JP2011168513A - Additive for foamy cosmetic - Google Patents
Additive for foamy cosmetic Download PDFInfo
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- JP2011168513A JP2011168513A JP2010032478A JP2010032478A JP2011168513A JP 2011168513 A JP2011168513 A JP 2011168513A JP 2010032478 A JP2010032478 A JP 2010032478A JP 2010032478 A JP2010032478 A JP 2010032478A JP 2011168513 A JP2011168513 A JP 2011168513A
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- foaming
- honey
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 134
- 239000000654 additive Substances 0.000 title claims description 29
- 230000000996 additive effect Effects 0.000 title claims description 29
- 239000006260 foam Substances 0.000 claims abstract description 237
- 239000000490 cosmetic additive Substances 0.000 claims abstract description 77
- 235000012907 honey Nutrition 0.000 claims abstract description 73
- 229920002643 polyglutamic acid Polymers 0.000 claims abstract description 35
- 239000004480 active ingredient Substances 0.000 claims abstract description 6
- 238000005187 foaming Methods 0.000 abstract description 76
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- HEBKCHPVOIAQTA-NGQZWQHPSA-N d-xylitol Chemical compound OC[C@H](O)C(O)[C@H](O)CO HEBKCHPVOIAQTA-NGQZWQHPSA-N 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、γポリグルタミン酸及び蜂蜜を有効成分として含有し、泡状化粧料の泡立ち及び泡質を向上させることができる泡状化粧料用添加剤に関する。 The present invention relates to a foam cosmetic additive that contains γ-polyglutamic acid and honey as active ingredients and can improve foaming and foam quality of the foam cosmetic.
一般的に、使用時に泡状で使用する泡状化粧料として、例えばシャンプー、ボディーソープ、ハンドソープ、洗顔料、及び石鹸が知られている。それらの泡状化粧料は、使用時の泡立ち、泡の量、並びに泡質、例えば泡のきめ細かさ、弾力性、持続性、及び塗布部に対する密着性を向上させるためにコンディショニング成分が配合されることがある。たとえば、特許文献１，２に開示される泡状化粧料が知られている。それらの泡状化粧料は、界面活性剤の他、泡質を向上させるために特定の水溶性高分子ポリマーを含有する。特許文献１の泡状化粧料は、水溶性高分子ポリマーとして半合成高分子、例えばカチオン化デンプンを含有する。特許文献２は、水溶性高分子ポリマーとしてアクリル酸系ポリマーを含有する。 In general, shampoos, body soaps, hand soaps, facial cleansers, and soaps are known as foam cosmetics to be used in the form of foam when used. These foam cosmetics are blended with conditioning ingredients to improve foaming during use, the amount of foam, and foam quality, for example foam fineness, elasticity, durability, and adhesion to the application area. Sometimes. For example, foam cosmetics disclosed in Patent Documents 1 and 2 are known. These foam cosmetics contain a specific water-soluble polymer in order to improve the foam quality in addition to the surfactant. The foam cosmetic of Patent Document 1 contains a semi-synthetic polymer such as cationized starch as a water-soluble polymer. Patent Document 2 contains an acrylic acid polymer as a water-soluble polymer.
しかしながら、特許文献１，２の泡状化粧料は、未だ泡立ち及び泡質の向上効果が不十分であるという問題があった。また、泡立ち及び泡質を向上させるコンディショニング成分は、当初より化粧料中に含有されているため、使用目的及び適用箇所等に応じ、泡立ち及び泡質を調整することは困難である。 However, the foam cosmetics of Patent Documents 1 and 2 still have a problem that the effect of improving foaming and foam quality is still insufficient. Moreover, since the conditioning component which improves foaming and foam quality is contained in cosmetics from the beginning, it is difficult to adjust foaming and foam quality according to a use purpose, an application location, etc.
ところで、従来より、化粧料に配合される保湿性分として、蜂蜜及びγポリグルタミン酸（γＰＧＡ）が知られている（特許文献３）。しかしながら、それらの成分を併用することにより、泡状化粧料の泡立ち及び泡質を向上させる点については未だ知られていない。 By the way, honey and γ polyglutamic acid (γPGA) are conventionally known as moisturizing ingredients blended in cosmetics (Patent Document 3). However, it has not yet been known about improving the foaming and foam quality of foamy cosmetics by using these components in combination.
本発明は、蜂蜜及びγポリグルタミン酸を併用することにより、泡状化粧料の泡質を大幅に向上できることを発見したことに基づくものである。また、泡状化粧料用添加剤として構成することにより、様々な泡状化粧料に対し、簡便に泡立ち及び泡質を向上できるとともに、泡立ち及び泡質も調整することができる。 The present invention is based on the discovery that the foam quality of foam cosmetics can be greatly improved by using honey and γ-polyglutamic acid in combination. Moreover, by comprising as an additive for foam cosmetics, foaming and foam quality can be easily improved and the foaming and foam quality can be adjusted for various foam cosmetics.
本発明の目的とするところは、簡便に泡状化粧料の泡立ち及び泡質を向上できる泡状化粧料用添加剤を提供することにある。 An object of the present invention is to provide an additive for foamed cosmetics that can easily improve foaming and foam quality of the foamed cosmetics.
上記目的を達成するために、請求項１に記載の泡状化粧料用添加剤は、γポリグルタミン酸及び蜂蜜を有効成分として含有することを特徴とする。
請求項２に記載の発明は、請求項１に記載の泡状化粧料用添加剤において、前記γポリグルタミン酸は、平均分子量が５０ｋＤａ〜７０００ｋＤａであることを特徴とする。
In order to achieve the above object, the foam cosmetic additive according to claim 1 is characterized by containing γ-polyglutamic acid and honey as active ingredients.
The invention according to claim 2 is characterized in that, in the foam cosmetic additive according to claim 1, the γ polyglutamic acid has an average molecular weight of 50 kDa to 7000 kDa.
請求項３に記載の発明は、請求項２に記載の泡状化粧料用添加剤において、前記γポリグルタミン酸は、平均分子量が１０００ｋＤａ〜６０００ｋＤａであることを特徴とする。 The invention according to claim 3 is the foam cosmetic additive according to claim 2, wherein the γ-polyglutamic acid has an average molecular weight of 1000 kDa to 6000 kDa.
請求項４に記載の発明は、請求項１から請求項３のいずれか一項に記載の泡状化粧料用添加剤において、前記泡状化粧料用添加剤中における前記γポリグルタミン酸の含有量に対する前記蜂蜜の含有量の質量比は、２００〜２０００であることを特徴とする。 The invention according to claim 4 is the foam cosmetic additive according to any one of claims 1 to 3, wherein the content of the γ polyglutamic acid in the foam cosmetic additive. The mass ratio of the content of the honey with respect to is 200 to 2000.
