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JP3087504B2 - Manufacturing method of surface-coated tungsten carbide based cemented carbide cutting tools with excellent wear and fracture resistance - Google Patents

Manufacturing method of surface-coated tungsten carbide based cemented carbide cutting tools with excellent wear and fracture resistance

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Publication number
JP3087504B2
JP3087504B2 JP05063431A JP6343193A JP3087504B2 JP 3087504 B2 JP3087504 B2 JP 3087504B2 JP 05063431 A JP05063431 A JP 05063431A JP 6343193 A JP6343193 A JP 6343193A JP 3087504 B2 JP3087504 B2 JP 3087504B2
Authority
JP
Japan
Prior art keywords
cutting
hard coating
layer
coating layer
based cemented
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP05063431A
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Japanese (ja)
Other versions
JPH06246513A (en
Inventor
俊克 須藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
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Mitsubishi Materials Corp
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Priority to JP05063431A priority Critical patent/JP3087504B2/en
Publication of JPH06246513A publication Critical patent/JPH06246513A/en
Application granted granted Critical
Publication of JP3087504B2 publication Critical patent/JP3087504B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】この発明は、すぐれた耐摩耗性と
耐欠損性を有し、特に耐欠損性が要求される、例えば鋼
の高送り切削や高切込み切削などの重切削において、こ
れの高速切削に用いた場合にすぐれた耐摩耗性を発揮す
る表面被覆炭化タングステン(以下、WCで示す)基超
硬合金製切削工具の製造法に関するものである。
BACKGROUND OF THE INVENTION The present invention has excellent wear resistance and chipping resistance, and is particularly useful for heavy cutting such as high feed cutting and high cutting of steel, which requires chipping resistance. The present invention relates to a method for producing a surface-coated tungsten carbide (hereinafter, referred to as WC) -based cemented carbide cutting tool that exhibits excellent wear resistance when used for high-speed cutting.

【0002】[0002]

【従来の技術】従来、一般に、例えば鋼の通常条件での
連続切削や断続切削に、重量%(質量%)で(重量%と
質量%は実質的に同じ割合を示すので、以下、%は重量
%、すなわち質量%を示す)、Coおよび/またはNi
を主体とする金属結合相:5〜20%を含有し、残りが
WCを主体とする硬質相からなるWC基超硬合金基体の
表面に、化学蒸着法を用いて、Tiの炭化物、窒化物、
炭窒化物、炭酸化物、窒酸化物、および炭窒酸化物、並
びに酸化アルミニウム(以下、それぞれTiC、Ti
N、TiCN、TiCO、TiNO、およびTiCN
O、並びにAl2 3で示す)のうちの1種の単層また
は2種以上の複層からなる硬質被覆層を1〜15μmの
平均層厚で形成してなる表面被覆WC基超硬合金製切削
工具が用いられていることは良く知られるところであ
る。また、例えば特開平2−254144号公報に記載
されるように、耐欠損性を向上させ、もって例えば鋼の
高送り切削や高切込み切削などの重切削での耐摩耗性を
向上させる目的で、上記の表面被覆WC基超硬合金製切
削工具の表面にショットピーニングを施して、これを構
成する硬質被覆層中にクラックを積極的に一様に形成し
てなる表面被覆WC基超硬合金製切削工具も知られてい
る。
2. Description of the Related Art Conventionally, in general, for example, in continuous cutting or intermittent cutting of steel under ordinary conditions, in terms of weight% (mass%) (weight% and mass% show substantially the same ratio, the following Weight%, ie, weight%), Co and / or Ni
Metal bonded phase mainly composed of: 5-20%, the remainder being made of a hard phase mainly composed of WC. ,
Carbonitrides, carbonates, nitrides, and carbonitrides, and aluminum oxides (hereinafter, TiC, Ti
N, TiCN, TiCO, TiNO, and TiCN
O and Al 2 O 3 ), a surface-coated WC-based cemented carbide formed by forming a hard coating layer composed of one kind of single layer or two or more kinds of layers with an average layer thickness of 1 to 15 μm. It is well known that cutting tools are used. Further, for example, as described in JP-A-2-254144, for the purpose of improving fracture resistance, and thereby improving wear resistance in heavy cutting such as high-feed cutting or high-cut cutting of steel, for example. The surface-coated WC-based cemented carbide is obtained by subjecting the surface of the cutting tool made of the surface-coated WC-based cemented carbide to shot peening to form cracks positively and uniformly in a hard coating layer constituting the cutting tool. Cutting tools are also known.

