JP2013255434A - Beverage composition - Google Patents
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Abstract
Description
本発明は飲料組成物に関する。詳細には、本発明は経時外観安定性に優れるポリフェノール類飲料組成物に関する。 The present invention relates to a beverage composition. Specifically, the present invention relates to a polyphenol beverage composition having excellent appearance stability over time.
近年の健康志向や美容意識の高まりによりポリフェノール類が有する抗酸化作用が着目されている。ポリフェノール類は飲料として一般的に摂取されるものが多いが、一般にポリフェノール類を含有する水性組成物は、加熱処理や経時によって組成物の着色/変色、濁りや沈殿物が発生するという問題がある。茶は水性飲料として摂取されるほか、そのエキスは食品フレーバーなどとしても幅広く利用されている。しかし、茶にはカテキンなどのポリフェノール類が多量に含まれるため、抽出や殺菌のための加熱処理など高温に晒された場合、特にpHが中性付近の茶飲料は温和な条件で加熱処理に付されるために褐色変化などの着色/変色を生じるという外観安定性上の問題がある。また、茶の粉末エキスをスプレードライなどにより製造する場合にも高温に晒され、ポリフェノール類が変色する。 Antioxidant action of polyphenols has attracted attention due to the recent increase in health consciousness and beauty consciousness. Polyphenols are generally ingested as beverages, but aqueous compositions containing polyphenols generally have problems that coloring / discoloration of the composition, turbidity, and precipitation occur due to heat treatment and aging. . In addition to being consumed as an aqueous beverage, tea is widely used as a food flavor. However, tea contains a large amount of polyphenols such as catechins, so when exposed to high temperatures, such as heat treatment for extraction and sterilization, tea beverages with a neutral pH are subjected to heat treatment under mild conditions. Therefore, there is a problem in appearance stability in that coloring / discoloration such as browning occurs. In addition, when a tea powder extract is produced by spray drying or the like, the polyphenols are discolored by being exposed to high temperatures.
このような問題に対して、特許文献1には緑茶の緑色を安定的に保持できる緑茶抽出物の安定化方法が開示されている。また、特許文献2には脂肪酸トリグリセリド中にポリフェノール類が高濃度に溶解した、安定性に優れたポリフェノール類製剤が開示されている。しかしながら、これらの先行技術によってもポリフェノール類の安定化を十分に図ることはできなかった。 For such problems, Patent Document 1 discloses a method for stabilizing a green tea extract that can stably maintain the green color of green tea. Patent Document 2 discloses a polyphenol preparation having excellent stability in which polyphenols are dissolved in fatty acid triglycerides at a high concentration. However, these prior arts cannot sufficiently stabilize polyphenols.
本発明の目的は、外観安定性、特に高温に晒された後の外観安定性に優れたポリフェノール類含有飲料組成物、および、ポリフェノール類含有飲料組成物の外観を安定化する方法を提供することにある。 An object of the present invention is to provide a polyphenols-containing beverage composition excellent in appearance stability, in particular, appearance stability after being exposed to a high temperature, and a method for stabilizing the appearance of the polyphenols-containing beverage composition. It is in.
本発明者らは、かかる課題のもとに鋭意検討した結果、これらのポリフェノール類を含有する飲料にオレウロペインを添加することによりこの課題を解決し得ることを見出し、本発明を完成するに至った。 As a result of intensive studies based on these problems, the present inventors have found that this problem can be solved by adding oleuropein to beverages containing these polyphenols, and have completed the present invention. .
すなわち、本発明は、
[1] オレウロペイン0.01−0.15質量%と、焙煎緑茶、ウーロン茶およびはと麦茶から選ばれる1種以上の茶抽出物とを含む飲料組成物;
[2] 茶抽出物がウーロン茶葉抽出物である前記[1]記載の飲料組成物;
[3] 茶系飲料組成物にオレウロペイン0.01−0.15質量%を添加することを特徴とする茶系飲料組成物の外観の安定化方法;および
[4] 茶系飲料組成物がウーロン茶である前記[3]記載の安定化方法
を提供する。
That is, the present invention
[1] A beverage composition comprising 0.01 to 0.15% by mass of oleuropein and at least one tea extract selected from roasted green tea, oolong tea and hato barley tea;
[2] The beverage composition according to the above [1], wherein the tea extract is an oolong tea leaf extract;
[3] A method for stabilizing the appearance of a tea-based beverage composition, characterized in that 0.01 to 0.15% by mass of oleuropein is added to the tea-based beverage composition; and [4] The tea-based beverage composition is oolong tea. The stabilization method according to the above [3], wherein
本発明によれば、外観安定性に優れたポリフェノール類を含有する飲料組成物を提供することができる。 According to the present invention, a beverage composition containing polyphenols having excellent appearance stability can be provided.
