JP2982350B2 - Lead storage battery - Google Patents
Lead storage batteryInfo
- Publication number
- JP2982350B2 JP2982350B2 JP3077618A JP7761891A JP2982350B2 JP 2982350 B2 JP2982350 B2 JP 2982350B2 JP 3077618 A JP3077618 A JP 3077618A JP 7761891 A JP7761891 A JP 7761891A JP 2982350 B2 JP2982350 B2 JP 2982350B2
- Authority
- JP
- Japan
- Prior art keywords
- bag
- separator
- glass mat
- width
- plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011521 glass Substances 0.000 claims description 19
- 239000005357 flat glass Substances 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 238000003466 welding Methods 0.000 claims description 5
- 101100345589 Mus musculus Mical1 gene Proteins 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 description 10
- -1 polyethylene Polymers 0.000 description 10
- 229920000573 polyethylene Polymers 0.000 description 10
- 101100491335 Caenorhabditis elegans mat-2 gene Proteins 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011149 active material Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Secondary Cells (AREA)
- Cell Separators (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明は、鉛蓄電池の性能向上に
関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to improving the performance of a lead storage battery.
【0002】[0002]
【従来の技術】従来、鉛蓄電池を組立てる場合、陽極
板、陰極板をセパレータと複数枚重ね合わせて必要な電
池を構成していた。その際、セパレータにはガラスマッ
トを貼り付けた、一般的に言う、平形セパレータを用い
て組立てていた。他に、最近、セパレータ材質としてポ
リエチレンなどの合成樹脂製の材料を用いたセパレータ
が採用されるようになってきた。ポリエチレンセパレー
タは従来のセパレータに比較して薄くできるため、電気
抵抗が低く、かつ、耐酸化性が良いというメリットがあ
る。2. Description of the Related Art Conventionally, when assembling a lead-acid battery, a required battery has been constructed by stacking a plurality of anode plates and cathode plates on a separator. At that time, a glass mat was attached to the separator, and the assembly was generally performed using a flat separator. In addition, recently, a separator using a synthetic resin material such as polyethylene as a separator material has been adopted. Polyethylene separators can be made thinner than conventional separators, and thus have the advantage of low electrical resistance and good oxidation resistance.
【0003】[0003]
【発明が解決しようとする課題】しかしながら、上記従
来のポリエチレンセパレータをガラスマットと一体に使
用した場合、図5に示すように、予めこのセパレータ1
にガラスマット2を貼り合わせた状態で長さ方向に折り
曲げ重ね合わせて袋状とするため、その張合せ部分3は
溶着あるいはメカニカルシールとするので、ガラスマッ
トがその部分にあると、溶着あるいはメカニカルシール
ができないという問題があった。そのため、ガラスマッ
ト幅をセパレータの張合せ部分巾を考慮した小さい巾、
すなわちガラスマット巾の両端がセパレータの張合せ部
分3にまで達していないガラスマット2をセパレータ1
と一体で採用していた。なお図5において、4は袋状セ
パレータ1に収納された陰極板、5は陽極板である。し
かしながら、ガラスマット2巾をこのように小さくする
と、鉛蓄電池を過酷な条件で使用中に、図6に示すよう
に、陽極板5が湾曲して、ポリエチレンセパレータ1と
接触して、酸化劣化し、この部分1Sで格子より脱落し
た活物質が付着等して陰極板4と短絡を起こす場合があ
った。However, when the above-mentioned conventional polyethylene separator is used integrally with a glass mat, as shown in FIG.
Since the glass mat 2 is bonded in a lengthwise direction in a state where the glass mat 2 is bonded to form a bag shape, the bonded portion 3 is formed by welding or a mechanical seal. There was a problem that sealing was not possible. Therefore, the width of the glass mat is small considering the width
That is, the glass mat 2 in which both ends of the glass mat width do not reach the bonded portion 3 of the separator is placed on the separator 1
Was adopted as one. In FIG. 5, reference numeral 4 denotes a cathode plate accommodated in the bag-like separator 1, and 5 denotes an anode plate. However, when the width of the glass mat 2 is reduced as described above, the anode plate 5 is bent and comes into contact with the polyethylene separator 1 during use of the lead-acid battery under severe conditions as shown in FIG. In some cases, the active material dropped from the lattice may adhere to the portion 1S and cause a short circuit with the cathode plate 4.
