JP2017008178A - Thermal peelable adhesive tape, information display, and method for decomposing the same - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a thermal peelable adhesive tape provided with exceedingly excellent adhesive force in a temperature region of about 60°C or less, also, capable of rapidly reducing the adhesive strength by heating, and exclusively usable for the fixing between a display panel and a touch panel member of an information display.SOLUTION: Provided is a thermal peelable adhesive tape used for the pasting between the information display and touch panel member of an information display panel.SELECTED DRAWING: Figure 1

Description

  The present invention relates to a heat-peelable pressure-sensitive adhesive tape that can be used for bonding with an information display panel and a touch panel member.

  Adhesive tapes are being considered for use in various electronic device manufacturing situations, including information display devices, copiers and multifunction machines with copy functions and scan functions, for example.

  The pressure-sensitive adhesive tape is, for example, a double-sided adhesive tape in which a pressure-sensitive adhesive layer is formed on both sides of a non-woven fabric substrate, the interlayer fracture area ratio of the double-sided adhesive tape is 10% or less, and the tensile strength of the double-sided adhesive tape A double-sided adhesive tape is known in which both the MD direction (longitudinal direction) and the TD direction (lateral direction) are 20 N / 10 mm or more (see, for example, Patent Document 1).

  By the way, many of the components that make up a liquid crystal display device are relatively expensive. For example, when the bonding position of the component is wrong in the manufacturing process of the liquid crystal display device, the wrong attachment position of the component is set. In some cases, the adhesive tape is required to be able to be separated from and reused.

  The parts may be separated by, for example, inserting a cutter knife or the like into an adhesive tape. However, since the conventional adhesive tape as described above retains a high adhesive force, when trying to strongly insert and peel the cutter knife etc., there is a high possibility of damaging the surface of parts such as a liquid crystal display panel, As a result, there are cases where the parts cannot be reused.

JP 2001-152111 A

  The problem to be solved by the present invention is that it has a very excellent adhesive force in a temperature range of about 60 ° C. or less, and can be rapidly reduced by heating, and is exclusively for information display. It is providing the heat peelable adhesive tape which can be used for fixation with the display panel of an apparatus, and a touchscreen member.

  This invention solves the said subject by using a heat peelable adhesive tape for bonding of the information display part of an information display panel, and a touchscreen member.

  The heat-peelable pressure-sensitive adhesive tape of the present invention is limited to a narrow range where the pressure-sensitive adhesive tape can be affixed (applied part), so even if it is unavoidable to use a narrow-width pressure-sensitive adhesive tape, In particular, the adhesive strength of a level that can sufficiently fix two or more adherends in a temperature range of about 20 ° C to 60 ° C.

On the other hand, the heat-peelable pressure-sensitive adhesive tape of the present invention can rapidly reduce its adhesive strength by heating to approximately 120 ° C., and as a result, can easily separate two or more adherends that have been adhered. Is provided.
Further, the disassembling method of the present invention can heat the heat-peelable adhesive tape or the area where the adhesive tape is affixed, while preventing failure or deformation of the parts existing in the area where the adhesive tape is not affixed. Can be prevented.

It is a conceptual diagram which shows the measuring method of surface adhesive strength. It is the conceptual diagram which looked at the test piece used with the evaluation method of thermal decomposability from the upper surface. It is the conceptual diagram seen from the side surface of the test piece used for the evaluation method of thermal decomposability.

  The heat-peelable pressure-sensitive adhesive tape of the present invention is exclusively used for bonding an information display part of an information display panel and a touch panel member.

  Here, the heat releasability has a strong adhesive force in a room temperature environment of about 60 ° C. or less, and can firmly adhere the information display panel as the adherend and the touch panel member, When heated to about 120 ° C., the adhesive strength is remarkably lowered, and the information display panel and the touch panel member can be easily separated.

  As the heat-peelable pressure-sensitive adhesive tape of the present invention, a so-called substrate-less pressure-sensitive adhesive tape constituted by a single layer or a laminated pressure-sensitive adhesive layer, the above-mentioned pressure-sensitive adhesive directly or via another layer on one or both sides of a substrate. What has an agent layer can be used. As the heat-peelable pressure-sensitive adhesive tape, it is preferable to use a heat-peelable pressure-sensitive adhesive tape having the pressure-sensitive adhesive layer on both sides of the substrate directly or via another layer.

As the pressure-sensitive adhesive layer constituting the heat-peelable pressure-sensitive adhesive tape of the present invention, any pressure-sensitive adhesive layer can be used, for example, a pressure-sensitive adhesive containing an acrylic block copolymer, or It is preferable for obtaining a heat-peelable pressure-sensitive adhesive tape having good heat-peelability to be a pressure-sensitive adhesive layer (A) formed using a pressure-sensitive adhesive containing a rubber-based block copolymer (a). It is more preferable to use the pressure-sensitive adhesive layer (A) obtained using a rubber-based pressure-sensitive adhesive.
The rubber-based pressure-sensitive adhesive contains, for example, a rubber-based block copolymer (a), a pressure-sensitive adhesive component that can be used as necessary, and other additives that can be used as necessary. Things can be used.

As the adhesive component contained in the pressure-sensitive adhesive layer, the storage elastic modulus _{G 120} at 120 ° C. at a frequency 1Hz uses what is ^{1.0 × 10 3 ~2.0 × 10 5} Pa. By using a heat-peelable pressure-sensitive adhesive tape having a pressure-sensitive adhesive layer (A) containing a pressure-sensitive adhesive component having a storage elastic modulus G ₁₂₀ in the above range, a very excellent adhesive force is exhibited in a temperature range of 60 ° C. or lower. On the other hand, when heated to about 120 ° C., the adhesive strength is significantly reduced, and the information display panel and the touch panel member can be easily separated.
Moreover, if it is a heat-peelable pressure-sensitive adhesive tape having a storage elastic modulus in the above-mentioned range, when it is heated, the adhesive strength is remarkably reduced by heating for a short time by using a halogen lamp described later. As a result, the bonded information display panel and touch panel member can be more easily separated. In addition, the said adhesion component refers to the binder which is a rubber-type block copolymer or an acryl-type block copolymer, and tackifying resin, for example, if it is an adhesive layer (A).

As the adhesive component, it is more preferable to use one having a storage elastic modulus G ₁₂₀ of 1.0 × 10 ³ Pa or more and 1.8 × 10 ⁵ Pa or less, and 5.0 × 10 ³ Pa or more and 1. Use of a material having a pressure of 6 × 10 ⁵ Pa or less can exhibit a very good adhesive force in a temperature range of 60 ° C. or lower, while remarkably lowering the adhesive force when heated to about 120 ° C. The information display panel and the touch panel member can be easily separated.
Moreover, if it is a heat-peelable pressure-sensitive adhesive tape having a storage elastic modulus in the above-mentioned range, when it is heated, the adhesive strength is remarkably reduced by heating for a short time by using a halogen lamp described later. As a result, the bonded information display panel and touch panel member can be more easily separated.

