JP2016195135A - Light emitting element, light emitting device, electronic apparatus and lighting device - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a light emitting element which enables high-intensity emission even in a state of a low driving voltage and which has a long operating life.SOLUTION: A light emitting element has n (n is a natural number of not less than 2) layers of EL layers between an anode and a cathode. Between the m-th (m is a natural number, 1≤m≤n-1) EL layer from the anode and the (m+1)-th EL layer, a first layer which contacts the m-th EL layer and contains a first donor material, a second layer which contacts the first layer and contains an electron-transport material and a second donor material, and a third layer which contacts the second layer and the (m+1)-th EL layer and contains a hole-transport material and an acceptor material.SELECTED DRAWING: Figure 1

Description

The present invention relates to a light emitting element having a light emitting layer between a pair of electrodes. In addition, the present invention relates to a light-emitting device using the light-emitting element, and an electronic device and a lighting device using the light-emitting device.

In recent years, a light-emitting element using a light-emitting organic compound or an inorganic compound as a light-emitting substance has been actively developed. In particular, a light-emitting element called an electroluminescence (hereinafter referred to as EL) element having a light-emitting layer containing a light-emitting substance between a pair of electrodes is the next generation because of its thin and lightweight characteristics, high-speed response, and direct current low-voltage drive. Has attracted attention as a flat panel display element. In addition, a display using an EL element is characterized by excellent contrast and image quality and a wide viewing angle. Furthermore, since the EL element is a planar light source, its application as a light source such as a backlight of a liquid crystal display or illumination is also considered.

The EL element includes a pair of electrodes and a light-emitting layer including a light-emitting substance provided between the pair of electrodes. The EL element can emit light of a predetermined color when a light-emitting substance is excited by passing a current through the light-emitting layer. In order to increase the light emission luminance of the EL element, it is effective to pass a high current through the light emitting layer. However, power consumption increases by passing a large current through the EL element. In addition, the deterioration of the EL element can be accelerated by passing a large current through the light emitting layer.

Therefore, a light emitting element in which a plurality of light emitting layers are stacked has been proposed (for example, Patent Document 1). Patent Document 1 discloses a light-emitting element having a plurality of light-emitting units (hereinafter also referred to as EL layers in the present specification) and each light-emitting unit partitioned by a charge generation layer. More specifically, a charge generation layer made of vanadium pentoxide is provided on the metal doping layer functioning as an electron injection layer of the first light-emitting unit, and a second light-emitting unit is further provided on the charge generation layer. A light-emitting element having the above structure is disclosed. The light-emitting element disclosed in Patent Document 1 can emit light with high brightness when compared with a light-emitting element having one light-emitting layer when a current having the same current density is supplied.

JP 2003-272860 A

  An object of one embodiment of the present invention is to provide a light-emitting element that can emit light with high luminance.

  Another object of one embodiment of the present invention is to provide a light-emitting element with a long lifetime.

Another object of one embodiment of the present invention is to provide a light-emitting element that can be driven at a low voltage.

Another object of one embodiment of the present invention is to provide a light-emitting device with reduced power consumption.

Another object of one embodiment of the present invention is to provide an electronic device or a lighting device with reduced power consumption.

One embodiment of the present invention includes an EL layer having n layers (n is a natural number of 2 or more) between an anode and a cathode, and the mth EL layer (m is a natural number, 1 ≦ m ≦ n−1) from the anode. And the (m + 1) th EL layer
a first layer containing a first donor material in contact with the mth EL layer; a second layer containing an electron transport material and a second donor material in contact with the first layer; Layers and the (m + 1) th EL
And a third layer containing a hole transporting substance and an acceptor substance in contact with the layer.

Another embodiment of the present invention includes an n-layer (n is a natural number of 2 or more) EL layer between an anode and a cathode, and the mth (m is a natural number, 1 ≦ m ≦ n−1) th from the anode. Between the EL layer and the (m + 1) th EL layer, the first layer containing the first electron transporting material and the first donor material, which is in contact with the mth EL layer, is in contact with the first layer. A second layer containing a second electron-transporting material and a second donor-like material having a lower lowest unoccupied molecular orbital level than the first electron-transporting material, a second layer, and an m + 1th EL layer; And a third layer containing a hole transporting substance and an acceptor substance, which are in contact with each other.

  Another embodiment of the present invention is a light-emitting device manufactured using the above light-emitting element.

  Another embodiment of the present invention is an electronic device including the above light-emitting device.

Another embodiment of the present invention is a lighting device including the above light-emitting device. In this specification, the lighting device is a light source that can be turned on and off, and illuminates the scene, the object to be seen and its surroundings so that it can be seen well, or transmits information by a visual signal, etc. It is a device that aims to make light useful for human life.

In this specification, the ordinal numbers attached as first or second are used for convenience and do not indicate the order of steps or the order of lamination. In addition, a specific name is not shown as a matter for specifying the invention in this specification.

The light-emitting element of one embodiment of the present invention includes a plurality of EL layers. Therefore, high luminance light emission is possible.

The light-emitting element of one embodiment of the present invention includes a plurality of EL layers. Therefore, the lifetime when the light emitting element emits light with high luminance can be improved.

The light-emitting element of one embodiment of the present invention has a structure that can favorably move carriers between a plurality of EL layers. Therefore, the driving voltage of the light emitting element can be reduced.

In addition, the light-emitting device of one embodiment of the present invention includes a light-emitting element with reduced driving voltage. Therefore, power consumption of the light-emitting device can be reduced.

The electronic device or the lighting device of one embodiment of the present invention includes a light-emitting device with reduced power consumption. Therefore, power consumption of the electronic device or the lighting device can be reduced.

FIGS. 3A and 3B each illustrate an example of an element structure and a band diagram of a light-emitting element described in Embodiment 1. FIGS. 3A and 3B illustrate an example of an element structure and a band diagram of a light-emitting element described in Embodiment 2. FIGS. 5A and 5B illustrate an example of an element structure and a band diagram of a light-emitting element described in Embodiment 3. FIGS. FIG. 6 illustrates an example of an element structure of a light-emitting element described in Embodiment 4; 6A and 6B illustrate an example of an element structure of a light-emitting element described in Embodiment 5 and an emission spectrum. FIG. 10 illustrates an active matrix light-emitting device described in Embodiment 6; FIG. 10 illustrates a passive matrix light-emitting device described in Embodiment 6; FIG. 9 illustrates an electronic device described in Embodiment 7; FIG. 9 illustrates a lighting device described in Embodiment 8; FIG. 9 illustrates a lighting device described in Embodiment 8; FIG. 4 shows an element structure of a light-emitting element described in Examples 1 and 2. FIG. 5 shows characteristics of a light-emitting element described in Example 1. FIG. 5 shows characteristics of a light-emitting element described in Example 1. FIG. 10 shows characteristics of a light-emitting element described in Example 2. FIG. 10 shows characteristics of a light-emitting element described in Example 2. FIG. 10 shows characteristics of a light-emitting element described in Example 3; FIG. 10 shows characteristics of a light-emitting element described in Example 3;

Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings. However, the present invention is not limited to the following description, and it is easily understood by those skilled in the art that modes and details can be variously changed without departing from the spirit and scope of the present invention. Therefore,
The present invention is not construed as being limited to the description of the embodiments below.

(Embodiment 1)
In this embodiment, one embodiment of a light-emitting element will be described with reference to FIGS.

A light-emitting element illustrated in FIG. 1A includes a first EL layer 103 and a second EL layer 107 including a light-emitting region between a pair of electrodes (anode 101 and cathode 102). In addition, the light-emitting element includes, from the anode 101 side, the electron injection buffer layer 104 in contact with the first EL layer 103, the electron relay layer 105 in contact with the electron injection buffer layer 104, the electron relay layer 105, and the second E
The charge generation layer 106 is in contact with the L layer 107.

The electron injection buffer layer 104 is a layer for the purpose of relaxing the injection barrier when electrons are injected into the first EL layer 103 and increasing the efficiency of electron injection into the first EL layer 103. In this embodiment mode, the electron injection buffer layer 104 includes a donor substance.

The electron relay layer 105 is a layer for the purpose of promptly sending electrons to the electron injection buffer layer 104. In this embodiment, the electron relay layer 105 includes an electron transporting substance and a donor substance. Note that the electron transporting substance applied to the electron relay layer 105 is
In addition to having high electron transport properties, its LUMO (lowest empty molecular orbital: Lowest
(Unoccupied Molecular Orbital) level is a material that occupies a level between the LUMO level of the first EL layer 103 described later in this embodiment and the acceptor level of the acceptor substance in the charge generation layer 106. . Specifically, a substance having an LUMO level of −5.0 eV or higher is preferably used as the electron transporting substance applied to the electron relay layer 105. Further, it is more preferable to use a material having an LUMO level of −5.0 eV or more and −3.0 eV or less as an electron transporting material applied to the electron relay layer 105.

The charge generation layer 106 is a layer for generating holes and electrons that are carriers of the light emitting element. In this embodiment mode, the charge generation layer 106 includes a hole transporting substance and an acceptor substance.

The diagram shown in FIG. 1B represents a band diagram in the element structure of FIG. In FIG. 1B, 111 is the Fermi level of the anode 101, 112 is the Fermi level of the cathode 102, 11
3 is the LUMO level of the first EL layer 103, 114 is the donor level of the donor substance in the electron relay layer 105, 115 is the LUMO level of the electron transport substance in the electron relay layer 105, and 116 is the charge generation layer 106. The acceptor level 117 of the acceptor substance in FIG. 11 indicates the LUMO level of the second EL layer 107.

In FIG. 1B, electrons generated in the charge generation layer 106 transition to the LUMO level of the electron transporting substance in the electron relay layer 105. Further, the transition is made to the LUMO level of the first EL layer 103 through the electron injection buffer layer 104. After that, in the first EL layer 103, holes injected from the anode 101 and electrons injected from the charge generation layer 106 are recombined. As a result, the first EL layer 103 emits light. Similarly, in the second EL layer 107, holes injected from the charge generation layer 106 and electrons injected from the cathode 102 are recombined. Accordingly, the second EL layer 107 emits light.

The light-emitting element described in this embodiment includes the electron-relay layer 105 including an electron-transport substance and a donor substance. The donor substance shifts the LUMO level of the electron transport substance to the low energy side. Since the electron-transporting material having an LUMO level lower than the LUMO level of the first EL layer 103 is used for the electron relay layer 105, the LUMO level that exists in a relatively low position from the beginning is used as the donor layer. It will be further reduced by sex substances. Thereby, the barrier when the electron relay layer 105 accepts electrons from the charge generation layer 106 is reduced. Also,
The electrons received by the electron relay layer 105 are quickly injected into the first EL layer 103 by the electron injection buffer layer 104 without causing a large injection barrier. As a result, the light emitting element can be driven at a low voltage.

  Next, specific examples of each substance described above will be described.

As the donor substance contained in the electron injection buffer layer 104 and the electron relay layer 105, an alkali metal, an alkaline earth metal, or a rare earth metal, or a compound of an alkali metal, an alkaline earth metal, or a rare earth metal (oxide, halogen, Including carbonates and carbonates). Specific examples include metals such as lithium (Li), cesium (Cs), magnesium (Mg), calcium (Ca), strontium (Sr), europium (Eu), ytterbium (Yb), and compounds of these metals. It is done. The metal or metal compound is preferable because of its high electron injection property.

As the electron transporting substance contained in the electron relay layer 105, a perylene derivative, a nitrogen-containing condensed aromatic compound, or the like can be used.

Specific examples of the perylene derivative include 3,4,9,10-perylenetetracarboxylic dianhydride (abbreviation: PTCDA), 3,4,9,10-perylenetetracarboxylic bisbenzimidazole (abbreviation: PTCBI). , N, N′-Dioctyl-3,4,9,10
-Perylenetetracarboxylic acid diimide (abbreviation: PTCDI-C8H), N, N'-dihexyl-3,4,9,10-perylenetetracarboxylic acid diimide (abbreviation: HexPTC), and the like.

Specific examples of the nitrogen-containing condensed aromatic compound include pyrazino [2,3-f] [1,10].
Phenanthroline-2,3-dicarbonitrile (abbreviation: PPDN), 2, 3, 6, 7, 1
0,11-hexacyano-1,4,5,8,9,12-hexaazatriphenylene (abbreviation: HAT (CN) ₆ ), 2,3-diphenylpyrido [2,3-b] pyrazine (abbreviation: 2P)
YPR) 2,3-bis (4-fluorophenyl) pyrido [2,3-b] pyrazine (abbreviation:
F2PYPR) and the like. Further, since the nitrogen-containing condensed aromatic compound is a stable compound, it is preferable as an electron transporting substance contained in the electron relay layer 105. In addition, it is preferable to use a compound having an electron withdrawing group such as a cyano group or a fluoro group among the nitrogen-containing condensed aromatic compounds because electrons can be easily received in the electron relay layer 105.

In addition, perfluoropentacene, 7,7,8,8, -tetracyanoquinodimethane (abbreviation: TCNQ), 1,4,5,8, -naphthalenetetracarboxylic dianhydride (abbreviation:
NTCDA), copper hexadecafluorophthalocyanine (abbreviation: F ₁₆ CuPc), N, N
'-Bis (2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctyl) -1,4,5,8-naphthalenetetra Carboxylic acid diimide (abbreviation: N
TCDI-C8F), 3 ′, 4′-dibutyl-5,5 ″ -bis (dicyanomethylene)-
5,5 ″ -dihydro-2,2 ′: 5 ′, 2 ″ -terthiophene (abbreviation: DCMT),
A methanofullerene (eg, [6,6] -phenyl C ₆₁ butyric acid methyl ester) or the like can also be used as an electron transporting substance contained in the electron relay layer 105.