【0004】本発明は、以上の点にかんがみてなされた
もので、ポリエチレンなどの袋状にして使用するセパレ
ータを用いた鉛蓄電池の寿命性能の向上を目的とするも
のである。The present invention has been made in view of the above points, and has as its object to improve the life performance of a lead storage battery using a separator used in the form of a bag such as polyethylene.
【0005】[0005]
【課題を解決するための手段】本発明は、上記鉛蓄電池
の問題点に鑑みなされたものであり、陰極板と両側端が
溶着あるいはメカニカルシールによって張り合わされた
袋状のセパレータと平板状のガラスマットと陽極板とを
有する極板群を備えた鉛蓄電池であって、前記陰極板
は、前記袋状のセパレータに包まれており、該袋状のセ
パレータと前記正極板との間には、前記袋状のセパレー
タとは別体の前記平板状のガラスマットが配されてお
り、該平板状のガラスマットは、前記陽極板と陰極板の
少なくとも全表面に亘って広がっており、当該平板状の
ガラスマットの巾は、前記溶着あるいはメカニカルシー
ルによって張り合わされた両側端を含む袋状セパレータ
の巾と前記溶着あるいはメカニカルシールによって張り
合わされた両側端部分の巾との差以上であることを特徴
とするものである。SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned problems of the lead-acid battery , and has a cathode plate and two side edges.
Bonded by welding or mechanical seal
A bag-shaped separator, a flat glass mat and an anode plate
A lead-acid battery comprising a group of electrodes having
Is wrapped in the bag-shaped separator.
Between the parator and the positive electrode plate, the bag-shaped separator
The flat glass mat separate from the
The flat glass mat is formed of the anode plate and the cathode plate.
At least over the entire surface, the flat plate
The width of the glass mat depends on the welding or mechanical
Bag-like separator with both sides glued together
And the above-mentioned welding or mechanical seal
It is characterized in that it is equal to or greater than the difference between the widths of the combined side end portions .
【0006】[0006]
【作用】本発明によるガラスマットの配置構造によっ
て、使用中に、陽極板の湾曲によって、該陽極板がポリ
エチレンセパレータを介して陰極板と接触しないように
でき、かつ、陽極板の寿命向上ができるという作用があ
る。According to the arrangement of the glass mat according to the present invention, the anode plate can be prevented from being in contact with the cathode plate through the polyethylene separator during use by the curvature of the anode plate during use, and the life of the anode plate can be improved. There is an effect.
【0007】[0007]
【実施例】本発明の実施例を説明する。図1は、本発明
の電池A1の平板状のガラスマット配置状態を示すもの
で、ガラスマット6巾が袋状のポリエチレンセパレータ
1巾と同一巾のものを、陽極板5との間に、セパレータ
1とは別体に配置したものである。An embodiment of the present invention will be described. FIG. 1 shows a flat glass mat arrangement of a battery A1 of the present invention. A glass mat 6 having the same width as a bag-shaped polyethylene separator 1 is placed between an anode plate 5 and a separator. It is arranged separately from 1.
【0008】図2は、本発明の電池A2の平板状のガラ
スマット配置状態を示すもので、ガラスマット7巾が袋
状のポリエチレンセパレータ1の張合せ部分巾を除いた
巾のものを、陽極板5との間に、セパレータ1とは別体
に配置したものである。FIG. 2 shows the arrangement of a flat glass mat of the battery A2 of the present invention. The width of the glass mat 7 is the same as the width of the bag-shaped polyethylene separator 1 excluding the width of the bonded portion. This is arranged between the anode plate 5 and the separator 1 separately from the separator 1.
