JP4497447B2 - Pulsed DC sputtering film forming method and film forming apparatus for the method - Google Patents

Description

[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a pulsed direct current sputtering film forming method and a film forming apparatus for the method, and in particular, substantially uniform on a contact hole, a through hole, a side wall or a bottom of a wiring groove formed on the surface of a semiconductor substrate. The present invention relates to a thin film forming method for forming a seed layer used for forming a barrier layer or electrolytic plating with a film thickness.
[0002]
[Prior art]
For example, in the semiconductor field, the miniaturization has progressed, and the aspect ratio (depth / hole diameter or groove width) of holes and wiring grooves formed on a substrate tends to increase more and more. Usually, in semiconductor wiring using copper as the wiring material, a barrier layer having a uniform film thickness of several tens to several hundreds of centimeters or a seed for electrolytic plating is formed on the inside (side wall or bottom surface) of such a hole or groove. There is a demand to form a layer.
[0003]
In particular, for the barrier layer, a conductive material having a large specific resistance is often used. Therefore, when this layer is formed on the entire inner wall surface of the hole or groove, the minimum film thickness that can maintain the diffusion prevention effect is limited. However, it is desired to have a film thickness distribution that is uniform over the entire inner wall surface. Alternatively, similarly to this, it is desired that the barrier layer has a film quality capable of reliably maintaining the diffusion preventing effect while minimizing the use of a conductive material having a large specific resistance.
[0004]
In order to form a film having high performance in terms of film thickness and film quality, there is a strong demand for a sputtering film forming method. This is because cost and process stability can be expected.
[0005]
For the above-mentioned demands related to the film thickness, a bias sputtering method is conventionally known as a means for improving the coverage of unevenness on the substrate surface. In this method, a direct current or high frequency power is supplied to both the target and the substrate electrode, and a bias voltage is applied to the surface of the substrate placed on the substrate electrode to form a thin film.
[0006]
As this type of bias sputtering method, for example, those shown in Patent Document 1 and Patent Document 2 are known. These are configured to generate a bias voltage with respect to the substrate, prevent the formation and growth of overhangs at the hole opening due to the reverse sputtering effect, and resputter the deposition material deposited on the bottom of the hole. By depositing on the side wall, a uniform film is formed on the inner wall of the hole.
[0007]
By the way, the holes and wiring trenches that are the targets of this film forming method have a high aspect ratio and are fine and complex shapes. When a barrier film is formed on these, holes and wiring grooves are formed in order to obtain a reliable diffusion preventing effect. It is necessary to form a very thin coating film with a uniform thickness over the entire surface of the substrate including the inner wall and bottom of the wiring groove.
[0008]
However, according to the study by the present inventors, when a film is formed by using only a constant substrate bias voltage as in the above-described prior art, a hole having an aspect ratio of about 5 or less or an opening size of 0.1 μm or more is used. Although effective for substrates with wiring grooves, etc., if the aspect ratio is larger or the aperture size is smaller, the place where resputtered particles adhere is limited to the place where there is a hole or a side wall in the groove. concentrate. In other words, since the coating film formed by resputtering particles formed on the side wall portion is formed with an uneven film thickness distribution, it is difficult to make the film thickness uniform over the entire inner wall surface of the hole or groove. It has been found. It has also been found that when the bias voltage on the substrate side is increased in order to secure the amount of film material adhering to the side wall, the overhang at the opening also increases.
[0009]
Furthermore, as a measure for improving the coverage, for example, a pulsed direct-current sputtering film forming method disclosed in Patent Document 3 or Patent Document 4 is known. In this case, since the voltage applied to the target is intermittently operated, when this is combined with the bias sputtering method described above, the overhang portion is reversed due to the substrate bias effect when the sputtering film formation by the target is stopped. It is expected that the growth of the overhang portion can be suppressed by being sputtered.
