JP2011226001A - Fabric and clothing preventing sweat stains - Google Patents
Fabric and clothing preventing sweat stains Download PDFInfo
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- JP2011226001A JP2011226001A JP2010094051A JP2010094051A JP2011226001A JP 2011226001 A JP2011226001 A JP 2011226001A JP 2010094051 A JP2010094051 A JP 2010094051A JP 2010094051 A JP2010094051 A JP 2010094051A JP 2011226001 A JP2011226001 A JP 2011226001A
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- 230000000052 comparative effect Effects 0.000 description 5
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- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 238000004043 dyeing Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
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- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920000747 poly(lactic acid) Polymers 0.000 description 2
- 239000004626 polylactic acid Substances 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000012620 biological material Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
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- 150000002334 glycols Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- 239000005080 phosphorescent agent Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000010020 roller printing Methods 0.000 description 1
- 238000010022 rotary screen printing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- IBBQVGDGTMTZRA-UHFFFAOYSA-N sodium;2-sulfobenzene-1,3-dicarboxylic acid Chemical compound [Na].OC(=O)C1=CC=CC(C(O)=O)=C1S(O)(=O)=O IBBQVGDGTMTZRA-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
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- 150000003609 titanium compounds Chemical class 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
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- Woven Fabrics (AREA)
- Knitting Of Fabric (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
本発明は、優れた汗じみ防止効果を有し、かつべとつき感が低減された汗じみ防止布帛および該汗じみ防止布帛を用いてなる汗じみ防止衣料に関する。 The present invention relates to a sweat-preventing fabric having an excellent anti-sweating effect and a reduced feeling of stickiness, and a sweat-preventing garment using the sweat-preventing fabric.
従来、汗をかいた際に発生する汗じみを防止する汗じみ防止布帛として、布帛の片側表面にのみ撥水加工したものが提案されている（例えば、特許文献１、特許文献２参照）。
しかしながら、従来の汗じみ防止布帛では、汗じみ防止効果の点でまだ十分とはいえなかった。また、べとつき感があるという問題があった。
2. Description of the Related Art Conventionally, as a sweat-preventing fabric that prevents sweating that occurs when sweating, a fabric that has been subjected to water-repellent treatment only on one surface of the fabric has been proposed (see, for example, Patent Document 1 and Patent Document 2).
However, conventional sweat-proof fabrics have not been sufficient in terms of sweat-prevention effects. There was also a problem of stickiness.
本発明は上記の背景に鑑みなされたものであり、その目的は、優れた汗じみ防止効果を有し、かつべとつき感が低減された汗じみ防止布帛および該汗じみ防止布帛を用いてなる汗じみ防止衣料を提供することにある。 The present invention has been made in view of the above background, and an object of the present invention is to provide a sweat-preventing fabric having an excellent sweat-preventing effect and having reduced stickiness, and a sweat-preventing garment using the sweat-preventing fabric. It is to provide.
本発明者は上記の課題を達成するため鋭意検討した結果、ポリエステル繊維で構成される汗じみ防止布帛において、布帛の一方表面にのみ撥水剤を付着させると同時に、他方表面に凹凸構造を形成すると、優れた汗じみ防止効果を有し、かつべとつき感が低減された汗じみ防止布帛が得られることを見出し、さらに鋭意検討を重ねることにより本発明を完成するに至った。 As a result of intensive studies to achieve the above-mentioned problems, the present inventor made a sweat-repellent fabric composed of polyester fibers to attach a water repellent agent only to one surface of the fabric and at the same time form an uneven structure on the other surface. The present inventors have found that a sweat-preventing fabric having an excellent anti-sweating effect and having a reduced feeling of stickiness can be obtained, and the present invention has been completed by intensive studies.
かくして、本発明によれば「ポリエステル繊維で構成される汗じみ防止布帛であって、該布帛の一方表面にのみ撥水剤が付着しており、他方表面に凹凸構造を有することを特徴とする汗じみ防止布帛。」が提供される。
その際、前記ポリエステル繊維の単繊維繊度が２．０ｄｔｅｘ以下であることが好ましい。また、布帛を構成する織編組織が、裏鹿の子編組織、裏ハニカム編組織、二重リップル編物、および緯二重織物からなる群より選択されるいずれかであることが好ましい。
また、本発明によれば、前記の汗じみ防止布帛を、撥水剤が付着した表面が外気側に位置するよう用いてなる汗じみ防止衣料が提供される。その際、該衣料が、撥水剤が付着した縫糸を用いて縫製されていることが好ましい。
Thus, according to the present invention, “a sweat-repellent fabric composed of polyester fibers, wherein the water-repellent agent is attached only to one surface of the fabric and has a concavo-convex structure on the other surface. Prevention fabric ".
In that case, it is preferable that the single fiber fineness of the said polyester fiber is 2.0 dtex or less. Moreover, it is preferable that the woven or knitted structure constituting the fabric is any one selected from the group consisting of a back deer knitted structure, a back honeycomb knitted structure, a double ripple knitted fabric, and a weft double woven fabric.
In addition, according to the present invention, there is provided a sweat-preventing garment using the above-mentioned sweat-preventing fabric so that the surface to which the water repellent is attached is located on the outside air side. In that case, it is preferable that the garment is sewn using a sewing thread to which a water repellent is attached.
本発明によれば、優れた汗じみ防止効果を有し、かつべとつき感が低減された汗じみ防止布帛および該汗じみ防止布帛を用いてなる汗じみ防止が得られる。 ADVANTAGE OF THE INVENTION According to this invention, it has the sweat-prevention effect which used the sweat-proof fabric which has the outstanding sweat-prevention effect and reduced the feeling of stickiness, and this sweat-proof fabric is obtained.
