JP2011231398A - Electric resistance welded steel tube with excellent machinability - Google Patents
Electric resistance welded steel tube with excellent machinability Download PDFInfo
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- JP2011231398A JP2011231398A JP2010278114A JP2010278114A JP2011231398A JP 2011231398 A JP2011231398 A JP 2011231398A JP 2010278114 A JP2010278114 A JP 2010278114A JP 2010278114 A JP2010278114 A JP 2010278114A JP 2011231398 A JP2011231398 A JP 2011231398A
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 67
- 239000010959 steel Substances 0.000 title claims abstract description 67
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 7
- 239000012535 impurity Substances 0.000 claims abstract description 3
- 238000003466 welding Methods 0.000 abstract description 13
- 229910052791 calcium Inorganic materials 0.000 abstract description 4
- 229910052760 oxygen Inorganic materials 0.000 abstract description 4
- 229910052782 aluminium Inorganic materials 0.000 abstract description 3
- 229910052748 manganese Inorganic materials 0.000 abstract description 3
- 229910052750 molybdenum Inorganic materials 0.000 abstract description 3
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 2
- 229910052717 sulfur Inorganic materials 0.000 abstract description 2
- 238000005520 cutting process Methods 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 230000007547 defect Effects 0.000 description 8
- 229910002796 Si–Al Inorganic materials 0.000 description 7
- 239000000463 material Substances 0.000 description 5
- 238000010622 cold drawing Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- 238000005553 drilling Methods 0.000 description 3
- 230000006698 induction Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 229910000915 Free machining steel Inorganic materials 0.000 description 2
- 229910006639 Si—Mn Inorganic materials 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 238000005482 strain hardening Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
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- Heat Treatment Of Steel (AREA)
Abstract
Description
本発明は、自動車や一般機械などに用いられる、切削時の工具寿命や切り屑処理性に優れた、被削性に優れる電縫鋼管に関する。 The present invention relates to an electric-resistance-welded steel pipe excellent in machinability and excellent in tool life during cutting and chip disposal, which is used in automobiles and general machines.
自動車や一般機械などに用いられる部品は、棒鋼などの中実の鋼材を素材とし、要求精度と製造効率に応じて、切削工程を経て製造されるものが多い。しかし、最近では部品の軽量化の観点から中空である鋼管を素材とする場合が増えてきている。鋼管の中でも、電縫鋼管は、シームレス鋼管よりも安価でかつシーム溶接部の信頼性が比較的高いため、自動車や一般機械に広く用いられている。 Many parts used in automobiles and general machines are manufactured by using a solid steel material such as bar steel as a raw material through a cutting process according to required accuracy and manufacturing efficiency. However, recently, from the viewpoint of weight reduction of parts, the case of using a hollow steel pipe as a raw material is increasing. Among steel pipes, ERW steel pipes are widely used in automobiles and general machinery because they are cheaper than seamless steel pipes and the reliability of seam welds is relatively high.
部品素材用の電縫鋼管は、多くの場合、冷間引き抜き等の冷間加工によって所定の寸法・形状に成形されるが、最後の切削工程では、冷間加工ままの加工硬化した状態で切削される場合が多い。したがって、被削性に優れた電縫鋼管が要求されている。しかし、一般に冷間加工ままの素材は冷間加工前に比べて被削性が低下する。 In many cases, ERW steel pipes for component materials are formed into predetermined dimensions and shapes by cold working such as cold drawing, but in the final cutting process, they are cut in a work-hardened state as cold worked. Often done. Therefore, there is a demand for an ERW steel pipe excellent in machinability. However, in general, a machinable material as cold-worked is less machinable than before cold-working.
電縫鋼管では、快削性を向上させる添加元素の介在物が溶接部に生成し、また、溶接割れが発生するという問題があるため、Ｓ、Ｎ、Ｏ、Ｃａ、Ａｌなどの含有量を制御した電縫鋼管が提案されている（例えば、特許文献１〜３）。しかし、これらは被削性が不十分であった。一方、中実材では、ＢＮを利用した快削鋼が提案されている（例えば、特許文献４、５）。しかし、これらの中実材は酸素量や酸化物を制御したものではない。 In ERW steel pipes, inclusions of additive elements that improve free-cutting properties are generated in the welds and weld cracks occur, so the content of S, N, O, Ca, Al, etc. Controlled ERW steel pipes have been proposed (for example, Patent Documents 1 to 3). However, these have insufficient machinability. On the other hand, free-cutting steel using BN has been proposed for solid materials (for example, Patent Documents 4 and 5). However, these solid materials do not control oxygen content or oxides.