【0009】本発明の電池A1,A2は図3、図4に示
すように、過酷な条件で使用中に陽極板5が湾曲して
も、陰、陽極板4,5間全面にわたってガラスマット
6,7が介在するために、陰、陽極板4,5間の短絡が
防止される。以下本発明による電池寿命テストを従来電
池と比較して説明する。袋状とするためガラスマット巾
の両端がポリエチレンセパレータのメカニカルシールの
張合せ部分に達していないガラスマットをセパレータと
一体に用いた従来の電池B(図5)と本発明による電池
A1,A2を比較する。電池は、12V、5HR容量4
8Ahの電池を製作し、寿命試験を実施した。試験条件
は75℃で行なった。充電は14.8V、10分、放電
は25A、4分で実施した。図7にそのときの30秒目
の放電電圧の推移を示した。As shown in FIGS. 3 and 4, the batteries A1 and A2 of the present invention have a glass mat 6 which covers the entire area between the anode and anode plates 4 and 5 even if the anode plate 5 is curved during use under severe conditions. , 7 are interposed, thereby preventing a short circuit between the negative and anode plates 4, 5. Hereinafter, the battery life test according to the present invention will be described in comparison with a conventional battery. The conventional battery B (FIG. 5) and the batteries A1 and A2 according to the present invention using a glass mat integral with the separator, in which both ends of the glass mat width do not reach the bonded portion of the mechanical seal of the polyethylene separator, to form a bag. Compare. Battery is 12V, 5HR capacity 4
An 8 Ah battery was manufactured and a life test was performed. The test was performed at 75 ° C. Charging was performed at 14.8 V for 10 minutes, and discharging was performed at 25 A for 4 minutes. FIG. 7 shows the transition of the discharge voltage at the 30 seconds at that time.
【0010】[0010]
【発明の効果】上述したように、本発明電池A1,A2
によれば、電池寿命が従来の電池Bに比べて約50%も
向上できたという効果があり、鉛蓄電池の寿命改善に有
効である。As described above, the batteries A1 and A2 of the present invention
According to the above, there is an effect that the battery life can be improved by about 50% as compared with the conventional battery B, which is effective for improving the life of the lead storage battery.
【図1】本発明の一実施例を示すもので、(イ)は上面
図、(ロ)は正面図である。FIG. 1 shows an embodiment of the present invention, wherein (a) is a top view and (b) is a front view.
【図2】本発明の他の一実施例を示すもので、(イ)は
上面図、(ロ)は正面図である。FIG. 2 shows another embodiment of the present invention, wherein (a) is a top view and (b) is a front view.
【図3】図1の使用後の状態図である。FIG. 3 is a state diagram after use of FIG. 1;
【図4】図2の使用後の状態図である。FIG. 4 is a state diagram after use of FIG. 2;
【図5】従来例を示すもので、(イ)は上面図、(ロ)
は正面図である。5A and 5B show a conventional example, in which FIG. 5A is a top view and FIG.
Is a front view.
【図6】図5の使用後の状態図である。FIG. 6 is a state diagram after use of FIG. 5;
【図7】本発明の電池と従来の電池との寿命テスト中の
30秒目電圧の推移を示す比較特性図である。FIG. 7 is a comparative characteristic diagram showing a change in voltage at 30 seconds during a life test between the battery of the present invention and a conventional battery.
1はポリエチレンセパレータ、3は張合せ部分、4は陰
極板、5は陽極板、6はガラスマット、7はガラスマッ
ト、A1は本発明電池、A2は本発明電池。1 is a polyethylene separator, 3 is a bonded portion, 4 is a cathode plate, 5 is an anode plate, 6 is a glass mat, 7 is a glass mat, A1 is a battery of the present invention, and A2 is a battery of the present invention.