第1の形態において、本発明はオレウロペインと、焙煎緑茶、ウーロン茶およびはと麦茶から選ばれる1種以上の茶抽出物とを含む飲料組成物を提供する。
また、第2の形態において、本発明は茶系飲料組成物にオレウロペインを添加することを含む茶系飲料組成物の外観を安定化する方法を提供する。
In a first aspect, the present invention provides a beverage composition comprising oleuropein and one or more tea extracts selected from roasted green tea, oolong tea, and barley tea.
In a second aspect, the present invention provides a method for stabilizing the appearance of a tea-based beverage composition comprising adding oleuropein to the tea-based beverage composition.
本発明に用いるオレウロペインは、フェノール系化合物の配糖体の一種であり、モクセイ科オリーブ属の植物の花、果皮、果実、葉、樹皮、根または種子を水または水・エタノール混液を用いて抽出することにより得られる。モクセイ科オリーブ属の植物としては、例えば、オリーブ(Olea europaea Linne)やその同属種(Olea welwitschii、Olea paniculataなど)などが挙げられる。オリーブの品種の代表例としては、例えば、ネバディブロンコ、マンザニロ、ピクアル、ホジブランコ、アルベキナ、カタマラ、コロネイキ、ピッチョリーネ、パラゴン、ワッガベルダル、ミッション、ワシントン、ウエストオースラリアミッション、サウスオーストラリアベルダル、アザパ、バルネア、コルニカブラ、ゴルダル、フラントイオ、レッチーノ、チプレッシーノ、ルッカ、アスコラーナテレナ、コレッジョッラ、モロイオロ、ブラックイタリアン、コラティーナ、ヘレナ、ロシオーラ、ワンセブンセブン、エルグレコ、ハーディズマンモスなどを挙げることができる。
また、本発明に用いるオレウロペインは市販されているものを用いることもでき、例えば、エーザイフードケミカル株式会社(商品名「オピエース」)などから商業的に入手できる。オレウロペインの飲料組成物中の含有量は、0.01−0.15質量%が好ましく、0.01−0.11質量%がより好ましく、0.01−0.07質量%がさらに好ましい。飲料組成物中のオレウロペインの含有量が0.01質量%未満である場合は、組成物に含まれるほうじ茶、ウーロン茶およびはと麦茶から選ばれる1種以上の抽出物中のポリフェノール類の外観安定性を向上することが困難となるため好ましくない。一方、飲料組成物中のオレウロペインの含有量が0.15質量%を超える場合は、飲料組成物の苦味が強くなるため好ましくない。
The oleuropein used in the present invention is a type of glycoside of a phenolic compound, and the flowers, pericarp, fruits, leaves, bark, roots or seeds of the genus Oleaceae are extracted with water or a mixture of water and ethanol. Can be obtained. Examples of the plants belonging to the genus Oleaceae include olives ( Olea europaea Linne) and the same species ( Olea welwitschii , Olea paniculata, etc.). Representative examples of olive varieties include, for example, Neva di Bronco, Manzanillo, Picual, Hogi Blanco, Albequina, Catamara, Colonnage, Pitchorine, Paragon, Wagga Verdal, Mission, Washington, West Australia Mission, South Australia Verdal, Azapa, Balnea , Cornicabra, Gordal, Frantoio, Retino, Cipressino, Lucca, Ascorana Terena, Correggiola, Moloioro, Black Italian, Colatina, Helena, Rossiola, One Seven Seven, El Greco, Hardys Mammoth and the like.
The oleuropein used in the present invention may be a commercially available product, and can be obtained commercially, for example, from Eisai Food Chemical Co., Ltd. (trade name “Opiace”). The content of oleuropein in the beverage composition is preferably from 0.01 to 0.15% by mass, more preferably from 0.01 to 0.11% by mass, and even more preferably from 0.01 to 0.07% by mass. When the content of oleuropein in the beverage composition is less than 0.01% by mass, the appearance stability of polyphenols in one or more extracts selected from roasted tea, oolong tea and hato barley tea contained in the composition It is not preferable because it is difficult to improve the ratio. On the other hand, when the content of oleuropein in the beverage composition exceeds 0.15% by mass, the bitterness of the beverage composition is increased, which is not preferable.