【0003】[0003]

【発明が解決しようとする課題】一方、近年の切削加工
のFA化および省力化はめざましく、これに伴ない、切
削工具にも切削条件に影響を受けにくい汎用性が強く望
まれているが、上記の硬質被覆層にショットピーニング
形成クラックが一様に存在する従来表面被覆WC基超硬
合金製切削工具は、通常の条件での重切削ではすぐれた
耐摩耗性を示すものの、これを高速化した場合、摩耗進
行が著しく速くなり、比較的短時間で使用寿命に至るの
が現状である。
On the other hand, in recent years, it has been remarkable that FA and labor saving of cutting work have been remarkable, and accordingly, there has been a strong demand for versatility of cutting tools which is less affected by cutting conditions. Conventional surface-coated WC-based cemented carbide cutting tools, in which shot peening cracks are uniformly present in the above-mentioned hard coating layer, show excellent wear resistance in heavy-duty cutting under normal conditions, but have a higher speed. In such a case, the wear progresses remarkably rapidly, and the service life is currently reached in a relatively short time.

【0004】[0004]

【課題を解決するための手段】そこで、本発明者等は、
上述のような観点から、上記の硬質被覆層にショットピ
ーニング形成クラックが一様に分布する従来表面被覆W
C基超硬合金製切削工具のもつ問題点を解決すべく研究
を行なった結果、上記の表面被覆WC基超硬合金製切削
工具を製造するに際して、これを構成する硬質被覆層の
形成を2回に分けて行ない、最初に形成された硬質被覆
層、望ましくは硬質被覆層の全層厚に対する割合で20
〜80%の層厚の硬質被覆層にショットピーニング処理
を施して、これをショットピーニング形成クラック分布
層とし、ついで残りの硬質被覆層を同じく化学蒸着法に
て前記ショットピーニング形成クラック分布層の表面
に、形成すると、この結果製造された表面被覆WC基超
硬合金製切削工具は、硬質被覆層における前記基体側下
方部分のショットピーニング形成クラック分布層によっ
てすぐれた耐欠損性が確保され、一方残りの表面側上方
部分によってすぐれた耐摩耗性が確保されることから、
耐欠損性が要求される、例えば鋼の重切削を高速で行な
っても切刃に欠損やチッピングの発生なく、摩耗進行が
著しく抑制されるようになり、長期に亘ってすぐれた切
削性能を発揮するという研究結果を得たのである。
Means for Solving the Problems Accordingly, the present inventors have
From the viewpoint as described above, the conventional surface coating W in which the shot peening cracks are uniformly distributed in the hard coating layer.
As a result of conducting research to solve the problems of the cutting tool made of C-base cemented carbide, when manufacturing the above-mentioned surface-coated cutting tool made of WC-based cemented carbide, the formation of the hard coating layer constituting the cutting tool was 2 times. The hard coating layer formed first is preferably 20% in a ratio to the total thickness of the hard coating layer.
A shot peening treatment is applied to the hard coating layer having a thickness of about 80% to obtain a shot peening-formed crack distribution layer, and the remaining hard coating layer is also subjected to chemical vapor deposition to form a surface of the shot peening-formed crack distribution layer. When formed, the resulting surface-coated WC-based cemented carbide cutting tool has excellent fracture resistance due to the shot peening formed crack distribution layer in the lower portion of the hard coating layer on the base side, while remaining The superior upper part of the surface ensures excellent wear resistance.
Fracture resistance is required, for example, even if heavy cutting of steel is performed at high speed, the cutting edge will not be chipped or chipped, the wear progress will be significantly suppressed, and excellent cutting performance will be exhibited over a long period of time The research result was obtained.