本発明は、溶接衝合部品質の良好な被削性に優れた電縫鋼管の提供を課題とするものである。 An object of the present invention is to provide an electric-resistance-welded steel pipe excellent in machinability with good weld-abutting section quality.
本発明者らは、硬質なＡｌ2Ｏ3の生成を防止し、ＭｎＳの延伸を抑制し、かつ、被削性の向上にはＣａ−Ｓｉ−Ａｌ系酸化物およびＢＮを利用することによって、電縫溶接品質を損なうことなく、被削性に優れた電縫鋼管が得られるという知見を得た。本発明は、このような知見に基づいてなされたものであり、その要旨は以下のとおりである。
（１）質量％で、Ｃ：０．０２〜０．２％、Ｓｉ：０．０５〜０．５％、Ｍｎ：０．２〜２．０％、Ｐ：０．００１〜０．０３％、Ｓ：０．０１〜０．０３％、Ｎ：０．００２〜０．０２％、Ａｌ：０．０００５〜０．００５％、Ｂ：０．００２〜０．０１５％、Ｏ：０．０００５〜０．００６％、Ｃａ：０．０００２〜０．００５％を含有し、残部がＦｅおよび不可避的不純物からなることを特徴とする被削性に優れた電縫鋼管。
（２）さらに、質量％で、Ｃｒ：０．０１〜２．０％、Ｍｏ：０．０１〜１．０％の一方または双方を含有することを特徴とする上記（１）に記載の被削性に優れた電縫鋼管。
（３）さらに、ＮおよびＢの含有量（質量％）［Ｎ］および［Ｂ］が、
０．６５＜［Ｎ］／［Ｂ］＜１．０４
を満足することを特徴とする上記（１）または（２）に記載の被削性に優れた電縫鋼管。
The present inventors prevent the generation of hard Al 2 O 3 , suppress the stretching of MnS, and improve the machinability by using Ca—Si—Al-based oxide and BN, We obtained the knowledge that ERW steel pipes with excellent machinability can be obtained without impairing ERW welding quality. This invention is made | formed based on such knowledge, The summary is as follows.
(1) By mass%, C: 0.02-0.2%, Si: 0.05-0.5%, Mn: 0.2-2.0%, P: 0.001-0.03% , S: 0.01-0.03%, N: 0.002-0.02%, Al: 0.0005-0.005%, B: 0.002-0.015%, O: 0.0005 An electric-welded steel pipe excellent in machinability characterized by containing ~ 0.006%, Ca: 0.0002-0.005%, and the balance being made of Fe and inevitable impurities.
(2) The coating according to (1), further comprising one or both of Cr: 0.01 to 2.0% and Mo: 0.01 to 1.0% by mass%. ERW steel pipe with excellent machinability.
(3) Further, the contents (mass%) of N and B [N] and [B]
0.65 <[N] / [B] <1.04
The electric-welded steel pipe excellent in machinability according to the above (1) or (2), wherein
本発明の電縫鋼管は、従来材と同様に優れた被削性を有するのにもかかわらず、被削性向上元素としてＢｉ、Ｐｂ、Ｔｅを含有しないために、製造時に疵が発生しにくく、環境負荷も小さい。電縫溶接衝合部の品質を損ねる元素の含有量を限定しているため、本発明によれば、電縫溶接部品質に優れた電縫鋼管を提供することが可能になり、産業上の貢献が極めて顕著である。 The electric resistance welded steel pipe of the present invention does not contain Bi, Pb, or Te as machinability improving elements even though it has excellent machinability as in the case of conventional materials. Environmental impact is also small. Since the content of the element that impairs the quality of the ERW weld abutting portion is limited, according to the present invention, it is possible to provide an ERW steel pipe excellent in ERW weld quality, The contribution is very significant.
以下、本発明の実施の形態について説明する。 Embodiments of the present invention will be described below.