本発明に用いる焙煎緑茶は、ツバキ科カメリア属の茶の葉および/または小枝(茎)を焙煎処理したものを意味し、具体的には醗酵処理工程の無い茶(緑茶)を焙煎することにより得ることができる。焙煎緑茶抽出物としては、通常、焙煎した緑茶葉の水および/またはエタノール抽出物、もしくは臨界抽出法を用いて得られる抽出物を使用することができ、例えば、ほうじ茶抽出物を挙げることができる。これら抽出物は、例えば、佐藤食品工業株式会社(商品名「ほうじ茶エキスH0102タイプ」)などから商業的に入手できる。 The roasted green tea used in the present invention means a product obtained by roasting tea leaves and / or twigs (stems) of the camellia family Camellia, specifically roasting tea (green tea) without a fermentation treatment step. Can be obtained. As the roasted green tea extract, usually, water and / or ethanol extract of roasted green tea leaves, or an extract obtained by using a critical extraction method can be used. Can do. These extracts are commercially available from, for example, Sato Foods Co., Ltd. (trade name “Hojicha Extract H0102 Type”).
本発明に用いるウーロン茶は、ツバキ科カメリア属の茶の葉を醗酵および加熱処理したものを意味し、具体的には茶葉の醗酵が終了する前の段階で加熱処理を行い、茶葉の醗酵を途中で終了させることにより得ることができる。ウーロン茶エキスとしては、通常、ウーロン茶葉の水および/またはエタノール抽出物、もしくは臨界抽出法を用いて得られる抽出物を使用することができる。これら抽出物は、例えば、佐藤食品工業株式会社(商品名「ウーロン茶エキスU1」)、三栄源エフエフアイ株式会社(商品名「ウーロン茶エキスNO.14266」、「FDウーロン茶エキスパウダーNO.16297」)、丸善製薬株式会社(商品名「ウーロン茶エキスM」)などから商業的に入手できる。 Oolong tea used in the present invention means a product obtained by fermenting and heat-treating tea leaves of the Camellia family Camellia, specifically, performing heat treatment at the stage before the fermentation of tea leaves, Can be obtained by ending with As the oolong tea extract, a water and / or ethanol extract of oolong tea leaves or an extract obtained by using a critical extraction method can be used. These extracts include, for example, Sato Food Industry Co., Ltd. (trade name “Oolong Tea Extract U1”), Saneigen FFI Co., Ltd. (trade names “Oolong Tea Extract NO.14266”, “FD Oolong Tea Extract Powder NO.16297”), Commercially available from Maruzen Pharmaceutical Co., Ltd. (trade name “Oolong Tea Extract M”).
本発明に用いるはと麦は、イネ科ジュズダマ属の一種であるハトムギの種子を意味し、はと麦茶はハトムギの種子を焙煎処理することにより得ることができる。はと麦茶エキスとしては、通常、焙煎したハトムギ種子の水および/またはエタノール抽出物、もしくは臨界抽出法を用いて得られる抽出物を使用することができる。これら抽出物は、例えば、丸善製薬株式会社(商品名「ハトムギエキスパウダーMF」)などから商業的に入手できる。
本発明の飲料組成物には、上記した茶抽出物を単独または2種以上を組み合わせて配合することができる。
Hato barley used in the present invention refers to seeds of pearl barley, which is a kind of Gramineae, and pearl barley tea can be obtained by roasting barley seeds. As the hato barley tea extract, a water and / or ethanol extract of roasted barley seeds or an extract obtained using a critical extraction method can be used. These extracts are commercially available from, for example, Maruzen Pharmaceutical Co., Ltd. (trade name “Bedley Extract Powder MF”).
In the beverage composition of the present invention, the above-described tea extract can be blended alone or in combination of two or more.
本発明の飲料組成物に含まれる焙煎緑茶、ウーロン茶およびはと麦茶から選ばれる1種以上の茶抽出物の量は、組成物中の乾燥粉末または顆粒として、0.01−5質量%が好ましく、0.01−1質量%がより好ましく、0.01−0.5質量%が最も好ましい。 The amount of one or more tea extracts selected from roasted green tea, oolong tea and hato barley tea contained in the beverage composition of the present invention is 0.01-5% by mass as a dry powder or granules in the composition. Preferably, 0.01-1% by mass is more preferable, and 0.01-0.5% by mass is most preferable.