As the adhesive component contained in the adhesive layer, it is preferable to use one having a storage elastic modulus G ′ at a frequency of 1 Hz at 23 ° C. of 1.0 × 10 ⁴ Pa or more, and 5.0 × 10 ⁴ Pa or more. It is more preferable to use one having a viscosity of 0.0 × 10 ⁶ Pa or less, and it is preferable to use one having a viscosity of 8.0 × 10 ⁵ or more and 1.5 × 10 ⁶ Pa or less to which the heat-peelable adhesive tape is applied. Even if it is a member limited to a very narrow area (applying part) and a narrow adhesive tape is unavoidable, it provides an adhesive force that can sufficiently fix the member. It is more preferable because it can be used.

As the adhesive component contained in the pressure-sensitive adhesive layer, the ratio of storage modulus _{G 23} as measured by dynamic viscoelasticity spectrum at 1Hz and 23 ° C. for the storage elastic modulus _{G 120 [G} 23 _{/ G 120]} Is 1-20. By using a heat-peelable pressure-sensitive adhesive tape having a pressure-sensitive adhesive layer containing a pressure-sensitive adhesive component in the above-mentioned range [G ₂₃ / G ₁₂₀ ], a very excellent adhesive force can be expressed in a temperature range of 60 ° C. or lower. On the other hand, when heated to about 120 ° C., the adhesive strength is remarkably reduced, and the information display panel and the touch panel member can be easily separated.
In addition, if the heat-peelable pressure-sensitive adhesive tape has a storage elastic modulus ratio in the above range, when it is heated, it is heated for a short time by using a halogen lamp, which will be described later. As a result, the bonded information display panel and touch panel member can be more easily separated.

The ratio [G ₂₃ / G ₁₂₀ ] is preferably in the range of 1-20, more preferably in the range of 1-18, and in the range of 1-15, the temperature range of 60 ° C. or less. While the adhesive strength can be exhibited below, the adhesive strength is remarkably lowered when heated to about 120 ° C., and the information display panel and the touch panel member can be easily separated.
In addition, if the heat-peelable pressure-sensitive adhesive tape has a ratio in the above range, when it is heated, by using a halogen lamp, which will be described later, its adhesive strength can be significantly reduced by being heated for a short time. As a result, the bonded information display panel and touch panel member can be more easily separated.

Further, as the pressure-sensitive adhesive layer, for example, it is easy to separate the information display panel and the touch panel member by using a material that is softened or melted by being heated using a heat source such as a laser light irradiation device or a halogen lamp. Is preferable.
The pressure-sensitive adhesive layer is preferably one that can be rapidly softened or melted when heated to a temperature exceeding the glass transition temperature of the rubber-based block copolymer (a).

  As described later, the pressure-sensitive adhesive layer can significantly reduce the adhesive strength at a relatively low temperature even when heated using a halogen lamp, and can cause separation of the information display panel and the touch panel member. . Therefore, when separating the information display panel and the touch panel member, it is difficult to cause deformation, discoloration, failure, or the like of the information display panel and the touch panel member due to the influence of heat. Specifically, the pressure-sensitive adhesive layer is preferably heated to a range of 80 ° C. to 130 ° C. and more preferably 80 ° C. to 125 ° C. when the information display panel and the touch panel member are separated. Preferably, it is more preferably heated to 90 ° C to 120 ° C. The heating is preferably performed for 3 seconds to 20 seconds, and more preferably performed for a relatively short time of 3 seconds to 15 seconds.

  In addition, the halogen lamp is normally heated to the suitable temperature range (for example, 80 ° C. to 130 ° C.) immediately after the power is turned on, and can quickly heat the object with the radiant heat. . Since the pressure-sensitive adhesive layer is easily softened or melted rapidly in the preferred temperature range, the adhesive strength is remarkably lowered when heated for a short time using a halogen lamp, and the information display panel and the touch panel member are separated. Easy to make.

  As the pressure-sensitive adhesive layer, a pressure-sensitive adhesive component composed of a binder such as the above-described rubber-based block copolymer (a) or acrylic block copolymer, and a tackifying resin that can be used as necessary, and necessary Depending on the layer, layers containing other additives can be used.

  Examples of the rubber block copolymer (a) include so-called ABA type block copolymers (triblock copolymers), AB type block copolymers (diblock copolymers), and mixtures thereof. Can be used.

  As the rubber-based block copolymer (a), it is possible to use a mixture of the triblock copolymer and the diblock copolymer, the storage elastic modulus at 23 ° C. and the storage elastic modulus at 120 ° C., It has a value obtained by dividing the storage elastic modulus at 23 ° C. by the storage elastic modulus measured at 120 ° C., and as a result, can exhibit a very high adhesive force in a normal temperature region of about 23 ° C., and It is preferable for obtaining a pressure-sensitive adhesive tape capable of reducing the adhesive force to such an extent that the information display panel and the touch panel member can be easily separated by being heated to 120 ° C., and the diblock copolymer is preferably used for the rubber-based block copolymer. It is more preferable to use what is contained in the range of 10% by mass to 90% by mass with respect to the entire polymer (a), and use in the range of 15% by mass to 80% by mass. But more preferably, it is particularly preferred to use a range of 20 wt% to 75 wt%.

  As the heat-peelable pressure-sensitive adhesive tape of the present invention, it is preferable to use one having a peeling distance of 20 mm or less in a constant load holding force test measured at 23 ° C., and using one having a thickness of 10 mm or less. Even when a certain external adaptation force is applied to the heat-peelable pressure-sensitive adhesive tape, it is preferable because it does not easily cause peeling.

  As the rubber block copolymer (a), a styrene block copolymer is preferably used. The styrenic block copolymer refers to a triblock copolymer, a diblock copolymer, or a mixture thereof having a polystyrene unit (a1) and a polyolefin unit.

  The polystyrene unit (a1) increases the elastic modulus of the pressure-sensitive adhesive layer, and can exhibit a very excellent adhesive force in a temperature range of 60 ° C. or lower, and significantly reduces the adhesive force when heated for a short time. This contributes to the characteristics that can be achieved.

  Examples of the styrenic block copolymer include polystyrene-poly (isopropylene) block copolymer, polystyrene-poly (isopropylene) block-polystyrene copolymer, polystyrene-poly (butadiene) block copolymer, polystyrene. -Poly (butadiene) block-polystyrene copolymer, polystyrene-poly (butadiene / butylene) block copolymer, polystyrene-poly (butadiene / butylene) block-polystyrene copolymer, polystyrene-poly (ethylene / propylene) block copolymer Polymer, polystyrene-poly (ethylene / propylene) block-polystyrene copolymer, polystyrene-poly (ethylene / butylene) block copolymer, polystyrene-poly (ethylene / butylene) block-polis Ren copolymer, polystyrene - poly (ethylene - ethylene / propylene) block copolymer, polystyrene - poly (ethylene - ethylene / propylene) block - can be used polystyrene copolymer. Among these, as the styrenic block copolymer, it is preferable to use a block copolymer having a polystyrene unit (a1) and a polyisoprene unit (a2), and a polystyrene-poly (isopropylene) block copolymer. The use of coalescence, polystyrene-poly (butadiene) block copolymer, polystyrene-poly (butadiene) block-polystyrene copolymer can exhibit very good adhesive force under a temperature range of 60 ° C. or lower. Further, it is more preferable to obtain a heat-peelable pressure-sensitive adhesive tape capable of remarkably reducing the adhesive strength when heated and separating the information display panel and the touch panel member.