【0005】この発明は、上記の研究結果にもとづいて
なされたものであって、Coおよび/またはNiを主体
とする金属結合相:5〜20%を含有し、残りがWCを
主体とする硬質相からなるWC基超硬合金基体の表面
に、1〜15μmの平均層厚を有する硬質被覆層を形成
するに際して、 (a)まず、化学蒸着法にて、TiC、TiN、TiC
N、TiCO、TiNO、TiCNO、およびAl2
3 のうちの1種の単層または2種以上の複層からなる硬
質被覆層を形成した後、これにショットピーニング処理
を施して、ショットピーニング形成クラック分布層と
し、 (b)ついで、上記(a)のショットピーニング形成ク
ラック分布層の表面に、同じく化学蒸着法にて、さらに
上記のTiC、TiN、TiCN、TiCO、TiN
O、TiCNO、およびAl2 3 のうちの1種の単層
または2種以上の複層からなる硬質被覆層を形成するこ
と、により耐摩耗性と耐欠損性のすぐれた表面被覆WC
基超硬合金製切削工具を製造する方法に特徴を有するも
のである。
The present invention has been made on the basis of the above-mentioned research results, and comprises a metal binder phase mainly composed of Co and / or Ni: 5 to 20%, with the balance being mainly composed of WC. When forming a hard coating layer having an average layer thickness of 1 to 15 μm on the surface of a WC-based cemented carbide substrate composed of a phase, (a) First, TiC, TiN, TiC
N, TiCO, TiNO, TiCNO, and Al 2 O
After forming a hard coating layer composed of one kind of single layer or two or more kinds of three layers, shot peening is performed on the hard coating layer to form a shot peening formed crack distribution layer. (B) a) On the surface of the shot peening formed crack distribution layer, the above-mentioned TiC, TiN, TiCN, TiCO, TiN
By forming a hard coating layer composed of a single layer of O, TiCNO, and Al 2 O 3 or a multilayer of two or more types, a surface coating WC having excellent wear resistance and chipping resistance can be obtained.
The present invention is characterized by a method of manufacturing a base cemented carbide cutting tool.

【0006】なお、この発明の切削工具の製造法におい
て、これを構成する基体の金属結合相の含有量を5〜2
0%としたのは、その含有量が5%未満では焼結性が低
下し、基体に十分な強度を確保することができず、一方
その含有量が20%を越えると硬さが低下し、基体自体
の摩耗進行が急激に加速されるようになるという理由に
よるものである。また、この発明の切削工具の製造法に
おいて、硬質被覆層の平均層厚を1〜15μmと限定し
たのは、その平均層厚が1μm未満では所望の耐摩耗性
向上効果が得られず、一方その平均層厚が15μmを越
えると、切刃に欠損やチッピング(微小欠け)が発生す
るようになるという理由にもとづくものである。
In the method of manufacturing a cutting tool according to the present invention, the content of the metal binder phase in the substrate constituting the cutting tool is set to 5 to 2%.
The reason why the content is set to 0% is that if the content is less than 5%, the sinterability deteriorates, and sufficient strength cannot be ensured for the substrate, while if the content exceeds 20%, the hardness decreases. This is because the wear of the substrate itself is rapidly accelerated. In the method for manufacturing a cutting tool according to the present invention, the average thickness of the hard coating layer is limited to 1 to 15 μm. If the average thickness is less than 1 μm, a desired effect of improving wear resistance cannot be obtained. When the average layer thickness exceeds 15 μm, it is based on the reason that chipping or chipping (micro chipping) occurs on the cutting edge.

