JP2011126829A - Emulsified composition for hair - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an emulsified composition for hair excellent in functionality and usability which is easily emulsified, does not produce aggregation and precipitation with time, has excellent preparation stability, is excellent in hairdressing power, is good in conformability with and spreadability of hair, and can reduce a feeling of stickiness. <P>SOLUTION: The emulsified composition for hair incudes (A) paraffin wax having a melting point of 70-77°C, (B) oily matter which is liquid at room temperature, (C) a nonionic surfactant, and (D) water. Optionally, the composition can include (E) a cationic polymer. In addition, the composition is desirably a hair wax. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

  The present invention relates to an emulsified composition for hair.

  In recent years, in addition to the characteristic hair-styling functions such as “launching”, “scattering”, “combining”, “twisting”, and “arranging”, the functionality such as “nobbit” and “glossy”, “stickiness” and “stiffness” have been reduced. Hairdressing agents with excellent usability have been developed. In addition to solid oils such as carnauba wax, candelilla wax, and high-melting-point microcrystalline wax that have a high melting point and hard properties, silicone oil, ester oil, Attempts have been made to blend polymers and the like.

  Specifically, for example, oily solid cosmetics containing 0.1 to 8% by mass of rice bran wax having an iodine value and an acid value of 3.0 or less, a total wax amount of 5 to 8% by mass, and a specific oily component ( For example, refer to Patent Document 1), a solid hair and liquid oil having a melting point of 45 ° C. or higher, a specific polymer compound, and an oily particle having an average particle diameter of 0.05 to 10 mm (for example, Patent Document) 2), solid oil content 10-20% by mass, polyhydric alcohol and 2-ethylhexanoic acid ester 4-12% by mass, silicone oil 0.2-10% by mass, polyglycerol isostearic acid ester 4-10% by mass. %, Emulsified hair styling composition containing 50-70% by weight of water (see, for example, Patent Document 3), waxes 1-30% by weight, paste form at 25 ° C., melting point or freezing point at 30-55 ° C. Have Hairdressing agent containing 2 to 50% by mass of oil agent, 0.01 to 2% by mass of high-polymerized polyethylene glycol having an average degree of polymerization of 20000 to 200000, and 0.1 to 10% by mass of low-polymerized polyethylene glycol having an average degree of polymerization of 2 to 200 (See, for example, Patent Document 4).

  However, using a solid oil component having a high melting point as described above can provide excellent hair-styling power, but if it is highly formulated, aggregation and precipitation occur over time due to its properties and composition, resulting in improved formulation stability. There are problems such as adverse effects. Among various dosage forms, particularly when the composition is high in the emulsifier type, emulsification becomes extremely difficult, and even if it can be emulsified, there is a problem that the stability is inferior due to the above problems. Moreover, when liquid oil, a high molecular compound, etc. are mix | blended too much in order to improve usability, the balance of a formulation itself will worsen and the problem that a hairdressing power may fall may also arise.

JP 2009-179564 A JP 2009-108003 A JP 2006-28153 A JP 2002-187825 A

  The present invention has been made in view of the above prior art, and it is an object to provide an emulsified composition for hair that is easily emulsified, does not cause aggregation / precipitation over time, and has excellent formulation stability. And It is another object of the present invention to provide an emulsified composition for hair that is excellent in hair styling power, has good fit and spreadability to the hair, and has excellent functionality and usability that can reduce the feeling of stickiness.

That is, the present invention
[1] An emulsified composition for hair comprising (A) a paraffin wax having a melting point of 70 to 77 ° C., (B) an oily substance which is liquid at room temperature, (C) a nonionic surfactant and (D) water,
[2] The hair emulsion composition according to [1], further comprising (E) a cationic polymer, and [3] the hair emulsion composition according to [1] or [2]. The present invention relates to an emulsified composition for hair, which is a hair wax.

  The emulsified composition for hair of the present invention does not cause aggregation / precipitation over time, and has the effect of having excellent formulation stability. In addition, the emulsified composition for hair of the present invention is excellent in hair styling power, has good effect on hair and spreadability, is excellent in operability during hair styling, and has an effect of reducing stickiness.