[0010]
On the other hand, what is shown in patent document 5 and patent document 6 is conventionally known about the thing regarding film quality among the said requests. These have an adhesion layer interposed between the seed layer and the barrier metal in order to stabilize the laminated structure, and a metal or a metal compound different from the barrier film is used as the adhesion layer material (Patent Document 5). Alternatively, a metal nitride having the same composition ratio as that of the barrier film is used (Patent Document 6).
[0011]
[Patent Document 1]
JP-A-8-264487 (page 5-10, FIG. 2-3)
[Patent Document 2]
JP 61-153275 A (pages 396-398, FIG. 1)
[Patent Document 3]
Japanese Patent Laid-Open No. 9-296266 (page 3, Fig. 1-2)
[Patent Document 4]
JP 61-261473 A (pages 396-397, FIG. 1)
[Patent Document 5]
JP 2001-284358 A (page 3-5, FIG. 3)
[Patent Document 6]
JP 2001-53077 A (page 4-5, FIG. 1)
[0012]
[Problems to be solved by the invention]
By the way, with respect to the above-mentioned measures regarding the film thickness, the duty ratio D of the sputtering power applied by the pulsed DC method is
D = Ton / (Ton + Toff) (1)
[Ton: Sputter power application time for cathode, Toff: Sputter power stop time for cathode]
And the instantaneous maximum power of sputtering changes depending on this.
[0013]
That is, the maximum power Pmax is relative to the average power Pave.
Pave = D × Pmax (2)
Therefore, the instantaneous maximum power when the duty ratio D is 0.1 is 10 times the average power, and the ionization efficiency increases instantaneously. Therefore, in this case, since an overhang exceeding the growth suppression effect expected at the time of Toff is formed, a simple combination of the bias sputtering film forming method and the pulsed DC sputtering film forming method is expected. It can be seen that uniform film thickness formation cannot be obtained.
[0014]
In the other related art related to film quality countermeasures, a new film forming process is required for forming the adhesion layer, which may be an impediment to improving the efficiency of the film forming process.
[0015]
In view of the above-mentioned problems, the present invention forms a film that ensures high film performance in terms of film thickness, film quality, etc., particularly on inner walls such as contact holes, through holes, and wiring grooves having a high aspect ratio. It is an object of the present invention to provide a pulsed direct current sputtering film forming method and a film forming apparatus for this method.
[0016]
[Means for Solving the Problems]
In order to solve the above-described problems, the present invention makes it possible to apply a variable bias voltage to a substrate side on which irregularities are formed in advance using a sputtering film forming method in which pulsed DC power is applied to a target. The duty ratio of the pulsed power is made variable while keeping the average power of the pulsed DC power constant, and the duty ratio is first set with the substrate bias voltage fixed to the initial value of the substrate bias voltage and the cathode voltage. While changing the thickness, a thin film is formed on the substrate having the unevenness, and then the duty ratio and the substrate bias are set so that the thickness of the thin film formed on each surface of the uneven sidewall and bottom becomes substantially uniform. The voltage is changed.
[0017]
Here, the initial film formation is performed while changing the duty ratio only with the substrate bias voltage fixed at an initial value, because initially the effect of ion irradiation is kept small and the film is formed using neutral particles. It is.
[0018]
Therefore, the duty ratio of the pulsed DC voltage applied to the target is also preferably large at the initial stage of bias sputtering, that is, the instantaneous maximum power is small.
[0019]
By the way, when a film is formed on a substrate surface having an uneven portion such as a contact hole by a pulsed direct current sputtering film forming method and a bias sputtering film forming method, the film thickness distribution on the surface of the side wall surface and the bottom surface of the hole is the ion intensity to be irradiated. There is a tendency to correlate with. That is, the duty ratio of the pulsed power under the condition of the constant average power directly connected to the ion intensity and the substrate bias voltage that changes the film thickness distribution according to the ion intensity are important factors for the correlation. This correlation is significant in the height direction of the side wall surface and the hole bottom surface, and therefore, the duty ratio function and the bias voltage function (respectively, the duty voltage function) that can eliminate the film thickness difference in the height direction of the side wall surface. Ratio, substrate bias voltage, application time, etc. will be variables). By controlling the increase / decrease of the duty ratio and substrate bias voltage with these functions, it is formed in the height direction of the sidewall surface of the uneven portion It becomes possible to eliminate the film thickness difference of the coating film to be made uniform.
