JP2019151620A - Hair composition - Google Patents
Hair composition Download PDFInfo
- Publication number
- JP2019151620A JP2019151620A JP2019024178A JP2019024178A JP2019151620A JP 2019151620 A JP2019151620 A JP 2019151620A JP 2019024178 A JP2019024178 A JP 2019024178A JP 2019024178 A JP2019024178 A JP 2019024178A JP 2019151620 A JP2019151620 A JP 2019151620A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- alcohol
- composition
- present
- hair composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 57
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims abstract description 41
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims abstract description 38
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 31
- 229940049292 n-(3-(dimethylamino)propyl)octadecanamide Drugs 0.000 claims abstract description 25
- WWVIUVHFPSALDO-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCCN(C)C WWVIUVHFPSALDO-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229960000541 cetyl alcohol Drugs 0.000 claims abstract description 21
- 235000019484 Rapeseed oil Nutrition 0.000 claims abstract description 19
- 235000014655 lactic acid Nutrition 0.000 claims abstract description 19
- 239000004310 lactic acid Substances 0.000 claims abstract description 19
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims abstract description 19
- 235000019198 oils Nutrition 0.000 claims abstract description 17
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims abstract description 13
- 150000003839 salts Chemical class 0.000 claims abstract description 10
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229960000735 docosanol Drugs 0.000 claims abstract description 7
- 150000005691 triesters Chemical class 0.000 claims abstract description 4
- 239000003921 oil Substances 0.000 claims description 16
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 230000003750 conditioning effect Effects 0.000 claims description 9
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 claims description 5
- OQILCOQZDHPEAZ-UHFFFAOYSA-N Palmitinsaeure-octylester Natural products CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 claims description 5
- GJQLBGWSDGMZKM-UHFFFAOYSA-N ethylhexyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(CC)CCCCC GJQLBGWSDGMZKM-UHFFFAOYSA-N 0.000 claims description 5
- 229940119170 jojoba wax Drugs 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 claims description 4
- 239000002453 shampoo Substances 0.000 claims description 4
- GHVNFZFCNZKVNT-UHFFFAOYSA-M decanoate Chemical compound CCCCCCCCCC([O-])=O GHVNFZFCNZKVNT-UHFFFAOYSA-M 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 abstract description 6
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 25
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 18
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 16
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical group CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 16
- 239000008213 purified water Substances 0.000 description 15
- 229940058015 1,3-butylene glycol Drugs 0.000 description 12
- 235000019437 butane-1,3-diol Nutrition 0.000 description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 235000011187 glycerol Nutrition 0.000 description 11
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 10
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 9
- 239000003755 preservative agent Substances 0.000 description 9
- 229960004889 salicylic acid Drugs 0.000 description 9
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 8
- BIVBRWYINDPWKA-VLQRKCJKSA-L Glycyrrhizinate dipotassium Chemical compound [K+].[K+].O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@H]1CC[C@]2(C)[C@H]3C(=O)C=C4[C@@H]5C[C@](C)(CC[C@@]5(CC[C@@]4(C)[C@]3(C)CC[C@H]2C1(C)C)C)C(O)=O)C([O-])=O)[C@@H]1O[C@H](C([O-])=O)[C@@H](O)[C@H](O)[C@H]1O BIVBRWYINDPWKA-VLQRKCJKSA-L 0.000 description 8
- -1 amine salt Chemical class 0.000 description 8
- 229940101029 dipotassium glycyrrhizinate Drugs 0.000 description 8
- 230000002335 preservative effect Effects 0.000 description 8
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 7
- 238000009472 formulation Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 239000003205 fragrance Substances 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 239000003814 drug Substances 0.000 description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 150000005846 sugar alcohols Polymers 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- YBJHBAHKTGYVGT-ZKWXMUAHSA-N (+)-Biotin Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)O)SC[C@@H]21 YBJHBAHKTGYVGT-ZKWXMUAHSA-N 0.000 description 2
- MPDGHEJMBKOTSU-YKLVYJNSSA-N 18beta-glycyrrhetic acid Chemical compound C([C@H]1C2=CC(=O)[C@H]34)[C@@](C)(C(O)=O)CC[C@]1(C)CC[C@@]2(C)[C@]4(C)CC[C@@H]1[C@]3(C)CC[C@H](O)C1(C)C MPDGHEJMBKOTSU-YKLVYJNSSA-N 0.000 description 2
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 description 2
- QFOHBWFCKVYLES-UHFFFAOYSA-N Butylparaben Chemical compound CCCCOC(=O)C1=CC=C(O)C=C1 QFOHBWFCKVYLES-UHFFFAOYSA-N 0.000 description 2
- 244000303965 Cyamopsis psoralioides Species 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- FWKQNCXZGNBPFD-UHFFFAOYSA-N Guaiazulene Chemical compound CC(C)C1=CC=C(C)C2=CC=C(C)C2=C1 FWKQNCXZGNBPFD-UHFFFAOYSA-N 0.000 description 2
- AUNGANRZJHBGPY-SCRDCRAPSA-N Riboflavin Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-SCRDCRAPSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 229960005070 ascorbic acid Drugs 0.000 description 2
- 239000011668 ascorbic acid Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- FUWUEFKEXZQKKA-UHFFFAOYSA-N beta-thujaplicin Chemical compound CC(C)C=1C=CC=C(O)C(=O)C=1 FUWUEFKEXZQKKA-UHFFFAOYSA-N 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- RMRCNWBMXRMIRW-BYFNXCQMSA-M cyanocobalamin Chemical compound N#C[Co+]N([C@]1([H])[C@H](CC(N)=O)[C@]\2(CCC(=O)NC[C@H](C)OP(O)(=O)OC3[C@H]([C@H](O[C@@H]3CO)N3C4=CC(C)=C(C)C=C4N=C3)O)C)C/2=C(C)\C([C@H](C/2(C)C)CCC(N)=O)=N\C\2=C\C([C@H]([C@@]/2(CC(N)=O)C)CCC(N)=O)=N\C\2=C(C)/C2=N[C@]1(C)[C@@](C)(CC(N)=O)[C@@H]2CCC(N)=O RMRCNWBMXRMIRW-BYFNXCQMSA-M 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 description 1
- IJALWSVNUBBQRA-UHFFFAOYSA-N 4-Isopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(O)C=C1C IJALWSVNUBBQRA-UHFFFAOYSA-N 0.000 description 1
- SQDAZGGFXASXDW-UHFFFAOYSA-N 5-bromo-2-(trifluoromethoxy)pyridine Chemical compound FC(F)(F)OC1=CC=C(Br)C=N1 SQDAZGGFXASXDW-UHFFFAOYSA-N 0.000 description 1
- 235000003261 Artemisia vulgaris Nutrition 0.000 description 1
- 240000006891 Artemisia vulgaris Species 0.000 description 1