  The emulsified composition for hair of the present invention contains (A) a paraffin wax having a melting point of 70 to 77 ° C., (B) an oily substance that is liquid at room temperature, (C) a nonionic surfactant, and (D) water.

  The paraffin wax (A) is a kind of petroleum wax in natural wax. Petroleum wax is a “solid hydrocarbon present in petroleum at normal temperature”, and is classified into three types of paraffin wax, microcrystalline wax, and petrolatum depending on the separated product after distillation. The paraffin wax is a solid wax separated and refined from a vacuum-distilled oil extracted from petroleum wax, and is a normal paraffin having a carbon number distribution of about 20 to 40, a molecular weight of about 300 to 550, and a linear weight of about 90%. General properties are low volatility, tasteless and odorless, and extremely low viscosity in the molten state. The melting point exists in the range of 40-80 ° C.

  The melting point of the paraffin wax used in the present invention is 70 to 77 ° C. from the viewpoint of emulsion stability and usability. If it is this melting | fusing point range, 1 type may be used independently and it can also be used in combination of 2 or more types from which melting | fusing point differs suitably.

  In addition, a commercial item can also be used for the said (A) component. Specifically, for example, SP-0165 (trade name, manufactured by Nippon Beeswax Co., Ltd.) can be exemplified.

  The content of the component (A) is not particularly limited as long as a desired effect is imparted, but usually 0.5% by mass or more is preferable in the composition from the viewpoint of hair styling power, and more preferably 3% by mass. % Or more. Moreover, from a viewpoint of spreadability, 25 mass% or less is preferable, More preferably, it is 20 mass% or less. From these viewpoints, the content of the component (A) is preferably 0.5 to 25% by mass, more preferably 3 to 20% by mass.

  The oily component that is liquid at room temperature as the component (B) is not particularly limited as long as it can be used as a raw material for cosmetics. Specific examples of the component include hydrocarbons that are liquid at room temperature such as isoparaffin and light isoparaffin. ; Cyclic silicone such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane; chain silicone such as octamethyltrisiloxane, tetradecamethylhexasiloxane, low viscosity methylpolysiloxane; ethyl isostearate, isostearic Isopropyl acid, cetyl 2-ethylhexanoate, cetostearyl 2-ethylhexanoate, glycerin 2-ethylhexanoate, macadamia nut oil fatty acid cholesteryl, diisostearyl malate, 2-ethylhexyl palmitate Glyceryl tri-2-ethylhexanoate, glyceryl triisopalmitate, pentaerythritol tetra-2-ethylhexanoate, isocetyl octoate, isostearyl octoate, isopropyl palmitate, isocetyl isostearate, dipentaerythritol fatty acid ester, octyl isostearate Examples include fatty acid ester oils that are liquid at room temperature, such as fatty acid ester oils such as dodecyl and isononanoyl isononate; animal and vegetable oils that are liquid at room temperature, such as liquid lanolin, squalane, jojoba oil, olive oil, macadamia nut oil, and almond oil. . These components may be used alone or in combination of two or more.

  Although content of (B) component will not be specifically limited if a desired effect is provided, Usually, 0.5 mass% or more is preferable in a composition from a functional viewpoint, More preferably, it is 1 mass. % Or more. Moreover, from a viewpoint of usability, 20 mass% or less is preferable, More preferably, it is 15 mass% or less. From these viewpoints, the content of the component (B) is preferably 0.5 to 20% by mass, more preferably 1 to 15% by mass.

  Examples of the nonionic surfactant of component (C) include glycerin fatty acid ester, polyglycerin fatty acid ester, ethylene oxide condensate of glycerin fatty acid ester, polyalkylene glycol fatty acid ester, sorbitan fatty acid ester, ethylene oxide of sorbitan fatty acid ester. In addition to fatty acid ester type nonionic surfactants such as condensates, polyoxyalkylene alkyl ether, polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene lanolin, sucrose fatty acid ester and the like can be mentioned. These components may be used alone or in combination of two or more.