  As the rubber-based block copolymer (a), a rubber having a weight average molecular weight in the range of 10,000 to 800,000 is used in order to further improve the excellent adhesive force and the disassembling property by heating. It is more preferable to use those having a weight average molecular weight in the range of 50,000 to 500,000, and it is more preferable to use those having a weight average molecular weight in the range of 150,000 to 450,000.

Moreover, as an acryl-type block copolymer which can be used for formation of the said adhesive layer, the block copolymer obtained by copolymerizing 2 or more types of the (meth) acryl monomer mentioned later, for example is used. So-called A-B block copolymers and A-B-A block copolymers can be used.
Examples of the (meth) acrylic monomer include acrylic acid, methacrylic acid, methyl acrylate, ethyl acrylate, propyl acrylate, n-butyl acrylate, isobutyl acrylate, hexyl acrylate, 2-ethylhexyl acrylate, acrylic Primary alcohols such as dodecyl acrylate, lauryl acrylate, methoxyethyl acrylate, dimethylaminoethyl acrylate, diethylaminoethyl acrylate, glycidyl acrylate, trimethoxysilylpropyl acrylate, trifluoromethyl acrylate, trifluoroethyl acrylate, etc. Esterified product of acrylic acid with isopropyl acrylate, cyclohexyl acrylate, isobornyl acrylate, etc .; esterified product of secondary alcohol with acrylic acid; tertiary such as tert-butyl acrylate It may be used ester of alcohol and acrylic acid.

  As the acrylic block copolymer, it is preferable to use a polymer having a weight average molecular weight in the range of 10,000 to 800,000 in order to further improve the excellent adhesive force and the dismantling property by heating, It is more preferable to use those having a weight average molecular weight in the range of 30,000 to 500,000, and it is more preferable to use those having a weight average molecular weight in the range of 50,000 to 450,000.

  As the pressure-sensitive adhesive layer, in addition to the rubber-based block copolymer (a) and the like, it is preferable to use a material containing a tackifying resin or the like as the pressure-sensitive adhesive component.

  Examples of the tackifying resin include a rosin tackifying resin, a polymerized rosin tackifying resin, a polymerized rosin ester tackifying resin, a rosin phenol tackifying resin, a hydrogenated rosin ester tackifying resin, and a disproportionated rosin ester. System-based tackifier resins, terpene-based tackifier resins, terpene-phenol-based tackifier resins, aliphatic (petroleum resin) -based tackifier resins, and C5-based petroleum-based tackifier resins can be used.

  Among these, as the tackifier resin, it is preferable to use a C5 petroleum-based tackifier resin or a terpene phenol-based tackifier resin in order to improve the wettability to the adherend surface. In particular, terpene phenol-based tackifying resins can impart moderate flexibility to the pressure-sensitive adhesive layer, can impart very high adhesive force in the temperature range of about 20 ° C to 60 ° C, and have a certain repulsive force on the tape. It is particularly preferable to use it for obtaining a thermally decomposable pressure-sensitive adhesive tape that can prevent peeling over time when added.

  As the C5 tackifying resin, a resin obtained by polymerizing the residue obtained by extracting and separating isoprene and cyclopentadiene from a C5 fraction generally obtained by decomposition of naphtha can be used.

  As the terpene phenol-based tackifier resin, a resin obtained by copolymerizing a terpene monomer and phenol can be used. As the terpene phenol-based tackifying resin, use of a resin having a softening point in the range of 105 ° C. to 145 ° C. improves compatibility with the rubber-based block copolymer (a), and as a result, 60 ° C. Obtaining a heat-peelable pressure-sensitive adhesive tape that can provide very high adhesive force under the following temperature range and has anti-peeling property that can prevent peeling over time when a certain repulsive force is applied to the tape In addition, it is preferable.

  The tackifier resin is preferably used in a range of 10 parts by mass to 150 parts by mass with respect to a total of 100 parts by mass of the rubber block copolymer (a) and the acrylic block copolymer, and 15 parts by mass. It is more preferable to use in the range of -100 mass parts.

  In particular, the terpene phenol-based tackifying resin is preferably used in a range of 50 to 100 parts by mass with respect to 100 parts by mass in total of the rubber-based block copolymer (a) and the acrylic block copolymer. When used in the range of 65 parts by weight to 80 parts by weight, it can give a very high adhesive force in a temperature range of 60 ° C. or less, and peels with time when a certain repulsive force is applied to the tape. It is preferable for obtaining a heat-peelable pressure-sensitive adhesive tape having anti-peeling property capable of preventing the above. Moreover, it is preferable to use the said C5 type tackifying resin in the range of 10 mass parts-100 mass parts with respect to a total of 100 mass parts of the said rubber-type block copolymer (a) and an acryl-type block copolymer. More preferably, it is used in the range of 20 to 50 parts by mass, and more preferably in the range of 25 to 50 parts by mass.

  Further, as the tackifying resin, in addition to those described above, a tackifying resin that is liquid at room temperature can also be used. Examples of the liquid tackifying resin include low molecular weight liquid rubbers such as process oil, polyester-based tackifying resin, and polybutene.

  As the adhesive layer, in addition to the adhesive component, an infrared absorber, an antioxidant, an ultraviolet absorber, a filler, a fiber made of glass or plastic, a thermally expandable balloon, a bead, a metal, if necessary. What contains fillers, such as powder, a pigment, a thickener, etc. can be used.

  In particular, the infrared absorbing agent can improve the rate at which the heat-peelable pressure-sensitive adhesive tape is heated when heating the heat-peelable pressure-sensitive adhesive tape of the present invention, and lowers the adhesive force in a shorter heating time. It is preferable to use the information display panel and the touch panel member because they can be separated.

  As the infrared absorber, known ones such as inorganic pigments such as carbon black and composite oxide pigments; organic pigments such as phthalocyanine pigments, lake pigments, polycyclic pigments, and various dyes can be appropriately used.

  It is preferable that the infrared absorber is included in a range of 0.01% by mass to 20% by mass with respect to the total amount of the pressure-sensitive adhesive layer.

  In addition, the thermally expandable balloon heats the heat-peelable pressure-sensitive adhesive tape of the present invention, and when separating the information display panel and the touch panel member, in order to make it possible to separate them with a weaker force, It can be preferably used.

  Examples of the thermally expandable balloon include “Matsumoto Microsphere” (trade name, manufactured by Matsumoto Yushi Seiyaku Co., Ltd.), “Microsphere Expandel” (trade name, manufactured by Nippon Philite Co., Ltd.), “Dai” Commercial products such as “form” (trade name, manufactured by Dainichi Seika Kogyo Co., Ltd.) can be used.