以下に、本発明において鋼管の化学成分を限定した理由について説明する。なお、以下に示す「％」は、特段の説明がない限りは、「質量％」を意味するものとする。 Below, the reason which limited the chemical component of the steel pipe in this invention is demonstrated. The “%” shown below means “% by mass” unless otherwise specified.
Ｃは、鋼の強度を確保するために必須の元素であり、自動車や一般機械などの部品として最低限必要な強度を確保するために下限を０．０２％とした。一方、Ｃ量が多すぎると強度が高くなりすぎて被削性が低下するばかりでなく、電縫溶接の際の熱影響部が著しく硬化し、割れに至る場合がある。特に本発明の電縫鋼管のようにＢを含有する鋼は焼き入れ性硬化性が高いため、Ｃ量の上限を０．２％に限定した。 C is an essential element for securing the strength of steel, and the lower limit is set to 0.02% in order to ensure the minimum strength required for parts such as automobiles and general machines. On the other hand, if the amount of C is too large, not only does the strength become too high and the machinability deteriorates, but the heat-affected zone at the time of ERW welding is markedly hardened and may crack. In particular, steel containing B like the ERW steel pipe of the present invention has high hardenability and curability, so the upper limit of C content is limited to 0.2%.
Ｓｉは、脱酸上含まれる元素であり、特に本発明の電縫鋼管のようにＡｌ量が低く制限されている中でＯ量を極力低減したい場合には必須の脱酸元素である。また、被削性を向上させる低融点のＣａ−Ｓｉ−Ａｌ系酸化物の生成にも寄与する。それらの効果を得るために下限を０．０５％とした。一方、Ｓｉは電縫溶接衝合部にＦｅ−Ｓｉ−Ｍｎ系の酸化物欠陥として残存しやすく、過剰に添加すると電縫溶接品質が著しく低下する。そのため、溶接品質を損なわないために上限を０．５％とした。 Si is an element included in deoxidation, and is an indispensable deoxidation element particularly when it is desired to reduce the amount of O as much as possible while the amount of Al is limited to be low as in the case of the electric resistance welded steel pipe of the present invention. It also contributes to the generation of a low melting point Ca—Si—Al-based oxide that improves machinability. In order to obtain these effects, the lower limit was made 0.05%. On the other hand, Si tends to remain as Fe-Si-Mn-based oxide defects in the ERW welding abutting portion. Therefore, the upper limit is made 0.5% so as not to impair the welding quality.
Ｍｎは、鋼中のＳと結合し、軟質なＭｎＳとなって被削性向上に寄与する。また、鋼の強度を確保するためにも必要な元素である。これらの効果を得るために、下限を０．２％に設定した。一方、過度に添加すると電縫溶接時にＦｅ−Ｓｉ−Ｍｎ系酸化物が生成しやすくなり、溶接欠陥発生の一因となるため、上限を２．０％とした。 Mn combines with S in the steel to become soft MnS and contributes to improvement of machinability. It is also an element necessary for securing the strength of steel. In order to obtain these effects, the lower limit was set to 0.2%. On the other hand, if excessively added, Fe—Si—Mn-based oxides are likely to be generated during ERW welding, which contributes to the generation of welding defects, so the upper limit was made 2.0%.
Ｐは、鋼を脆化させて機械的性質、熱間加工性、電縫溶接性等を劣化させるので、少ない方が望ましく、上限を０．０３％とした。一方で鋼を脆化させることが被削性に対しては好ましい方向に寄与するため、微量を含有することは快削鋼にとっては有益であり、Ｐ量の下限を０．００１％とした。Ｐ量の好ましい下限は０．００５％である。 P makes the steel brittle and degrades mechanical properties, hot workability, electro-weldability, and the like, so it is desirable that P be less and the upper limit is 0.03%. On the other hand, since embrittlement of the steel contributes to a preferable direction for machinability, it is beneficial for free-cutting steel to contain a trace amount, and the lower limit of the P content is set to 0.001%. A preferable lower limit of the amount of P is 0.005%.
