JP2012219422A - Method for producing fiber fabric and fiber fabric - Google Patents
Method for producing fiber fabric and fiber fabric Download PDFInfo
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- JP2012219422A JP2012219422A JP2011089614A JP2011089614A JP2012219422A JP 2012219422 A JP2012219422 A JP 2012219422A JP 2011089614 A JP2011089614 A JP 2011089614A JP 2011089614 A JP2011089614 A JP 2011089614A JP 2012219422 A JP2012219422 A JP 2012219422A
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- fiber fabric
- fabric
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- nylon
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- 239000004744 fabric Substances 0.000 title claims abstract description 154
- 239000000835 fiber Substances 0.000 title claims abstract description 122
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 33
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims abstract description 102
- 229920001778 nylon Polymers 0.000 claims abstract description 53
- 238000005452 bending Methods 0.000 claims abstract description 48
- 239000007788 liquid Substances 0.000 claims abstract description 43
- 235000019445 benzyl alcohol Nutrition 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- 238000003860 storage Methods 0.000 claims description 12
- 229920005989 resin Polymers 0.000 abstract description 9
- 239000011347 resin Substances 0.000 abstract description 9
- 238000009940 knitting Methods 0.000 abstract description 4
- 238000009941 weaving Methods 0.000 abstract description 4
- 239000004677 Nylon Substances 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 14
- 239000011162 core material Substances 0.000 description 11
- 238000004043 dyeing Methods 0.000 description 11
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 229920000728 polyester Polymers 0.000 description 8
- 238000005259 measurement Methods 0.000 description 6
- 230000008961 swelling Effects 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 208000012886 Vertigo Diseases 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 4
- 238000009991 scouring Methods 0.000 description 4
- 238000009958 sewing Methods 0.000 description 4
- 235000017550 sodium carbonate Nutrition 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 238000009987 spinning Methods 0.000 description 4
- 229920001864 tannin Polymers 0.000 description 4
- 235000018553 tannin Nutrition 0.000 description 4
- 239000001648 tannin Substances 0.000 description 4
- 239000002759 woven fabric Substances 0.000 description 4
- 230000037303 wrinkles Effects 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 239000005871 repellent Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 229920002292 Nylon 6 Polymers 0.000 description 2
- 239000000980 acid dye Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 241000872198 Serjania polyphylla Species 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- -1 antibacterial Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000013305 flexible fiber Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002121 nanofiber Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/01—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with hydrogen, water or heavy water; with hydrides of metals or complexes thereof; with boranes, diboranes, silanes, disilanes, phosphines, diphosphines, stibines, distibines, arsines, or diarsines or complexes thereof
- D06M11/05—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with hydrogen, water or heavy water; with hydrides of metals or complexes thereof; with boranes, diboranes, silanes, disilanes, phosphines, diphosphines, stibines, distibines, arsines, or diarsines or complexes thereof with water, e.g. steam; with heavy water
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Woven Fabrics (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
本発明は、硬い風合いを有する繊維布帛の製造方法に関するものである。 The present invention relates to a method for producing a fiber fabric having a hard texture.
ナイロンやポリエステルなどを用いた繊維布帛は、絹のような風合いが求められており、柔らかくするために種々の工夫がなされている。その一つとして、例えば、繊維布帛を構成する繊維一本の太さを細くする方法が挙げられる。繊維を細くする方法としては、紡糸の段階で、細い繊維を直接曳く方法、あるいは、ナイロンとポリエステルとを複合した複合糸を紡糸し、後でアルカリを用いて、ポリエステル成分を溶解除去する方法などがある。また、ナイロンを膨潤させるベンジルアルコールなどの膨潤剤を用いて、ナイロンを膨潤させて複合糸を割繊する方法もある(特許文献1)。このような方法によって、細い繊維を製造し、柔軟な繊維布帛を得ることが行われている。 A fiber fabric using nylon, polyester, or the like is required to have a silky texture, and various measures have been taken to make it soft. As one of the methods, for example, there is a method of reducing the thickness of one fiber constituting the fiber fabric. As a method of thinning the fiber, a method of directly spinning the thin fiber at the spinning stage, or a method of spinning a composite yarn composed of nylon and polyester and then dissolving and removing the polyester component using an alkali, etc. There is. There is also a method of splitting a composite yarn by swelling nylon using a swelling agent such as benzyl alcohol that swells nylon (Patent Document 1). By such a method, a thin fiber is manufactured and a flexible fiber fabric is obtained.
しかしながら、近年、消費者の志向が変化し、硬めの風合いを有する繊維布帛が求められるようになってきている。そこで、太い糸を用い、かつ、高密度の織物などを製造することが行われている。 However, in recent years, consumer preferences have changed and fiber fabrics having a hard texture have been demanded. In view of this, it has been practiced to produce a high-density fabric using a thick thread.
しかしながら、特別に太い糸を製造することは、糸の製造に使用される樹脂量が増加し、また1ロットあたりの生産量も少なく、紡糸や糸の製造コストが上昇してしまうという問題がある。また、高密度の織物を織ることも生産性が低下し、好ましくない。 However, producing a specially thick yarn has a problem that the amount of resin used for yarn production increases, the production amount per lot is small, and the production cost of spinning and yarn increases. . In addition, weaving a high-density fabric is not preferable because productivity decreases.
他方、メラミン樹脂などの硬仕上用樹脂を用い、汎用的な繊維布帛に付与することも行われてはいるが、樹脂を用いたものでは、樹脂特有の風合いがあらわれたり、洗濯や摩耗により樹脂が剥がれたりするため耐久性が十分ではない。 On the other hand, a resin for hard finishing such as a melamine resin is used and applied to a general-purpose fiber fabric. However, in the case of using a resin, a texture peculiar to the resin appears or the resin is washed or worn. As it peels off, the durability is not sufficient.
本発明は、上記課題を解決するためになされたものであり、特別に太い糸を用いたり、織成や編成の段階にて負荷の大きな高密度のものを製造したりしなくとも、また、硬仕上げ樹脂加工を行わなくとも、硬い風合いの繊維布帛を得ることのできる繊維布帛の製造方法を提供することを目的とする。 The present invention has been made to solve the above-mentioned problems, and without using specially thick yarns or manufacturing high-density ones with a large load at the stage of weaving or knitting, It is an object of the present invention to provide a method for producing a fiber cloth that can obtain a fiber cloth having a hard texture without performing hard finish resin processing.
本発明者らは、上記課題を解決するために鋭意検討した結果、従来、ナイロンとポリエステルとの複合繊維を用いたものに対して、柔らかい布帛を製造するために用いられていたベンジルアルコールを含む処理液を用いて、ポリエステル繊維を含まないナイロン繊維からなる布帛を処理することにより、硬い風合いを有する繊維布帛が得られることを見出し、本発明を完成するに至った。 As a result of intensive studies to solve the above problems, the inventors of the present invention include benzyl alcohol, which has been conventionally used for producing soft fabrics compared to those using a composite fiber of nylon and polyester. The present inventors have found that a fiber fabric having a hard texture can be obtained by treating a fabric composed of nylon fibers not containing polyester fibers using the treatment liquid, and has completed the present invention.