Examples of the hole transporting material contained in the charge generation layer 106 include aromatic amine compounds, carbazole derivatives, aromatic hydrocarbons, and high molecular compounds (oligomers, dendrimers, polymers, etc.).
It is possible to apply various organic compounds. Note that the substances described here are mainly substances having a hole mobility of 1 × 10 ⁻⁶ cm ² / Vs or higher.

Specific examples of the aromatic amine compound include 4,4′-bis [N- (1-naphthyl)-
N-phenylamino] biphenyl (abbreviation: NPB) and N, N′-bis (3-methylphenyl) -N, N′-diphenyl- [1,1′-biphenyl] -4,4′-diamine (abbreviation:
TPD), 4,4 ′, 4 ″ -tris (carbazol-9-yl) triphenylamine (
Abbreviation: TCTA), 4,4 ′, 4 ″ -tris (N, N-diphenylamino) triphenylamine (abbreviation: TDATA), 4,4 ′, 4 ″ -tris [N- (3-methylphenyl) ) -N-phenylamino] triphenylamine (abbreviation: MTDATA), N, N'-bis (4-methylphenyl) -N, N'-diphenyl-p-phenylenediamine (abbreviation: DT)
DPPA), 4,4′-bis [N- (4-diphenylaminophenyl) -N-phenylamino] biphenyl (abbreviation: DPAB), N, N′-bis [4- [bis (3-methylphenyl) amino ] Phenyl] -N, N′-diphenyl- [1,1′-biphenyl] -4,4 ′
-Diamine (abbreviation: DNTPD), 1,3,5-tris [N- (4-diphenylaminophenyl) -N-phenylamino] benzene (abbreviation: DPA3B), and the like.

Specific examples of the carbazole derivative include 3- [N- (9-phenylcarbazole-
3-yl) -N-phenylamino] -9-phenylcarbazole (abbreviation: PCzPCA1)
), 3,6-bis [N- (9-phenylcarbazol-3-yl) -N-phenylamino] -9-phenylcarbazole (abbreviation: PCzPCA2), 3- [N- (1-naphthyl)
-N- (9-phenylcarbazol-3-yl) amino] -9-phenylcarbazole (
Abbreviations: PCzPCN1) and the like. In addition, 4,4′-di (N-carbazolyl) biphenyl (abbreviation: CBP), 1,3,5-tris [4- (N-carbazolyl) phenyl]
Benzene (abbreviation: TCPB), 9- [4- (10-phenyl-9-anthracenyl) phenyl] -9H-carbazole (abbreviation: CzPA), 1,4-bis [4- (N-carbazolyl) phenyl] -2 3,5,6-tetraphenylbenzene and the like.

Specific examples of the aromatic hydrocarbon include 2-tert-butyl-9,10-di (2-naphthyl) anthracene (abbreviation: t-BuDNA), 2-tert-butyl-9,10-di (1- Naphthyl) anthracene, 9,10-bis (3,5-diphenylphenyl) anthracene (abbreviation: DPPA), 2-tert-butyl-9,10-bis (4-phenylphenyl) anthracene (abbreviation: t-BuDBA), 9,10-di (2-naphthyl) anthracene (abbreviation: DNA), 9,10-diphenylanthracene (abbreviation: DPAnth), 2
-Tert-butylanthracene (abbreviation: t-BuAnth), 9,10-bis (4-methyl-1-naphthyl) anthracene (abbreviation: DMNA), 9,10-bis [2- (1-naphthyl) phenyl]- 2-tert-butylanthracene, 9,10-bis [2- (1-
Naphthyl) phenyl] anthracene, 2,3,6,7-tetramethyl-9,10-di (1
-Naphthyl) anthracene, 2,3,6,7-tetramethyl-9,10-di (2-naphthyl) anthracene, 9,9'-bianthryl, 10,10'-diphenyl-9,9'-bianthryl, 10 , 10′-bis (2-phenylphenyl) -9,9′-bianthryl,
10,10′-bis [(2,3,4,5,6-pentaphenyl) phenyl] -9,9′-
Bianthryl, anthracene, tetracene, rubrene, perylene, 2,5,8,11-tetra (tert-butyl) perylene and the like can be mentioned. The aromatic hydrocarbon may have a vinyl skeleton. Examples of the aromatic hydrocarbon having a vinyl group include 4
, 4′-bis (2,2-diphenylvinyl) biphenyl (abbreviation: DPVBi), 9,10
-Bis [4- (2,2-diphenylvinyl) phenyl] anthracene (abbreviation: DPVPA)
) And the like.

Alternatively, a high molecular compound such as poly (N-vinylcarbazole) (abbreviation: PVK) or poly (4-vinyltriphenylamine) (abbreviation: PVTPA) can be used as the hole-transport substance.

Furthermore, the hole transporting material is preferably a material having a hole mobility of 1 × 10 ⁻⁶ cm ² / Vs or higher. However, if the substance has a higher hole transportability than electrons,
Other than these can also be applied.

In addition, when the aromatic hydrocarbon is formed into a film by a vapor deposition method,
From the viewpoint of film quality after film formation, the number of carbon atoms forming the condensed ring is more preferably 14 to 42.

As the acceptor substance included in the charge generation layer 106, a transition metal oxide or an oxide of a metal belonging to Groups 4 to 8 in the periodic table can be used. Specific examples include metal oxides such as vanadium oxide, niobium oxide, tantalum oxide, chromium oxide, molybdenum oxide, tungsten oxide, manganese oxide, and rhenium oxide. The metal oxide is preferable because of its high electron accepting property. Further, the acceptor substance is more preferably molybdenum oxide. Note that molybdenum oxide has a feature of low hygroscopicity.

The electron injection buffer layer 104, the electron relay layer 105, and the charge generation layer 106 can be manufactured by a dry process (for example, a vacuum evaporation method or a sputtering method) or a wet process (for example, an inkjet method, a spin coating method, Various methods can be applied regardless of the application method or the like.

  Next, specific examples of the anode 101 and the cathode 102 described above will be described.

As the anode 101, a metal, an alloy, an electrically conductive compound, a mixture thereof, or the like having a high work function (specifically, 4.0 eV or more is preferable) can be used. Specifically, indium oxide-tin oxide (ITO: Indium Tin Oxide),
Indium oxide containing silicon or silicon oxide-tin oxide, indium oxide-
Examples thereof include conductive metal oxides such as zinc oxide (IZO: Indium Zinc Oxide), tungsten oxide, and indium oxide containing zinc oxide.

The conductive metal oxide thin film can be formed by a sputtering method. Further, the conductive metal oxide can be manufactured by applying a sol-gel method or the like. For example, indium oxide-zinc oxide (IZO) is 1-20 w with respect to indium oxide.
It can be formed by a sputtering method using a target to which t% of zinc oxide is added. Further, indium oxide containing tungsten oxide and zinc oxide can be formed by a sputtering method using a target containing 0.5 to 5 wt% tungsten oxide and 0.1 to 1 wt% zinc oxide with respect to indium oxide. Is possible.

In addition, gold (Au), platinum (Pt), nickel (Ni), tungsten (W), chromium (Cr), molybdenum (Mo), iron (Fe), cobalt (Co), copper (Cu), palladium ( Pd), titanium (Ti), and nitrides thereof (for example, titanium nitride) and oxides such as molybdenum oxide, vanadium oxide, ruthenium oxide, tungsten oxide, manganese oxide, and titanium oxide are used as the anode 101. It is possible. Poly (3
, 4-ethylenedioxythiophene) / poly (styrenesulfonic acid) (abbreviation: PEDOT)
/ PSS), conductive polymers such as polyaniline / poly (styrenesulfonic acid) (abbreviation: PAni / PSS) can also be applied. However, in the case where a charge generation layer in contact with the anode 101 is provided as part of the first EL layer 103, various conductive materials can be applied to the anode 101 regardless of the work function. Note that the charge generation layer can have the same structure as the charge generation layer 106 provided between the first EL layer 103 and the second EL layer 107 described above.

As the cathode 102, a metal, an alloy, an electrically conductive compound, a mixture thereof, or the like having a low work function (specifically, preferably 3.8 eV or less) can be used. Specifically, elements belonging to Group 1 or Group 2 of the periodic table of elements, that is, alkali metals such as lithium (Li) and cesium (Cs), magnesium (Mg), calcium (C
a), alkaline earth metals such as strontium (Sr), and alloys containing them (MgAg)
, AlLi, etc.), and rare earth metals such as europium (Eu) and ytterbium (Yb), and alloys containing these. Note that a film of an alkali metal, an alkaline earth metal, or an alloy containing these can be formed by a vacuum evaporation method. An alloy containing an alkali metal and an alkaline earth metal can also be formed by a sputtering method.

In addition, compounds of alkali metals, alkaline earth metals, or rare earth metals (for example, lithium fluoride (LiF), lithium oxide (LiOx), cesium fluoride (CsF), calcium fluoride (CaF ₂ ), erbium fluoride The cathode 102 can also be formed by stacking a thin film (such as (ErF ₃ )) and a metal film such as aluminum. However, in the case where a charge generation layer in contact with the cathode 102 is provided as part of the second EL layer 107, various conductive substances can be applied to the cathode 102 regardless of the work function. Note that the charge generation layer can have the same structure as the charge generation layer 106 provided between the first EL layer 103 and the second EL layer 107 described above.

Note that in the light-emitting element described in this embodiment, at least one of the anode 101 and the cathode 102 only needs to transmit a light emission wavelength. Translucency can be ensured by using a transparent electrode such as ITO, or by reducing the film thickness of the electrode.

  Next, specific examples of the above-described first EL layer and second EL layer will be described.

The first EL layer 103 and the second EL layer 107 may include at least a light emitting layer having a light emitting substance. That is, the first EL layer 103 and the second EL layer 107 are
A structure in which a light emitting layer and a layer other than the light emitting layer are stacked may be employed. Note that the first EL layer 10
3 and the light-emitting layer included in the second EL layer 107 may be different from each other. The first EL layer 103 and the second EL layer 107 may each have a stacked structure in which a light emitting layer and a layer other than the light emitting layer are stacked independently.

As a layer other than the light emitting layer, a layer containing a hole injecting substance (hole injection layer), a layer containing a hole transporting substance (hole transporting layer), a layer containing an electron transporting substance (electron transporting layer) And a layer containing an electron injecting substance (electron injecting layer) and a layer containing a bipolar (electron transporting and hole transporting) substance. These can be combined as appropriate.

Hereinafter, substances constituting each layer when the first EL layer 103 and the second EL layer 107 are configured to include a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer, and an electron injection layer. A specific example is shown.

The hole injection layer is a layer containing a hole injection material. Examples of the hole injecting substance include hole injecting substances such as molybdenum oxide, vanadium oxide, ruthenium oxide, tungsten oxide, and manganese oxide. In addition, phthalocyanine compounds such as phthalocyanine (abbreviation: H ₂ Pc) and copper phthalocyanine (abbreviation: CuPc), and polymers such as PEDOT / PSS (abbreviation) can also be used as the hole injecting substance.

The hole transport layer is a layer containing a hole transport material. As the hole transporting substance, NPB
(Abbreviation), TPD (abbreviation), TCTA (abbreviation), TDATA (abbreviation), MTDATA (abbreviation), and 4,4′-bis [N- (spiro-9,9′-bifluoren-2-yl) -N -
Aromatic amine compounds such as phenylamino] biphenyl (abbreviation: BSPB), and PCz
PCA1 (abbreviation), PCzPCA2 (abbreviation), PCzPCN1 (abbreviation), CBP (abbreviation)
, TCPB (abbreviation), and CzPA (abbreviation) carbazole derivatives. Also,
PVK (abbreviation), PVTPA (abbreviation), poly [N- (4- {N ′-[4- (4-diphenylamino) phenyl] phenyl-N′-phenylamino} phenyl) methacrylamide]
(Abbreviation: PTPDMA), poly [N, N′-bis (4-butylphenyl) -N, N′-bis (phenyl) benzidine] (abbreviation: Poly-TPD) is applied as the hole transporting substance. Is also possible. The substances described here are mainly substances having a hole mobility of 1 × 10 ⁻⁶ cm ² / Vs or higher. Note that other than these substances, any substance that has a property of transporting more holes than electrons may be used. Further, the hole transport layer is not limited to a single layer, and may be a stack of two or more layers made of the above substances.

The light emitting layer is a layer containing a light emitting substance. As the light-emitting substance, the following fluorescent compounds and phosphorescent compounds can be used.