【0007】[0007]

【実施例】つぎに、この発明の表面被覆WC基超硬合金
製切削工具の製造法を実施例により具体的に説明する。
原料粉末として、いずれも1〜6μmの範囲内の所定の
平均粒径を有するWC粉末、TiC粉末、TiN粉末、
TaC粉末、NbC粉末、Cr3 2 粉末、VC粉末、
Co粉末、およびNi粉末を用意し、これら原料粉末を
表1に示される配合組成に配合し、ボールミルで72時
間湿式混合した後、1ton/cm2(98MPa)の
圧力で圧粉体にプレス成形し、この圧粉体を、10〜1
00torr(1.3〜13KPa)の範囲内の所定の
2 分圧の窒素雰囲気中、1380〜1430℃の範囲
内の所定温度に1時間保持の条件で焼結してISO規格
SNMN432のスローアウェイチップ形状を有するW
C基超硬合金基体A〜Iを形成した。
Next, a method for producing a surface-coated WC-based cemented carbide cutting tool according to the present invention will be described in detail with reference to examples.
As the raw material powder, WC powder, TiC powder, TiN powder, each having a predetermined average particle size in the range of 1 to 6 μm,
TaC powder, NbC powder, Cr 3 C 2 powder, VC powder,
A Co powder and a Ni powder are prepared, and these raw material powders are blended in the composition shown in Table 1, wet-mixed for 72 hours by a ball mill, and then press-molded into a green compact at a pressure of 1 ton / cm 2 (98 MPa). Then, this green compact is 10-1
In a nitrogen atmosphere at a predetermined partial pressure of N 2 within a range of 00 torr (1.3 to 13 KPa), sintering is performed at a predetermined temperature within a range of 1380 to 1430 ° C. for 1 hour, and throw-away according to ISO standard SNNM432. W having a chip shape
C-base cemented carbide substrates A to I were formed.

【0008】ついで、上記基体A〜Iの表面に、通常の
化学蒸着装置を用い、表2に※印を付した組成および平
均層厚の単層または複層の硬質被覆層を形成し、これ
に、 ショット:0.4mmの平均粒径を有する鋳鉄球、 投射速度:60m/sec 、 投射時間:3分、 の条件でショットピーニングを施して、これをショット
ピーニング形成クラック分布層とし、引続いて、これの
上に同じく表2に示される組成および平均層厚の単層ま
たは複層の硬質被覆層を形成することにより本発明法を
実施し、硬質被覆層の基体側下方部分をショットピーニ
ング形成クラック分布層とした本発明表面被覆WC基超
硬合金製切削工具(以下、本発明被覆切削工具という)
1〜13それぞれを製造した。
Next, a single-layer or multiple-layer hard coating layer having a composition and an average layer thickness marked with * in Table 2 is formed on the surfaces of the substrates A to I using a conventional chemical vapor deposition apparatus. In addition, shot: cast iron ball having an average particle diameter of 0.4 mm, projection speed: 60 m / sec, projection time: 3 minutes, shot peening is performed, and this is used as a shot peening formed crack distribution layer. Then, the method of the present invention was carried out by forming a single-layer or multiple-layer hard coating layer having the same composition and average layer thickness as shown in Table 2, and shot peening the lower portion of the hard coating layer on the substrate side. A cutting tool made of a surface-coated WC-based cemented carbide of the present invention having a formed crack distribution layer (hereinafter, referred to as a coated cutting tool of the present invention)
1 to 13 were each manufactured.

【0009】また、比較の目的で、上記の基体A〜Iの
表面に、同じ化学蒸着装置を用い、上記の本発明法で製
造された本発明被覆切削工具1〜13のそれぞれに対応
した組成および平均層厚の硬質被覆層全体を形成した
後、 ショット:0.4mmの平均粒径を有する鋳鉄球、 投射速度:60m/sec 、 投射時間:3分、 の条件でショットピーニングを施して、硬質被覆層に一
様なクラック分布密度のショットピーニング形成クラッ
クを形成することにより従来法を行い、表面被覆WC基
超硬合金製切削工具(以下、従来被覆切削工具という)
1〜13をそれぞれ製造した。
For the purpose of comparison, the compositions corresponding to each of the coated cutting tools 1 to 13 of the present invention manufactured by the above-described method of the present invention using the same chemical vapor deposition apparatus on the surfaces of the above substrates A to I. And after forming the entire hard coating layer having an average thickness, shot: cast iron ball having an average particle size of 0.4 mm; projection speed: 60 m / sec; projection time: 3 minutes; The conventional method is performed by forming a shot peening forming crack having a uniform crack distribution density in the hard coating layer, and a cutting tool made of a surface-coated WC-based cemented carbide (hereinafter referred to as a conventional coated cutting tool).
1 to 13 were manufactured respectively.