本発明によれば、簡便に泡状化粧料の泡立ち及び泡質を向上できる泡状化粧料用添加剤を提供することができる。 ADVANTAGE OF THE INVENTION According to this invention, the foam cosmetic additive which can improve foaming and foam quality of a foam cosmetic simply can be provided.
以下、本発明の泡状化粧料用添加剤を具体化した実施形態を説明する。
本実施形態の泡状化粧料用添加剤は、有効成分としてγポリグルタミン酸及び蜂蜜を含有する。蜂蜜は、γポリグルタミン酸と併用することにより泡状化粧料の泡立ち性及び泡質を向上させる。また、蜂蜜は、γポリグルタミン酸と併用することにより泡状化粧料の保湿性能を一層向上させる。本実施形態において使用される蜂蜜の産地は、特に限定されないが、例えば中国、台湾、日本等のアジア諸国、ヨーロッパ諸国、北アメリカ諸国、ブラジル等の南アメリカ諸国、及びオーストラリア等のオセアニア諸国のいずれでもよい。また、蜂蜜の密源植物も特に限定されないが、例えばレンゲ、ニセアカシア、ローズマリー、オレンジ、レモン、ユーカリ、ミカン、クローバー、ソバ、クリ、ラベンダー、及びコーヒーが挙げられる。
Hereinafter, the embodiment which actualized the additive for foamy cosmetics of this invention is described.
The foam cosmetic additive of this embodiment contains γ polyglutamic acid and honey as active ingredients. Honey improves the foaming property and foam quality of foamy cosmetics when used in combination with γ-polyglutamic acid. In addition, honey further improves the moisturizing performance of the foamy cosmetic when used in combination with γ-polyglutamic acid. The production area of honey used in the present embodiment is not particularly limited. For example, any of Asian countries such as China, Taiwan and Japan, European countries, North American countries, South American countries such as Brazil, and Oceanian countries such as Australia. But you can. Further, the dense source plant of honey is not particularly limited, and examples thereof include astragalus, false acacia, rosemary, orange, lemon, eucalyptus, mandarin orange, clover, buckwheat, chestnut, lavender, and coffee.
泡状化粧料用添加剤中に配合される蜂蜜の一部を、蜂蜜以外の糖類及び多価アルコールから選ばれる少なくとも一種の置換成分に置換しても、泡状化粧料の泡立ち性及び泡質を向上させる効果を維持することができる。蜂蜜以外の糖類及び多価アルコールから選ばれる少なくとも一種の置換成分の蜂蜜中へ配合量は、元の蜂蜜の使用量（１００質量％）に対し、好ましくは７５質量％以下（蜂蜜２５質量％以上）、より好ましくは５０質量％以下（蜂蜜５０質量％以上）、さらに好ましくは３０質量％以下（蜂蜜７０質量％以上）である。泡状化粧料の泡立ち性及び泡質を向上させる効果を得るために、蜂蜜より安価又は入手が容易な成分に蜂蜜の一部を代替することができる。蜂蜜以外の糖類として、単糖類、例えばブドウ糖、果糖、キシロース、アラビノース、マンノース、及びガラクトース、小糖類、例えば麦芽糖、乳糖、ショ糖、トレハロース、及びラフィノース、オリゴ糖、例えばキシロオリゴ糖、イソマルトオリゴ糖、ガラクトオリゴ糖、コーヒー豆マンノオリゴ糖、大豆オリゴ糖、乳果オリゴ糖、フラクトオリゴ糖、及びラクチュロース、並びに多糖類が挙げられる。多価アルコールとして、例えばグリセリン、キシリトール、ソルビトール、プロピレングリコール、ブチレングリコール、及びジ・ポリグリセリンが挙げられる。 Even if a part of the honey blended in the additive for foamy cosmetics is replaced with at least one substitution component selected from sugars other than honey and polyhydric alcohols, the foaming properties and foam quality of the foamed cosmetics The effect of improving can be maintained. The blending amount of saccharides other than honey and polyhydric alcohol into honey is preferably 75% by mass or less (25% by mass or more of honey) with respect to the amount of original honey used (100% by mass). ), More preferably 50% by mass or less (honey 50% by mass or more), and further preferably 30% by mass or less (honey 70% by mass or more). In order to obtain the effect of improving the foamability and foam quality of the foamy cosmetic, a part of the honey can be replaced with an ingredient that is cheaper or easier to obtain than honey. As sugars other than honey, simple sugars such as glucose, fructose, xylose, arabinose, mannose, and galactose, small sugars such as maltose, lactose, sucrose, trehalose, and raffinose, oligosaccharides such as xylooligosaccharide, isomaltoligosaccharide, Examples include galactooligosaccharides, coffee bean manno-oligosaccharides, soybean oligosaccharides, dairy oligosaccharides, fructo-oligosaccharides, and lactulose, and polysaccharides. Examples of the polyhydric alcohol include glycerin, xylitol, sorbitol, propylene glycol, butylene glycol, and di-polyglycerin.
γポリグルタミン酸は、上記蜂蜜と併用することにより泡状化粧料の泡立ち性及び泡質を向上させる。また、γポリグルタミン酸は、蜂蜜と併用することにより泡状化粧料の保湿性能を一層向上させる。γポリグルタミン酸は、グルタミン酸を重合単位とするポリペプチドの一種で、γ位のカルボキシル基とα位のアミノ基がペプチド結合を形成している。γポリグルタミン酸は、天然物由来のものを使用してもよく、化学的に合成したものを使用してもよい。また、市販品を入手してもよい。γポリグルタミン酸は、納豆菌及び炭疽菌より分泌されるため、それらの菌体又は分泌物より公知の方法を用いて抽出してもよい。 γ-polyglutamic acid improves the foaming property and foam quality of the foamy cosmetic when used in combination with the honey. Moreover, (gamma) polyglutamic acid improves the moisture retention performance of foamy cosmetics further by using together with honey. γ-polyglutamic acid is a kind of polypeptide having glutamic acid as a polymerization unit, and a carboxyl group at the γ-position and an amino group at the α-position form a peptide bond. γ-polyglutamic acid may be derived from a natural product or chemically synthesized. Moreover, you may obtain a commercial item. Since γ-polyglutamic acid is secreted from Bacillus natto and Bacillus anthracis, it may be extracted from these cells or secretions using a known method.