[0020]
Similarly, there should be a duty ratio function and a bias voltage function that can eliminate the film thickness difference of the coating film between the substrate center side and the substrate edge side on the hole bottom surface. By controlling, the difference in film thickness of the coating film formed on the bottom surface of the uneven portion can be eliminated.
[0021]
Furthermore, not only the unevenness of the film thickness in the height direction of the side wall portion and the bottom surface is individually resolved, but also the side wall surface and the bottom portion are selected by appropriately selecting each of the above duty ratio functions and bias voltage functions. It is also possible to eliminate the difference in film thickness between both surfaces at the same time.
[0022]
This makes it possible to form a coating film having a uniform film thickness over the entire surface of the substrate, even on a coating surface having fine and complex irregularities.
[0023]
In this case, furthermore, by making the sputtered particles flying from the target incident substantially perpendicularly, the formation of an overhang generated at the opening such as a hole is suppressed, and a considerable amount of deposited film can be retained at the bottom of the unevenness. . For this reason, if a pulsed direct current sputtering film forming method combined with bias sputtering film forming using the deposited film at the bottom as a film forming source is performed, film formation on the side wall can be surely performed and the uniform film formation described above can be performed. The selection range of the duty ratio function and the bias voltage function that enables this is widened.
[0024]
As an example of the substantially perpendicular incidence of the sputtered particles described above, the distance between the target and the substrate is set to a separation distance that exceeds the diameter of the wafer to be used, and the mean free path of the sputtered particles sets this separation distance. This can be realized by performing sputter deposition using a degree of vacuum higher than that. In some cases, a collimator may be inserted between the substrate and the target. However, this method requires attention because the collimator itself is sputtered and becomes a dust generation source.
[0025]
On the other hand, the present invention uses a sputtering film forming method in which a pulsed DC power is applied to a target, so that a reactive gas as a compound species can be introduced in advance and the average power of the pulsed DC power is kept constant. The duty ratio of the pulsed power can be made variable and the composition ratio of the metal compound thin film formed on the substrate can be varied by changing the duty ratio in a state where the reaction gas is introduced at a predetermined flow rate. .
[0026]
That is, when a film is formed on a substrate surface having an uneven portion such as a contact hole by a pulsed direct current sputtering film forming method, the film composition in the film thickness growth direction tends to correlate with the duty ratio. That is, since the instantaneous maximum power changes in accordance with the change in the duty ratio of the pulsed power under the condition that the average power is constant, it becomes an important factor that determines the compounding frequency of the compound type that depends on the maximum power. This correlation is conspicuous in the film thickness growth direction. Therefore, a duty ratio function (duty ratio, application time, etc. becomes a variable) that can control the film composition of the coating film in the depth direction of the side wall surface or bottom. By controlling the increase / decrease of the duty ratio by these functions, the film composition of the coating film formed in the depth direction of the side wall surface and the bottom surface of the concavo-convex portion can be made different. In this way, even when the adhesion layer having a different composition ratio is formed while the metal compound layer is of the same type as the barrier layer, it is not necessary to change the flow rate setting of the reaction gas as in the prior art. In addition, it is possible to switch to the formation of a thin film having a film composition changed to a desired composition ratio by increasing or decreasing the duty ratio without considering the response delay which is unavoidable with such a flow rate change.
[0027]
In addition, the coating film formed in this way has good coating characteristics, particularly a substantially uniform film thickness distribution on the uneven inner surface (side wall surface or bottom surface), and is also required for functional films such as adhesion layers. Therefore, it is useful as a barrier layer for copper wiring and as a seed layer during electrolytic plating film formation.
