JP4412598B2 - イオンポリマーゲル電解質およびその前駆体組成物 - Google Patents
イオンポリマーゲル電解質およびその前駆体組成物 Download PDFInfo
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- JP4412598B2 JP4412598B2 JP2004212276A JP2004212276A JP4412598B2 JP 4412598 B2 JP4412598 B2 JP 4412598B2 JP 2004212276 A JP2004212276 A JP 2004212276A JP 2004212276 A JP2004212276 A JP 2004212276A JP 4412598 B2 JP4412598 B2 JP 4412598B2
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
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- H—ELECTRICITY
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- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
- H01B1/122—Ionic conductors
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
- H01G11/56—Solid electrolytes, e.g. gels; Additives therein
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/181—Cells with non-aqueous electrolyte with solid electrolyte with polymeric electrolytes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/103—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
- H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. in situ polymerisation or in situ crosslinking
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0085—Immobilising or gelification of electrolyte
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- Power Engineering (AREA)
- Sustainable Energy (AREA)
- Sustainable Development (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Inorganic Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Dispersion Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Crystallography & Structural Chemistry (AREA)
- Secondary Cells (AREA)
- Conductive Materials (AREA)
- Primary Cells (AREA)
- Fuel Cell (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Hybrid Cells (AREA)
Description
Claims (6)
- 重合性のイオン対化合物(A)と、該イオン対化合物(A)との共重合が可能な不飽和基を2個以上有する架橋剤(B)と、非重合性のイオン対化合物(C)とからなり、
前記重合性のイオン対化合物(A)が、下記化学式Iで示される重合性モノマーであり、
前記架橋剤(B)が、トリアリルメチルアンモニウム、トリアリルエチルアンモニウム、トリアリルプロピルアンモニウム、トリアリルブチルアンモニウム、及びトリアリルヘキシルアンモニウムからなる群より一種以上選ばれてなるカチオン基と、
(CF 3 SO 2 ) 2 N - 、(FSO 2 ) 2 N - 、及び(NC) 2 N - からなる群より一種以上選ばれるアニオン基とからなるイオン対であるか、または、
ジアリルフタレート、ジアリルテレフタレート、トリアリルイソシアヌレート、及びトリメチロールプロパントリアリルエーテルからなる群より選ばれる1種以上の非イオン化合物であることを特徴とするイオンポリマーゲル電解質の前駆体組成物。
- 前記非重合性のイオン対化合物(C)におけるカチオン基が、プロトン、アルカリ金属イオン、アルカリ土類金属イオン、亜鉛イオン、カドミウムイオン、水銀イオン、希土類元素のイオン、ジアゾニウムイオン、ホスホニウムイオン、スルホニウムイオン、オキソニウムイオン、または、一般式NuR+で表される有機カチオンであることを特徴とする請求項1に記載のイオンポリマーゲル電解質。
なお、上記一般式NuR+において、Nuは、アンモニア、アルキルアミン、ピリジン、イミダゾール、アミジン、グアニジンまたはアルカロイドであり、Rは、炭素数1〜20のアルキル基もしくはオキシアルキル基、または炭素数6〜30のアリール基である。 - 前記重合性のイオン対化合物(A)が、ジアリルジメチルアンモニウムと、(FSO 2 ) 2 N - からなるイオン対化合物であることを特徴とする請求項1または2に記載のイオンポリマーゲル電解質の前駆体組成物。
- 前記架橋剤(B)が、トリアリルメチルアンモニウムと、(CF 3 SO 2 ) 2 N - とからなるイオン対であるか、または、トリアリルイソシアヌレート及びジアリルテレフタレートからなる群より選ばれる1種以上の非イオン化合物であることを特徴とする請求項1〜3のいずれかに記載のイオンポリマーゲル電解質の前駆体組成物。
- 前記非重合性のイオン対化合物(C)が、プロピルメチルイミダゾリウム、エチルメチルイミダゾリウム、エチルプロピルイミダゾリウム、トリメチルブチルアンモニウム、からなる群より一種以上選ばれるカチオン基と、(FSO 2 ) 2 N - 、(CF 3 SO 2 ) 2 N - 、及び(NC) 2 N - からなる群より一種以上選ばれるアニオン基とからなるイオン対化合物であることを特徴とする請求項1〜4のいずれかに記載のイオンポリマーゲル電解質の前駆体組成物。
- 請求項1〜5のいずれかに記載の前駆体組成物を重合してなるイオンポリマーゲル電解質。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004212276A JP4412598B2 (ja) | 2004-07-20 | 2004-07-20 | イオンポリマーゲル電解質およびその前駆体組成物 |
US11/184,263 US7279540B2 (en) | 2004-07-20 | 2005-07-18 | Ion-polymer gel electrolyte and its precursor composition |
CA2512326A CA2512326C (en) | 2004-07-20 | 2005-07-18 | Ion-polymer gel electrolyte and its precursor composition |
EP05015693A EP1619742B1 (en) | 2004-07-20 | 2005-07-19 | Ion-polymer gel electrolyte and its precursor composition |