Ｓは、鋼中のＭｎと結合し、軟質なＭｎＳとなって被削性向上に寄与するので、被削性の観点から０．０１％以上を添加する。しかし、Ｓ量の増大と共に熱間延性が低下して熱延時に疵が発生しやすくなり、また、溶接部で割れ易いなどの電縫溶接性の著しい低下が生じる。そのため、Ｓ量の上限を０．０３％とする。 S combines with Mn in steel and becomes soft MnS to contribute to improvement of machinability, so 0.01% or more is added from the viewpoint of machinability. However, as the amount of S increases, the hot ductility decreases, so that flaws are likely to occur during hot rolling, and the electro-weldability is significantly reduced, such as being easily cracked at the weld. Therefore, the upper limit of the S amount is set to 0.03%.
Ｎは、固溶状態で青熱脆性を誘発させる元素であり、切削加工時の切り屑分断性を向上させる。また、鋼中でＢと結合してＢＮが生成すると被削性が著しく向上する。その効果を得るためには０．００２％以上のＮの添加が必要である。しかし、０．０２％以上のＮを添加すると鋳造時に気泡が発生して鋳片内部に残存したり、溶接時に気化して溶接が困難になったりする。そのため、上限を０．０２％、下限を０．００２％とした。固溶Ｎによる被削性向上の効果を得るには、０．００４％以上のＮを含有させることが好ましい。電縫溶接部の品質を向上させるためには、Ｎ量を０．０１％以下にすることが好ましい。 N is an element that induces blue brittleness in a solid solution state, and improves chip breaking property during cutting. Further, when BN is produced by combining with B in steel, the machinability is remarkably improved. In order to obtain the effect, 0.002% or more of N needs to be added. However, if N of 0.02% or more is added, bubbles are generated during casting and remain inside the slab, or vaporize during welding, making welding difficult. Therefore, the upper limit is made 0.02% and the lower limit is made 0.002%. In order to obtain the effect of improving the machinability by solute N, it is preferable to contain 0.004% or more of N. In order to improve the quality of the ERW weld, it is preferable to set the N content to 0.01% or less.
Ａｌは、本発明では極めて重要な元素であり、軟質で被削性向上に寄与するＣａ−Ｓｉ−Ａｌ系酸化物を生成させるため、０．０００５％を下限とした。また、Ａｌを過剰に添加すると、ＡｌＮを生成してＮを固定し、Ｎ添加による被削性向上効果が損なわれるため、０．００５％以下に制限する。更に、Ａｌ量が過剰であると、硬質なＡｌ2Ｏ3系酸化物が生成して工具寿命を短縮させることがある。そのため、Ａｌ量の上限を０．００４％にすることが好ましい。 Al is an extremely important element in the present invention. In order to generate a Ca—Si—Al-based oxide that is soft and contributes to improvement of machinability, 0.0005% was made the lower limit. Further, if Al is added excessively, AlN is generated and N is fixed, and the machinability improving effect by adding N is impaired, so the content is limited to 0.005% or less. Furthermore, if the amount of Al is excessive, a hard Al 2 O 3 -based oxide may be generated and the tool life may be shortened. Therefore, it is preferable to set the upper limit of the Al amount to 0.004%.
Ｂは、ＢＮとして鋼中に析出することにより被削性を向上させる元素であり、０．００２％以上を添加する。一方、０．０１５％を超えるＢを添加しても効果は飽和するため、上限を０．０１５％以下とする。Ｂを多量に添加すると、耐火物の損傷など製鋼上の問題もあるため、０．０１％以下にすることが望ましい。 B is an element that improves machinability by being precipitated in steel as BN, and is added in an amount of 0.002% or more. On the other hand, since the effect is saturated even if B exceeding 0.015% is added, the upper limit is made 0.015% or less. If B is added in a large amount, there are also problems in steel making such as damage to the refractory, so it is desirable to make it 0.01% or less.
Ｏは、被削性を向上させる低融点のＣａ−Ｓｉ−Ａｌ系酸化物の生成に必要な元素であり、下限を０．０００５％とする。一方、Ｏ量が多すぎると、Ｃａの酸化物を生じて、硫化物の形態制御する効果が失われる。さらに、Ｃａ系介在物が電縫溶接衝合部に残存し、酸化物欠陥の発生を助長するため、Ｏ量の上限を０．００６％に定めた。 O is an element necessary for producing a low melting point Ca—Si—Al-based oxide that improves machinability, and the lower limit is made 0.0005%. On the other hand, if the amount of O is too large, Ca oxide is produced and the effect of controlling the form of sulfide is lost. Furthermore, the upper limit of the amount of O is set to 0.006% in order that Ca inclusions remain in the ERW welding abutting portion and promote the generation of oxide defects.