  In the present invention, glycerin fatty acid ester means both glycerin fatty acid ester and polyglycerin fatty acid ester. Specifically, glyceryl monocaprylate, glyceryl monocaprate, glyceryl monolaurate, glyceryl monomyristate Glyceryl fatty acid esters such as glyceryl monopalmitate, glyceryl monostearate, glyceryl monoisostearate, glyceryl monobehenate, glyceryl monooleate, glyceryl monoerucate, glyceryl sesquioleate, glyceryl distearate, glyceryl diisostearate, glyceryl diarachiate ; Diglyceryl monocaprylate, decaglyceryl monocaprylate, hexaglyceryl monocaprate, tetraglyceryl monolaurate Hexaglyceryl monolaurate, decaglyceryl monolaurate, poly (4-10) glyceryl monolaurate, decaglyceryl monomyristate, decaglyceryl monostearate, decaglyceryl monoisostearate, poly (2-10) glyceryl monostearate, mono Diglyceryl oleate, hexaglyceryl monooleate, diglyceryl sesquioleate, poly (2-10) glyceryl diisostearate, poly (6-10) glyceryl distearate, diglyceryl triisostearate, poly (10) tristearate Examples thereof include polyglycerol fatty acid esters having a polymerization degree of 2 to 10 as described above, such as glyceryl. Examples of the ethylene oxide condensate of glycerol fatty acid ester include polyoxyethylene glyceryl monostearate and polyoxyethylene glyceryl monooleate.

  Examples of the polyalkylene glycol fatty acid ester include polyethylene glycol fatty acid esters such as polyethylene glycol monooleate, polyethylene glycol monostearate, polyethylene glycol monolaurate; propylene glycol monostearate, propylene glycol monolaurate, propylene glycol monooleate, etc. And propylene glycol fatty acid esters.

  Examples of sorbitan fatty acid esters include sorbitan monooleate, sorbitan monostearate, sorbitan monoisostearate, sorbitan monopalmitate, sorbitan monolaurate, sorbitan trioleate, sorbitan tristearate, sorbitan sesquistearate, sesquioleate Examples include sorbitan fatty acid esters such as sorbitan, sorbitan sesquiisostearate, and coconut oil fatty acid sorbitan. Examples of the ethylene oxide condensate of sorbitan fatty acid ester include polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene monoisostearate Examples include sorbitan, mono coconut oil fatty acid polyoxyethylene sorbitan, polyoxyethylene sorbitan tristearate, polyoxyethylene sorbitan trioleate, and the like.

  Specific examples of the polyoxyalkylene alkyl ether include, for example, polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene polyoxypropylene lauryl ether, polyoxypropylene cetyl Examples include ether, polyoxypropylene isocetyl ether, polyoxypropylene stearyl ether, polyoxypropylene oleyl ether, and the like.

  The content of the component (C) is not particularly limited as long as a desired effect is imparted, but usually 0.5% by mass or more is preferable in the composition from the viewpoint of formulation stability, and more preferably 1 It is at least mass%. Moreover, from a viewpoint of usability, 15 mass% or less is preferable, More preferably, it is 10 mass% or less. From these viewpoints, the content of the component (C) is preferably 0.5 to 15% by mass, and more preferably 1 to 10% by mass.

  The water of component (D) is not particularly limited as long as it can be used as a cosmetic raw material, but purified water is usually used. Although content of (D) component will not be specifically limited if a desired effect is provided, Usually, 20-90 mass% is preferable in a composition from a viewpoint of a feeling of use, More preferably, it is 20-75. % By mass.

  The emulsified composition for hair according to the present invention may contain (E) a cationic polymer from the viewpoint of improving the feel during hair styling, protecting the hair, and improving the gloss of the hair. Specific examples of the component (E) include, for example, vinylpyrrolidone / N, N-dialkylaminomethacrylate copolymer, cationized cellulose, cationized guar gum, cationized starch, hydroxyethylcellulose dimethyldiallylammonium chloride, polydimethylmethylene chloride. Examples thereof include peridinium and dimethyldiallylammonium chloride / acrylamide copolymer. These components may be used alone or in combination of two or more.