- 235000000832 Ayote Nutrition 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 229920001287 Chondroitin sulfate Polymers 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 244000124209 Crocus sativus Species 0.000 description 1
- 235000015655 Crocus sativus Nutrition 0.000 description 1
- 240000004244 Cucurbita moschata Species 0.000 description 1
- 235000009854 Cucurbita moschata Nutrition 0.000 description 1
- 235000009804 Cucurbita pepo subsp pepo Nutrition 0.000 description 1
- AUNGANRZJHBGPY-UHFFFAOYSA-N D-Lyxoflavin Natural products OCC(O)C(O)C(O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-UHFFFAOYSA-N 0.000 description 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
- 244000061508 Eriobotrya japonica Species 0.000 description 1
- 235000009008 Eriobotrya japonica Nutrition 0.000 description 1
- MPDGHEJMBKOTSU-UHFFFAOYSA-N Glycyrrhetinsaeure Natural products C12C(=O)C=C3C4CC(C)(C(O)=O)CCC4(C)CCC3(C)C1(C)CCC1C2(C)CCC(O)C1(C)C MPDGHEJMBKOTSU-UHFFFAOYSA-N 0.000 description 1
- 240000004670 Glycyrrhiza echinata Species 0.000 description 1
- 235000001453 Glycyrrhiza echinata Nutrition 0.000 description 1
- 235000006200 Glycyrrhiza glabra Nutrition 0.000 description 1
- 235000017382 Glycyrrhiza lepidota Nutrition 0.000 description 1
- 235000008694 Humulus lupulus Nutrition 0.000 description 1
- 241000546188 Hypericum Species 0.000 description 1
- 235000017309 Hypericum perforatum Nutrition 0.000 description 1
- 235000006679 Mentha X verticillata Nutrition 0.000 description 1
- 235000002899 Mentha suaveolens Nutrition 0.000 description 1
- 235000001636 Mentha x rotundifolia Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 244000178231 Rosmarinus officinalis Species 0.000 description 1
- 240000006661 Serenoa repens Species 0.000 description 1
- 235000005318 Serenoa repens Nutrition 0.000 description 1
- 239000004288 Sodium dehydroacetate Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 240000002299 Symphytum officinale Species 0.000 description 1
- 235000005865 Symphytum officinale Nutrition 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- TUFYVOCKVJOUIR-UHFFFAOYSA-N alpha-Thujaplicin Natural products CC(C)C=1C=CC=CC(=O)C=1O TUFYVOCKVJOUIR-UHFFFAOYSA-N 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 235000020958 biotin Nutrition 0.000 description 1
- 239000011616 biotin Substances 0.000 description 1
- 229960002685 biotin Drugs 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 229940067596 butylparaben Drugs 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- SHZIWNPUGXLXDT-UHFFFAOYSA-N caproic acid ethyl ester Natural products CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 1
- 229940082500 cetostearyl alcohol Drugs 0.000 description 1
- YZIYKJHYYHPJIB-UUPCJSQJSA-N chlorhexidine gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O.C1=CC(Cl)=CC=C1NC(=N)NC(=N)NCCCCCCNC(=N)NC(=N)NC1=CC=C(Cl)C=C1 YZIYKJHYYHPJIB-UUPCJSQJSA-N 0.000 description 1
- 229960003333 chlorhexidine gluconate Drugs 0.000 description 1
- 229940059329 chondroitin sulfate Drugs 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 229960002104 cyanocobalamin Drugs 0.000 description 1
- 235000000639 cyanocobalamin Nutrition 0.000 description 1
- 239000011666 cyanocobalamin Substances 0.000 description 1
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 1
- NAPSCFZYZVSQHF-UHFFFAOYSA-N dimantine Chemical class CCCCCCCCCCCCCCCCCCN(C)C NAPSCFZYZVSQHF-UHFFFAOYSA-N 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- IUNMPGNGSSIWFP-UHFFFAOYSA-N dimethylaminopropylamine Chemical compound CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 229960003720 enoxolone Drugs 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 229940074774 glycyrrhizinate Drugs 0.000 description 1
- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 description 1
- 229960002350 guaiazulen Drugs 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 230000003699 hair surface Effects 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229920002674 hyaluronan Polymers 0.000 description 1
- 229960003160 hyaluronic acid Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- NFIDBGJMFKNGGQ-UHFFFAOYSA-N isopropylmethylphenol Natural products CC(C)CC1=CC=CC=C1O NFIDBGJMFKNGGQ-UHFFFAOYSA-N 0.000 description 1
- 229960000448 lactic acid Drugs 0.000 description 1
- 229940010454 licorice Drugs 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- UTBABEVADWVTHM-UHFFFAOYSA-N n,n-dimethylpropan-1-amine;octadecanamide Chemical compound CCCN(C)C.CCCCCCCCCCCCCCCCCC(N)=O UTBABEVADWVTHM-UHFFFAOYSA-N 0.000 description 1
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 description 1
- 229940081510 piroctone olamine Drugs 0.000 description 1
- 210000002826 placenta Anatomy 0.000 description 1
- TXGSOSAONMOPDL-UHFFFAOYSA-N propan-2-yl 3,4,5-trihydroxybenzoate Chemical compound CC(C)OC(=O)C1=CC(O)=C(O)C(O)=C1 TXGSOSAONMOPDL-UHFFFAOYSA-N 0.000 description 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 1
- 229960003415 propylparaben Drugs 0.000 description 1
- 235000015136 pumpkin Nutrition 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 229960000342 retinol acetate Drugs 0.000 description 1
- QGNJRVVDBSJHIZ-QHLGVNSISA-N retinyl acetate Chemical compound CC(=O)OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C QGNJRVVDBSJHIZ-QHLGVNSISA-N 0.000 description 1
- 235000019173 retinyl acetate Nutrition 0.000 description 1
- 239000011770 retinyl acetate Substances 0.000 description 1
- 229960002477 riboflavin Drugs 0.000 description 1
- 235000019192 riboflavin Nutrition 0.000 description 1
- 239000002151 riboflavin Substances 0.000 description 1
- 235000013974 saffron Nutrition 0.000 description 1
- 239000004248 saffron Substances 0.000 description 1
- 235000002020 sage Nutrition 0.000 description 1
- 239000010018 saw palmetto extract Substances 0.000 description 1
- 235000019259 sodium dehydroacetate Nutrition 0.000 description 1
- 229940079839 sodium dehydroacetate Drugs 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229940037001 sodium edetate Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- UIERGBJEBXXIGO-UHFFFAOYSA-N thiamine mononitrate Chemical compound [O-][N+]([O-])=O.CC1=C(CCO)SC=[N+]1CC1=CN=C(C)N=C1N UIERGBJEBXXIGO-UHFFFAOYSA-N 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- PDSVZUAJOIQXRK-UHFFFAOYSA-N trimethyl(octadecyl)azanium Chemical class CCCCCCCCCCCCCCCCCC[N+](C)(C)C PDSVZUAJOIQXRK-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
- 229930007845 β-thujaplicin Natural products 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、ステアラミドプロピルジメチルアミンを含有し、製剤安定性の優れた毛髪用組成物に関する。 The present invention relates to a hair composition containing stearamidopropyldimethylamine and having excellent formulation stability.
