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JP2763589B2 - 冷凍機用潤滑剤 - Google Patents

冷凍機用潤滑剤

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Publication number
JP2763589B2
JP2763589B2 JP1138026A JP13802689A JP2763589B2 JP 2763589 B2 JP2763589 B2 JP 2763589B2 JP 1138026 A JP1138026 A JP 1138026A JP 13802689 A JP13802689 A JP 13802689A JP 2763589 B2 JP2763589 B2 JP 2763589B2
Authority
JP
Japan
Prior art keywords
group
refrigerators
integer
weight
lubricant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP1138026A
Other languages
English (en)
Other versions
JPH0328296A (ja
Inventor
民次 鎌倉
裕二 馬場
公義 波浪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Adeka Corp
Original Assignee
Asahi Denka Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=15212317&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=JP2763589(B2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Asahi Denka Kogyo KK filed Critical Asahi Denka Kogyo KK
Priority to JP1138026A priority Critical patent/JP2763589B2/ja
Priority to US07/509,632 priority patent/US5032305A/en
Priority to DE69000991T priority patent/DE69000991T3/de
Priority to AT90304583T priority patent/ATE86291T1/de
Priority to EP90304583A priority patent/EP0401969B2/en
Publication of JPH0328296A publication Critical patent/JPH0328296A/ja
Application granted granted Critical
Publication of JP2763589B2 publication Critical patent/JP2763589B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M111/00—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
    • C10M111/04—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential at least one of them being a macromolecular organic compound
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    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/50—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing halogen
    • C10M105/52—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing halogen containing carbon, hydrogen and halogen only
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    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/20—Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
    • C10M107/30—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M107/32—Condensation polymers of aldehydes or ketones; Polyesters; Polyethers
    • C10M107/34—Polyoxyalkylenes
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    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
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    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
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    • C10M169/04—Mixtures of base-materials and additives
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    • C10M171/00—Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
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    • C10M2207/09—Metal enolates, i.e. keto-enol metal complexes
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Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、冷凍機用潤滑剤に関する。詳しくは、冷凍
機内でフロンと相溶性の良いポリオキシアルキレングリ
コール系の冷凍機用潤滑剤に関する。
〔従来の技術及び発明が解決しようとする課題〕
フロン化合物は、化学的安定性、低毒性、不燃性など
の面で優れた物質であり、冷媒、エアゾール、発泡、洗
浄などの分野で広く用いられてきた。しかし、最近で
は、大気中に放出されたフロンが成層圏においてオゾン
層を破壊するとともに、地球の温暖化、いわゆる「温室
効果」の原因となっているとして、特定種類のフロンの
生産量および消費量の削減の動きが強まっている。
このため、オゾン層破壊、温室効果の恐れのないフロ