γポリグルタミン酸の平均分子量は、特に限定されないが、好ましくは５０ｋＤａ〜７０００ｋＤａ、より好ましくは１０００ｋＤａ〜６０００ｋＤａ、さらに好ましくは２０００ｋＤａ〜５０００ｋＤａである。γポリグルタミン酸の平均分子量が５０ｋＤａ未満であると泡立ち性及び泡質を向上させる効果が低下する場合がある。γポリグルタミン酸の平均分子量が７０００ｋＤａを超えると泡立ち性及び泡質を向上させる効果が低下する場合がある。尚、γポリグルタミン酸の平均分子量は、分子ふるい、例えばゲル電気泳動、ろ過及び分子排斥クロマトグラフィーを用いることにより決定することができる。 The average molecular weight of γ polyglutamic acid is not particularly limited, but is preferably 50 kDa to 7000 kDa, more preferably 1000 kDa to 6000 kDa, and further preferably 2000 kDa to 5000 kDa. If the average molecular weight of γ polyglutamic acid is less than 50 kDa, the effect of improving foamability and foam quality may be reduced. When the average molecular weight of γ polyglutamic acid exceeds 7000 kDa, the effect of improving foamability and foam quality may be reduced. The average molecular weight of γ polyglutamic acid can be determined by using a molecular sieve such as gel electrophoresis, filtration, and molecular exclusion chromatography.
泡状化粧料用添加剤中におけるγポリグルタミン酸の含有量に対する蜂蜜の含有量の質量比（蜂蜜の含有量／γポリグルタミン酸の含有量）は、好ましくは２００〜２０００、より好ましくは５００〜１５００である。γポリグルタミン酸の含有量に対する蜂蜜の含有量の質量比が２００未満であると、γポリグルタミン酸の含有量の割合が多いため、泡状化粧料用添加剤がゲル化し、泡状化粧料との混合性及び取り扱い性が低下するおそれがある。γポリグルタミン酸の含有量に対する蜂蜜の含有量の質量比が２０００を超えると、泡立ち性及び泡質を向上させる効果が低下する場合がある。 The mass ratio of the honey content to the γ-polyglutamic acid content in the foam cosmetic additive (honey content / γ-polyglutamic acid content) is preferably 200 to 2000, more preferably 500 to 1500. It is. If the mass ratio of the content of honey to the content of γ-polyglutamic acid is less than 200, since the proportion of the content of γ-polyglutamic acid is large, the foam cosmetic additive is gelled, Mixability and handleability may be reduced. When the mass ratio of the content of honey to the content of γ-polyglutamic acid exceeds 2000, the effect of improving foaming properties and foam quality may be reduced.
泡状化粧料用添加剤は、使用時に泡状で使用される泡状化粧料に配合することにより使用される。使用時に泡状で使用される泡状化粧料としては、例えばシャンプー、ボディーソープ、ハンドソープ、洗顔料、及び石鹸が挙げられる。泡状化粧料用添加剤と泡状化粧料は、例えば泡状化粧料の成分、種類、使用目的及び適用箇所に応じ、泡立ち及び泡質を調整しながら混合される。泡状化粧料用添加剤と泡状化粧料の混合比は、所望の泡立ち及び泡質が得られる範囲であれば特に限定されないが、泡立ち及び泡質をより向上させる観点から、好ましくは質量比として０．１〜１０：１、より好ましくは０．５〜１．５：１である。尚、泡状化粧料がシャンプーの場合、好ましくは質量比として０．１〜１０：１、より好ましくは０．５〜５：１である。 The additive for foamy cosmetics is used by blending into the foamed cosmetics used in the form of foams at the time of use. Examples of the foam cosmetic used in the form of foam when used include shampoos, body soaps, hand soaps, facial cleansers, and soaps. The foam cosmetic additive and the foam cosmetic are mixed while adjusting foaming and foam quality according to, for example, the components, type, usage purpose and application location of the foam cosmetic. The mixing ratio of the foam cosmetic additive and the foam cosmetic is not particularly limited as long as desired foaming and foam quality can be obtained, but from the viewpoint of further improving foaming and foam quality, a mass ratio is preferable. 0.1 to 10: 1, more preferably 0.5 to 1.5: 1. When the foam cosmetic is a shampoo, the mass ratio is preferably 0.1 to 10: 1, more preferably 0.5 to 5: 1.
本実施形態によって発揮される効果について、以下に記載する。
（１）本実施形態の泡状化粧料用添加剤は、γポリグルタミン酸及び蜂蜜を有効成分として含有する。したがって、簡便に泡状化粧料の泡立ち及び泡質を向上させることができる。
The effects exhibited by this embodiment will be described below.
(1) The foam cosmetic additive of the present embodiment contains γ polyglutamic acid and honey as active ingredients. Therefore, foaming and foam quality of the foam cosmetic can be easily improved.
（２）また、泡状化粧料に対し、保湿性向上効果を付与することができる。
（３）また、泡状化粧料に対し、泡状化粧料の濯ぎ時の泡切れ及び洗浄時おける使用感の向上効果を付与することができる。
(2) Moreover, a moisturizing improvement effect can be provided with respect to foamy cosmetics.
(3) Moreover, the foaming cosmetics can be provided with an effect of improving the feeling of use when the foaming cosmetics are washed out and when the foamed cosmetics are rinsed.
（４）また、泡状化粧料に対し、使用後の肌の感触、例えばさっぱり感、つっぱり感のなさ、つるつる感（すべり感）、しっとり感（密着感・保湿感）、もっちり感（弾力感）、及び化粧のり・もちの良さ、並びに洗浄後の使用感の向上効果を付与することができる。 (4) Also, for foamy cosmetics, the skin feel after use, for example, a refreshing feeling, no feeling of smoothness, a smooth feeling (smooth feeling), a moist feeling (adhesion feeling / moisturizing feeling), a tight feeling (elasticity) Sensation), good makeup paste and stickiness, and an effect of improving the feeling of use after washing.
（５）本実施形態の泡状化粧料用添加剤は、使用時に泡状化粧料と混合して使用される。したがって、様々な泡状化粧料に対し、簡便に泡立ち及び泡質を調整することができる。 (5) The foam cosmetic additive of the present embodiment is used by mixing with the foam cosmetic at the time of use. Therefore, foaming and foam quality can be easily adjusted for various foamy cosmetics.
