粘剤、分散剤、防カビ剤、防藻剤等を配合し、適度の流動性、塗布性を付与させることができる。
ベース塗料中の樹脂分は5〜25%が適当し、5%以下では粘着性、塗布性等が低下して好ましくない。また25%以上になると粘度が高くなる、添加剤、配合剤等の配合に制約が生じ好ましくない。
The base layer of the first step in the present invention is formed to apply the synthetic resin emulsion by spraying so as to adjust the unevenness of the base and ensure the adhesion of the overcoat layer.
The base layer base paint is blended with the main component synthetic resin emulsion with aggregates, fillers, pigments, thickeners, dispersants, fungicides, algae-proofing agents, etc. to give appropriate fluidity and coating properties. Can be made.
The resin content in the base paint is suitably 5 to 25%, and if it is 5% or less, the tackiness, applicability, etc. are unfavorable. On the other hand, if it is 25% or more, the viscosity becomes high, and there are restrictions on the blending of additives, blending agents, etc., which is not preferable.
第一工程のベース層の塗布量として0.5〜1.0kg/m 2 塗布する。
適正粘度としては250〜500Pa・s/30℃であり、250Pa・s/30℃以下ではタレが生じて好ましくない。また500Pa・s/30℃以上では塗布作業が難しくなり好ましくない。このような適正粘度にするためには添加剤の種類、配合量等の選定により調整することができる。
As a coating amount of the base layer in the first step, 0.5 to 1.0 kg / m 2 is applied.
The proper viscosity is 250 to 500 Pa · s / 30 ° C., and if it is 250 Pa · s / 30 ° C. or less, sagging occurs, which is not preferable. Further, if it is 500 Pa · s / 30 ° C. or higher, the coating operation becomes difficult, which is not preferable. In order to obtain such an appropriate viscosity, it can be adjusted by selecting the kind of additive, the blending amount, and the like.
前記の合成樹脂エマルジョンとして例示すれば、アクリル酸エステル共重合系樹脂、酢酸ビニル樹脂、エチレン・酢酸ビニル系樹脂、酢酸ビニル・アクリル酸エステル系樹脂、エチレン・塩化ビニル系樹脂、シリコン変性アクリル系樹脂、ウレタン系樹脂等の合成樹脂エマルジョンが使用され、これらには架橋タイプ、粉末型のエマルジョン等であっても使用できる。 Examples of the synthetic resin emulsion include acrylate copolymer resins, vinyl acetate resins, ethylene / vinyl acetate resins, vinyl acetate / acrylate resins, ethylene / vinyl chloride resins, and silicon-modified acrylic resins. Synthetic resin emulsions such as urethane resins are used, and these can be used even in cross-linked type, powder type emulsions and the like.
骨材の種類は、一般に塗料に配合されるものであれば何ら問題無く使用できる。
例示すれば、珪砂、炭酸カルシウム、山砂、ガラス粉砕物、セラミック粉砕物等があり、これらは塗布方法により適正なサイズのものが選定使用されればよい。
また、粉体状の充填材、顔料も適宜使用される。
充填材、顔料の例として炭酸カルシュウム、カオリン、クレー、陶土、珪藻土、タルク、酸化チタン、ホワイトカーボン、酸化鉄、ベンガラ等があり、更に前記のように増粘剤、分散剤、防カビ剤、防藻剤等が適宜配合される。
Any type of aggregate can be used without any problem as long as it is generally blended with a paint.
For example, there are silica sand, calcium carbonate, mountain sand, glass pulverized material, ceramic pulverized material, etc., and these may be appropriately selected according to the coating method.
In addition, powdery fillers and pigments are also used as appropriate.
Examples of fillers and pigments include calcium carbonate, kaolin, clay, porcelain clay, diatomaceous earth, talc, titanium oxide, white carbon, iron oxide, bengara and the like. An algae or the like is appropriately blended.
ベース層を形成後、吹き付けガンにより0.5〜2.0kg/m 2 の塗布量で上塗り層が形成される。
該上塗り層は主成分の合成樹脂エマルジョンとワラスサとを少なくとも配合したものからなり、その他の骨材、充填材、着色顔料、増粘剤、防カビ剤、防藻剤等が配合される。上塗り塗料の樹脂分は5〜25%が適合していて、5%以下では粘着性、塗布性等が確保しにくく好ましくない。25%以上ではコストが高くなり、また粘着性が高くなりすぎて作業性に難があり好ましくない。粘度に関しては250〜500Pa・s/30℃が適合し、250Pa・s/30℃以下では塗料がタレるため好ましくない。500Pa・s/30℃以上では塗布作業性が著しく悪くなるため好ましくない。主成分の合成樹脂エマルジョン、その他充填剤等の配合剤は前記下塗り層に使用したと同様なものが使用できる。
After forming the base layer, an overcoat layer is formed with a spray gun at a coating amount of 0.5 to 2.0 kg / m 2 .