以下、本発明の実施の形態について詳細に説明する。
本発明の汗じみ防止布帛は、ポリエステル繊維で構成される汗じみ防止布帛であって、該布帛の一方表面にのみ撥水剤が付着しており、他方表面に凹凸構造を有する布帛である。
Hereinafter, embodiments of the present invention will be described in detail.
The sweat-preventing fabric of the present invention is a sweat-preventing fabric composed of polyester fibers, which has a water-repellent agent attached to only one surface of the fabric and has a concavo-convex structure on the other surface.
ここで、撥水剤が布帛の一方表面にのみ付着していることが肝要である。布帛の両面に撥水剤が付着していると、布帛が汗を吸わなくなるためべとつき感が発生し好ましくない。また、布帛の一方表面にのみ付着する撥水剤は、表面に部分的に付着していてもよいが、表面全面に付着していることが優れた汗じみ防止効果を得る上で好ましい。 Here, it is important that the water repellent is attached only to one surface of the fabric. If the water repellent is attached to both surfaces of the fabric, the fabric will not absorb sweat, which is not preferable because a sticky feeling is generated. Further, the water repellent agent that adheres only to one surface of the fabric may partially adhere to the surface, but it is preferable to adhere to the entire surface to obtain an excellent sweating prevention effect.
また、本発明の汗じみ防止布帛において、撥水剤が付着していない方の表面に凹凸構造が形成されていることが肝要である。かかる凹凸構造により、肌と布帛との接触面積が小さくなるためべとつき感が低減される。また同時に、汗が凹凸構造の凹部に沿って拡散されることにより乾燥速度が速くなるため、汗じみ防止効果が向上する。撥水剤が付着している表面については、凹凸構造が形成されていてもよいし、凹凸構造が形成されていないフラットな表面でもよいが、表面全面に撥水剤を付着させる上で凹凸構造が形成されていないフラットな表面であることが好ましい。 Moreover, in the fabric for preventing sweating of the present invention, it is important that a concavo-convex structure is formed on the surface to which the water repellent is not attached. Such an uneven structure reduces the feeling of stickiness because the contact area between the skin and the fabric is reduced. At the same time, sweat is diffused along the concave and convex portions of the concavo-convex structure, so that the drying speed is increased, so that the sweat prevention effect is improved. The surface on which the water repellent is attached may have a concavo-convex structure, or may be a flat surface on which no concavo-convex structure is formed. It is preferable that the surface is a flat surface on which no is formed.
なお、本発明でいう「凹凸構造」とは、織編組織によって形成される凹凸構造であって、一辺が５００μｍの正方形よりも面積が大であり、かつ深さが５００μｍ以上の凹部が表面に存在する、という意味である。 The “concavo-convex structure” referred to in the present invention is an uneven structure formed by a woven or knitted structure, and has an area larger than a square having a side of 500 μm and a depth of 500 μm or more on the surface. It means that it exists.
本発明の汗じみ防止布帛において、少なくとも一方表面に前記の凹凸構造を有する布帛であれば織編組織は特に制限されないが、一方の表面にのみ凹凸構造を有する織編組織が好ましく、優れた汗じみ防止効果と低べとつき感を得る上で、裏鹿の子編組織、裏ハニカム編組織、二重リップル編物、緯二重織物などが好ましい。 In the fabric for preventing sweating according to the present invention, the woven or knitted structure is not particularly limited as long as it is a fabric having the above uneven structure on at least one surface, but a woven or knitted structure having an uneven structure only on one surface is preferable, and excellent sweating prevention. In order to obtain an effect and a low stickiness, a back knitting knitted structure, a back honeycomb knitted structure, a double ripple knitted fabric, a weft double woven fabric and the like are preferable.
また、布帛の織編密度としては、優れた汗じみ防止効果を得る上で高密度であるほうが好ましく、例えば編物であれば、４０コース／２．５４ｃｍ以上（より好ましくは４０〜１００コース／２．５４ｃｍ）かつ３０ウエール／２．５４ｃｍ以上（より好ましくは３０〜９０コース／２．５４ｃｍ）であることが好ましい。また、織物であれば経緯とも８０本／２．５４ｃｍ以上（より好ましくは１００〜２００本／２．５４ｃｍ）であることが好ましい。 Further, the woven / knitted density of the fabric is preferably higher in order to obtain an excellent sweating prevention effect. For example, in the case of a knitted fabric, 40 courses / 2.54 cm or more (more preferably 40-100 courses / 2. 54 cm) and 30 wales / 2.54 cm or more (more preferably 30 to 90 courses / 2.54 cm). In the case of a woven fabric, the background is preferably 80 pieces / 2.54 cm or more (more preferably 100 to 200 pieces / 2.54 cm).
本発明の汗じみ防止布帛はポリエステル繊維で構成されることが、優れた汗じみ防止効果と低べとつき感を得る上で肝要である。ここで、布帛がポリエステル繊維のみで構成されることが最も好ましいが、布帛重量に対して５０重量％以下であれば、他の繊維が含まれていてもよい。 It is essential for the sweat-proof fabric of the present invention to be composed of polyester fibers in order to obtain an excellent sweat-proof effect and low stickiness. Here, it is most preferable that the fabric is composed of only polyester fibers, but other fibers may be included as long as the fabric weight is 50% by weight or less.