フロントページの続き (56)参考文献 特開 昭63−252354(JP,A) 特開 昭63−24547(JP,A) 実開 昭53−72133(JP,U) 実開 昭57−23868(JP,U) (58)調査した分野(Int.Cl.6,DB名) H01M 2/16 - 2/18 Continuation of the front page (56) References JP-A-63-252354 (JP, A) JP-A-63-24547 (JP, A) JP-A-53-72133 (JP, U) JP-A-57-23868 (JP) , U) (58) Field surveyed (Int.Cl. 6 , DB name) H01M 2/16-2/18
Claims (2)
シールによって張り合わされた袋状のセパレータと平板
状のガラスマットと陽極板とを有する極板群を備えた鉛
蓄電池であって、前記陰極板は、前記袋状のセパレータ
に包まれており、該袋状のセパレータと前記正極板との
間には、前記袋状のセパレータとは別体の前記平板状の
ガラスマットが配されており、該平板状のガラスマット
は、前記陽極板と陰極板の少なくとも全表面に亘って広
がっており、当該平板状のガラスマットの巾は、前記溶
着あるいはメカニカルシールによって張り合わされた両
側端を含む袋状セパレータの巾と前記溶着あるいはメカ
ニカルシールによって張り合わされた両側端部分の巾と
の差以上であることを特徴とする鉛蓄電池。1. The cathode plate and both ends are welded or mechanically bonded.
Bag-shaped separator and flat plate bonded by a seal
With an electrode group having a glass-like mat and an anode plate
A storage battery, wherein the cathode plate is the bag-shaped separator
Wrapped in the bag-shaped separator and the positive electrode plate
In between, the plate-shaped separator separate from the bag-shaped separator
A glass mat is provided, and the flat glass mat is provided.
Is spread over at least the entire surface of the anode plate and the cathode plate.
The width of the flat glass mat is
Both attached to each other by mechanical or mechanical seals
The width of the bag-shaped separator including the side end and the welding or mechanical
With the width of both end parts stuck by the nical seal
The lead-acid battery is not less than the difference between the two .
カニカルシールによって張り合わされた両側端を含む袋
状セパレータの巾と同一巾であることを特徴とする請求
項1に記載の鉛蓄電池。2. The glass mat according to claim 1 , wherein
A bag containing both ends glued together by a canal seal
2. The lead-acid battery according to claim 1, wherein the width of the lead- shaped separator is the same as the width of the separator .
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3077618A JP2982350B2 (en) | 1990-04-18 | 1991-04-10 | Lead storage battery |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2-102154 | 1990-04-18 | ||
JP10215490 | 1990-04-18 | ||
JP3077618A JP2982350B2 (en) | 1990-04-18 | 1991-04-10 | Lead storage battery |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH04218259A JPH04218259A (en) | 1992-08-07 |
JP2982350B2 true JP2982350B2 (en) | 1999-11-22 |
Family
ID=26418686
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP3077618A Expired - Lifetime JP2982350B2 (en) | 1990-04-18 | 1991-04-10 | Lead storage battery |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2982350B2 (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4771678B2 (en) * | 2004-09-29 | 2011-09-14 | 古河電池株式会社 | Open-type lead-acid battery for automobiles |
JP6323791B2 (en) * | 2014-03-13 | 2018-05-16 | 株式会社Gsユアサ | Liquid lead-acid battery |
EP3343671A1 (en) * | 2015-08-24 | 2018-07-04 | Hitachi Chemical Co., Ltd. | Lead storage-battery separator, lead storage-battery, and method for producing same |
WO2018015853A1 (en) * | 2016-07-16 | 2018-01-25 | Seshadri Sathyanarayana Mysore | High energy density fast re-chargeable lead-acid batteries with plastic-reinforced conductors |
EP3683885A4 (en) * | 2017-10-31 | 2021-06-30 | GS Yuasa International Ltd. | Lead storage battery |
EP4131625A4 (en) * | 2020-03-30 | 2024-10-09 | Asahi Kasei Kabushiki Kaisha | LEAD-ACTIVE ACCUMULATOR |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57136167U (en) * | 1981-02-19 | 1982-08-25 | ||
JPS63252354A (en) * | 1987-04-08 | 1988-10-19 | Matsushita Electric Ind Co Ltd | Sealed lead-acid battery |
JP2742804B2 (en) * | 1988-12-20 | 1998-04-22 | 松下電器産業株式会社 | Lead storage battery |
-
1991
- 1991-04-10 JP JP3077618A patent/JP2982350B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPH04218259A (en) | 1992-08-07 |
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