As the fluorescent compound, N, N′-bis [4- (9H-carbazol-9-yl) is used.
Phenyl] -N, N′-diphenylstilbene-4,4′-diamine (abbreviation: YGA2S
), 4- (9H-carbazol-9-yl) -4 '-(10-phenyl-9-anthryl) triphenylamine (abbreviation: YGAPA), 4- (9H-carbazol-9-yl)-
4 ′-(9,10-diphenyl-2-anthryl) triphenylamine (abbreviation: 2YGA)
PPA), N, 9-diphenyl-N- [4- (10-phenyl-9-anthryl) phenyl] -9H-carbazol-3-amine (abbreviation: PCAPA), perylene, 2,5,8,
11-tetra-tert-butylperylene (abbreviation: TBP), 4- (10-phenyl-9
-Anthryl) -4 ′-(9-phenyl-9H-carbazol-3-yl) triphenylamine (abbreviation: PCBAPA), N, N ″-(2-tert-butylanthracene-9
, 10-Diyldi-4,1-phenylene) bis [N, N ′, N′-triphenyl-1,4
-Phenylenediamine] (abbreviation: DPABPA), N, 9-diphenyl-N- [4- (9
, 10-diphenyl-2-anthryl) phenyl] -9H-carbazol-3-amine (
Abbreviation: 2PCAPPA), N- [4- (9,10-diphenyl-2-anthryl) phenyl] -N, N ′, N′-triphenyl-1,4-phenylenediamine (abbreviation: 2DPAP)
PA), N, N, N ′, N ′, N ″, N ″, N ′ ″, N ′ ″-octaphenyldibenzo [g, p] chrysene-2,7,10,15-tetraamine (Abbreviation: DBC1), coumarin 30, N- (9,10-diphenyl-2-anthryl) -N, 9-diphenyl-9
H-carbazol-3-amine (abbreviation: 2PCAPA), N- [9,10-bis (1,1
'-Biphenyl-2-yl) -2-anthryl] -N, 9-diphenyl-9H-carbazol-3-amine (abbreviation: 2PCABPhA), N- (9,10-diphenyl-2-anthryl) -N, N ', N'-triphenyl-1,4-phenylenediamine (abbreviation: 2DP)
APA), N- [9,10-bis (1,1′-biphenyl-2-yl) -2-anthryl] -N, N ′, N′-triphenyl-1,4-phenylenediamine (abbreviation: 2DPABP)
hA), 9,10-bis (1,1′-biphenyl-2-yl) -N- [4- (9H-carbazol-9-yl) phenyl] -N-phenylanthracen-2-amine (abbreviation: 2Y)
GABPhA), N, N, 9-triphenylanthracen-9-amine (abbreviation: DPhA)
PhA), coumarin 545T, N, N′-diphenylquinacridone, (abbreviation: DPQd)
, Rubrene, 5,12-bis (1,1′-biphenyl-4-yl) -6,11-diphenyltetracene (abbreviation: BPT), 2- (2- {2- [4- (dimethylamino) phenyl]
Ethenyl} -6-methyl-4H-pyran-4-ylidene) propanedinitrile (abbreviation: D
CM1), 2- {2-methyl-6- [2- (2,3,6,7-tetrahydro-1H, 5H).
-Benzo [ij] quinolizin-9-yl) ethenyl] -4H-pyran-4-ylidene} propanedinitrile (abbreviation: DCM2), N, N, N ′, N′-tetrakis (4-methylphenyl) tetracene- 5,11-diamine (abbreviation: p-mPhTD), 7,14-diphenyl-N, N, N ′, N′-tetrakis (4-methylphenyl) acenaphtho [1,2-a
] Fluoranthene-3,10-diamine (abbreviation: p-mPhAFD), 2- {2-isopropyl-6- [2- (1,1,7,7-tetramethyl-2,3,6,7-tetrahydro-]
1H, 5H-benzo [ij] quinolizin-9-yl) ethenyl] -4H-pyran-4-ylidene} propanedinitrile (abbreviation: DCJTI), 2- {2-tert-butyl-6-
[2- (1,1,7,7-tetramethyl-2,3,6,7-tetrahydro-1H, 5H-
Benzo [ij] quinolizin-9-yl) ethenyl] -4H-pyran-4-ylidene} propanedinitrile (abbreviation: DCJTB), 2- (2,6-bis {2- [4- (dimethylamino) phenyl] Ethenyl} -4H-pyran-4-ylidene) propanedinitrile (abbreviation:
BisDCM), 2- {2,6-bis [2- (8-methoxy-1,1,7,7-tetramethyl-2,3,6,7-tetrahydro-1H, 5H-benzo [ij] quinolidine- 9-yl) ethenyl] -4H-pyran-4-ylidene} propanedinitrile (abbreviation: BisDC)
JTM).

As the phosphorescent compound, bis [2- (4 ′, 6′-difluorophenyl) pyridinato-N, C ^{2 ′} ] iridium (III) tetrakis (1-pyrazolyl) borate (abbreviation:
FIr6), bis [2- (4 ′, 6′-difluorophenyl) pyridinato-N, C ^{2 ′} ]
Iridium (III) picolinate (abbreviation: FIrpic), bis [2- (3 ′, 5′-
Bistrifluoromethylphenyl) pyridinato-N, C ^{2 ′} ] iridium (III) picolinate (abbreviation: Ir (CF ₃ ppy) ₂ (pic)), bis [2- (4 ′, 6′-difluorophenyl) pyridinato-N , C ^{2 ′} ] iridium (III) acetylacetonate (abbreviation: FIracac), tris (2-phenylpyridinato) iridium (III) (
Abbreviations: Ir (ppy) ₃ ), bis (2-phenylpyridinato) iridium (III) acetylacetonate (abbreviation: Ir (ppy) ₂ (acac)), bis (benzo [h] quinolinato) iridium (III) Acetylacetonate (abbreviation: Ir (bzq) ₂ (acac
)), Bis (2,4-diphenyl-1,3-oxazolate-N, C ^{2 ′} ) iridium (I
II) Acetylacetonate (abbreviation: Ir (dpo) ₂ (acac)), bis [2- (4
'-Perfluorophenylphenyl) pyridinato] iridium (III) acetylacetonate (abbreviation: Ir (p-PF-ph) ₂ (acac)), bis (2-phenylbenzothiazolate-N, C ^{2 ′} ) iridium (III) Acetylacetonate (abbreviation: Ir (bt
) ₂ (acac)), bis [2- (2′-benzo [4,5-α] thienyl) pyridinato-
N, C ^{3 ′} ] iridium (III) acetylacetonate (abbreviation: Ir (btp) ₂ (a
cac)), bis (1-phenylisoquinolinato-N, C ^{2 ′} ) iridium (III) acetylacetonate (abbreviation: Ir (piq) ₂ (acac)), (acetylacetonato)
Bis [2,3-bis (4-fluorophenyl) quinoxalinato] iridium (III) (
Abbreviations: Ir (Fdpq) ₂ (acac)), (acetylacetonato) bis (2,3,5-
Triphenylpyrazinato) iridium (III) (abbreviation: Ir (tppr) ₂ (acac
)), 2,3,7,8,12,13,17,18-octaethyl-21H, 23H-porphyrin platinum (II) (abbreviation: PtOEP), tris (acetylacetonato) (monophenanthroline) terbium (III) (Abbreviation: Tb (acac) ₃ (Phen)), tris (1,3-diphenyl-1,3-propanedionate) (monophenanthroline) europium (III) (abbreviation: Eu (DBM) ₃ (Phen)), Tris [1- (2-thenoyl) -3,3,3-trifluoroacetonato] (monophenanthroline) europium (
III) (abbreviation: Eu (TTA) ₃ (Phen)).

Note that the light-emitting layer preferably has a structure in which these light-emitting substances are dispersed in a host material. As host materials, NPB (abbreviation), TPD (abbreviation), TCTA (abbreviation), TDA
Aromatic amine compounds such as TA (abbreviation), MTDATA (abbreviation), BSPB (abbreviation), P
CzPCA1 (abbreviation), PCzPCA2 (abbreviation), PCzPCN1 (abbreviation), CBP (abbreviation), TCPB (abbreviation), carbazole derivatives such as CzPA (abbreviation), and PVK (abbreviation), PVTPA (abbreviation), PTPDMA (abbreviation), Hole-transporting substances including polymer compounds such as Poly-TPD (abbreviation), tris (8-quinolinolato) aluminum (abbreviation: Alq), tris (4-methyl-8-quinolinolato) aluminum (abbreviation: Almq)
₃ ), bis (10-hydroxybenzo [h] quinolinato) beryllium (abbreviation: BeBq ₂
), Bis (2-methyl-8-quinolinolato) (4-phenylphenolato) aluminum (
Abbreviation: BAlq), a metal complex having a quinoline skeleton or a benzoquinoline skeleton, bis [2- (2-hydroxyphenyl) benzoxazolate] zinc (abbreviation: Zn (BOX) ₂
), Bis [2- (2-hydroxyphenyl) benzothiazolate] zinc (abbreviation: Zn (BT
Z) a metal complex having an oxazole-based or thiazole-based ligand such as ₂ ), 2- (4-biphenylyl) -5- (4-tert-butylphenyl) -1,3,4-oxadiazole (
Abbreviation: PBD), 1,3-bis [5- (p-tert-butylphenyl) -1,3,4-
Oxadiazol-2-yl] benzene (abbreviation: OXD-7), 9- [4- (5-phenyl-1,3,4-oxadiazol-2-yl) phenyl] carbazole (abbreviation: CO1
1), 3- (4-biphenylyl) -4-phenyl-5- (4-tert-butylphenyl) -1,2,4-triazole (abbreviation: TAZ), bathophenanthroline (abbreviation: BPh)
en), bathocuproine (abbreviation: BCP), poly [(9,9-dihexylfluorene-
2,7-diyl) -co- (pyridine-3,5-diyl)] (abbreviation: PF-Py), and poly [(9,9-dioctylfluorene-2,7-diyl) -co- (2, 2'-bipyridine-6,6'-diyl)] (abbreviation: PF-BPy) and the like.

The electron transport layer is a layer containing an electron transport material. As the electron transporting substance, Alq
(Abbreviations), Almq ₃ (abbreviations), BeBq ₂ (abbreviations), metal complexes having a quinoline skeleton or a benzoquinoline skeleton, such as BAlq (abbreviations), and Zn (BOX) ₂ (abbreviations) and Zn (BTZ) ₂ ( (Abbreviations) and the like, and metal complexes having an oxazole or thiazole ligand. In addition to metal complexes, PBD (abbreviation), OXD-7 (abbreviation)
, CO11 (abbreviation), TAZ (abbreviation)), BPhen (abbreviation), BCP (abbreviation), PF-
Py (abbreviation), PF-BPy (abbreviation), or the like can be used as the electron-transporting substance. The substances mentioned here are mainly substances having an electron mobility of 1 × 10 ⁻⁶ cm ² / Vs or higher. Note that other than these substances, any substance that has a property of transporting more electrons than holes may be used. Further, the electron-transporting layer is not limited to a single layer, and a layer in which two or more layers including the above substances are stacked may be used.

The electron injection layer is a layer containing an electron injecting substance. Examples of the electron injecting substance include alkali metals such as lithium fluoride (LiF), cesium fluoride (CsF), and calcium fluoride (CaF ₂ ), alkaline earth metals, and compounds thereof. In addition, an alkali metal, an alkaline earth metal, or a compound containing these compounds in an electron transporting substance (for example,
It is also possible to apply Alq (abbreviation) containing magnesium (Mg) or the like as the electron injecting substance. With such a structure, the efficiency of electron injection from the cathode 102 can be further increased.

In the case where a charge generation layer is provided in the first EL layer 103 or the second EL layer 107, the charge generation layer is a layer including a hole transporting substance and an acceptor substance. Note that the charge generation layer includes not only a case where a hole transporting substance and an acceptor substance are contained in the same film, but also a layer containing a hole transporting substance and a layer containing an acceptor substance. May be. Note that in the case of a stacked structure, a layer containing an acceptor substance is in contact with the anode 101 or the cathode 102.

By providing the charge generation layer in the first EL layer 103 or the second EL layer 107, the anode 101 or the cathode 102 can be formed without considering the work function of the substance forming the electrode. Note that the charge generation layer provided in the first EL layer 103 or the second EL layer 107 is similar to the charge generation layer 106 provided between the first EL layer 103 and the second EL layer 107 described above. Configurations and materials can be applied. For this reason, the above description is incorporated herein.

Note that the first EL layer 103 and the second EL layer 107 can be formed by stacking these layers in appropriate combination. In addition, as a formation method of the first EL layer 103 and the second EL layer 107, various methods (eg, a dry method and a wet method) can be selected as appropriate depending on a material to be used. For example, a vacuum evaporation method, an inkjet method, a spin coating method, or the like can be used. Further, different methods may be used for each layer.

By combining the above substances, the light-emitting element described in this embodiment can be manufactured. The light-emitting element can emit light from the above-described light-emitting substance. Therefore, various emission colors can be obtained by changing the type of the light-emitting substance used for the light-emitting layer. In addition, by using a plurality of light-emitting substances having different emission colors as the light-emitting substance, broad spectrum light emission or white light emission can be obtained.

Note that although a light-emitting element provided with two EL layers is described in this embodiment mode, the number of EL layers is not limited to two, and two or more layers, for example, three layers. There may be. In the case where an EL layer having n layers (n is a natural number of 2 or more) is provided in the light-emitting element, m (m is a natural number, 1 ≦
By stacking an electron injection buffer layer, an electron relay layer, and a charge generation layer in this order from the anode side between the m ≦ n−1) th EL layer and the (m + 1) th EL layer, the driving voltage of the light emitting element is obtained. Can be reduced.

In addition, the light-emitting element described in this embodiment can be manufactured over various substrates. As the substrate, for example, glass, plastic, metal plate, metal foil or the like can be applied. In addition, when light emitted from the light-emitting element is extracted from the substrate side, a light-transmitting substrate may be used. However, if the substrate functions as a support in the light emitting element manufacturing process,
Other than these may be used.

Note that the contents described in this embodiment can be combined as appropriate with any of the contents described in the other embodiments.

