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JP2020057587A - Electrode body, secondary battery and secondary battery manufacturing method - Google Patents

Electrode body, secondary battery and secondary battery manufacturing method Download PDF

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JP2020057587A
JP2020057587A JP2019040334A JP2019040334A JP2020057587A JP 2020057587 A JP2020057587 A JP 2020057587A JP 2019040334 A JP2019040334 A JP 2019040334A JP 2019040334 A JP2019040334 A JP 2019040334A JP 2020057587 A JP2020057587 A JP 2020057587A
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negative electrode
positive electrode
electrode sheet
sheet
current collecting
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JP7118021B2 (en
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遼太郎 坂井
Ryotaro Sakai
遼太郎 坂井
昌宏 九澤
Masahiro Kuzawa
昌宏 九澤
明紀 増田
Akinori Masuda
明紀 増田
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Primearth EV Energy Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Battery Electrode And Active Subsutance (AREA)

Abstract

To provide an electrode body, a secondary battery and a secondary battery manufacturing method, with which it is possible to increase a power storage capacity of the electrode body without causing short circuit due to breakage of a separator in the electrode body, in which a positive electrode sheet, a negative electrode sheet and the separator are laminated, and without causing lowering of battery performance.SOLUTION: In an electrode body 30 according to the present invention, positive electrode sheets 200 to 202, negative electrode sheets 210 to 212, and separators 220 to 226 are laminated. In a positive electrode current collecting end part of the electrode body 30, the positive electrode sheets, the negative electrode sheets, and the separators are buckled at least in part inwardly in a lamination direction at a first buckling position positioned inside with respect to end parts of the negative electrode sheets in a width direction. In a negative electrode current collecting end part of the electrode body 30, the negative electrode sheets, the positive electrode sheets, and the separators are buckled at least in part inwardly in the lamination direction at a second buckling position positioned inside with respect to end parts of the positive electrode sheets in the width direction.SELECTED DRAWING: Figure 2

Description

本発明は電極体、二次電池及び二次電池の製造方法に関し、特に、正極シート、負極シート及びセパレータが積層された電極体、当該電極体を備えた二次電池並びに当該二次電池の製造方法に関する。   The present invention relates to an electrode assembly, a secondary battery, and a method for manufacturing a secondary battery, and in particular, an electrode assembly in which a positive electrode sheet, a negative electrode sheet, and a separator are stacked, a secondary battery including the electrode assembly, and a method for manufacturing the secondary battery. About the method.

現在、電気自動車やハイブリッド車、プラグインハイブリッド車等では、リチウムイオン電池やニッケル水素電池等の角型二次電池が採用されている。このような角型二次電池は、捲回型電極体や積層型電極体等の電極体を備えている。電極体の幅方向の端部では、集電体の活物質未塗工部が、幅方向に延在して集電板と接合される。その際、電極体端部は束ねた状態で集電板と接合されるため、図3に示すように、電極体の積層方向の外側では、延在した集電体の活物質未塗工部が、隣接する電極シートの端部位置で積層方向内側に座屈し、セパレータが当該電極シートの端部と接触してセパレータに圧力が加わる。その結果、セパレータが破損し、短絡が発生するという問題があった。   At present, rectangular secondary batteries such as lithium-ion batteries and nickel-metal hydride batteries are used in electric vehicles, hybrid vehicles, plug-in hybrid vehicles, and the like. Such a prismatic secondary battery includes an electrode body such as a wound electrode body or a stacked electrode body. At the end in the width direction of the electrode body, the active material uncoated portion of the current collector extends in the width direction and is joined to the current collector plate. At this time, since the ends of the electrode body are bonded to the current collector plate in a bundled state, as shown in FIG. 3, the active material uncoated portion of the extended current collector extends outside the lamination direction of the electrode body. However, the separator buckles inward in the stacking direction at the end of the adjacent electrode sheet, and the separator comes into contact with the end of the electrode sheet to apply pressure to the separator. As a result, there is a problem that the separator is damaged and a short circuit occurs.

この点に関し、特許文献1が開示する電極組立体では、集電板の近傍で集電体を座屈させることにより、集電体が、隣接する対極の電極板と接触するのを回避し、短絡が発生することを防止する。   In this regard, in the electrode assembly disclosed in Patent Document 1, by buckling the current collector near the current collector, the current collector is prevented from contacting the adjacent counter electrode plate, Prevent short circuit from occurring.

特開2015−82499号公報JP-A-2015-82499

しかしながら、特許文献1が開示する電極組立体では、集電体が、隣接する対極の電極板と接触するのを回避するために、集電板の近傍で集電体を座屈させる構成を採用するため(特許文献1の図3)、一定の大きさの折り曲げ領域を電極体の集電端部に確保しなければならない。このため、正極合剤層の領域及び負極合剤層の領域を幅方向外側に拡張することができず、電極体の蓄電容量を増大させることができないという問題があった。   However, the electrode assembly disclosed in Patent Literature 1 employs a configuration in which the current collector buckles in the vicinity of the current collector in order to prevent the current collector from contacting the adjacent counter electrode plate. (FIG. 3 of Patent Document 1), it is necessary to secure a bent area of a certain size at the current collecting end of the electrode body. For this reason, the region of the positive electrode mixture layer and the region of the negative electrode mixture layer cannot be expanded outward in the width direction, and there is a problem that the storage capacity of the electrode body cannot be increased.

本発明は、このような問題を解決するためになされたものであり、正極シート、負極シート及びセパレータが積層された電極体においてセパレータの破損に起因する短絡を発生させることなく、また、電池性能を低下させることなく、電極体の蓄電容量を増大させることが可能な電極体、二次電池及び二次電池の製造方法を提供すること目的とする。   The present invention has been made in order to solve such a problem, and does not cause a short circuit due to breakage of a separator in an electrode body in which a positive electrode sheet, a negative electrode sheet and a separator are laminated, and improve battery performance. It is an object of the present invention to provide an electrode body, a secondary battery, and a method for manufacturing a secondary battery, which can increase the storage capacity of the electrode body without lowering the battery capacity.