Ｃａは、本発明では、被削性を向上させる低融点のＣａ−Ｓｉ−Ａｌ系酸化物を生成し、さらに、圧延方向に伸長しやすいＭｎＳを楕円状の（Ｃａ、Ｍｎ）Ｓに変化させる、極めて重要な元素である。特に、Ｃａの添加により、材質異方性を低減させるとともに、造管成型時の端面アップセットによって電縫溶接衝合部近傍に生じる、メタルフローの立ち上がりに沿ったＭｎＳの伸長を防止し、電縫溶接部品質を向上させる。それらの効果を得るために、Ｃａ量の下限を０．０００２％とした。Ｃａ量の好ましい下限は、０．００１％以上である。一方、Ｃａを過剰に添加すると、ＣａＯが電縫溶接衝合部に集積して溶接部の健全性が損なわれるため、Ｃａ量の上限を０．００５％とした。 In the present invention, Ca generates a low-melting point Ca—Si—Al-based oxide that improves machinability, and further changes MnS that is easily elongated in the rolling direction to elliptical (Ca, Mn) S. Is an extremely important element. In particular, the addition of Ca reduces material anisotropy and prevents MnS from stretching along the rise of the metal flow that occurs near the end of the ERW weld due to the end face upset during pipe forming. Improve the quality of the welded seam. In order to obtain these effects, the lower limit of the Ca content is set to 0.0002%. A preferable lower limit of the Ca content is 0.001% or more. On the other hand, when Ca is added excessively, CaO accumulates in the ERW welding abutting portion and the soundness of the welded portion is impaired, so the upper limit of the Ca amount is set to 0.005%.
本発明では、上記の元素に加えて、電縫鋼管の機械的特性や耐食性を調整するためにＣｒとＭｏを添加することができる。但し、これらの元素は焼き入れ性を高めるために、多量に添加すると強度が高くなりすぎて被削性が低下するために、Ｃｒの上限値は２％、Ｍｏの上限値は１％と定め、いずれも下限値はその効果が発揮される限界である０．０１％とした。 In the present invention, in addition to the above elements, Cr and Mo can be added to adjust the mechanical properties and corrosion resistance of the electric resistance welded steel pipe. However, in order to increase the hardenability of these elements, if added in a large amount, the strength becomes too high and the machinability decreases, so the upper limit value of Cr is set to 2% and the upper limit value of Mo is set to 1%. In both cases, the lower limit was set to 0.01%, which is the limit at which the effect was exhibited.
さらに、本発明では、ＮとＢの含有量（質量％）［Ｎ］および［Ｂ］について、
０．６５＜［Ｎ］／［Ｂ］＜１．０４
を満足させることにより、被削性のさらなる向上を得ることができる。これは、添加したＢの５０％はＢＮとして析出し、Ｂと結合しないＮは鋼中に固溶して切削温度における青熱脆性を誘発し、いずれも切り屑分断性を良好なものとするが、固溶Ｎが多すぎるとかえって硬くなりすぎて工具寿命を低下させることに基づく。固溶Ｎによる被削性向上の効果を得るには、［Ｎ］／［Ｂ］を０．６５超にすることが好ましい。一方、ＢＮの析出量を確保して被削性を向上させ、さらに過剰な固溶Ｎの含有を防止するには、［Ｎ］／［Ｂ］を１．０４未満にすることが好ましい。
Furthermore, in this invention, about content (mass%) [N] and [B] of N and B,
0.65 <[N] / [B] <1.04
By satisfying the above, further improvement of machinability can be obtained. This is because 50% of the added B precipitates as BN, and N that does not combine with B dissolves in the steel and induces blue heat embrittlement at the cutting temperature, both of which have good chip breaking properties. However, it is based on the fact that too much solute N is too hard and the tool life is shortened. In order to obtain the effect of improving machinability by solute N, it is preferable to set [N] / [B] to more than 0.65. On the other hand, it is preferable to set [N] / [B] to less than 1.04 in order to secure the precipitation amount of BN to improve the machinability and to prevent the excessive solute N from being contained.