(Embodiment 2)
In this embodiment, an example of the light-emitting element described in Embodiment 1 will be described. In particular,
The case where the electron-injection buffer layer 104 included in the light-emitting element described in Embodiment 1 is formed using a single layer of a donor substance is described with reference to FIGS.

In the light-emitting element described in this embodiment, the first EL layer 103 and the second EL layer 107 including a light-emitting region are sandwiched between a pair of electrodes (anode 101 and cathode 102) as shown in FIG. It is. In addition, the light-emitting element includes, from the anode 101 side, an electron injection buffer layer 104 in contact with the first EL layer 103, an electron relay layer 105 in contact with the electron injection buffer layer 104, an electron relay layer 105, and a second EL layer. The charge generation layer 106 is in contact with 107.

In the present embodiment, the structure and materials described in Embodiment 1 are used for the anode 101, the cathode 102, the first EL layer 103, the electron relay layer 105, the charge generation layer 106, and the second EL layer 107. Can be used. Therefore, the description of Embodiment 1 is used here.

In this embodiment, substances used for the electron injection buffer layer 104 include alkali metals such as lithium (Li) and cesium (Cs), magnesium (Mg), calcium (
Ca) and alkaline earth metals such as strontium (Sr), rare earth metals such as europium (Eu) and ytterbium (Yb), alkali metal compounds (oxides such as lithium oxide, halides, lithium carbonate, cesium carbonate, etc. And materials having high electron injection properties such as alkaline earth metal compounds (including oxides, halides and carbonates), and rare earth metal compounds (including oxides, halides and carbonates). It is done. Note that these highly electron-injecting substances are preferable because they are stable in the air and thus have high productivity and are suitable for mass production.

In the light-emitting element described in this embodiment, the electron injection buffer layer 104 is provided with a single layer of the above metal or a compound thereof. The electron injection buffer layer 104 is formed with a very thin film thickness (specifically, 1 nm or less) in order to avoid an increase in driving voltage. However, after the electron transport layer 108 is formed, the electron injection buffer layer 104 is formed on the electron transport layer 108.
A part of the substance forming the electron injection buffer layer 104 is formed by the first EL.
It can also be present in the electron transport layer 108 that is part of the layer 103. In other words, the electron injection buffer layer 104 having a very small thickness exists at the interface between the electron relay layer 105 and the electron transport layer 108 which is a part of the first EL layer 103. Note that in this embodiment, it is preferable to form the electron transport layer 108 in the first EL layer 103 so as to be in contact with the electron injection buffer layer 104.

The diagram shown in FIG. 2B represents a band diagram in the element structure of FIG. In FIG. 2B, an electron injection buffer layer 104 is provided at the interface between the electron relay layer 105 and the first EL layer 103 (electron transport layer 108), whereby the charge generation layer 106 and the first EL layer 103 (electron layer 103) The injection barrier between the transport layers 108) can be relaxed. Therefore, the charge generation layer 106
Can be easily injected into the first EL layer 103.

In addition, the structure of the electron injection buffer layer described in this embodiment is compared with an electron injection buffer layer described later in Embodiment 3 (a layer formed by adding a donor substance to an electron transporting substance). Thus, the driving voltage of the light emitting element can be reduced.

Note that the contents described in this embodiment can be combined as appropriate with any of the contents described in the other embodiments.

(Embodiment 3)
In this embodiment, an example of the light-emitting element described in Embodiment 1 will be described. In particular,
The case where the electron-injection buffer layer 104 included in the light-emitting element described in Embodiment 1 includes an electron-transporting substance and a donor substance is described with reference to FIGS. To do.

In the light-emitting element described in this embodiment, the first EL layer 103 and the second EL layer 107 including a light-emitting region are sandwiched between a pair of electrodes (anode 101 and cathode 102) as shown in FIG. It is. In addition, the light-emitting element includes, from the anode 101 side, an electron injection buffer layer 104 in contact with the first EL layer 103, an electron relay layer 105 in contact with the electron injection buffer layer 104, an electron relay layer 105, and a second EL layer. The charge generation layer 106 is in contact with 107.

Further, the electron injection buffer layer 104 includes an electron transporting substance and a donor substance.
Note that in this embodiment mode, the donor substance is preferably added at a mass ratio of 0.001 to 0.1 with respect to the electron transporting substance. Thereby, the electron injection buffer layer 104 with good film quality is obtained. In addition, the electron injection buffer layer 104 with high reactivity can be obtained.

Anode 101, cathode 102, first EL layer 103, and electronic relay layer 1 in this embodiment
05, the structure and materials described in Embodiment Mode 1 can be used for the charge generation layer 106 and the second EL layer 107. Therefore, the description of Embodiment 1 is used here.

In this embodiment, the electron transporting substance contained in the electron injection buffer layer 104 includes a quinoline skeleton or a benzoquinoline skeleton such as Alq (abbreviation), Almq ₃ (abbreviation), BeBq ₂ (abbreviation), and BAlq (abbreviation). Metal complex, Zn (BOX) ₂ (abbreviation), Z
a metal complex having an oxazole-based or thiazole-based ligand such as n (BTZ) ₂ (abbreviation),
PBD (abbreviation), OXD-7 (abbreviation), CO11 (abbreviation), TAZ (abbreviation), BPhen
(Abbreviation), BCP (abbreviation), and the like. The substances mentioned here are mainly 1 × 10
It is a substance having an electron mobility of ⁻⁶ cm ² / Vs or higher.

In addition, a high molecular compound such as PF-Py (abbreviation) or PF-BPy (abbreviation) can be used as the electron-transporting substance included in the electron-injection buffer layer 104.

In this embodiment, the donor substance contained in the electron injection buffer layer 104 includes alkali metals, alkaline earth metals, rare earth metals, and compounds thereof (including oxides, halides, and carbonates). Is mentioned. Tetrathianaphthacene (abbreviation:
It is also possible to apply an organic compound such as TTN), nickelocene, or decamethyl nickelocene as a donor substance contained in the electron injection buffer layer 104.

Note that in this embodiment mode, the first EL layer 103 includes the electron injection buffer layer 104.
The electron transport layer 108 may be formed so as to be in contact with each other. In the case where the electron transport layer 108 is formed so as to be in contact with the electron injection buffer layer 104, an electron transport material used for the electron injection buffer layer 104 and an electron transport used for the electron transport layer 108 which is a part of the first EL layer 103. The sex substance may be the same substance or a different substance.

A light-emitting element described in this embodiment includes an electron-injection buffer layer including an electron-transporting substance and a donor substance between the first EL layer 103 and the electron-relay layer 105 as illustrated in FIG. 1
04 is provided.

The diagram shown in FIG. 3B represents a band diagram in the element structure of FIG. By forming the electron injection buffer layer 104, an injection barrier between the electron relay layer 105 and the first EL layer 103 (electron transport layer 108) can be relaxed. Therefore, the charge generation layer 106
Can be easily injected into the first EL layer 103.

Note that the contents described in this embodiment can be combined as appropriate with any of the contents described in the other embodiments.

(Embodiment 4)
In this embodiment, an example of the light-emitting element described in Embodiment 1 will be described. In particular,
4A, the structure of the charge generation layer 106 included in the light-emitting element described in Embodiment 1
A description will be given using (B).

The light-emitting element described in this embodiment includes a pair of electrodes (anode 1) as illustrated in FIGS.
01, the cathode 102), the first EL layer 103 and the second EL layer 107 including the light emitting region are sandwiched. In addition, the light-emitting element includes an electron injection buffer layer 104 in contact with the first EL layer 103 and an electron relay layer 105 in contact with the electron injection buffer layer 104 from the anode 101 side.
And the charge generation layer 106 in contact with the electron relay layer 105 and the second EL layer 107. 4A and 4B, the anode 101, the cathode 102, the first EL layer 103, the electron injection buffer layer 104, the electron relay layer 105, and the second EL layer 107 are formed in Embodiment Modes 1 to 1. The structure and substance described in 3 can be used. Therefore, the description of Embodiments 1 to 3 is used here.

In the light-emitting element illustrated in FIGS. 4A and 4B, the charge generation layer 106 is a layer including a hole-transporting substance and an acceptor substance. Note that in the charge generation layer 106, holes and electrons are generated when the acceptor substance withdraws electrons from the hole transporting substance.

The charge generation layer 106 illustrated in FIG. 4A has a structure in which a hole transporting substance and an acceptor substance are included in the same film. In this case, the mass ratio with respect to the hole transporting substance is 0.1.
It is preferable to add the acceptor substance at a ratio of 4.0 or less because carriers are easily generated in the charge generation layer 106.

In FIG. 4A, since the acceptor substance is doped with the hole transporting substance, an increase in driving voltage can be suppressed even when the charge generation layer 106 is thickened.
Therefore, an increase in driving voltage of the light emitting element can be suppressed, and color purity can be improved by optical adjustment. In addition, by increasing the thickness of the charge generation layer 106, a short circuit of the light emitting element can be prevented.

On the other hand, the charge generation layer 106 illustrated in FIG. 4B includes a layer 106 a containing a hole transporting substance in contact with the second EL layer 107 and a layer 10 containing an acceptor substance in contact with the electron relay layer 105.
6b is laminated. In the charge generation layer 106 of the light-emitting element illustrated in FIG. 4B, the electron-transfer complex formed by the transfer of electrons between the hole-transporting material and the acceptor material includes a hole-transporting material. It is formed only at the interface between the layer 106a and the layer 106b containing an acceptor substance. Therefore, the light-emitting element illustrated in FIG. 4B is preferable because a visible light absorption band is hardly formed even when the thickness of the charge generation layer 106 is increased.

Note that as the hole-transporting substance contained in the charge generation layer 106, various organic compounds such as aromatic amine compounds, carbazole derivatives, aromatic hydrocarbons, and high molecular compounds (oligomers, dendrimers, polymers, and the like) are used. Can do.

Specific examples of the aromatic amine compound include NPB (abbreviation), TPD (abbreviation), and TCT.
A (abbreviation), TDATA (abbreviation), MTDATA (abbreviation), DTDPPA (abbreviation), DP
AB (abbreviation), DNTPD (abbreviation), DPA3B (abbreviation), and the like can be given.

Specific examples of the carbazole derivative include PCzPCA1 (abbreviation), PCzPCA2
(Abbreviation), PCzPCN1 (abbreviation), and the like. Others, CBP (abbreviation), TCPB
(Abbreviation), CzPA (abbreviation), 1,4-bis [4- (N-carbazolyl) phenyl] -2
3,5,6-tetraphenylbenzene and the like.

Specific examples of the aromatic hydrocarbon include t-BuDNA (abbreviation), DPPA (abbreviation),
t-BuDBA (abbreviation), DNA (abbreviation), DPAnth (abbreviation), t-BuAnth (
Abbreviation), DMNA (abbreviation), 9,10-bis [2- (1-naphthyl) phenyl] -2-t
ert-butylanthracene, 9,10-bis [2- (1-naphthyl) phenyl] anthracene, 2,3,6,7-tetramethyl-9,10-di (1-naphthyl) anthracene,
2,3,6,7-tetramethyl-9,10-di (2-naphthyl) anthracene, 9,9 ′
-Bianthryl, 10,10'-diphenyl-9,9'-bianthryl, 10,10'-
Bis (2-phenylphenyl) -9,9′-bianthryl, 10,10′-bis [(2,
3,4,5,6-pentaphenyl) phenyl] -9,9′-bianthryl, anthracene, tetracene, rubrene, perylene, 2,5,8,11-tetra (tert-butyl) perylene and the like. The aromatic hydrocarbon may have a vinyl skeleton.
Examples of the aromatic hydrocarbon having a vinyl group include DPVBi (abbreviation) and DPVP.
A (abbreviation) etc. are mentioned.

In addition, a high molecular compound such as PVK (abbreviation) or PVTPA (abbreviation) can be used as the hole-transporting substance.

Furthermore, the hole transporting material is preferably a material having a hole mobility of 1 × 10 ⁻⁶ cm ² / Vs or higher. However, if the substance has a higher hole transportability than electrons,
Other than these can also be applied.

In addition, when the aromatic hydrocarbon is formed into a film by a vapor deposition method,
From the viewpoint of film quality after film formation, the number of carbon atoms forming the condensed ring is more preferably 14 to 42.

Examples of the acceptor substance included in the charge generation layer 106 include 7,7,8,8-tetracyano-2,3,5,6-tetrafluoroquinodimethane (abbreviation: F ₄ -TCNQ), chloranil, and the like. Can do. In addition, as the acceptor substance, a transition metal oxide can be given. In addition, oxides of metals belonging to Groups 4 to 8 in the periodic table can be given. Specifically, vanadium oxide, niobium oxide, tantalum oxide, chromium oxide, molybdenum oxide, tungsten oxide, manganese oxide, and rhenium oxide are preferable because of their high electron accepting properties. Further, the acceptor substance is more preferably molybdenum oxide. Note that molybdenum oxide has a feature of low hygroscopicity.

Note that the contents described in this embodiment can be combined as appropriate with any of the contents described in the other embodiments.

(Embodiment 5)
In this embodiment, an example of the light-emitting element described in Embodiment 1 will be described. In particular,
An example of the light-emitting element described in Embodiment 1 will be described with reference to FIGS.