  The heat-expandable balloon is a heat-peelable pressure-sensitive adhesive tape capable of separating the information display panel and the touch panel member with a weaker force by heating while maintaining an excellent adhesive force in a temperature range of 60 ° C. or lower. When obtaining, it is preferable to use in the range of 3 mass%-50 mass% with respect to the mass of the said adhesive component contained in the said adhesive layer, and it is more preferable to use in the range of 5 mass%-30 mass%. It is particularly preferable to use in the range of 10% by mass to 20% by mass.

  As the heat-peelable pressure-sensitive adhesive tape, for example, it is preferable to use one having a thickness of the pressure-sensitive adhesive layer (A) provided on one side of the substrate of 25 μm or more, and one having a thickness of 60 μm to 120 μm. It is more preferable to use a material having a thickness of 80 μm to 120 μm, which is excellent in cohesive force and can exhibit a very excellent adhesive force in a temperature range of 60 ° C. or lower, and can be bonded when heated. It is further preferable for obtaining a heat-peelable pressure-sensitive adhesive tape capable of significantly reducing the force and separating the information display panel and the touch panel member.

  As the heat-peelable pressure-sensitive adhesive tape, for example, it is preferable to use a tape having a total thickness of 50 μm or more of the pressure-sensitive adhesive layer (A) provided on both sides of the substrate, and a range of 50 μm to 300 μm. It is more preferable that it is in the range of 100 μm to 250 μm, and that it is in the range of 100 μm to 210 μm is excellent in cohesive force, and exhibits excellent adhesive strength in a temperature range of 60 ° C. or lower. It is more preferable to obtain a heat-peelable pressure-sensitive adhesive tape capable of separating the information display panel and the touch panel member with a weaker force by heating.

  As the heat-peelable pressure-sensitive adhesive tape of the present invention, as described above, one having the pressure-sensitive adhesive layer directly or via another layer on one side or both sides of the substrate can be used.

  As said base material, a nonwoven fabric base material, a resin film base material, etc. can be used, for example. Especially, as said base material, it is preferable to use the base material (infrared absorptive base material) which is excellent in the absorptivity of infrared rays.

  Examples of the infrared absorbing substrate include a resin film substrate containing an infrared absorbing inorganic filler, an organic dye, an inorganic dye, a dye, and a pigment, and a substrate provided with an infrared absorbing layer on a resin film.

  In particular, as the infrared absorbing base material, the use of a black base material gives a suitable endothermic property or heat storage property to the adhesive tape, and is a case where it is heated using a relatively simple halogen lamp. However, since the temperature of the adhesive tape can be raised in a short time to such an extent that separation of the information display panel and the touch panel member occurs, the irradiation time can be shortened. This is preferable because the work efficiency of the step of separating the information display panel and the touch panel member can be significantly improved.

  On the other hand, when the heat-peelable adhesive tape obtained using the black base material is irradiated by using a local heating device such as a semiconductor laser, the output of the black base material is only the base material unless the output is strictly controlled. May be heated and the two or more adherends cannot be sufficiently separated, or only the base material may be heated to cause deformation and the like. Thus, the heat-peelable pressure-sensitive adhesive tape obtained using the black base material is preferably used in combination with a heating method using a halogen lamp.

  The black base material is not particularly limited as long as it is black. For example, a black base layer printed on a resin base material, a resin and black pigment kneaded into a film, a non-woven base material And the like in which black pigment is dispersed.

  The substrate preferably has a thickness of 4 μm to 100 μm, and preferably has a thickness of 10 μm to 75 μm. It is more preferable for imparting excellent followability to.

  A polyethylene terephthalate substrate or the like can be used as the resin film substrate. In addition, as the resin film substrate, one that has been subjected to corona treatment or anchor coat treatment can be used for improving the anchoring property of the pressure-sensitive adhesive layer.

  The heat-peelable pressure-sensitive adhesive tape of the present invention, for example, applies and drys the pressure-sensitive adhesive containing the rubber-based block copolymer (a) or the like on one side or both sides of the base material using a roll coater or a die coater. It can be manufactured by forming a pressure-sensitive adhesive layer.

  The heat-peelable pressure-sensitive adhesive tape is prepared by previously applying a pressure-sensitive adhesive containing the rubber-based block copolymer (a) or the like to the surface of the release liner using a roll coater or the like and drying it. An adhesive layer can be formed, and then the adhesive layer can be produced by a transfer method in which the adhesive layer is bonded to one or both sides of the substrate.

  The heat-peelable pressure-sensitive adhesive tape of the present invention exhibits a very excellent adhesive force, for example, in a temperature range of 60 ° C. or lower. Therefore, the heat-peelable pressure-sensitive adhesive tape can be suitably used for bonding various adherends.

  The pressure-sensitive adhesive tape preferably has an adhesive strength of about 15 N / 20 mm to 40 N / 20 mm, for example, at a normal temperature (23 ° C.) environment, by peeling off 180 ° from the stainless steel plate. It is more preferable to have an adhesive strength of about 40 N / 20 mm in order to firmly adhere the adherend and prevent peeling over time.

Since the heat-peelable pressure-sensitive adhesive tape of the present invention has a very excellent adhesive force in a temperature range of 60 ° C. or lower, it can be used exclusively for fixing the information display panel and the touch panel member.
In some cases, the adhesive tape is usually required to be thermally peelable from the viewpoint of re-sticking or promoting recycling. However, in applications where it is desired to prevent peeling due to the influence of heat, a tape having excellent heat resistance tends to be used even if the recyclability is sacrificed. For example, an adhesive tape that hardly causes peeling due to the influence of heat is often used for bonding between a liquid crystal display panel and a touch panel member. The present invention has been found that a heat-peelable pressure-sensitive adhesive tape that would be unthinkable even by those skilled in the art can be used in the bonding situation between a liquid crystal display panel and a touch panel member that require heat resistance as described above. .

As a method of manufacturing an information display device by bonding the information display panel and the touch panel member using the heat-peelable pressure-sensitive adhesive tape, for example, on the information display unit surface of the information display panel or the surface of the touch panel member, Manufactured by applying one adhesive layer (A) constituting the heat-peelable adhesive tape, then applying the other adherend to the surface of the other adhesive layer, and pressing them as necessary can do.
At that time, the heat-peelable adhesive tape is preferably cut into a shape corresponding to the outer shape of the information display unit and the touch panel member of the information display panel. For example, the information display unit and the touch panel member have a square shape. If it is, it is preferable that it is a square window frame shape corresponding to it.
As the heat-peelable pressure-sensitive adhesive tape, one having a window frame shape with a width of 3 mm or less is preferably used, and one having a window frame shape with a width of 1 mm or less is more preferably used.

Examples of the information display panel include those provided with an information display unit for displaying images, videos, character information, and the like, such as a liquid crystal display panel and an organic EL display panel.
As the liquid crystal display panel, it is preferable to use a liquid crystal display panel in which the surface to which the touch panel member is attached (the outermost surface of the information display unit) is composed of an optical film, and the surface is composed of a polarizing plate. It is preferable to use it.
The liquid crystal display panel may be bonded to a member having a backlight in advance.
Moreover, as said touch panel member, the member which has the structure which consists of what is called an ITO film is mentioned, for example. Specifically, examples of the touch panel member include a laminate of a film uniaxially stretched as necessary and the ITO film.
The touch panel member preferably has a total thickness of about 0.1 mm to 0.5 mm.