本発明の一実施形態に係る電極体は、正極シートと、負極シートと、前記正極シート及び前記負極シートを絶縁するセパレータが積層された電極体であり、前記電極体の正極集電端部では、前記正極シート、前記負極シート及び前記セパレータの少なくとも一部が、積層方向に略垂直な幅方向において前記負極シートの端部よりも内側に位置する第1の座屈位置で積層方向内側に座屈され、前記電極体の負極集電端部では、前記負極シート、前記正極シート及び前記セパレータの少なくとも一部が、前記幅方向において前記正極シートの端部よりも内側に位置する第2の座屈位置で積層方向内側に座屈されている。   The electrode body according to one embodiment of the present invention is an electrode body in which a positive electrode sheet, a negative electrode sheet, and a separator that insulates the positive electrode sheet and the negative electrode sheet are stacked, and a positive electrode current collecting end of the electrode body has At least a part of the positive electrode sheet, the negative electrode sheet, and the separator is seated inward in the stacking direction at a first buckling position located inside an end of the negative electrode sheet in a width direction substantially perpendicular to the stacking direction. At the negative electrode current collecting end of the electrode body, at least a part of the negative electrode sheet, the positive electrode sheet, and the separator is located in a second seat located inside the end of the positive electrode sheet in the width direction. Buckled in the stacking direction at the bending position.

また、前記正極シートは、正極集電体と、前記正極集電体の両面に形成された正極合剤層とを含み、前記電極体の正極集電端部では、前記正極合剤層の端部が、前記幅方向において前記負極シートの端部よりも内側に配置され、前記第1の座屈位置は、前記正極合剤層の端部と、前記負極シートの端部との間にあることが好ましい。さらに、前記負極シートは、負極集電体と、前記負極集電体の両面に形成された負極合剤層とを含み、前記電極体の負極集電端部では、前記負極合剤層の端部が、前記幅方向において前記正極シートの端部よりも内側に配置され、前記第2の座屈位置は、前記負極合剤層の端部と、前記正極シートの端部との間にあることが好ましい。   Further, the positive electrode sheet includes a positive electrode current collector, and a positive electrode mixture layer formed on both surfaces of the positive electrode current collector, and at a positive electrode current collecting end of the electrode body, an end of the positive electrode mixture layer The portion is disposed inside the end of the negative electrode sheet in the width direction, and the first buckling position is between the end of the positive electrode mixture layer and the end of the negative electrode sheet. Is preferred. Further, the negative electrode sheet includes a negative electrode current collector, and a negative electrode mixture layer formed on both surfaces of the negative electrode current collector, and at a negative electrode current collecting end of the electrode body, an end of the negative electrode mixture layer The portion is disposed inside the end of the positive electrode sheet in the width direction, and the second buckling position is between the end of the negative electrode mixture layer and the end of the positive electrode sheet. Is preferred.

さらに、前記正極合剤層の端部及び前記負極合剤層の端部が先細り形状をしている場合、前記第1の座屈位置は、前記正極合剤層の先細り開始位置と、前記負極シートの端部との間にあり、前記第2の座屈位置は、前記負極合剤層の先細り開始位置と、前記正極シートの端部との間にあることが好ましい。この場合、前記正極集電端部における前記正極シート、前記負極シート及び前記セパレータの座屈角度は、前記正極合剤層の先細り形状が為す角度と同程度であり、前記負極集電端部における前記正極シート、前記負極シート及び前記セパレータの座屈角度は、前記負極合剤層の先細り形状が為す角度と同程度であることが好ましい。   Further, when the end of the positive electrode mixture layer and the end of the negative electrode mixture layer have a tapered shape, the first buckling position is a taper start position of the positive electrode mixture layer, It is preferable that the second buckling position is between an end of the positive electrode sheet and the end of the positive electrode sheet. In this case, the buckling angle of the positive electrode sheet, the negative electrode sheet, and the separator at the positive electrode current collecting end is substantially the same as the angle formed by the tapered shape of the positive electrode mixture layer, and at the negative electrode current collecting end. The buckling angles of the positive electrode sheet, the negative electrode sheet, and the separator are preferably substantially the same as the angle formed by the tapered shape of the negative electrode mixture layer.

さらに、前記正極合剤層の端部及び前記負極合剤層の端部が略垂直面を有する場合、前記第1の座屈位置は、前記正極合剤層の略垂直面と、前記負極シートの端部との間にあり、前記第2の座屈位置は、前記負極合剤層の略垂直面と、前記正極シートの端部との間にあることが好ましい。   Furthermore, when the end of the positive electrode mixture layer and the end of the negative electrode mixture layer have a substantially vertical surface, the first buckling position is substantially perpendicular to the positive electrode mixture layer and the negative electrode sheet. It is preferable that the second buckling position is between a substantially vertical surface of the negative electrode mixture layer and an end of the positive electrode sheet.

さらに、前記電極体は、捲回型電極体または積層型電極体とすることができる。   Further, the electrode body may be a wound electrode body or a laminated electrode body.

さらに、本発明の一実施形態に係る電極体は、前記正極集電端部と接触する接触面を有し、前記接触面を介して前記正極集電端部に応力を加えることにより、前記正極シート、前記負極シート及び前記セパレータの少なくとも一部を座屈させる正極端子と、前記負極集電端部と接触する接触面を有し、前記接触面を介して前記負極集電端部に応力を加えることにより、前記負極シート、前記正極シート及び前記セパレータの少なくとも一部を座屈させる負極端子とを備えることができる。前記正極端子の接触面の幅方向内側端部及び前記負極端子の接触面の幅方向内側端部は、湾曲していることが好ましい。   Further, the electrode body according to one embodiment of the present invention has a contact surface that is in contact with the positive electrode current collecting end portion, and applies stress to the positive electrode current collecting end portion through the contact surface, thereby forming the positive electrode A sheet, a positive electrode terminal that buckles at least a part of the negative electrode sheet and the separator, and a contact surface that is in contact with the negative electrode current collecting end portion. Stress is applied to the negative electrode current collecting end portion through the contact surface. In addition, a negative electrode terminal that buckles at least a part of the negative electrode sheet, the positive electrode sheet, and the separator can be provided. It is preferable that the widthwise inner end of the contact surface of the positive electrode terminal and the widthwise inner end of the contact surface of the negative electrode terminal are curved.

さらに、本発明の一実施形態に係る二次電池は、前記電極体を備える。   Further, a secondary battery according to an embodiment of the present invention includes the electrode body.