毛髪は、へアカラーによる化学処理や、洗髪、ドライヤーの熱による物理処理によってダメージを受ける。毛髪はダメージを受けると、パサつく、まとまりが悪い、つやがなくなるといった様に美的観点においても負要素が発生することはよく知られている。そのため、ダメージを受けた毛髪をケアし、また毛髪に滑らかさ、しっとり感を付与する目的、所謂コンディショニング効果を毛髪に与えるものとして広く用いられてきた。コンディショニング剤は、通常ダメージケア効果や優れた滑らかさ、すべり感などを毛髪に付与することを目的として、ジメチコンやアモジメチコンなどのシリコン類が配合されている。シリコンは摩擦力低減能、展延性などの特徴を有していることから多用されているが、これらシリコンを含有したコンディショニング剤を長期的に使用することによって、シリコン類が毛髪に蓄積し、毛髪表面及びキューティクル間に皮膜を形成するといった報告がある（特許文献１）。一方、シリコン類が配合されていないコンディショニング剤においては、毛髪表面を保護している油分の除去に対し、毛髪に油分を補充して毛髪の感触を改善する目的で、一般にステアリルトリメチルアンモニウム塩やジステアリルジメチルアンモニウム塩といったカチオン性界面活性剤及び高級アルコールを主成分として、更に様々な油剤を添加し、乳化状態とすることで、毛髪に滑らかさやしっとり感を付与して毛髪の表面状態を整えることが知られている（特許文献２〜３）。しかし、毛髪に十分なまとまりを与えるために、製品に配合する油剤の量が増大する傾向があるため（特許文献１）、乳化が経時的に崩壊されてしまう懸念がある。 Hair is damaged by chemical treatment with hair color, shampooing, and physical treatment with the heat of a dryer. It is well known that when hair is damaged, negative elements are generated from an aesthetic point of view, such as dryness, poor texture, and loss of gloss. Therefore, it has been widely used for the purpose of caring damaged hair and imparting a so-called conditioning effect to the hair for the purpose of imparting smoothness and moistness to the hair. Conditioning agents are usually blended with silicones such as dimethicone and amodimethicone for the purpose of imparting damage-care effects, excellent smoothness, slipperiness and the like to the hair. Silicon is widely used because it has features such as ability to reduce frictional force and spreadability, but by using these silicone-containing conditioning agents for a long period of time, silicon accumulates in the hair and hair There is a report that a film is formed between the surface and the cuticle (Patent Document 1). On the other hand, in the case of conditioning agents that do not contain silicones, stearyltrimethylammonium salts and diazides are generally used for the purpose of improving the feel of the hair by replenishing the hair with respect to the removal of the oil that protects the hair surface. The main ingredient is a cationic surfactant such as stearyldimethylammonium salt and higher alcohols, and various oils are added to make it an emulsified state, thereby giving the hair a smooth and moist feeling and adjusting the surface state of the hair. Is known (Patent Documents 2 to 3). However, since there is a tendency that the amount of the oil added to the product increases in order to give the hair a sufficient unit (Patent Document 1), there is a concern that the emulsification may be destroyed over time.
カチオン性界面活性剤はアミン塩型と４級アンモニウム塩型に大別され、通常アミン塩型は、４級アンモニウム塩と比較して、皮膚や粘膜に対する作用が温和であると言われている。アミン塩型のうちアミドアミン化合物は、近年毛髪に滑らかさや柔軟性を付与することが見出され、アミドアミン化合物又はその塩類を配合したコンディショニング剤が提案されており（特許文献４〜５）、また高級アルコールを配合する事で、毛髪を処理前の滑らかな感触に戻すことが知られている（特許文献６）。ステアラミドプロピルジメチルアミンはステアリン酸とジメチルアミノプロピルアミンから得られる植物由来のアミドアミン化合物である。 Cationic surfactants are roughly classified into amine salt types and quaternary ammonium salt types, and it is generally said that amine salt types have milder action on skin and mucous membranes than quaternary ammonium salts. Of the amine salt types, amidoamine compounds have recently been found to impart smoothness and flexibility to hair, and conditioning agents containing amidoamine compounds or salts thereof have been proposed (Patent Documents 4 to 5). It is known that hair is returned to a smooth feel before treatment by blending alcohol (Patent Document 6). Stearamidopropyldimethylamine is a plant-derived amidoamine compound obtained from stearic acid and dimethylaminopropylamine.
高級アルコールは、乳化安定化剤や起泡剤として、クリーム、乳液、あるいはシャンプーなどで用いられており（特許文献７〜８）、またセトステアリルアルコールや水添ナタネ油アルコールといった複数の高級アルコールと水を配合したものも上市されている。 Higher alcohols are used as emulsion stabilizers and foaming agents in creams, emulsions, shampoos, etc. (Patent Documents 7 to 8), and a plurality of higher alcohols such as cetostearyl alcohol and hydrogenated rapeseed oil alcohol The one containing water is also on the market.
本発明者らは、ステアラミドプロピルジメチルアミンを含有する毛髪用組成物を調製し保存したところ、経時的に製剤が分離してしまい、製剤安定性が劣るといった課題を見出した。したがって、本発明はステアラミドプロピルジメチルアミンを含有し、製剤安定性に優れた毛髪用組成物を提供することを課題とする。 When the present inventors prepared and stored a hair composition containing stearamidopropyldimethylamine, the inventors found that the formulation was separated over time, resulting in poor formulation stability. Therefore, an object of the present invention is to provide a hair composition containing stearamidopropyldimethylamine and having excellent formulation stability.
本発明者らは、上記課題を解決すべく鋭意検討を重ねた結果、特定の高級アルコールと特定の酸及び／又はその塩、並びに特定の液状油を含有し、前記高級アルコールと液状油を特定の割合で配合すると、上記課題を解決できることを見出し、本発明を完成するに至った。 As a result of intensive studies to solve the above problems, the inventors of the present invention contain a specific higher alcohol, a specific acid and / or salt thereof, and a specific liquid oil, and specify the higher alcohol and the liquid oil. When it mix | blended in the ratio, it discovered that the said subject could be solved and came to complete this invention.
すなわち本発明は、
（１）（ａ）ステアラミドプロピルジメチルアミン、（ｂ）（ｂ１）セチルアルコール、並びに（ｂ２）水添ナタネ油アルコール、ステアリルアルコール、及びベヘニルアルコールからなる群から選ばれる少なくとも１種の高級アルコール、（ｃ）乳酸及び／又はその塩、及び（ｄ）トリエステル、及びモノエステルからなる群から選ばれる少なくとも１種の液状油、を含有し、（ｂ１＋ｂ２）／（ｄ）の質量比が１．３以上であることを特徴とする毛髪用組成物、
（２）（ｄ）の液状油が、トリ（カプリル・カプリン酸）グリセリル、ホホバ油、ミリスチン酸イソプロピル、パルミチン酸エチルヘキシル、及びエチルヘキサン酸セチルからなる群から選ばれる少なくとも１種である、（１）に記載の毛髪用組成物、
（３）シリコン類を含有しないことを特徴とする（１）又は（２）記載の毛髪用組成物、
（４）毛髪用シャンプー剤、毛髪用リンス剤、毛髪用トリートメント剤、又は毛髪用コンディショニング剤である、（１）〜（３）のいずれかに記載の毛髪用組成物、
である。
That is, the present invention
(1) at least one higher alcohol selected from the group consisting of (a) stearamidopropyldimethylamine, (b) (b1) cetyl alcohol, and (b2) hydrogenated rapeseed oil alcohol, stearyl alcohol, and behenyl alcohol; c) at least one liquid oil selected from the group consisting of lactic acid and / or a salt thereof, and (d) a triester and a monoester, and a mass ratio of (b1 + b2) / (d) is 1.3. A composition for hair characterized by the above,
(2) The liquid oil of (d) is at least one selected from the group consisting of tri (caprylic / capric acid) glyceryl, jojoba oil, isopropyl myristate, ethylhexyl palmitate, and cetyl ethylhexanoate, (1 ) Hair composition according to
(3) The hair composition according to (1) or (2), which does not contain silicon,
(4) The hair composition according to any one of (1) to (3), which is a shampoo for hair, a rinse for hair, a treatment for hair, or a conditioning agent for hair,
It is.
本発明により、ステアラミドプロピルジメチルアミンを含有し、経時的な製剤の分離が抑制された毛髪用組成物を提供することが可能になった。 According to the present invention, it has become possible to provide a hair composition containing stearamidopropyldimethylamine and capable of suppressing the separation of the preparation over time.