On the other hand, as a method of dismantling the information display device, for example, the heat-peelable adhesive tape constituting the information display device, or the information display panel or touch panel member is irradiated with a laser beam, or a halogen lamp is approached or There is a method in which the information display panel and the touch panel member are separated by contacting them and heating the heat-peelable pressure-sensitive adhesive tape directly or indirectly.
For the heating, it is preferable to use a halogen lamp, and the use of a portable halogen heater makes it possible to heat the tape easily and in a short time even when the information display device is disassembled and the work efficiency is small. To preferred.

  During the heating, a halogen lamp may be approached or brought into contact with the heat-peelable adhesive tape, and the heat-peelable adhesive tape is indirectly brought into contact with or brought into contact with the information display panel or the touch panel member. You may heat. For example, when an end portion of the heat-peelable pressure-sensitive adhesive tape protrudes outside an end portion of the information display panel or the touch panel member, a halogen lamp may approach or contact the end portion of the heat-peelable pressure-sensitive adhesive tape. Good.

  In the heating step, using a heating device equipped with a halogen lamp, it is preferable to heat the pressure-sensitive adhesive tape to a temperature of 80 ° C to 130 ° C, more preferably to 85 ° C to 125 ° C, More preferably, heating is performed until the temperature reaches 90 ° C to 120 ° C. The heating is preferably within 20 seconds, more preferably within 15 seconds, and further preferably within a relatively short period of time within 10 seconds.

  Specifically, the heating step using the halogen lamp is a step of setting the temperature of the pressure-sensitive adhesive tape to 100 ° C. within 20 seconds, so that the disassembly efficiency of the article can be improved and the heat of the adherend This is preferable because deformation can be prevented.

  In addition, as a heating device equipped with a halogen lamp, for example, a “parallel light type halogen lamp heater” capable of heating a certain area in a short time, a condensing halogen type lamp capable of local heating, or the like may be used. In addition, the use of a parallel light type halogen lamp heater can heat a wide range at a time, so that the heating time can be shortened to the time described above.

Area heatable in the parallel light type halogen lamp heater ^once, preferably a 10cm ² ~500cm 2 about. Moreover, it is preferable that the heating device such as a parallel light type halogen lamp heater has a portable size and weight in order to improve the efficiency of the work for disassembling the article. The weight is preferably 3 kg or less, preferably 2 kg or less, and more preferably 0.1 kg to 1 kg.

  The information display device heated by the method can be easily disassembled by applying little or no force to the information display panel and the touch panel member constituting the information display device. Moreover, since there is almost no adhesive residue derived from the heat-peelable adhesive tape on the surface of the information display panel and the touch panel member, the information display panel and the touch panel member can be used for recycling and the like.

  Moreover, as the said disassembly method, the method of heating the said heat | fever peelable adhesive tape by irradiating a hot air, an active energy ray, or a laser beam, for example instead of using the said halogen lamp is mentioned.

  Examples of the active energy rays include ultraviolet rays, infrared rays, visible rays, α rays, β rays, gamma rays, and the like, and commercially available ultraviolet irradiation devices and the like can be used. Examples of the laser beam include those that can be irradiated by a commercially available laser irradiation apparatus. By irradiating the tape with the hot air, active energy ray or laser beam, the pressure-sensitive adhesive layer (A) constituting the pressure-sensitive adhesive tape is heated and softened to easily separate the information display panel and the touch panel member. can do.

  Examples will be described in detail below.

Example 1
Styrene-butadiene block copolymer S having a weight average molecular weight of 300,000 (a mixture of a triblock copolymer and a diblock copolymer. The ratio of the diblock copolymer to the total amount of the mixture is 20% by mass. The mass proportion of polystyrene units in the whole styrene-butadiene block copolymer is 20 mass%, the mass proportion of polybutadiene units is 80 mass%) 100 mass parts, C5 petroleum-based tackifying resin (softening point 100 ° C, number average molecular weight) 885) An adhesive (a-1) was obtained by dissolving 40 parts by mass in toluene.

The pressure-sensitive adhesive (a-1) was applied to the surface of the release liner using an applicator so that the thickness after drying was 100 μm, and dried at 85 ° C. for 5 minutes to form a pressure-sensitive adhesive layer. . The pressure-sensitive adhesive layer is bonded to both surfaces of a base material provided with a black ink layer having a thickness of 4 μm on both sides of a polyethylene terephthalate film having a thickness of 38 μm, and then pressure-bonded with 4 kgf / cm ² to laminate. 1 was produced.

  The adhesive tape 1 was cut into a window frame shape having a side length of 50 mm and a width of 1 mm. An adherend was prepared by sticking the cut adhesive tape to both ends of a long side of a glass touch panel having a length of 50 mm, a width of 50 mm, and a thickness of 0.4 mm.

Next, the surface on the adhesive tape side of the adherend is affixed to approximately the center of a liquid crystal display module unit having a length of 60 mm, a width of 60 mm, and a thickness of 2 mm, and 10 seconds at 50 N / cm ² using a press machine. After the pressurization, the pressurized state was released, and the article 1 was produced by allowing to stand in an environment of 85 ° C. for 24 hours.

Three articles 1 obtained in Example 1 were prepared, and a parallel light type halogen lamp heater (made by Heat Tech Co., Ltd., two halogen lamp tubes having a length of 10 cm was mounted in a 23 ° C. environment, and light generated from the halogen lamp. Wavelength: near infrared region 2 μm, rated voltage 100 V, rated power consumption 850 W, portable type, weight 0.7 kg, collective irradiation area about 200 cm ² ) to the distance from the glass plate constituting the article to 10 mm did.

  Next, the three articles 1 were heated using the heater for 5 seconds, 10 seconds, and 15 seconds, respectively. The temperature of the adhesive tape when heated for 5 seconds is about 90 ° C., the temperature of the adhesive tape when heated for 10 seconds is about 105 ° C., and the temperature of the adhesive tape when heated for 15 seconds is about It was 120 ° C.

  After the heating, each article 1 was left at 23 ° C. for 5 seconds, and a force was applied with a finger in the shearing direction of the glass plate to separate the glass plate constituting the article 1 from the article.

(Example 2)
Instead of the polyethylene terephthalate film having the black ink layer used in Example 1, 600 parts by weight of Foret GS-1000 (manufactured by Soken Chemical Co., Ltd., polymethyl methacrylate, 30% by mass solution), infrared absorbing dye CIR-RL (Nippon Carlit Co., Ltd., diimonium salt compound) A coating solution containing 6.4 parts by mass, 400 parts by mass of methyl ethyl ketone and 400 parts by mass of toluene is applied to a polyethylene terephthalate film having a thickness of 38 μm and a thickness after drying to 4 μm. A pressure-sensitive adhesive tape 2 and an article 2 were produced in the same manner as in Example 1 except that a substrate having an infrared absorption layer obtained by coating and drying was used.
Heating and peeling were performed in the same manner as in Example 1 except that the article 2 was used instead of the article 1.