（６）本実施形態の泡状化粧料用添加剤において、γポリグルタミン酸の平均分子量は、好ましくは５０ｋＤａ〜７０００ｋＤａである。したがって、泡状化粧料の泡立ち及び泡質をより向上させることができる。 (6) In the foam cosmetic additive of the present embodiment, the average molecular weight of γ-polyglutamic acid is preferably 50 kDa to 7000 kDa. Therefore, foaming and foam quality of the foam cosmetic can be further improved.
（７）本実施形態の泡状化粧料用添加剤において、γポリグルタミン酸の含有量に対する蜂蜜の含有量の質量比は、好ましくは２００〜２０００である。したがって、泡状化粧料の泡立ち及び泡質をより向上させることができる。 (7) In the foam cosmetic additive of the present embodiment, the mass ratio of the content of honey to the content of γ-polyglutamic acid is preferably 200 to 2000. Therefore, foaming and foam quality of the foam cosmetic can be further improved.
（８）泡状化粧料用添加剤と泡状化粧料は、好ましくは質量比として０．１〜１０：１の割合で混合して使用される。したがって、泡状化粧料の泡立ち及び泡質をより向上させることができる。 (8) The foam cosmetic additive and the foam cosmetic are preferably mixed and used at a mass ratio of 0.1 to 10: 1. Therefore, foaming and foam quality of the foam cosmetic can be further improved.
（９）本実施形態の泡状化粧料用添加剤は、天然成分としてのγポリグルタミン酸及び蜂蜜から構成することができる。したがって、より安全に化粧料に適用することができる。 (9) The additive for foamy cosmetics of this embodiment can be composed of γ polyglutamic acid and honey as natural ingredients. Therefore, it can be applied to cosmetics more safely.
なお、上記実施形態は以下のように変更してもよい。
・上記実施形態の泡状化粧料用添加剤は、本発明の効果を阻害しない範囲において、一般に化粧品に共通して配合される基剤を配合してもよい。基剤としては、溶媒、例えば油分、水、及びアルコール、保湿剤、例えばヒアルロン酸、界面活性剤、酸化防止剤、ｐＨ調整剤、防腐剤、並びに香料が挙げられる。
In addition, you may change the said embodiment as follows.
-The additive for foamy cosmetics of the said embodiment may mix | blend the base generally mix | blended commonly in cosmetics in the range which does not inhibit the effect of this invention. Bases include solvents such as oils, water, and alcohols, humectants such as hyaluronic acid, surfactants, antioxidants, pH adjusters, preservatives, and perfumes.
・上記実施形態の泡状化粧料用添加剤は、本発明の効果を阻害しない範囲において、最初に化粧水、水又はお湯に適量を溶かした後、泡状化粧料と混合して使用してもよい。かかる構成により、泡状化粧料との混合性を向上させることができる。 -The foam cosmetic additive of the above embodiment is used within the range that does not impair the effects of the present invention, after first dissolving an appropriate amount in lotion, water or hot water, and then mixed with the foam cosmetic. Also good. With this configuration, the mixing property with the foamy cosmetic can be improved.
以下に実施例を挙げ、前記実施形態をさらに具体的に説明するが、本発明はこれらに限定されるものではない。
＜泡状化粧料用添加剤の調製＞
ニセアカシアが密源植物である蜂蜜に、平均分子量が５０ｋＤａ、５００ｋＤａ、２０００ｋＤａ、５０００ｋＤａ、及び７０００ｋＤａの各γポリグルタミン酸（γＰＧＡ：バイオリーダース社製）をそれぞれ０．１質量％添加した。そして、一晩攪拌することによって、各泡状化粧料用添加剤を作製した。
Examples are given below to describe the above embodiments more specifically, but the present invention is not limited to these examples.
<Preparation of foam cosmetic additive>
0.1% by mass of each γ-polyglutamic acid (γPGA: manufactured by BioLeaders) having an average molecular weight of 50 kDa, 500 kDa, 2000 kDa, 5000 kDa, and 7000 kDa was added to honey, which is a dense source plant. And each additive for foamy cosmetics was produced by stirring overnight.
＜試験例１：泡の弾力性試験１＞
上記の各泡状化粧料用添加剤と市販の泡状化粧料を混合し、泡立てた後、泡の弾力性を泡の潰れる時間を測定することにより評価した。市販の泡状化粧料として、表１に示される洗顔料である泡状化粧料Ａ，Ｂ，Ｃを使用した。各泡状化粧料用添加剤０．６ｇと泡状化粧料Ａ０．９ｇを手のひらに取り、手のひら同士を１分３０秒間擦り合わせることにより泡立てた。各泡状化粧料用添加剤０．６ｇと泡状化粧料Ｂ０．６ｇ又は泡状化粧料Ｃ０．６ｇを泡立てボールを用いて攪拌することにより泡立てた。泡立て後の各泡状化粧料について、板の上に一定量を置いて、その上に１円玉（１ｇ）１枚を乗せてから、１円玉が板に接触するまでに要する時間を測定した（Ｎ＝５）。コントロールとしての市販の各泡状化粧料のみを泡立てた場合の時間を１００とした時の相対値（平均値）を表２に示す。比較例として、蜂蜜のみから泡状化粧料用添加剤を構成したもの、γＰＧＡ（分子量：２０００ｋＤａ）のみから泡状化粧料用添加剤を構成したものについても、それぞれ同様に評価した。
<Test Example 1: Foam elasticity test 1>
Each foam cosmetic additive and a commercial foam cosmetic were mixed and foamed, and then the elasticity of the foam was evaluated by measuring the time for foam collapse. As the commercially available foam cosmetics, foam cosmetics A, B, and C, which are the face wash shown in Table 1, were used. 0.6 g of each foam cosmetic additive and 0.9 g of foam cosmetic A were taken on the palm and foamed by rubbing the palms for 1 minute 30 seconds. Each foam cosmetic additive 0.6 g and foam cosmetic B 0.6 g or foam cosmetic C 0.6 g was foamed by stirring with a foaming ball. For each foamed cosmetic after whipping, measure the time required for a 1-yen coin to contact the board after placing a certain amount on the board and placing 1-yen coin (1 g) on it. (N = 5). Table 2 shows the relative values (average values) when the time when foaming only each commercially available foam cosmetic material as a control is 100 is shown. As comparative examples, evaluations were similarly made for those in which the foam cosmetic additive was composed only of honey and in which the foam cosmetic additive was composed only of γPGA (molecular weight: 2000 kDa).