本発明の毛髪用組成物において用いる各成分は、通常医薬品、医薬部外品、又は化粧品に用いられる品質のものを適宜使用することができる。 Each component used in the hair composition of the present invention can be appropriately selected from those usually used in pharmaceuticals, quasi drugs, and cosmetics.
本発明の毛髪用組成物中におけるステアラミドプロピルジメチルアミンの含有量は、０．０１〜１０ｗ／ｗ％が好ましく、０．１〜７ｗ／ｗ％がより好ましい。 The content of stearamidopropyldimethylamine in the hair composition of the present invention is preferably from 0.01 to 10 w / w%, more preferably from 0.1 to 7 w / w%.
本発明の毛髪用組成物には、本発明の効果及び使用感等の点から高級アルコールであるセチルアルコールの配合が必須である。そして、セチルアルコール以外に、水添ナタネ油アルコール、ステアリルアルコール、及びベヘニルアルコールから選ばれる少なくとも１種の高級アルコールの配合が必要である。本発明の毛髪用組成物中におけるセチルアルールの含有量は、０．０５〜２０ｗ／ｗ％が好ましく、０．５〜１０ｗ／ｗ％がより好ましい。また、水添ナタネ油アルコール、ステアリルアルコール、またはベヘニルアルコールの含有量は、それぞれ０．０５〜２０ｗ／ｗ％が好ましく、０．５〜１０ｗ／ｗ％がより好ましい。本発明の毛髪組成物中のセタノール、水添ナタネ油アルコール、ステアリルアルコール、及びベヘニルアルコールの合計量としては、本発明の毛髪用組成物中０．１〜４０ｗ／ｗ％が好ましく、１〜２０ｗ／ｗ％がより好ましい。 The hair composition of the present invention must contain cetyl alcohol, which is a higher alcohol, in view of the effects of the present invention and the feeling of use. In addition to cetyl alcohol, blending of at least one higher alcohol selected from hydrogenated rapeseed oil alcohol, stearyl alcohol, and behenyl alcohol is necessary. 0.05-20 w / w% is preferable and, as for content of the cetyl rule in the composition for hair of this invention, 0.5-10 w / w% is more preferable. Moreover, the content of hydrogenated rapeseed oil alcohol, stearyl alcohol, or behenyl alcohol is preferably 0.05 to 20 w / w%, more preferably 0.5 to 10 w / w%. The total amount of cetanol, hydrogenated rapeseed oil alcohol, stearyl alcohol, and behenyl alcohol in the hair composition of the present invention is preferably 0.1 to 40 w / w% in the hair composition of the present invention, and 1 to 20 w / w% is more preferable.
本発明の毛髪用組成物中における乳酸及び／又はその塩の含有量は、本発明の効果の点から０．０５〜５ｗ／ｗ％が好ましく、０．１〜２．５ｗ／ｗ％がより好ましい。また、本発明の組成物中にクエン酸及び／又はその塩を含有すると、製剤の分離が生じてしまうおそれがあるため、本発明の毛髪用組成物中にクエン酸及び／又はその塩は含まないものとすることが好ましい。 The content of lactic acid and / or a salt thereof in the hair composition of the present invention is preferably 0.05 to 5 w / w%, more preferably 0.1 to 2.5 w / w% from the viewpoint of the effect of the present invention. preferable. In addition, when citric acid and / or a salt thereof are contained in the composition of the present invention, there is a possibility that separation of the preparation may occur. Therefore, citric acid and / or a salt thereof is included in the hair composition of the present invention. It is preferable not to have it.
本発明の液状油とは、トリエステル、及び／又はモノエステルを指し、このうち、トリ（カプリル・カプリン酸）グリセリル、ホホバ油、ミリスチン酸イソプロピル、パルミチン酸エチルヘキシル、及びエチルヘキサン酸セチルから選ばれる１種又は２種以上組み合わせて使用することが好ましい。本発明の毛髪用組成物中における液状油の含有量は、本発明の効果の点から０．０１〜３０ｗ／ｗ％が好ましく、０．１〜１５ｗ／ｗ％がより好ましい。 The liquid oil of the present invention refers to triesters and / or monoesters, and is selected from tri (capryl / capric acid) glyceryl, jojoba oil, isopropyl myristate, ethylhexyl palmitate, and cetyl ethylhexanoate. It is preferable to use 1 type or in combination of 2 or more types. The content of the liquid oil in the hair composition of the present invention is preferably 0.01 to 30 w / w%, more preferably 0.1 to 15 w / w% from the viewpoint of the effect of the present invention.
また、本発明の高級アルコール及び液状油の含有比率は、本発明の効果の点から、高級アルコール／液状油の質量比を１．３以上とする必要があり、使用感の観点から、上限値は好ましくは４．０未満である。 In addition, the content ratio of the higher alcohol and the liquid oil of the present invention needs to have a mass ratio of the higher alcohol / liquid oil of 1.3 or more from the viewpoint of the effect of the present invention. Is preferably less than 4.0.
本発明の毛髪用組成物は、更に必要により多価アルコールや水を配合することができる。多価アルコールの例としては、１,３−ブチレングリコール、ジプロピレングリコール、プロピレングリコール、グリセリン等が挙げられ、これらを１種又は２種以上組み合わせてもよい。多価アルコールの配合量は、全組成物中好ましくは２〜５０ｗ／ｗ％であり、より好ましくは２〜３０ｗ／ｗ％未満である。水の配合量は、２〜９０ｗ／ｗ％が好ましく、より好ましくは５〜８５ｗ／ｗ％である。 The hair composition of the present invention can further contain a polyhydric alcohol or water if necessary. Examples of the polyhydric alcohol include 1,3-butylene glycol, dipropylene glycol, propylene glycol, glycerin and the like, and these may be used alone or in combination. The blending amount of the polyhydric alcohol is preferably 2 to 50 w / w% in the total composition, and more preferably less than 2 to 30 w / w%. As for the compounding quantity of water, 2-90 w / w% is preferable, More preferably, it is 5-85 w / w%.
本発明の毛髪用組成物は、更に必要によりステアラミドプロピルジメチルアミン以外の各種界面活性剤を配合することができる。ステアラミドプロピルジメチルアミン以外の界面活性剤は、１種又は２種以上組み合わせてもよい。界面活性剤の配合量は、全組成物中好ましくは０．００１〜７５ｗ／ｗ％であり、より好ましくは０．０１〜４０ｗ／ｗ％未満である。 The hair composition of the present invention can further contain various surfactants other than stearamidepropyldimethylamine as necessary. Surfactants other than stearamidepropyldimethylamine may be used alone or in combination. The blending amount of the surfactant is preferably 0.001 to 75 w / w%, more preferably 0.01 to less than 40 w / w% in the entire composition.