(Example 3)
A method similar to Example 1 except that a 38 μm thick polyethylene terephthalate film (PET film) having no black ink layer was used instead of the polyethylene terephthalate film having a black ink layer used in Example 1. Thus, an adhesive tape 3 and an article 3 were prepared.
Heating and peeling were performed in the same manner as in Example 1 except that the article 3 was used instead of the article 1.

Example 4
Instead of the pressure-sensitive adhesive (a-1), the pressure-sensitive adhesive (a-1) was mixed with 0.5 parts by mass of “carbon black” (infrared absorber) manufactured by Evonik Degussa Japan which is not a pressure-sensitive adhesive component. An adhesive tape 4 and an article 4 were produced in the same manner as in Production Example 3 except that the adhesive (a-2) was used.
Heating and peeling were performed in the same manner as in Example 1 except that the article 4 was used instead of the article 1.

(Example 5)
Instead of the styrene-butadiene block copolymer S, a styrene-butadiene block copolymer T having a weight average molecular weight of 300,000 (a mixture of a triblock copolymer and a diblock copolymer. The diblock relative to the total amount of the mixture). The proportion of the copolymer is 20% by mass, the proportion of polystyrene units in the total styrene-butadiene block copolymer is 15% by mass, and the proportion of polybutadiene units is 85% by mass). A pressure-sensitive adhesive tape 5 and an article 5 were produced in the same manner as in Example 3.
Heating and peeling were performed in the same manner as in Example 1 except that the article 5 was used instead of the article 1.

(Example 6)
In place of the styrene-butadiene block copolymer S, a styrene-butadiene block copolymer U having a weight average molecular weight of 320,000 (a mixture of a triblock copolymer and a diblock copolymer. The diblock relative to the total amount of the mixture). The copolymer accounted for 30% by mass, with the exception of using 20% by mass of polystyrene units and 80% by mass of polybutadiene units in the styrene-butadiene block copolymer. An adhesive tape 6 and an article 6 were produced in the same manner as in Example 3.
Heating and peeling were performed in the same manner as in Example 1 except that the article 6 was used instead of the article 1.

(Example 7)
Instead of the styrene-butadiene block copolymer S, a styrene-butadiene block copolymer V having a weight average molecular weight of 400,000 (a mixture of a triblock copolymer and a diblock copolymer. The diblock relative to the total amount of the mixture). The copolymer accounted for 15% by mass, except that 10% by mass of polystyrene units and 90% by mass of polybutadiene units were used in the styrene-butadiene block copolymer. A pressure-sensitive adhesive tape 7 and an article 7 were produced in the same manner as in Example 3.
Heating and peeling were performed in the same manner as in Example 1 except that the article 7 was used instead of the article 1.

(Example 8)
An adhesive tape 8 and an article 8 are produced in the same manner as in Example 3 except that the amount of C5 petroleum-based tackifying resin (softening point 100 ° C., number average molecular weight 885) used is changed from 40 parts by mass to 20 parts by mass. did.
Heating and peeling were performed in the same manner as in Example 1 except that the article 8 was used instead of the article 1.

Example 9
Instead of the styrene-butadiene block copolymer S, a styrene-butadiene block copolymer X having a weight average molecular weight of 300,000 (a mixture of a triblock copolymer and a diblock copolymer. The diblock relative to the total amount of the mixture). The proportion of the copolymer is 50% by mass, the mass proportion of polystyrene units in the total of the styrene-butadiene block copolymer is 30% by mass, and the mass proportion of polybutadiene units is 70% by mass. A pressure-sensitive adhesive tape 9 and an article 9 were produced in the same manner as in Example 1 except that 65 parts by mass of a terpene phenol-based tackifying resin (softening point 115 ° C., molecular weight 1000) was used instead of the C5 petroleum-based tackifying resin. .
Heating and peeling were performed in the same manner as in Example 1 except that the article 9 was used instead of the article 1.

(Example 10)
The adhesive tape 10 was prepared in the same manner as in Example 9 except that a 25 μm thick polyethylene terephthalate film kneaded with black pigment was used instead of the polyethylene terephthalate film having the black ink layer used in Production Example 9. And the article 10 was produced.
Heating and peeling were performed in the same manner as in Example 1 except that the article 10 was used instead of the article 1.

(Example 11)
Adhesive tape in the same manner as in Example Preparation Example 9 except that the amount of the terpene phenol-based tackifying resin (softening point 115 ° C., molecular weight 1000) used in Preparation Example 9 was changed from 65 parts by mass to 75 parts by mass. 11 and article 11 were produced.
Heating and peeling were performed in the same manner as in Example 1 except that the article 11 was used instead of the article 1.

(Example 12)
Instead of the adhesive used in Example 9, the adhesive used in Example 9 and Matsumoto Microsphere F-48 which is not an adhesive component (manufactured by Matsumoto Yushi Seiyaku Co., Ltd., the coefficient of thermal expansion at 120 ° C. is 370%. Example 9 except that an adhesive obtained by mixing an expansion start temperature of 90 ° C. to 100 ° C., a maximum expansion temperature of 125 ° C. to 135 ° C., and an average particle size (before expansion) of 9 μm to 15 μm) was used. A pressure-sensitive adhesive tape 12 and an article 12 were produced in the same manner. The Matsumoto Microsphere F-48 was used in an amount of 15 parts by mass with respect to the adhesive component (the total of the styrene-butadiene block copolymer W and the terpene phenol tackifying resin).
Heating and peeling were performed in the same manner as in Example 1 except that the article 12 was used instead of the article 1.

(Example 13)
Parallel type halogen lamp heater used in Example 1 (Heat Tech, 2 halogen lamp tubes with a length of 10 cm, wavelength of light generated from halogen lamp: near infrared region 2 μm, rated voltage 100 V, rated power consumption Instead of 850 W, portable, weight 0.7 kg, collective irradiation area about 200 cm ² ), scan with semiconductor laser (output 4 W, wavelength 940 nm, weight 250 kg, collective irradiation area about 0.1 cm ² (local heating)) The article 1 was heated and peeled in the same manner as in Example 1 except that it was used at a speed of 500 mm / min.

(Example 14)
Parallel type halogen lamp heater used in Example 9 (Heattech Co., Ltd., equipped with two 10 cm long halogen lamp tubes, wavelength of light generated from halogen lamp: near infrared region 2 μm, rated voltage 100 V, rated power consumption Instead of 850 W, portable, weight 0.7 kg, collective irradiation area about 200 cm ² ), scan with semiconductor laser (output 4 W, wavelength 940 nm, weight 250 kg, collective irradiation area about 0.1 cm ² (local heating)) The article 9 was heated and peeled off in the same manner as in Example 9 except that it was used at a speed of 500 mm / min.

(Example 15)
Parallel type halogen lamp heater used in Example 1 (Heat Tech, 2 halogen lamp tubes with a length of 10 cm, wavelength of light generated from halogen lamp: near infrared region 2 μm, rated voltage 100 V, rated power consumption 850 W, portable type, weight 0.7 kg, collective irradiation possible area about 200 cm ² ), except that a dryer set at 120 ° C. was used, and heating the article 1 in the same manner as in Example 1 Peeling was performed.