[0028]
Thereby, if the barrier layer and the adhesion layer are formed with the minimum film thickness having a diffusion preventing function, the advantage of using the copper wiring having a smaller electric resistance than aluminum can be efficiently utilized. In addition, even when used as a seed layer for electrolytic plating or an adhesion layer associated therewith, uniform plating film formation is possible, and generation of voids in the wiring can be suppressed.
[0029]
Then, in order to perform film formation with a desired film thickness distribution by the pulsed DC sputtering film forming method described above, an AC or DC power source with variable output for the substrate electrode and a constant average power for the cathode are used. A pulsed direct current power source capable of outputting with a variable duty ratio and a control system are provided. This control system is a pulsed cathode when the substrate and the target are separated by a predetermined distance in advance under a predetermined substrate bias voltage condition. Two-component reference data of the voltage duty ratio and the film thickness distribution of the thin film on each surface corresponding to the duty ratio is stored. A film forming apparatus for controlling the output of the pulsed DC power supply can be configured by a duty ratio function obtained by selecting a duty ratio that makes the film thickness substantially uniform from reference data during film formation on each surface.
[0030]
The duty ratio function used here does not mean a mathematical function, but stores the duty ratio and the film thickness distribution of the thin film on each surface corresponding to the duty ratio as a reference data, and creates a database accordingly. This means that the duty ratio is appropriately changed so as to correct the film thickness, and includes setting the duty ratio to zero during an appropriate time interval in the middle of pulsed DC sputtering film formation.
[0031]
Furthermore, it is a matter of course that a better coating characteristic can be obtained by appropriately changing the duty ratio and controlling the amount of incident sputtered particles at the time of pulsed DC sputtering film formation.
[0032]
Note that the factors that influence the film thickness distribution include not only the duty ratio function but also the bias voltage function, and it is possible to obtain a desired film thickness distribution solution by simultaneously changing both factors. In order to avoid this, the control system of this apparatus creates and stores a duty ratio function for each predetermined substrate bias voltage.
[0033]
In addition, in order to perform film formation with a desired film composition by the pulsed direct current sputtering film forming method, a pulsed direct current power source that can output with a variable duty ratio under a condition where the average power is constant with respect to the cathode, a control system, The control system includes a duty ratio of a pulsed cathode voltage when a reaction gas is introduced at a predetermined flow rate, and a composition ratio of a metal compound layer formed on the substrate corresponding to the duty ratio. Two-component reference data is stored. At the time of film formation, a film forming apparatus that controls the film composition of the metal compound layer by selecting a duty ratio for combining the metal compound at a desired composition ratio from the reference data can be configured. As described above, the duty ratio function used here does not mean a mathematical function.
[0034]
DETAILED DESCRIPTION OF THE INVENTION
FIG. 1 is a schematic cross-sectional view of a film forming apparatus for performing pulsed direct current sputtering film formation (first aspect) of the present invention. The film forming chamber 1 is provided with an exhaust gas 2 and a gas inlet 3 connected to a vacuum exhaust system (not shown) on its side wall, and a sputter cathode 4 and a substrate stage 5 are disposed inside the film forming chamber 1. The Ta target 6 and the silicon substrate 7 placed on each of them are configured to face each other. At this time, the distance between the target 6 and the substrate 7 is set to be equal to or larger than the diameter (200 mm) of the substrate 7.
[0035]
Further, the sputter cathode 4 is connected to a cathode power supply 8 outside the apparatus, the substrate stage 5 is connected to an AC or DC power supply 9 outside the apparatus, and the cathode power supply 8 and the power supply 9 are connected to a pulsed DC voltage and a substrate bias voltage. Are connected to a control system 10 that respectively performs output control. Further, a holder 11a that can be rotationally driven by a motor 11 is disposed immediately above the cathode 4 outside the apparatus, and magnets 12a, 13a (N pole or S pole) and 12b, 13b (on the holder 11a) are provided. The S pole or the N pole) rotates during the sputtering film formation so that the magnetron sputtering film formation can be performed. Note that the connection portion 14 that connects the substrate stage 5 and the power source 9 has a structure that penetrates into the film forming chamber 1 via an insulator 15.