【0010】つぎに、この結果得られた各種の被覆切削
工具について、クラック分布密度を検討するために、そ
の硬質被覆層の縦断面を顕微鏡観察し、これの基体界面
と最表面における長さ:1mm内に存在するクラック本数
を任意5個所について目視測定した。この測定結果を平
均値として表3,4に示した。
Next, in order to examine the crack distribution density of the various coated cutting tools obtained as a result, the longitudinal section of the hard coating layer was observed with a microscope, and the length of the hard coating layer at the interface between the substrate and the outermost surface was: The number of cracks within 1 mm was visually measured at any five locations. The measurement results are shown in Tables 3 and 4 as average values.

【0011】また、上記の各種被覆切削工具について、 被削材:SNCM439(硬さ:HB 260)の丸棒、 切削速度:230m/min 、 切込み:4mm、 送り:0.25mm/rev.、 切削時間:30分、 の条件での鋼の連続高切込み高速切削試験、並びに、 被削材:SNCM439(硬さ:HB 260)の丸棒、 切削速度:150m/min 、 切込み:4mm、 送り:0.25mm/rev.、 切削時間:30分、 の条件での鋼の連続高切込み切削試験を行ない、いずれ
の試験でも切刃の逃げ面摩耗幅を測定した。これらの測
定結果も表3,4に示した。
Further, the above-mentioned various coated cutting tool, work material: SNCM439 (Hardness: H B 260) round bar, Cutting speed: 230 m / min, cut: 4 mm, Feed: 0.25 mm / rev,. cutting time: 30 min, continuous high cut speed cutting test of the steel under the condition of, and, workpiece: SNCM439 (hardness: H B 260) round bar, cutting speed: 150 meters / min, cut: 4 mm, feed : 0.25 mm / rev., Cutting time: 30 minutes, a continuous high-cut cutting test of steel was performed, and the flank wear width of the cutting edge was measured in each test. These measurement results are also shown in Tables 3 and 4.

【0012】[0012]

【表1】 [Table 1]

【0013】[0013]

【表2】 [Table 2]

【0014】[0014]

【表3】 [Table 3]

【0015】[0015]

【表4】 [Table 4]

【0016】[0016]

【発明の効果】表1〜4に示される結果から、いずれの
被覆切削工具も耐欠損性にすぐれているので、耐欠損性
が要求される鋼の高切込み切削試験を行なっても切削速
度が150m/min の通常の切削条件では切刃に欠損や
チッピングが発生することはないが、切削速度が230
m/min の高速切削になると硬質被覆層の基体側下方部
分だけをショットピーニング形成クラック分布層とした
本発明被覆切削工具1〜13の方が、硬質被覆層全体を
ショットピーニング形成クラック分布層とした従来被覆
切削工具1〜13に比して一段とすぐれた耐摩耗性を示
すことが明らかである。上述のように、この発明の方法
によれば、表面被覆WC基超硬合金製切削工具は、すぐ
れた耐摩耗性と耐欠損性を有する表面被覆WC基超硬合
金製切削工具を製造することができ、したがってこれ
を、特に耐欠損性が要求される、例えば鋼の重切削に用
いた場合に、これを高速切削で行なっても摩耗進行が著
しく抑制されることから、長期に亘ってすぐれた切削性
能を発揮するのである。
According to the results shown in Tables 1 to 4, all the coated cutting tools are excellent in chipping resistance. Therefore, even if a high cutting depth test of steel requiring chipping resistance is performed, the cutting speed is reduced. Under normal cutting conditions of 150 m / min, there is no chipping or chipping on the cutting edge, but the cutting speed is 230 m / min.
In the case of high-speed cutting at m / min, the coated cutting tools 1 to 13 of the present invention, in which only the lower part of the hard coating layer on the substrate side is a shot peening-formed crack distribution layer, use the shot peening-formed crack distribution layer as the entire hard coating layer. It is clear that the abrasion resistance is much higher than that of the conventional coated cutting tools 1 to 13 described above. As described above, according to the method of the present invention, a surface-coated WC-based cemented carbide cutting tool can produce a surface-coated WC-based cemented carbide cutting tool having excellent wear resistance and chipping resistance. Therefore, when it is used for heavy cutting of steel, for example, which is required to have high fracture resistance, the wear progress is remarkably suppressed even when the cutting is performed at high speed. It demonstrates excellent cutting performance.