すなわち、上記課題を解決するために、本発明に係る繊維布帛の製造方法は、主にナイロン繊維からなる布帛を、ベンジルアルコールを含む処理液で処理するものである。 That is, in order to solve the above-mentioned problem, the method for producing a fiber fabric according to the present invention is to treat a fabric mainly composed of nylon fibers with a treatment liquid containing benzyl alcohol.
さらに、本発明に係る繊維布帛の製造方法において、前記処理液での処理は、JIS L1096に規定される45°カンチレバー法に準じて前記繊維布帛の剛軟度を測定したときにおいて、前記繊維布帛におけるタテ方向及びヨコ方向の少なくとも一方の剛軟度が100mm以上となるように行われることが好ましい。 Furthermore, in the method for producing a fiber fabric according to the present invention, the treatment with the treatment liquid is performed when the bending resistance of the fiber fabric is measured according to the 45 ° cantilever method defined in JIS L1096. It is preferable that the bending resistance of at least one of the vertical direction and the horizontal direction is 100 mm or more.
さらに、本発明に係る繊維布帛の製造方法において、前記処理液は、前記ベンジルアルコールが10g/l以上と水とを含むものであることが好ましい。 Furthermore, in the manufacturing method of the fiber fabric which concerns on this invention, it is preferable that the said process liquid contains the said benzyl alcohol 10g / l or more and water.
さらに、本発明に係る繊維布帛の製造方法において、前記ナイロン繊維からなる布帛がロープ状である場合、前記処理液での処理は、80℃から130℃の温度で行われることが好ましい。 Furthermore, in the method for producing a fiber fabric according to the present invention, when the fabric made of nylon fibers is rope-shaped, the treatment with the treatment liquid is preferably performed at a temperature of 80 ° C to 130 ° C.
また、本発明に係る繊維布帛の製造方法において、前記ナイロン繊維からなる布帛が拡布状である場合も、前記処理液での処理は、80℃から130℃の温度で行われることが好ましい。 Moreover, in the method for producing a fiber fabric according to the present invention, even when the fabric made of nylon fibers is in the form of an expanded fabric, the treatment with the treatment liquid is preferably performed at a temperature of 80 ° C to 130 ° C.
さらに、本発明に係る繊維布帛の製造方法において、前記布帛は、ナイロン繊維のみからなることが好ましい。 Furthermore, in the method for producing a fiber fabric according to the present invention, the fabric is preferably made of only nylon fibers.
また、本発明に係る繊維布帛は、主にナイロン繊維からなる布帛を、ベンジルアルコールを含む処理液で処理することによって得られるものである。 Further, the fiber fabric according to the present invention is obtained by treating a fabric mainly composed of nylon fibers with a treatment liquid containing benzyl alcohol.
さらに、本発明に係る繊維布帛において、前記処理液で処理した後の前記繊維布帛におけるタテ方向及びヨコ方向の少なくとも一方の剛軟度は、JIS L1096に規定される45°カンチレバー法に準じて測定したときに、100mm以上であることが好ましい。 Furthermore, in the fiber fabric according to the present invention, the bending resistance of at least one of the vertical direction and the horizontal direction in the fiber fabric after being treated with the treatment liquid is measured according to the 45 ° cantilever method defined in JIS L1096. When it is, it is preferable that it is 100 mm or more.
さらに、本発明に係る繊維布帛において、前記布帛は、ナイロン繊維のみからなることが好ましい。 Furthermore, in the fiber fabric according to the present invention, it is preferable that the fabric is made of only nylon fibers.
また、本発明に係る繊維布帛は、衣服として用いることができる。あるいは、本発明に係る繊維布帛は、収納具として用いることができる。 Moreover, the fiber fabric which concerns on this invention can be used as clothes. Alternatively, the fiber fabric according to the present invention can be used as a storage tool.
本発明に係る繊維布帛の製造方法によれば、硬い風合いの繊維布帛が得られる。従って、芯材等を用いなくとも形状を保持することができるので、意匠性に優れ、ニーズに適した繊維製品を得ることができる。 According to the method for producing a fiber fabric according to the present invention, a fiber fabric having a hard texture can be obtained. Accordingly, since the shape can be maintained without using a core material or the like, it is possible to obtain a textile product that is excellent in design and suitable for needs.
また、本発明に係る繊維布帛の製造方法では、汎用的な太さの糸を用いることができ、特別に高密度の織物や編物を織製したり編製したりすることなく風合いの硬い繊維布帛が得られる。従って、糸の製造や織編物を製造する段階での製造コストも低減することができる。 In the method for producing a fiber fabric according to the present invention, a yarn having a general thickness can be used, and a fiber fabric having a hard texture without knitting or knitting a special high-density fabric or knitted fabric. Is obtained. Therefore, the manufacturing cost at the stage of manufacturing the yarn and the knitted or knitted fabric can also be reduced.
以下、本発明に係る繊維布帛の製造方法及び繊維布帛について、実施の形態に基づいて説明する。 Hereinafter, the manufacturing method of the fiber fabric and the fiber fabric according to the present invention will be described based on the embodiments.
本発明は、主にナイロン繊維からなる布帛を、ベンジルアルコールを含む処理液で処理することにより、硬い風合いを有する繊維布帛を得るものである。 The present invention obtains a fiber fabric having a hard texture by treating a fabric mainly composed of nylon fibers with a treatment liquid containing benzyl alcohol.
本発明におけるナイロン繊維は、公知のナイロン繊維を用いることができ、例えば、ナイロン6、ナイロン10、ナイロン11、ナイロン12、ナイロン6.6、ナイロン6.10、あるいは、これらの共重合ポリアミドなどが挙げられる。中でも、ナイロン6、ナイロン6.6が染色性や強度などの繊維特性及びコストの観点より好ましい。 As the nylon fiber in the present invention, a known nylon fiber can be used, for example, nylon 6, nylon 10, nylon 11, nylon 12, nylon 6.6, nylon 6.10, or a copolymerized polyamide thereof. Can be mentioned. Among these, nylon 6 and nylon 6.6 are preferable from the viewpoint of fiber characteristics such as dyeability and strength, and cost.
なお、ナイロン繊維の太さも特に限定されるものではなく、単繊維の太さでナノファイバーといわれる0.0001デシテックスから500デシテックス程度のものが挙げられる。また、ナイロン繊維は、モノフィラメントであってもマルチフィラメントであってもよく、あるいは、ステープルであってもよい。 The thickness of the nylon fiber is not particularly limited, and may be about 0.0001 dtex to 500 dtex, which is referred to as nanofiber with a single fiber thickness. The nylon fiber may be a monofilament, a multifilament, or a staple.
また、糸(糸条)の太さは0.0001デシテックスから1000デシテックス程度のものを挙げることができるが、特に限定されるものではない。 Further, the thickness of the yarn (yarn) may be about 0.0001 dtex to 1000 dtex, but is not particularly limited.
低コストで汎用的な糸を用いかつ加工性がよいとの観点からは、単繊維の太さが0.1〜10デシテックス、糸条の太さが10デシテックス〜500デシテックスのナイロン繊維を用いることが好ましい。 From the viewpoint of using low-cost, general-purpose yarn and good workability, use a nylon fiber with a single fiber thickness of 0.1 to 10 dtex and a yarn thickness of 10 dtex to 500 dtex. Is preferred.