(Example 16)
Parallel type halogen lamp heater used in Example 9 (Two halogen lamp tubes with a length of 10 cm manufactured by Heat Tech Co., Ltd. are mounted. Wavelength of light generated from the halogen lamp: near infrared region 2 μm, rated voltage 100 V, rated consumption Heating the article 9 in the same manner as in Example 9 except that a dryer set at 120 ° C. was used instead of an electric power of 850 W, a portable type, a weight of 0.7 kg, and a collective irradiation area of about 200 cm ² ). And peeling off.

(Comparative Example 1)
Instead of the styrene-butadiene block copolymer S, a styrene-butadiene block copolymer W having a weight average molecular weight of 1,000,000 (a mixture of a triblock copolymer and a diblock copolymer. The diblock relative to the total amount of the mixture). The copolymer accounted for 20% by mass, except that the polystyrene unit mass ratio of the styrene-butadiene block copolymer was 30% by mass and the polybutadiene unit mass ratio was 70% by mass). An adhesive tape 13 and an article 13 were produced in the same manner as in Example 1.
Heating and peeling were performed in the same manner as in Example 1 except that the article 13 was used instead of the article 1.

(Comparative Example 2)
(Preparation of pressure-sensitive adhesive (a-3))
In a reaction vessel equipped with a stirrer, reflux condenser, thermometer, dropping funnel and nitrogen gas inlet, 44.9 parts by mass of butyl acrylate, 50 parts by mass of 2-ethylhexyl acrylate, 2 parts by mass of acrylic acid, 3 parts by mass of vinyl acetate By dissolving 0.1 part by mass of 4-hydroxybutyl acrylate and 0.1 part by mass of 2,2′-azobisisobutylnitrile as a polymerization initiator in 100 parts by mass of ethyl acetate and polymerizing at 70 ° C. for 10 hours. An acrylic random copolymer X solution having a weight average molecular weight of 800,000 was obtained.

  Next, by adding 30 parts by mass of polymerized rosin ester tackifier resin D-135 (manufactured by Arakawa Chemical Co., Ltd.) to 100 parts by mass of acrylic random copolymer X, and adding ethyl acetate and mixing. An acrylic adhesive having a nonvolatile content of 45% by mass was obtained.

  1.1 parts by mass of “Coronate L-45” (isocyanate-based crosslinking agent, solid content: 45% by mass) manufactured by Nippon Polyurethane Industry Co., Ltd. was added to 100 parts by mass of the acrylic pressure-sensitive adhesive and stirred for 15 minutes. The acrylic pressure-sensitive adhesive layer is formed by applying the acrylic pressure-sensitive adhesive (a-3) on the separator using an applicator so that the thickness after drying becomes 100 μm and drying at 85 ° C. for 5 minutes. did.

Next, the acrylic pressure-sensitive adhesive layer was laminated on both sides of a 38 μm polyethylene terephthalate film having a 4 μm-thick black ink layer provided on the surface, and then pressure-bonded and laminated at 4 kgf / cm ^2. 14 was produced.

An article 14 was produced in the same manner as in Example 1 except that the above adhesive tape 14 was used instead of the adhesive tape used in Example 1.
Heating and peeling were performed in the same manner as in Example 1 except that the article 14 was used instead of the article 1.

(Comparative Example 3)
Other than using a 38 μm thick polyethylene terephthalate film that does not have a 4 μm thick black ink layer instead of the 38 μm polyethylene terephthalate film having a 4 μm thick black ink layer used in Comparative Example 2. Produced the adhesive tape 15 and the article 15 in the same manner as in Comparative Example 2.
Except for using the article 15 instead of the article 1, heating and peeling were performed in the same manner as in Example 1.

(Comparative Production Example 4)
(Preparation of adhesive (a-4))
In a reaction vessel equipped with a stirrer, reflux condenser, thermometer, dropping funnel and nitrogen gas inlet, 64.9 parts by mass of butyl acrylate, 30 parts by mass of 2-ethylhexyl acrylate, 2 parts by mass of acrylic acid, 3 parts by mass of vinyl acetate, By dissolving 0.1 part by mass of 4-hydroxybutyl acrylate and 0.1 part by mass of 2,2′-azobisisobutylnitrile as a polymerization initiator in 100 parts by mass of ethyl acetate and polymerizing at 70 ° C. for 10 hours, 100 parts by mass of a monomer blend of an acrylic random copolymer combination having a weight average molecular weight of 700,000 and 0.2 part by mass of 2,2′-azobisisobutyronitrile as a polymerization initiator are dissolved in 100 parts by mass of ethyl acetate, Polymerization was performed at 0 ° C. for 8 hours to obtain an acrylic random copolymer Y solution.

  Next, 10 parts by mass of rosin ester-based resin A-100 (manufactured by Arakawa Chemical Industries, Ltd.) and polymerized rosin ester-based tackifier resin D-135 (Arakawa Chemical Industries, Ltd.) with respect to 100 parts by mass of the acrylic random copolymer Y 20 parts by mass) was added and diluted with toluene to obtain an adhesive (a-4) having a nonvolatile content of 45% by mass.

  1.1 parts by mass of “Coronate L-45” (isocyanate-based crosslinking agent, solid content: 45% by mass) manufactured by Nippon Polyurethane Industry Co., Ltd. was added to 100 parts by mass of the pressure-sensitive adhesive (a-4) and stirred for 15 minutes. The pressure-sensitive adhesive layer was applied on a separator using an applicator so that the thickness after drying was 100 μm, and dried at 85 ° C. for 5 minutes to form an adhesive layer.

Next, the pressure-sensitive adhesive layer was bonded to both surfaces of a 38 μm polyethylene terephthalate film having a 4 μm thick black ink layer provided on the surface, and then the pressure-sensitive adhesive tape 16 was laminated by pressing at 4 kgf / cm ^2. Produced.

An article 16 was produced in the same manner as in Example 1 except that the above-mentioned adhesive tape 16 was used instead of the adhesive tape 1.
Heating and peeling were performed in the same manner as in Example 1 except that the above-described article 16 was used instead of the article 1.

(Measurement of dynamic viscoelasticity of adhesive layer)
The thickness of the adhesive component (total of rubber-based block copolymer or acrylic copolymer and tackifying resin) used in the production of the adhesive tapes obtained in Examples and Comparative Examples after drying using an applicator A plurality of adhesive layers each having a thickness of 100 μm were formed by applying to the surface of the release liner so as to be 100 μm and drying at 85 ° C. for 5 minutes.

  Next, the test piece which consists of an adhesive layer with a thickness of 2 mm was each created by overlapping the adhesive layer obtained using the same adhesive.