前記ポリエステル繊維はジカルボン酸成分とジグリコール成分とから製造される。ジカルボン酸成分としては、主としてテレフタル酸が用いられることが好ましく、ジグリコール成分としては主としてエチレングリコール、トリメチレングリコール及びテトラメチレングリコールから選ばれた１種以上のアルキレングリコールを用いることが好ましい。また、ポリエステル樹脂には、前記ジカルボン酸成分及びグリコール成分の他に第３成分を含んでいてもよい。該第３成分としては、カチオン染料可染性アニオン成分、例えば、ナトリウムスルホイソフタル酸；テレフタル酸以外のジカルボン酸、例えばイソフタル酸、ナフタレンジカルボン酸、アジピン酸、セバシン酸；及びアルキレングリコール以外のグリコール化合物、例えばジエチレングリコール、ポリエチレングリコール、ビスフェノールＡ、ビスフェノールスルフォンの１種以上を用いることができる。かかるポリエステルとしては、マテリアルリサイクルまたはケミカルリサイクルされたポリエステルや、バイオマスすなわち生物由来の物質を原材料として得られたモノマー成分を使用してなるポリエチレンテレフタレート、ポリ乳酸、ステレオコンプレックスポリ乳酸であってもよい。さらには、特開２００４−２７００９７号公報や特開２００４−２１１２６８号公報に記載されているような、特定のリン化合物およびチタン化合物を含む触媒を用いて得られたポリエステルでもよい。 The polyester fiber is produced from a dicarboxylic acid component and a diglycol component. As the dicarboxylic acid component, terephthalic acid is preferably used mainly, and as the diglycol component, it is preferable to use one or more alkylene glycols selected from ethylene glycol, trimethylene glycol and tetramethylene glycol. Moreover, the polyester resin may contain a third component in addition to the dicarboxylic acid component and the glycol component. Examples of the third component include cationic dye dyeable anion components such as sodium sulfoisophthalic acid; dicarboxylic acids other than terephthalic acid such as isophthalic acid, naphthalenedicarboxylic acid, adipic acid, sebacic acid; and glycol compounds other than alkylene glycol. For example, one or more of diethylene glycol, polyethylene glycol, bisphenol A, and bisphenol sulfone can be used. Such polyester may be material recycled or chemically recycled polyester, or polyethylene terephthalate, polylactic acid, or stereocomplex polylactic acid using a monomer component obtained using biomass, that is, a biological material as a raw material. Furthermore, the polyester obtained using the catalyst containing the specific phosphorus compound and titanium compound which are described in Unexamined-Japanese-Patent No. 2004-270097 and 2004-21268 may be sufficient.
前記ポリエステル繊維の形状としては、短繊維でもよいし長繊維（マルチフィラメント）でもよいが、吸水性を向上させることによりべとつき感を低減する上で長繊維であることが好ましい。さらには、通常の仮撚捲縮加工が施された仮撚捲縮加工糸や２種以上の構成糸条を空気混繊加工や複合仮撚加工させた複合糸であってもよい。 The shape of the polyester fiber may be a short fiber or a long fiber (multifilament), but is preferably a long fiber in order to reduce stickiness by improving water absorption. Furthermore, a false twisted crimped yarn subjected to a normal false twist crimping process or a composite yarn obtained by subjecting two or more kinds of constituent yarns to air-mixing or composite false twisting may be used.
前記ポリエステル繊維の単繊維繊度、総繊度、単糸数は、単繊維繊度０．１〜１０．０ｄｔｅｘ、総繊度２０〜３００ｄｔｅｘ、単糸数１０〜２００本の範囲であることが好ましい。特に、布帛の吸水性を向上させることによりべとつき感を低減する上で単糸繊維繊度が２．０ｄｔｅｘ以下（より好ましくは０．０００１〜２．０ｄｔｅｘ）であることが特に好ましい。 The single fiber fineness, total fineness, and single yarn number of the polyester fiber are preferably in the range of single fiber fineness of 0.1 to 10.0 dtex, total fineness of 20 to 300 dtex, and single yarn number of 10 to 200. In particular, it is particularly preferable that the single yarn fiber fineness is 2.0 dtex or less (more preferably 0.0001 to 2.0 dtex) in order to reduce the feeling of stickiness by improving the water absorption of the fabric.
また、前記ポリエステル繊維において、単糸繊維の断面形状には制限はなく、通常の円形断面のほかに三角、扁平、くびれ付扁平、十字形、六様形、あるいは中空形などの異型断面形状であってもよい。 Further, in the polyester fiber, the cross-sectional shape of the single yarn fiber is not limited, and in addition to the normal circular cross-section, the cross-sectional shape is triangular, flat, constricted flat, cross-shaped, hexagonal, hollow, or other irregular cross-sectional shapes. There may be.
本発明の汗じみ防止布帛は例えば以下の製造方法により製造することができる。
まず、前記のようなポリエステル繊維を用いて織編物を織編成する。ここで、織編物の織編組織としては、少なくとも一方表面に凹凸構造を有する織編組織であれば特に限定されないが、一方の表面にのみ凹凸構造を有する織編組織が好ましく、前記のような裏鹿の子編組織、裏ハニカム編組織、二重リップル編物、緯二重織物などが好適に例示される。なお、製編織に用いる製編織機械としては通常のものでよい。
The sweat-proof fabric of the present invention can be produced, for example, by the following production method.
First, a woven or knitted fabric is knitted using the polyester fiber as described above. Here, the woven or knitted structure of the knitted or knitted fabric is not particularly limited as long as it has a concavo-convex structure on at least one surface, but a woven or knitted structure having a concavo-convex structure only on one surface is preferable. Preferable examples include a reverse deer knitting structure, a reverse honeycomb knitting structure, a double ripple knitted structure, and a weft double woven fabric. In addition, a normal weaving machine may be used as the weaving machine.