＜試験例２：泡の弾力性試験２＞
上記の各泡状化粧料用添加剤と市販の泡状化粧料を混合し、泡立てた後、泡の弾力性を泡が潰れる重さを測定することにより評価した。市販の泡状化粧料として、表１に示される泡状化粧料Ａを使用した。各泡状化粧料用添加剤０．６ｇと泡状化粧料Ａ０．９ｇを手のひらに取り、手のひら同士を１分３０秒間擦り合わせることにより泡立てた。泡立て後の泡状化粧料について、板の上に一定量を置いて、その上に１円玉（１ｇ）を１枚ずつ乗せて、１円玉が板に接触するまでに要する重さを測定した（Ｎ＝３）。コントロールとしての泡状化粧料Ａのみを泡立てた場合の重さを１００とした時の相対値（平均値）を表２に示す。比較例として、蜂蜜のみから泡状化粧料用添加剤を構成したもの、γＰＧＡ（分子量：２０００ｋＤａ）のみから泡状化粧料用添加剤を構成したものについても、それぞれ同様に評価した。
<Test Example 2: Foam elasticity test 2>
Each foam cosmetic additive described above and a commercial foam cosmetic were mixed and foamed, and then the elasticity of the foam was evaluated by measuring the weight of foam collapse. As a commercially available foam cosmetic, the foam cosmetic A shown in Table 1 was used. 0.6 g of each foam cosmetic additive and 0.9 g of foam cosmetic A were taken on the palm and foamed by rubbing the palms for 1 minute 30 seconds. About foamed cosmetics after whipping, place a certain amount on the board, put 1 yen coin (1g) on it one by one, and measure the weight required for 1 yen coin to contact the board (N = 3). Table 2 shows the relative value (average value) when the weight when only the foamy cosmetic A as a control is foamed is 100. As comparative examples, evaluations were similarly made for those in which the foam cosmetic additive was composed only of honey and in which the foam cosmetic additive was composed only of γPGA (molecular weight: 2000 kDa).
＜試験例３：保湿性試験＞
上記の各泡状化粧料用添加剤と市販の泡状化粧料を混合し、顔に塗布して洗顔した後、頬の皮膚の水分値を測定した。市販の泡状化粧料として、表１に示される泡状化粧料Ｃを使用した。各泡状化粧料用添加剤０．６ｇと泡状化粧料Ｃ０．６ｇを泡立てボールを用いて攪拌することにより泡立てた。泡立て後の泡状化粧料について、顔に塗布して常法に従い洗顔し、洗浄後、余分な水をタオルでふき取った。洗顔後の頬の皮膚の水分値を所定時間経過毎に皮膚粘弾性測定装置キュートメーター（ＭＰＡ５８０：インテグラル社製）にて測定した（Ｎ＝２）。コントロールとしての洗顔前の頬の皮膚の水分値を１００とした場合の相対値を表４に示す。比較例として、蜂蜜のみから泡状化粧料用添加剤を構成したもの、γＰＧＡ（分子量：２０００ｋＤａ）のみから泡状化粧料用添加剤を構成したものについても、それぞれ同様に評価した。また、泡状化粧料用添加剤と混合しない泡状化粧料Ｃのみを用いて洗顔した場合も同様に評価した。
<Test Example 3: Moisturizing test>
Each of the above foam cosmetic additives and a commercial foam cosmetic were mixed, applied to the face and washed, and then the moisture value of the cheek skin was measured. As a commercially available foam cosmetic, foam cosmetic C shown in Table 1 was used. Each foam cosmetic additive 0.6g and foam cosmetic C 0.6g were foamed by stirring with a foaming ball. The foamed cosmetic after foaming was applied to the face and washed according to a conventional method. After washing, excess water was wiped off with a towel. The moisture content of the cheek skin after face washing was measured with a skin viscoelasticity measuring device cut meter (MPA580: manufactured by Integral) every predetermined time (N = 2). Table 4 shows the relative values when the moisture value of the skin of the cheeks before washing as a control is taken as 100. As comparative examples, evaluations were similarly made for those in which the foam cosmetic additive was composed only of honey and in which the foam cosmetic additive was composed only of γPGA (molecular weight: 2000 kDa). Moreover, the same evaluation was performed when the face was washed using only the foam cosmetic C that was not mixed with the foam cosmetic additive.
＜試験例４：泡立ち及び泡質の評価＞
上記の各泡状化粧料用添加剤と市販の泡状化粧料を混合し、泡立てた後、泡立ち及び泡質について官能評価を行った。市販の泡状化粧料として、表１に示される泡状化粧料Ｂ，Ｃを使用した。尚、コントロールとして各泡状化粧料用添加剤と混合しない泡状化粧料Ｂ，Ｃを使用した。比較例として、蜂蜜のみから泡状化粧料用添加剤を構成したもの、γＰＧＡ（平均分子量：２０００ｋＤａ）のみから泡状化粧料用添加剤を構成したものを使用した。各泡状化粧料用添加剤０．６ｇと泡状化粧料Ｂ０．６ｇ又は泡状化粧料Ｃ０．６ｇを泡立てボールを用いて１分３０秒（約１５０回転）攪拌することにより泡立てた。泡立て時において、パネラー（１０名）が泡立ちやすさ、泡の量、泡のきめの細かさ、泡の弾力性、及び泡の密着性についてコントロールより良いか否かについて判断した。各パネラーの判断より下記基準に従い官能評価の結果とした。結果を表５に示す。
◎：コントロールより良いと答えた人数が８名以上
○：コントロールより良いと答えた人数が６名以上、８名未満
△：コントロールより良いと答えた人数が４名以上、６名未満
×：コントロールより良いと答えた人数が４名未満
<Test Example 4: Evaluation of foaming and foam quality>
Each foam cosmetic additive described above and a commercially available foam cosmetic were mixed and foamed, and then sensory evaluation was performed on foaming and foam quality. As commercially available foam cosmetics, foam cosmetics B and C shown in Table 1 were used. In addition, the foam cosmetics B and C which were not mixed with each additive for foam cosmetics were used as control. As comparative examples, a foam cosmetic additive composed only of honey and a foam cosmetic additive composed only of γPGA (average molecular weight: 2000 kDa) were used. Each foam cosmetic additive 0.6 g and foam cosmetic B 0.6 g or foam cosmetic C 0.6 g was foamed by stirring for 1 minute 30 seconds (about 150 rotations) using a foaming ball. At the time of foaming, panelists (10 persons) judged whether the ease of foaming, the amount of foam, the fineness of foam, the elasticity of foam, and the adhesion of foam were better than the control. The results of sensory evaluation were determined according to the following criteria from the judgment of each panel. The results are shown in Table 5.