上記化学成分で構成された鋼は、転炉あるいは電気炉で溶製され、鋳造後、熱間圧延により所定の幅、厚さのホットコイルとされる。その後、冷間あるいは温間にて造管ロールにより管状に成型され、通電加熱あるいは誘導加熱の方式によりシーム溶接される。溶接部のビード切削や定型の工程を経た管は、必要に応じて熱処理され、あるいは熱間で絞り圧延され、また、場合によっては、さらに冷間で引抜等の加工を受けた後、自動車や一般機械などの部材となる電縫鋼管として、切削加工等を受けて使用に供される。 The steel composed of the above chemical components is melted in a converter or an electric furnace, and after casting, is hot-rolled into a hot coil having a predetermined width and thickness. Thereafter, it is formed into a tubular shape by a tube-forming roll in the cold or warm state, and seam welded by a method of energization heating or induction heating. Pipes that have undergone bead cutting of the welded part or a standard process are heat-treated as necessary, or hot drawn and rolled, and in some cases, after undergoing cold drawing or other processing, As an electric resistance welded steel pipe to be a member of a general machine or the like, it is used after being subjected to cutting or the like.
以下、本発明を実施例によりさらに具体的に説明する。 Hereinafter, the present invention will be described more specifically with reference to examples.
表１に示す組成を有する各種鋼を溶製し、鋳造した。得られた鋳片を１１５０℃に加熱し、圧延仕上げ温度９００℃、巻き取り温度６３０℃で熱間圧延し、板厚６．５ｍｍの鋼板とした。これらの熱間圧延鋼板を所定の幅にスリットし、ロール成形した後、高周波誘導加熱方式による電縫溶接にて外径９０ｍｍの電縫溶接鋼管とした。引き続きこれらの鋼管を高周波誘導加熱により１０００℃に加熱してストレッチレデューサーにより縮径圧延を施し、外径３０ｍｍ、肉厚６ｍｍの電縫鋼管を製造した。さらにこれらの鋼管を冷間引き抜きにより、外径２２ｍｍ、肉厚５ｍｍに伸管した。 Various steels having the compositions shown in Table 1 were melted and cast. The obtained slab was heated to 1150 ° C. and hot-rolled at a rolling finishing temperature of 900 ° C. and a winding temperature of 630 ° C. to obtain a steel plate having a thickness of 6.5 mm. These hot-rolled steel sheets were slit to a predetermined width, roll-formed, and then formed into an electric resistance welded steel pipe having an outer diameter of 90 mm by electric resistance welding using a high frequency induction heating method. Subsequently, these steel pipes were heated to 1000 ° C. by high-frequency induction heating and subjected to reduction rolling with a stretch reducer to produce ERW steel pipes having an outer diameter of 30 mm and a wall thickness of 6 mm. Further, these steel pipes were drawn by cold drawing to an outer diameter of 22 mm and a wall thickness of 5 mm.
これらの電縫鋼管に対してドリル穿孔試験を行い、被削性を評価した。ドリル穿孔試験は、電縫鋼管のＣ断面に対してＬ方向に向けて、任意の切削速度にて、ＮＡＣＨＩ（登録商標）製のドリルで９ｍｍ深さの穴を複数回開け続け、累計穴深さ１０００ｍｍまで切削可能だった最高の切削速度（いわゆるＶＬ１０００，単位：ｍ／ｍｉｎ）を求める方法を用いた。表２に試験条件を示す。 Drill drilling tests were conducted on these ERW steel pipes to evaluate machinability. In the drill drilling test, a 9 mm deep hole was continuously drilled several times with a drill made of NACHI (registered trademark) at an arbitrary cutting speed in the L direction with respect to the C section of the ERW steel pipe. A method for obtaining the maximum cutting speed (so-called VL1000, unit: m / min) that was capable of cutting up to 1000 mm was used. Table 2 shows the test conditions.
また、切り屑処理性を評価するために、ドリル穿孔試験の際に得られた切り屑を採取して、切り屑が２０ｍｍを越えた曲率半径で３巻き以上連続してカールして長く伸びた場合を×とし、巻き数が多くとも曲率半径が小さいもの、あるいは曲率半径が大きくとも切り屑長さが１００ｍｍに達しなかったもの○とし、その中間を△とした。 In addition, in order to evaluate the chip disposability, the chips obtained during the drill drilling test were collected, and the chips were curled and extended longer by 3 or more turns with a radius of curvature exceeding 20 mm. The case was marked with x, the number of turns was small with a small radius of curvature, or the number of turns was large with a large radius of curvature and the chip length did not reach 100 mm.