本発明の毛髪用組成物は、上記した各成分の他に、本発明の効果を損なわない範囲で、通常の化粧料、医薬部外品、医薬品などに用いられる各種成分を加えることができる。例えば、賦形剤、香料、清涼化剤（メントール、ハッカ油、カンフル等）、抗炎症剤（グアイアズレン、サリチル酸、グリチルリチン酸塩、グリチルレチン酸等）、殺菌剤（グルコン酸クロルヘキシジン、イソプロピルメチルフェノール、第４級アンモニウム塩、ピロクトンオラミン等）、防腐剤（パラベン類（メチルパラベン、ブチルパラベン、プロピルパラベン等）、安息香酸又はその塩、デヒドロ酢酸ナトリウム、ヒノキチオール等）、保湿剤（ヒアルロン酸又はその塩、コンドロイチン硫酸等）、各種動植物（イチイ、ボタンピ、カンゾウ、オトギリソウ、附子、ビワ、カワラヨモギ、コンフリー、アシタバ、サフラン、サンシシ、ローズマリー、セージ、モッコウ、セイモッコウ、ホップ、プラセンタ、ノコギリヤシ、パンプキンシード等）の抽出物、ビタミン類（酢酸レチノール、アスコルビン酸、硝酸チアミン、シアノコバラミン、ビオチン、リボフラビン等）、抗酸化剤（ジブチルヒドロキシトルエン、ピロ亜硫酸ナトリウム、トコフェロール、エデト酸ナトリウム、アスコルビン酸、イソプロピルガレート等）、溶解補助剤（各種植物油、各種動物油、アルキルグリセリルエーテル、炭化水素類等）、代謝賦活剤、ゲル化剤（水溶性高分子等）、粘着剤から成る群より選ばれた成分が挙げられる。 In addition to the components described above, the hair composition of the present invention can contain various components used in ordinary cosmetics, quasi-drugs, pharmaceuticals, and the like as long as the effects of the present invention are not impaired. For example, excipients, fragrances, refreshing agents (menthol, mint oil, camphor, etc.), anti-inflammatory agents (guaiazulene, salicylic acid, glycyrrhizinate, glycyrrhetinic acid, etc.), bactericides (chlorhexidine gluconate, isopropylmethylphenol, Quaternary ammonium salts, piroctone olamine, etc.), preservatives (parabens (methylparaben, butylparaben, propylparaben, etc.), benzoic acid or salts thereof, sodium dehydroacetate, hinokitiol, etc.), humectants (hyaluronic acid or salts thereof) , Chondroitin sulfate, etc.), various animals and plants (yew, buttonpi, licorice, hypericum, appendix, loquat, riverwood mugwort, comfrey, ashitaba, saffron, sanshishi, rosemary, sage, mokko, seimokko, hops, placenta, saw palmetto, pumpkin Extract), vitamins (retinol acetate, ascorbic acid, thiamine nitrate, cyanocobalamin, biotin, riboflavin, etc.), antioxidants (dibutylhydroxytoluene, sodium pyrosulfite, tocopherol, sodium edetate, ascorbic acid, isopropyl Gallate, etc.), solubilizing agents (various vegetable oils, various animal oils, alkyl glyceryl ethers, hydrocarbons, etc.), metabolic activators, gelling agents (water-soluble polymers, etc.), and adhesives. Can be mentioned.
また、本発明の毛髪用組成物はシリコン類を含まないものとすることが好ましい。 The hair composition of the present invention preferably contains no silicon.
これら選択成分の添加量は、特に制約はなく、使用感等を考慮しながら実験的に定めることができる。 The addition amount of these selective components is not particularly limited, and can be determined experimentally in consideration of a feeling of use and the like.
本発明の毛髪用組成物は化粧料、医薬部外品、医薬品などの用途に使用できる。また、本発明の毛髪用組成物は、毛髪用シャンプー剤、毛髪用リンス剤、毛髪用トリートメント剤、及び毛髪用コンディショニング剤等として使用すること好ましく、より好ましくは、毛髪用コンディショニング剤である。 The composition for hair of this invention can be used for uses, such as cosmetics, a quasi-drug, and a pharmaceutical. The hair composition of the present invention is preferably used as a hair shampoo, hair rinse, hair treatment, hair conditioning agent, and the like, and more preferably a hair conditioning agent.
本発明の毛髪用組成物の調製は、常法に従い、上記各成分を含有することにより調製される。 The hair composition of the present invention is prepared by containing each of the above components according to a conventional method.
以下に、実施例、比較例及び試験例を記載し、本発明をさらに具体的に説明するが、本発明はこれら実施例等により何ら制約されるものではない。 EXAMPLES Examples, comparative examples, and test examples will be described below, and the present invention will be described more specifically. However, the present invention is not limited by these examples.
以下表１に示す処方に従い実施例１〜９及び比較例１〜３の毛髪用組成物を常法により調製した。
具体的には、約８０℃の湯浴中で、ステアラミドプロピルジメチルアミン、高級アルコール、液状油、多価アルコール及びｌ−メントールを混合した後、酸、ポリクオタニウム−１０、サリチル酸、防腐剤及び精製水を添加しホモミキサーを用いて乳化した。その後、約５０℃まで冷却し、グリチルリチン酸ジカリウム、香料及び精製水を加えて混合し、毛髪用組成物を得た。
The hair compositions of Examples 1 to 9 and Comparative Examples 1 to 3 were prepared by a conventional method according to the formulation shown in Table 1 below.
Specifically, stearamidepropyldimethylamine, higher alcohol, liquid oil, polyhydric alcohol and l-menthol are mixed in a hot water bath at about 80 ° C., and then acid, polyquaternium-10, salicylic acid, preservative and purification. Water was added and emulsified using a homomixer. Then, it cooled to about 50 degreeC, the dipotassium glycyrrhizinate, the fragrance | flavor, and purified water were added and mixed, and the composition for hair was obtained.
（実施例１）
水添ナタネ油アルコール４ｇ、セチルアルコール４ｇ、ステアラミドプロピルジメチルアミン３ｇ、トリ（カプリル・カプリン酸）グリセリル６ｇ、乳酸０．６５ｇ、ポリクオタニウム−１０ ０．１ｇ、１，３−ブチレングリコール４ｇ、濃グリセリン２ｇ、サリチル酸０．１ｇ、グリチルリチン酸ジカリウム０．１ｇ、ｌ−メントール０．５ｇ、防腐剤０．２ｇ、香料０．４ｇ、精製水で全量を１００ｇとした毛髪用組成物を得た。
Example 1
Hydrogenated rapeseed oil alcohol 4g, cetyl alcohol 4g, stearamidopropyldimethylamine 3g, tri (capryl / capric acid) glyceryl 6g, lactic acid 0.65g, polyquaternium-10 0.1g, 1,3-butylene glycol 4g, concentrated glycerin 2 g, 0.1 g salicylic acid, 0.1 g dipotassium glycyrrhizinate, 0.5 g l-menthol, 0.2 g preservative, 0.4 g fragrance, and 100 g of purified water were used to obtain a hair composition.
（実施例２）
水添ナタネ油アルコール４ｇ、セチルアルコール４ｇ、ステアラミドプロピルジメチルアミン３ｇ、トリ（カプリル・カプリン酸）グリセリル６ｇ、乳酸０．９ｇ、ポリクオタニウム−１０ ０．１ｇ、１，３−ブチレングリコール６ｇ、サリチル酸０．１ｇ、グリチルリチン酸ジカリウム０．１ｇ、ｌ−メントール０．６ｇ、防腐剤０．２ｇ、精製水で全量を１００ｇとした毛髪用組成物を得た。
(Example 2)
Hydrogenated rapeseed oil alcohol 4 g, cetyl alcohol 4 g, stearamidopropyldimethylamine 3 g, tri (capryl-capric acid) glyceryl 6 g, lactic acid 0.9 g, polyquaternium-10 0.1 g, 1,3-butylene glycol 6 g, salicylic acid 0 .1 g, 0.1 g of dipotassium glycyrrhizinate, 0.6 g of 1-menthol, 0.2 g of preservative, and 100 g of purified water were obtained.