[0036]
Incidentally, a concave contact hole (not shown) is provided in the insulating film formed on the surface of the substrate 7 in order to perform wiring of the conductive material on the semiconductor substrate 7. In order to prevent the wiring material such as copper from diffusing inside the insulating film SiO ₂ , a conductive material (barrier metal or diffusion prevention film) having a relatively large electrical resistance such as Ta, TaN, TiN, WN, etc. ) To prevent deterioration of semiconductor performance.
[0037]
Such a barrier metal film needs to cover the entire inner wall surface of the hole while maintaining a good covering accuracy, that is, a thin and uniform film thickness. The film forming apparatus shown in FIG. 1 is used to form a barrier metal film made of Ta on the inner wall portion of the contact hole by using a pulsed direct current sputtering method and a bias sputtering method.
[0038]
As described above, when film formation is performed on a substrate surface having an uneven portion such as a contact hole by pulsed direct current sputtering film forming method and bias sputtering film forming method, the film thickness distribution on the surface of the sidewall surface and the bottom surface of the hole is ion In addition, the ion intensity depends on the duty ratio of the pulsed power under the condition of constant average power, and is an important factor in the change of the film thickness distribution in combination with the action of the substrate bias voltage. It is believed that there is.
[0039]
Thus, during the film formation, the film thickness difference on the inner surface of the recess can be eliminated by using a modulation technique for the duty ratio of the pulsed power. In other words, a film thickness distribution pattern under a predetermined condition is obtained in advance, and this is used as a database, and this is used to eliminate the film thickness difference on each surface at the opening, side wall, and bottom of the recess. By performing sputter film formation while selecting the duty ratio, a coating film having a uniform film thickness distribution can be obtained.
[0040]
An example of modulation obtained by operating the control system 10 with respect to the pulse voltage output from the cathode power supply 8 of FIG. 1 is shown in FIG.
[0041]
FIG. 2 shows three patterns of pulsed power waveforms of input times t ₁ , t ₂ , and t ₃ corresponding to powers P ₁ , P ₂ , and P ₃ , respectively. Since the average power is constant in each pattern, the maximum power decreases as the input time increases, that is, as the duty ratio D defined in (1) increases.
[0042]
Regarding the specific film thickness formation of the coating film, for example, at the time of the minimum power P _{1, the} overhang in the concave opening and the increase in the side wall coverage in the side wall are suppressed. Further, when the power is increased (for example, P ₂ → P ₃ ), the ion irradiation amount is increased, but the substrate bias voltage to be applied correspondingly is controlled by the control system 10 to increase the resputtering ratio. As a result, a method such as increasing the sidewall coverage becomes possible.
[0043]
In this embodiment, the local growth of the film thickness in the recess is referred to as overhang, sidewall coverage, and bottom coverage for each local area in the recess. The maximum thickness (%) of the growth portion of the opening, the maximum thickness (%) of the side wall growth portion with respect to the flat surface thickness, and the maximum thickness (%) of the bottom surface with respect to the flat surface thickness are defined.
[0044]
FIG. 3 shows local growth when a coating film is formed in a recess (hole diameter 0.2 μm, depth 0.85 μm) on the substrate 7 using the film forming apparatus of FIG.
[0045]
In FIG. 3, a to c are cases where a DC voltage (a) and a pulsed DC voltage (b and c) are used as cathode voltages, respectively. Furthermore, when using a pulsed DC voltage, the modulation pattern was set as follows.
b: D ₁ = 0.5, D ₂ = 0.33, D ₃ = 0.25
c: D ₁ = 0.5, D ₂ = 0.15, D ₃ = 0.1
[0046]
It can be seen that in both cases b and c, the overhang in the recess is reduced as compared with the case where a normal DC voltage is used. From these, it can be seen that the film thickness distribution in the recess approaches a flat one by changing the duty ratio and converging the maximum power to the optimum range.