さらに、溶接部の健全性を調べるために、冷間引き抜き前の管の電縫溶接部の反対側に切り込みを入れて、電縫溶接部が中央となるように展開して板状に戻し、ノッチ位置を電縫溶接部と一致させたサブサイズシャルピーＶノッチ試験片を各々１０本づつ作成し、１６０℃でシャルピー衝撃試験を実施した。試験後の破面を実体顕微鏡にて観察し、酸化物欠陥の面積率を測定した。欠陥面積率が０．０５％以上の場合を欠陥ありと判定した。結果を併せて表１に示す。 Furthermore, in order to investigate the soundness of the welded part, cut in the opposite side of the ERW welded part of the tube before cold drawing, expand it so that the ERW welded part becomes the center, and return it to a plate shape, Ten sub-size Charpy V-notch test pieces each having the notch position coincident with the ERW weld were prepared and subjected to a Charpy impact test at 160 ° C. The fracture surface after the test was observed with a stereomicroscope, and the area ratio of oxide defects was measured. The case where the defect area ratio was 0.05% or more was determined to be defective. The results are also shown in Table 1.
表１に示した鋼番１〜１０は本発明である。いずれもＶＬ１０００が１００ｍ／ｍｉｎ以上の良好な被削性を示し、切り屑処理性も良好である。いずれも電縫溶接部は健全であった。なお、［Ｎ］／［Ｂ］が好ましい範囲内（０．６５超、１．０４未満）である鋼番１、２、４〜８、１０は、鋼番３、９に比べて、より被削性及び切り屑処理性が優れている。 Steel numbers 1 to 10 shown in Table 1 are the present invention. In any case, VL1000 exhibits good machinability of 100 m / min or more, and the chip disposability is also good. In both cases, the ERW weld was healthy. Steel numbers 1, 2, 4 to 8 and 10 in which [N] / [B] are within a preferable range (over 0.65 and less than 1.04) are more covered than steel numbers 3 and 9. Excellent machinability and chip disposal.
それに対して、鋼番１１はＳが低い一般的な電縫鋼管であり、被削性が良くない。鋼番１２〜１４は一般的な電縫鋼管よりもＳ量が高く、被削性は改善されているものの、何れもＶＬ１０００が１００ｍ／ｍｉｎに未達である。鋼番１２はＢ量が低すぎた例、鋼番１３はＣａ量が低すぎた例、鋼番１４はＡｌ量が高すぎた例であり、被削性が不十分である。また鋼番１５はＣａ量が高すぎて、被削性は良好であったものの、溶接欠陥が発生した例である。鋼番１６は、Ｓｉ量が高すぎて被削性は良好であったものの、溶接欠陥が発生した例である。鋼番１７は、Ｓｉ量が低すぎて脱酸が不十分となりＯが高くなり過ぎて、被削性は良好であったものの、溶接欠陥が発生した例である。鋼番１８はＡｌ量が低すぎて被削性が不十分である。 On the other hand, the steel number 11 is a general ERW steel pipe having a low S, and the machinability is not good. Steel Nos. 12 to 14 have an S amount higher than that of a general ERW steel pipe and machinability is improved, but in all cases, VL1000 does not reach 100 m / min. Steel No. 12 is an example in which the B amount is too low, Steel No. 13 is an example in which the Ca amount is too low, and Steel No. 14 is an example in which the Al amount is too high, and machinability is insufficient. Steel No. 15 is an example in which a weld defect occurred although the amount of Ca was too high and machinability was good. Steel No. 16 is an example in which a weld defect occurred although the amount of Si was too high and machinability was good. Steel No. 17 is an example in which welding defects occurred although the amount of Si was too low, deoxidation was insufficient and O was too high, and machinability was good. In steel No. 18, the amount of Al is too low and the machinability is insufficient.