次いで、前記布帛に必要に応じて染色仕上げ加工や親水化加工（吸水加工）を施す。特に、布帛に親水化加工（吸水加工）を施すことは、優れた汗じみ防止効果と低べとつき感を得る上で好ましいことである。親水剤としては例えば高松油脂（株）ＳＲ−１０００など通常のものでよい。また、かかる親水化加工（吸水加工）は染色工程と同時でもよいし、別工程でもよい。 Next, the fabric is subjected to a dyeing finishing process or a hydrophilization process (water absorption process) as necessary. In particular, it is preferable to apply a hydrophilic treatment (water absorption treatment) to the fabric in order to obtain an excellent anti-sweat effect and low stickiness. The hydrophilic agent may be a normal one such as Takamatsu Yushi Co., Ltd. SR-1000. Further, the hydrophilization process (water absorption process) may be performed simultaneously with the dyeing process or may be performed separately.
次いで、かかる布帛の一方の表面にのみ撥水剤を付着させる。ここで、布帛の一方表面にのみ凹凸構造が形成されている場合は、凹凸構造が形成されていない方の表面にのみ撥水剤を付着させる。 Subsequently, a water repellent is made to adhere only to one surface of this fabric. Here, when the concavo-convex structure is formed only on one surface of the fabric, the water repellent is attached only to the surface where the concavo-convex structure is not formed.
撥水剤としては、特に限定されず、フッ素系、シリコン系、ワックス系などの撥水剤が例示される。また、撥水剤をバインダー樹脂とともに布帛に付着させることが、撥水性の耐久性を高める上で好ましい。かかる撥水剤としては、繊維との接触角が９０度以下（好ましくは７０度以下、さらに好ましくは５０度以下）のものが好適である。該接触角が小さい程ぬれ性がよいため、バインダー樹脂が単糸繊維表面に均一に皮膜する。その結果、撥水性の耐久性が向上するだけでなく布帛のソフトな風合いが損なわれることがない。繊維との接触角が９０度以下のバインダー樹脂としては、メラミン樹脂、エポキシ樹脂、ウレタン樹脂、アクリル系樹脂などが例示される。 The water repellent is not particularly limited, and examples thereof include fluorine-based, silicon-based, and wax-based water repellents. In addition, it is preferable to attach the water repellent together with the binder resin to the fabric in order to improve the water repellency durability. As such a water repellent, those having a contact angle with the fiber of 90 degrees or less (preferably 70 degrees or less, more preferably 50 degrees or less) are suitable. Since the wettability is better as the contact angle is smaller, the binder resin uniformly coats the surface of the single yarn fiber. As a result, the durability of water repellency is not only improved, but the soft texture of the fabric is not impaired. Examples of the binder resin having a contact angle with the fiber of 90 degrees or less include melamine resin, epoxy resin, urethane resin, and acrylic resin.
また、撥水剤とバインダー樹脂の布帛に対する付着量としては、各々樹脂固形分重量基準で、撥水剤０．０１〜４０ｇ／ｍ２（より好ましくは１〜１０ｇ／ｍ２）、バインダー樹脂０．０１〜４０ｇ／ｍ２（より好ましくは１〜１０ｇ／ｍ２）の範囲が適当である。 In addition, the adhesion amounts of the water repellent and the binder resin to the cloth are each 0.01 to 40 g / m 2 (more preferably 1 to 10 g / m 2 ) of the water repellent and 0 binder resin based on the weight of the resin solid content. A range of 0.01 to 40 g / m 2 (more preferably 1 to 10 g / m 2 ) is appropriate.
前記の撥水剤とバインダー樹脂とは、通常両者の配合組成物として布帛に付与される。その際、かかる配合組成物は水系、溶剤系のいずれで構成してもよいが、加工工程の作業環境上水系の方が好ましい。なお、溶剤としては、トルエン、イソプロピルアルコール、ジメチルホルムアミド、メチエチルケトン、酢酸エチルなどが例示される。この配合組成物には、エポキシ系などの架橋剤を併用してもよい。さらに、布帛に対する付着性を向上させる等の目的で適当な添加剤をさらに配合してもよい。 The water repellent and the binder resin are usually applied to the fabric as a blended composition of both. In this case, the blended composition may be composed of either an aqueous system or a solvent system, but an aqueous system is preferable in view of the working environment of the processing step. Examples of the solvent include toluene, isopropyl alcohol, dimethylformamide, methyl ethyl ketone, and ethyl acetate. This blended composition may be used in combination with an epoxy-based crosslinking agent. Furthermore, you may further mix | blend an appropriate additive for the objective of improving the adhesiveness with respect to a fabric.
前記の撥水剤、または撥水剤とバインダー樹脂とを布帛に付着させる方法としては、例えばグラビアロール法、キスロール法、泡加工法、ロータリスクリーン捺染法、フラットスクリーン法、ローラー捺染法等が例示される。また、撥水剤の塗布に際しては、撥水剤が布帛の反対面までは浸透しないように、撥水剤を含む配合組成物の粘度、スキージ等による布帛への付与圧力、捺染速度を適宜調整する必要がある。 Examples of the method for adhering the water repellent or the water repellent and the binder resin to the fabric include a gravure roll method, a kiss roll method, a foam processing method, a rotary screen printing method, a flat screen method, and a roller printing method. Is done. In addition, when applying the water repellent, the viscosity of the composition containing the water repellent, the pressure applied to the fabric with a squeegee, and the printing speed are adjusted as appropriate so that the water repellent does not penetrate to the opposite surface of the fabric. There is a need to.
なお、前記布帛には、必要に応じて通常のアルカリ減量加工が施されてもよい。さらには、常法の起毛加工、紫外線遮蔽あるいは、抗菌剤、消臭剤、防虫剤、蓄光剤、再帰反射剤、マイナスイオン発生剤等の機能を付与する各種加工を付加適用してもよい。 The fabric may be subjected to normal alkali weight reduction processing as necessary. Further, conventional brushing processing, ultraviolet ray shielding, or various processing imparting functions such as antibacterial agent, deodorant agent, insect repellent agent, phosphorescent agent, retroreflective agent, and negative ion generator may be additionally applied.