[0047]
Moreover, the 2nd aspect of the pulsed direct-current sputtering film-forming method of this invention can be performed using the film-forming apparatus of FIG.
[0048]
That is, in the case where a barrier metal film made of tantalum nitride is formed in a concave contact hole on the insulating film formed on the surface of the substrate 7, in order to improve the adhesion or to reduce the specific resistance value. Therefore, the formation of a two-layer film composed of a TaN film and a Ta ₁₀ N film may be required.
[0049]
In this case, in the conventional sputter film forming method, the Ar / N ₂ flow rate ratio in the argon-nitrogen mixed gas introduced from the gas inlet 3 of the apparatus of FIG. In many cases, a bilayer film composed of the composition is formed.
[0050]
FIG. 4 shows Auger electron spectroscopy showing changes in the composition ratio in the film thickness growth direction when forming a bilayer film composed of a Ta ₂ N film / Ta ₁₀ N film each having a film thickness of 7.5 nm by switching the flow rate ratio. It is a spectrum. In FIG. 4, the Ar / N ₂ flow rate ratio is switched from 10/20 sccm to 10/5 sccm in the vicinity of the film thickness of 8 nm, but the response until the composition ratio finally changes is long. Change will be continuous. This is because the flow rate control is performed by the flow rate controller, but the remaining N ₂ amount continuously changes, and this is not suitable for barrier metal film applications that require film formation with the minimum film thickness. It is.
[0051]
As described above, the film composition in the direction of film growth by the pulsed DC sputtering film forming method correlates with the duty ratio and is considered to be an important factor that determines the compound frequency of the compound type depending on the instantaneous maximum power. It is done. Therefore, during film formation, the film composition in the film thickness growth direction can be made desired by using a modulation technique for the duty ratio of pulsed power. That is, a film composition pattern at a predetermined duty ratio is obtained in advance, and this is made into a database. Further, using this, sputter film formation is performed while selecting an optimum duty ratio for obtaining a desired film composition on each surface in the recess. By doing so, the film composition can be controlled according to the function.
[0052]
For example, when forming a tantalum nitride film, it is understood that the Ta / N ratio at a predetermined duty ratio has a good correlation as shown in FIG.
[0053]
FIG. 6 shows a composition in the direction of film thickness growth when a bilayer film composed of a Ta ₂ N film / Ta ₁₀ N film having a thickness of 7.5 nm is formed on the substrate 7 using the film forming apparatus of FIG. It is an Auger electron spectroscopy spectrum which shows a ratio change. That is, the Ar / N ₂ flow rate ratio is fixed to 10/4 sccm from the gas inlet 3 of the film forming apparatus of FIG. 1, and the duty ratio is set to 0 during the film formation with the argon-nitrogen mixed gas introduced. When switching from 0.07 to 0.7, the composition ratio of tantalum nitride changes discontinuously. As a result, a double-layered film of Ta ₂ N film / Ta ₁₀ N film having a desired film thickness of 7.5 nm is obtained. You can see that it was formed.
[0054]
In the present embodiment, the contact hole is a contact hole. However, the present invention is not limited to this, and a through hole, a wiring groove, or a simple step shape can be used as long as it is a side wall portion caused by the uneven shape on the substrate. Needless to say, this is applicable to. In addition, the second aspect of the present invention can be used to form any metal compound film regardless of the substrate shape.
[0055]
【The invention's effect】
As is apparent from the above description, the pulsed DC sputtering film forming method of the present invention can be applied to the height direction of the side wall portion and the concave portion when the coating film is formed on the side wall portion and bottom surface of the uneven portion on the substrate. Since the duty ratio of the pulsed DC power and the substrate bias power are increased / decreased so as to eliminate the film thickness difference of the coating film generated on the bottom surface of the film, the coating film can be formed with a uniform film thickness. Therefore, a coating film having a good film thickness distribution can be formed.