さらに、ナイロン繊維は、生糸であっても、また、仮ヨリや撚糸、タスラン加工などが施こされた加工糸であってもよい。 Further, the nylon fiber may be a raw yarn or a processed yarn subjected to temporary twisting, twisting, taslan processing, or the like.
本発明におけるナイロン繊維からなる布帛は、ナイロン繊維を主とするものである。すなわち、ナイロン繊維からなる布帛には、硬い風合いの布帛を得るとの本発明の目的を脱しない範囲で他の繊維を併用してもよいが、硬い風合いの布帛を得るとの観点からは、ポリエステル繊維等の他の繊維は含まずナイロン繊維のみからなる布帛を用いることが好ましい。 The fabric made of nylon fibers in the present invention is mainly made of nylon fibers. That is, in the fabric made of nylon fibers, other fibers may be used in combination as long as the object of the present invention for obtaining a fabric with a hard texture is not removed, but from the viewpoint of obtaining a fabric with a hard texture, It is preferable to use a cloth made of only nylon fibers without including other fibers such as polyester fibers.
なお、従来のようなポリエステル繊維とナイロン繊維とをおおよそ50%ずつ組み合わせたものに対してベンジルアルコールを含む処理液で処理すると、硬い風合いの繊維布帛が得られない。これは、ベンジルアルコールを含む処理液で処理する際に、ナイロン繊維とポリエステル繊維とで繊維の収縮性が大きくことなるからである。すなわち、収縮性がナイロン繊維と大きく異なる繊維を併用した布帛を用いた場合には、本発明の効果である低コストで硬い風合いの繊維布帛が得られない。 If a conventional polyester fiber and nylon fiber combined approximately 50% each is treated with a treatment liquid containing benzyl alcohol, a fiber fabric with a hard texture cannot be obtained. This is because when the treatment is performed with a treatment liquid containing benzyl alcohol, the shrinkage of the fibers is greatly increased between the nylon fibers and the polyester fibers. That is, when a fabric using a fiber having shrinkage significantly different from that of nylon fiber is used, a low-cost and hard texture fiber fabric, which is the effect of the present invention, cannot be obtained.
本発明で用いられるナイロン繊維からなる布帛は、汎用的に使用されている繊維、糸状、織編組織であっても、硬い風合いの繊維布帛を得ることができる。 Even if the fabric made of nylon fibers used in the present invention is a generally used fiber, yarn, or woven or knitted structure, a fabric fabric having a hard texture can be obtained.
次に、本発明に係る繊維布帛の製造方法について、より具体的に説明する。 Next, the method for producing the fiber fabric according to the present invention will be described more specifically.
本発明では、ナイロン繊維からなる布帛を、ベンジルアルコールを含む処理液で処理を行うが、処理方法としては、ベンジルアルコールが10g/l〜300g/lと水とを含む処理液にて処理を行うことが好ましい。 In the present invention, a fabric made of nylon fiber is treated with a treatment liquid containing benzyl alcohol. As a treatment method, treatment is performed with a treatment liquid containing 10 g / l to 300 g / l of benzyl alcohol and water. It is preferable.
ベンジルアルコールの量が10g/l未満では十分に硬い繊維布帛が得られないおそれがある。繊維布帛の硬化の観点から、より好ましくは、30g/l以上とすることが好ましい。一方、ベンジルアルコールの量が300g/を超えても薬剤の量の増加分ほど繊維布帛が硬化せず、逆に、ナイロン繊維の強度が低下するおそれがある。また、ベンジルアルコールの量が多くなると、処理液の廃水処理などの負荷が大きくなってしまう。 If the amount of benzyl alcohol is less than 10 g / l, a sufficiently hard fiber fabric may not be obtained. From the viewpoint of curing the fiber fabric, it is more preferably 30 g / l or more. On the other hand, even if the amount of benzyl alcohol exceeds 300 g /, the increase in the amount of the drug does not cure the fiber fabric, and conversely, the strength of the nylon fiber may decrease. Moreover, when the amount of benzyl alcohol increases, the load of the wastewater treatment of the treatment liquid increases.
なお、ベンジルアルコールは、乳化剤などを用いて乳化したものの方が、加工の安定性の観点より好ましい。また、ベンジルアルコールを含む処理液には、消泡剤、浴中柔軟剤、あたり防止剤等を添加してもよい。 Benzyl alcohol is preferably emulsified with an emulsifier or the like from the viewpoint of processing stability. Moreover, you may add a defoamer, a bath softening agent, a hit prevention agent, etc. to the process liquid containing benzyl alcohol.
また、ベンジルアルコールを含む処理液による処理温度は、60℃〜150℃で行うことができる。 Moreover, the process temperature by the process liquid containing benzyl alcohol can be performed at 60 to 150 degreeC.
また、比較的平坦な繊維布帛を得たいときには、ベンジルアルコールを含む処理液での処理は、布帛を拡布状として行うことが好ましく、その処理温度は、80℃から130℃の温度で行うとよい。 Further, when it is desired to obtain a relatively flat fiber fabric, the treatment with the treatment liquid containing benzyl alcohol is preferably performed with the fabric expanded, and the treatment temperature may be 80 ° C to 130 ° C. .
この場合、処理温度が80℃を下まわると、十分に硬い繊維布帛が得られないおそれがある。また、ナイロンの種類にもよるが、処理温度が130℃を越えると、繊維布帛の引裂強度等の強度が低下するおそれがある。風合い硬化の観点からは、90℃から125℃、より好ましくは100℃超から120℃の温度で処理するとよい。 In this case, if the treatment temperature falls below 80 ° C., a sufficiently hard fiber fabric may not be obtained. Further, although depending on the type of nylon, when the treatment temperature exceeds 130 ° C., the strength such as tear strength of the fiber fabric may be lowered. From the viewpoint of texture hardening, the treatment may be performed at a temperature of 90 ° C to 125 ° C, more preferably more than 100 ° C to 120 ° C.
処理時間は、処理温度やベンジルアルコールの濃度にもよるが、5分〜180分程度がよい。処理時間が5分未満であると、硬化部分がムラ状となったり、十分に硬い風合いを有する繊維布帛が得られないおそれがあり、処理時間が180分を超えると、生産性の観点より好ましくない。 The treatment time is preferably about 5 minutes to 180 minutes, depending on the treatment temperature and the concentration of benzyl alcohol. If the treatment time is less than 5 minutes, the cured part may be uneven or a fiber fabric having a sufficiently hard texture may not be obtained. If the treatment time exceeds 180 minutes, it is preferable from the viewpoint of productivity. Absent.
さらに、処理時間は7分以上120分以内とする方が、風合いの硬化の均一性、硬さ及び生産性の観点より好ましい。 Further, the treatment time is preferably 7 minutes or more and 120 minutes or less from the viewpoints of uniformity of texture hardening, hardness, and productivity.
なお、平坦な繊維布帛を得る場合の加工機としては、常圧ジッカーや高圧ジッカーなどが挙げられる。 In addition, as a processing machine in the case of obtaining a flat fiber fabric, an atmospheric pressure zicker, a high pressure zicker, etc. are mentioned.