  Although content of (E) component will not be specifically limited if a desired effect is provided, Usually, 0.001 mass% or more is preferable in a composition from a functional viewpoint, More preferably, it is 0.00. 01% by mass or more. Moreover, from a viewpoint of stability maintenance, 5 mass% or less is preferable, More preferably, it is 2 mass% or less. From these viewpoints, the content of the component (E) is preferably 0.001 to 5% by mass, and more preferably 0.01 to 2% by mass.

  The emulsified composition for hair of the present invention may contain a thickening polymer other than the component (E) in order to further improve the formulation stability. Examples of the thickening polymer used include water-soluble natural polymers, semi-synthetic polymers, and synthetic polymers. Specific examples of natural polymers include gum arabic, tragacanth gum, guar gum, locust bean gum, karaya gum, iris moss, quince seed, gelatin, shellac, rosin, and casein. Specific examples of the semi-synthetic polymer include sodium carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose, ethyl cellulose, sodium alginate, ester gum, nitrocellulose, hydroxypropyl cellulose, hydroxypropyl methylcellulose, crystalline cellulose and the like. Specific examples of the synthetic polymer include polyvinyl alcohol, sodium polyacrylate, carboxyvinyl polymer, acrylic acid / alkyl methacrylate copolymer, polyvinyl methyl cellulose, polyamide resin, polyethylene glycol, and the like. These components may be used alone or in combination of two or more. As a suitable thickening polymer, it is preferable to use a carboxyvinyl polymer and an acrylic acid / alkyl methacrylate copolymer.

  When a carboxyvinyl polymer or an acrylic acid / alkyl methacrylate copolymer is used as the thickening polymer, it is usually neutralized with a basic substance. Examples of the basic substance include alkanolamines such as triethanolamine and monoethanolamine, inorganic bases such as ammonia, sodium hydroxide and potassium hydroxide, and basic amino acids such as arginine. Moreover, the addition amount of the basic substance is an amount sufficient to neutralize the carboxyvinyl polymer or the acrylic acid / alkyl methacrylate copolymer, and may be appropriately blended depending on the type and amount of use of these components. .

  The content of the thickening polymer other than the component (E) is not particularly limited, but is usually preferably 0.01% by mass or more in the composition from the viewpoint of further improving the stability of the preparation, and more preferably 0. 1% by mass or more. Moreover, from a viewpoint of a usability | use_condition, 15 mass% or less is preferable, More preferably, it is 10 mass% or less. From these viewpoints, the content of the thickening polymer other than the component (E) is preferably 0.01 to 15% by mass, more preferably 0.1 to 10% by mass.

  The emulsified composition for hair of the present invention may contain waxes that are solid at room temperature and / or hydrocarbons that are solid at room temperature other than the component (A) in order to further improve hairdressing properties. Specific examples of waxes that are solid at room temperature include carnauba wax, candelilla wax, beeswax, rice bran wax, shellac wax, whale wax, lanolin, and the like. Specific examples of hydrocarbons solid at room temperature other than the component (A) include ceresin, ozokerite, paraffin, microcrystalline wax, polyethylene powder, polyethylene wax, petrolatum and the like. These components may be used alone or in combination of two or more. In addition, "room temperature" in this invention represents the temperature range of 1-30 degreeC.

  The content of waxes solid at room temperature and / or hydrocarbons solid at room temperature other than the component (A) is not particularly limited, but is usually 0.5% by mass in the composition from the viewpoint of enhancing hair styling ability. The above is preferable, and more preferably 3% by mass or more. Moreover, from a viewpoint of the usability at the time of application | coating, 30 mass% or less is preferable, More preferably, it is 20 mass% or less. From these viewpoints, the content of waxes solid at room temperature and / or hydrocarbons solid at room temperature other than the component (A) is preferably 0.5 to 30% by mass, more preferably 3 to 20% by mass. It is.

  The emulsified composition for hair of the present invention may contain a polyhydric alcohol in order to adjust the spreadability on the hair to a good viscosity. Specific examples of the polyhydric alcohol include, for example, ethylene glycol, dipropylene glycol, propylene glycol, isoprene glycol, glycerin, concentrated glycerin, diglycerin, 1,3-butylene glycol, 1,2-pentanediol, 1,2- Examples include hexanediol, 1,2-octanediol, 1,2-decanediol, and the like. These components may be used alone or in combination of two or more.