In the light-emitting element described in this embodiment, the first EL layer 103 and the second EL layer 107 including a light-emitting region are sandwiched between a pair of electrodes (anode 101 and cathode 102) as shown in FIG. It is. In addition, the light-emitting element includes, from the anode 101 side, an electron injection buffer layer 104 in contact with the first EL layer 103, an electron relay layer 105 in contact with the electron injection buffer layer 104, an electron relay layer 105, and a second EL layer. The charge generation layer 106 is in contact with 107.

The structures and materials described in Embodiments 1 to 4 can be used for the anode 101, the cathode 102, the electron injection buffer layer 104, the electron relay layer 105, and the charge generation layer 106 in this embodiment. Therefore, the description of Embodiments 1 to 4 is used here.

In this embodiment, the first EL layer 103 includes a first light-emitting layer 103a that exhibits a light emission spectrum having a peak in the blue to blue-green wavelength region, and a light emission spectrum that has a peak in the yellow to orange wavelength region. A second light-emitting layer 103b. In addition, the second EL layer 107
Is a third light-emitting layer 107 showing an emission spectrum having a peak in the blue-green to green wavelength region.
a and the fourth light emitting layer 107 showing an emission spectrum having a peak in the orange to red wavelength region.
b. Note that the first light-emitting layer 103a and the second light-emitting layer 103b may be stacked in reverse order. Further, the third light emitting layer 107a and the fourth light emitting layer 107b may be stacked in reverse order.

When a bias is applied to such a light emitting element with the anode 101 side being positive and the cathode 102 side being negative, the holes injected from the anode 101 and the charge generation layer 106 are generated.
Electrons injected through the electron relay layer 105 and the electron injection buffer layer 104 are recombined in the first light emitting layer 103a or the second light emitting layer 103b. Thereby, the 1st light emission 330 is obtained. Further, electrons injected from the cathode 102 and holes generated and injected in the charge generation layer 106 are recombined in the third light-emitting layer 107a or the fourth light-emitting layer 107b. Thereby, the second light emission 340 is obtained.

FIG. 5B schematically shows emission spectra of the first emission 330 and the second emission 340. The first light emission 330 includes a first light emitting layer 103a and a second light emitting layer 103b.
The combined emission from both. Therefore, blue to blue-green wavelength region and yellow to
An emission spectrum having peaks in both of the orange wavelength regions is shown. That is, the first EL layer 103 emits light of a two-wavelength type white color or a color close to white. The second light emission 340 is a combination of light emission from both the third light emitting layer 107a and the fourth light emitting layer 107b. Therefore, an emission spectrum having peaks in both a blue-green to green wavelength region and an orange to red wavelength region is shown. That is, the second EL layer 107 includes the first EL layer 1
It emits light of a two-wavelength type white or a color close to white different from 03.

Therefore, the light-emitting element in this embodiment mode includes the first light emission 330 and the second light emission 34.
As a result of overlapping 0, light emission covering a blue to blue-green wavelength region, a blue-green to green wavelength region, a yellow to orange wavelength region, and an orange to red wavelength region is obtained.

For example, even if the light emission luminance of the first light-emitting layer 103a (showing a light emission spectrum having a peak in the blue to blue-green wavelength region) changes with time or due to current density, the first light-emitting layer with respect to the entire light emission spectrum. Since the contribution of 103a is about 1/4, the chromaticity shift can be relatively small.

In the above description, the first EL layer 103 has an emission spectrum having peaks in both the blue to blue-green wavelength region and the yellow to orange wavelength region, and the second EL layer 107 has a blue-green to The case where an emission spectrum having peaks in both the green wavelength range and the orange to red wavelength range has been described as an example, but the opposite relationship may be used. That is, the second EL layer 107 exhibits an emission spectrum having peaks in both the blue to blue-green wavelength region and the yellow to orange wavelength region, and the first EL layer 103 has a blue-green to green wavelength region and orange color. -The structure which shows the emission spectrum which has a peak in both of a red wavelength range may be sufficient. The first E
Each of the L layer 103 and the second EL layer 107 may have a stacked structure in which layers other than the light emitting layer are formed.

Next, substances that can be used as a light-emitting organic compound for the EL layer of the light-emitting element described in this embodiment will be described. Note that substances that can be used for the light-emitting element described in this embodiment are not limited thereto.

Blue to blue-green light emission can be obtained, for example, by using perylene, TBP (abbreviation), 9,10-diphenylanthracene or the like as a guest material and dispersing it in a suitable host material. Alternatively, it can be obtained from a styrylarylene derivative such as DPVBi (abbreviation) or an anthracene derivative such as DNA (abbreviation) and t-BuDNA (abbreviation). A polymer such as poly (9,9-dioctylfluorene) may also be used. As a blue light emitting guest material, YGA2S (abbreviation) and N, N′-diphenyl-N, N′-bis (9-phenyl-9H-carbazol-3-yl) stilbene-4,4′-diamine (
Abbreviations: styrylamine derivatives such as PCA2S). In particular, YGA2S (abbreviation) has a peak around 450 nm and is preferable. The host material is preferably an anthracene derivative, and t-BuDNA (abbreviation) and CzPA (abbreviation) are preferable. In particular, CzPA (abbreviation) is preferable because it is electrochemically stable.

Blue-green to green light emission is, for example, coumarin dyes such as coumarin 30 and coumarin 6, F
Irpic (abbreviation), Ir (ppy) ₂ (acac) (abbreviation), or the like is used as a guest material and dispersed in an appropriate host material. In addition, BAlq (abbreviation), Z
n (BTZ) ₂ (abbreviation), bis (2-methyl-8-quinolinolato) chlorogallium (Ga
It can also be obtained from metal complexes such as (mq) ₂ Cl). A polymer such as poly (p-phenylene vinylene) may also be used. In addition, the above-mentioned perylene and TBP (abbreviation) are 5w
It can also be obtained by dispersing in a suitable host material at a high concentration of t% or more. As a guest material for the blue-green to green light-emitting layer, an anthracene derivative is preferable because highly efficient light emission can be obtained. For example, highly efficient blue-green light emission can be obtained by using DPABPA (abbreviation). An anthracene derivative having an amino group substituted at the 2-position is preferable because highly efficient green light emission can be obtained, and 2PCAPA (abbreviation) is particularly preferable because of its long life. As these host materials, anthracene derivatives are preferable, and CzPA (abbreviation) described above is preferable because it is electrochemically stable. When a light-emitting element having two peaks in the blue to green wavelength region is manufactured by combining green light emission and blue light emission, an electron-transporting anthracene derivative such as CzPA (abbreviation) is used as a host of the blue light-emitting layer. It is preferable to use an aromatic amine compound having a hole transport property such as NPB (abbreviation) as the host of the green light emitting layer because light emission is obtained at the interface between the blue light emitting layer and the green light emitting layer. That is, in this case, 2PCAPA (
As a host of a green light emitting material such as (abbreviation), an aromatic amine compound such as NPB (abbreviation) is preferable.

The yellow to orange light emission is, for example, rubrene, DCM1 (abbreviation), DCM2 (abbreviation), bis [2- (2-thienyl) pyridinato] acetylacetonatoiridium (Ir (thp) _2.
(Acac)), bis (2-phenylquinolinato) acetylacetonatoiridium (Ir
(Pq) ₂ (acac)) or the like is used as a guest material and dispersed in a suitable host material. In particular, tetracene derivatives such as rubrene as guest materials
It is preferable because it is highly efficient and chemically stable. As a host material in this case, NPB (
An aromatic amine compound such as (abbreviation) is preferable. As another host material, a metal complex such as bis (8-quinolinolato) zinc (abbreviation: Znq ₂ ) or bis [2-cinnamoyl-8-quinolinolato] zinc (abbreviation: Znsq ₂ ) can be used. Further, a polymer such as poly (2,5-dialkoxy-1,4-phenylene vinylene) may be used.

For example, BisDCM (abbreviation), 4- (dicyanomethylene) -2 is emitted from orange to red.
, 6-Bis [2- (julolidin-9-yl) ethynyl] -4H-pyran DCM1), 2
-{2-methyl-6- [2- (2,3,6,7-tetrahydro-1H, 5H-benzo [i
j] quinolinidin-9-yl) ethenyl] -4H-pyran-4-ylidene} propanedinitrile (abbreviation: DCM2), Ir (thp) ₂ (acac) (abbreviation) and the like as a guest material It is obtained by dispersing in Znq ₂ (abbreviation) or Zn
It can also be obtained from a metal complex such as sq ₂ (abbreviation). A polymer such as poly (3-alkylthiophene) may also be used. As a guest material exhibiting red light emission, BisDC
4H-pyran derivatives such as M (abbreviation), DCM2 (abbreviation), DCJTI (abbreviation), and BisDCJTM (abbreviation) have high efficiency and are preferable. In particular, DCJTI (abbreviation), BisD
CJTM (abbreviation) is preferable because it has an emission peak near 620 nm.

Note that in the above structure, a suitable host material may be any material that emits light with a shorter wavelength or has a larger energy gap than the light-emitting organic compound. Specifically, a hole transport material or an electron transport material typified by the example shown in Embodiment Mode 1 can be selected as appropriate. Alternatively, CBP (abbreviation), TCTA (abbreviation), TCPB (abbreviation), or the like may be used.

In the light-emitting element described in this embodiment mode, the emission spectrum of the first EL layer and the emission spectrum of the second EL layer are overlapped. As a result, the blue to blue-green wavelength region, the blue-green to green wavelength region, yellow White light emission covering a wide range of the orange wavelength region and the orange to red wavelength region can be obtained.

In addition, by adjusting the film thickness of each stack and intentionally causing light to interfere slightly, the occurrence of protruding sharp peaks can be suppressed and a trapezoidal emission spectrum can be obtained, resulting in natural light having a continuous spectrum. It may be close. Moreover, the peak position of the emission spectrum can also be changed by adjusting the film thickness of each layer and intentionally causing slight interference of light. It is possible to obtain white light emission having a more trapezoidal emission spectrum by adjusting the film thickness of each stack so that the plurality of peak intensities appearing in the emission spectrum are substantially the same, and further reducing the interval between the peaks. it can.

Note that in this embodiment mode, an EL layer in which white light emission is obtained by superimposing luminescent colors that are complementary to each other in each of a plurality of light emitting layers is shown. Hereinafter, a specific configuration of an EL layer that emits white light according to a complementary color relationship will be described.

The EL layer provided in the light-emitting element described in this embodiment includes, for example, a hole-transporting substance and a first layer.
A first layer containing a light emitting material, a second layer containing a hole transporting material and a second light emitting material, and a third layer containing an electron transporting material and a second light emitting material. It can be set as the structure laminated | stacked in order from 101. FIG.

In the EL layer of the light-emitting element described in this embodiment, in order to obtain white light emission, both the first light-emitting substance and the second light-emitting substance need to emit light. Therefore, in order to adjust the carrier transportability in the EL layer, it is preferable that both the hole transporting substance and the electron transporting substance are host materials. Note that as the hole-transporting substance or the electron-transporting substance that can be used for the EL layer, the substances exemplified in Embodiment 1 can be used as appropriate.

In addition, as the first light-emitting substance and the second light-emitting substance, substances whose emission colors have a complementary color relationship can be selected and used. Examples of complementary colors include blue and yellow or blue green and red. The substance that emits blue, yellow, blue-green, or red light may be appropriately selected from, for example, the light-emitting substances listed above. Note that, by setting the emission wavelength of the second luminescent material to be shorter than the emission wavelength of the first luminescent material, a part of the excitation energy of the second luminescent material is transferred to the first luminescent material, The first light-emitting substance can emit light. Therefore, in the light-emitting element of this embodiment mode, the emission peak wavelength of the second light-emitting substance is preferably shorter than the emission peak wavelength of the first light-emitting substance.

In the structure of the light-emitting element described in this embodiment mode, both light emission from the first light-emitting substance and light emission from the second light-emitting substance can be obtained, and the light emission colors of the first light-emitting substance and the second light-emitting substance can be obtained. Since these are complementary colors, white light emission can be obtained. In addition, with the structure of the light-emitting element described in this embodiment, a light-emitting element with a long lifetime can be obtained.

Note that the contents described in this embodiment can be combined as appropriate with any of the contents described in the other embodiments.

(Embodiment 6)
In this embodiment, one embodiment of a light-emitting device including the light-emitting element described in any of Embodiments 1 to 5 will be described with reference to FIGS. FIG. 6 is a cross-sectional view of the light emitting device.

In FIG. 6, the light-emitting device of this embodiment includes a substrate 10, a light-emitting element 12 and a transistor 11 provided on the substrate 10. The light-emitting element 12 includes a layer 15 containing an organic compound between the first electrode 13 and the second electrode 14. The layer 15 containing an organic compound has n (n is 2
(M is a natural number) layers, and m (m is a natural number, 1 ≦ m ≦ n−1) th EL layer (
Between the (m + 1) th EL layer, the electron injection buffer layer in contact with the mth EL layer, the electron relay layer in contact with the electron injection buffer layer, and the charge generation in contact with the electron relay layer and the (m + 1) th EL layer And having a layer. Each EL layer is provided with at least a light emitting layer, and in addition to the light emitting layer, a hole injection layer, a hole transport layer, an electron transport layer, or an electron injection layer is appropriately provided. That is, the light-emitting element 12 is the light-emitting element described in any of Embodiments 1 to 5. The drain region of the transistor 11 and the first electrode 13 are connected to the first interlayer insulating film 16.
They are electrically connected by wiring 17 penetrating through a, 16b and 16c. The light emitting element 12 is separated from another light emitting element provided adjacent thereto by a partition wall layer 18.