[0056]
In addition, the pulsed DC sputtering film forming method of the present invention increases or decreases the duty ratio of the pulsed DC power when forming a coating film on a substrate, thereby forming a metal compound film in a film growth direction with a desired composition. You can switch to a ratio.
[0057]
Therefore, when this coating film is used as a functional film such as a barrier layer, a plating seed layer, and an adhesion layer associated therewith, product quality can be improved.
[Brief description of the drawings]
FIG. 1 is a schematic cross-sectional view of a pulsed DC sputtering film forming apparatus according to the present invention. FIG. 2 is a diagram showing an example of modulation by a pulsed power waveform. FIG. 3 shows a state of local growth (coverage) of a coating film. Fig. 4 is an Auger electron spectroscopic spectrum showing the composition ratio change in the film thickness growth direction during the formation of a bilayer film by switching the flow rate ratio. Fig. 5 is a diagram showing the correlation between the duty ratio and the Ta / N composition ratio. FIG. 6 Auger electron spectroscopic spectrum showing composition ratio change in the film thickness growth direction when forming a bilayer film by the method of the present invention.
1 Deposition chamber 2 Exhaust port 3 Gas introduction b 6 Target 7 Substrate 8 Cathode power (pulsed DC power)
9 Substrate bias power supply 10 Control system

Claims (5)

In a sputtering film forming method in which pulsed DC power is applied to a target, a variable substrate bias voltage can be applied to a substrate side on which irregularities are formed in advance, and the average power of the pulsed DC power is kept constant. the duty ratio of the pulsed power is variable while, initially, in a state of fixing the substrate bias voltage to the initial value of the substrate bias voltage and the cathode voltage, the side of the overhang and the side wall of the concave opening A first step of forming a thin film on the substrate having the unevenness while reducing the duty ratio under the condition that an increase in wall coverage is suppressed, and then formed on each surface of the sidewall and bottom of the unevenness The duty ratio is reduced and the ion irradiation amount is increased so that the thickness of the thin film is substantially uniform, and the cathode is increased. And a second step of increasing the sidewall coverage by increasing the proportion of re-sputtering by controlling the substrate bias voltage applied in response to pressure, the duty ratio of the second step first A pulsed direct current sputtering film forming method, wherein the duty ratio is smaller than a duty ratio of a process. The pulsed DC sputter deposition method according to claim 1 , wherein sputtered particles flying from the target are incident substantially perpendicular to the substrate. The pulsed direct-current sputter deposition method according to claim 1 or 2 , wherein the thin film is used for a barrier layer or a seed layer for electrolytic plating. First, while fixing the substrate bias voltage to the initial value of the substrate bias voltage and the cathode voltage, under conditions where increase in sidewall coverage in the overhang and the side wall of the concave opening is suppressed, the duty The first step of forming a thin film on the substrate having the unevenness while reducing the ratio, and then the film thickness of the thin film formed on each surface of the sidewall and bottom of the unevenness is made substantially uniform In addition, the duty ratio is decreased, the ion irradiation amount is increased, and the substrate bias voltage to be applied corresponding to the cathode voltage is controlled to increase the resputtering ratio and increase the sidewall coverage . a pulsed direct sputtering deposition system which performs sputtering method characterized by having a second step, to the substrate electrode An AC or DC power source with variable output, a pulsed DC power source capable of outputting with a variable duty ratio under a condition where the average power is constant with respect to the cathode, and a control system, the control system having a predetermined substrate in advance Two-component reference data of the duty ratio of the pulsed cathode voltage when the substrate and the target are separated by a predetermined distance under the bias voltage condition and the film thickness distribution of the thin film on each surface corresponding to the duty ratio is stored. The output of the pulsed DC power supply is controlled by a duty ratio function obtained by selecting from the reference data a duty ratio that makes the film thickness substantially uniform at the time of film formation on each surface. A pulsed DC sputter deposition apparatus characterized in that the ratio is smaller than the duty ratio of the first step . Pulsed direct sputtering deposition system according to claim 4, sputtering particles flying from the target, characterized in that as incident substantially perpendicular to the substrate.

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