一方、膨らみ感やシワ感、やや強めの凹凸感を有する繊維布帛を得たいときには、ベンジルアルコールを含む処理液での処理は、布帛をロープ状として行うことが好ましく、その処理温度は、80℃から130℃の温度で行うとよい。 On the other hand, when it is desired to obtain a fiber fabric having a feeling of swelling, wrinkle, or slightly strong unevenness, the treatment with the treatment liquid containing benzyl alcohol is preferably performed in the form of a rope, and the treatment temperature is 80 ° C. To 130 ° C.
この場合、処理温度が80℃を下まわると、十分に硬い繊維布帛が得られないおそれがある。また、ナイロンの種類にもよるが、処理温度が130℃を越えると、繊維布帛の引裂強度等の強度が低下するおそれがある。風合い硬化の観点からは、90℃から125℃、より好ましくは100℃超から125℃の温度で処理するとよい。 In this case, if the treatment temperature falls below 80 ° C., a sufficiently hard fiber fabric may not be obtained. Further, although depending on the type of nylon, when the treatment temperature exceeds 130 ° C., the strength such as tear strength of the fiber fabric may be lowered. From the viewpoint of texture hardening, the treatment may be performed at a temperature of 90 ° C to 125 ° C, more preferably more than 100 ° C to 125 ° C.
なお、シワ感や、やや強めの凹凸感を有する繊維布帛を得たいときに用いる加工機としては、高圧液流染色機や高圧型ウインスなどが挙げられるが、硬化の均一性の観点からは液流染色機を用いることが好ましい。 In addition, as a processing machine used when it is desired to obtain a fiber fabric having a wrinkle feeling or a slightly strong uneven feeling, a high-pressure liquid flow dyeing machine, a high-pressure type winch or the like can be mentioned. It is preferable to use a flow dyeing machine.
また、本発明に係る繊維布帛の製造方法は、衣服又は収納具などの形状をした繊維布帛に適用することもできる。 Moreover, the manufacturing method of the fiber fabric which concerns on this invention can also be applied to the fiber fabric which carried out shapes, such as clothes or a storage tool.
例えば、ナイロン繊維からなる布帛を用いて得られた衣服又は収納具などの縫製品などを硬化させる場合には、ワッシャー(ドラム式処理装置)を用いて、80℃から130℃の温度で5分〜180分程度、ベンジルアルコールを含む処理液で処理してもよい。より好ましくは、90℃から125℃の処理温度で処理するとよい。 For example, in the case of curing a sewing product such as clothes or a storage tool obtained using a fabric made of nylon fibers, a washer (drum processing device) is used for 5 minutes at a temperature of 80 to 130 ° C. You may process with the process liquid containing benzyl alcohol for about -180 minutes. More preferably, the treatment is performed at a treatment temperature of 90 ° C. to 125 ° C.
以上、本発明に係る繊維布帛の製造方法の実施形態について説明してきたが、本発明において、ナイロン繊維からなる布帛を、ベンジルアルコールを含む処理液で処理した後は、ソーピングを行なうことが好ましい。 As mentioned above, although embodiment of the manufacturing method of the fiber fabric which concerns on this invention has been demonstrated, after processing the cloth which consists of nylon fibers with the process liquid containing benzyl alcohol in this invention, it is preferable to perform soaping.
ソーピングは、水洗又は40〜100℃程度の湯洗による処理、又は、常温の水又は40〜100℃程度の湯に、苛性ソーダ、ソーダ灰又はトリポリリン酸ソーダなどのアルカリ剤、界面活性剤あるいはキレート剤などを添加したソーピング溶液による処理である。 Soaping is a treatment by washing with water or hot water at about 40 to 100 ° C., or an alkaline agent such as caustic soda, soda ash or sodium tripolyphosphate, a surfactant or a chelating agent in normal temperature water or hot water at about 40 to 100 ° C. It is the process by the soaping solution which added.
また、ソーピングは、複数回行ってもよい。この場合、1回目のソーピングには、アルカリ剤や界面活性剤を添加したソーピング溶液を用い、2回目のソーピングは、水のみで処理するようなソーピングを行なってもよい。 Further, the soaping may be performed a plurality of times. In this case, a soaping solution to which an alkali agent or a surfactant is added may be used for the first soaping, and the second soaping may be performed with water alone.
さらに、ソーピングを行った後は、必要に応じ、乾燥や熱セットを行なったり、染色加工、撥水加工、抗菌加工、消臭加工、吸水加工、紫外線遮蔽加工又は制電加工などの加工を施したりしてもよい。 In addition, after soaping, if necessary, dry or heat set, and perform processing such as dyeing, water-repellent, antibacterial, deodorant, water-absorbing, UV shielding or antistatic processing. Or you may.
なお、これらの染色加工等は、縫製等を行った後に行ってもよい。また、補足的に、ポリエステル樹脂などを用いて硬仕上加工を行なってもよい。 In addition, you may perform these dyeing | staining processes etc., after performing sewing etc. In addition, hard finishing may be performed using a polyester resin or the like.
また、ベンジルアルコールを含む処理液にて処理されたナイロン繊維からなる布帛に対して予備セットや仕上セットなどの熱処理を行う場合、当該熱処理の温度は、本発明の目的とする、風合い、外観、目付、密度等に合わせて、120℃〜200℃程度にて任意に設定すればよい。 In addition, when performing a heat treatment such as a preliminary set or a finishing set on a fabric made of nylon fiber treated with a treatment liquid containing benzyl alcohol, the temperature of the heat treatment is the object of the present invention, texture, appearance, What is necessary is just to set arbitrarily in about 120 to 200 degreeC according to a fabric weight, a density, etc.
本発明では、上記の製造方法により、硬い風合いを有する繊維布帛を製造することができる。 In the present invention, a fiber fabric having a hard texture can be produced by the production method described above.
本発明の製造方法で得られた繊維布帛は、「JIS L1096」に規定される45°カンチレバー法に準じて、測定時の環境を20℃×40%RHとして測定したタテ方向及びヨコ方向の少なくとも一方の剛軟度が100mm以上であることが好ましい。さらに、繊維布帛におけるタテ方向及びヨコ方向の少なくとも一方の剛軟度は、150mm以上であることが、より好ましい。また、タテ方向及びヨコ方向のいずれの剛軟度も100mm以上あるとよく、さらに、タテ方向及びヨコ方向のいずれの剛軟度も150mm以上であると、より好ましい。 The fiber fabric obtained by the production method of the present invention has at least a vertical direction and a horizontal direction measured according to the 45 ° cantilever method specified in “JIS L1096” with the measurement environment set to 20 ° C. × 40% RH. It is preferable that one bending resistance is 100 mm or more. Furthermore, the bending resistance of at least one of the vertical direction and the horizontal direction in the fiber fabric is more preferably 150 mm or more. Further, it is preferable that the bending flexibility in the vertical direction and the horizontal direction is 100 mm or more, and it is more preferable that the bending flexibility in the vertical direction and the horizontal direction is 150 mm or more.
