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JP2018123181A5 - Selection method and inkjet ink - Google Patents

Selection method and inkjet ink Download PDF

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JP2018123181A5
JP2018123181A5 JP2017013923A JP2017013923A JP2018123181A5 JP 2018123181 A5 JP2018123181 A5 JP 2018123181A5 JP 2017013923 A JP2017013923 A JP 2017013923A JP 2017013923 A JP2017013923 A JP 2017013923A JP 2018123181 A5 JP2018123181 A5 JP 2018123181A5
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molecular weight
axis
dispersant
maximum
absorption
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JP6822175B2 (en
JP2018123181A (en
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Claims (7)

色材、分散剤および水を含有するインクジェットインクに用いる前記分散剤の選定方法であって、
外吸光度検出器を用いてGPC(Gel Permeation Chromatography)法で測定された、前記分散剤の、分子量および前記分子量と対応する紫外線吸収スペクトルにおいて、x軸;時間(分子量)、y軸;UV波長、z軸;強度(AU)で表した3次元の前記z軸真上から描いた等高線において、前記y軸値がmaxの時の分子量(UV吸収波長最大時の分子量)をBa、前記y軸値がmaxの時のUV吸収波長(UV吸収波長最大値)をBb、前記z軸値がmaxの時の分子量(UV吸収強度最大時の分子量)をAa、前記Aaと対応するUV吸収波長(UV吸収強度最大時のUV吸収波長)をAbとしたとき、式(1)、(2)を満たすように前記分散剤を選定する、選定方法
|Bb−Ab|≧50[nm] ・・・(1)
1000≦|Ba−Aa|≦30000 ・・・(2)
A method for selecting the dispersant used in an inkjet ink containing a coloring material, a dispersant, and water,
In the molecular weight of the dispersant and an ultraviolet absorption spectrum corresponding to the molecular weight measured by a GPC (Gel Permeation Chromatography) method using an ultraviolet absorbance detector, x axis: time (molecular weight), y axis: UV wavelength In the three-dimensional contour line drawn from directly above the z-axis expressed by intensity (AU), the molecular weight when the y-axis value is max (the molecular weight at the maximum UV absorption wavelength) is Ba, the y-axis. The UV absorption wavelength (maximum UV absorption wavelength) when the value is max is Bb, the molecular weight when the z-axis value is max (the molecular weight when the UV absorption intensity is maximum) is Aa, and the UV absorption wavelength corresponding to the Aa ( A method for selecting the dispersant so as to satisfy Formulas (1) and (2), where Ab is the UV absorption wavelength at the maximum UV absorption intensity.
| Bb−Ab | ≧ 50 [nm] (1)
1000 ≦ | Ba−Aa | ≦ 30000 (2)
前記分子量Aa及び分子量Baが、ともに1000以上である請求項1に記載の選定方法The selection method according to claim 1, wherein both the molecular weight Aa and the molecular weight Ba are 1000 or more. 前記分散剤が、分子構造中に1つ以上の芳香環を含む請求項1または請求項2に記載の選定方法The selection method according to claim 1, wherein the dispersant includes one or more aromatic rings in a molecular structure. 前記分散剤が、芳香族スルホン酸塩のホルマリン縮合物、またはリグニンスルホン酸塩、アクリル系樹脂、スチレン−アクリル系樹脂、スチレン−マレイン酸系樹脂の群から選ばれる1つ以上である請求項1から請求項3のいずれか1項に記載の選定方法The dispersant is a formalin condensate of an aromatic sulfonate, or one or more selected from the group consisting of a lignin sulfonate, an acrylic resin, a styrene-acrylic resin, and a styrene-maleic acid resin. The selection method according to any one of claims 1 to 3. 前記色材が、水不溶性または水難溶性である請求項1から請求項4のいずれか1項に記載の選定方法The selection method according to any one of claims 1 to 4, wherein the coloring material is insoluble in water or hardly soluble in water. 前記色材が、分散染料である請求項1から請求項5のいずれか1項に記載の選定方法The selection method according to claim 1, wherein the coloring material is a disperse dye. 色材、分散剤および水を含有するインクジェットインクであって、An inkjet ink containing a coloring material, a dispersant, and water,
前記分散剤が、紫外吸光度検出器を用いてGPC(Gel Permeation Chromatography)法で測定された、前記分散剤の、分子量および前記分子量と対応する紫外線吸収スペクトルにおいて、x軸;時間(分子量)、y軸;UV波長、z軸;強度(AU)で表した3次元の前記z軸真上から描いた等高線において、前記y軸値がmaxの時の分子量(UV吸収波長最大時の分子量)をBa、前記y軸値がmaxの時のUV吸収波長(UV吸収波長最大値)をBb、前記z軸値がmaxの時の分子量(UV吸収強度最大時の分子量)をAa、前記Aaと対応するUV吸収波長(UV吸収強度最大時のUV吸収波長)をAbとしたとき、式(1)、(2)を満たすインクジェットインク。The molecular weight of the dispersant measured by GPC (Gel Permeation Chromatography) using an ultraviolet absorbance detector and the ultraviolet absorption spectrum corresponding to the molecular weight of the dispersant, x-axis; time (molecular weight), y Axis: UV wavelength, z-axis: In a three-dimensional contour line drawn from directly above the z-axis expressed by the intensity (AU), the molecular weight when the y-axis value is max (the molecular weight at the maximum UV absorption wavelength) is Ba. The UV absorption wavelength when the y-axis value is max (maximum UV absorption wavelength) corresponds to Bb, and the molecular weight when the z-axis value is max (molecule weight when the UV absorption intensity is maximum) corresponds to Aa and Aa. An inkjet ink that satisfies the formulas (1) and (2) when the UV absorption wavelength (UV absorption wavelength at the maximum UV absorption intensity) is Ab.
|Bb−Ab|≧50[nm] ・・・(1)| Bb−Ab | ≧ 50 [nm] (1)
1000≦|Ba−Aa|≦30000 ・・・(2)1000 ≦ | Ba−Aa | ≦ 30000 (2)
JP2017013923A 2017-01-30 2017-01-30 Selection method Active JP6822175B2 (en)