DE602005026483T DE602005026483D1 (de) | 2004-07-20 | 2005-07-19 | Ionen-Polymergelelektrolyt und seine Vorläuferzusammensetzung |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004212276A JP4412598B2 (ja) | 2004-07-20 | 2004-07-20 | イオンポリマーゲル電解質およびその前駆体組成物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2006032237A JP2006032237A (ja) | 2006-02-02 |
JP4412598B2 true JP4412598B2 (ja) | 2010-02-10 |
Family
ID=35229856
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2004212276A Expired - Fee Related JP4412598B2 (ja) | 2004-07-20 | 2004-07-20 | イオンポリマーゲル電解質およびその前駆体組成物 |
Country Status (5)
Country | Link |
---|---|
US (1) | US7279540B2 (ja) |
EP (1) | EP1619742B1 (ja) |
JP (1) | JP4412598B2 (ja) |
CA (1) | CA2512326C (ja) |
DE (1) | DE602005026483D1 (ja) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
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JP5555407B2 (ja) | 2006-10-06 | 2014-07-23 | 株式会社クラレ | 高分子固体電解質、電気化学デバイス及びアクチュエータ素子 |
JP2008156430A (ja) * | 2006-12-22 | 2008-07-10 | Japan Carlit Co Ltd:The | 帯電防止用組成物および帯電防止ハードコート形成物 |
JP5041518B2 (ja) * | 2007-04-05 | 2012-10-03 | 日本カーリット株式会社 | 帯電防止用組成物および帯電防止ハードコート形成物 |
GB0722631D0 (en) * | 2007-11-17 | 2007-12-27 | Novel Polymer Solutions Ltd | Method of encapsulating a substance |
CN102020748B (zh) * | 2009-09-17 | 2012-08-08 | 中国科学院化学研究所 | 聚合物-金属离子络合物凝胶电解质及其制备方法与应用 |
JP7163909B2 (ja) * | 2017-04-21 | 2022-11-01 | 昭和電工マテリアルズ株式会社 | 電気化学デバイス用電極の製造方法 |
JP6881570B2 (ja) * | 2017-04-21 | 2021-06-02 | 昭和電工マテリアルズ株式会社 | ポリマ電解質組成物及びポリマ二次電池 |
JPWO2018193628A1 (ja) * | 2017-04-21 | 2020-02-27 | 日立化成株式会社 | ポリマ電解質組成物及びポリマ二次電池 |
WO2018193630A1 (ja) | 2017-04-21 | 2018-10-25 | 日立化成株式会社 | 電気化学デバイス用電極及び電気化学デバイス |
JP6973477B2 (ja) * | 2017-04-21 | 2021-12-01 | 昭和電工マテリアルズ株式会社 | ポリマ電解質組成物及びポリマ二次電池 |
JP6981072B2 (ja) * | 2017-07-19 | 2021-12-15 | 昭和電工マテリアルズ株式会社 | ポリマ電解質組成物及びポリマ二次電池 |
JP6981071B2 (ja) * | 2017-07-19 | 2021-12-15 | 昭和電工マテリアルズ株式会社 | ポリマ電解質組成物及びポリマ二次電池 |
CN118248936A (zh) * | 2023-02-13 | 2024-06-25 | 深圳市固易能科技有限责任公司 | 包含离子型聚合物的凝胶电解质锂离子电池及制备方法 |
CN117039140B (zh) * | 2023-08-14 | 2025-05-06 | 江西师范大学 | 一种具有垂直取向孔道的凝胶聚合物电解质及其制备方法和应用 |
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EP1391952A3 (fr) * | 1996-12-30 | 2016-04-27 | Hydro-Quebec | Sels d'anions pentacycliques ou dérivés de tétrazapentalène, et leurs utilisations comme matériaux à conduction ionique |
JPH10265673A (ja) | 1997-03-25 | 1998-10-06 | Mitsubishi Chem Corp | 高分子化合物複合体及びその製造方法 |
AU2003264517A1 (en) * | 2002-09-20 | 2004-04-08 | Nisshinbo Industries, Inc. | Composition for polyelectrolytes, polyelectrolytes, electrical double layer capacitors and nonaqueous electrolyte secondary cells |
-
2004
- 2004-07-20 JP JP2004212276A patent/JP4412598B2/ja not_active Expired - Fee Related
-
2005
- 2005-07-18 US US11/184,263 patent/US7279540B2/en not_active Expired - Fee Related
- 2005-07-18 CA CA2512326A patent/CA2512326C/en not_active Expired - Fee Related
- 2005-07-19 DE DE602005026483T patent/DE602005026483D1/de active Active
- 2005-07-19 EP EP05015693A patent/EP1619742B1/en not_active Not-in-force
Also Published As
Publication number | Publication date |
---|---|
CA2512326A1 (en) | 2006-01-20 |
US20060020093A1 (en) | 2006-01-26 |
DE602005026483D1 (de) | 2011-04-07 |
CA2512326C (en) | 2011-02-15 |
EP1619742B1 (en) | 2011-02-23 |
EP1619742A3 (en) | 2009-04-01 |
US7279540B2 (en) | 2007-10-09 |
EP1619742A2 (en) | 2006-01-25 |
JP2006032237A (ja) | 2006-02-02 |
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