（実施例３）
水添ナタネ油アルコール３．５ｇ、セチルアルコール３．５ｇ、ステアラミドプロピルジメチルアミン３．５ｇ、トリ（カプリル・カプリン酸）グリセリル２ｇ、乳酸０．３５ｇ、流動パラフィン２ｇ、ポリクオタニウム−１０ ０．１ｇ、１，３−ブチレングリコール４ｇ、濃グリセリン２ｇ、サリチル酸０．１ｇ、グリチルリチン酸ジカリウム０．１ｇ、ｌ−メントール０．５ｇ、防腐剤０．２ｇ、香料０．４ｇ、精製水で全量を１００ｇとした毛髪用組成物を得た。
(Example 3)
Hydrogenated rapeseed oil alcohol 3.5 g, cetyl alcohol 3.5 g, stearamidopropyldimethylamine 3.5 g, tri (capryl / capric acid) glyceryl 2 g, lactic acid 0.35 g, liquid paraffin 2 g, polyquaternium-10 0.1 g, 1,3-butylene glycol 4 g, concentrated glycerin 2 g, salicylic acid 0.1 g, dipotassium glycyrrhizinate 0.1 g, l-menthol 0.5 g, preservative 0.2 g, fragrance 0.4 g, and purified water to a total amount of 100 g A hair composition was obtained.
（実施例４）
水添ナタネ油アルコール４ｇ、セチルアルコール４ｇ、ステアラミドプロピルジメチルアミン３ｇ、トリ（カプリル・カプリン酸）グリセリル３ｇ、流動パラフィン３ｇ、乳酸０．６５ｇ、ポリクオタニウム−１０ ０．１ｇ、１，３−ブチレングリコール４ｇ、濃グリセリン２ｇ、サリチル酸０．１ｇ、グリチルリチン酸ジカリウム０．１ｇ、ｌ−メントール０．５ｇ、防腐剤０．２ｇ、香料０．４ｇ、精製水で全量を１００ｇとした毛髪用組成物を得た。
Example 4
Hydrogenated rapeseed oil alcohol 4 g, cetyl alcohol 4 g, stearamidopropyldimethylamine 3 g, tri (capryl / capric acid) glyceryl 3 g, liquid paraffin 3 g, lactic acid 0.65 g, polyquaternium-10 0.1 g, 1,3-butylene glycol 4 g, concentrated glycerin 2 g, salicylic acid 0.1 g, dipotassium glycyrrhizinate 0.1 g, l-menthol 0.5 g, preservative 0.2 g, fragrance 0.4 g, and purified water with a total amount of 100 g are obtained. It was.
（実施例５）
水添ナタネ油アルコール３．５ｇ、セチルアルコール３．５ｇ、ステアラミドプロピルジメチルアミン３．５ｇ、トリ（カプリル・カプリン酸）グリセリル２ｇ、乳酸０．９ｇ、ポリクオタニウム−１０ ０．１ｇ、１，３−ブチレングリコール４ｇ、濃グリセリン２ｇ、精製水で全量を１００ｇとした毛髪用組成物を得た。
(Example 5)
Hydrogenated rapeseed oil alcohol 3.5 g, cetyl alcohol 3.5 g, stearamidopropyldimethylamine 3.5 g, tri (capryl-capric acid) glyceryl 2 g, lactic acid 0.9 g, polyquaternium-10 0.1 g, 1,3- A hair composition having a total amount of 100 g was obtained with 4 g of butylene glycol, 2 g of concentrated glycerin and purified water.
（実施例６）
水添ナタネ油アルコール３．５ｇ、セチルアルコール３．５ｇ、ステアラミドプロピルジメチルアミン３．５ｇ、ミリスチン酸イソプロピル４ｇ、乳酸０．９ｇ、ポリクオタニウム−１０ ０．１ｇ、１，３−ブチレングリコール４ｇ、濃グリセリン２ｇ、精製水で全量を１００ｇとした毛髪用組成物を得た。
(Example 6)
Hydrogenated rapeseed oil alcohol 3.5 g, cetyl alcohol 3.5 g, stearamidopropyldimethylamine 3.5 g, isopropyl myristate 4 g, lactic acid 0.9 g, polyquaternium-10 0.1 g, 1,3-butylene glycol 4 g, concentrated A hair composition having a total amount of 100 g with 2 g of glycerin and purified water was obtained.
（実施例７）
水添ナタネ油アルコール３．５ｇ、セチルアルコール３．５ｇ、ステアラミドプロピルジメチルアミン３．５ｇ、ホホバ油４ｇ、乳酸０．９ｇ、ポリクオタニウム−１０ ０．１ｇ、１，３−ブチレングリコール４ｇ、濃グリセリン２ｇ、精製水で全量を１００ｇとした毛髪用組成物を得た。
(Example 7)
Hydrogenated rapeseed oil alcohol 3.5 g, cetyl alcohol 3.5 g, stearamidopropyldimethylamine 3.5 g, jojoba oil 4 g, lactic acid 0.9 g, polyquaternium-10 0.1 g, 1,3-butylene glycol 4 g, concentrated glycerin A hair composition having a total amount of 100 g with 2 g of purified water was obtained.
（実施例８）
ベヘニルアルコール３．５ｇ、セチルアルコール３．５ｇ、ステアラミドプロピルジメチルアミン３．５ｇ、トリ（カプリル・カプリン酸）グリセリル４ｇ、乳酸０．９ｇ、ポリクオタニウム−１０ ０．１ｇ、１，３−ブチレングリコール６ｇ、精製水で全量を１００ｇとした毛髪用組成物を得た。
(Example 8)
Behenyl alcohol 3.5 g, cetyl alcohol 3.5 g, stearamidopropyldimethylamine 3.5 g, tri (capryl / capric acid) glyceryl 4 g, lactic acid 0.9 g, polyquaternium-10 0.1 g, 1,3-butylene glycol 6 g, A composition for hair having a total amount of 100 g with purified water was obtained.
（実施例９）
ステアリルアルコール３．５ｇ、セチルアルコール３．５ｇ、ステアラミドプロピルジメチルアミン３．５ｇ、トリ（カプリル・カプリン酸）グリセリル４ｇ、乳酸０．９ｇ、ポリクオタニウム−１０ ０．１ｇ、１，３−ブチレングリコール６ｇ、精製水で全量を１００ｇとした毛髪用組成物を得た。
Example 9
Stearyl alcohol 3.5 g, cetyl alcohol 3.5 g, stearamidopropyldimethylamine 3.5 g, tri (capryl / capric acid) glyceryl 4 g, lactic acid 0.9 g, polyquaternium-10 0.1 g, 1,3-butylene glycol 6 g The composition for hair which made the whole quantity 100g with purified water was obtained.
（実施例１０）
水添ナタネ油アルコール３ｇ、セチルアルコール０．５ｇ、ステアリルアルコール３ｇ、ステアラミドプロピルジメチルアミン２ｇ、パルミチン酸エチルヘキシル５ｇ、乳酸１．０ｇ、グアーヒドロキシプロピルトリモニウムクロリド０．３ｇ、１，３−ブチレングリコール４ｇ、濃グリセリン２ｇ、精製水で全量を１００ｇとした毛髪用組成物を得た。
(Example 10)
Hydrogenated rapeseed oil alcohol 3 g, cetyl alcohol 0.5 g, stearyl alcohol 3 g, stearamide propyldimethylamine 2 g, ethylhexyl palmitate 5 g, lactic acid 1.0 g, guar hydroxypropyltrimonium chloride 0.3 g, 1,3-butylene glycol A hair composition having a total amount of 100 g with 4 g, concentrated glycerin 2 g and purified water was obtained.