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JP2018123181A JP2018123181A (en) 2018-08-09
JP2018123181A5 true JP2018123181A5 (en) 2020-01-09
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JP7340903B2 (en) * 2018-12-13 2023-09-08 日本化薬株式会社 Colored dispersions, inkjet printing inks, ink sets, printed hydrophobic fibers, and methods for printing hydrophobic fibers.

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JP4365060B2 (en) * 2001-12-17 2009-11-18 株式会社ニデック Plastic lens dyeing method and plastic lens dyeing ink used in the method
JP3484187B2 (en) * 2001-12-18 2004-01-06 紀和化学工業株式会社 Ink for inkjet recording
JP3573156B2 (en) * 2002-08-27 2004-10-06 紀和化学工業株式会社 Inkjet recording ink for sublimation transfer, its production method and dyeing method
JP3515779B1 (en) * 2002-08-27 2004-04-05 紀和化学工業株式会社 Inkjet recording ink for sublimation transfer and dyeing method
WO2007058209A1 (en) * 2005-11-16 2007-05-24 Kiwa Chemical Industry Co., Ltd. Disperse die, disperse die composition, ink for ink-jet printing, and staining method and stained material using the die, composition or ink
JP5473114B2 (en) * 2009-07-17 2014-04-16 日本化薬株式会社 Ink-jet ink for sublimation transfer, dyeing method and dyed product using the same
JP6123296B2 (en) * 2013-01-07 2017-05-10 セイコーエプソン株式会社 Ink for ink jet recording and recorded matter
JP2015083630A (en) * 2013-10-25 2015-04-30 セイコーエプソン株式会社 Inkjet ink composition for textile printing
JP6771570B2 (en) * 2016-08-19 2020-10-21 富士フイルム株式会社 Ink for inkjet recording, inkjet recording method, infrared reading method, and photographic paper

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