組織観察および電解抽出した析出物の調査により、Ｂ量が低い鋼番１２は、ＢＮの生成が不十分であることがわかった。また、Ｃａ量が低い鋼番１３は、軟質なＣａ−Ｓｉ−Ａｌ系酸化物の生成が不十分であり、延伸したＭｎＳが見られた。Ａｌ量が多い鋼番１４は、ＡｌＮ及び硬質なＡｌ2Ｏ3が生成し、Ａｌ量が低い鋼番１８は、Ｃａ−Ｓｉ−Ａｌ系酸化物の生成が不十分であることがわかった。 Observation of the structure and investigation of the electrolytically extracted precipitates revealed that Steel No. 12 with a low B content produced insufficient BN. Steel No. 13, which has a low Ca content, had insufficient generation of a soft Ca—Si—Al-based oxide, and stretched MnS was observed. It was found that steel No. 14 with a large amount of Al produced AlN and hard Al 2 O 3, and Steel No. 18 with a low Al amount produced insufficient generation of Ca—Si—Al-based oxides.
Claims (3)
Ｃ：０．０２〜０．２％、
Ｓｉ：０．０５〜０．５％、
Ｍｎ：０．２〜２．０％、
Ｐ：０．００１〜０．０３％、
Ｓ：０．０１〜０．０３％、
Ｎ：０．００２〜０．０２％、
Ａｌ：０．０００５〜０．００５％、
Ｂ：０．００２〜０．０１５％、
Ｏ：０．０００５〜０．００６％、
Ｃａ：０．０００２〜０．００５％
を含有し、残部がＦｅおよび不可避的不純物からなることを特徴とする被削性に優れた電縫鋼管。 % By mass
C: 0.02 to 0.2%,
Si: 0.05 to 0.5%,
Mn: 0.2 to 2.0%,
P: 0.001 to 0.03%,
S: 0.01-0.03%,
N: 0.002 to 0.02%,
Al: 0.0005 to 0.005%,
B: 0.002 to 0.015%,
O: 0.0005 to 0.006%,
Ca: 0.0002 to 0.005%
An electric-welded steel pipe excellent in machinability, characterized in that the balance is made of Fe and inevitable impurities.
Ｃｒ：０．０１〜２．０％、
Ｍｏ：０．０１〜１．０％
の一方または双方を含有することを特徴とする請求項１に記載の被削性に優れた電縫鋼管。 Furthermore, in mass%,
Cr: 0.01 to 2.0%,
Mo: 0.01 to 1.0%
One or both of these are contained, The electric-resistance-welded steel pipe excellent in machinability of Claim 1 characterized by the above-mentioned.
０．６５＜［Ｎ］／［Ｂ］＜１．０４
を満足することを特徴とする請求項１または２に記載の被削性に優れた電縫鋼管。 Furthermore, the contents (mass%) of N and B [N] and [B]
0.65 <[N] / [B] <1.04
The electric-welded steel pipe excellent in machinability according to claim 1 or 2, wherein:
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|---|---|---|---|---|
| JPH04187742A (en) * | 1990-11-21 | 1992-07-06 | Nippon Steel Corp | Electric resistance welded steel tube for machine structure excellent in machinability |
| JP2000094009A (en) * | 1998-09-22 | 2000-04-04 | Kawasaki Steel Corp | Manufacture of steel tube |
| JP2004124228A (en) * | 2002-10-07 | 2004-04-22 | Jfe Steel Kk | Method for producing electric resistance welded tube having low yield ratio for building and square column |
| WO2008066194A1 (en) * | 2006-11-28 | 2008-06-05 | Nippon Steel Corporation | Free-cutting steel excellent in manufacturability |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04187742A (en) * | 1990-11-21 | 1992-07-06 | Nippon Steel Corp | Electric resistance welded steel tube for machine structure excellent in machinability |
| JP2000094009A (en) * | 1998-09-22 | 2000-04-04 | Kawasaki Steel Corp | Manufacture of steel tube |
| JP2004124228A (en) * | 2002-10-07 | 2004-04-22 | Jfe Steel Kk | Method for producing electric resistance welded tube having low yield ratio for building and square column |
| WO2008066194A1 (en) * | 2006-11-28 | 2008-06-05 | Nippon Steel Corporation | Free-cutting steel excellent in manufacturability |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014009374A (en) * | 2012-06-29 | 2014-01-20 | Jfe Steel Corp | Electroseamed steel pipe having excellent low temperature toughness and method for producing the same |
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