Note that the transistor 11 illustrated in FIGS. 6A and 6B is a top-gate transistor in which a gate electrode is provided on the side opposite to a substrate with a semiconductor layer as a center. However, the structure of the transistor 11 is not particularly limited, and may be, for example, a bottom gate type. Further, in the case of the bottom gate type, a semiconductor layer that forms a channel may have a protective film (channel protection type), or a part of the semiconductor layer that forms the channel may be concave. A thing (channel etch type) may be used.

In addition, examples of the material of the semiconductor layer included in the transistor 11 include group 14 elements in the periodic table of elements such as silicon (Si) and germanium (Ge), compounds such as gallium arsenide and indium phosphide, and zinc oxide and tin oxide. Any material may be used as long as it is a substance exhibiting semiconductor characteristics, such as an oxide. In addition, the semiconductor layer may have a crystalline structure or an amorphous structure.

Furthermore, oxides (oxide semiconductors) that exhibit semiconductor characteristics include indium, gallium,
A complex oxide of an element selected from aluminum, zinc and tin can be used. For example, zinc oxide (ZnO), indium oxide containing zinc oxide (IZO: Indium Zin)
Examples thereof include c Oxide) and oxides (IGZO: Indium Gallium Zinc Oxide) made of indium oxide, gallium oxide, and zinc oxide. As a specific example of the semiconductor layer having a crystalline structure, a single crystal semiconductor, a polycrystalline semiconductor, or a microcrystalline semiconductor can be given. These may be formed by laser crystallization, or may be formed by crystallization by a solid phase growth method using nickel or the like, for example.

Note that a microcrystalline semiconductor in this specification belongs to a metastable state which is intermediate between an amorphous state and a single crystal state in consideration of Gibbs free energy. That is, it is a semiconductor having a third state that is stable in terms of free energy, and has a short-range order and lattice distortion. Microcrystalline silicon, which is a typical example of a microcrystalline semiconductor, has a Raman spectrum indicating single crystal silicon.
It is shifted to a lower wave number side than 20 cm ⁻¹ . That is, 520c indicating single crystal silicon
There is a Raman spectrum peak of microcrystalline silicon between m ⁻¹ and 480 cm ⁻¹ indicating amorphous silicon. In addition, at least 1 atomic% or more of hydrogen or halogen is contained to terminate dangling bonds (dangling bonds). Further, by adding a rare gas element such as helium, argon, krypton, or neon to further promote lattice distortion, stability can be improved and a good microcrystalline semiconductor layer can be obtained.

Note that in the case where the semiconductor layer is formed of an amorphous material, for example, amorphous silicon, the transistor 11 and other transistors (transistors constituting a circuit for driving a light-emitting element) are all N-channel transistors. A light-emitting device having a configured circuit is preferable. This is because the manufacturing process of the light-emitting device is simplified. In addition, zinc oxide (ZnO), indium oxide containing zinc oxide (IZO), oxide made of indium oxide, gallium oxide, and zinc oxide (IGZO), and the like are N-type semiconductors. Therefore, a transistor in which these oxides are used for a semiconductor layer is an n-channel transistor. Note that the light-emitting device may be a light-emitting device including a circuit including one of N-channel or P-channel transistors, or may be a light-emitting device including a circuit including both transistors.

Further, the first interlayer insulating films 16a to 16c may be a multilayer as shown in FIGS. 6A and 6C, or may be a single layer. The first interlayer insulating film 16a is made of an inorganic material such as silicon oxide or silicon nitride, and the first interlayer insulating film 16b is made of acrylic, siloxane (silicon (Si
) And oxygen (O) are combined to form a skeletal structure, and the substituent contains at least hydrogen.
It is made of a material having self-flatness such as silicon oxide that can be coated and formed. Further, the first interlayer insulating film 16c is a silicon nitride film containing argon (Ar). In addition, there is no limitation in particular about the substance which comprises each layer, You may use things other than what was described here. Also,
You may further combine the layer which consists of substances other than these. As described above, the first interlayer insulating films 16a to 16c may be formed using both an inorganic material or an organic material, or may be formed using either an inorganic film or an organic film.

The partition layer 18 preferably has a shape in which the radius of curvature continuously changes at the edge portion. The partition layer 18 can be formed using acrylic, siloxane, silicon oxide, or the like. In addition, the partition layer 18 may be formed by either one of the inorganic film and the organic film, or may be formed by using both.

In FIGS. 6A and 6C, only the first interlayer insulating films 16a to 16c are transistors 1.
1 and the light-emitting element 12 as shown in FIG. 6B. In addition to the first interlayer insulating films 16a to 16c, the second interlayer insulating films 19a and 19b are provided. There may be.
In the light-emitting device shown in FIG. 6B, the first electrode 13 is formed of the second interlayer insulating films 19a and 19
It penetrates b and is electrically connected to the wiring 17.

Similar to the first interlayer insulating films 16a to 16c, the second interlayer insulating films 19a and 19b may be a multilayer or a single layer. The second interlayer insulating film 19a is made of a material having self-planarity such as acrylic, siloxane, or silicon oxide that can be coated. Further, the second interlayer insulating film 19b is a silicon nitride film containing argon (Ar). In addition, there is no limitation in particular about the substance which comprises each layer, You may use things other than what was described here. Moreover, you may further combine the layer which consists of substances other than these. Thus, the second interlayer insulating films 19a and 19b
May be formed using either an inorganic material or an organic material, or may be formed using either an inorganic film or an organic film.

In the light-emitting element 12, when each of the first electrode 13 and the second electrode 14 is formed using a light-transmitting substance, the first electrode 13 and the second electrode 14 are represented by the white arrows in FIG. 1 electrode 1
Light emission can be extracted from both the 3 side and the second electrode 14 side. Also, the second electrode 14
In the case where only the light-transmitting substance is used, light emission can be extracted only from the second electrode 14 side as represented by a white arrow in FIG. In this case, it is preferable that the first electrode 13 is made of a highly reflective material or a film (reflective film) made of a highly reflective material is provided below the first electrode 13. In addition, in the case where only the first electrode 13 is formed using a light-transmitting substance, light emission is extracted only from the first electrode 13 side as represented by a white arrow in FIG. be able to. In this case, it is preferable that the second electrode 14 is made of a highly reflective material, or a reflective film is provided above the second electrode 14.

The light-emitting element 12 is formed by laminating a layer 15 containing an organic compound so as to operate when a voltage is applied so that the potential of the second electrode 14 is higher than the potential of the first electrode 13. The layer 15 containing an organic compound may be stacked so as to operate when a voltage is applied so that the potential of the second electrode 14 is lower than the potential of the first electrode 13. May be. In the former case, the first electrode 13 is an anode, the second electrode 14 is a cathode, and the transistor 11 is an N-channel transistor. In the latter case, the first electrode 13 is a cathode, the second electrode 14 is an anode, and the transistor 11 is a P-channel transistor.

As described above, in this embodiment mode, an active matrix light-emitting device in which driving of a light-emitting element is controlled by a transistor has been described. In addition, a driving element such as a transistor is provided over the same substrate as the light-emitting element. Alternatively, a passive matrix light-emitting device that drives the light-emitting element may be used. FIG. 7A is a perspective view of a passive matrix light-emitting device manufactured using the light-emitting element described in any of Embodiments 1 to 5. In addition, FIG.
) Is a cross-sectional view taken along broken line XY in FIG.

In FIG. 7, a light emitting element 955 is provided between the electrode 952 and the electrode 956 on the substrate 951. A light-emitting element 955 is the light-emitting element described in any of Embodiments 1 to 5. Electrode 95
2 is covered with an insulating layer 953. A partition layer 954 is provided over the insulating layer 953. It is preferable that the side wall of the partition wall layer 954 has an inclination such that the distance between one side wall and the other side wall becomes narrower as it approaches the substrate surface. That is, the partition layer 954
The cross section in the short side direction is trapezoidal, and the bottom side (facing the same direction as the surface direction of the insulating layer 953,
The side that is in contact with the insulating layer 953 is shorter than the upper side (the side that is in the same direction as the surface direction of the insulating layer 953 and is not in contact with the insulating layer 953). In this manner, by providing the partition layer 954, defects in the light-emitting element due to static electricity or the like can be prevented. In addition, by applying any of the light-emitting elements described in Embodiments 1 to 5 to a passive matrix light-emitting device, a light-emitting device with low power consumption can be obtained.

The light-emitting device described in this embodiment is a light-emitting device that can emit light with high luminance and can be driven at a low voltage because the light-emitting element shown as an example in Embodiments 1 to 5 is used. The light-emitting device is a light-emitting device with low power consumption.

(Embodiment 7)
In this embodiment, electronic devices including the light-emitting device shown as an example in Embodiment 6 will be described.

As an electronic device of this embodiment, a television, a video camera, a digital camera, a goggle type display, a navigation system, a computer, a game device, a portable information terminal (mobile computer, cellular phone, portable game machine, electronic book, or the like), An image reproducing apparatus provided with a recording medium (specifically, Digital Versatile Disc (DV
D) and the like, and a device provided with a display unit that can display the image. Specific examples of these electronic devices are shown in FIGS.

FIG. 8A illustrates an example of the portable information terminal device 800. Portable information terminal device 800
Has a built-in computer and can perform various data processing. As such a portable information terminal device 800, a PDA (Personal Digital As
(sistance).

The portable information terminal device 800 includes two housings, a housing 801 and a housing 803. The housing 801 and the housing 803 are connected to each other by a connecting portion 807 so as to be foldable. Case 8
01 includes a display portion 802, and the housing 803 includes a keyboard 805. Of course, the configuration of the portable information terminal device 800 is not limited to the above-described configuration, and can be a configuration in which other accessory equipment is appropriately provided. The display portion 802 is formed by arranging light-emitting elements similar to those described in Embodiments 1 to 5 in a matrix. The light emitting element is
It is characterized by high brightness, low driving voltage, and low power consumption. Since the display portion 802 including the light-emitting elements has similar features, this portable information terminal device has low power consumption.

FIG. 8B illustrates an example of a digital video camera 810 according to this embodiment.
In the digital video camera 810, a display portion 812 is incorporated in a housing 811 and various operation portions are provided. The configuration of the digital video camera 810 is not particularly limited,
In addition, it can be set as the structure in which the attached equipment was provided suitably.

In the digital video camera 810, the display portion 812 includes light-emitting elements similar to those described in Embodiments 1 to 5 arranged in a matrix. The light-emitting element is characterized by low driving voltage, high luminance, and low power consumption. Since the display portion 812 including the light-emitting elements has similar features, the digital video camera 810 achieves low power consumption.

FIG. 8C illustrates an example of a mobile phone 820 according to this embodiment. The mobile phone 820 includes two housings, a housing 821 and a housing 822, and is connected to each other by a connecting portion 823 so as to be foldable. A display portion 824 is incorporated in the housing 822, and operation keys 825 are provided in the housing 821. Note that there is no particular limitation on the structure of the mobile phone 820, and any other attached facilities can be provided as appropriate.

In the cellular phone 820, the display portion 824 includes light-emitting elements similar to those described in Embodiments 1 to 5 arranged in a matrix. The light-emitting element is characterized by high brightness, low driving voltage, and low power consumption. Since the display portion 824 including the light-emitting elements has similar features, low power consumption is achieved in this mobile phone. Alternatively, the light-emitting element described in the above embodiment may be used as a backlight of a display provided in a mobile phone or the like.

FIG. 8D illustrates an example of a portable computer 830. Computer 83
0 includes a housing 831 and a housing 834 which are connected to each other so as to be openable and closable. A display portion 832 is incorporated in the housing 831, and the housing 834 includes a keyboard 833 and the like. Note that there is no particular limitation on the configuration of the computer 830, and other auxiliary facilities can be provided as appropriate.

In the computer 830, the display portion 832 includes light-emitting elements similar to those described in Embodiment Modes 1 to 5, arranged in a matrix. The light-emitting element is characterized by high brightness, low driving voltage, and low power consumption. Since the display portion 832 including the light-emitting elements has similar features, this computer achieves low power consumption.

FIG. 8E illustrates an example of the television 840. In the television 840, a display portion 842 is incorporated in a housing 841. An image can be displayed on the display portion 842. Here, a configuration in which the housing 841 is supported by the stand 843 is shown.

The television 840 can be operated with an operation switch (not shown) provided in the housing 841 or a separate remote controller 850. Channels and volume can be operated with the operation keys 851 provided in the remote controller 850, and an image displayed on the display portion 842 can be operated. In addition, the remote controller 850 is connected to the remote controller 85.
A display portion 852 that displays information output from 0 may be provided.

Note that the television 840 is provided with a receiver, a modem, and the like. General TV broadcasts can be received by a receiver, and connected to a wired or wireless communication network via a modem, so that it can be unidirectional (sender to receiver) or bidirectional (sender and receiver). It is also possible to perform information communication between each other or between recipients).

In the television 840, at least one of the display portion 842 and the display portion 852 is formed by arranging light-emitting elements similar to those described in Embodiments 1 to 5 in a matrix. The light-emitting element is characterized by high brightness, low driving voltage, and low power consumption. A display portion including the light-emitting element has similar characteristics.

As described above, the applicable range of the light-emitting device is so wide that the light-emitting device can be applied to electronic devices in various fields. In addition, by using the light-emitting device including the light-emitting element described in any of Embodiments 1 to 5, an electronic device that emits light with high luminance and has a display portion with low power consumption can be provided. .