本発明の飲料組成物には、本発明の効果を損なわない範囲で、食品で使用できる任意の成分を配合できる。例えば、ほうじ茶を包含する焙煎緑茶、ウーロン茶およびはと麦茶以外の茶抽出物、タンパク質、炭水化物、糖類、食物繊維、動植物油脂、エタノール、多価アルコール、糖アルコール、増粘・粘稠剤、乳化剤、ガムベース、包接化合物、酸化防止剤、抗酸化剤、キレート剤、甘味剤、pH調整剤、塩類、アミノ酸類、生薬、酸味料、軟化剤、着色料、光沢剤、ビタミン類、香料、防腐剤、水などを配合することができる。 The beverage composition of the present invention can contain any component that can be used in foods as long as the effects of the present invention are not impaired. For example, roasted green tea including roasted green tea, oolong tea and tea extract other than hato barley tea, protein, carbohydrate, sugar, dietary fiber, animal and vegetable oil, ethanol, polyhydric alcohol, sugar alcohol, thickener / thickener, emulsifier , Gum base, inclusion compound, antioxidant, antioxidant, chelating agent, sweetener, pH adjuster, salt, amino acids, herbal medicine, acidulant, softener, colorant, brightener, vitamins, flavoring, antiseptic An agent, water and the like can be blended.
本発明の飲料組成物は、液体飲料だけでなく、フリーズドライ処理やスプレードライ処理などにより粉末化飲料形態としたものであってもよい。
本発明の飲料組成物は、一般食品として、または歯周組織の健康維持や血糖値改善効果を訴求した特定保健食品として適用できる。
The beverage composition of the present invention may be in the form of a powdered beverage not only by liquid beverage but also by freeze-drying treatment or spray-drying treatment.
The beverage composition of the present invention can be applied as a general food or as a specific health food that promotes periodontal tissue health and blood sugar level improving effects.
以下、実施例および比較例を示して本発明を具体的に説明するが、本発明は下記実施例に限定されるものではない。なお、各例中の配合量は、特に規定がない限り質量%を示す。
表1の処方に従って飲料組成物を調製し、種々の濃度のオレウロペインが及ぼす飲料組成物の外観安定性への影響を調べた。
EXAMPLES Hereinafter, although an Example and a comparative example are shown and this invention is demonstrated concretely, this invention is not limited to the following Example. In addition, the compounding quantity in each example shows the mass% unless there is special prescription | regulation.
Beverage compositions were prepared according to the formulation in Table 1, and the influence of various concentrations of oleuropein on the appearance stability of the beverage composition was examined.
黄色度(YI:Yellow Index)は下式により求めた。
YI=100(1.28X-1.06Z)
Y
※X, Y, Z:XYZ表色系の三刺激値
The yellowness index (YI: Yellow Index) was determined by the following equation.
YI = 100 (1.28X-1.06Z)
Y
* X, Y, Z: Tristimulus values in the XYZ color system
上記処方に従って飲料組成物を製造し、黄色度(YI-0)を測定した。
つぎに、飲料組成物を飲料用パウチに封入し、123℃にて15分の加熱処理後、加熱直後の黄色度(YI-1)を測定し、黄変度 △YI-1 = 〔(YI-1)-(YI-0)〕を算出した。
未開封の加熱処理パウチサンプルをさらに40℃にて1ヶ月放置後、黄色度(YI-2)を測定し、黄変度 △YI-2 = 〔(YI-2)-(YI-1)〕を算出した。
飲料組成物の外観安定性の総合評価は、黄変度 △YI-3 = 〔(YI-2)-(YI-0)〕を評価して行った。
黄色度の測定には、分光光度計 UV2450(株式会社 島津製作所製)を使用した。その結果を図1−図3に示す。
A beverage composition was produced according to the above formulation, and the yellowness (YI-0) was measured.
Next, the beverage composition is enclosed in a beverage pouch, and after yellowing at 123 ° C. for 15 minutes, the yellowness (YI-1) immediately after heating is measured, and the yellowing degree ΔYI-1 = [(YI -1)-(YI-0)] was calculated.
The unopened heat-treated pouch sample was further left at 40 ° C. for 1 month, and then the yellowness (YI-2) was measured, and the yellowing degree ΔYI-2 = [(YI-2)-(YI-1)] Was calculated.
The overall evaluation of the appearance stability of the beverage composition was performed by evaluating the degree of yellowing ΔYI−3 = [(YI−2) − (YI−0)].
For the measurement of yellowness, a spectrophotometer UV2450 (manufactured by Shimadzu Corporation) was used. The results are shown in FIGS.