  The content of the polyhydric alcohol is not particularly limited, but is preferably 0.01% by mass or more, more preferably 0.1% by mass or more in the composition from the viewpoint of further improving the spreadability on the hair. . Moreover, from a viewpoint of hair-styling power, 20 mass% or less is preferable, More preferably, it is 15 mass% or less. From these viewpoints, the content of the polyhydric alcohol is preferably 0.01 to 20% by mass, more preferably 0.1 to 15% by mass.

  In the emulsified composition for hair of the present invention, as long as it does not impair the effects of the present invention, in addition to the above-described components, a film that is usually used in cosmetics, for example, an alkyl acrylate copolymer, polyvinylpyrrolidone, etc. Agents: higher alcohols such as myristyl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol; hydrocarbon oils that are liquid at room temperature such as liquid paraffin, liquid isoparaffin, squalane; at room temperature such as myristyl myristate, stearyl stearate, cetyl palmitate Solid linear fatty acid ester; a lower alcohol, an ultraviolet absorber, a fragrance, an antioxidant, a moisturizer, a refreshing agent, vitamins, a plant extract, and the like can be appropriately blended depending on the purpose.

  The emulsified composition for hair of the present invention can be applied to emulsifier types such as hair wax, hair cream, and hair milk. Of these, hair conformity and spreadability are good, hair styling power is high, and an effect of excellent emulsification stability can be obtained, so that it can be suitably used as a hair wax. The hair wax in the present invention is a dosage form in a solidified state at room temperature. When the container is filled into a wide-mouthed container and tilted at 45 degrees for 5 seconds, the filled composition hangs down from the wide-mouthed container. Say something without.

  When the emulsified composition for hair of the present invention is used as a hair wax, it can be produced by mixing the above components and emulsifying them by a known method, for example, a phase inversion emulsification method using a homomixer. . Moreover, mixing and emulsification may be performed separately or simultaneously.

  EXAMPLES Hereinafter, although this invention is demonstrated further in detail based on an Example, this invention is not limited only to these Examples. The blending amount represents “% by mass” unless otherwise specified.

(Sample preparation)
According to the composition described in Table 1 and Table 2, each sample of Examples 1-5 and Comparative Examples 1-3 was made into the form of hair wax according to the conventional method, and it used for the following evaluation. The results are shown in Table 1 and Table 2, respectively.
In addition, all evaluation was implemented on the constant conditions of constant temperature and humidity of 23 degreeC and 60% of humidity.

(Test Example 1: Evaluation of formulation stability)
Each sample obtained in the examples and comparative examples was filled in a 120 g capacity wide-mouthed container, stored in a constant temperature bath at 40 ° C. for 4 weeks, the state of the preparation was visually observed, and evaluated according to the following evaluation criteria. .

<Evaluation criteria for formulation stability>
○: No change is observed immediately after production Δ: Slight heterogeneity, precipitate, or separation is observed X: Nonuniformity, precipitate, or separation is clearly recognized

(Test Example 2: Evaluation of hair styling power, familiarity, spreadability, and stickiness)
By using 20 evaluation panels, each sample obtained in the examples and comparative examples was actually hair-styled using wigs (Lesson Mannequin: manufactured by Eucalyptus Japan). The fit of the hair to the hair, spreadability and stickiness were sensory evaluated according to the following evaluation criteria.