(Embodiment 8)
In this embodiment, an illumination device including the light-emitting device shown as an example in Embodiment 6 will be described.

FIG. 9 is a diagram illustrating an indoor lighting device. The tabletop lighting device 900 shown in FIG.
01. The light-emitting element described in any of Embodiments 1 to 5 is applied to the lighting portion 901. The light-emitting element is characterized by high brightness, low driving voltage, and low power consumption. Since the lighting unit 901 including the light-emitting elements has similar characteristics, the desktop lighting device 900 achieves low power consumption. Further, since the light-emitting element can have a large area, the light-emitting element can also be used as the lighting portion 911 of the ceiling lighting device 910. further,
Since the light-emitting element can be flexible, the illumination unit 9 of the roll-type illumination device 920 is used.
It is also possible to apply to 21.

FIG. 10A illustrates a traffic light. The traffic light 1000 includes a blue illumination unit 1001, a yellow illumination unit 1002, and a red illumination unit 1003. The traffic light 1000 includes the light-emitting elements described in Embodiments 1 to 5 in at least one of the lighting units corresponding to blue, yellow, and red. The light-emitting element is characterized by high brightness, low driving voltage, and low power consumption. Since each illumination part corresponding to blue, yellow, and red composed of the light emitting elements has the same characteristics, this traffic light is designed to reduce power consumption.

FIG. 10B is a diagram showing an escape exit guide light. The evacuation exit guide light 1010 includes an illumination unit,
A fluorescent plate provided with a fluorescent portion can be combined. Moreover, it can also comprise combining the illumination part which light-emits a specific color, and the light-shielding plate provided with the transmission part of a shape like drawing. The light-emitting element described in any of Embodiments 1 to 5 is applied to the illumination portion of the escape exit guide light 1010. The light-emitting element is characterized by high brightness, low driving voltage, and low power consumption. Since the illumination unit composed of the light-emitting elements has the same characteristics, the emergency exit guide light has low power consumption.

FIG. 10C illustrates a streetlight. The streetlight includes a support body 1021 and an illumination unit 1022. The light-emitting element described in any of Embodiments 1 to 5 is applied to the lighting portion 1022. The light-emitting element is characterized by high brightness, low driving voltage, and low power consumption. Since the lighting unit composed of the light-emitting elements has the same characteristics, this street lamp is designed to reduce power consumption.

As shown in FIG. 10C, a power supply voltage can be supplied to the streetlight through the power transmission line 1024 of the utility pole 1023. However, the method of supplying the power supply voltage is not limited to this. For example, a photoelectric conversion device can be provided on the support 1021, and a voltage obtained by the photoelectric conversion device can be used as a power supply voltage.

FIGS. 10D and 10E illustrate an example in which the lighting device is applied to portable lighting. FIG. 10D is a diagram illustrating a configuration of a wearable light, and FIG. 10E is a diagram illustrating a configuration of a handheld light.

FIG. 10D is a diagram showing a mounting light. The mounting light includes a mounting portion 1031,
And an illumination unit 1032. The illumination unit 1032 is fixed to the mounting unit 1031.
The light-emitting element described in any of Embodiments 1 to 5 is applied to the lighting portion 1032. The light-emitting element is characterized by high brightness, low driving voltage, and low power consumption. Since the illuminating section composed of the light emitting elements has the same characteristics, the power consumption of the mounting light is reduced.

Note that the structure of the wearable light shown in FIG. 10D is not limited, and for example, the wearing portion 1031 is a ring-shaped flat cord or rubber cord belt, the lighting portion 1032 is fixed to the belt, and the belt is attached to the head. It can also be set as the structure wound around a part directly.

FIG. 10E illustrates a handheld light. The handheld light includes a housing 1041, a lighting unit 1042, and a switch 1043. The lighting unit 1042 includes the first embodiment.
The light emitting elements shown in FIGS. 5 to 5 are applied. The light-emitting element has high brightness and low driving voltage,
It has the feature of low power consumption. Since the lighting unit 1042 including the light-emitting elements has similar characteristics, the power consumption of the handheld light is reduced.

Note that the switch 1043 has a function of controlling light emission or non-light emission of the lighting portion 1042. In addition, the switch 1043 can be provided with a function of adjusting the luminance of the lighting unit 1042 during light emission.

As described above, the applicable range of the light-emitting device is so wide that the light-emitting device can be applied to lighting devices in various fields. In addition, by using the lighting device including the light-emitting element described in any of Embodiments 1 to 5, it is possible to provide a lighting device that emits light with high luminance and includes a display portion with low power consumption. .

In this example, a light-emitting element which is one embodiment of the present invention will be described with reference to FIGS. The chemical formulas of the substances used in this example and Examples 2 and 3 are shown below.

  A method for manufacturing the light-emitting elements 1 to 4 and the comparative light-emitting element 5 of this example will be described below.

First, the light-emitting element 1 will be described (see FIG. 11A). A first electrode 2101 was formed over the substrate 2100 by depositing indium tin oxide containing silicon oxide by a sputtering method. The film thickness was 110 nm and the electrode area was 2 mm × 2 mm.

Next, the substrate 2100 on which the first electrode 2101 is formed is fixed to a substrate holder provided in the vacuum evaporation apparatus so that the surface on which the first electrode is formed is downward, and is approximately 10 ⁻⁴ Pa. And the organic compound and the inorganic compound are deposited on the first electrode 2101 by co-evaporation of NPB (abbreviation) which is a hole transporting substance and molybdenum oxide (VI) which is an acceptor substance. A first charge generation layer 2103a containing a composite material obtained by combining the above was formed. The film thickness was 50 nm, and the ratio of NPB (abbreviation) to molybdenum oxide (VI) was adjusted to 4: 1 (= NPB: molybdenum oxide) by mass ratio. Note that the co-evaporation method is an evaporation method in which evaporation is performed simultaneously from a plurality of evaporation sources in one processing chamber.

Next, NPB (abbreviation) was formed to a thickness of 10 nm over the first charge generation layer 2103a by an evaporation method using resistance heating, so that a hole transport layer 2103b was formed.

Further, CzPA (abbreviation) and 2PCAPA (abbreviation) were co-evaporated to form a light-emitting layer 2103c having a thickness of 30 nm on the hole-transport layer 2103b. Where CzPA
The mass ratio of (abbreviation) and 2PCAPA (abbreviation) is 1: 0.05 (= CzPA: 2PCAPA
). Note that CzPA (abbreviation) is an electron transporting substance, and 2PCAPA (abbreviation) as a guest material is a substance that emits green light.

Thereafter, Aln (abbreviation) is added to 10 n on the light emitting layer 2103c by using a resistance heating vapor deposition method.
An electron transport layer 2103d was formed to have a thickness of m. Thus, the first charge generation layer 2103a, the hole transport layer 2103b, the light emitting layer 2103c, and the electron transport layer 21
A first EL layer 2103 containing 03d was formed.

Next, BPhen (abbreviation) and lithium (Li) were co-evaporated to form an electron injection buffer layer 2104 having a thickness of 20 nm on the electron transport layer 2103d. Here, the mass ratio of BPhen (abbreviation) to lithium (Li) is 1: 0.02 (= BPhen: L
i) was adjusted.

Next, PTCBI (abbreviation) and lithium (Li) were co-evaporated to form an electron relay layer 2105 having a thickness of 3 nm on the electron injection buffer layer 2104. Here, the mass ratio of PTCBI (abbreviation) to lithium (Li) is 1: 0.02 (= PTCBI: L
i) was adjusted. Note that the LUMO level of PTCBI (abbreviation) is about −4.0 eV from the result of cyclic voltammetry (CV) measurement.

Next, a second charge generation layer 2106 is formed on the electron relay layer 2105 by co-evaporation of NPB (abbreviation) which is a hole-transporting substance and molybdenum oxide (VI) which is an acceptor substance. did. The film thickness is 60 nm, and NPB (abbreviation) and molybdenum oxide (VI
) Was adjusted so that the mass ratio was 4: 1 (= NPB: molybdenum oxide).

Next, a second EL layer 2107 was formed over the second charge generation layer 2106. The manufacturing method is as follows. First, NPB (on the second charge generation layer 2106 is formed by vapor deposition using resistance heating.
(Abbreviation) was formed to a thickness of 10 nm to form a hole transport layer 2107a.

Thereafter, CzPA (abbreviation) and 2PCAPA (abbreviation) were co-evaporated to form a light-emitting layer 2107b having a thickness of 30 nm on the hole-transport layer 2107a. Where CzPA
The mass ratio of (abbreviation) and 2PCAPA (abbreviation) is 1: 0.05 (= CzPA: 2PCAPA
). That is, the light emitting layer 2107 b included in the second EL layer 2107 has the same structure as the light emitting layer 2103 c included in the first EL layer 2103.

Next, Alq (abbreviation) is formed to a thickness of 10 nm over the light-emitting layer 2107b, and then BPhen (
An electron transport layer 2107c was formed by depositing 20 nm by abbreviation. An electron injection layer 2107d was formed on the electron transport layer 2107c by depositing lithium fluoride (LiF) with a thickness of 1 nm. Thus, the hole transport layer 2107a and the light emitting layer 2107 are obtained.
b, a second EL layer 2107 including an electron transport layer 2107c and an electron injection layer 2107d was formed.

Finally, an evaporation method by resistance heating is used to form aluminum (Al
) Was formed to a thickness of 200 nm, whereby the second electrode 2102 was formed, whereby the light-emitting element 1 was manufactured.

Next, the light emitting element 2 will be described. The light emitting element 2 was manufactured in the same manner as the light emitting element 1 except for the electronic relay layer 2105. Therefore, here, the light emitting elements 2 other than the electronic relay layer 2105
The above description is incorporated for the configuration and manufacturing method. The electron-relay layer 2105 included in the light-emitting element 2 is formed on the electron-injection buffer layer 2104 by co-evaporation of PPDN (abbreviation) that is an electron-transporting substance and lithium (Li) that is a donor substance.
An electronic relay layer 2105 having a thickness of nm was formed. Here, PPDN (abbreviation) and lithium (
The mass ratio of Li) was adjusted to be 1: 0.02 (= PPDN: Li). P
The LUMO level of PDN (abbreviation) is based on the result of cyclic voltammetry (CV) measurement-
It is about 3.83 eV.

Next, the light emitting element 3 will be described. The light-emitting element 3 was manufactured in the same manner as the light-emitting element 1 except for the electronic relay layer 2105. Therefore, here, the light emitting elements 3 other than the electronic relay layer 2105
The above description is incorporated for the configuration and manufacturing method. The electron-relay layer 2105 included in the light-emitting element 3 is formed by co-evaporating PTCBI (abbreviation) that is an electron-transporting substance and lithium oxide (Li ₂ O) that is a donor-related substance, whereby an electron-injection buffer layer 210 is formed.
On 4, an electronic relay layer 2105 having a thickness of 3 nm was formed. Here, PTCBI (abbreviation)
The mass ratio of lithium oxide (Li ₂ O) was adjusted to be 1: 0.02 (= PTCBI: Li ₂ O).

Next, the light emitting element 4 will be described. The light-emitting element 4 was manufactured in the same manner as the light-emitting element 1 except for the electronic relay layer 2105. Therefore, here, the light emitting elements 4 other than the electronic relay layer 2105 are used.
The above description is incorporated for the configuration and manufacturing method. The electron-relay layer 2105 included in the light-emitting element 4 is formed by co-evaporating PPDN (abbreviation) that is an electron-transporting substance and lithium oxide (Li ₂ O) that is a donor substance, whereby an electron-injection buffer layer 2104 is formed.
An electronic relay layer 2105 having a thickness of 3 nm was formed thereon. Here, the mass ratio of PPDN (abbreviation) and lithium oxide (Li ₂ O) was adjusted to be 1: 0.02 (= PPDN: Li ₂ O).

Next, the comparative light-emitting element 5 will be described (see FIG. 11B). The comparative light-emitting element 5 has a structure in which the electron relay layer 2105 is deleted from the light-emitting elements 1 to 4, and the other layers are formed by the same manufacturing method as the light-emitting elements 1 to 4. That is, in the comparative light-emitting element 5, after the electron injection buffer layer 2104 was formed, the second charge generation layer 2106 was formed on the electron injection buffer layer 2104. Thus, a comparative light-emitting element 5 of this example was obtained.

  Table 1 below shows element structures of the light-emitting elements 1 to 4 and the comparative light-emitting element 5.

The light-emitting elements 1 to 4 and the comparative light-emitting element 5 obtained as described above were sealed in a glove box in a nitrogen atmosphere so that each light-emitting element was not exposed to the atmosphere, and then the operating characteristics of these light-emitting elements Was measured. The measurement was performed at room temperature (atmosphere kept at 25 ° C.).

FIG. 12 shows voltage-luminance characteristics of the light-emitting elements 1 to 4 and the comparative light-emitting element 5. In FIG. 12, the horizontal axis represents applied voltage (V), and the vertical axis represents luminance (cd / m ² ). In addition, FIG. 13 shows voltage-current density characteristics of the light-emitting elements 1 to 4 and the comparative light-emitting element 5. In FIG. 13, the horizontal axis represents voltage (V) and the vertical axis represents current density (mA / cm ² ). In addition, Table 2 below shows voltages when the luminance of each light-emitting element is around 1000 cd / m ² .

From FIG. 12, it can be seen that the light emitting elements 1 to 4 provided with the electronic relay layer can obtain higher luminance than the comparative light emitting element 5. Further, it can be seen from FIG. 13 that the light emitting elements 1 to 4 provided with the electronic relay layer have a higher current density than the comparative light emitting element 5.