さらに、本発明の一実施形態に係る二次電池の製造方法は、正極シートと、負極シートと、前記正極シート及び前記負極シートを絶縁するセパレータが積層された電極体を備える二次電池の製造方法であり、前記電極体の正極集電端部における前記正極シート、前記負極シート及び前記セパレータの少なくとも一部を、積層方向に略垂直な幅方向において前記負極シートの端部よりも内側に位置する第1の座屈位置で積層方向内側に座屈させる第1の座屈工程と、前記電極体の負極集電端部における前記負極シート、前記正極シート及び前記セパレータの少なくとも一部を、前記幅方向において前記正極シートの端部よりも内側に位置する第2の座屈位置で積層方向内側に座屈させる第2の座屈工程とを含む。   Furthermore, the method for manufacturing a secondary battery according to one embodiment of the present invention includes manufacturing a secondary battery including an electrode body in which a positive electrode sheet, a negative electrode sheet, and a separator that insulates the positive electrode sheet and the negative electrode sheet are stacked. A method, wherein at least a part of the positive electrode sheet, the negative electrode sheet and the separator at a positive electrode current collecting end of the electrode body are located inside an end of the negative electrode sheet in a width direction substantially perpendicular to a laminating direction. A first buckling step of buckling inward in the stacking direction at a first buckling position, and at least a part of the negative electrode sheet, the positive electrode sheet, and the separator at a negative electrode current collecting end of the electrode body, A second buckling step of buckling inward in the stacking direction at a second buckling position located inside the end of the positive electrode sheet in the width direction.

さらに、本発明の一実施形態に係る二次電池の製造方法は、前記第1の座屈工程において、上側押圧部材及び下側押圧部材の押圧面を介して前記正極集電端部に応力を加えることにより、前記正極シート、前記負極シート及び前記セパレータの少なくとも一部を座屈させ、前記第2の座屈工程において、上側押圧部材及び下側押圧部材の押圧面を介して前記負極集電端部に応力を加えることにより、前記負極シート、前記正極シート及び前記セパレータの少なくとも一部を座屈させることができる。前記上側押圧部材の押圧面の前記電極体側の端部及び前記下側押圧部材の押圧面の前記電極体側の端部は、湾曲していることが好ましい。   Furthermore, in the method for manufacturing a secondary battery according to one embodiment of the present invention, in the first buckling step, a stress is applied to the positive electrode current collecting end portion via the pressing surfaces of the upper pressing member and the lower pressing member. In addition, at least a part of the positive electrode sheet, the negative electrode sheet, and the separator are buckled, and in the second buckling step, the negative electrode current is collected via pressing surfaces of an upper pressing member and a lower pressing member. By applying a stress to the end, at least a part of the negative electrode sheet, the positive electrode sheet, and the separator can be buckled. It is preferable that an end of the pressing surface of the upper pressing member on the electrode body side and an end of the pressing surface of the lower pressing member on the electrode body side are curved.

本発明により、正極シート、負極シート及びセパレータが積層された電極体においてセパレータの破損に起因する短絡を発生させることなく、また、電池性能を低下させることなく、電極体の蓄電容量を増大させることが可能な電極体、二次電池及び二次電池の製造方法を提供することができる。   According to the present invention, it is possible to increase the storage capacity of an electrode body without causing a short circuit due to breakage of the separator in an electrode body in which a positive electrode sheet, a negative electrode sheet and a separator are laminated, and without lowering battery performance. The present invention can provide an electrode body, a secondary battery, and a method for manufacturing a secondary battery, which can perform the following.

本発明の一実施形態に係る二次電池であるバッテリーモジュールを示す概略図である。1 is a schematic diagram illustrating a battery module that is a secondary battery according to an embodiment of the present invention. 本発明の一実施形態に係る電極体の積層方向外側の正極集電端部を示す水平断面図である。FIG. 3 is a horizontal cross-sectional view showing a positive electrode current collecting end on the outer side in the stacking direction of the electrode body according to one embodiment of the present invention. 従来の電極体の集電端部における座屈の様子を示す図である。It is a figure which shows the mode of buckling in the current collection end part of the conventional electrode body. 従来の電極体の集電端部における座屈の様子を示す図である。It is a figure which shows the mode of buckling in the current collection end part of the conventional electrode body. 本発明の一実施形態に係る電極体の集電端部を座屈させるための上側押圧部材及び下側押圧部材の一例を示す図である。It is a figure which shows an example of the upper side pressing member and the lower side pressing member for buckling the collector end of the electrode body which concerns on one Embodiment of this invention. 図5に示す上側押圧部材及び下側押圧部材を用いて電極体の集電端部を座屈させた様子を示す図である。FIG. 6 is a diagram illustrating a state where a current collecting end of an electrode body is buckled using the upper pressing member and the lower pressing member illustrated in FIG. 5.

以下、図面を参照して本発明の実施形態について説明する。本発明の一実施形態に係る角型二次電池であるバッテリーモジュール10を示す概略図である。バッテリーモジュール10は、バッテリーセルである捲回型電極体または積層型電極体等の電極体を収容している。これらの電極体は、正極を構成する電極シート(以下、「正極シート」とする。)と、負極を構成する電極シート(以下、「負極シート」とする。)を備えている。正極シート及び負極シートに蓄電された電気は、それぞれ正極集電端部及び負極集電端部で集電され、正極端子11及び負極端子12から出力される。   Hereinafter, embodiments of the present invention will be described with reference to the drawings. 1 is a schematic diagram illustrating a battery module 10 that is a rectangular secondary battery according to an embodiment of the present invention. The battery module 10 houses an electrode body such as a wound electrode body or a laminated electrode body which is a battery cell. These electrode bodies include an electrode sheet constituting a positive electrode (hereinafter, referred to as “positive sheet”) and an electrode sheet constituting a negative electrode (hereinafter, referred to as “negative electrode sheet”). The electricity stored in the positive electrode sheet and the negative electrode sheet is collected at the positive current collecting end and the negative current collecting end, respectively, and output from the positive terminal 11 and the negative terminal 12.

以下の説明では、バッテリーモジュール10内の正極シート及び負極シートが積層された方向を積層方向とし、積層方向に略垂直な方向を幅方向とする。なお、本実施形態では、正極端子11及び負極端子12は、バッテリーモジュール10の上面に配置されるが、バッテリーモジュール10の幅方向の側面に正極端子11及び負極端子12を配置してもよい。   In the following description, a direction in which the positive electrode sheet and the negative electrode sheet in the battery module 10 are stacked is referred to as a stacking direction, and a direction substantially perpendicular to the stacking direction is referred to as a width direction. In the present embodiment, the positive electrode terminal 11 and the negative electrode terminal 12 are arranged on the upper surface of the battery module 10, but the positive electrode terminal 11 and the negative electrode terminal 12 may be arranged on the side surface in the width direction of the battery module 10.

図2は、本発明の一実施形態に係る電極体の積層方向外側の正極集電端部を示す水平断面図であり、押圧される前の電極体20と、積層方向の両側から押圧された後の電極体30を示している。なお、図2は、積層方向において電極体20,30の正極集電端部の一方の外側のみを示しているが、電極体20,30の正極集電端部の他方の外側も同様に座屈される。   FIG. 2 is a horizontal cross-sectional view showing the positive electrode collecting end on the outer side in the stacking direction of the electrode body according to one embodiment of the present invention, and the electrode body 20 before being pressed and pressed from both sides in the stacking direction. The rear electrode body 30 is shown. FIG. 2 shows only one outside of the positive electrode current collecting ends of the electrode bodies 20 and 30 in the stacking direction, but the other outside of the positive electrode current collecting ends of the electrode bodies 20 and 30 is similarly seated. Succumbed.