◎: More than 8 people answered that it was better than control ○: More than 6 people answered that it was better than control △: More than 4 people answered that it was better than control ×: Less than 6 people Less than 4 people answered better
＜試験例５：泡立て時の泡立ち、泡質及び使用感等、化粧料の濯ぎ時の使用感等、並びに洗浄後の使用感等の評価＞
蜂蜜とγＰＧＡ（平均分子量２０００ｋＤａ）を含有する泡状化粧料用添加剤と市販の泡状化粧料を混合した後、泡立て時の泡立ち、泡質及び使用感等、化粧料の濯ぎ時の使用感等、並びに使用後の使用感等の評価を行った。市販の泡状化粧料として、表１に示される泡状化粧料Ｂ又はＣを使用した。尚、コントロールとして泡状化粧料用添加剤と混合しない泡状化粧料Ｂ又はＣを使用した。比較例として、蜂蜜のみから泡状化粧料用添加剤を構成したものを使用した。
<Test Example 5: Evaluation of foaming at the time of foaming, foam quality and feeling of use, feeling of use when rinsing cosmetics, and feeling after use, etc.>
Foam cosmetic additive containing honey and γPGA (average molecular weight 2000 kDa) and commercially available foam cosmetic are mixed, then foaming, foam quality and feeling of use, etc. And the feeling after use were evaluated. As a commercially available foam cosmetic, foam cosmetic B or C shown in Table 1 was used. In addition, the foam cosmetics B or C which are not mixed with the additive for foam cosmetics were used as control. As a comparative example, a foam cosmetic additive composed only of honey was used.
上記泡状化粧料用添加剤０．６ｇと泡状化粧料Ｂ又はＣ０．６ｇを泡立てボールを用いて１分３０秒（約１５０回転）攪拌することにより泡立てた。泡立て後の泡状化粧料を用いて、パネラー（１０名）が常法に従い洗顔し、洗浄後、余分な水をタオルでふき取った。パネラーは、泡立て時、濯ぎ時、及び洗浄後（使用後）における下記表６に示される泡立ち、泡質又は使用感の各評価を行った。コントロールの評価を３（普通）とした場合、下記に示される基準に従い点数を付けた。パネラーの平均点を表６に示す。
１０：非常に良い、５：良い、３：普通（コントロール）、２：悪い、１：非常に悪いとして評価した。
The above foam cosmetic additive 0.6g and foam cosmetic B or C 0.6g were foamed by stirring for 1 minute 30 seconds (about 150 rotations) using a foaming ball. Panelers (10 persons) washed their face according to a conventional method using the foamed cosmetic material after whipping. After washing, excess water was wiped off with a towel. The panelists evaluated each of foaming, foam quality, and feeling of use shown in Table 6 below when foaming, rinsing, and after washing (after use). When the evaluation of the control was 3 (normal), the score was assigned according to the criteria shown below. Table 6 shows the average points of the panelists.
10: very good, 5: good, 3: normal (control), 2: bad, 1: very bad.
＜試験例６：泡状化粧料として石鹸を使用した場合の泡立ち及び泡質の評価＞
上記「泡状化粧料用添加剤の調製」欄における各泡状化粧料用添加剤と市販の泡状化粧料を混合し、泡立てた後、泡立ち及び泡質について官能評価を行った。市販の泡状化粧料として、石鹸（成分：石ケン素地、（シャボン玉浴用無添加石鹸：シャボン玉石けん社製））を使用した。尚、コントロールとして泡状化粧料用添加剤と混合しない石鹸を使用した。比較例として、蜂蜜のみから泡状化粧料用添加剤を構成したもの、γＰＧＡ（平均分子量：２０００ｋＤａ）のみから泡状化粧料用添加剤を構成したものをそれぞれ使用した。
<Test Example 6: Evaluation of foaming and foam quality when soap is used as the foam cosmetic>
Each foam cosmetic additive in the “Preparation of foam cosmetic additive” column and a commercial foam cosmetic were mixed and foamed, and then sensory evaluation was performed on foaming and foam quality. As a commercially available foamy cosmetic, soap (component: soap base, (additive soap for soap bubble bath: manufactured by soap bubble soap)) was used. As a control, a soap that was not mixed with the foam cosmetic additive was used. As comparative examples, those in which the additive for foamed cosmetics was composed only of honey and those in which the additive for foamed cosmetics was composed only of γPGA (average molecular weight: 2000 kDa) were used.
上記石鹸に各泡状化粧料用添加剤０．６ｇを添加した後、泡立てネット（ＣＡＣ化粧品社製）を用いて、常法に従い１分間石鹸を泡立てた。泡立て時において、パネラー（１０名）が泡立ちやすさ、泡の量、泡のきめの細かさ、泡の弾力性、及び泡の密着性についてコントロールより良いか否かについて判断した。各パネラーの判断より、下記基準に従い官能評価の結果とした。結果を表７に示す。
◎：コントロールより良いと答えた人数が８名以上
○：コントロールより良いと答えた人数が６名以上、８名未満
△：コントロールより良いと答えた人数が４名以上、６名未満
×：コントロールより良いと答えた人数が４名未満
After 0.6 g of each foam cosmetic additive was added to the soap, the soap was foamed for 1 minute according to a conventional method using a foaming net (CAC Cosmetics Co., Ltd.). At the time of foaming, panelists (10 persons) judged whether the ease of foaming, the amount of foam, the fineness of foam, the elasticity of foam, and the adhesion of foam were better than the control. Based on the judgment of each panel, the result of sensory evaluation was determined according to the following criteria. The results are shown in Table 7.
◎: More than 8 people answered that it was better than control ○: More than 6 people answered that it was better than control △: More than 4 people answered that it was better than control ×: Less than 6 people Less than 4 people answered better
＜試験例７：泡状化粧料としてシャンプーを使用した場合の泡立ち及び泡質の評価＞
上記「泡状化粧料用添加剤の調製」欄における各泡状化粧料用添加剤と市販の泡状化粧料を混合した後、泡立ち及び泡質について官能評価を行った。市販の泡状化粧料として、表８に示されるシャンプーを使用した。尚、コントロールとして泡状化粧料用添加剤と混合しないシャンプーを使用した。比較例として、蜂蜜のみから泡状化粧料用添加剤を構成したもの、γＰＧＡ（平均分子量：２０００ｋＤａ）のみから泡状化粧料用添加剤を構成したものをそれぞれ使用した。
<Test Example 7: Evaluation of foaming and foam quality when shampoo is used as foamy cosmetics>
After each foam cosmetic additive in the above-mentioned "Preparation of foam cosmetic additive" column and a commercially available foam cosmetic were mixed, sensory evaluation was performed on foaming and foam quality. The shampoo shown in Table 8 was used as a commercially available foam cosmetic. As a control, a shampoo that was not mixed with the foam cosmetic additive was used. As comparative examples, those in which the additive for foamed cosmetics was composed only of honey and those in which the additive for foamed cosmetics was composed only of γPGA (average molecular weight: 2000 kDa) were used.