The overcoat layer comprises at least a main component synthetic resin emulsion and a wallacea, and other aggregates, fillers , color pigments, thickeners, fungicides, algaeproofing agents, and the like. The resin content of the top coating material is 5 to 25%, and if it is 5% or less, it is difficult to secure the adhesiveness, coating property, etc., which is not preferable. If it is 25% or more, the cost becomes high, and the tackiness becomes too high, resulting in difficulty in workability. With respect to the viscosity, 250 to 500 Pa · s / 30 ° C. is suitable, and if it is 250 Pa · s / 30 ° C. or less, the paint sagging is not preferable. When it is 500 Pa · s / 30 ° C. or higher, the coating workability is remarkably deteriorated. Compounding agents such as a synthetic resin emulsion as a main component and other fillers can be the same as those used for the undercoat layer.
上塗り層に配合するワラスサは長さが0.5〜15mmの形状を呈するものであり、0.5mm以下では吹付けた時に、ワラスサが露出しないため好ましくない。また、15mm以上では吹付けの時に、吹き付けガンの先端にワラスサが詰まるため好ましくない。 The wallacesa to be blended in the topcoat layer has a shape with a length of 0.5 to 15 mm, and when it is 0.5 mm or less, it is not preferable because the wallacesa is not exposed when sprayed. On the other hand, when the diameter is 15 mm or more, the tip of the spray gun becomes clogged with the tip of the spray gun, which is not preferable.
ワラスサの配合量は表面層に使用される塗料中の樹脂固形分10重量部(以下部と称する)当たり0.1〜0.5部が適当し、0.1部以下では意匠性の発現が難しく目的を達成することができない。0.5部以上であってはワラスサ同士の重なり、凝集等のため仕上がりが悪くなるため好ましくない。
0.1 to 0.5 part is suitable for the blending amount of the wallacesa per 10 parts by weight (hereinafter referred to as “part”) of the resin solid content in the coating material used for the surface layer. Difficult to achieve purpose. An amount of 0.5 parts or more is not preferable because the finish is deteriorated due to the overlap and aggregation of the walls.
本発明による塗装仕上げ方法によれば、吹き付けガンによる塗装仕上げ方法により特有の風合いを持つ意匠性に優れた塗装仕上げ方法を確立するに至った。
このように吹き付けガンで様々な塗装仕上がりが特に高度の熟練度を要することなく実現できる。
According to the paint finishing method of the present invention, a paint finish method having a unique texture and excellent design properties has been established by a paint finishing method using a spray gun.
Thus, various painting finishes can be realized with a spray gun without requiring a high degree of skill.
実施例1
石膏ボード下地に固形分50%の酢酸ビニル・アクリル酸エステル系樹脂エマルジョン(以下樹脂エマルジョンという)20部に平均粒子径0.05〜0.2mmの硅砂を50部配合した粘度400Pa・s/30℃、樹脂固形分12.5%のベース塗料を口径4〜6mmの吹き付けガンにて吹き付け、厚み約0.3mmのベース層を形成したのち、ベース塗料と同一の樹脂エマルジョン20部にサイズが0.5〜15mmのワラスサを0.1部、充填材として粒度0.1〜0.2ミクロンの炭酸カルシウム、着色顔料として酸化チタンを各々、表1の通り配合した、粘度400Pa・s/30℃、樹脂固形分10.0%の上塗り層を吹き付けガンにより1.2kg/m2程度吹き付けた。結果は、ワラスサが露出した独特の吹き付け塗装仕上がりが得られた。
Example 1
Viscosity of 400 Pa · s / in which 20 parts of vinyl acetate / acrylic ester resin emulsion (hereinafter referred to as resin emulsion) having a solid content of 50% is mixed with 50 parts of sand with an average particle size of 0.05 to 0.2 mm on a gypsum board base. After spraying a base paint with a resin solid content of 12.5% at 30 ° C. with a spray gun having a diameter of 4 to 6 mm to form a base layer having a thickness of about 0.3 mm, the size of the resin emulsion is the same as 20 parts of the base paint. Viscosity of 400 Pa · s / in which 0.1 parts of 0.5 to 15 mm wallacesa, calcium carbonate having a particle size of 0.1 to 0.2 microns as a filler, and titanium oxide as a coloring pigment were blended as shown in Table 1. About 1.2 kg / m 2 was sprayed on the top coat layer at 30 ° C. and 10.0% resin solid content with a spray gun. As a result, a unique spray-painted finish with an exposed wallacea was obtained.