電極体20は、正極シート200,201,202と、負極シート210,211,212と、セパレータ220〜226とを備えており、これらの正極シート、負極シート及びセパレータが積層されている。積層方向において最外側でないセパレータ221〜226は、正極シート200,201,202と、負極シート210,211,212との間に配置され、これらの正極シート及び負極シートを絶縁する。ここで、捲回型電極体は、例えば、1枚の正極シートと、1枚の負極シートと、2枚のセパレータを積層して捲回することによって形成される。一方、積層型電極体は、複数の正極シートと、複数の負極シートと、複数のセパレータを積層することによって形成される。   The electrode body 20 includes positive electrode sheets 200, 201, 202, negative electrode sheets 210, 211, 212, and separators 220 to 226, and the positive electrode sheet, the negative electrode sheet, and the separator are stacked. The separators 221 to 226 that are not the outermost in the laminating direction are arranged between the positive electrode sheets 200, 201, 202 and the negative electrode sheets 210, 211, 212, and insulate these positive electrode sheets and negative electrode sheets. Here, the wound electrode body is formed, for example, by laminating and winding one positive electrode sheet, one negative electrode sheet, and two separators. On the other hand, a laminated electrode body is formed by laminating a plurality of positive electrode sheets, a plurality of negative electrode sheets, and a plurality of separators.

正極シート200,201,202は、それぞれ正極集電体200a,201a,202aと、これらの正極集電体の両面に形成された正極合剤層200b,201b,202bとを含む。正極集電体200a,201a,202aは、幅方向外側に延在し、正極集電板(図示せず)と接合される。正極合剤層200b,201b,202bは、正極活物質(コバルト酸リチウム等)や導電剤、バインダを含む正極合剤スラリーで構成され、正極合剤スラリーを正極集電体(アルミニウム等)に塗布し、乾燥焼入れすることによって形成される。本図に示すように、正極集電端部では、先細り形状の正極合剤層200b,201b,202bの端部が、幅方向において負極シート210,211,212の端部よりも内側に配置される。   The positive electrode sheets 200, 201, and 202 include positive electrode current collectors 200a, 201a, and 202a, respectively, and positive electrode mixture layers 200b, 201b, and 202b formed on both surfaces of these positive electrode current collectors. The positive electrode current collectors 200a, 201a, and 202a extend outward in the width direction and are joined to a positive electrode current collector plate (not shown). The positive electrode mixture layers 200b, 201b, and 202b are composed of a positive electrode mixture slurry containing a positive electrode active material (such as lithium cobalt oxide), a conductive agent, and a binder, and the positive electrode mixture slurry is applied to a positive electrode current collector (such as aluminum). Formed by dry quenching. As shown in the drawing, at the positive electrode current collecting end, the ends of the tapered positive electrode mixture layers 200b, 201b, and 202b are arranged inside the ends of the negative electrode sheets 210, 211, and 212 in the width direction. You.

負極シート210,211,212は、それぞれ負極集電体210a,211a,212aと、これらの負極集電体の両面に形成された負極合剤層210b,211b,212bとを含む。負極集電体210a,211a,212aは、幅方向外側に延在し、負極集電板と接合される(図示せず)。負極合剤層210b,211b,212bは、負極活物質(グラファイト等)や導電剤、バインダを含む負極合剤スラリーで構成され、負極合剤スラリーを負極集電体(銅等)に塗布し、乾燥焼入れすることによって形成される。正極集電端部と同様に、負極集電端部では、先細り形状の負極合剤層210b,211b,212bの端部が、幅方向において正極シート200,201,202の端部よりも内側に配置される(図示せず)。   Negative electrode sheets 210, 211, 212 include negative electrode current collectors 210a, 211a, 212a, respectively, and negative electrode mixture layers 210b, 211b, 212b formed on both surfaces of these negative electrode current collectors. The negative electrode current collectors 210a, 211a, and 212a extend outward in the width direction and are joined to the negative electrode current collector plate (not shown). The negative electrode mixture layers 210b, 211b, and 212b are formed of a negative electrode mixture slurry containing a negative electrode active material (eg, graphite), a conductive agent, and a binder, and the negative electrode mixture slurry is applied to a negative electrode current collector (eg, copper). It is formed by dry quenching. Similarly to the positive electrode current collecting end, at the negative electrode current collecting end, the ends of the tapered negative electrode mixture layers 210b, 211b, and 212b are located inside the ends of the positive electrode sheets 200, 201, and 202 in the width direction. (Not shown).

本発明の二次電池の製造方法では、電極体20の正極集電端部及び負極集電端部に積層方向両側から圧力を加える。より詳細には、電極体20の正極集電端部では、本図に示すように、正極合剤層200b,201b,202bの先細り開始位置と、負極シート210,211,212の端部位置との間の第1の座屈位置で電極体20が座屈されるように、電極体20を押圧する。ここで、正極合剤層200b,201b,202bの先細り開始位置は、正極合剤層200b,201b,202bとセパレータ221〜226が接触する位置のうち幅方向最外側の位置である。   In the method of manufacturing a secondary battery of the present invention, pressure is applied to the positive electrode current collecting end and the negative electrode current collecting end of the electrode body 20 from both sides in the stacking direction. More specifically, at the positive electrode current collecting end of the electrode body 20, as shown in the figure, the taper start positions of the positive electrode mixture layers 200b, 201b, and 202b and the end positions of the negative electrode sheets 210, 211, and 212 The electrode body 20 is pressed so that the electrode body 20 is buckled at the first buckling position between the two. Here, the taper start position of the positive electrode mixture layers 200b, 201b, and 202b is the outermost position in the width direction among the positions where the positive electrode mixture layers 200b, 201b, and 202b are in contact with the separators 221 to 226.

電極体20を積層方向外側から押圧すると、電極体20の正極集電端部は、電極体30のような形状に変化する。電極体30の正極集電端部では、正極集電体200a,201a,202aと、負極シート211,212と、セパレータ222,223,224,225,226が、第1の座屈位置で積層方向内側に座屈する。   When the electrode body 20 is pressed from the outside in the stacking direction, the positive electrode current collecting end of the electrode body 20 changes into a shape like the electrode body 30. At the positive electrode current collecting end of the electrode body 30, the positive electrode current collectors 200a, 201a, and 202a, the negative electrode sheets 211 and 212, and the separators 222, 223, 224, 225, and 226 are stacked in the first buckling position in the stacking direction. Buckle inward.