<Evaluation criteria for hair styling power (power to raise hair)>
◎: 16 or more out of 20 responded that they had excellent startup power. ○: 11-15 of 20 responded that they had excellent startup power. △: 6-10 of 20 responded that they had excellent startup power. ×: 5 or less out of 20 responded that they have excellent startup power

<Familiar evaluation criteria>
◎: More than 16 out of 20 people answered that they are familiar with hair ○: 11-15 out of 20 people answered that they are familiar with hair Δ: 6-10 out of 20 people are familiar with hair Answer that it is good ×: 5 or less of 20 people answered that they are familiar with hair

<Evaluation criteria for spreadability>
◎: Reply if 16 or more out of 20 people are excellent in spreadability ○: Reply if 11-15 in 20 people are excellent in spreadability △: Reply if 6-10 out of 20 people are excellent in spreadability ×: 20 Less than 5 of the names responded that extensibility was excellent

<Evaluation criteria for stickiness>
A: Reply if 16 or more out of 20 people did not feel sticky ○: Reply if 11-15 people out of 20 did not feel sticky Δ: Reply if 6-10 out of 20 people did not feel sticky ×: 20 Less than 5 people answered that there was no stickiness

  From the results shown in Table 1 and Table 2, the emulsified composition for hair obtained in each example was found to be non-uniform, precipitates, or separated in comparison with those obtained in each comparative example. Thus, it can be seen that it has excellent formulation stability. Moreover, it turns out that it is excellent in hair-styling power, familiarity to hair, and extensibility, and there is no stickiness.

  Hereinafter, formulation examples of the emulsified composition for hair according to the present invention will be shown. In addition, content is mass%.

(Formulation example 1: hair wax)
Carnauba Arrow 3.0
Paraffin wax (melting point 74 ° C) 5.0
Microcrystalline wax (melting point 76.5 ° C.) 4.0
Beeswax 2.0
Polyoxyethylene sorbitan monostearate (20E.O.) 3.0
Sorbitan monostearate 2.0
Liquid paraffin 6.0
Decamethylcyclopentasiloxane 3.0
2-ethylhexyl palmitate 4.0
Glycerin 3.0
1,2-octanediol 0.1
Stearyl alcohol 1.0
Carboxyvinyl polymer 0.2
Triethanolamine 1.0
Stearic acid 1.0
Vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate 0.1
Purified water balance part Total 100.0

(Formulation example 2: hair wax)
Carnauba Arrow 5.0
Paraffin wax (melting point 74 ° C) 3.0
Microcrystalline wax (melting point 76.5 ° C.) 1.0
Vaseline 3.0
Polyoxyethylene cetyl ether (20E.O.) 2.0
Sorbitan monostearate 2.0
Liquid paraffin 5.0
Isononyl isononanoate 5.0
Methylpolysiloxane 2.0
Glycerin 4.0
1,2-octanediol 0.3
Stearyl alcohol 1.0
Carboxyvinyl polymer 0.2
Triethanolamine 1.0
Stearic acid 1.0
Vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate 0.1
Purified water balance part Total 100.0

(Formulation example 3: hair wax)
Paraffin wax (melting point 74 ° C) 6.0
Microcrystalline wax (melting point 76.5 ° C.) 4.0
Candelilla Row 2.0
Vaseline 5.0
Glyceryl monostearate 2.0
Polyoxyethylene sorbitan monostearate (20E.O.) 2.0
Liquid paraffin 5.0
2-ethylhexyl palmitate 3.0
Dipentaerythritol fatty acid ester 2.0
1,3-butylene glycol 6.0
1,2-octanediol 0.3
Cetanol 1.0
Carboxyvinyl polymer 0.2
Triethanolamine 1.0
Stearic acid 1.0
PEG-90 0.1
Vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate 0.1
Purified water balance part Total 100.0

(Formulation example 4: hair wax)
Paraffin wax (melting point 74 ° C) 5.0
Microcrystalline wax (melting point 76.5 ° C.) 3.0
Candelilla Row 2.0
Beeslow 4.0
Vaseline 3.0
Glyceryl monostearate 2.0
Polyoxyethylene sorbitan monostearate (20E.O.) 2.0
Liquid paraffin 5.0
2-ethylhexyl palmitate 3.0
Dipentaerythritol fatty acid ester 2.0
1,3-butylene glycol 4.0
1,2-octanediol 0.3
Cetanol 1.0
Carboxyvinyl polymer 0.2
Triethanolamine 1.0
Stearic acid 1.0
PEG-90 0.1
Vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate 0.1
Purified water balance part Total 100.0