かくして得られた布帛において、汗が凹凸構造の凹部に沿って拡散されることにより乾燥速度が速くなるため、優れた汗じみ防止効果が得られる。また、布帛がポリエステル繊維で構成され、かつ肌と布帛との接触面積が小さくなるためべとつき感が低減される。 In the fabric thus obtained, sweat is diffused along the concave and convex portions of the concavo-convex structure, so that the drying speed is increased, so that an excellent sweating prevention effect is obtained. Further, since the fabric is made of polyester fiber and the contact area between the skin and the fabric is small, the feeling of stickiness is reduced.
次に、本発明の汗じみ防止衣料は、前記布帛を、撥水剤が付着した表面が外気側に位置するよう（すなわち、凹凸構造を有する表面が肌側に位置するよう）用いてなる汗じみ防止衣料である。前記布帛を用いて汗じみ防止衣料を縫製する際、通常の縫糸を用いてもよいが、撥水剤が付着した縫糸を用いると、汗が縫糸を通して外衣を濡らすのを防ぐことができ好ましい。なお、かかる衣料には、スポーツ衣料、インナー衣料、紳士衣料、婦人衣料、裏地衣料などが含まれるが、これらに限定されないことはいうまでもない。かかる衣料は前記の前記布帛を用いているので、優れた汗じみ防止効果を有し、かつべとつき感が低減される。
なお、前記汗じみ防止布帛は衣料だけでなく、寝装寝具、カーシート表皮材、帽子などの生活資材など他の用途に用いてもよい。
Next, the sweat-preventing garment of the present invention is a sweat-preventing fabric obtained by using the fabric so that the surface to which the water-repellent agent is attached is located on the outside air side (that is, the surface having an uneven structure is located on the skin side). It is clothing. When sewing the sweat-preventing garment using the fabric, a normal sewing thread may be used. However, it is preferable to use a sewing thread to which a water repellent is attached because sweat prevents the outer garment from getting wet through the sewing thread. Such clothing includes sports clothing, inner clothing, men's clothing, women's clothing, lining clothing, and the like, but it goes without saying. Since the garment uses the above-described fabric, it has an excellent anti-sweat effect and reduces the feeling of stickiness.
The sweat-proof fabric may be used not only for clothing but also for other uses such as bedding, bedding, car seat skin materials, and hats.
＜凹凸部構造の有無＞
布帛表面を目視により判定し、一辺が５００μｍの正方形よりも面積が大であり、かつ深さが５００μｍ以上の凹部が表面に存在する場合、「凹凸部構造があり」と判定した。
<Existence of uneven structure>
The surface of the fabric was visually determined, and when a concave portion having a side larger than a square having a side of 500 μm and a depth of 500 μm or more was present on the surface, it was determined that “there was an uneven structure”.
＜濡れ変色判定（汗じみ防止効果）＞
汗じみ防止効果の代用特性として、布帛を水中に浸漬する前後の変色度合いをＪＩＳ−Ｌ−０８０１−１０により判定を行った。ただし、撥水剤を付与した表面について判定を行った。４級よりも大であれば良好とする。
<Wet discoloration judgment (prevention of sweating)>
As a substitute characteristic of the sweat sweat preventing effect, the degree of discoloration before and after the fabric was immersed in water was determined according to JIS-L-0801-10. However, the surface to which the water repellent was applied was determined. If it is larger than 4th grade, it is considered good.
＜保水率＞
乾燥性ＪＩＳ−Ｌ−１０９６−８．２５．２Ｂ法（法）の前処理条件により湿潤処理を行い、乾燥時の布帛質量対比の水分率を保水率（％）とした。保水率が１００％以上であれば、保水率良好とする。
保水率（％）＝（湿潤時の布帛質量［ｇ］−乾燥時の布帛質量［ｇ］）／（乾燥時の布帛質量［ｇ］）×１００
<Water retention rate>
Drying Wet treatment was performed under the pretreatment conditions of JIS-L-1096-8.25.2B method (method), and the moisture content relative to the fabric mass at the time of drying was defined as the water retention rate (%). If the water retention rate is 100% or more, the water retention rate is considered good.
Water retention (%) = (wet fabric mass [g] -dry fabric mass [g]) / (dry fabric mass [g]) × 100
＜べとつき感＞
実施例および比較例で得られた布帛を用いて半袖のＴシャツ（スポーツ衣料）を作り、温度２８℃、湿度５０％ＲＨに調節された室内に、被験者３人がランニング（１０ｍ／ｈ）を行った際のべとつき感を○（べとつき感がほとんどなく快適である。）、△（べとつき感が少しある。）、×（べとつき感があり不快である。）の３段階で評価した。
<Smoothness>
Using the fabrics obtained in the examples and comparative examples, T-shirts (sports clothing) with short sleeves are made, and three subjects run (10 m / h) in a room adjusted to a temperature of 28 ° C. and a humidity of 50% RH. The feeling of stickiness when going was evaluated in three stages: ○ (there was almost no stickiness and comfortable), Δ (there was a little stickiness), and × (there was sticky and uncomfortable).
＜縫糸の濡れ変色＞
実施例および比較例で得られた布帛を用いてべとつき感の評価を行った際の縫糸部分の濡れによる変色を○（ほとんど変色しなかった。）、△（少し変色した。）、×（変色した。）の３段階で目視評価した。
<Wetted discoloration of sewing thread>
When the feeling of stickiness was evaluated using the fabrics obtained in the examples and comparative examples, the discoloration due to wetting of the sewing thread portion was ○ (almost no discoloration), Δ (a little discoloration), × (discoloration). The visual evaluation was performed in three stages.