From the above, it was confirmed that the light-emitting elements 1 to 4 of this example exhibited characteristics as light-emitting elements and functioned sufficiently. From Table 2, it was confirmed that the light-emitting elements 1 to 4 were light-emitting elements that could be driven at a lower voltage than the comparative light-emitting element 5.

In this example, a light-emitting element which is one embodiment of the present invention will be described with reference to FIGS. Note that in the light-emitting element and the comparative light-emitting element described in this example, the above description is referred to for portions that are common to the light-emitting element described in Example 1.

  A method for manufacturing the light-emitting elements 6 to 9 and the comparative light-emitting element 10 of this example will be described below.

First, the light-emitting element 6 will be described (see FIG. 11A). The light emitting element 6 of this example is
Except for the electron injection buffer layer 2104, the light-emitting element 1 was manufactured in the same manner as in Example 1.
Therefore, the description of Example 1 is used here for the configuration and manufacturing method of the light-emitting element 6 other than the electron injection buffer layer 2104. In the light emitting element 6 of this example,
BPhen (abbreviation) which is an electron transporting substance and lithium oxide (Li ₂ ) which is a donor substance.
O) was co-evaporated to form an electron injection buffer layer 2104 having a thickness of 20 nm on the electron transport layer 2103d. Here, BPhen (abbreviation) and lithium oxide (Li ₂ O
) Mass ratio was adjusted to be 1: 0.02 (= BPhen: Li ₂ O).

Next, the light emitting element 7 will be described. The light-emitting element 7 of this example was manufactured in the same manner as the light-emitting element 2 shown in Example 1 except for the electron injection buffer layer 2104. Therefore, here, the description of Example 1 is referred to for the configuration and manufacturing method of the light-emitting element 7 other than the electron-injection buffer layer 2104. In the light-emitting element 7 of this example, BPhen (abbreviation), which is an electron transporting substance, and lithium oxide (Li ₂ O), which is a donor substance, are co-evaporated, whereby a 20 nm thickness is formed on the electron transporting layer 2103d. Thickness electron injection buffer layer 2104
Formed. Here, the mass ratio of BPhen (abbreviation) and lithium oxide (Li ₂ O) is 1:
0.02: it was adjusted (= BPhen _Li 2 O) and so as.

Next, the light emitting element 8 will be described. The light-emitting element 8 of this example was manufactured in the same manner as the light-emitting element 3 shown in Example 1 except for the electron injection buffer layer 2104. Therefore, the description of Example 1 is used here for the configuration and manufacturing method of the light-emitting element 8 other than the electron-injection buffer layer 2104. In the light-emitting element 8 of this example, BPhen (abbreviation) which is an electron transporting substance and lithium oxide (Li ₂ O) which is a donor substance are co-evaporated to form 20 nm on the electron transporting layer 2103d. Thickness electron injection buffer layer 2104
Formed. Here, the mass ratio of BPhen (abbreviation) and lithium oxide (Li ₂ O) is 1:
0.02: it was adjusted (= BPhen _Li 2 O) and so as.

Next, the light emitting element 9 will be described. The light-emitting element 9 of this example was manufactured in the same manner as the light-emitting element 4 shown in Example 1 except for the electron injection buffer layer 2104. Therefore, here, the description of Example 1 is referred to for the configuration and the manufacturing method of the light-emitting element 9 other than the electron-injection buffer layer 2104. In the light-emitting element 9 of this example, BPhen (abbreviation) which is an electron transporting substance and lithium oxide (Li ₂ O) which is a donor substance are co-evaporated, whereby a 20 nm thickness is formed on the electron transporting layer 2103d. Thickness electron injection buffer layer 2104
Formed. Here, the mass ratio of BPhen (abbreviation) and lithium oxide (Li ₂ O) is 1:
0.02: it was adjusted (= BPhen _Li 2 O) and so as.

Next, the comparative light-emitting element 10 will be described (see FIG. 11B). The comparative light-emitting element 10 has a structure in which the electron relay layer 2105 is deleted from the light-emitting elements 6 to 9, and the other layers were formed by the same manufacturing method as the light-emitting elements 6 to 9. That is, in the comparative light-emitting element 10, after the electron injection buffer layer 2104 was formed, the second charge generation layer 2106 was formed on the electron injection buffer layer 2104. Thus, a comparative light emitting device 10 of this example was obtained.

  Table 3 below shows element structures of the light-emitting elements 6 to 9 and the comparative light-emitting element 10.

After the light emitting elements 6 to 9 and the comparative light emitting element 10 obtained as described above were sealed in a glove box in a nitrogen atmosphere so that each light emitting element was not exposed to the atmosphere, the operating characteristics of these light emitting elements Was measured. The measurement was performed at room temperature (atmosphere kept at 25 ° C.).

FIG. 14 shows voltage-luminance characteristics of the light-emitting elements 6 to 9 and the comparative light-emitting element 10. In FIG. 14, the horizontal axis represents applied voltage (V), and the vertical axis represents luminance (cd / m ² ). In addition, FIG. 15 shows voltage-current density characteristics of the light-emitting elements 6 to 9 and the comparative light-emitting element 10. In FIG. 15, the horizontal axis represents voltage (V) and the vertical axis represents current density (mA / cm ² ). In addition, Table 4 below shows voltages when the luminance of each light-emitting element is around 1000 cd / m ² .

From FIG. 14, it is understood that the light emitting elements 6 to 9 provided with the electronic relay layer can obtain higher luminance than the comparative light emitting element 10. 15 that the light emitting elements 6 to 9 provided with the electronic relay layer have a higher current density than the comparative light emitting element 10.

From the above, it was confirmed that the light-emitting elements 6 to 9 of this example have characteristics as light-emitting elements and function sufficiently. Further, it was confirmed that the light-emitting elements 6 to 9 were light-emitting elements that can be driven at a low voltage.

In this example, a light-emitting element which is one embodiment of the present invention will be described with reference to FIGS. Note that in the light-emitting element and the comparative light-emitting element described in this example, the above description is referred to for portions that are common to the light-emitting element described in Example 1.

  A method for manufacturing the light-emitting element 11 and the comparative light-emitting element 12 of this example will be described below.

First, the light-emitting element 11 is described (see FIG. 11A). Light emitting device 11 of this example
Were manufactured in the same manner as the light-emitting element 1 described in Example 1, except for the electron transport layer 2103d and the electron injection buffer layer 2104 of the first EL layer 2103. Therefore, here the electron transport layer 2
For the configuration and manufacturing method of the light-emitting element 11 other than 103d and the electron injection buffer layer 2104, the description of Example 1 is cited. In the light-emitting element 11 of this example, Alq (abbreviation) has a thickness of 10 nm and BPhen (abbreviation) has a thickness of 20 on the light-emitting layer 2103c.
The electron transport layer 2103d was formed by depositing the layers by nm deposition. Further, an electron injection buffer layer 2104 was formed on the electron transport layer 2103d by depositing lithium oxide (Li ₂ O) to a thickness of 0.1 nm. Thus, the light-emitting element 11 of this example was obtained.

Next, the comparative light-emitting element 12 will be described (see FIG. 11B). The comparative light-emitting element 12 of this example has a structure in which the electron relay layer 2105 is deleted from the light-emitting element 11, and the other layers were formed by the same manufacturing method as the light-emitting element 11. In the comparative light-emitting element 12, after the electron injection buffer layer 2104 was formed, the second charge generation layer 2106 was formed on the electron injection buffer layer 2104. Thus, a comparative light emitting device 12 of this example was obtained.

  Table 5 below shows element structures of the light-emitting element 11 and the comparative light-emitting element 12.

After the light-emitting element 11 and the comparative light-emitting element 12 obtained as described above were sealed in a glove box in a nitrogen atmosphere so that each light-emitting element was not exposed to the atmosphere, the operating characteristics of these light-emitting elements were measured. Went. The measurement was performed at room temperature (atmosphere kept at 25 ° C.).

FIG. 16 shows voltage-luminance characteristics of the light-emitting element 11 and the comparative light-emitting element 12. In FIG. 16, the horizontal axis represents applied voltage (V), and the vertical axis represents luminance (cd / m ² ). In addition, FIG. 17 shows voltage-current density characteristics of the light-emitting element 11 and the comparative light-emitting element 12. In FIG. 17, the horizontal axis represents voltage (V) and the vertical axis represents current density (mA / cm ² ). Further, the luminance of each light emitting element is 1
The voltage at around 000 cd / m ² is shown in Table 6 below.

From FIG. 16, the light emitting element 11 provided with the electronic relay layer is compared with the comparative light emitting element 12.
It can be seen that high luminance can be obtained. Further, it can be seen from FIG. 17 that the light emitting element 11 provided with the electronic relay layer has a higher current density than the comparative light emitting element 12.

From the above, it was confirmed that the light-emitting element 11 of this example has characteristics as a light-emitting element and functions well. Further, it was confirmed that the light-emitting element 11 was a light-emitting element that could be driven with a low voltage.

DESCRIPTION OF SYMBOLS 10 Substrate 11 Transistor 12 Light emitting element 13 Electrode 14 Electrode 15 Layer containing organic compound 16a Interlayer insulation film 16b Interlayer insulation film 16c Interlayer insulation film 17 Wiring 18 Partition layer 19a Interlayer insulation film 19b Interlayer insulation film 101 Anode 102 Cathode 103 EL layer 103a First light-emitting layer 103b Second light-emitting layer 104 Electron injection buffer layer 105 Electron relay layer 106 Charge generation layer 106a Layer 106b containing a hole-transporting substance 107 Layer 107 containing an acceptor substance EL layer 107a Third light-emitting layer 107b Fourth light-emitting layer 108 Electron transport layer 111 Anode Fermi level 112 Cathode Fermi level 113 LUMO level 114 of the first EL layer Donor level 115 of the donor substance in the electron relay layer Electron transport in the electron relay layer LUMO level 116 of the conductive material in the charge generation layer Acceptor level 117 of the acceptor substance LUMO level of the second EL layer 330 First light emission 340 Second light emission 800 Portable information terminal device 801 Case 802 Display portion 803 Case 805 Keyboard 807 Connection portion 810 Digital video camera 811 Case 812 Display unit 820 Mobile phone 821 Case 822 Case 823 Connection unit 824 Display unit 825 Operation key 830 Computer 831 Case 832 Display unit 833 Keyboard 834 Case 840 Television 841 Case 842 Display unit 843 Stand 850 Remote control Operating device 851 Operation key 852 Display unit 900 Desktop illumination device 901 Illumination unit 910 Ceiling illumination device 911 Illumination unit 920 Roll illumination device 921 Illumination unit 951 Substrate 952 Electrode 953 Insulating layer 954 Partition layer 955 Light emitting element 956 Electrode 10 0 traffic light 1001 illuminating unit 1002 illuminating unit 1003 illuminating unit 1010 evacuation exit guide light 1021 support 1022 illuminating unit 1023 power pole 1024 power transmission line 1031 mounting unit 1032 illuminating unit 1041 housing 1042 illuminating unit 1043 switch 2100 substrate 2101 electrode 2102 electrode 2103 EL layer 2103a Charge generation layer 2103b Hole transport layer 2103c Light emission layer 2103d Electron transport layer 2104 Electron injection buffer layer 2105 Electron relay layer 2106 Charge generation layer 2107 EL layer 2107a Hole transport layer 2107b Light emission layer 2107c Electron transport layer 2107d Electron injection layer

Claims (10)

N (n is a natural number of 2 or more) layers between the anode and the cathode,
Between the m (m is a natural number, 1 ≦ m ≦ n−1) th EL layer and the m + 1th EL layer from the anode,
A first layer containing a first donor material in contact with the mth EL layer;
A second layer in contact with the first layer, the first layer including a first electron transporting substance and a second donor substance;
A third layer containing a first hole transporting substance and an acceptor substance in contact with the second layer and the (m + 1) th EL layer,
The mth EL layer has a fourth layer in contact with the first layer,
The fourth layer includes a second electron transporting substance;
The LUMO level of the first electron transporting material is lower than the LUMO level of the second electron transporting material,
The (m + 1) th EL layer has a fifth layer in contact with the third layer,
The fifth layer is a light-emitting element including a second hole transporting substance. In claim 1,
The light-emitting element in which the LUMO level of the first electron transporting material is −5.0 eV or more. In claim 1 or claim 2,
The light-emitting element in which the first electron transporting substance is a perylene derivative or a nitrogen-containing condensed aromatic compound. In any one of Claims 1 thru | or 3,
The light-emitting element in which the first donor substance is an alkali metal, an alkaline earth metal, a rare earth metal, an alkali metal compound, an alkaline earth metal compound, or a rare earth metal compound. In any one of Claims 1 thru | or 4,
The light-emitting element in which the acceptor substance is an oxide of a metal belonging to Groups 4 to 8 in the periodic table. In any one of Claims 1 thru | or 5,
The light-emitting element wherein the acceptor substance is molybdenum oxide. In any one of Claims 1 thru | or 6,
The light-emitting element in which the third layer is a layer in which a layer containing a hole-transporting substance in contact with the (m + 1) th EL layer and a layer containing an acceptor substance in contact with the second layer are stacked.   A light-emitting device including the light-emitting element according to claim 1.   An electronic device comprising the light emitting device according to claim 8.   The illuminating device containing the light-emitting device of Claim 8.

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