(Formulation example 5: hair wax)
Paraffin wax (melting point 74 ° C) 5.0
Microcrystalline wax (melting point 76.5 ° C.) 3.0
Candelilla Row 2.0
Beeslow 4.0
Vaseline 3.0
Polyoxyethylene cetyl ether (20E.O.) 2.0
Sorbitan monostearate 2.0
Liquid paraffin 5.0
2-ethylhexyl palmitate 3.0
Dipentaerythritol fatty acid ester 2.0
1,3-butylene glycol 4.0
1,2-octanediol 0.3
Cetanol 1.0
Carboxyvinyl polymer 0.2
Triethanolamine 1.0
Stearic acid 1.0
PEG-90 0.1
Vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate 0.1
Purified water balance part Total 100.0

(Formulation example 6: hair wax)
Paraffin wax (melting point 74 ° C) 4.0
Microcrystalline wax (melting point 76.5 ° C.) 3.0
Candelilla Row 3.0
Beeslow 4.0
Vaseline 3.0
Lipophilic glyceryl monostearate 2.0
Polyoxyethylene sorbitan monostearate (20E.O.) 2.0
Liquid paraffin 5.0
2-ethylhexyl palmitate 3.0
Dipentaerythritol fatty acid ester 2.0
Diglycerin 4.0
1,2-octanediol 0.3
Myristyl alcohol 1.0
Carboxyvinyl polymer 0.2
Triethanolamine 1.0
Isostearic acid 1.0
Vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate 0.1
Purified water balance part Total 100.0

(Prescription Example 7: Hair Cream)
Paraffin wax (melting point 74 ° C.) 1.0
Vaseline 1.0
Lipophilic glyceryl monostearate 3.0
Polyoxyethylene sorbitan monostearate (20E.O.) 3.0
Liquid paraffin 35.0
Stearic acid 3.0
Cetyl 2-ethylhexanoate 3.0
Methylpolysiloxane 1.5
1,2-octanediol 0.3
Cetanol 1.0
Carboxyvinyl polymer 0.1
Triethanolamine 1.0
Stearic acid 3.0
Vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate 0.1
Purified water balance part Total 100.0

(Prescription Example 8: Hair wax)
Paraffin wax (melting point 74 ° C) 3.0
Microcrystalline wax (melting point 76.5 ° C.) 4.0
Carnauba wax 2.0
Beeswax 5.0
Fischer-Tropsch Wax 2.0
Lipophilic glyceryl monostearate 3.0
Polyoxyethylene sorbitan monostearate (20E.O.) 3.0
Polyethylene glycol distearate (250 EO) 0.05
Liquid paraffin 8.0
Stearic acid 3.0
2-ethylhexyl palmitate 3.0
Methylpolysiloxane 2.0
Polyoxypropylene Sorbit (9PO) 2.0
1,2-octanediol 0.3
Cetanol 1.0
Talc 4.0
Carboxyvinyl polymer 0.1
Potassium hydroxide 0.5
Vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate 0.1
Purified water balance part Total 100.0

(Formulation example 9: hair milk)
Paraffin wax (melting point 74 ° C.) 1.0
Vaseline 1.0
Polyoxyethylene hydrogenated castor oil (60 EO) 3.0
Polyoxyethylene sorbitan monostearate (20E.O.) 2.0
Liquid paraffin 15.0
Stearic acid 0.5
Cetyl 2-ethylhexanoate 3.0
Methylpolysiloxane 1.5
1,2-octanediol 0.3
Cetanol 1.0
Carboxyvinyl polymer 0.1
Triethanolamine 0.5
Stearic acid 2.0
Polyvinylpyrrolidone 0.1
Maltitol solution 2.0
Vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate 0.1
Purified water balance part Total 100.0

Claims (3)

  An emulsified composition for hair comprising (A) a paraffin wax having a melting point of 70 to 77 ° C., (B) an oily substance that is liquid at room temperature, (C) a nonionic surfactant, and (D) water.   The emulsion composition for hair according to claim 1, further comprising (E) a cationic polymer.   An emulsified composition for hair, wherein the emulsified composition for hair according to claim 1 or 2 is a hair wax.