このように、剛軟度が100mm以上であると、従来の硬仕上加工と比べ、硬い風合いとすることができ、仕立て栄えの観点からも好ましい。 Thus, when the bending resistance is 100 mm or more, it is possible to obtain a hard texture as compared with the conventional hard finishing, which is also preferable from the viewpoint of tailoring.
また、剛軟度が100mm以上であると、従来は別途芯地と組み合わせて製造されていたシャツの襟、カフス、帽子又は靴などの衣服において、芯地(芯材)を用いなくとも、本発明における繊維布帛のみで形状を保持したシャツの襟等を製造することができる。 In addition, if the bending resistance is 100 mm or more, the present invention can be applied to a shirt collar, cuffs, hat, shoes, and other clothing that has been manufactured separately in combination with the interlining without using the interlining (core). A shirt collar or the like whose shape is maintained only by the fiber fabric in the invention can be manufactured.
さらに、剛軟度が100mm以上であると、本発明における繊維布帛を用いて、鞄、あるいは、雑誌ラック、収納ボックス又は衣装ケースなどの収納具を製造する場合も、繊維布帛に硬質の樹脂をコーティングしたり含浸させたり、また、繊維布帛に、ダンボール、プラスチック板、木、金属又は樹脂製などの芯材と組み合わせなくとも形状を保持した靴や収納ボックスなどの収納具を得ることができる。 Furthermore, when the bending resistance is 100 mm or more, a hard resin is used for the fiber cloth even when a storage device such as a bag or a magazine rack, a storage box or a costume case is manufactured using the fiber cloth of the present invention. A storage device such as a shoe or a storage box can be obtained which is coated or impregnated, and which retains its shape without being combined with a core material such as corrugated cardboard, plastic board, wood, metal or resin.
なお、剛軟度の上限は特に限定されるものではなく、衣服や鞄などのデザインなども考慮し、必要な剛軟度のものを用いればよい。なお、JIS L1096に規定された剛軟性45°カンチレバー法に従って測定によると、本発明における繊維布帛の剛軟度は150mmが上限となっているが、これを超える物であっても用いることができる。 In addition, the upper limit of the bending resistance is not particularly limited, and the one having the necessary bending resistance may be used in consideration of the design of clothes and a bag. In addition, according to the measurement according to the 45 ° cantilever method of bending resistance defined in JIS L1096, the upper limit of the bending resistance of the fiber fabric in the present invention is 150 mm, but even a material exceeding this can be used. .
また、硬い風合いを有するシワを形成した場合、剛軟性の測定時にそのシワ部において、測定用試料が折れ曲がってしまい、剛軟度が100mm未満と測定されることがある。その場合は、剛軟性の測定に影響の少ない箇所から測定用試料をサンプリングし、剛軟性を測定するとよい。 Further, when a wrinkle having a hard texture is formed, the measurement sample may be bent at the wrinkle portion when measuring the bending resistance, and the bending resistance may be measured to be less than 100 mm. In that case, it is preferable to measure the bending resistance by sampling a measurement sample from a location having little influence on the bending resistance measurement.
以上、本発明の製造方法で得られた繊維布帛は硬い風合いを有するので、この繊維布帛を用いて、ジャケット、帽子、靴などの衣服を製造すれば、従来にない風合いを有し、外観も粗野な力強いものが得られる。また、芯材を用いなくとも、形状を維持することができる衣服が得られる。 As described above, since the fiber fabric obtained by the production method of the present invention has a hard texture, if clothes such as jackets, hats, and shoes are manufactured using this fiber fabric, it has an unprecedented texture and appearance. A crude and powerful one is obtained. Moreover, the clothes which can maintain a shape without using a core material are obtained.
また、本発明の製造方法で得られた硬い風合いを有する繊維布帛を用いて、鞄、袋、雑誌ラック、収納ボックス又は衣装ケースなどの収納具を製造することにより、布帛の質感を有していながら、芯材を用いなくとも形状保持性に優れた、新規な収納具が得られる。 Further, by using the fiber fabric having a hard texture obtained by the production method of the present invention, a storage device such as a bag, a bag, a magazine rack, a storage box, or a costume case is manufactured, thereby having the texture of the fabric. However, a novel storage device having excellent shape retention can be obtained without using a core material.
以下に、本発明に係る繊維布帛の製造方法について、実施例及び比較例に基づいて、より具体的に説明を行う。なお、本発明はこれらの実施例に限定されるものではない。また、以下の実施例及び比較例における剛軟度は、JIS L1096に規定される45°カンチレバー法に準じて、測定時の環境が20℃×40%RHの雰囲気にて測定を行なった。 Below, the manufacturing method of the fiber fabric which concerns on this invention is demonstrated more concretely based on an Example and a comparative example. The present invention is not limited to these examples. Further, the bending resistance in the following examples and comparative examples was measured in an atmosphere where the measurement environment was 20 ° C. × 40% RH according to the 45 ° cantilever method defined in JIS L1096.
(実施例1)
まず、実施例1について説明する。実施例1では、ナイロン繊維からなる織物(ツイル、タテ糸、ヨコ糸とも6−ナイロンが100%であり、タテ糸を78デシテックス/34フィラメントとし、ヨコ糸を235デシテックス/34フィラメントとした。織り上げ密度は、タテ密度×ヨコ密度=244本/2.54cm×77本/2.54cmである。)を用いた。
Example 1
First, Example 1 will be described. In Example 1, a woven fabric made of nylon fibers (twill, warp yarn, weft yarn is 6-nylon 100%, warp yarn is 78 dtex / 34 filament, and weft yarn is 235 dtex / 34 filament. The density was vertical density × horizontal density = 244 / 2.54 cm × 77 / 2.54 cm.
そして、この織物を精練した後に、水にベンジルアルコールの乳化分散液を投入し、150g/lのベンジルアルコールを含む処理液にて、常圧ジッカーを用いて室温から98℃まで40分かけて昇温し、98℃を維持して40分間の処理を行った(拡布状)。その後、引続き、ソーピングとして80℃のお湯にて2回湯洗いをおこなった。 After scouring this fabric, an emulsified dispersion of benzyl alcohol is added to water, and the mixture is heated from room temperature to 98 ° C. over 40 minutes using an atmospheric pressure zicker in a treatment liquid containing 150 g / l of benzyl alcohol. Warm and maintain at 98 ° C. for 40 minutes (expanded). Subsequently, the bath was washed twice with 80 ° C. hot water as soaping.
次に、常圧ジッカーを用い酸性染料にて黒色に染色(95℃×60分)し、ソーピング、合成タンニンを用いたフィックス処理をおこなった。その後、引続き、乾燥、すなわち140℃での仕上セットを行なった。 Next, it dye | stained black with an acidic dye using an atmospheric pressure zicker (95 degreeC x 60 minutes), and the fix process using a soaping and synthetic tannin was performed. Thereafter, drying, that is, finishing setting at 140 ° C. was performed.
得られた繊維布帛の密度は、タテ密度×ヨコ密度=270本/2.54cm×88本/2.54cmであった。 The density of the obtained fiber fabric was warp density × width density = 270 / 2.54 cm × 88 / 2.54 cm.