ン、すなわち分子内に塩素を含まず、比較的分解されや
すいフロンの開発が進んでいる。
こうした中で、家庭用冷蔵庫、空調機、業務用小型冷
蔵庫、カーエアコンなどの冷媒として広く用いられてき
たフロン12（ジクロロジフルオロメタン）の代替品とし
て、フロン12と物性が類似したフロン134a（1,1,1,2−
テトラフルオロエタン）が開発された。
しかしながら、フロン134aは従来冷凍機油として用い
られてきたナフテン系鉱油やアルキルベンゼンとの相溶
性が悪く、蒸発器中での油戻り成の悪化やコンプレッサ
ーの焼付け、異常振動などのトラブルを起こすため、こ
れと相溶性の良い冷凍機油の開発が求められている。
かかるフロン134aを冷媒とした冷凍機油に関しては分
子量200以下の２官能以上のポリオキシアルキレングリ
コールを用いたものがUSP4755316に提案されているが、
このものは吸湿しやすく、水分により冷凍機の膨張弁の
作動不良や閉塞（水分チョーク）を起こしたり、フロン
の分解を促し、生成したフッ化水素酸により金属部を腐
食させたりする恐れがある。
〔課題を解決するための手段〕
本発明者らは、種々の合成潤滑油について鋭意検討を
行った結果、ある特定の種類のポリオキシアルキレング
リコールジアルキルエーテルが、一般のフロン系冷媒だ
けでなく、フロン134aとの相溶性も優れていること、吸
湿性が少ないこと、フロンに対する安定性が優れている
ことなどを見出し、本発明を完成させた。
即ち、本発明の冷凍機用潤滑剤は、 一般式（１） （式中ｍは、ｍ＝１ ｎは、ｎ＝１ ｐは、１≦ｐ≦80の整数 ｑは、０≦ｑ≦60の整数 ｒは、０または１ ただし、 を示す。） で示される化合物80重量％以上含有し、かつ40℃におけ
る動粘度が6cst以上、500cst以下であることを特徴とす
る。
上記一般式（１）において、 の各ユニットの配列はブロックでもランダムでも良い。
CmH2m+1またはCnH2n+1で示されるアルキル基の例とし
ては、メチル基、エチル基、１−プロピル基、２−プロ
ピル基、１−ブチル基、２−ブチル基、２−メチル−１
−プロピル基、２−メチル−２−プロピル基、１−ペン
チル基、２−ペンチル基、３−ペンチル基、２−メチル
−１−ブチル基、３−メチル−１−ブチル基、２−メチ
ル−２−ブチル基、１−ヘキシル基、４−メチル−２−
ペンチル基、２−エチル−１−ブチル基、１−ヘプチル
基、２−ヘプチル基、３−ヘプチル基、１−オクチル
基、２−オクチル基、２−エチルヘキシル基などが挙げ
られる。
このうち、特に好ましいのは、原料の入手のしやすさ
から、メチル基、エチル基、１−プロピル基、１−ブチ
ル基、２−メチル−１−プロピル基、２−エチルヘキシ
ル基などである。
また上記式において、ｍ＝０またはｎ＝０のものは、
吸湿性が高く、冷凍機用潤滑剤としては不向きである。
ｍ＝９以上またはｎ＝９以上のものは、冷凍機用潤滑剤
の実際の使用温度範囲である−50〜60℃の間でフロン13
4aとの分離を起こし、種々のトラブルを引き起こし、冷
凍機用潤滑剤として好ましくない。
また上記式において、 の条件を満足しないものは、冷凍機用潤滑剤の実際の使
用温度範囲である−50〜60℃の間でフロン134aとの分離
を起こし、種々のトラブルを引き起こす。
かかる本発明のポリオキシアルキレングリコールジア
ルキルエーテルは、アルコール類、アルキレンオキサイ
ド類などを原料とし、通常の付加反応、エーテル化反応
などを適宜組み合わせて得ることができる。
また、本発明の冷凍機用潤滑剤において、充分な性能
を発揮させるためには、上記一般式（１）で示されるポ
リオキシアルキレングリコールジアルキルエーテルを全
組成物中80重量％以上含有する必要がある。
さらに、本発明の冷凍機用潤滑剤は、40℃における動
粘度が6cst以上、500cst以下であることを要し、40℃に
おける動粘度が6cst未満であると、充分な潤滑性を出す
ことが出来ず、また500cstを越えるものは、コンプレッ
サーの負荷が増大してエネルギー的に不利であるばかり
でなく、冷凍機の油分離管内での油戻り性が悪くなる。
本発明の冷凍機用潤滑剤は、上記一般式（１）で示さ
れるポリオキシアルキレングリコールジアルキルエーテ
ルからのみで構成されていてもよいが、フロンを冷媒と
した冷凍機用潤滑剤の添加剤として公知のもの、例えば
トリクレジルホスフェートなどの燐酸エステル、トリエ
チルホスファイトなどの亜燐酸エステル、エポキシ化大
豆油、ビスフェノールＡジグリシジルエーテルなどのエ
ポキシ化合物、ジブチル錫ラウレートなどの有機錫化合
物、α−ナフチルベンジルアミン、フェノチアジン、BH
Tなどの酸価防止剤を上記範囲内で添加してもよい。
かかる本発明の冷凍機用潤滑剤は、冷凍機用潤滑剤の
実際の使用温度範囲である−50〜60℃の間で、フロン13
4aと、事実上あらゆる範囲（1:99〜99:1）で完全に溶解
しあう。
〔発明の効果〕
本発明の冷凍機用潤滑剤は、冷凍機内でフロンと相溶
性が良く、とりわけフロン134aとの相溶性が良く、広範
囲な用途での利用が期待される。
〔実施例〕
以下、実施例により、本発明を更に詳細に説明する
が、本発明はこれらの実施例に限定されるものではな
い。
尚、以下の実施例においては、次に示す試料１〜16を
用いて相溶性を調べた。
実施例１ １ガラス製オートクレーブに、第１表に示す試料
15重量部、第１表に示すフロン85重量部、第１表に示
す試料60重量部、第１表に示すフロン40重量部を仕込
み、−50℃〜60℃における相溶性を調べた。
結果を第１表に示した。
比較例１ 実施例１と同様にして第２表に示す試料の相溶性を
調べた。結果を第２表に示した。
実施例２ 100mlビーカーに第３表に示す試料10gを取り、20℃、
湿度60％の恒温恒湿槽に入れ、24時間後の重量変化を調
べた。
結果を第３表に示す。
比較例２ 第４表に示す試料を用い、実施例２と同様の方法で吸
水性を調べた。結果を第４表に示す。
第４表から明らかな如く、いずれも、実施例２におけ
るよりも重量の増加が大きく、吸水性が高い。
実施例３ 100mlステンレス（SUS−316）製オートクレーブに第
５表に示す試料（試料No.1,2）14重量部、ジブチル錫ラ
ウレート（アデカアーガス製マークBT−11）0.7重量
部、エポキシ化大豆油（アデカアーガス製アデカサイガ
ーＯ−130P）0.3重量部、を取り、試験前の冷凍機用潤
滑剤の粘度及び外観を評価した。次いで、これにフロン
22を75重量部加え、さらに、鋼、銅、アルミニウムの金
属片（50×25×1.5mm）各１枚を入れ、密封した後150℃
で14日間（336時間）加熱した。加熱試験終了後、真空
脱気してフロン22を除去し、試験後の冷凍機用潤滑剤の
粘度と外観を評価した。また、金属片はトルエン及びエ
タノールで洗浄し、重量の増減を測定した。
本発明の冷凍機用潤滑剤は、いずれも粘度変化率が−
10〜22％であり、金属への影響も少なく、フロン共存時
における化学的安定性が優れていることが明らかであ
る。
試験結果は第５表に示す。
比較例３ 実施例３と同様の方法で、第５表に示す各試料（試料
No.12〜16）に対する安定性を調べた。いずれも実施例
３と比較して、粘度変化率が大きく、金属の影響も大き
いことが判明した。
試験結果は第５表に示す。
───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.6，ＤＢ名) C10M 105/18 C10M 107/34 C10N 40:30