実施例2
実施例1と同一のベース層上に、実施例1の上塗り塗料の配合においてワラスサの配合量を0.5部、水25部とした以外は同一にして、粘度420Pa・s/30℃の上塗り塗料を調製し、吹き付けガンにより1.2kg/m 2 程度吹き付けた。結果は、ワラスサが露出した独特の吹き付け塗装仕上がりが得られた。
Example 2
On the same base layer as in Example 1, the viscosity of 420 Pa · s / 30 ° C. is the same except that in the formulation of the top coat of Example 1, the blending amount of Wallacesa is 0.5 part and 25 parts of water. A top coating was prepared and sprayed with about 1.2 kg / m 2 with a spray gun. As a result, a unique spray-painted finish with an exposed wallacea was obtained.
実施例3
実施例1と同一のベース層上に、実施例1の上塗り塗料の配合においてワラスサの配合量を0.5部、充填材の配合量を150部、水35部とした以外は同一にして、粘度420Pa・s/30℃の上塗り塗料を調製し、吹き付けガンにより1.2kg/m 2 程度吹き付けた。結果は、ワラスサが露出した独特の吹き付け塗装仕上がりが得られた。
Example 3
On the same base layer as in Example 1, the same composition as in Example 1 except that the blending amount of Wallacesa was 0.5 part, the blending amount of the filler was 150 parts, and water was 35 parts, A top coat with a viscosity of 420 Pa · s / 30 ° C. was prepared, and sprayed with a spray gun on the order of 1.2 kg / m 2 . As a result, a unique spray-painted finish with an exposed wallacea was obtained.
比較例1、2
実施例1と同一のベース層上に、実施例1の上塗り塗料の配合においてワラスサの配合量を0部、1.0部、水の配合量を15部、45部とする以外は実施例1と同一にして比較例1、2の上塗り塗料を調製し、吹き付けガンにより1.2kg/m 2 程度吹き付けた。結果は、比較例1では、ワラスサが配合されていないため意匠性の無い平坦な仕上がり状態であった。比較例2では、ワラスサの配合量が過大なため、塗料粘度が高くなりすぎて吹き付け作業がしずらい状態となり、吹き付けガンの先端にワラスサが詰まり施工ができなくなった。
Comparative Examples 1 and 2
Example 1 on the same base layer as in Example 1, except that the amount of Hurassa is 0 parts, 1.0 part, and the amount of water is 15 parts, 45 parts in the composition of the top coat of Example 1. The top coat of Comparative Examples 1 and 2 was prepared in the same manner as above, and sprayed by about 1.2 kg / m 2 with a spray gun. As a result, in Comparative Example 1, since the wallacesa was not blended, it was a flat finish without design. In Comparative Example 2, the amount of the wallacesa was excessive, so that the viscosity of the coating became too high, making the spraying operation difficult, and the tip of the spraying gun became clogged and the construction could not be performed.
比較例3
実施例1と同一のベース層上に、実施例1の上塗り塗料の配合においてワラスサの配合量を0.2部、水の配合量を25部とし、ワラスサの長さが20mm以上のものを使用した、以外は実施例1と同一にして比較例3の上塗り塗料を調製し、吹き付けガンにより1.2kg/m 2 程度吹き付けた。結果は、ワラスサが長いためガンの先端に詰まり施工ができなくなった。
Comparative Example 3
On the same base layer as in Example 1, in the formulation of the top coat of Example 1, 0.2% of the amount of Hurassa is blended, 25 parts of water is used, and the length of the Wallacesa is 20 mm or more. The top coat of Comparative Example 3 was prepared in the same manner as in Example 1 except that it was sprayed with about 1.2 kg / m 2 with a spray gun. As a result, because the wallacesa was long, it was clogged at the tip of the gun and could not be installed.
実施例、比較例の塗装仕上げ状態の結果は表1の通りである。
表1
Table 1 shows the results of the paint finishing states of the examples and comparative examples.
table 1
Claims (1)
In the first step, a base coating comprising a synthetic resin emulsion as a main component is applied to form a base layer, and in the second step, the synthetic resin emulsion and 10 wt parts of the resin solid content are long on the base layer. 0.1 to 0.5 parts by weight of 0.1 to 0.5 parts by weight of a wallet, 0.5 to 15 mm in thickness, and an overcoating paint having a viscosity of 250 to 500 Pa · s / 30 ° C. with a spray gun of 4 to 6 mm in diameter 5~2.0kg / m 2 spray coating to form a topcoat layer, painted wherein the finish up isosamples expose at least a part of the surface of the Warasusa.
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