同様に、電極体20の負極集電端部では、負極合剤層210b,211b,212bの先細り開始位置と、正極シート200,201,202の端部位置との間の第2の座屈位置で電極体20が座屈されるように、電極体20を押圧する。ここで、負極合剤層210b,211b,212bの先細り開始位置は、負極合剤層210b,211b,212bとセパレータ221〜226が接触する位置のうち幅方向最外側の位置である。電極体20を積層方向外側から押圧すると、電極体20の負極集電端部では、負極集電体210a,211a,212aと、正極シート200,201,202と、セパレータ222,223,224,225,226が、第2の座屈位置で積層方向内側に座屈する。   Similarly, at the negative electrode current collecting end of the electrode body 20, the second buckling position between the taper start position of the negative electrode mixture layers 210b, 211b, 212b and the end position of the positive electrode sheets 200, 201, 202 The electrode body 20 is pressed so that the electrode body 20 is buckled. Here, the taper start position of the negative electrode mixture layers 210b, 211b, 212b is the outermost position in the width direction among the positions where the negative electrode mixture layers 210b, 211b, 212b and the separators 221 to 226 are in contact. When the electrode body 20 is pressed from the outside in the stacking direction, the negative electrode current collectors 210a, 211a, 212a, the positive electrode sheets 200, 201, 202, the separators 222, 223, 224, and 225 are formed at the negative electrode current collecting end of the electrode body 20. , 226 buckle in the stacking direction in the second buckling position.

なお、本図では、負極シート210及びセパレータ220,221には、説明の便宜上、積層方向内側に座屈していないが、本発明の二次電池の製造方法によって電極体に加わる押圧力の大きさに依存して、負極シート210及びセパレータ220,221が積層方向内側に座屈する。また、積層方向外側の正極シート、負極シート及びセパレータは、積層方向内側の正極シート、負極シート及びセパレータに比べ、座屈の程度が大きくなる。さらに、中心部の正極シート、負極シート及びセパレータは座屈しない。すなわち、本発明の二次電池の製造方法により、正極シート、負極シート及びセパレータの少なくとも一部が積層方向内側に座屈する。   In this figure, the negative electrode sheet 210 and the separators 220 and 221 do not buckle inward in the stacking direction for convenience of explanation, but the magnitude of the pressing force applied to the electrode body by the method of manufacturing a secondary battery of the present invention. , The negative electrode sheet 210 and the separators 220 and 221 buckle inward in the stacking direction. The degree of buckling of the positive electrode sheet, the negative electrode sheet, and the separator on the outer side in the stacking direction is larger than that of the positive electrode sheet, the negative electrode sheet, and the separator on the inner side in the stacking direction. Further, the positive electrode sheet, the negative electrode sheet and the separator at the center do not buckle. That is, according to the method for manufacturing a secondary battery of the present invention, at least a part of the positive electrode sheet, the negative electrode sheet and the separator buckle in the laminating direction.

図5は、電極体30の集電端部を座屈させるための上側押圧部材40及び下側押圧部材50を示す図である。図6は、上側押圧部材40及び下側押圧部材50を用いて、電極体30の集電端部を座屈させた様子を示す図である。   FIG. 5 is a diagram illustrating the upper pressing member 40 and the lower pressing member 50 for buckling the current collecting end of the electrode body 30. FIG. 6 is a diagram illustrating a state where the current collecting end of the electrode body 30 is buckled using the upper pressing member 40 and the lower pressing member 50.

上側押圧部材40は、ホーンに固定され、電極体30の正極集電端部及び負極集電端部を上側から押圧する部材である。上側押圧部材40は、押圧面である底面を介して電極体30の集電端部に応力を加えることにより、電極体30の集電端部の正極シート、負極シート及びセパレータを座屈させる。上側押圧部材40の押圧面の電極体側の端部41は、図5に示すように湾曲している。また、上側押圧部材40には、電極体30の集電端部に取付けられた集電端子との干渉を回避するため、開口42を設けることができる。   The upper pressing member 40 is a member that is fixed to the horn and that presses the positive current collecting end and the negative current collecting end of the electrode body 30 from above. The upper pressing member 40 buckles the positive electrode sheet, the negative electrode sheet, and the separator at the current collecting end of the electrode body 30 by applying stress to the current collecting end of the electrode body 30 via the bottom surface that is the pressing surface. The end 41 of the pressing surface of the upper pressing member 40 on the electrode body side is curved as shown in FIG. The upper pressing member 40 can be provided with an opening 42 in order to avoid interference with the current collecting terminal attached to the current collecting end of the electrode body 30.

下側押圧部材50は、アンビルに固定され、電極体30の正極集電端部及び負極集電端部を下側から押圧する部材である。下側押圧部材50は、押圧面である上面を介して電極体30の集電端部に応力を加えることにより、電極体30の集電端部の正極シート、負極シート及びセパレータを座屈させる。下側押圧部材50の押圧面の電極体側の端部51は、図5に示すように湾曲している。   The lower pressing member 50 is a member that is fixed to the anvil and presses the positive electrode collecting end and the negative electrode collecting end of the electrode body 30 from below. The lower pressing member 50 buckles the positive electrode sheet, the negative electrode sheet, and the separator at the current collecting end of the electrode body 30 by applying stress to the current collecting end of the electrode body 30 via the upper surface that is the pressing surface. . The end 51 of the pressing surface of the lower pressing member 50 on the electrode body side is curved as shown in FIG.

上側押圧部材40は、ホーンが下側に移動することにより、上側押圧部材40が下側押圧部材50に向かって移動し、図6に示すように、上側押圧部材40の押圧面及び下側押圧部材50の押圧面を介して電極体30の集電端部に応力が加わるため、電極体30の集電端部に対して応力を分散的に加えることができる。このため、集電端部に含まれるセパレータの一部に対して応力が集中的に加わることがないため、セパレータの破損を防ぐことができ、これに起因する短絡の発生を防止することができる。また、上側押圧部材40及び下側押圧部材50の押圧面の電極体側の端部41,51が湾曲していることにより、これらの端部と接する電極体30の集電端部を滑らかに座屈させることができ、当該集電端部に含まれるセパレータの破損を確実に防止することができる。   As the horn moves downward, the upper pressing member 40 moves toward the lower pressing member 50, and as shown in FIG. 6, the pressing surface of the upper pressing member 40 and the lower pressing member Since stress is applied to the current collecting end of the electrode body 30 via the pressing surface of the member 50, stress can be dispersedly applied to the current collecting end of the electrode body 30. For this reason, since stress is not intensively applied to a part of the separator included in the current collecting end portion, it is possible to prevent the separator from being damaged and to prevent a short circuit caused by this. . In addition, since the end surfaces 41 and 51 of the pressing surfaces of the upper pressing member 40 and the lower pressing member 50 on the electrode body side are curved, the current collecting end of the electrode body 30 in contact with these ends is smoothly seated. And the separator included in the current collecting end can be reliably prevented from being broken.