また、剛軟度を測定すると、タテ方向の剛軟度は148mmであり、ヨコ方向の剛軟度は118mmであり、硬い風合いの繊維布帛が得られた。 Further, when the bending resistance was measured, the bending resistance in the vertical direction was 148 mm, the bending resistance in the horizontal direction was 118 mm, and a fiber fabric having a hard texture was obtained.
また、得られた繊維布帛を用いて鞄を作製すると、得られた鞄は、芯材を用いなくとも繊維布帛のみで鞄の立体的な形状を維持でき、見栄えのするものであった。 Moreover, when a cocoon was produced using the obtained fiber fabric, the obtained cocoon was able to maintain the three-dimensional shape of the cocoon only with the fiber fabric without using a core material, and looked good.
(比較例1)
次に、比較例1について説明する。比較例1では、ベンジルアルコールを含む処理液による処理を行なわなかった以外は、実施例1と同様にして繊維布帛を得た。
(Comparative Example 1)
Next, Comparative Example 1 will be described. In Comparative Example 1, a fiber fabric was obtained in the same manner as in Example 1 except that the treatment with the treatment liquid containing benzyl alcohol was not performed.
得られた繊維布帛の密度は、タテ密度×ヨコ密度=250本/2.54cm×79本/2.54cmであった。 The density of the obtained fiber fabric was vertical density × horizontal density = 250 / 2.54 cm × 79 / 2.54 cm.
また、剛軟度を測定すると、タテ方向の剛軟度は42mmであり、ヨコ方向の剛軟度は85mmであり、柔らかい風合いの繊維布帛が得られた。 Further, when the bending resistance was measured, the bending resistance in the vertical direction was 42 mm, the bending resistance in the horizontal direction was 85 mm, and a soft fabric fabric was obtained.
また、得られた繊維布帛を用いて鞄を作製すると、得られた鞄は、芯材を用いなかったため、鞄の立体的な形状を維持できなかった。 Moreover, when a cocoon was produced using the obtained fiber fabric, the obtained cocoon did not use a core material, and thus the three-dimensional shape of the cocoon could not be maintained.
(実施例2)
次に、実施例2について説明する。実施例2では、ナイロン繊維からなる織物(ツイル、タテ糸、ヨコ糸とも6−ナイロンが100%であり、タテ糸を355デシテックス/192フィラメントとし、ヨコ糸を355デシテックス/192フィラメントとした。織り上げ密度は、タテ密度×ヨコ密度=95本/2.54cm×62本/2.54cmである。)を用いた。
(Example 2)
Next, Example 2 will be described. In Example 2, a woven fabric made of nylon fibers (twill, warp yarn, weft yarn is 6-nylon 100%, warp yarn is 355 dtex / 192 filament, and weft yarn is 355 dtex / 192 filament. The density was vertical density × width density = 95 / 2.54 cm × 62 / 2.54 cm.
そして、この織物を精練した後に、水にベンジルアルコールの乳化分散液を投入し、60g/lのベンジルアルコールを含む処理液にて、液流染色機を用いて室温から50分かけて110℃まで昇温し、110℃を維持して40分間の処理を行った(ロープ状)。 Then, after scouring this fabric, an emulsified dispersion of benzyl alcohol is added to water, and a treatment liquid containing 60 g / l of benzyl alcohol is used, from a room temperature to 110 ° C. over 50 minutes using a liquid dyeing machine. The temperature was raised and the temperature was maintained at 110 ° C. for 40 minutes (rope).
次に、ソーピングとして、90℃で10分間、ソーダ灰と界面活性剤を添加したお湯で湯洗いを行った後、水のみで水洗し、乾燥した。 Next, as soaping, hot water was washed with hot water to which soda ash and a surfactant were added at 90 ° C. for 10 minutes, and then washed with water alone and dried.
次に、160℃で予備セットを行なった後、酸性染料を用い黄色に染色(105℃×30分)、合成タンニンを用いたフィックス処理を行ない、引き続き、120℃にて乾燥した。 Next, after preliminary setting at 160 ° C., it was dyed yellow using an acid dye (105 ° C. × 30 minutes), fixed with synthetic tannin, and subsequently dried at 120 ° C.
次に、アサヒガードAG710(旭硝子(株)製)からなるフッ素系撥水剤の5%水溶液を用いて撥水処理をした後、140℃にて仕上セットを行なった。 Next, a water repellent treatment was performed using a 5% aqueous solution of a fluorine-based water repellent made of Asahi Guard AG710 (manufactured by Asahi Glass Co., Ltd.), and finish setting was performed at 140 ° C.
得られた繊維布帛の密度は、タテ密度×ヨコ密度=116本/2.54cm×85本/2.54cmであった。 The density of the obtained fiber fabric was warp density × width density = 116 / 2.54 cm × 85 / 2.54 cm.
また、剛軟度を測定すると、タテ方向の剛軟度は148mmであり、ヨコ方向の剛軟度は117mmであり、膨らみ感があり、かつ、硬い風合いを有する繊維布帛が得られた。 Further, when the bending resistance was measured, the bending resistance in the vertical direction was 148 mm, the bending resistance in the horizontal direction was 117 mm, and a fiber fabric having a feeling of swelling and a hard texture was obtained.
また、得られた繊維布帛を用いてコートを作製すると、得られたコートは、全体がごわついた感じがあり、力強い外観品位のコートが得られた。 Moreover, when a coat was produced using the obtained fiber fabric, the obtained coat had a feeling of being stiff overall, and a strong coat having a good appearance quality was obtained.
(比較例2)
次に、比較例2について説明する。比較例2では、ベンジルアルコールを含む処理液による処理を行なわなかった以外は、実施例2と同様にして(液流染色処理あり)、繊維布帛を得るとともに、コートを作製した。
(Comparative Example 2)
Next, Comparative Example 2 will be described. In Comparative Example 2, a fiber fabric was obtained and a coat was produced in the same manner as in Example 2 (with liquid dyeing treatment) except that the treatment with the treatment liquid containing benzyl alcohol was not performed.
得られた繊維布帛の密度は、タテ密度×ヨコ密度=98本/2.54cm×69本/2.54cmであった。 The density of the obtained fiber fabric was warp density × width density = 98 / 2.54 cm × 69 / 2.54 cm.
また、剛軟度を測定すると、タテ方向の剛軟度は40mmであり、ヨコ方向の剛軟度は35mmであり、柔らかい風合いの繊維布帛が得られた。また、コートは、風合いが柔らかく、ドレープ感が有り、やさしい感じの得られる外観のコートが得られた。 Further, when the bending resistance was measured, the bending resistance in the vertical direction was 40 mm, the bending resistance in the horizontal direction was 35 mm, and a fiber fabric with a soft texture was obtained. Also, the coat had a soft texture, a drape feeling, and an appearance with a gentle feeling.
(実施例3)
次に、実施例3について説明する。実施例3では、ナイロン繊維からなる織物(平織物、タテ糸、ヨコ糸とも6−ナイロンが100%であり、タテ糸を355デシテックス/192フィラメントとし、ヨコ糸を355デシテックス/192フィラメントとした。織り上げ密度は、タテ密度×ヨコ密度=89本/2.54cm×42本/2.54cmである)を用いた。
(Example 3)
Next, Example 3 will be described. In Example 3, a woven fabric made of nylon fibers (plain fabric, warp yarn, weft yarn is 6-nylon 100%, warp yarn is 355 dtex / 192 filament, and weft yarn is 355 dtex / 192 filament. The weaving density was vertical density × width density = 89 / 2.54 cm × 42 / 2.54 cm).