飲料組成物は加熱殺菌により変色し、放置することでさらに変色する傾向がみられた。一方、飲料にオレウロペインを0.01%以上添加することにより黄変を抑制でき、外観安定性を向上できることが示された。 The beverage composition was discolored by heat sterilization, and a tendency to discolor further when allowed to stand was observed. On the other hand, it was shown that yellowing can be suppressed and appearance stability can be improved by adding 0.01% or more of oleuropein to the beverage.
飲料組成物を調製後、レトルト殺菌せずにそのままの飲料について5人のパネラーによる香味評価を行った。評価は以下の基準に従い、得られた点数の平均値として表した。
評 価 点数
苦味を感じない 1
苦味をやや感じる 2
苦味を感じる 3
苦味を強く感じる 4
香味評価の結果を表2に示す。
After preparing the beverage composition, the flavor was evaluated by five panelists for the beverage as it was without retort sterilization. The evaluation was expressed as an average value of the obtained scores according to the following criteria.
Evaluation score
I do not feel bitterness 1
I feel a little bitterness 2
Feel bitterness 3
I strongly feel the bitterness 4
The results of flavor evaluation are shown in Table 2.
表2に示されるように、種々な飲料組成物にオレウロペインを配合するにあたり、香味の観点から配合量の上限は0.15%が好ましいことが判明した。
これらの外観安定性および香味評価の結果から、茶系飲料組成物に配合するオレウロペインの配合量は0.01−0.15%が好ましいことが判明した。
As shown in Table 2, when blending oleuropein into various beverage compositions, it was found that the upper limit of the blending amount is preferably 0.15% from the viewpoint of flavor.
From the results of appearance stability and flavor evaluation, it was found that 0.01 to 0.15% of the amount of oleuropein blended in the tea-based beverage composition was preferable.
以下に、本発明に係る処方例を記載する。
実施例1
成分 配合量(%)
ウーロン茶エキス 0.2
オレウロペイン 0.07
香料 0.2
ビタミンC 0.1
水 残部
合計 100
Below, the prescription example which concerns on this invention is described.
Example 1
Ingredient Amount (%)
Oolong tea extract 0.2
Oleuropein 0.07
Fragrance 0.2
Vitamin C 0.1
Water balance Total 100
実施例2
成分 配合量(%)
ウーロン茶エキス 0.2
オレウロペイン 0.01
香料 0.2
エリスリトール 6
水 残部
合計 100
Example 2
Ingredient Amount (%)
Oolong tea extract 0.2
Oleuropein 0.01
Fragrance 0.2
Erythritol 6
Water balance Total 100
実施例3
成分 配合量(%)
ウーロン茶エキス 0.2
オレウロペイン 0.11
香料 0.2
ステビア 0.02
水 残部
合計 100
Example 3
Ingredient Amount (%)
Oolong tea extract 0.2
Oleuropein 0.11
Fragrance 0.2
Stevia 0.02
Water balance Total 100
実施例4
成分 配合量(%)
ウーロン茶エキス 1
ほうじ茶エキス 0.01
オレウロペイン 0.15
香料 0.2
水 残部
合計 100
Example 4
Ingredient Amount (%)
Oolong tea extract 1
Hojicha Extract 0.01
Oleuropein 0.15
Fragrance 0.2
Water balance Total 100
実施例5
成分 配合量(%)
ほうじ茶エキス 0.01
紅茶エキス 0.2
オレウロペイン 0.07
香料 0.2
水 残部
合計 100
Example 5
Ingredient Amount (%)
Hojicha Extract 0.01
Black tea extract 0.2
Oleuropein 0.07
Fragrance 0.2
Water balance Total 100
実施例6
成分 配合量(%)
ほうじ茶エキス 1
ウーロン茶エキス 0.01
オレウロペイン 0.01
香料 0.2
水 残部
合計 100
Example 6
Ingredient Amount (%)
Hojicha Extract 1
Oolong tea extract 0.01
Oleuropein 0.01
Fragrance 0.2
Water balance Total 100
実施例7
成分 配合量(%)
ほうじ茶エキス 0.4
ルイボスエキス 1
オレウロペイン 0.15
香料 0.2
水 残部
合計 100
Example 7
Ingredient Amount (%)
Hojicha extract 0.4
Rooibos extract 1
Oleuropein 0.15
Fragrance 0.2
Water balance Total 100
本発明の飲料組成物および方法は、茶系飲料組成物の外観安定性を向上するために茶系飲料組成物およびその乾燥粉末の製造に利用される。 The beverage composition and method of the present invention are used for producing a tea-based beverage composition and its dry powder in order to improve the appearance stability of the tea-based beverage composition.
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