上述した実施形態では、正極集電端部において負極シートの端部よりも幅方向内側の第1の座屈位置で正極集電体、負極シート及びセパレータが座屈され、負極集電端部において正極シートの端部よりも幅方向内側の第2の座屈位置で負極集電体、正極シート及びセパレータが座屈される。このため、図3に示すような正極の集電体を負極シートの端部位置で屈曲させる構成、または、負極の集電体を正極シートの端部位置で屈曲させる構成に比べて、正極集電体及び負極集電体が、それぞれ隣接するセパレータに加える応力を低下させることができ、セパレータの破損に起因する短絡を防止することができる。また、図4に示すような電極体の集電端部においてセパレータの端部よりも幅方向外側で集電体を座屈させる構成と異なり、セパレータの端部よりも幅方向外側に座屈領域を設ける必要がない。このため、正極集電端部における正極合剤層の領域を拡張できると共に、負極集電端部における負極合剤層の領域を拡張することができ、電極体の蓄電容量を増大させることができる。   In the above-described embodiment, the positive electrode current collector, the negative electrode sheet, and the separator are buckled at the first buckling position on the inner side in the width direction from the end of the negative electrode sheet at the positive electrode current collecting end, and at the negative electrode current collecting end. The negative electrode current collector, the positive electrode sheet, and the separator are buckled at the second buckling position on the inner side in the width direction from the end of the positive electrode sheet. For this reason, the positive electrode current collector is bent at the end position of the negative electrode sheet as shown in FIG. 3 or the positive electrode current collector is bent at the end position of the negative electrode sheet as compared with the positive electrode current collector. The current collector and the negative electrode current collector can reduce stress applied to adjacent separators, respectively, and can prevent short circuit due to breakage of the separator. Further, unlike the configuration in which the current collector is buckled at the current collector end of the electrode body in the width direction outside of the end of the separator as shown in FIG. 4, a buckling region is formed outside the end of the separator in the width direction. There is no need to provide For this reason, the area of the positive electrode mixture layer at the positive electrode current collecting end can be expanded, and the area of the negative electrode mixture layer at the negative electrode current collecting end can be expanded, so that the storage capacity of the electrode body can be increased. .

さらに、上述した実施形態では、正極集電体及び負極シートを、正極合剤層が存在しない第1の座屈位置で座屈させると共に、負極集電体及び正極シートを、負極合剤層が存在しない第2の座屈位置で座屈させるが、本発明を創作する過程において、このような座屈位置で正極シート及び負極シートの双方を座屈させても、電池性能への悪影響が無いことが新たに判明した。すなわち、本発明は、上述した第1及び第2の座屈位置で電極シートを座屈させることにより、電池性能の低下を防ぐことができる。   Further, in the above-described embodiment, the positive electrode current collector and the negative electrode sheet are buckled at the first buckling position where the positive electrode mixture layer does not exist, and the negative electrode current collector and the positive electrode sheet are Although buckling is performed at the second buckling position that does not exist, in the process of creating the present invention, even if both the positive electrode sheet and the negative electrode sheet buckle at such a buckling position, there is no adverse effect on battery performance. It is newly found. That is, according to the present invention, the battery performance can be prevented from deteriorating by buckling the electrode sheet at the above-described first and second buckling positions.

なお、本発明は上記実施形態に限られたものではなく、趣旨を逸脱しない範囲で適宜変更することが可能である。例えば、図2に示す実施形態では、正極合剤層の先細り開始位置よりも幅方向外側の位置と、負極合剤層の先細り開始位置よりも幅方向外側の位置で電極シート及びセパレータを座屈させるが、他の実施形態では、正極合剤層の先細り開始位置及び負極合剤層の先細り開始位置で電極シート及びセパレータを座屈させてもよい。これは、これらの合剤層の先細り部分は電池性能への寄与度が小さいため、当該先細り部分に隣接する電極シートを座屈させても、電池性能に悪影響を及ぼさないことによる。この場合、正極集電端部における電極シート及びセパレータの座屈角度を、正極合剤層の先細り形状が為す角度と同程度とし、負極集電端部における電極シート及びセパレータの座屈角度を、負極合剤層の先細り形状が為す角度と同程度とすることが好ましい。これにより、正極合剤層及び負極合剤層同士が圧迫されることがなく、電池性能への悪影響を確実に防ぐことができる。   The present invention is not limited to the above-described embodiment, and can be appropriately changed without departing from the gist. For example, in the embodiment shown in FIG. 2, the electrode sheet and the separator are buckled at a position outside the taper start position of the positive electrode mixture layer in the width direction and at a position outside the taper start position of the negative electrode mixture layer in the width direction. However, in another embodiment, the electrode sheet and the separator may be buckled at the taper start position of the positive electrode mixture layer and the taper start position of the negative electrode mixture layer. This is because the tapered portion of these mixture layers has a small contribution to battery performance, and therefore, even if the electrode sheet adjacent to the tapered portion is buckled, the battery performance is not adversely affected. In this case, the buckling angle of the electrode sheet and the separator at the positive electrode current collecting end is substantially equal to the angle formed by the tapered shape of the positive electrode mixture layer, and the buckling angle of the electrode sheet and the separator at the negative electrode current collecting end is It is preferable that the angle is approximately the same as the angle formed by the tapered shape of the negative electrode mixture layer. Thereby, the positive electrode mixture layer and the negative electrode mixture layer are not pressed against each other, and the adverse effect on the battery performance can be reliably prevented.

また、上述した実施形態では、正極合剤層の端部及び負極合剤層の端部が先細り形状をしているが、他の実施形態では、正極合剤層の端部及び負極合剤層の端部が略垂直面を有してもよい。この場合、第1の座屈位置は、正極合剤層の端部の略垂直面と、負極シートの端部との間にあり、第2の座屈位置は、負極合剤層の端部の略垂直面と、正極シートの端部との間にある。   In the above-described embodiment, the end of the positive electrode mixture layer and the end of the negative electrode mixture layer have a tapered shape. In other embodiments, the end of the positive electrode mixture layer and the negative electrode mixture layer have a tapered shape. May have a substantially vertical surface. In this case, the first buckling position is between the substantially vertical surface of the end of the positive electrode mixture layer and the end of the negative electrode sheet, and the second buckling position is the end of the negative electrode mixture layer. And the edge of the positive electrode sheet.