［実施例１］
２８Ｇの丸編機を使用して総繊度６６ｄｔｅｘ／７２ｆｉｌのポリエチレンテレフタレートマルチフィラメント（ポリエステル繊維）だけを用い、裏鹿の子組織の編物を編成した後、１３０℃３０分間通常の染色加工を実施し、親水剤（高松油脂(株)ＳＲ−１０００）を５％ｏｗｆ用いて１３０℃３０分間親水化処理を行い、乾燥、セットを行った。該編物において、一方表面にのみ凹凸構造が形成されており、他方表面はフラットであった。
次いで、該布帛のフラットな表面（凹凸構造が形成されている表面とは反対側表面）に、下記の処方からなる処理液を約２０ｇ／ｍ２の塗布量となるよう、フラットな表面にのみグラビア転写にて塗布し、その後、１３５℃で乾燥した後、１６０℃４５秒で乾熱処理を行い、汗じみ防止布帛を得た。得られた汗じみ防止は編物密度５７コース／２．５４ｃｍ、４５ウェル／２．５４ｃｍ、布帛目付け１０７ｇ／ｍ２であった。
[処理液の組成]
・ 水９１．６重量％
・ フッ素系撥水剤８重量％（旭硝子(株)製「アサヒガードＡＧ７１０」）
・ メラミン系バインダー樹脂０．３重量％
（住友化学(株)製「スミテックスレジンＭ−３」接触角６７．５度）
・ 触媒０．１重量％（スミテックス アクセレーターＡＣＸ）
得られた布帛を測定したところ、撥水剤が付着した表面には凹凸構造が存在せず（フラットな表面）、他方表面には、撥水剤が付着しておらず、かつ凹凸構造が形成されていた。濡れ変色判定は４−５級で良好であった。また保水率を測定したところ、２８０％で良好あった。
次いで、該布帛を用いて撥水剤が付着した面を外気表面に位置するようにし、縫糸として、ポリエステル繊維にフッ素加工剤からなる撥水剤を繊維重量に対して５重量％付与した糸を用い、半袖のＴシャツを縫製し濡れ変色とべとつき感を評価したところ判定はともに○（快適）であった。また縫い糸部分の濡れ変色もなく見た目も良好な結果であった。評価結果を表１に示す。
[Example 1]
Using a 28G circular knitting machine, a knitted fabric with a back deer structure was knitted using only polyethylene terephthalate multifilament (polyester fiber) with a total fineness of 66 dtex / 72 fil. Hydrophilic treatment was performed at 130 ° C. for 30 minutes using 5% owf of an agent (Takamatsu Yushi Co., Ltd. SR-1000), followed by drying and setting. In the knitted fabric, an uneven structure was formed only on one surface, and the other surface was flat.
Next, on the flat surface of the fabric (the surface opposite to the surface on which the uneven structure is formed), the treatment liquid having the following formulation is applied only to the flat surface so that the application amount is about 20 g / m 2. After applying by gravure transfer and then drying at 135 ° C., a dry heat treatment was performed at 160 ° C. for 45 seconds to obtain a sweat-preventing fabric. The obtained sweat permeation prevention had a knitted fabric density of 57 courses / 2.54 cm, 45 wells / 2.54 cm, and a fabric basis weight of 107 g / m 2 .
[Composition of treatment solution]
・ 91.6% by weight of water
・ Fluorine-based water repellent 8% by weight ("Asahi Guard AG710" manufactured by Asahi Glass Co., Ltd.)
・ 0.3% by weight of melamine binder resin
(Sumitomo Chemical "Sumitex Resin M-3" contact angle 67.5 degrees)
・ 0.1% by weight of catalyst (Smitex Accelerator ACX)
When the obtained fabric was measured, there was no uneven structure on the surface to which the water repellent was attached (flat surface), and no water repellent was attached to the other surface, and an uneven structure was formed. It had been. The wetting discoloration judgment was good at 4-5 grade. Moreover, when the water retention was measured, it was good at 280%.
Next, using the fabric, the surface on which the water repellent is adhered is positioned on the outside air surface, and a thread in which a water repellent composed of a fluorine processing agent is applied to the polyester fiber by 5% by weight is used as a sewing thread. Using a short-sleeved T-shirt and evaluating wet discoloration and stickiness, both judgments were good (comfortable). Also, the appearance of the sewing thread part was good with no wet discoloration. The evaluation results are shown in Table 1.
［実施例２］
２８Ｇの丸編機を使用して総繊度６６ｄｔｅｘ／７２ｆｉｌのポリエチレンテレフタレートマルチフィラメントと総繊度５６ｄｔｅｘ／７２ｆｉｌのポリエチレンテレフタレートマルチフィラメントとを用い、裏ハニカム組織の編物を編成した後、実施例１と同じ染色加工と親水化処理を行い、フラットな表面にのみ実施例１と同じグラビア転写を実施し汗じみ防止布帛を得た。得られた布帛は編物密度５５コース／２．５４ｃｍ、４４ウェル／２．５４ｃｍ、布帛目付け９８ｇ／ｍ２であった。
得られた布帛を測定したところ、撥水剤が付着した表面には凹凸構造が存在せず（フラットな表面）、他方表面には、撥水剤が付着しておらず、かつ凹凸構造が形成されていた。濡れ変色判定は４−５級で良好であった。また保水率を測定したところ、２５０％で良好あった。
次いで、該布帛を用いて、実施例１と同様に撥水剤が付着した表面を外気側表面となるようにし、実施例１と同じ縫糸を用い、半袖のＴシャツを縫製し濡れ変色とベトツキ感を評価したところ、判定はともに○（快適）であった。また縫糸部分の濡れ変色もなく見た目も良好な結果であった。評価結果を表１に示す。
[Example 2]
Using a 28G circular knitting machine, a knitted fabric of a back honeycomb structure was knitted using a polyethylene terephthalate multifilament having a total fineness of 66 dtex / 72 fil and a polyethylene terephthalate multifilament having a total fineness of 56 dtex / 72 fil, and then the same dyeing as in Example 1 Processing and hydrophilization treatment were performed, and the same gravure transfer as in Example 1 was performed only on a flat surface to obtain a sweat-proof fabric. The obtained fabric had a knitted fabric density of 55 courses / 2.54 cm, 44 wells / 2.54 cm, and a fabric basis weight of 98 g / m 2 .