Claims (1)

    (57)【特許請求の範囲】
  1. 【請求項１】一般式（１） （式中ｍは、ｍ＝１ ｎは、ｎ＝１ ｐは、１≦ｐ≦80の整数 ｑは、０≦ｑ≦60の整数 ｒは、０または１ ただし、 を示す。） で示される化合物を80重量％以上含有し、かつ40℃にお
    ける動粘度が6cst以上、500cst以下であることを特徴と
    する冷凍機用潤滑剤。
JP1138026A 1989-05-31 1989-05-31 冷凍機用潤滑剤 Expired - Fee Related JP2763589B2 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP1138026A JP2763589B2 (ja) 1989-05-31 1989-05-31 冷凍機用潤滑剤
US07/509,632 US5032305A (en) 1989-05-31 1990-04-13 Lubricant for refrigerant
DE69000991T DE69000991T3 (de) 1989-05-31 1990-04-26 Schmiermittel für Kühlapparate.
AT90304583T ATE86291T1 (de) 1989-05-31 1990-04-26 Schmiermittel fuer kuehlapparate.
EP90304583A EP0401969B2 (en) 1989-05-31 1990-04-26 Lubricant for refrigerant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1138026A JP2763589B2 (ja) 1989-05-31 1989-05-31 冷凍機用潤滑剤

Publications (2)

Publication Number Publication Date
JPH0328296A JPH0328296A (ja) 1991-02-06
JP2763589B2 true JP2763589B2 (ja) 1998-06-11

Family

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Application Number Title Priority Date Filing Date
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Country Status (5)

Country Link
US (1) US5032305A (ja)
EP (1) EP0401969B2 (ja)
JP (1) JP2763589B2 (ja)
AT (1) ATE86291T1 (ja)
DE (1) DE69000991T3 (ja)

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Also Published As

Publication number Publication date
US5032305A (en) 1991-07-16
DE69000991T2 (de) 1993-07-22
DE69000991T3 (de) 1997-04-10
DE69000991D1 (de) 1993-04-08
ATE86291T1 (de) 1993-03-15
EP0401969B2 (en) 1996-09-11
JPH0328296A (ja) 1991-02-06
EP0401969A1 (en) 1990-12-12
EP0401969B1 (en) 1993-03-03

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