シャンプー３．０ｇに各泡状化粧料用添加剤０．６ｇを添加した後、シャンプーを手のひらの上で泡立てた。泡立て時において、パネラー（１０名）が泡立ちやすさ、泡の量、泡のきめの細かさ、及び使用時のすべり感（指通り）についてコントロールより良いか否かについて判断した。各パネラーの判断より、下記基準に従い官能評価の結果とした。結果を表９に示す。
◎：コントロールより良いと答えた人数が８名以上
○：コントロールより良いと答えた人数が６名以上、８名未満
△：コントロールより良いと答えた人数が４名以上、６名未満
×：コントロールより良いと答えた人数が４名未満
After adding 0.6 g of each foam cosmetic additive to 3.0 g of shampoo, the shampoo was foamed on the palm. At the time of foaming, panelists (10 persons) judged whether the foaming was easy, the amount of foam, the fineness of the foam, and the slipping feeling during use (as per finger) was better than the control. Based on the judgment of each panel, the result of sensory evaluation was determined according to the following criteria. The results are shown in Table 9.
◎: More than 8 people answered that it was better than control ○: More than 6 people answered that it was better than control △: More than 4 people answered that it was better than control ×: Less than 6 people Less than 4 people answered better
＜試験例８：蜂蜜の一部を蜂蜜以外の糖類又はグリセリンに置換した場合の泡の弾力性、泡立ち及び泡質の評価＞
ニセアカシアが蜜源植物である蜂蜜に置換成分として果糖ブドウ糖液糖又はグリセリンを表１０に示される割合で混合することにより各蜂蜜混合物を調製した。その蜂蜜混合物に平均分子量２０００ｋＤａのγＰＧＡ（バイオリーダース社製）をそれぞれ０．１％添加することにより泡状化粧料用添加剤を調製した。該泡状化粧料用添加剤０．６ｇと泡状化粧料Ｂ０．６ｇを泡立てボールを用いて攪拌することにより泡立てた。泡立て後の各泡状化粧料の泡の弾力性について、実施例１と同様に泡の上に１円玉（１ｇ）１枚を乗せてから、１円玉が板に接触するまでに要する時間を測定することにより評価した。コントロールとしての泡状化粧料Ｂのみを泡立てた場合の時間を１００とした時の相対値（平均値）を表１０に示す。
<Test Example 8: Evaluation of foam elasticity, foaming and foam quality when a part of honey is replaced with sugars other than honey or glycerin>
Each honey mixture was prepared by mixing fructose dextrose liquid sugar or glycerin as a substitute component in the ratio shown in Table 10 to the honey whose false acacia is a honey source plant. Foam cosmetic additives were prepared by adding 0.1% each of γPGA (BioLeaders) having an average molecular weight of 2000 kDa to the honey mixture. The foam cosmetic additive 0.6 g and the foam cosmetic B 0.6 g were foamed by stirring with a foaming ball. About the elasticity of the foam of each foamy cosmetic after foaming, the time required for the 1 yen coin to contact the plate after placing 1 yen coin (1 g) on the foam as in Example 1. Was evaluated by measuring. Table 10 shows the relative value (average value) when the time when only foamed cosmetic B as a control is foamed is 100.
また、泡立て後の各泡状化粧料について、パネラー（１０名）が泡立ちやすさ、泡の量、泡のきめの細かさ、泡の弾力性、及び泡の密着性についてコントロールより良いか否かについて判断した。各パネラーの判断より下記基準に従い官能評価の結果とした。結果を表１１に示す。
◎：コントロールより良いと答えた人数が８名以上
○：コントロールより良いと答えた人数が６名以上、８名未満
△：コントロールより良いと答えた人数が４名以上、６名未満
×：コントロールより良いと答えた人数が４名未満
In addition, for each foam cosmetic after foaming, whether panelists (10 persons) are better than controls for foaming ease, amount of foam, fineness of foam, foam elasticity, and foam adhesion Judged about. The results of sensory evaluation were determined according to the following criteria from the judgment of each panel. The results are shown in Table 11.
◎: More than 8 people answered that it was better than control ○: More than 6 people answered that it was better than control △: More than 4 people answered that it was better than control ×: Less than 6 people Less than 4 people answered better
＜試験例９：蜂蜜とγＰＧＡの配合比率の検討＞
泡状化粧料用添加剤中における蜂蜜とγＰＧＡの配合比率を変えた場合の泡立ち及び泡質について評価した。ニセアカシアが密源植物である蜂蜜に、平均分子量が２０００ｋＤａのγＰＧＡ（バイオリーダース社製）を０．０５質量％（γＰＧＡの含有量に対する蜂蜜の含有量の質量比：１９９９）、０．１質量％（同質量比：９９９）、０．３質量％（同質量比：３３２）、０．５質量％（同質量比：１９９）、及び１．３質量％（同質量比：７６）それぞれ添加した。そして、一晩攪拌することによって、各泡状化粧料用添加剤を作製した。
<Test Example 9: Examination of mixing ratio of honey and γPGA>
Foaming and foam quality were evaluated when the blending ratio of honey and γPGA in the foam cosmetic additive was changed. 0.05 mass% (mass ratio of the content of honey to the content of γPGA: 1999), 0.1 mass of γPGA (manufactured by BioLeaders Co., Ltd.) having an average molecular weight of 2000 kDa, % (Same mass ratio: 999), 0.3 mass% (same mass ratio: 332), 0.5 mass% (same mass ratio: 199), and 1.3 mass% (same mass ratio: 76) are added respectively. did. And each additive for foamy cosmetics was produced by stirring overnight.