When the obtained fabric was measured, there was no uneven structure on the surface to which the water repellent was attached (flat surface), and no water repellent was attached to the other surface, and an uneven structure was formed. It had been. The wetting discoloration judgment was good at 4-5 grade. Further, when the water retention rate was measured, it was good at 250%.
Next, using the fabric, the surface to which the water repellent was adhered was made to be the outside air side surface as in Example 1, and using the same sewing thread as in Example 1, a short-sleeved T-shirt was sewn to wet discoloration and stickiness. When the feeling was evaluated, both judgments were ○ (comfortable). Moreover, the wet thread discoloration of the sewing thread part did not appear and the result was also good. The evaluation results are shown in Table 1.
［比較例１］
実施例１において、表裏を逆にし、凹凸構造が形成されている表面にのみグラビア転写を実施すること以外は実施例１と同様にした。得られた布帛は編物密度５７コース／２．５４ｃｍ、４５ウェル／２．５４ｃｍ、布帛目付け１０７ｇ／ｍ２であった。
得られた編物を測定したところ、撥水剤が付着した表面には凹凸構造が存在しており、他方表面には、撥水剤が付着しておらず、かつフラットな表面であった。濡れ変色判定は凹部の濡れ変色が目立ち２−３級と不良であった。また保水率を測定したところ、３５０％で良好あった。
次いで、該布帛を用いて撥水剤が付着した面を外気側表面となるようにし、縫い糸に撥水処理を施した糸を用い、半袖のＴシャツを縫製し濡れ変色とベトツキ感を評価したところ、肌側に凹部がなく判定は×（不快）であった。一方、縫糸部分は濡れ変色もなく見た目も良好な結果であった。評価結果を表１に示す。
[Comparative Example 1]
Example 1 was the same as Example 1 except that the front and back sides were reversed and gravure transfer was performed only on the surface where the concavo-convex structure was formed. The obtained fabric had a knitted fabric density of 57 courses / 2.54 cm, 45 wells / 2.54 cm, and a fabric basis weight of 107 g / m 2 .
When the obtained knitted fabric was measured, a concavo-convex structure was present on the surface to which the water repellent was adhered, and the other surface was flat with no water repellent adhered. The wetting discoloration determination was not good, as the wetting discoloration of the recesses was conspicuous 2-3 grade. Further, the water retention rate was measured and found to be good at 350%.
Next, using the fabric, the surface to which the water repellent was attached was the outside air side surface, and a thread having a water repellent treatment was used on the sewing thread, and a short-sleeved T-shirt was sewn to evaluate wet discoloration and stickiness. However, there was no recess on the skin side, and the determination was x (uncomfortable). On the other hand, the sewing thread part did not show discoloration and the appearance was good. The evaluation results are shown in Table 1.
［比較例２］
２８Ｇの丸編機を使用して総繊度１１０ｄｔｅｘ／１４４ｆｉｌのポリエチレンテレフタレートマルチフィラメントを用い、スムース組織の編物を編成した後、実施例１と同じ染色加工と親水化処理、一方の表面にのみ実施例１と同じグラビア転写を実施し布帛を得た。
得られた編物を測定したところ、撥水剤が付着した表面はフラットな表面であり、他方表面には、撥水剤が付着しておらず、かつフラットな表面であった。
得られた布帛は編物密度５７コース／２．５４ｃｍ、４５ウェル／２．５４ｃｍ、布帛目付け１９０ｇ／ｍ２であった。
得られた布帛を測定したところ、撥水剤が付着した表面は凹凸構造が存在しておらず、濡れ変色判定は４級であった。また保水率を測定したところ、１８０％で良好あった。
次いで、該布帛を用いて撥水剤が付着した表面を外気側となるようにし、実施例１と同じ縫糸を用い、半袖のＴシャツを縫製し濡れ変色とベトツキ感を評価したところ、肌側に凹部がなく判定は×（不快）であった。一方、縫糸部分は濡れ変色もなく見た目も良好な結果であった。評価結果を表１に示す。
[Comparative Example 2]
After knitting a smooth knitted fabric using a polyethylene terephthalate multifilament having a total fineness of 110 dtex / 144 fil using a 28 G circular knitting machine, the same dyeing process and hydrophilization treatment as in Example 1 were carried out. The same gravure transfer as in No. 1 was performed to obtain a fabric.
When the obtained knitted fabric was measured, the surface to which the water repellent was adhered was a flat surface, and the water repellent was not adhered to the other surface, and the surface was flat.
The resulting fabric had a knitted fabric density of 57 courses / 2.54 cm, 45 wells / 2.54 cm, and a fabric basis weight of 190 g / m 2 .
When the obtained fabric was measured, the surface to which the water repellent was adhered did not have an uneven structure, and the wet discoloration determination was grade 4. Moreover, when the water retention was measured, it was good at 180%.