さらに、上述した実施形態では、正極集電端部における第1の座屈位置の幅方向内側の限界位置は、正極合剤層200b,201b,202bの先細り開始位置としているが、他の実施形態では、電池性能に悪影響を及ぼさない限りにおいて、正極合剤層200b,201b,202bの先細り開始位置よりも幅方向内側の位置を、第1の座屈位置の幅方向内側の限界位置としてもよい。同様に、負極集電端部では、負極合剤層210b,211b,212bの先細り開始位置よりも幅方向内側の位置を、第2の座屈位置の幅方向内側の限界位置としてもよい。   Further, in the above-described embodiment, the widthwise inner limit position of the first buckling position at the positive electrode current collecting end is the taper start position of the positive electrode mixture layers 200b, 201b, and 202b. Then, as long as the battery performance is not adversely affected, the position in the width direction from the taper start position of the positive electrode mixture layers 200b, 201b, and 202b may be set as the limit position in the width direction inside of the first buckling position. . Similarly, at the negative electrode current collecting end, a position in the width direction inside of the taper start position of the negative electrode mixture layers 210b, 211b, 212b may be set as a widthwise inner limit position of the second buckling position.

さらに、他の実施形態では、上側押圧部材40の下部形状及び下側押圧部材50の上部形状と同様の形状を有する正極端子及び負極端子を電極体30の集電端部に取付けることができる。正極端子は、電極体30の正極集電端部と接触する接触面を有しており、当該接触面を介して正極集電端部に応力を加えることにより、正極シート、負極シート及びセパレータの少なくとも一部を座屈させることができる。負極端子は、電極体30の負極集電端部と接触する接触面を有しており、当該接触面を介して負極集電端部に応力を加えることにより、負極シート、正極シート及びセパレータの少なくとも一部を座屈させることができる。正極端子の接触面の幅方向内側端部及び負極端子の接触面の幅方向内側端部は、上側押圧部材40及び下側押圧部材50の押圧面の電極体側の端部41,51と同様に湾曲していることが好ましい。   Further, in another embodiment, a positive electrode terminal and a negative electrode terminal having the same shape as the lower shape of the upper pressing member 40 and the upper shape of the lower pressing member 50 can be attached to the current collecting end of the electrode body 30. The positive electrode terminal has a contact surface that comes into contact with the positive electrode current collecting end of the electrode body 30, and applies stress to the positive electrode current collecting end via the contact surface to form a positive electrode sheet, a negative electrode sheet, and a separator. At least a portion can be buckled. The negative electrode terminal has a contact surface that comes into contact with the negative electrode current collecting end of the electrode body 30, and by applying stress to the negative electrode current collecting end via the contact surface, the negative electrode sheet, the positive electrode sheet, and the separator At least a portion can be buckled. The widthwise inner end of the contact surface of the positive terminal and the widthwise inner end of the contact surface of the negative terminal are similar to the ends 41 and 51 of the pressing surfaces of the upper pressing member 40 and the lower pressing member 50 on the electrode body side. Preferably it is curved.

10 バッテリーモジュール
11 正極端子
12 負極端子
20 電極体
30 電極体
200〜202 正極シート
200a〜202a 正極集電体
200b〜202b 正極合剤層
210〜212 負極シート
210a〜212a 負極集電体
210b〜212b 負極合剤層
220〜226 セパレータ
Reference Signs List 10 battery module 11 positive electrode terminal 12 negative electrode terminal 20 electrode body 30 electrode body 200 to 202 positive electrode sheet 200a to 202a positive electrode current collector 200b to 202b positive electrode mixture layer 210 to 212 negative electrode sheet 210a to 212a negative electrode current collector 210b to 212b negative electrode Mixture layer 220-226 Separator

Claims (12)