そして、この織物を精練した後に、水にベンジルアルコールの乳化分散液を投入し、50g/lのベンジルアルコールを含む処理液にて、液流染色機を用いて室温から50分かけて115℃まで昇温し、115℃を維持して10分間の処理を行った(ロープ状)。 Then, after scouring this fabric, an emulsified dispersion of benzyl alcohol is added to water, and the solution containing 50 g / l of benzyl alcohol is heated from room temperature to 115 ° C. over 50 minutes using a liquid dyeing machine. The temperature was raised and maintained at 115 ° C. for 10 minutes (rope).
次に、ソーピングとして、90℃で10分間、ソーダ灰と界面活性剤を添加したお湯で湯洗いを行った後、水のみで水洗し、乾燥した。 Next, as soaping, hot water was washed with hot water to which soda ash and a surfactant were added at 90 ° C. for 10 minutes, and then washed with water alone and dried.
得られた繊維布帛の密度は、タテ密度×ヨコ密度=109本/2.54cm×59本/2.54cmであった。 The density of the obtained fiber fabric was vertical density × width density = 109 / 2.54 cm × 59 / 2.54 cm.
また、剛軟度を測定すると、タテ方向の剛軟度は150mm以上であり、ヨコ方向の剛軟度は105mm以上となり、膨らみ感があり、かつ、硬い風合いを有する繊維布帛が得られた。 Further, when the bending resistance was measured, the bending resistance in the vertical direction was 150 mm or more, the bending resistance in the horizontal direction was 105 mm or more, and a fiber fabric having a feeling of swelling and a hard texture was obtained.
次に、得られた布帛を用いて鞄を縫製した後、酸性染料を用いて赤色に染色し(105℃×30分)、合成タンニンを用いたフィックス処理を行い、その後、120℃にて乾燥した。得られた鞄は、芯材を用いなくとも繊維布帛のみで鞄の立体的な形状を維持でき、見栄えのするものであった。 Next, after sewing a heel using the obtained fabric, it is dyed red using an acidic dye (105 ° C. × 30 minutes), fixed with synthetic tannin, and then dried at 120 ° C. did. The obtained cocoons were able to maintain the three-dimensional shape of the cocoons with only the fiber fabric without using a core material, and looked good.
(比較例3)
次に、比較例3について説明する。比較例3では、ベンジルアルコールを含む処理液による処理を行なわず、また、縫製後の染色処理を行なわなかった(液流染色機での処理なし)以外は、実施例3と同様にして繊維布帛及び鞄を得た。
(Comparative Example 3)
Next, Comparative Example 3 will be described. In Comparative Example 3, the fiber fabric was treated in the same manner as in Example 3 except that the treatment with the treatment liquid containing benzyl alcohol was not performed and the dyeing treatment after sewing was not performed (no treatment with a liquid dyeing machine). And got a spear.
得られた繊維布帛の密度は、タテ密度×ヨコ密度=96本/2.54cm×45本/2.54cmであった。 The density of the obtained fiber fabric was warp density × width density = 96 / 2.54 cm × 45 / 2.54 cm.
また、剛軟度を測定すると、タテ方向の剛軟度は56mmであり、ヨコ方向の剛軟度は45mmとなり、柔らかい風合いの繊維布帛が得られた。 Further, when the bending resistance was measured, the bending resistance in the vertical direction was 56 mm, and the bending resistance in the horizontal direction was 45 mm, and a fiber fabric having a soft texture was obtained.
また、得られた鞄は、芯材を用いなかったため、鞄の立体的な形状を維持できなかった。 Moreover, since the obtained cocoon did not use a core material, the three-dimensional shape of the cocoon could not be maintained.
(実施例4)
次に、実施例4について説明する。実施例4では、ナイロン繊維からなる織物(ツイル、タテ糸、ヨコ糸とも6−ナイロンが100%であり、タテ糸を355デシテックス/192フィラメントとし、ヨコ糸を355デシテックス/192フィラメントとした。織り上げ密度は、タテ密度×ヨコ密度=91本/2.54cm×62本/2.54cmである)を用いた。
Example 4
Next, Example 4 will be described. In Example 4, a woven fabric made of nylon fibers (twill, warp yarn, weft yarn is 6-nylon 100%, warp yarn is 355 dtex / 192 filament, and weft yarn is 355 dtex / 192 filament. The density was vertical density × width density = 91 / 2.54 cm × 62 / 2.54 cm).
そして、この織物を精練した後に、水にベンジルアルコールの乳化分散液を投入し、40g/lのベンジルアルコールを含む処理液にて、液流染色機を用いて室温から50分かけて105℃まで昇温し、105℃を維持して20分間の処理を行った(ロープ状)。 Then, after scouring this fabric, an emulsified dispersion of benzyl alcohol is added to water, and a treatment liquid containing 40 g / l of benzyl alcohol is heated from room temperature to 105 ° C. over 50 minutes using a liquid dyeing machine. The temperature was raised, and the treatment was carried out for 20 minutes while maintaining 105 ° C. (rope shape).
次に、ソーピングとして、90℃で10分間、ソーダ灰と界面活性剤を添加したお湯で湯洗いを行った後、水のみで水洗し、乾燥した。 Next, as soaping, hot water was washed with hot water to which soda ash and a surfactant were added at 90 ° C. for 10 minutes, and then washed with water alone and dried.
得られた繊維布帛の密度は、タテ密度×ヨコ密度=120本/2.54cm×85本/2.54cmであった。 The density of the obtained fiber fabric was warp density × width density = 120 / 2.54 cm × 85 / 2.54 cm.
また、剛軟度を測定すると、タテ方向の剛軟度は150mm以上であり、ヨコ方向の剛軟度は116mm以上となり、膨らみ感があり、かつ、硬い風合いを有する繊維布帛が得られた。 Further, when the bending resistance was measured, the bending resistance in the vertical direction was 150 mm or more, the bending resistance in the horizontal direction was 116 mm or more, and a fiber fabric having a feeling of swelling and a hard texture was obtained.
次に、得られた布帛を用いて帽子を縫製した後、酸性染料を用いてネイビーに染色し(105℃×30分)、合成タンニンを用いたフィックス処理を行い、その後、120℃にて乾燥した。得られた鞄は、芯材を用いなくとも繊維布帛のみで帽子の立体的な形状を維持でき、見栄えのするものであった。 Next, a hat is sewed using the obtained fabric, and then dyed in navy using an acid dye (105 ° C. × 30 minutes), fixed using synthetic tannin, and then dried at 120 ° C. did. The obtained cocoons were able to maintain the three-dimensional shape of the hat with only the fiber fabric without using a core material, and looked good.