Next, the surface on which the water repellent was adhered using the fabric was placed on the outside air side, and the same sewing thread as in Example 1 was used to sew a short-sleeved T-shirt to evaluate wet discoloration and stickiness. The determination was x (unpleasant). On the other hand, the sewing thread part did not show discoloration and the appearance was good. The evaluation results are shown in Table 1.
［比較例３］
実施例１において、グラビア転写の塗布量を４０ｇ／ｍ２となるように変更し、フラットな表面側だけでなく凹凸構造が形成された表面にも撥水剤を付着させること以外は、実施例１と同様にした。
得られた布帛は編物密度５７コース／２．５４ｃｍ、４５ウェル／２．５４ｃｍ、布帛目付け１０７ｇ／ｍ２であった。
得られた布帛を測定したところ、片側表面には凹凸構造が存在せず、濡れ変色判定は４−５級と良好であった。また保水率を測定したところ４０％であった。
次いで、該布帛を用いてフラットな表面が外気側となるようにし、実施例１と同じ縫糸を用い、半袖のＴシャツを縫製し濡れ変色とべとつき感を評価したところ、肌側に凹凸構造が存在するが保水率が低く×（不快）であった。一方、縫糸部分は濡れ変色もなく見た目も良好な結果であった。評価結果を表１に示す。
[Comparative Example 3]
In Example 1, the application amount of gravure transfer was changed to 40 g / m 2 , except that the water repellent was adhered not only to the flat surface side but also to the surface on which the concavo-convex structure was formed. Same as 1.
The obtained fabric had a knitted fabric density of 57 courses / 2.54 cm, 45 wells / 2.54 cm, and a fabric basis weight of 107 g / m 2 .
When the obtained fabric was measured, there was no concavo-convex structure on one surface, and the wet discoloration judgment was as good as 4-5 grade. The water retention rate was 40%.
Next, using the fabric so that the flat surface is on the outside air side, the same sewing thread as in Example 1 was used to sew a short-sleeved T-shirt and the wet discoloration and stickiness were evaluated. Although it was present, the water retention rate was low and x (uncomfortable). On the other hand, the sewing thread part did not show discoloration and the appearance was good. The evaluation results are shown in Table 1.
［実施例３］
実施例１において、縫糸に撥水処理を施さない糸を用いること以外は実施例１と同様にして、半袖のＴシャツを縫製し濡れ変色とベトツキ性を評価した。判定は○（快適）であった。一方、縫い糸部分は濡れ変色がみられ、見た目にやや不良な結果であった。評価結果を表１に示す。
[Example 3]
In Example 1, a short-sleeved T-shirt was sewn in the same manner as in Example 1 except that a thread that was not subjected to water repellency treatment was used, and the wet discoloration and stickiness were evaluated. The judgment was ○ (comfortable). On the other hand, the sewing thread part was wet and discolored, and the result was somewhat poor in appearance. The evaluation results are shown in Table 1.
本発明によれば、優れた汗じみ防止効果を有し、かつべとつき感が低減された汗じみ防止布帛および該汗じみ防止布帛を用いてなる汗じみ防止衣料が提供され、その工業的価値は極めて大である。 ADVANTAGE OF THE INVENTION According to this invention, the anti-sweating fabric which has the outstanding anti-sweating effect and the feeling of stickiness was reduced, and the anti-sweating clothing which uses this sweat-proof fabric are provided, The industrial value is very large. .
１：凸部
２：凹部
３：撥水剤
1: Convex part 2: Concave part 3: Water repellent
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010094051A JP2011226001A (en) | 2010-04-15 | 2010-04-15 | Fabric and clothing preventing sweat stains |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010094051A JP2011226001A (en) | 2010-04-15 | 2010-04-15 | Fabric and clothing preventing sweat stains |
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| Publication Number | Publication Date |
|---|---|
| JP2011226001A true JP2011226001A (en) | 2011-11-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010094051A Pending JP2011226001A (en) | 2010-04-15 | 2010-04-15 | Fabric and clothing preventing sweat stains |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015086489A (en) * | 2013-10-31 | 2015-05-07 | 帝人フロンティア株式会社 | Stain suppressing fabric and textile product |
| JP2018016923A (en) * | 2016-07-29 | 2018-02-01 | 帝人株式会社 | Clothing for assist suit |
| WO2018225286A1 (en) | 2017-06-09 | 2018-12-13 | 花王株式会社 | Water repellency-imparting fiber article |
| CN114075712A (en) * | 2020-08-10 | 2022-02-22 | 东丽纤维研究所（中国）有限公司 | Knitted fabric |
| KR20220104383A (en) * | 2021-01-18 | 2022-07-26 | 정영훈 | Method for producing embossing on woven fabric and embossed fabric produced by same |
-
2010
- 2010-04-15 JP JP2010094051A patent/JP2011226001A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015086489A (en) * | 2013-10-31 | 2015-05-07 | 帝人フロンティア株式会社 | Stain suppressing fabric and textile product |
| JP2018016923A (en) * | 2016-07-29 | 2018-02-01 | 帝人株式会社 | Clothing for assist suit |
| WO2018225286A1 (en) | 2017-06-09 | 2018-12-13 | 花王株式会社 | Water repellency-imparting fiber article |
| CN114075712A (en) * | 2020-08-10 | 2022-02-22 | 东丽纤维研究所（中国）有限公司 | Knitted fabric |
| KR20220104383A (en) * | 2021-01-18 | 2022-07-26 | 정영훈 | Method for producing embossing on woven fabric and embossed fabric produced by same |
| KR102496122B1 (en) | 2021-01-18 | 2023-02-06 | 정영훈 | Method for producing embossing on woven fabric and embossed fabric produced by same |
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