───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7,DB名) B23B 27/14 B23P 15/28 C04B 35/56 C23C 16/30 ──────────────────────────────────────────────────続 き Continued on the front page (58) Field surveyed (Int. Cl. 7 , DB name) B23B 27/14 B23P 15/28 C04B 35/56 C23C 16/30

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 Coおよび/またはNiを主体とする金
属結合相:5〜20重量%(質量%)を含有し、残りが
炭化タングステンを主体とする硬質相からなる炭化タン
グステン基超硬合金基体の表面に、1〜15μmの平均
層厚を有する硬質被覆層を形成するに際して、 (a)まず、化学蒸着法にて、Tiの炭化物、窒化物、
炭窒化物、炭酸化物、窒酸化物、および炭窒酸化物、並
びに酸化アルミニウムのうちの1種の単層または2種以
上の複層からなる硬質被覆層を形成した後、これにショ
ットピーニング処理を施して、ショットピーニング形成
クラック分布層とし、 (b)ついで、上記(a)のショットピーニング形成ク
ラック分布層の表面に、同じく化学蒸着法にて、さらに
上記のTiの炭化物、窒化物、炭窒化物、炭酸化物、窒
酸化物、および炭窒酸化物、並びに酸化アルミニウムの
うちの1種の単層または2種以上の複層からなる硬質被
覆層を形成すること、を特徴とする耐摩耗性および耐欠
損性のすぐれた表面被覆炭化タングステン基超硬合金製
切削工具の製造法。
1. A tungsten carbide-based cemented carbide substrate comprising a metal binder phase mainly composed of Co and / or Ni: 5 to 20% by weight (mass%), the remainder being a hard phase mainly composed of tungsten carbide. When a hard coating layer having an average layer thickness of 1 to 15 μm is formed on the surface of (a), first, a carbide, nitride,
After forming a hard coating layer comprising a single layer or a multilayer of two or more of carbonitride, carbonate, nitroxide, and carbonitride, and aluminum oxide, this is subjected to shot peening treatment. To form a shot peening-formed crack distribution layer. (B) Then, on the surface of the shot peening-formed crack distribution layer of (a), the above-mentioned Ti carbide, nitride, and carbon Forming a hard coating layer composed of a single layer or a multilayer of at least one of nitride, carbonate, nitroxide, and carbonitride, and aluminum oxide. Method for manufacturing surface-coated tungsten carbide based cemented carbide cutting tools with excellent fracture and fracture resistance.
JP05063431A 1993-02-26 1993-02-26 Manufacturing method of surface-coated tungsten carbide based cemented carbide cutting tools with excellent wear and fracture resistance Expired - Fee Related JP3087504B2 (en)

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JP3087504B2 true JP3087504B2 (en) 2000-09-11

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DE19652872C2 (en) * 1996-12-18 2000-07-06 Fraunhofer Ges Forschung Process for increasing the surface layer strength on surfaces of workpieces made of brittle hard materials
DE19743579C2 (en) * 1997-10-02 2001-08-16 Mtu Aero Engines Gmbh Thermal barrier coating and process for its manufacture
WO1999024198A1 (en) * 1997-11-06 1999-05-20 Sumitomo Electric Industries, Ltd. Coated tool of cemented carbide
EP2708299B1 (en) * 2011-05-10 2019-03-06 Sumitomo Electric Hardmetal Corp. Surface-coated cutting tool
WO2013042790A1 (en) * 2011-09-22 2013-03-28 株式会社タンガロイ Surface-coated cutting tool
BR112016009492B1 (en) * 2013-11-08 2020-12-01 Tungaloy Corporation coated cutting tool

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