(比較例4)
次に、比較例4について説明する。比較例4では、ベンジルアルコールを含む乳化分散液を投入しなかった以外は、実施例4と同様にして(液流染色機での処理あり)、繊維布帛を得た。
(Comparative Example 4)
Next, Comparative Example 4 will be described. In Comparative Example 4, a fiber fabric was obtained in the same manner as in Example 4 (with treatment using a liquid flow dyeing machine) except that the emulsified dispersion containing benzyl alcohol was not added.
得られた繊維布帛の密度は、タテ密度×ヨコ密度=102本/2.54cm×72本/2.54cmであった。 The density of the obtained fiber fabric was warp density × width density = 102 / 2.54 cm × 72 / 2.54 cm.
また、剛軟度を測定すると、タテ方向の剛軟度は40mmであり、ヨコ方向の剛軟度は30mmとなり、柔らかい風合いの繊維布帛が得られた。 Further, when the bending resistance was measured, the bending resistance in the vertical direction was 40 mm, and the bending resistance in the horizontal direction was 30 mm, and a fiber fabric having a soft texture was obtained.
また、得られた繊維布帛を用いて帽子を作製した。得られた帽子は、芯材を用いなかったため、帽子の立体的な形状を維持できなかった。 Moreover, the hat was produced using the obtained fiber fabric. Since the obtained hat did not use a core material, the three-dimensional shape of the hat could not be maintained.
本発明は、コートや靴などの衣服、鞄や衣装ケースなどの収納具など、繊維布帛を用いた繊維製品に広く利用することができる。 INDUSTRIAL APPLICABILITY The present invention can be widely used for textile products using fiber fabrics such as clothes such as coats and shoes, and storage devices such as bags and costume cases.
Claims (11)
繊維布帛の製造方法。 A method for producing a fiber fabric, wherein a fabric mainly composed of nylon fibers is treated with a treatment liquid containing benzyl alcohol.
請求項1に記載の繊維布帛の製造方法。 In the treatment with the treatment liquid, when the bending resistance of the fiber fabric is measured according to the 45 ° cantilever method specified in JIS L1096, the bending resistance of at least one of the vertical and horizontal directions of the fiber cloth is determined. The method for producing a fiber fabric according to claim 1, wherein the fiber fabric is made to be 100 mm or more.
請求項1又は2に記載の繊維布帛の製造方法。 The method for producing a fiber fabric according to claim 1, wherein the treatment liquid contains 10 g / l or more of the benzyl alcohol and water.
前記処理液での処理は、80℃から130℃の温度で行われる
請求項1〜3のいずれか1項に記載の繊維布帛の製造方法。 The cloth made of the nylon fiber is rope-shaped,
The method for producing a fiber fabric according to any one of claims 1 to 3, wherein the treatment with the treatment liquid is performed at a temperature of 80 ° C to 130 ° C.
前記処理液での処理は、80℃から130℃の温度で行われる
請求項1〜3のいずれか1項に記載の繊維布帛の製造方法。 The cloth made of the nylon fiber is in an expanded form,
The method for producing a fiber fabric according to any one of claims 1 to 3, wherein the treatment with the treatment liquid is performed at a temperature of 80 ° C to 130 ° C.
請求項1〜5のいずれか1項に記載の繊維布帛の製造方法。 The method for producing a fiber fabric according to any one of claims 1 to 5, wherein the fabric is made of only nylon fibers.
繊維布帛。 A fiber fabric obtained by treating a fabric mainly composed of nylon fibers with a treatment liquid containing benzyl alcohol.
請求項7に記載の繊維布帛。 When the bending resistance of at least one of the vertical direction and the horizontal direction in the fiber fabric obtained by processing with the processing liquid is measured according to the 45 ° cantilever method defined in JIS L1096, it is 100 mm or more. The fiber fabric according to claim 7.
請求項7又は8に記載の繊維布帛。 The fiber fabric according to claim 7 or 8, wherein the fabric is made of only nylon fibers.
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JP2011089614A JP5730110B2 (en) | 2011-04-13 | 2011-04-13 | Fabric manufacturing method and fiber fabric |
KR1020137025931A KR101888221B1 (en) | 2011-04-13 | 2011-09-09 | Method for producing fibrous fabric, and fibrous fabric |
ES11863535.8T ES2678519T3 (en) | 2011-04-13 | 2011-09-09 | Method to produce a fibrous tissue, and fibrous tissue |
US14/110,260 US20140020187A1 (en) | 2011-04-13 | 2011-09-09 | Method for manufacturing fiber fabric, and fiber fabric |
CN201180069971.6A CN103476984B (en) | 2011-04-13 | 2011-09-09 | The manufacture method of fiber fabric and fiber fabric |
PCT/JP2011/005102 WO2012140704A1 (en) | 2011-04-13 | 2011-09-09 | Method for producing fibrous fabric, and fibrous fabric |
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KR20200129762A (en) | 2019-05-10 | 2020-11-18 | 주식회사 노나 | Manufacturing method of paper mulberry fiber |
CN113249849A (en) * | 2021-06-07 | 2021-08-13 | 常州雅美特窗饰股份有限公司 | Production method of high-flatness light-transmitting curtain fabric |
CN114214851A (en) * | 2021-11-15 | 2022-03-22 | 吴江德伊时装面料有限公司 | Dyeing process of nylon fabric |
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JPH05311574A (en) * | 1992-05-07 | 1993-11-22 | Kanebo Ltd | Production of woven fabric having uneven surface |
JPH0641844A (en) * | 1992-07-16 | 1994-02-15 | Seiren Co Ltd | Base cloth for air-bag of car |
JPH06299465A (en) * | 1993-04-12 | 1994-10-25 | Toray Ind Inc | Production of bag base cloth |
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US4812140A (en) * | 1987-07-15 | 1989-03-14 | Burlington Industries, Inc. | Continuous aqueous dyeing process for high-tenacity industrial nylon fabrics |
JP2712037B2 (en) * | 1988-11-29 | 1998-02-10 | ダイニック株式会社 | Printing sheet material |
JPH0778314B2 (en) * | 1990-07-25 | 1995-08-23 | 鐘紡株式会社 | Method for dyeing polyamide fiber structure |
JPH07305284A (en) | 1994-04-28 | 1995-11-21 | Kanebo Ltd | Production of polyamide fiber structure having excellent wet dimensional stability |
US6805969B2 (en) * | 2001-03-14 | 2004-10-19 | E. I. Du Pont De Nemours And Company | Coating solutions suitable for improving the adhesion of nylon coatings and processes for the application thereof |
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JP3994814B2 (en) * | 2002-07-25 | 2007-10-24 | 東レ株式会社 | Dyed fabric and method for producing the same |
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JPH0314648A (en) * | 1989-03-27 | 1991-01-23 | Kanebo Ltd | High density fibrous structural article of polyamide and its production |
JPH05311574A (en) * | 1992-05-07 | 1993-11-22 | Kanebo Ltd | Production of woven fabric having uneven surface |
JPH0641844A (en) * | 1992-07-16 | 1994-02-15 | Seiren Co Ltd | Base cloth for air-bag of car |
JPH06299465A (en) * | 1993-04-12 | 1994-10-25 | Toray Ind Inc | Production of bag base cloth |
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EP2698470A4 (en) | 2014-11-26 |
WO2012140704A1 (en) | 2012-10-18 |
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