各泡状化粧料用添加剤と市販の泡状化粧料を混合する際の混合性、泡立ちを評価した。市販の泡状化粧料として、泡状化粧料Ｂ又はＣを使用した。各泡状化粧料用添加剤０．６ｇと泡状化粧料Ｂ又はＣ０．６ｇを手のひらに取り、手のひらを擦り合わせることにより泡立てた。コントロールとして泡状化粧料用添加剤と混合しない泡状化粧料Ｂ又はＣを使用した。泡立て時において、パネラー（１０名）が泡立ちやすさ、及び混合性についてコントロールより良いか否かについて判断した。混合性の評価は、泡状化粧料用添加剤と泡状化粧料Ｂ又はＣを混合する際、溶液がゲル化することにより、混合性及び取り扱い性が低下するか否かの観点から行った。各パネラーの判断より下記基準に従い官能評価の結果とした。結果を表１２に示す。表中の「蜂蜜の質量比」は、γＰＧＡの含有量に対する蜂蜜の含有量の質量比を示す。
◎：コントロールより良いと答えた人数が８名以上
○：コントロールより良いと答えた人数が６名以上、８名未満
△：コントロールより良いと答えた人数が４名以上、６名未満
×：コントロールより良いと答えた人数が４名未満
The mixing property and foaming at the time of mixing each foam cosmetic additive and commercially available foam cosmetic were evaluated. Foam cosmetic B or C was used as a commercially available foam cosmetic. 0.6 g of each foam cosmetic additive and 0.6 g of foam cosmetic B or C were taken on the palm and foamed by rubbing the palm together. As a control, a foam cosmetic B or C that was not mixed with an additive for foam cosmetic was used. At the time of foaming, it was judged whether the panelists (10 persons) were better than the control in terms of ease of foaming and mixing. The evaluation of the mixing property was performed from the viewpoint of whether the mixing property and the handling property are reduced due to gelation of the solution when the foam cosmetic additive and the foam cosmetic B or C are mixed. . The results of sensory evaluation were determined according to the following criteria from the judgment of each panel. The results are shown in Table 12. “Mass ratio of honey” in the table indicates the mass ratio of the honey content to the γPGA content.
◎: More than 8 people answered that it was better than control ○: More than 6 people answered that it was better than control △: More than 4 people answered that it was better than control ×: Less than 6 people Less than 4 people answered better
＜試験例１０：泡状化粧料用添加剤と泡状化粧料の配合比率の検討＞
泡状化粧料用添加剤と泡状化粧料の混合比率を変えた場合の泡立ち及び泡質について評価した。蜂蜜とγＰＧＡ（平均分子量２０００ｋＤａ）を含有する泡状化粧料用添加剤と市販の泡状化粧料を所定の比率で混合した後、泡立て時における泡立ちの評価を行った。市販の泡状化粧料として、表１に示される泡状化粧料Ａ，Ｂ，Ｃを使用した。泡立て方法は、試験例１の方法に従った。尚、コントロールとして泡状化粧料用添加剤と混合しない各泡状化粧料を使用した。泡立て後の泡状化粧料について、パネラー（１０名）が泡立ちやすさについて各コントロールより良いか否かについて判断した。各パネラーの判断より下記基準に従い官能評価の結果とした。結果を表１３に示す。
◎：コントロールより良いと答えた人数が８名以上
○：コントロールより良いと答えた人数が６名以上、８名未満
△：コントロールより良いと答えた人数が４名以上、６名未満
×：コントロールより良いと答えた人数が４名未満
<Test Example 10: Examination of blending ratio of foam cosmetic additive and foam cosmetic>
Foaming and foam quality were evaluated when the mixing ratio of the foam cosmetic additive and foam cosmetic was changed. Foam cosmetic additives containing honey and γPGA (average molecular weight 2000 kDa) and a commercial foam cosmetic were mixed at a predetermined ratio, and then foaming was evaluated during foaming. As commercially available foam cosmetics, foam cosmetics A, B, and C shown in Table 1 were used. The foaming method followed the method of Test Example 1. In addition, each foam cosmetic which is not mixed with the additive for foam cosmetics was used as control. About the foam cosmetic after foaming, it was judged whether a panelist (10 persons) was better than each control about foaming ease. The results of sensory evaluation were determined according to the following criteria from the judgment of each panel. The results are shown in Table 13.
◎: More than 8 people answered that it was better than control ○: More than 6 people answered that it was better than control △: More than 4 people answered that it was better than control ×: Less than 6 people Less than 4 people answered better
次に、上記実施形態及び別例から把握できる技術的思想について、以下に追記する。（ａ）前記泡状化粧料用添加剤は、泡状化粧料の配合量に対し、質量比として０．１〜１０の割合で混合して使用される前記泡状化粧料用添加剤の使用方法。 Next, the technical idea that can be grasped from the above embodiment and other examples will be described below. (A) Use of the additive for foam cosmetics used by mixing the foam cosmetic additive in a mass ratio of 0.1 to 10 with respect to the blending amount of the foam cosmetic. Method.
Claims (4)
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| JP2002145723A (en) * | 2000-11-07 | 2002-05-22 | Ichimaru Pharcos Co Ltd | Cosmetic containing y-polyglutamic acid or its salt |
| JP2004210699A (en) * | 2002-12-27 | 2004-07-29 | Ichimaru Pharcos Co Ltd | Cosmetic composition |
| JP2006131507A (en) * | 2004-11-02 | 2006-05-25 | Etsuko Yano | Cosmetic and manufacturing method therefor |
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| JP2009057347A (en) * | 2007-09-03 | 2009-03-19 | Toyobo Co Ltd | COSMETIC CONTAINING POLY-gamma-L-GLUTAMIC ACID OR ITS SALT |
| JP2009196971A (en) * | 2008-01-24 | 2009-09-03 | Fancl Corp | Detergent composition |
| JP2009275200A (en) * | 2008-05-19 | 2009-11-26 | B Bee:Kk | Method for producing honey soap |
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|---|---|---|---|---|
| JPS6490297A (en) * | 1987-09-30 | 1989-04-06 | Nobuyasu Muranaka | Toilet soap containing chinese medicine |
| JP2002145723A (en) * | 2000-11-07 | 2002-05-22 | Ichimaru Pharcos Co Ltd | Cosmetic containing y-polyglutamic acid or its salt |
| JP2004210699A (en) * | 2002-12-27 | 2004-07-29 | Ichimaru Pharcos Co Ltd | Cosmetic composition |
| JP2006131507A (en) * | 2004-11-02 | 2006-05-25 | Etsuko Yano | Cosmetic and manufacturing method therefor |
| JP2007320889A (en) * | 2006-05-31 | 2007-12-13 | Umo Inc Co Ltd | Method for preparing face-beautifying medicine |
| JP2008120725A (en) * | 2006-11-10 | 2008-05-29 | Toyobo Co Ltd | External preparation for skin |
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| JP2009196971A (en) * | 2008-01-24 | 2009-09-03 | Fancl Corp | Detergent composition |
| JP2009275200A (en) * | 2008-05-19 | 2009-11-26 | B Bee:Kk | Method for producing honey soap |
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