（実施例１１）
水添ナタネ油アルコール３ｇ、セチルアルコール１．０ｇ、ステアリルアルコール２ｇ、ステアラミドプロピルジメチルアミン２ｇ、エチルヘキサン酸セチル４ｇ、乳酸０．９ｇ、グアーヒドロキシプロピルトリモニウムクロリド０．３ｇ、１，３−ブチレングリコール４ｇ、ジプロピレングリコール２ｇ、精製水で全量を１００ｇとした毛髪用組成物を得た。
(Example 11)
Hydrogenated rapeseed oil alcohol 3 g, cetyl alcohol 1.0 g, stearyl alcohol 2 g, stearamidopropyldimethylamine 2 g, ethyl hexanoate cetyl 4 g, lactic acid 0.9 g, guar hydroxypropyltrimonium chloride 0.3 g, 1,3-butylene A hair composition having a total amount of 100 g with 4 g of glycol, 2 g of dipropylene glycol and purified water was obtained.
（比較例１）
水添ナタネ油アルコール４ｇ、セチルアルコール４ｇ、ステアラミドプロピルジメチルアミン３ｇ、トリ（カプリル・カプリン酸）グリセリル６ｇ、クエン酸０．５ｇ、クエン酸ナトリウム０．０１５ｇ、ポリクオタニウム−１０ ０．１ｇ、１，３−ブチレングリコール４ｇ、濃グリセリン２ｇ、サリチル酸０．１ｇ、グリチルリチン酸ジカリウム０．１ｇ、ｌ−メントール０．５ｇ、防腐剤０．２ｇ、精製水で全量を１００ｇとした毛髪用組成物を得た。
(Comparative Example 1)
Hydrogenated rapeseed oil alcohol 4 g, cetyl alcohol 4 g, stearamidopropyldimethylamine 3 g, tri (capryl / capric acid) glyceryl 6 g, citric acid 0.5 g, sodium citrate 0.015 g, polyquaternium-10 0.1 g, 1, A hair composition having a total amount of 100 g with 4 g of 3-butylene glycol, 2 g of concentrated glycerin, 0.1 g of salicylic acid, 0.1 g of dipotassium glycyrrhizinate, 0.5 g of l-menthol, preservative 0.2 g and purified water was obtained. .
（比較例２）
水添ナタネ油アルコール８ｇ、ステアラミドプロピルジメチルアミン３ｇ、トリ（カプリル・カプリン酸）グリセリル６ｇ、乳酸０．９ｇ、ポリクオタニウム−１０ ０．１ｇ、１，３−ブチレングリコール４ｇ、濃グリセリン２ｇ、サリチル酸０．１ｇ、グリチルリチン酸ジカリウム０．１ｇ、ｌ−メントール０．５ｇ、防腐剤０．２ｇ、精製水で全量を１００ｇとした毛髪用組成物を得た。
(Comparative Example 2)
8 g of hydrogenated rapeseed oil alcohol, 3 g of stearamidopropyldimethylamine, 6 g of tri (capryl / capric) glyceryl, 0.9 g of lactic acid, 0.1 g of polyquaternium-10, 4 g of 1,3-butylene glycol, 2 g of concentrated glycerin, 0 of salicylic acid .1 g, 0.1 g of dipotassium glycyrrhizinate, 0.5 g of 1-menthol, 0.2 g of preservative, and 100 g of purified water were obtained.
（比較例３）
水添ナタネ油アルコール３ｇ、セチルアルコール３ｇ、ステアラミドプロピルジメチルアミン３ｇ、トリ（カプリル・カプリン酸）グリセリル６ｇ、乳酸０．６５ｇ、ポリクオタニウム−１０ ０．１ｇ、１，３−ブチレングリコール４ｇ、濃グリセリン２ｇ、サリチル酸０．１ｇ、グリチルリチン酸ジカリウム０．１ｇ、ｌ−メントール０．５ｇ、防腐剤０．２ｇ、香料０．４ｇ、精製水で全量を１００ｇとした毛髪用組成物を得た。
(Comparative Example 3)
Hydrogenated rapeseed oil alcohol 3 g, cetyl alcohol 3 g, stearamidopropyldimethylamine 3 g, tri (capryl / capric acid) glyceryl 6 g, lactic acid 0.65 g, polyquaternium-10 0.1 g, 1,3-butylene glycol 4 g, concentrated glycerin 2 g, 0.1 g salicylic acid, 0.1 g dipotassium glycyrrhizinate, 0.5 g l-menthol, 0.2 g preservative, 0.4 g fragrance, and 100 g of purified water were used to obtain a hair composition.
＜試験例：製剤の分離の評価＞
実施例１〜実施例１１、及び比較例１〜比較例３に関し、５０℃条件下４日保存した後の製剤の状況を目視で観察した。結果を表２に示す。
<Test Example: Evaluation of Separation of Formulation>
Regarding Examples 1 to 11 and Comparative Examples 1 to 3, the condition of the preparations after storage for 4 days under 50 ° C. was visually observed. The results are shown in Table 2.
ステアラミドプロピルジメチルアミン、乳酸、セチルアルコールを含む特定の２種以上の高級アルコール、及びトリ（カプリル・カプリン酸）グリセリル、ホホバ油、ミリスチン酸イソプロピル、パルミチン酸エチルヘキシル又はエチルヘキサン酸セチルをそれぞれ組み合わせた実施例１〜実施例１１では、製剤の分離が認められなかった。一方、乳酸の代わりにクエン酸及びクエン酸ナトリウムを含有した比較例１と、セチルアルコールを含有していない比較例２、及び高級アルコール／液状油の質量比が１．３未満である比較例３は製剤の分離が認められた。 Two or more specific higher alcohols including stearamidopropyldimethylamine, lactic acid, cetyl alcohol, and glyceryl tri (capryl / caprate), jojoba oil, isopropyl myristate, ethylhexyl palmitate, or cetyl ethylhexanoate In Examples 1 to 11, no separation of the preparation was observed. On the other hand, Comparative Example 1 containing citric acid and sodium citrate instead of lactic acid, Comparative Example 2 containing no cetyl alcohol, and Comparative Example 3 having a higher alcohol / liquid oil mass ratio of less than 1.3 Separation of the formulation was observed.
本発明により、ステアラミドプロピルジメチルアミンを含有し、製剤の分離が抑制された優れた毛髪用組成物を提供することが可能になった。 According to the present invention, it has become possible to provide an excellent hair composition containing stearamidopropyldimethylamine and in which separation of the preparation is suppressed.