正極シートと、負極シートと、前記正極シート及び前記負極シートを絶縁するセパレータが積層された電極体であって、
前記電極体の正極集電端部では、前記正極シート、前記負極シート及び前記セパレータの少なくとも一部が、積層方向に略垂直な幅方向において前記負極シートの端部よりも内側に位置する第1の座屈位置で積層方向内側に座屈され、
前記電極体の負極集電端部では、前記負極シート、前記正極シート及び前記セパレータの少なくとも一部が、前記幅方向において前記正極シートの端部よりも内側に位置する第2の座屈位置で積層方向内側に座屈されていることを特徴とする、電極体。
A positive electrode sheet, a negative electrode sheet, and an electrode body in which a separator for insulating the positive electrode sheet and the negative electrode sheet is laminated,
At the positive electrode current collecting end of the electrode body, at least a part of the positive electrode sheet, the negative electrode sheet and the separator is located inside the end of the negative electrode sheet in the width direction substantially perpendicular to the laminating direction. Buckled in the stacking direction at the buckling position
At the negative electrode current collecting end of the electrode body, at least a part of the negative electrode sheet, the positive electrode sheet, and the separator are at a second buckling position located inside the end of the positive electrode sheet in the width direction. An electrode body characterized in that it is buckled inward in the stacking direction.
前記正極シートは、正極集電体と、前記正極集電体の両面に形成された正極合剤層とを含み、
前記正極集電端部では、前記正極合剤層の端部が、前記幅方向において前記負極シートの端部よりも内側に配置されており、
前記第1の座屈位置は、前記正極合剤層の端部と、前記負極シートの端部との間にあり、
前記負極シートは、負極集電体と、前記負極集電体の両面に形成された負極合剤層とを含み、
前記負極集電端部では、前記負極合剤層の端部が、前記幅方向において前記正極シートの端部よりも内側に配置されており、
前記第2の座屈位置は、前記負極合剤層の端部と、前記正極シートの端部との間にある、請求項1に記載の電極体。
The positive electrode sheet includes a positive electrode current collector, and a positive electrode material mixture layer formed on both surfaces of the positive electrode current collector,
At the positive electrode current collecting end, an end of the positive electrode mixture layer is disposed inside an end of the negative electrode sheet in the width direction,
The first buckling position is between an end of the positive electrode mixture layer and an end of the negative electrode sheet,
The negative electrode sheet includes a negative electrode current collector, and a negative electrode mixture layer formed on both surfaces of the negative electrode current collector,
At the negative electrode current collecting end, an end of the negative electrode mixture layer is disposed inside an end of the positive electrode sheet in the width direction,
The electrode body according to claim 1, wherein the second buckling position is between an end of the negative electrode mixture layer and an end of the positive electrode sheet.
前記正極合剤層の端部及び前記負極合剤層の端部が先細り形状をしている場合、
前記第1の座屈位置は、前記正極合剤層の先細り開始位置と、前記負極シートの端部との間にあり、
前記第2の座屈位置は、前記負極合剤層の先細り開始位置と、前記正極シートの端部との間にある、請求項2に記載の電極体。
When the end of the positive electrode mixture layer and the end of the negative electrode mixture layer have a tapered shape,
The first buckling position is between a taper start position of the positive electrode mixture layer and an end of the negative electrode sheet,
The electrode body according to claim 2, wherein the second buckling position is between a taper start position of the negative electrode mixture layer and an end of the positive electrode sheet.
前記正極集電端部における前記正極シート、前記負極シート及び前記セパレータの座屈角度は、前記正極合剤層の先細り形状が為す角度と同程度であり、
前記負極集電端部における前記正極シート、前記負極シート及び前記セパレータの座屈角度は、前記負極合剤層の先細り形状が為す角度と同程度である、請求項3に記載の電極体。
The buckling angle of the positive electrode sheet, the negative electrode sheet and the separator at the positive electrode current collecting end is substantially the same as the angle formed by the tapered shape of the positive electrode mixture layer,
4. The electrode body according to claim 3, wherein a buckling angle of the positive electrode sheet, the negative electrode sheet, and the separator at the negative electrode current collecting end is substantially equal to an angle formed by a tapered shape of the negative electrode mixture layer.
前記正極合剤層の端部及び前記負極合剤層の端部が略垂直面を有する場合、
前記第1の座屈位置は、前記正極合剤層の略垂直面と、前記負極シートの端部との間にあり、
前記第2の座屈位置は、前記負極合剤層の略垂直面と、前記正極シートの端部との間にある、請求項2に記載の電極体。
When the end of the positive electrode mixture layer and the end of the negative electrode mixture layer have a substantially vertical surface,
The first buckling position is between a substantially vertical surface of the positive electrode mixture layer and an end of the negative electrode sheet,
The electrode body according to claim 2, wherein the second buckling position is between a substantially vertical surface of the negative electrode mixture layer and an end of the positive electrode sheet.
前記電極体は、捲回型電極体または積層型電極体である、請求項1〜5のいずれか1項に記載の電極体。   The electrode body according to any one of claims 1 to 5, wherein the electrode body is a wound electrode body or a laminated electrode body. 前記正極集電端部と接触する接触面を有し、前記接触面を介して前記正極集電端部に応力を加えることにより、前記正極シート、前記負極シート及び前記セパレータの少なくとも一部を座屈させる正極端子と、
前記負極集電端部と接触する接触面を有し、前記接触面を介して前記負極集電端部に応力を加えることにより、前記負極シート、前記正極シート及び前記セパレータの少なくとも一部を座屈させる負極端子と
を備える、請求項1〜6のいずれか1項に記載の電極体。
A contact surface that contacts the positive electrode current collecting end portion, and stress is applied to the positive electrode current collecting end portion through the contact surface to seat at least a part of the positive electrode sheet, the negative electrode sheet, and the separator. A positive terminal to bend,
A contact surface that contacts the negative electrode current collecting end portion, and stress is applied to the negative electrode current collecting end portion through the contact surface to seat at least a part of the negative electrode sheet, the positive electrode sheet, and the separator. The electrode body according to any one of claims 1 to 6, further comprising: a negative electrode terminal that bends.
前記正極端子の接触面の幅方向内側端部及び前記負極端子の接触面の幅方向内側端部が、湾曲していることを特徴とする、請求項7に記載の電極体。   The electrode body according to claim 7, wherein a width direction inner end of the contact surface of the positive electrode terminal and a width direction inner end of the contact surface of the negative electrode terminal are curved. 請求項1〜8のいずれか1項に記載の電極体を備えた二次電池。   A secondary battery comprising the electrode body according to claim 1. 正極シートと、負極シートと、前記正極シート及び前記負極シートを絶縁するセパレータが積層された電極体を備える二次電池の製造方法であって、
前記電極体の正極集電端部における前記正極シート、前記負極シート及び前記セパレータの少なくとも一部を、積層方向に略垂直な幅方向において前記負極シートの端部よりも内側に位置する第1の座屈位置で積層方向内側に座屈させる第1の座屈工程と、
前記電極体の負極集電端部における前記負極シート、前記正極シート及び前記セパレータの少なくとも一部を、前記幅方向において前記正極シートの端部よりも内側に位置する第2の座屈位置で積層方向内側に座屈させる第2の座屈工程と
を含む、二次電池の製造方法。
A method for manufacturing a secondary battery including a positive electrode sheet, a negative electrode sheet, and an electrode body in which a separator for insulating the positive electrode sheet and the negative electrode sheet is stacked,
At least a part of the positive electrode sheet, the negative electrode sheet, and the separator at the positive electrode current collecting end of the electrode body is located inside the end of the negative electrode sheet in the width direction substantially perpendicular to the laminating direction. A first buckling step of buckling inward in the stacking direction at the buckling position;
At least a part of the negative electrode sheet, the positive electrode sheet, and the separator at the negative electrode current collecting end of the electrode body are stacked at a second buckling position located inside the end of the positive electrode sheet in the width direction. And a second buckling step of buckling inward in the direction.
前記第1の座屈工程において、上側押圧部材及び下側押圧部材の押圧面を介して前記正極集電端部に応力を加えることにより、前記正極シート、前記負極シート及び前記セパレータの少なくとも一部を座屈させ、
前記第2の座屈工程において、上側押圧部材及び下側押圧部材の押圧面を介して前記負極集電端部に応力を加えることにより、前記負極シート、前記正極シート及び前記セパレータの少なくとも一部を座屈させることを特徴とする、請求項10に記載の二次電池の製造方法。
In the first buckling step, at least a portion of the positive electrode sheet, the negative electrode sheet, and the separator is formed by applying stress to the positive electrode current collecting end via the pressing surfaces of the upper pressing member and the lower pressing member. Buckle,
In the second buckling step, at least a part of the negative electrode sheet, the positive electrode sheet, and the separator is formed by applying stress to the negative electrode current collecting end portion via the pressing surfaces of the upper pressing member and the lower pressing member. The method for manufacturing a secondary battery according to claim 10, wherein the secondary battery is buckled.
前記上側押圧部材の押圧面の前記電極体側の端部及び前記下側押圧部材の押圧面の前記電極体側の端部が、湾曲していることを特徴とする、請求項11に記載の二次電池の製造方法。   The secondary according to claim 11, wherein an end of the pressing surface of the upper pressing member on the electrode body side and an end of the pressing surface of the lower pressing member on the electrode body side are curved. Battery manufacturing method.
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