A parallel plate having a diameter of 7.9 mm was attached to a viscoelasticity tester (ARES 2kSTD) manufactured by TA Instruments Japan. The test specimen is sandwiched between the parallel plates with a compressive load of 40 to 60 g, and a storage elastic modulus (23 ° C.) at a frequency of 1 Hz, a temperature range of −60 to 150 ° C., and a temperature increase rate of 2 ° C./min ( G ₂₃ ) and storage elastic modulus (G ₁₂₀ ) at 120 ° C. were measured.

[Ratio of storage elastic modulus (G ₂₃ ) at ₂₃ ° C. and storage elastic modulus (G ₁₂₀ ) at 120 ° C.]
The ratio of the storage elastic modulus (G ₂₃ ) at 23 ° C. to the storage elastic modulus (G ₁₂₀ ) at 120 ° C. measured by the above method was calculated.

[Adhesive strength evaluation method (surface adhesive strength)]
Under the environment of 23 ° C., the pressure-sensitive adhesive tapes obtained in Examples and Comparative Examples were cut into a frame shape having a side (outer shape) length of 14 mm and a width of 2 mm.

  The cut adhesive tape 2 was attached to a glass plate 1 which is a rectangular parallelepiped having a length of 15 mm, a width of 15 mm, and a thickness of 2 mm. At that time, a test piece 1 was prepared by attaching one side of the cut adhesive tape 2 so as to correspond to one side 15 mm of the acrylic plate 1.

Next, SUS3 having a length of 20 mm, a width of 50 mm, and a thickness of 1 mm having a hole with a diameter of 10 mm in the center and a surface of the test piece 1 on the adhesive tape side are pasted so that their centers coincide, and press After pressurizing at 80 N / cm ² for 10 seconds using a machine, the pressed state was released, and the test piece 2 was produced by leaving still in an environment of 23 ° C. for 1 hour.

Next, a tensile tester (A & D Tensilon RTA-100, compression mode) equipped with a stainless steel probe 4 having a diameter of 8 mm was prepared. When the probe 4 applied a force to the test piece 1 constituting the test piece 2 through the hole of the SUS plate 3 constituting the test piece 2, the test piece 1 was peeled off from the polycarbonate plate 3. The strength (N / cm ² ) at the time was measured in a temperature environment of 23 ° C. and 120 ° C., respectively. The speed at which the probe 4 pushes the test piece 1 was set to 10 mm / min.

[Evaluation method of adhesive strength (180 degree peeling adhesive strength)]
180 degree peeling adhesion was measured according to JIS Z 0237. Specifically, the release liner on one side of the pressure-sensitive adhesive tapes obtained in Examples and Comparative Examples was peeled off, and the pressure-sensitive adhesive layer was lined with a polyethylene terephthalate film (PET film) having a thickness of 25 μm.

  The backed adhesive tape was cut into a width of 20 mm, the release liner on the other side was peeled off, and the adhesive layer was bonded to a glass touch panel plate to make a test piece 3.

  The test piece 3 was allowed to stand in an environment of 23 ° C. and 50% RH for 30 minutes, and then a Tensilon tensile tester [manufactured by A & D Co., Ltd., model: RTM-100] in each of the temperature environments of 23 ° C. and 120 ° C. The adhesive strength when the double-sided pressure-sensitive adhesive tape constituting the test piece 3 was peeled from the polycarbonate plate at a speed of 300 mm / min in the direction of 180 degrees was measured.

[Evaluation method of constant load holding force]
One side of the adhesive tape was lined with a polyethylene terephthalate film having a thickness of 25 μm, and cut into a width of 10 mm and a length of 70 mm to prepare a test tape. A range of 50 mm in length of the test tape was affixed to a glass touch panel plate, and was reciprocated using a 2 kg roller to adhere them. The bonded material was left in an atmosphere of 23 ° C. and 50% RH for 1 hour, then a load of 300 g was applied in the direction of 90 ° with respect to the peeling direction, and after left for 3 hours, the test tape was removed from the SUS plate. The peel distance was measured and evaluated according to the following criteria. In addition, the above-described evaluation method of the constant load holding force is a substitute evaluation method assuming a case where a deformation stress is applied to the test tape from the outside for a long time, and indicates that the longer the peeling distance, the better the constant load holding force. The values in the table indicate the peeling distance (mm) after standing for 3 hours.

[Evaluation of thermal decomposability]
Heat until the surface temperature of the adhesive tape reaches 120 ° C by the heating method described in the examples and comparative examples, attach a rubber sucker (diameter 40 mm) to the glass touch panel, and pull the glass touch panel while holding down the liquid crystal display module. The ease of peeling was evaluated according to the following criteria.

○: It was possible to peel off with a force of 20N or more and less than 30N.
X: It could not be peeled even with a force of 30 N or more, or the glass touch panel was broken.

1 Glass plate 2 Cut adhesive tape 3 Stainless steel plate (SUS304)
4 Probe 5 Glass touch panel 6 Cut adhesive tape 7 Liquid crystal display module unit

Claims (10)

A heat-peelable pressure-sensitive adhesive tape, which is used for bonding an information display part of an information display panel and a touch panel member. The adhesive layer (A) formed by using an adhesive containing an acrylic block copolymer or an adhesive containing a rubber block copolymer (a). Heat peelable adhesive tape. The pressure-sensitive adhesive layer (A) is a pressure-sensitive adhesive layer containing a rubber-based block copolymer (a), and the dynamic viscoelasticity at 1 Hz and 120 ° C. of the pressure-sensitive adhesive component contained in the pressure-sensitive adhesive layer (A). storage modulus _{G 120} measured in the spectrum is in the range of ^{1.0 × 10 3 Pa~2.0 × 10 5} Pa, with respect to the storage elastic modulus _{G 120,} dynamic viscoelasticity spectrum at 1Hz and 23 ° C. The heat-peelable pressure-sensitive adhesive tape according to claim 1, wherein the ratio [G ₂₃ / G ₁₂₀ ] of the storage elastic modulus G ₂₃ measured by 1 is 1-20. The heat-peelable pressure-sensitive adhesive tape according to claim 3, wherein the pressure-sensitive adhesive component is the rubber-based block copolymer (a) and a tackifying resin. The heat-peelable pressure-sensitive adhesive tape according to claim 1, having a total thickness of 50 μm to 1 mm. An information display device having a configuration in which an information display unit and a touch panel member of an information display panel are bonded together by the heat-peelable adhesive tape according to claim 1. The information display device according to claim 6, wherein the heat-peelable pressure-sensitive adhesive tape has a window frame shape having a width of 3 mm or less. The information display device according to claim 6 or 7, wherein a surface of the information display unit to which the heat-peelable adhesive tape is attached is composed of a polarizing plate. The information display part of an information display panel and a touch panel member are the methods of disassembling the information display apparatus which has the structure bonded together by the heat peelable adhesive tape of Claim 1, Comprising: The said heat peelable adhesive tape is directly attached. Alternatively, the information display device is disassembled by indirectly heating the information display panel and the touch panel member. The heating of the heat-peelable pressure-sensitive adhesive tape is a step performed by irradiating the heat-peelable pressure-sensitive adhesive tape, the information display panel, or the touch panel member with a laser, or bringing a halogen lamp close to or in contact therewith. Method of dismantling the information display device.

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