Claims (4)
（ｂ）（ｂ１）セチルアルコール、並びに（ｂ２）水添ナタネ油アルコール、ステアリルアルコール、及びベヘニルアルコールからなる群から選ばれる少なくとも１種の高級アルコール、
（ｃ）乳酸及び／又はその塩、及び
（ｄ）トリエステル、及びモノエステルからなる群から選ばれる少なくとも１種の液状油を含有し、
（ｂ１＋ｂ２）／（ｄ）の質量比が１．３以上であることを特徴とする毛髪用組成物。 (A) stearamidopropyldimethylamine,
(B) (b1) cetyl alcohol, and (b2) at least one higher alcohol selected from the group consisting of hydrogenated rapeseed oil alcohol, stearyl alcohol, and behenyl alcohol,
(C) containing at least one liquid oil selected from the group consisting of lactic acid and / or a salt thereof, and (d) a triester and a monoester,
A composition for hair, wherein the mass ratio of (b1 + b2) / (d) is 1.3 or more.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2018036721 | 2018-03-01 | ||
| JP2018036721 | 2018-03-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2019151620A true JP2019151620A (en) | 2019-09-12 |
Family
ID=67948207
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019024178A Pending JP2019151620A (en) | 2018-03-01 | 2019-02-14 | Hair composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2019151620A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3146273A1 (en) * | 2023-03-03 | 2024-09-06 | L'oreal | COMPOSITION SUITABLE FOR TREATMENT OF SCALP/HAIR |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005314306A (en) * | 2004-04-28 | 2005-11-10 | Kao Corp | Hair cosmetic |
| EP2116226A1 (en) * | 2008-05-08 | 2009-11-11 | Beiersdorf AG | Hair care formulas with cationic amphoteric polymers |
| WO2010016591A1 (en) * | 2008-08-08 | 2010-02-11 | 株式会社 資生堂 | Hair conditioner composition |
| WO2010090219A1 (en) * | 2009-02-03 | 2010-08-12 | 株式会社 資生堂 | Hair conditioner composition and low-energy manufacturing method for the same |
| JP2012236804A (en) * | 2011-05-13 | 2012-12-06 | Kao Corp | Hair cosmetic |
| JP2014062226A (en) * | 2012-08-31 | 2014-04-10 | Kawaken Fine Chemicals Co Ltd | Thickener composition |
| US20170165160A1 (en) * | 2014-08-29 | 2017-06-15 | Henkel Ag & Co. Kgaa | Method of increasing the wash resistance of artificially colored hair |
| JP2017109952A (en) * | 2015-12-16 | 2017-06-22 | ヘンケルジャパン株式会社 | Hair dye cosmetic |
-
2019
- 2019-02-14 JP JP2019024178A patent/JP2019151620A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005314306A (en) * | 2004-04-28 | 2005-11-10 | Kao Corp | Hair cosmetic |
| EP2116226A1 (en) * | 2008-05-08 | 2009-11-11 | Beiersdorf AG | Hair care formulas with cationic amphoteric polymers |
| WO2010016591A1 (en) * | 2008-08-08 | 2010-02-11 | 株式会社 資生堂 | Hair conditioner composition |
| WO2010090219A1 (en) * | 2009-02-03 | 2010-08-12 | 株式会社 資生堂 | Hair conditioner composition and low-energy manufacturing method for the same |
| JP2012236804A (en) * | 2011-05-13 | 2012-12-06 | Kao Corp | Hair cosmetic |
| JP2014062226A (en) * | 2012-08-31 | 2014-04-10 | Kawaken Fine Chemicals Co Ltd | Thickener composition |
| US20170165160A1 (en) * | 2014-08-29 | 2017-06-15 | Henkel Ag & Co. Kgaa | Method of increasing the wash resistance of artificially colored hair |
| JP2017109952A (en) * | 2015-12-16 | 2017-06-22 | ヘンケルジャパン株式会社 | Hair dye cosmetic |
Non-Patent Citations (10)
| Title |
|---|
| AEKYUNG, SOUTH KOREA: "Scalp & Hair Pack", MINTEL GNPD [ONLINE], JPN6023028134, November 2017 (2017-11-01), ISSN: 0005195064 * |
| ANGFA, JAPAN: "Pack Conditioner", MINTEL GNPD [ONLINE], JPN6023028140, September 2017 (2017-09-01), ISSN: 0005195069 * |
| BEIERSDORF, GERMANY: "Conditioner", MINTEL GNPD [ONLINE], JPN6023028137, July 2011 (2011-07-01), ISSN: 0005195067 * |
| INDOLA, GERMANY: "Conditioner", MINTEL GNPD [ONLINE], JPN6023028138, October 2017 (2017-10-01), ISSN: 0005195068 * |
| JAPAN GATEWAY, JAPAN: "Treatment", MINTEL GNPD [ONLINE], JPN6023046819, June 2016 (2016-06-01), ISSN: 0005195063 * |
| KOSE, JAPAN: "Color Treatment", MINTEL GNPD [ONLINE], JPN6023028136, September 2017 (2017-09-01), ISSN: 0005195066 * |
| LOVE LABO, JAPAN: "Treatment", MINTEL GNPD [ONLINE], JPN6023046818, March 2013 (2013-03-01), ISSN: 0005195062 * |
| PROFOUND BEAUTY, USA: "Time-Out Treatment", MINTEL GNPD [ONLINE], JPN6023006121, October 2009 (2009-10-01), ISSN: 0005195071 * |
| UNILEVER: "Nourish & Replenish Conditioner", MINTEL GNPD [ONLINE], JPN6023028135, December 2015 (2015-12-01), ISSN: 0005195065 * |
| WATSONS PERSONAL CARE STORES, MALAYSIA: "Treatment Conditioner", MINTEL GNPD [ONLINE], JPN6023028139, March 2016 (2016-03-01), ISSN: 0005195070 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3146273A1 (en) * | 2023-03-03 | 2024-09-06 | L'oreal | COMPOSITION SUITABLE FOR TREATMENT OF SCALP/HAIR |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5699476B2 (en) | Hair growth | |
| JP6907527B2 (en) | Topical composition | |
| JP5342736B2 (en) | Oil-in-water emulsion and method for producing the same | |
| JP2010163418A (en) | Cosmetic | |
| JP2002193755A (en) | Antidandruff and anti-itching hair cosmetic and hair- shampooing cosmetic | |
| JP2014051444A (en) | Two layer separation type liquid composition for oral cavity | |
| JP2019151620A (en) | Hair composition | |
| JP6754171B2 (en) | Water-in-oil emulsified composition | |
| JP6424815B2 (en) | Composition for external use | |
| JP2009234993A (en) | Water-in-oil emulsion composition containing salicylic acid or salicylic acid derivative | |
| JP6221536B2 (en) | Composition for external use | |
| JP6903411B2 (en) | Topical composition | |
| JP2021004184A (en) | Method of stabilizing allantoin and/or derivative thereof | |
| JP4972895B2 (en) | Urea formulation for external use | |
| JP2019151619A (en) | Hair composition | |
| JP2015203029A (en) | Pharmaceutical composition and preparation for xeroderma or atopic dermatitis | |
| JP2007169243A (en) | Hair cosmetic | |
| WO2019151275A1 (en) | Method for improving stickiness of adenosine-phosphate-containing composition | |
| JP2016088872A (en) | TEXTURE IMPROVING AGENT IN WHICH α GEL-STRUCTURE IS FORMED, AND COSMETIC OR EXTERNAL SKIN PREPARATION FOR IMPROVING TEXTURE CONTAINING THE SAME | |
| JP2021091609A (en) | Emulsion composition | |
| JP2021001138A (en) | External composition | |
| JP6845608B2 (en) | Topical skin agent | |
| JP7575722B2 (en) | External pharmaceutical composition | |
| JP2018197197A (en) | Emulsion type external preparation for skin | |
| TW202228712A (en) | Emulsified composition for external application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20220204 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20230214 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20230221 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20230405 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20230711 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20230817 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20231114 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20231206 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20240220 |
|
| RD03 | Notification of appointment of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7423 Effective date: 20240308 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20240513 |
|
| A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20240520 |
|
| A912 | Re-examination (zenchi) completed and case transferred to appeal board |
Free format text: JAPANESE INTERMEDIATE CODE: A912 Effective date: 20240712 |